KR100285867B1 - Separation method of p-xylene from c8 aromatic hydrocarbons by simulated moving bed adsorption and crystallization and apparatus thereof - Google Patents

Separation method of p-xylene from c8 aromatic hydrocarbons by simulated moving bed adsorption and crystallization and apparatus thereof Download PDF

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Publication number
KR100285867B1
KR100285867B1 KR1019920016074A KR920016074A KR100285867B1 KR 100285867 B1 KR100285867 B1 KR 100285867B1 KR 1019920016074 A KR1019920016074 A KR 1019920016074A KR 920016074 A KR920016074 A KR 920016074A KR 100285867 B1 KR100285867 B1 KR 100285867B1
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KR
South Korea
Prior art keywords
xylene
solvent
crystallization
moving bed
simulated moving
Prior art date
Application number
KR1019920016074A
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English (en)
Inventor
Hotier Gerard
Roux Guerraz Claude
Nguyen Thanh Than
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR919111004A external-priority patent/FR2681066B1/fr
Priority claimed from FR929208497A external-priority patent/FR2693186B1/fr
Priority claimed from FR929208498A external-priority patent/FR2693187B1/fr
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Application granted granted Critical
Publication of KR100285867B1 publication Critical patent/KR100285867B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/14—Purification; Separation; Use of additives by crystallisation; Purification or separation of the crystals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
KR1019920016074A 1991-09-05 1992-09-04 Separation method of p-xylene from c8 aromatic hydrocarbons by simulated moving bed adsorption and crystallization and apparatus thereof KR100285867B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR919111004A FR2681066B1 (fr) 1991-09-05 1991-09-05 Procede et dispositif de separation des paraxylenes dans une charge d'hydrocarbures aromatiques en c8.
FR929208497A FR2693186B1 (fr) 1992-07-06 1992-07-06 Procédé de séparation du paraxylène dans des hydrocarbures aromatiques en C8 avec une adsorption à contre-courant simulé et une cristallisation.
FR929208498A FR2693187B1 (fr) 1992-07-06 1992-07-06 Procédé de séparation du paraxylène dans des hydrocarbures aromatiques en C8 avec une adsorption à co-courant simulé et une cristallisation.

Publications (1)

Publication Number Publication Date
KR100285867B1 true KR100285867B1 (en) 2001-01-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920016074A KR100285867B1 (en) 1991-09-05 1992-09-04 Separation method of p-xylene from c8 aromatic hydrocarbons by simulated moving bed adsorption and crystallization and apparatus thereof

Country Status (11)

Country Link
US (4) US5284992A (ko)
EP (1) EP0531191B1 (ko)
JP (2) JPH05201886A (ko)
KR (1) KR100285867B1 (ko)
CN (1) CN1034069C (ko)
CA (1) CA2077635C (ko)
DE (1) DE69202944T2 (ko)
DK (1) DK0531191T3 (ko)
ES (1) ES2076017T3 (ko)
NO (1) NO177386C (ko)
TW (1) TW200454B (ko)

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KR100725003B1 (ko) * 2001-12-03 2007-06-04 에스케이 주식회사 디에틸벤젠 이성질체 혼합물로부터 1,2-디에틸벤젠을분리하는 방법
KR100741750B1 (ko) 2005-12-26 2007-07-23 삼성토탈 주식회사 로터리 밸브의 스위칭 타임이 비균일한 유사 이동층 흡착 분리 방법
KR100741749B1 (ko) 2005-12-26 2007-07-23 삼성토탈 주식회사 최종 제품을 2차 세척 액체로 사용하는 유사 이동층 흡착 분리 방법
KR100843435B1 (ko) 2007-04-27 2008-07-03 삼성토탈 주식회사 유사 이동층 크실렌 혼합물 전처리 공정 및 추가의 크실렌이성질화 공정을 포함하는 방향족 화합물의 분리 방법
KR20080096448A (ko) * 2007-04-26 2008-10-30 아이에프피 모사 이동층 흡착 및 결정화를 포함하는 고순도메타-자일렌의 제조방법
KR20140053785A (ko) * 2012-10-26 2014-05-08 아이에프피 에너지스 누벨 총 개수 22 개 이하의 층을 갖는 직렬의 2 개의 흡착기로 구성되는, 파라-크실렌의 모의 역류 제조를 위한 방법 및 장치
KR101861418B1 (ko) * 2013-02-22 2018-05-28 아르끄마 프랑스 150 내지 500 미크론의 입도를 가지는 제올라이트성 흡착성 고형물에 의한 모사 이동층에서 크실렌을 분리하는 방법

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TW200454B (ko) * 1991-09-05 1993-02-21 Inst Of France Petroleum
US6663780B2 (en) * 1993-01-26 2003-12-16 Danisco Finland Oy Method for the fractionation of molasses
US5523503A (en) * 1994-07-13 1996-06-04 Uop Cocurrent simulated moving bed hydrocarbon alkylation process
FR2728894A1 (fr) * 1994-12-29 1996-07-05 Inst Francais Du Petrole Procede de separation de paraxylene comportant au moins deux etages de cristallisation a haute temperature
FR2728893A1 (fr) * 1994-12-29 1996-07-05 Inst Francais Du Petrole Procede de separation de paraxylene comportant au moins un etage de cristallisation a haute temperature et au moins un traitement a la terre situe en amont de la zone d'adsorption
FR2729660A1 (fr) * 1995-01-20 1996-07-26 Inst Francais Du Petrole Procede de production de paraxylene comportant une cristallisation a haute temperature a au moins un etage et une fusion partielle des cristaux
FR2730728B1 (fr) * 1995-02-21 1997-05-23 Inst Francais Du Petrole Procede de separation du p-xylene comportant un pretraitement par hydrogenation selective et par de la terre activee
CN1045286C (zh) * 1995-03-30 1999-09-29 中国石油化工总公司石油化工科学研究院 高纯度间二甲苯的制备方法
FR2739097B1 (fr) * 1995-09-22 1997-12-19 Rattheon Engineers & Construct Procede de purification de paraxylene par cristallisation fractionnee
FR2739375B1 (fr) * 1995-09-29 1997-12-05 Inst Francais Du Petrole Production de paraxylene a partir d'un effluent de dismutation paraselective du toluene par un procede de cristallisation associe a une adsorption en lit mobile simule
FR2743068B1 (fr) * 1995-12-27 1998-02-06 Inst Francais Du Petrole Procede de production de paraxylene en deux etapes d'adsorption combinees
FR2755879B1 (fr) * 1996-11-19 1999-01-08 Inst Francais Du Petrole Dispositif d'equilibrage de pression et de rincage dans une enceinte
JPH10151301A (ja) * 1996-11-26 1998-06-09 Mitsui Chem Inc 混合液から晶析により物質を分離乃至精製する方法
FR2757507B1 (fr) * 1996-12-20 1999-01-29 Inst Francais Du Petrole Procede de separation de paraxylene comprenant une adsorption avec injection d'eau et une cristallisation
US6336334B1 (en) * 1997-06-16 2002-01-08 Institut Francais De Petrole Device for crystallization by isentropic expansion and its use
FR2764521B1 (fr) * 1997-06-16 1999-07-16 Inst Francais Du Petrole Dispositif de cristallisation par detente isentropique et son utilisation
FR2767524B1 (fr) 1997-08-21 1999-09-24 Ceca Sa Procede ameliore d'obtention de paraxylene a partir de coupes de c8 aromatiques
FR2768724B1 (fr) * 1997-09-23 1999-12-03 Inst Francais Du Petrole Procede de production de paraxylene comprenant une etape d'adsorption et une etape d'isomerisation en phase liquide
US6004452A (en) * 1997-11-14 1999-12-21 Chevron Chemical Company Llc Process for converting hydrocarbon feed to high purity benzene and high purity paraxylene
FR2773149B1 (fr) * 1997-12-26 2000-02-18 Inst Francais Du Petrole Procede de coproduction et de separation d'ethylbenzene et de paraxylene
US6045703A (en) * 1998-06-15 2000-04-04 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6036865A (en) * 1998-06-15 2000-03-14 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
FR2782714B1 (fr) * 1998-08-26 2000-09-29 Inst Francais Du Petrole Procede de coproduction de metaxylene et de paraxylene
CN1075482C (zh) * 1998-11-13 2001-11-28 中国石油化工集团公司 一种间、对混合二甲苯的异构化方法
FR2789914B1 (fr) * 1999-02-22 2001-04-06 Ceca Sa Adsorbants zeolitiques agglomeres a faible taux de liant inerte, leur procede d'obtention et leurs utilisations
FR2795069B1 (fr) * 1999-06-17 2001-08-03 Inst Francais Du Petrole Procede de coproduction et de separation d'ethylbenzene et de paraxylene
FR2795407B1 (fr) * 1999-06-22 2001-10-05 Inst Francais Du Petrole Procede de production d'au moins un isomere des xylenes comprenant une etape d'adsorption et une etape d'isomerisation avec un catalyseur de type structural euo
FR2795406B1 (fr) 1999-06-22 2002-11-29 Inst Francais Du Petrole Procede de production d'un isomere des xylenes en trois etapes: separation, isomerisation en presence d'un catalyseur a base de zeolithe euo et transalkylation
FR2795405B1 (fr) * 1999-06-22 2003-01-10 Inst Francais Du Petrole Production d'un isomere du xylene en trois etapes: separation, isomerisation avec un catalyseur a base de zeolithe euo et transalkylation avec recyclage des aromatiques en c10
TWI240716B (en) 2000-07-10 2005-10-01 Bp Corp North America Inc Pressure swing adsorption process for separating paraxylene and ethylbenzene from mixed C8 aromatics
US6573418B2 (en) 2000-07-10 2003-06-03 Bp Corporation North America Inc. Process for production of para-xylene incorporating pressure swing adsorption and simulated moving bed adsorption
US6627783B2 (en) 2000-07-10 2003-09-30 Bp Corporation North America Inc. Pressure swing adsorption process for separating para-xylene and ethylbenzene from mixed C8 aromatics
WO2002040129A2 (en) 2000-11-15 2002-05-23 Purdue Research Foundation Systems and processes for performing separations using a simulated moving bed apparatus
FR2822820B1 (fr) * 2001-03-29 2003-05-30 Inst Francais Du Petrole Procede de coproduction de paraxylene et de metaxylene comprenant deux etapes de separation
FR2829758B1 (fr) * 2001-09-20 2003-12-05 Inst Francais Du Petrole Procede de coproduction de paraxylene de metaxylene et/ou d'orthoxylene
CN1297524C (zh) * 2001-12-18 2007-01-31 环球油品公司 吸附分离产物的分馏回收方法
FR2833592B1 (fr) * 2001-12-19 2004-02-13 Inst Francais Du Petrole Procede de coproduction de paraxylene et d'orthoxylene comprenant deux etapes de separation
US20040010170A1 (en) * 2002-01-09 2004-01-15 Vickers George H. Para-xylene and ethylbenzene separation from mixed C8 aromatics
FR2843893B1 (fr) * 2002-08-28 2004-10-15 Inst Francais Du Petrole Methode pour optimiser le fonctionnement d'une unite de separation de xylenes par contre courant simule
FR2844790B1 (fr) * 2002-09-20 2004-10-22 Inst Francais Du Petrole Procede de coproduction de paraxylene et de styrene
FR2862638B1 (fr) * 2003-11-26 2005-12-30 Inst Francais Du Petrole Procede de production de paraxylene comprenant une etape d'adsorption et deux etapes d'isomerisation
US7358414B2 (en) * 2004-01-30 2008-04-15 Miller Jeffrey T Para-xylene process using perm-selective separations
FR2877237B1 (fr) * 2004-10-29 2006-12-29 Inst Francais Du Petrole Procede de separation par adsorption selective sur un solide contenant une zeolithe de structure cristalline analogue a l'im-12.
FR2883283B1 (fr) * 2005-03-16 2007-05-18 Inst Francais Du Petrole Procede de production combinee de paraxylene et de benzene de productivite amelioree
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FR2904776B1 (fr) * 2006-08-08 2009-01-23 Inst Francais Du Petrole Procede et dispositif de separation en lit mobile simule a nombre de vannes reduit
FR2907021B1 (fr) * 2006-10-16 2009-02-06 Inst Francais Du Petrole Procede et dispositif de separation en lit mobile simule a nombre de vannes de grand diametre reduit
US7687674B2 (en) * 2006-12-28 2010-03-30 Uop Llc Low temperature process for recovering and producing para-xylene and heat exchange network therefore
KR100843436B1 (ko) * 2007-04-27 2008-07-03 삼성토탈 주식회사 유사 이동층 크실렌 혼합물 전처리 공정 및 추가의 크실렌이성질화 공정을 포함하는 방향족 화합물의 분리 방법
FR2919604B1 (fr) * 2007-07-30 2012-09-21 Inst Francais Du Petrole Procede et dispositif de separation ameliore de metaxylene en lit mobile simule
FR2919603B1 (fr) * 2007-07-30 2012-09-21 Inst Francais Du Petrole Procede et dispositif de separation ameliore de paraxylene en lit mobile simule
KR100929115B1 (ko) 2008-01-17 2009-11-30 삼성토탈 주식회사 추출액을 2차 세척용 액체로 사용하는 유사 이동층 흡착분리 방법
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CN101735001B (zh) * 2008-11-21 2013-04-03 中国石油化工股份有限公司 对二甲苯结晶分离的方法
CN101735002A (zh) * 2008-11-21 2010-06-16 中国石油化工股份有限公司 结晶分离对二甲苯的方法
CN101993332B (zh) * 2009-08-31 2013-06-19 中国石油化工股份有限公司 联合生产芳烃的组合方法
CN102267860B (zh) * 2010-06-02 2013-10-02 中国石油化工集团公司 一种生产对二甲苯的方法及吸附设备
CN102267861B (zh) * 2010-06-02 2014-09-10 中国石油化工集团公司 一种吸附-结晶分离对二甲苯的方法及装置
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US8754281B2 (en) * 2010-08-25 2014-06-17 Uop Llc Energy conservation in heavy-hydrocarbon distillation
US8609922B2 (en) * 2010-08-25 2013-12-17 Uop Llc Energy conservation in heavy-hydrocarbon distillation
US8993825B2 (en) * 2010-08-25 2015-03-31 Uop Llc Energy conservation in heavy-hydrocarbon distillation
FR2976501B1 (fr) * 2011-06-16 2013-05-31 IFP Energies Nouvelles Procede et dispositif de separation chromatographique a contre-courant simule utilisant deux adsorbeurs en parallele pour la production optimisee de paraxylene.
FR2979252B1 (fr) * 2011-08-26 2013-08-16 IFP Energies Nouvelles Procede et dispositif de production de paraxylene en contre-courant simule a grande flexibilite
CN103508837B (zh) * 2012-06-27 2015-05-20 中国石油化工股份有限公司 一种由吸附-结晶过程生产对二甲苯的方法
FR2999098B1 (fr) 2012-12-12 2022-01-14 Ceca Sa Adsorbants zeolithiques, leur procede de preparation et leurs utilisations
FR3004966B1 (fr) 2013-04-30 2016-02-05 IFP Energies Nouvelles Adsorbants zeolithiques comprenant de la zeolithe emt, leur procede de preparation et leurs utilisations
FR3010402B1 (fr) 2013-09-09 2015-08-28 Ceca Sa Adsorbants zeolithiques de haute surface externe, leur procede de preparation et leurs utilisations
CN104511184B (zh) * 2013-09-29 2016-07-06 中国石油化工股份有限公司 一种吸附分离c8芳烃所用模拟移动床的管线冲洗方法
JP6350259B2 (ja) * 2013-12-27 2018-07-04 東レ株式会社 芳香族化合物異性体の製造方法
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FR3024666B1 (fr) 2014-08-05 2022-01-14 Ifp Energies Now Adsorbants zeolithiques comprenant une zeolithe a porosite hierarchisee
FR3024667B1 (fr) 2014-08-05 2022-01-14 Ceca Sa Adsorbants zeolithiques a faible taux de liant et a haute surface externe, leur procede de preparation et leurs utilisations
FR3028430B1 (fr) 2014-11-13 2018-08-17 IFP Energies Nouvelles Adsorbants zeolithiques a base de zeolithe lsx de surface externe controlee, leur procede de preparation et leurs utilisations
FR3028431B1 (fr) 2014-11-13 2016-11-18 Ceca Sa Adsorbants zeolithiques a base de zeolithe x a faible taux de liant et a faible surface externe, leur procede de preparation et leurs utilisations
CN107001183B (zh) 2014-11-21 2020-02-14 埃克森美孚化学专利公司 制备对二甲苯的方法
FR3038528B1 (fr) 2015-07-09 2020-10-23 Ifp Energies Now Adsorbants zeolithiques, leur procede de preparation et leurs utilisations
FR3038529B1 (fr) 2015-07-09 2020-10-23 Ceca Sa Adsorbants zeolithiques, leur procede de preparation et leurs utilisations
CN106390518B (zh) * 2015-07-28 2019-11-15 中国石油化工股份有限公司 一种用液相模拟移动床同时吸附分离多股原料的方法
CN108017502B (zh) * 2016-10-28 2021-08-06 中国石油化工股份有限公司 模拟移动床吸附分离碳八芳烃中对二甲苯的方法
FR3070685B1 (fr) * 2017-09-04 2021-08-13 Ifp Energies Now Procede hybride de production de paraxylene de haute purete avec solvant toluene
FR3075792B1 (fr) 2017-12-22 2019-11-29 Arkema France Adsorbants zeolitiques contenant du strontium
FR3075793B1 (fr) 2017-12-22 2019-11-29 Arkema France Adsorbants zeolithiques a base de baryum, strontium et potassium, leur procede de preparation et leurs utilisations
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CN113209670B (zh) * 2021-06-23 2022-11-11 内蒙古工业大学 顺序式模拟移动床耦合结晶过程的低聚木糖分离纯化系统及工艺
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Cited By (9)

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Publication number Priority date Publication date Assignee Title
KR100725003B1 (ko) * 2001-12-03 2007-06-04 에스케이 주식회사 디에틸벤젠 이성질체 혼합물로부터 1,2-디에틸벤젠을분리하는 방법
KR100741750B1 (ko) 2005-12-26 2007-07-23 삼성토탈 주식회사 로터리 밸브의 스위칭 타임이 비균일한 유사 이동층 흡착 분리 방법
KR100741749B1 (ko) 2005-12-26 2007-07-23 삼성토탈 주식회사 최종 제품을 2차 세척 액체로 사용하는 유사 이동층 흡착 분리 방법
KR20080096448A (ko) * 2007-04-26 2008-10-30 아이에프피 모사 이동층 흡착 및 결정화를 포함하는 고순도메타-자일렌의 제조방법
KR101587648B1 (ko) * 2007-04-26 2016-01-21 아이에프피 에너지스 누벨 모사 이동층 흡착 및 결정화를 포함하는 고순도메타-자일렌의 제조방법
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KR20140053785A (ko) * 2012-10-26 2014-05-08 아이에프피 에너지스 누벨 총 개수 22 개 이하의 층을 갖는 직렬의 2 개의 흡착기로 구성되는, 파라-크실렌의 모의 역류 제조를 위한 방법 및 장치
KR102095601B1 (ko) * 2012-10-26 2020-03-31 아이에프피 에너지스 누벨 총 개수 22 개 이하의 층을 갖는 직렬의 2 개의 흡착기로 구성되는, 파라-크실렌의 모의 역류 제조를 위한 방법 및 장치
KR101861418B1 (ko) * 2013-02-22 2018-05-28 아르끄마 프랑스 150 내지 500 미크론의 입도를 가지는 제올라이트성 흡착성 고형물에 의한 모사 이동층에서 크실렌을 분리하는 방법

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JP2002220352A (ja) 2002-08-09
NO923442L (no) 1993-03-08
NO177386C (no) 1995-09-05
DE69202944T2 (de) 1995-11-02
CN1072922A (zh) 1993-06-09
US5284992A (en) 1994-02-08
CA2077635C (fr) 2007-04-17
DK0531191T3 (da) 1995-11-13
US5629467A (en) 1997-05-13
JPH05201886A (ja) 1993-08-10
US5922924A (en) 1999-07-13
NO923442D0 (no) 1992-09-03
ES2076017T3 (es) 1995-10-16
TW200454B (ko) 1993-02-21
EP0531191A1 (fr) 1993-03-10
DE69202944D1 (de) 1995-07-20
US5401476A (en) 1995-03-28
CN1034069C (zh) 1997-02-19
JP3496122B2 (ja) 2004-02-09
CA2077635A1 (fr) 1993-03-06
EP0531191B1 (fr) 1995-06-14
NO177386B (no) 1995-05-29

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