KR100540828B1 - 디에틸렌글리콜 에스테르계 가소제 조성물 및 이를 이용한폴리염화비닐 수지 - Google Patents
디에틸렌글리콜 에스테르계 가소제 조성물 및 이를 이용한폴리염화비닐 수지 Download PDFInfo
- Publication number
- KR100540828B1 KR100540828B1 KR1020030063160A KR20030063160A KR100540828B1 KR 100540828 B1 KR100540828 B1 KR 100540828B1 KR 1020030063160 A KR1020030063160 A KR 1020030063160A KR 20030063160 A KR20030063160 A KR 20030063160A KR 100540828 B1 KR100540828 B1 KR 100540828B1
- Authority
- KR
- South Korea
- Prior art keywords
- diethylene glycol
- weight
- ethoxy
- glycol ester
- polyvinyl chloride
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/28—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with dihydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/78—Benzoic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Abstract
Description
Claims (6)
- R1 및 R2가 3 내지 12개의 탄소수를 가지는 알킬기(alkyl group)인 하기 화학식 1의 디에틸렌글리콜 에스테르 화합물 5 내지 80 중량%;R1이 페닐기이고, R2가 3 내지 12개의 탄소수를 가지는 알킬기인 하기 화학식 1의 디에틸렌글리콜 에스테르 화합물 10 내지 80 중량%; 및R1 및 R2가 페닐기(phenyl group)인 하기 화학식 1의 디에틸렌글리콜 에스테르(diethyleneglycol ester) 화합물 5 내지 60 중량%;을 포함하여 이루어짐을 특징으로 하는 디에틸렌글리콜 에스테르계 가소제 조성물:[화학식 1]R1OCO-(CH2)2-O-(CH2)2-OCOR2
- 삭제
- 제1항에 있어서,상기 (가)의 디에틸렌글리콜 에스테르 화합물이 2-에틸헥사노익에시드 2-{2-(2-에틸헥사노일옥시)-에톡시}-에틸 에스테르[2-ethylhexanoic acid 2-{2-(2-ethylhexanoyloxy)-ethoxy}-ethyl ester]이고,상기 (나)의 디에틸렌글리콜 에스테르 화합물이 벤조익에시드 2-{2-(2-에틸헥사노일옥시)-에톡시}-에틸 에스테르[benzoic acid 2-{2-(2-ethylhexanoyloxy)-ethoxy} ethyl ester]이며, 그리고상기 (다)의 디에틸렌글리콜 에스테르 화합물이 벤조익에시드 2-{2-(벤조일옥시)-에톡시}-에틸 에스테르[benzoic acid 2-{2-(benzoyloxy)-ethoxy}-ethyl ester]임을 특징으로 하는 디에틸렌글리콜 에스테르계 가소제 조성물.
- 제3항에 있어서,상기 2-에틸헥사노익에시드 2-{2-(2-에틸헥사노일옥시)-에톡시}-에틸 에스테르가 5 내지 80중량%이고,상기 벤조익에시드 2-{2-(2-에틸헥사노일옥시)-에톡시}-에틸 에스테르가 10 내지 80중량%이며, 그리고상기 벤조익에시드 2-{2-(벤조일옥시)-에톡시}-에틸 에스테르가 5 내지 60중량%임을 특징으로 하는 디에틸렌글리콜 에스테르계 가소제 조성물.
- 디에틸렌글리콜(diethylene glycol) 10 내지 40중량%, 2-에틸헥사노익에시드(2-ethylhexanoic acid) 20 내지 70중량%, 벤조익에시드(benzoic acid) 10 내지 60중량%, 크실렌(xylene) 1 내지 10중량% 및 테트라이소프로필티타네이트(tetraisopropyltitanate) 0.01 내지 1중량%을 220℃에서 4 내지 10시간 동안 반응시키는 단계를 포함하여 이루어짐을 특징으로 하는 디에틸렌글리콜 에스테르계 가소제 조성물의 제조방법.
- 제1항 기재의 디에틸렌글리콜 에스테르계 가소제 조성물을 이용한 폴리염화비닐 수지.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020030063160A KR100540828B1 (ko) | 2003-09-09 | 2003-09-09 | 디에틸렌글리콜 에스테르계 가소제 조성물 및 이를 이용한폴리염화비닐 수지 |
DE602004017482T DE602004017482D1 (de) | 2003-09-09 | 2004-09-09 | Weichmacherzusammensetzung auf diethylenglykolesterbasis und polyvinylchloridharz damit |
EP04774566A EP1664178B1 (en) | 2003-09-09 | 2004-09-09 | Diethyleneglycol ester based plasticizer composition and polyvinyl chloride resin using the same |
AT04774566T ATE412698T1 (de) | 2003-09-09 | 2004-09-09 | Weichmacherzusammensetzung auf diethylenglykolesterbasis und polyvinylchloridharz damit |
US10/570,960 US20070027240A1 (en) | 2003-09-09 | 2004-09-09 | Diethyleneglycol ester based plasticizer composition and polyvinyl chloride resin using the same |
CNB200480029390XA CN100453588C (zh) | 2003-09-09 | 2004-09-09 | 基于二甘醇酯的增塑剂组合物及使用该组合物的聚氯乙烯树脂 |
JP2006524588A JP2007504126A (ja) | 2003-09-09 | 2004-09-09 | ジエチレングリコールエステル系可塑剤組成物及びこれを利用したポリ塩化ビニル樹脂 |
PCT/KR2004/002307 WO2005023926A1 (en) | 2003-09-09 | 2004-09-09 | Diethyleneglycol ester based plasticizer composition and polyvinyl chloride resin using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020030063160A KR100540828B1 (ko) | 2003-09-09 | 2003-09-09 | 디에틸렌글리콜 에스테르계 가소제 조성물 및 이를 이용한폴리염화비닐 수지 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20050026178A KR20050026178A (ko) | 2005-03-15 |
KR100540828B1 true KR100540828B1 (ko) | 2006-01-11 |
Family
ID=36241973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020030063160A KR100540828B1 (ko) | 2003-09-09 | 2003-09-09 | 디에틸렌글리콜 에스테르계 가소제 조성물 및 이를 이용한폴리염화비닐 수지 |
Country Status (8)
Country | Link |
---|---|
US (1) | US20070027240A1 (ko) |
EP (1) | EP1664178B1 (ko) |
JP (1) | JP2007504126A (ko) |
KR (1) | KR100540828B1 (ko) |
CN (1) | CN100453588C (ko) |
AT (1) | ATE412698T1 (ko) |
DE (1) | DE602004017482D1 (ko) |
WO (1) | WO2005023926A1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100828725B1 (ko) | 2006-06-12 | 2008-05-09 | 주식회사 엘지화학 | 염화비닐계 수지 플라스티졸, 상기 플라스티졸의 제조 방법및 이를 이용한 딥핑 또는 샤워링 성형 장갑 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004060042A1 (de) * | 2004-12-14 | 2006-06-29 | Lanxess Deutschland Gmbh | Estermischungen |
KR100676303B1 (ko) * | 2005-04-12 | 2007-01-30 | 주식회사 엘지화학 | 폴리염화비닐 수지용 트리에틸렌글리콜 에스테르 가소제조성물 |
US20080064795A1 (en) * | 2006-09-08 | 2008-03-13 | George Bittner | Materials free of endocrine disruptive activity |
KR20100029978A (ko) * | 2008-09-09 | 2010-03-18 | 에스케이에너지 주식회사 | 가소제 및 이를 포함한 폴리염화비닐 수지 조성물 |
CN101987888B (zh) * | 2009-08-07 | 2012-05-23 | 成都亚恩科技实业有限公司 | 一种多元醇苯甲酸酯增塑剂 |
CN101987819B (zh) * | 2009-08-07 | 2012-08-22 | 成都亚恩科技实业有限公司 | 一种多元醇苯甲酸酯增塑剂的制备方法 |
WO2011021400A1 (ja) * | 2009-08-20 | 2011-02-24 | 三井化学ファブロ株式会社 | ポリ塩化ビニル系ストレッチフィルム |
KR101773606B1 (ko) | 2010-05-04 | 2017-09-12 | 에스케이이노베이션 주식회사 | 가소제 및 이의 제조방법 |
KR101909434B1 (ko) * | 2010-11-29 | 2018-10-19 | 에스케이이노베이션 주식회사 | 수지 조성물용 가소제 및 이를 포함하는 수지 조성물 |
KR101902281B1 (ko) * | 2011-05-19 | 2018-09-28 | 에스케이이노베이션 주식회사 | 수지 조성물용 가소제 및 이를 포함하는 수지 조성물 |
CN102775310B (zh) * | 2012-08-06 | 2015-04-08 | 南京林业大学 | 一种二元醇二苯甲酸酯的合成方法 |
CN103086891B (zh) * | 2013-02-22 | 2015-12-23 | 厦门大学 | 增塑剂二甘醇二苯甲酸酯的制备方法 |
CN103881273B (zh) * | 2014-04-11 | 2016-08-24 | 厦门港光塑胶工业有限公司 | 一种耐油耐寒pvc透明粒料及其制备方法 |
JP6817756B2 (ja) * | 2016-09-15 | 2021-01-20 | タイガースポリマー株式会社 | 耐放射線塩化ビニル樹脂組成物および耐放射線塩化ビニル樹脂組成物を含む可撓性ホースおよび可撓性チューブ |
WO2019059801A1 (en) | 2017-09-21 | 2019-03-28 | Public Joint Stock Company "Sibur Holding" | PROCESS FOR THE PREPARATION OF BENZOIC ACID ESTERS |
KR102236923B1 (ko) | 2017-12-04 | 2021-04-07 | 주식회사 엘지화학 | 가소제 조성물 및 이를 포함하는 수지 조성물 |
KR20220113098A (ko) * | 2021-02-05 | 2022-08-12 | 한화솔루션 주식회사 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2585448A (en) * | 1948-11-23 | 1952-02-12 | Monsanto Chemicals | Plasticizers |
US5746783A (en) * | 1994-03-30 | 1998-05-05 | Martin Marietta Energy Systems, Inc. | Low emissions diesel fuel |
US20030023112A1 (en) * | 2001-04-11 | 2003-01-30 | Jiamin Lang | Benzoate/alkanoate ester compositions |
-
2003
- 2003-09-09 KR KR1020030063160A patent/KR100540828B1/ko active IP Right Grant
-
2004
- 2004-09-09 US US10/570,960 patent/US20070027240A1/en not_active Abandoned
- 2004-09-09 CN CNB200480029390XA patent/CN100453588C/zh active Active
- 2004-09-09 DE DE602004017482T patent/DE602004017482D1/de active Active
- 2004-09-09 WO PCT/KR2004/002307 patent/WO2005023926A1/en active Application Filing
- 2004-09-09 EP EP04774566A patent/EP1664178B1/en active Active
- 2004-09-09 AT AT04774566T patent/ATE412698T1/de not_active IP Right Cessation
- 2004-09-09 JP JP2006524588A patent/JP2007504126A/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100828725B1 (ko) | 2006-06-12 | 2008-05-09 | 주식회사 엘지화학 | 염화비닐계 수지 플라스티졸, 상기 플라스티졸의 제조 방법및 이를 이용한 딥핑 또는 샤워링 성형 장갑 |
Also Published As
Publication number | Publication date |
---|---|
JP2007504126A (ja) | 2007-03-01 |
KR20050026178A (ko) | 2005-03-15 |
WO2005023926A1 (en) | 2005-03-17 |
ATE412698T1 (de) | 2008-11-15 |
EP1664178A1 (en) | 2006-06-07 |
DE602004017482D1 (de) | 2008-12-11 |
CN1863858A (zh) | 2006-11-15 |
US20070027240A1 (en) | 2007-02-01 |
CN100453588C (zh) | 2009-01-21 |
EP1664178B1 (en) | 2008-10-29 |
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