KR100577629B1 - 캡슐화된 활성제 및 이의 제조방법 - Google Patents
캡슐화된 활성제 및 이의 제조방법 Download PDFInfo
- Publication number
- KR100577629B1 KR100577629B1 KR1020007011990A KR20007011990A KR100577629B1 KR 100577629 B1 KR100577629 B1 KR 100577629B1 KR 1020007011990 A KR1020007011990 A KR 1020007011990A KR 20007011990 A KR20007011990 A KR 20007011990A KR 100577629 B1 KR100577629 B1 KR 100577629B1
- Authority
- KR
- South Korea
- Prior art keywords
- active agent
- particles
- encapsulated
- polymer
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
- B01J13/206—Hardening; drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2989—Microcapsule with solid core [includes liposome]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8312798P | 1998-04-27 | 1998-04-27 | |
| US60/083,127 | 1998-04-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010043104A KR20010043104A (ko) | 2001-05-25 |
| KR100577629B1 true KR100577629B1 (ko) | 2006-05-10 |
Family
ID=22176365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020007011990A Expired - Fee Related KR100577629B1 (ko) | 1998-04-27 | 1999-04-27 | 캡슐화된 활성제 및 이의 제조방법 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6224793B1 (https=) |
| EP (1) | EP1077763B1 (https=) |
| JP (2) | JP2002513045A (https=) |
| KR (1) | KR100577629B1 (https=) |
| CN (1) | CN1207090C (https=) |
| AT (1) | ATE259257T1 (https=) |
| AU (1) | AU3666799A (https=) |
| BR (1) | BR9910337B1 (https=) |
| CA (1) | CA2330472C (https=) |
| DE (1) | DE69914739T2 (https=) |
| ES (1) | ES2212552T3 (https=) |
| WO (1) | WO1999055454A1 (https=) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2205812T3 (es) * | 1998-04-27 | 2004-05-01 | Essex Specialty Products, Inc. | Metodo para unir un vidrio de ventana a un sustrato utilizando una composicion adhesiva con funcionalidad silano. |
| JP2000044636A (ja) * | 1998-05-27 | 2000-02-15 | Hitachi Chem Co Ltd | 熱硬化性樹脂組成物及びこれを用いたコイルの製造法 |
| JP2000273323A (ja) * | 1999-03-24 | 2000-10-03 | Hitachi Chem Co Ltd | 硬化剤組成物、熱硬化性樹脂組成物、これを用いた管ライニング材及び管ライニング工法 |
| JP2001200021A (ja) * | 2000-01-19 | 2001-07-24 | Hitachi Chem Co Ltd | 樹脂組成物 |
| US6518330B2 (en) * | 2001-02-13 | 2003-02-11 | Board Of Trustees Of University Of Illinois | Multifunctional autonomically healing composite material |
| GB2377661B (en) | 2001-07-20 | 2005-04-20 | Univ Newcastle | Methods of manufacturing particles |
| MXPA03002222A (es) * | 2002-03-28 | 2004-10-29 | Rohm & Haas | Polvos de recubrimiento, metodos para su elaboracion y articulos formados a partir de los mismos. |
| US7179766B2 (en) * | 2002-12-19 | 2007-02-20 | Sud-Chemie Inc. | Method and apparatus for production of enrobed catalyst pastilles or flakes |
| US7192991B2 (en) * | 2003-11-26 | 2007-03-20 | 3M Innovative Properties Company | Cationically curable composition |
| DE102004020429A1 (de) * | 2004-04-27 | 2005-11-24 | Degussa Ag | Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind und (teil-)kristalline Harze enthalten |
| US7566747B2 (en) * | 2004-05-07 | 2009-07-28 | The Board Of Trustees Of The University Of Illinois | Wax particles for protection of activators, and multifunctional autonomically healing composite materials |
| JP4733933B2 (ja) * | 2004-06-18 | 2011-07-27 | 東レ・ダウコーニング株式会社 | 硬化性オルガノポリシロキサン組成物 |
| EP1784302B1 (en) * | 2004-09-01 | 2016-07-06 | Encapsys, Llc | Encapsulated cure systems |
| EP1690528A1 (de) * | 2005-02-11 | 2006-08-16 | Abbott GmbH & Co. KG | Herstellung von Dosierungsformen mit einer festen Dispersion eines mikrokristallinen Wirkstoffs |
| CN101155632A (zh) * | 2005-04-07 | 2008-04-02 | 三井化学株式会社 | 含烯烃类聚合物的囊状微粒 |
| US7612152B2 (en) * | 2005-05-06 | 2009-11-03 | The Board Of Trustees Of The University Of Illinois | Self-healing polymers |
| JP4678591B2 (ja) * | 2005-08-31 | 2011-04-27 | カシオ電子工業株式会社 | 超音波破壊用マイクロカプセル |
| DE102006040123A1 (de) * | 2006-08-26 | 2008-03-20 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Mikropartikeln |
| WO2007082153A2 (en) * | 2006-01-05 | 2007-07-19 | The Board Of Trustees Of The University Of Illinois | Self-healing coating system |
| US20070173602A1 (en) * | 2006-01-25 | 2007-07-26 | Brinkman Larry F | Encapsulated Michael addition catalyst |
| CN101442979B (zh) * | 2006-05-11 | 2013-08-21 | 气体产品与化学公司 | 含有官能化聚合物的个人护理组合物 |
| US7569625B2 (en) * | 2006-06-02 | 2009-08-04 | The Board Of Trustees Of The University Of Illinois | Self-healing elastomer system |
| EP2500015A1 (en) * | 2006-12-05 | 2012-09-19 | Landec Corporation | Delivery of drugs |
| US8399007B2 (en) * | 2006-12-05 | 2013-03-19 | Landec Corporation | Method for formulating a controlled-release pharmaceutical formulation |
| US20100004124A1 (en) * | 2006-12-05 | 2010-01-07 | David Taft | Systems and methods for delivery of materials for agriculture and aquaculture |
| US20090263346A1 (en) * | 2006-12-05 | 2009-10-22 | David Taft | Systems and methods for delivery of drugs |
| US20090246155A1 (en) * | 2006-12-05 | 2009-10-01 | Landec Corporation | Compositions and methods for personal care |
| JP5340956B2 (ja) * | 2006-12-20 | 2013-11-13 | アーケマ・インコーポレイテッド | ポリマーの封入および/または結合 |
| US7842146B2 (en) * | 2007-01-26 | 2010-11-30 | Dow Global Technologies Inc. | Ultrasonic energy for adhesive bonding |
| EP1953199A1 (en) * | 2007-02-01 | 2008-08-06 | Stichting Dutch Polymer Institute | Powder coating composition comprising an encapsulated crosslinker |
| US7846551B2 (en) | 2007-03-16 | 2010-12-07 | Tdy Industries, Inc. | Composite articles |
| US20080299391A1 (en) * | 2007-05-31 | 2008-12-04 | White Scott R | Capsules, methods for making capsules, and self-healing composites including the same |
| US8114883B2 (en) | 2007-12-04 | 2012-02-14 | Landec Corporation | Polymer formulations for delivery of bioactive materials |
| US20090181254A1 (en) * | 2008-01-15 | 2009-07-16 | The Board Of Trustees Of The University Of Illinois | Multi-capsule system and its use for encapsulating active agents |
| US9233063B2 (en) * | 2009-12-17 | 2016-01-12 | Air Products And Chemicals, Inc. | Polymeric compositions for personal care products |
| US8663596B2 (en) * | 2010-01-25 | 2014-03-04 | Fluor Enterprises, Inc. | Reactor, a structure packing, and a method for improving oxidation of hydrogen sulfide or polysulfides in liquid sulfur |
| US8361432B2 (en) | 2010-12-08 | 2013-01-29 | Fluor Enterprises, Inc. | Reactor, a retained catalyst structure, and a method for improving decomposition of polysulfides and removal of hydrogen sulfide in liquid sulfur |
| CN103889918B (zh) | 2011-06-14 | 2017-11-07 | 西格纳化学有限责任公司 | 可用在地下井作业中的包含金属硅化物的泡沫水泥组合物 |
| CN102417613A (zh) * | 2011-07-26 | 2012-04-18 | 东莞市贝特利新材料有限公司 | 一种应用于加成型液体硅橡胶中的添加剂的制备方法 |
| CN106397708A (zh) * | 2012-02-02 | 2017-02-15 | 阿科玛股份有限公司 | 通过包封活性组分改善的含有卤代烯烃的多元醇共混物的保质期 |
| CA2877132A1 (en) | 2012-06-25 | 2014-01-03 | Signa Chemistry, Inc. | Use of metal silicides in hydrocarbon production and transportation |
| TW201414796A (zh) * | 2012-07-27 | 2014-04-16 | Dow Corning | 自黏結可固化聚矽氧黏著劑之組成物及製造彼之方法 |
| JP6057589B2 (ja) * | 2012-07-27 | 2017-01-11 | 東レ・ダウコーニング株式会社 | 微粒子及びそれを含む硬化性オルガノポリシロキサン組成物 |
| JP6075074B2 (ja) * | 2013-01-22 | 2017-02-08 | 住友ベークライト株式会社 | 注入剤および充填方法 |
| EP3016752A4 (en) * | 2013-07-01 | 2017-06-14 | Mark Andy Inc. | Method and apparatus for in-line solventless lamination |
| US9018327B1 (en) * | 2013-11-08 | 2015-04-28 | Ppg Industries Ohio, Inc. | Catalyst compositions and methods of preparing them |
| US9683129B2 (en) * | 2014-12-04 | 2017-06-20 | Prc-Desoto International, Inc. | Polythioether sealants with extended working time |
| EP3387036A1 (en) * | 2015-12-10 | 2018-10-17 | PRC-Desoto International, Inc. | Cure-on-demand moisture-curable urethane-containing fuel resistant prepolymers and compositions thereof |
| CN106833098A (zh) * | 2017-02-16 | 2017-06-13 | 佛山市涂亿装饰材料科技有限公司 | 一种专用于低温固化的热固性粉末涂料超细微胶囊固化促进剂产品的生产工艺 |
| CN110392707A (zh) * | 2017-03-09 | 2019-10-29 | 建筑研究和技术有限公司 | 微囊包封的加聚催化剂 |
| CN110382580B (zh) | 2017-03-09 | 2022-04-19 | 巴斯夫欧洲公司 | 制备复合元件的聚氨酯制剂 |
| CN111630081B (zh) | 2018-01-26 | 2023-10-31 | 湛新荷兰有限公司 | 粉末涂料组合物 |
| JP7318250B2 (ja) * | 2018-03-29 | 2023-08-01 | 東ソー株式会社 | 触媒内包ポリビニル樹脂微粒子、該微粒子組成物、触媒内包ポリビニル樹脂微粒子及び該微粒子組成物の製造方法 |
| WO2020165135A1 (en) | 2019-02-11 | 2020-08-20 | Basf Se | Acrylic copolymer capsule designed to open up at < 90°c for controlled release of in-situ forming pu/pir catalyst |
| CN110549037B (zh) * | 2019-09-23 | 2021-06-01 | 广东省科学院中乌焊接研究所 | 囊壳材料、软钎焊用微胶囊活性剂及其制备方法、锡膏及其应用 |
| JP7501130B2 (ja) * | 2020-06-10 | 2024-06-18 | 東ソー株式会社 | 脂質微粒子 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3317433A (en) | 1958-10-23 | 1967-05-02 | Ncr Co | Heat rupturable capsules |
| DE2526603A1 (de) | 1975-06-13 | 1976-12-16 | Ruetgerswerke Ag | Lagerstabile, sehr schnell aushaertbare, einkomponentige dichtungsmasse auf basis merkaptoendstaendiger polymere |
| US4091130A (en) | 1976-06-21 | 1978-05-23 | Allied Paper Incorporated | Method for obtaining controlled cure in the coating of papers |
| DE3064094D1 (en) | 1979-05-08 | 1983-08-18 | Ciba Geigy Ag | Crystalline epoxy resin based one component systems and their application |
| US4461854A (en) | 1982-08-11 | 1984-07-24 | General Electric Company | Room temperature vulcanizable polysiloxane having a heat-activated catalyst |
| FR2553784B1 (fr) | 1983-10-19 | 1986-12-12 | Rhone Poulenc Spec Chim | Encapsulation de l'accelerateur de durcissement de compositions organopolysiloxaniques contenant des polyacyloxysilanes et durcissant en elastomeres |
| US4517337A (en) | 1984-02-24 | 1985-05-14 | General Electric Company | Room temperature vulcanizable organopolysiloxane compositions and method for making |
| US4503161A (en) | 1984-03-23 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Latent Lewis acid catalyst encapsulated within polymerized cycloaliphatic epoxide and polyhydric alcohol |
| US4528354A (en) | 1984-04-25 | 1985-07-09 | Mcdougal John R | Process and composition for the manufacture of products from silicone rubber |
| HU198403B (en) * | 1984-05-18 | 1989-10-30 | Univ Washington | Method and apparatus for coating solid particles or liquid drops |
| DE3587828T2 (de) | 1984-07-26 | 1994-09-29 | Kanegafuchi Chemical Ind | Vernetzbare Polymerzusammensetzung. |
| US5310786A (en) | 1987-01-08 | 1994-05-10 | Hoechst Aktiengesellschaft | Reversibly precipitable, water-soluble polymer conjugates |
| US4788170A (en) | 1987-07-06 | 1988-11-29 | General Electric Company | Method for preparing tin complex curing catalyst |
| US4766176A (en) | 1987-07-20 | 1988-08-23 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing microencapsulated platinum-containing catalysts |
| GB8729069D0 (en) | 1987-12-12 | 1988-01-27 | Rapra Techn Ltd | Temperature activated catalysts for liquid polymer cures |
| US5010119A (en) | 1987-12-23 | 1991-04-23 | Mcelrath Jr Kenneth O | Ternary adhesive compositions |
| FR2625745B1 (fr) | 1988-01-08 | 1992-10-09 | Picardie Lainiere | Produit textile thermocollant comprenant un agent de reticulation microencapsule |
| FR2630444B1 (fr) | 1988-04-21 | 1990-09-07 | Rhone Poulenc Chimie | Composes d'etain utilisables notamment comme catalyseurs latents pour la preparation de polyurethannes |
| DE3824771C1 (https=) | 1988-07-21 | 1990-04-05 | Teroson Gmbh, 6900 Heidelberg, De | |
| EP0363006A3 (en) | 1988-09-02 | 1991-01-09 | Dow Corning Corporation | A method for curing storage stable organosiloxane compositions containing microencapsulated ingredients |
| FR2652580B1 (fr) | 1989-10-02 | 1993-06-25 | Rhone Poulenc Chimie | Composes d'etain (iv) eventuellement chelates utilisables notamment comme catalyseurs latents. |
| US5120349A (en) | 1990-12-07 | 1992-06-09 | Landec Labs, Inc. | Microcapsule having temperature-dependent permeability profile |
| CA2101629A1 (en) | 1991-02-12 | 1992-08-13 | Edward E. Schmitt | Temperature zone specific pressure-sensitive adhesive compositions, and adhesive assemblies and methods of use associated therewith |
| US5194460A (en) | 1992-01-02 | 1993-03-16 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing a microencapsulated catalyst and method for preparing said catalyst |
| CA2113961A1 (en) | 1993-03-31 | 1994-10-01 | Alexander Henderson | One part cross-linkable hot melt adhesives |
| US5601761A (en) * | 1994-09-26 | 1997-02-11 | The Dow Chemical Company | Encapsulated active materials and method for preparing same |
| WO1996027641A1 (en) | 1995-03-07 | 1996-09-12 | Landec Corporation | Polymeric composition |
| US5665428A (en) * | 1995-10-25 | 1997-09-09 | Macromed, Inc. | Preparation of peptide containing biodegradable microspheres by melt process |
| JP2001500187A (ja) | 1996-09-12 | 2001-01-09 | ランデック コーポレイション | 変性剤を含むポリマー組成物 |
-
1999
- 1999-04-27 JP JP2000545641A patent/JP2002513045A/ja not_active Withdrawn
- 1999-04-27 ES ES99918850T patent/ES2212552T3/es not_active Expired - Lifetime
- 1999-04-27 US US09/300,339 patent/US6224793B1/en not_active Expired - Lifetime
- 1999-04-27 WO PCT/US1999/009105 patent/WO1999055454A1/en not_active Ceased
- 1999-04-27 CN CNB998055018A patent/CN1207090C/zh not_active Expired - Fee Related
- 1999-04-27 CA CA002330472A patent/CA2330472C/en not_active Expired - Fee Related
- 1999-04-27 AT AT99918850T patent/ATE259257T1/de not_active IP Right Cessation
- 1999-04-27 DE DE69914739T patent/DE69914739T2/de not_active Expired - Lifetime
- 1999-04-27 EP EP99918850A patent/EP1077763B1/en not_active Expired - Lifetime
- 1999-04-27 AU AU36667/99A patent/AU3666799A/en not_active Abandoned
- 1999-04-27 KR KR1020007011990A patent/KR100577629B1/ko not_active Expired - Fee Related
- 1999-04-27 BR BRPI9910337-0A patent/BR9910337B1/pt not_active IP Right Cessation
-
2010
- 2010-11-25 JP JP2010262560A patent/JP5351131B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE259257T1 (de) | 2004-02-15 |
| BR9910337A (pt) | 2001-01-09 |
| BR9910337B1 (pt) | 2010-08-24 |
| EP1077763B1 (en) | 2004-02-11 |
| DE69914739D1 (de) | 2004-03-18 |
| US6224793B1 (en) | 2001-05-01 |
| JP5351131B2 (ja) | 2013-11-27 |
| JP2011072999A (ja) | 2011-04-14 |
| CA2330472A1 (en) | 1999-11-04 |
| EP1077763A1 (en) | 2001-02-28 |
| AU3666799A (en) | 1999-11-16 |
| DE69914739T2 (de) | 2004-09-30 |
| CN1207090C (zh) | 2005-06-22 |
| CA2330472C (en) | 2007-09-04 |
| CN1298321A (zh) | 2001-06-06 |
| ES2212552T3 (es) | 2004-07-16 |
| JP2002513045A (ja) | 2002-05-08 |
| WO1999055454A1 (en) | 1999-11-04 |
| KR20010043104A (ko) | 2001-05-25 |
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