KR100441136B1 - 7-아릴퀴논메티드를이용한불포화단량체의억제 - Google Patents

7-아릴퀴논메티드를이용한불포화단량체의억제 Download PDF

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Publication number
KR100441136B1
KR100441136B1 KR1019960010081A KR19960010081A KR100441136B1 KR 100441136 B1 KR100441136 B1 KR 100441136B1 KR 1019960010081 A KR1019960010081 A KR 1019960010081A KR 19960010081 A KR19960010081 A KR 19960010081A KR 100441136 B1 KR100441136 B1 KR 100441136B1
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KR
South Korea
Prior art keywords
tert
compound
formula
mixture
monomers
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KR1019960010081A
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English (en)
Korean (ko)
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KR960037632A (ko
Inventor
에반스 사무엘
에드워드 켄더 마태
네스바드바 피터
하트무트 본 안 볼케
아써 에드윈 윈터 로랜드
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날코/엑손 에너지 케미칼즈, 엘.피.
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Publication of KR960037632A publication Critical patent/KR960037632A/ko
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C46/00—Preparation of quinones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/56—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and doubly-bound oxygen atoms bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/45—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by at least one doubly—bound oxygen atom, not being part of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
    • C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrogenated Pyridines (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
KR1019960010081A 1995-04-14 1996-04-04 7-아릴퀴논메티드를이용한불포화단량체의억제 KR100441136B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/422,284 US5616774A (en) 1995-04-14 1995-04-14 Inhibition of unsaturated monomers with 7-aryl quinone methides
US08/422284 1995-04-14

Publications (2)

Publication Number Publication Date
KR960037632A KR960037632A (ko) 1996-11-19
KR100441136B1 true KR100441136B1 (ko) 2004-10-20

Family

ID=23674187

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960010081A KR100441136B1 (ko) 1995-04-14 1996-04-04 7-아릴퀴논메티드를이용한불포화단량체의억제

Country Status (12)

Country Link
US (1) US5616774A (cs)
EP (1) EP0737660B1 (cs)
JP (1) JP3774854B2 (cs)
KR (1) KR100441136B1 (cs)
CN (1) CN1054594C (cs)
AT (1) ATE222224T1 (cs)
BR (1) BR9601346A (cs)
CA (1) CA2174060C (cs)
CZ (1) CZ296467B6 (cs)
DE (1) DE69622910T2 (cs)
ES (1) ES2181861T3 (cs)
TW (1) TW394786B (cs)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090045871A (ko) * 2007-11-02 2009-05-08 에보니크 데구사 게엠베하 올레핀계 불포화 단량체의 안정화 방법
KR20140115258A (ko) * 2013-03-20 2014-09-30 에보닉 인두스트리에스 아게 시클로펜타디엔 화합물의 중합을 억제하기 위한 방법 및 조성물

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DE19609312A1 (de) * 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
DE69710163T2 (de) * 1996-12-02 2002-10-02 Ondeo Nalco Energy Serv Lp Hemmung der Polymerisation von vinylaromatischen Monomeren
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
AU760809B2 (en) * 1998-09-09 2003-05-22 Baker Hughes Incorporated Styrene monomer polymerization inhibition using substituted dihydroxyarenes and nitroxides
DE60023542T2 (de) 1999-12-02 2006-07-20 Crompton Corp., Middlebury Polymerisationsinhibierung von ungesättigten monomeren
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
CA2422655A1 (en) * 2000-10-16 2002-04-25 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
KR100822007B1 (ko) * 2001-03-20 2008-04-15 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 방염성 조성물
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US6926820B2 (en) * 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
JP4790414B2 (ja) * 2003-03-17 2011-10-12 伯東株式会社 芳香族ビニル化合物の重合抑制剤および重合抑制方法
US7128826B2 (en) * 2003-07-31 2006-10-31 General Electric Company Polymerization inhibitor for styrene dehydrogenation units
WO2006024621A1 (en) * 2004-09-03 2006-03-09 Ciba Specialty Chemicals Holding Inc. In-can stabilizers
CN101163736B (zh) * 2005-04-21 2011-06-08 西巴特殊化学品控股有限公司 罐内稳定剂混合物
US7553896B2 (en) * 2005-06-17 2009-06-30 Chemtura Corporation Ortho-nitrosophenols as polymerization inhibitors
US8247593B2 (en) * 2008-05-13 2012-08-21 Nalco Company Process for preparing substituted 7-cyano quinone methides
US8187346B2 (en) * 2008-12-29 2012-05-29 Fina Technology, Inc. Stabilization of pygas for storage
US8298440B2 (en) * 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9206268B2 (en) 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
WO2013156360A1 (de) * 2012-04-20 2013-10-24 Hilti Aktiengesellschaft Kombination aus einem stabilen nitroxylradikal und einem quinonmethid als stabilisator für reaktionsharzmörtel auf basis radikalisch härtbarer verbindungen
US9611336B2 (en) 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
WO2014130008A1 (en) * 2013-02-19 2014-08-28 General Electric Company Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers
ES2624415T3 (es) 2014-09-08 2017-07-14 Evonik Degussa Gmbh (Tio)acetales fenólicos como agentes inhibidores de la polimerización de monómeros olefínicamente insaturados
TWI669317B (zh) 2014-09-22 2019-08-21 德商贏創德固賽有限責任公司 反應性單體的改良製造方法
EP3820836A1 (en) 2018-07-13 2021-05-19 Ecolab USA, Inc. Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
US11312793B2 (en) 2018-09-28 2022-04-26 Ecolab Usa Inc. Amino-quinone antipolymerants and methods of using
JP7247630B2 (ja) * 2019-02-13 2023-03-29 栗田工業株式会社 不飽和芳香族単量体の重合を抑制する方法
TW202114976A (zh) 2019-10-11 2021-04-16 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
CN115490711A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-(3-苯硼酸)亚甲基-2，6-二叔丁基-2，5-环己二烯-1-酮化合物的合成和应用
CN115490666A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-噻吩亚甲基-2，6-二叔丁基-2，5-环己二烯-1-酮化合物的合成及应用
CN115490653A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-呋喃亚甲基-2,6-二叔丁基-2,5-环己二烯-1-酮化合物的合成及应用
CN114656353A (zh) * 2022-04-13 2022-06-24 卫星化学股份有限公司 一种绿色环保型化合物在丙烯酸生产过程中的应用
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

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US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US4003800A (en) * 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4032547A (en) * 1976-02-23 1977-06-28 Gulf Research & Development Company Quinone alkide synthesis system
CA2070551C (en) * 1991-07-12 2003-04-01 Anthony V. Grossi Polymerization inhibitors for acrylic acids and esters
US5221764A (en) * 1992-02-18 1993-06-22 Betz Laboratories, Inc. Methods and compositions for inhibiting acrylic acid polymerization
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090045871A (ko) * 2007-11-02 2009-05-08 에보니크 데구사 게엠베하 올레핀계 불포화 단량체의 안정화 방법
KR101616126B1 (ko) 2007-11-02 2016-04-27 에보니크 데구사 게엠베하 올레핀계 불포화 단량체의 안정화 방법
KR20140115258A (ko) * 2013-03-20 2014-09-30 에보닉 인두스트리에스 아게 시클로펜타디엔 화합물의 중합을 억제하기 위한 방법 및 조성물
KR102079982B1 (ko) * 2013-03-20 2020-02-24 에보니크 오퍼레이션즈 게엠베하 시클로펜타디엔 화합물의 중합을 억제하기 위한 방법 및 조성물

Also Published As

Publication number Publication date
DE69622910D1 (de) 2002-09-19
CN1139094A (zh) 1997-01-01
CZ106896A3 (en) 1996-11-13
CZ296467B6 (cs) 2006-03-15
KR960037632A (ko) 1996-11-19
CA2174060C (en) 2009-08-11
EP0737660B1 (en) 2002-08-14
JP3774854B2 (ja) 2006-05-17
ATE222224T1 (de) 2002-08-15
BR9601346A (pt) 1998-01-13
ES2181861T3 (es) 2003-03-01
US5616774A (en) 1997-04-01
JPH09165408A (ja) 1997-06-24
EP0737660A1 (en) 1996-10-16
DE69622910T2 (de) 2003-05-08
TW394786B (en) 2000-06-21
CN1054594C (zh) 2000-07-19
CA2174060A1 (en) 1996-10-15

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