FR3038529B1 - Adsorbants zeolithiques, leur procede de preparation et leurs utilisations - Google Patents

Adsorbants zeolithiques, leur procede de preparation et leurs utilisations Download PDF

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Publication number
FR3038529B1
FR3038529B1 FR1556524A FR1556524A FR3038529B1 FR 3038529 B1 FR3038529 B1 FR 3038529B1 FR 1556524 A FR1556524 A FR 1556524A FR 1556524 A FR1556524 A FR 1556524A FR 3038529 B1 FR3038529 B1 FR 3038529B1
Authority
FR
France
Prior art keywords
zeolithic
adsorbants
preparation process
adsorbents
xylenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1556524A
Other languages
English (en)
Other versions
FR3038529A1 (fr
Inventor
Ludivine Bouvier
Catherine Laroche
Julien Grandjean
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Arkema France SA
Original Assignee
IFP Energies Nouvelles IFPEN
Carbonisation et Charbons Actifs CECA SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN, Carbonisation et Charbons Actifs CECA SA filed Critical IFP Energies Nouvelles IFPEN
Priority to FR1556524A priority Critical patent/FR3038529B1/fr
Priority to CN201680040333.4A priority patent/CN107847904B/zh
Priority to EP16741570.2A priority patent/EP3319724A1/fr
Priority to US15/742,636 priority patent/US10745329B2/en
Priority to PCT/EP2016/066296 priority patent/WO2017005908A1/fr
Priority to TW105121848A priority patent/TWI759268B/zh
Publication of FR3038529A1 publication Critical patent/FR3038529A1/fr
Application granted granted Critical
Publication of FR3038529B1 publication Critical patent/FR3038529B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
    • C07C37/82—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne des adsorbants zéolithiques à base de cristaux agglomérés de zéolithe X comprenant du baryum, du potassium et du sodium. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes.
FR1556524A 2015-07-09 2015-07-09 Adsorbants zeolithiques, leur procede de preparation et leurs utilisations Expired - Fee Related FR3038529B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1556524A FR3038529B1 (fr) 2015-07-09 2015-07-09 Adsorbants zeolithiques, leur procede de preparation et leurs utilisations
CN201680040333.4A CN107847904B (zh) 2015-07-09 2016-07-08 沸石吸附剂、其制备方法和其用途
EP16741570.2A EP3319724A1 (fr) 2015-07-09 2016-07-08 Adsorbants zéolithiques, leur procédé de préparation et leurs utilisations
US15/742,636 US10745329B2 (en) 2015-07-09 2016-07-08 Zeolite adsorbents, preparation process therefor and uses thereof
PCT/EP2016/066296 WO2017005908A1 (fr) 2015-07-09 2016-07-08 Adsorbants zéolithiques, leur procédé de préparation et leurs utilisations
TW105121848A TWI759268B (zh) 2015-07-09 2016-07-11 沸石吸附劑、其製備方法及其用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1556524A FR3038529B1 (fr) 2015-07-09 2015-07-09 Adsorbants zeolithiques, leur procede de preparation et leurs utilisations

Publications (2)

Publication Number Publication Date
FR3038529A1 FR3038529A1 (fr) 2017-01-13
FR3038529B1 true FR3038529B1 (fr) 2020-10-23

Family

ID=53879711

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1556524A Expired - Fee Related FR3038529B1 (fr) 2015-07-09 2015-07-09 Adsorbants zeolithiques, leur procede de preparation et leurs utilisations

Country Status (6)

Country Link
US (1) US10745329B2 (fr)
EP (1) EP3319724A1 (fr)
CN (1) CN107847904B (fr)
FR (1) FR3038529B1 (fr)
TW (1) TWI759268B (fr)
WO (1) WO2017005908A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112642391B (zh) * 2019-10-10 2022-07-15 中国石油化工股份有限公司 一种聚结型对位二取代基苯吸附剂及其制备方法
CN113457212A (zh) * 2021-06-25 2021-10-01 中触媒新材料股份有限公司 一种同时提高间甲基苯酚纯度和改善其色度的捕集剂制备与使用方法
CN115990454A (zh) * 2021-10-20 2023-04-21 中国石油化工股份有限公司 一种改性x沸石及其制备方法和应用

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US2985589A (en) 1957-05-22 1961-05-23 Universal Oil Prod Co Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets
US3558730A (en) 1968-06-24 1971-01-26 Universal Oil Prod Co Aromatic hydrocarbon separation by adsorption
US3626020A (en) 1969-03-12 1971-12-07 Universal Oil Prod Co Separation of paraxylene from mixture of c aromatic utilizing crystalline aluminosilicate adsorbent
US3558732A (en) 1969-05-12 1971-01-26 Universal Oil Prod Co Aromatic hydrocarbon separation by adsorption
US3663638A (en) 1970-08-31 1972-05-16 Universal Oil Prod Co Aromatic hydrocarbon separation by adsorption
US3686342A (en) 1970-09-18 1972-08-22 Universal Oil Prod Co Aromatic hydrocarbon separation by adsorption
US3706813A (en) * 1971-07-08 1972-12-19 Universal Oil Prod Co Selectively adsorbing multibranched paraffins
US3960774A (en) 1973-05-02 1976-06-01 Universal Oil Products Company Zeolitic adsorbent for xylene separation
US3943184A (en) * 1974-02-15 1976-03-09 Universal Oil Products Company Aromatic hydrocarbon isomer separation process
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FR2791187B1 (fr) 1999-03-15 2001-05-04 Schneider Electric Sa Appareil electrique a encliqueter sur un rail
US6284021B1 (en) 1999-09-02 2001-09-04 The Boc Group, Inc. Composite adsorbent beads for adsorption process
FR2832077B1 (fr) * 2001-11-12 2004-08-27 Air Liquide Adsorbant zeolitique au baryum et calcium pour la purification de gaz, en particulier de l'air
CN1267185C (zh) 2003-06-30 2006-08-02 中国石油化工股份有限公司 对二甲苯吸附剂及制备方法
KR100727288B1 (ko) 2005-10-14 2007-06-13 한국과학기술원 메조다공성 골격을 갖는 미세다공성 결정성 분자체의제조방법
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KR101584751B1 (ko) 2012-08-16 2016-01-12 주식회사 케이티 송수신 포인트의 상향링크 제어채널 자원 설정 방법, 그 송수신 포인트, 단말의 상향링크 제어채널 자원 매핑방법 및 그 단말
FR2999098B1 (fr) * 2012-12-12 2022-01-14 Ceca Sa Adsorbants zeolithiques, leur procede de preparation et leurs utilisations
FR3002461B1 (fr) * 2013-02-22 2016-12-09 Ifp Energies Now Procede de separation des xylenes en lit mobile simule au moyen d'un solide adsorbant zeolithique de granulometrie comprise entre 150 et 500 microns
FR3004966B1 (fr) 2013-04-30 2016-02-05 IFP Energies Nouvelles Adsorbants zeolithiques comprenant de la zeolithe emt, leur procede de preparation et leurs utilisations
FR3010402B1 (fr) 2013-09-09 2015-08-28 Ceca Sa Adsorbants zeolithiques de haute surface externe, leur procede de preparation et leurs utilisations
US20150105600A1 (en) 2013-10-15 2015-04-16 Uop Llc Adsorbents for the separation of para-xylene from c8 alkyl aromatic hydrocarbon mixtures, methods for separating para-xylene using the adsorbents and methods for making the adsorbents
KR102194141B1 (ko) * 2013-11-06 2020-12-22 삼성전자주식회사 메조다공성 차바자이트 제올라이트 포함 이산화탄소 흡착제 및 그 제조 방법
FR3028430B1 (fr) * 2014-11-13 2018-08-17 IFP Energies Nouvelles Adsorbants zeolithiques a base de zeolithe lsx de surface externe controlee, leur procede de preparation et leurs utilisations
FR3028431B1 (fr) * 2014-11-13 2016-11-18 Ceca Sa Adsorbants zeolithiques a base de zeolithe x a faible taux de liant et a faible surface externe, leur procede de preparation et leurs utilisations

Also Published As

Publication number Publication date
TW201707786A (zh) 2017-03-01
WO2017005908A1 (fr) 2017-01-12
US10745329B2 (en) 2020-08-18
CN107847904B (zh) 2022-01-28
US20180201556A1 (en) 2018-07-19
FR3038529A1 (fr) 2017-01-13
CN107847904A (zh) 2018-03-27
EP3319724A1 (fr) 2018-05-16
TWI759268B (zh) 2022-04-01

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