KR100599466B1 - 전달 수소화 방법 및 촉매 - Google Patents

전달 수소화 방법 및 촉매 Download PDF

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Publication number
KR100599466B1
KR100599466B1 KR1019997008700A KR19997008700A KR100599466B1 KR 100599466 B1 KR100599466 B1 KR 100599466B1 KR 1019997008700 A KR1019997008700 A KR 1019997008700A KR 19997008700 A KR19997008700 A KR 19997008700A KR 100599466 B1 KR100599466 B1 KR 100599466B1
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South Korea
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group
catalyst
optionally substituted
hydrocarbyl
formula
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Expired - Fee Related
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KR1019997008700A
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English (en)
Korean (ko)
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KR20010005633A (ko
Inventor
블랙커앤드류존
멜러벤제임스
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아베시아 리미티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/34—Sulfonyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/34—Sulfonyl groups
    • B01J2540/345—Sulfonyl groups being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019997008700A 1997-03-26 1998-03-20 전달 수소화 방법 및 촉매 Expired - Fee Related KR100599466B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9706321.8A GB9706321D0 (en) 1997-03-26 1997-03-26 Catalytic hydrogenation
GB9706321.8 1997-03-26
PCT/GB1998/000862 WO1998042643A1 (en) 1997-03-26 1998-03-20 Transfer hydrogenation process and catalyst

Publications (2)

Publication Number Publication Date
KR20010005633A KR20010005633A (ko) 2001-01-15
KR100599466B1 true KR100599466B1 (ko) 2006-07-12

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KR1019997008700A Expired - Fee Related KR100599466B1 (ko) 1997-03-26 1998-03-20 전달 수소화 방법 및 촉매

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Country Link
US (2) US6372931B1 (enExample)
EP (1) EP0971865B1 (enExample)
JP (1) JP4090078B2 (enExample)
KR (1) KR100599466B1 (enExample)
CN (1) CN1130324C (enExample)
AT (1) ATE222223T1 (enExample)
AU (1) AU739341B2 (enExample)
CA (1) CA2284777C (enExample)
CZ (1) CZ296027B6 (enExample)
DE (1) DE69807199T2 (enExample)
DK (1) DK0971865T3 (enExample)
ES (1) ES2182288T3 (enExample)
GB (1) GB9706321D0 (enExample)
HU (1) HU226707B1 (enExample)
IL (1) IL131913A (enExample)
NO (1) NO312663B1 (enExample)
PT (1) PT971865E (enExample)
WO (1) WO1998042643A1 (enExample)

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US6353112B1 (en) 1998-07-17 2002-03-05 The University Of Tennessee Research Corporation Sultams: Solid phase and other synthesis of anti-HIV compounds and compositions
US6562850B1 (en) 1998-07-17 2003-05-13 The University Of Tennessee Research Corporation Methods of synthesizing sultams and anti-viral compositions
GB9821067D0 (en) 1998-09-29 1998-11-18 Zeneca Ltd Transfer hydrogenation process
JP2000327659A (ja) * 1999-03-15 2000-11-28 Mitsubishi Chemicals Corp 光学活性ピリジルアルコール類の製造方法
US6458962B1 (en) 1999-03-25 2002-10-01 The University Of Tennesseee Research Corporation Sultams: catalyst systems for asymmetric reduction of a C=N intermediate biological compositions and methods for making the sultams
SK19372001A3 (sk) * 1999-07-01 2002-04-04 Merck & Co., Inc. Spôsob výroby (R)-1-(3,5-bis(trifluórmetyl)fenyl)etan-1-olu a spôsob jeho čistenia
FR2796938B1 (fr) * 1999-07-29 2004-04-02 Ppg Sipsy Nouveaux derives chiraux n-substitues de la norephedrine, leur preparation et leur utilisation pour la synthese de composes fonctionnalises optiquement actifs par transfert d'hydrogene
GB9919118D0 (en) * 1999-08-14 1999-10-13 Avecia Ltd Transfer hydrogenation process
EP1132372A3 (en) 2000-03-06 2003-11-19 Solvias AG Bicyclic 1,3-aminoalcohols, d8-metal complexes and hydrogenation processes
JP3720235B2 (ja) * 2000-03-14 2005-11-24 高砂香料工業株式会社 光学活性ルテニウムホスフィン錯体の製造方法及び該錯体を用いた光学活性アルコールの製造方法
US6534653B2 (en) 2000-04-13 2003-03-18 Solvias Ag 3,5-Dioxa-8-aza-tricyclo[5.2.1.00,0]decane-9-methanols, their metal complexes and enantio-selective hydrogenation processes
GB0029356D0 (en) * 2000-12-01 2001-01-17 Avecia Ltd Transfer hydrogenation
EP1346972A4 (en) * 2000-12-25 2005-06-01 Ajinomoto Kk PROCESS FOR PREPARING OPTICALLY ACTIVE HALOHYDRIN COMPOUND
JP5008800B2 (ja) * 2001-03-13 2012-08-22 株式会社ダイセル イリジウム化合物を触媒とする酸化還元方法
US8828902B2 (en) 2001-07-12 2014-09-09 Reaxa Limited Microencapsulated catalyst methods of preparation and method of use thereof
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US7161008B2 (en) 2002-05-03 2007-01-09 Sanofi - Aventis Deutschland GmbH Optically active β-aminoketones, optically active 1,3-amino alcohols and processes for preparing them
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ITPD20040115A1 (it) * 2004-05-04 2004-08-04 Univ Degli Studi Udine Complessi di rutenio con 2-(amminometil)piridine e fosfine, loro preparazione ed uso come catalizzatori
CN101176853B (zh) * 2006-11-09 2010-11-17 中国科学院大连化学物理研究所 手性二胺-金属配合物多相催化剂及制备方法和应用
JPWO2008059854A1 (ja) 2006-11-16 2010-03-04 アステラス製薬株式会社 ピペリジン誘導体またはその塩
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ITPD20070237A1 (it) * 2007-07-11 2009-01-12 Univ Degli Studi Udine Nuovi leganti della classe della benzo[h]chinolina e complessi di metalli di transizione che li contengono e uso di tali complessi come catalizzatori
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JP5536541B2 (ja) * 2009-07-13 2014-07-02 高砂香料工業株式会社 ルテニウム−ジアミン錯体および光学活性化合物の製造方法
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TWI535442B (zh) 2010-05-10 2016-06-01 Kyowa Hakko Kirin Co Ltd A nitrogen-containing heterocyclic compound having an action of inhibiting the production of canine erythritine
JP5680878B2 (ja) 2010-05-13 2015-03-04 関東化学株式会社 光学活性アルコールの製造方法
JP5656474B2 (ja) 2010-06-28 2015-01-21 関東化学株式会社 脂肪族光学活性フルオロアルコールの製造方法
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CN103058897A (zh) * 2012-12-27 2013-04-24 苏州大学 一种手性β-羟基磺酰胺的制备方法
CN105050983A (zh) 2013-03-15 2015-11-11 微麦德斯公司 用于制备烷基呋喃的方法
CN104059009A (zh) * 2013-03-21 2014-09-24 四川金辉药业有限公司 一种依折麦布重要中间体的合成方法
BR112017026103B1 (pt) 2015-06-04 2023-10-03 Sol-Gel Technologies Ltd Composições tópicas com composto inibidor de hedgehog, sistema de entrega tópica e seus usos
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CN107602357B (zh) * 2017-09-28 2020-06-02 万华化学集团股份有限公司 一种制备薄荷酮的方法
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Publication number Publication date
AU6739198A (en) 1998-10-20
JP4090078B2 (ja) 2008-05-28
DK0971865T3 (da) 2002-12-09
ATE222223T1 (de) 2002-08-15
IL131913A0 (en) 2001-03-19
CN1130324C (zh) 2003-12-10
EP0971865A1 (en) 2000-01-19
US20020156282A1 (en) 2002-10-24
US6545188B2 (en) 2003-04-08
DE69807199D1 (de) 2002-09-19
JP2002501490A (ja) 2002-01-15
ES2182288T3 (es) 2003-03-01
HUP0002058A2 (hu) 2000-10-28
NO994677L (no) 1999-11-24
EP0971865B1 (en) 2002-08-14
KR20010005633A (ko) 2001-01-15
NO994677D0 (no) 1999-09-24
NO312663B1 (no) 2002-06-17
GB9706321D0 (en) 1997-05-14
DE69807199T2 (de) 2003-05-08
CA2284777C (en) 2007-07-17
CZ296027B6 (cs) 2005-12-14
US6372931B1 (en) 2002-04-16
WO1998042643A1 (en) 1998-10-01
IL131913A (en) 2004-05-12
AU739341B2 (en) 2001-10-11
MX9908650A (es) 2000-04-30
CZ337499A3 (cs) 1999-12-15
HU226707B1 (en) 2009-07-28
CN1257468A (zh) 2000-06-21
PT971865E (pt) 2002-11-29
CA2284777A1 (en) 1998-10-01

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