JPWO2019226840A5 - - Google Patents
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- Publication number
- JPWO2019226840A5 JPWO2019226840A5 JP2020564835A JP2020564835A JPWO2019226840A5 JP WO2019226840 A5 JPWO2019226840 A5 JP WO2019226840A5 JP 2020564835 A JP2020564835 A JP 2020564835A JP 2020564835 A JP2020564835 A JP 2020564835A JP WO2019226840 A5 JPWO2019226840 A5 JP WO2019226840A5
- Authority
- JP
- Japan
- Prior art keywords
- transition metal
- group
- working electrode
- salt
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 32
- 239000011780 sodium chloride Substances 0.000 claims description 26
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M Lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 20
- 229910052803 cobalt Inorganic materials 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 claims description 18
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 16
- 239000010941 cobalt Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- 238000007747 plating Methods 0.000 claims description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 11
- 239000011572 manganese Substances 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229910052723 transition metal Inorganic materials 0.000 claims description 9
- 150000003624 transition metals Chemical class 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- -1 Co 2 O 3 Inorganic materials 0.000 claims description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 claims description 7
- 239000011888 foil Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- HUCVOHYBFXVBRW-UHFFFAOYSA-M Caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 4
- CPRMKOQKXYSDML-UHFFFAOYSA-M Rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 claims description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M Sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 150000004679 hydroxides Chemical class 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 4
- 229910020599 Co 3 O 4 Inorganic materials 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 229910018663 Mn O Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 150000002826 nitrites Chemical class 0.000 claims description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Inorganic materials [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 239000011698 potassium fluoride Substances 0.000 claims description 2
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Inorganic materials [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 2
- 235000009518 sodium iodide Nutrition 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 239000008151 electrolyte solution Substances 0.000 claims 7
- 229910013553 LiNO Inorganic materials 0.000 claims 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M Lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims 4
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 239000003792 electrolyte Substances 0.000 claims 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Inorganic materials [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims 2
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N Hafnium Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 229920001940 conductive polymer Polymers 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 229910001410 inorganic ion Inorganic materials 0.000 claims 1
- 229910001507 metal halide Inorganic materials 0.000 claims 1
- 150000005309 metal halides Chemical class 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 238000001228 spectrum Methods 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 239000012535 impurity Substances 0.000 description 32
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 12
- 238000002484 cyclic voltammetry Methods 0.000 description 10
- 230000005496 eutectics Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000009713 electroplating Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 210000002356 Skeleton Anatomy 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 238000009854 hydrometallurgy Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 231100000989 no adverse effect Toxicity 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000003334 potential Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002194 synthesizing Effects 0.000 description 2
- 229910013733 LiCo Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium Ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000003181 co-melting Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000010192 crystallographic characterization Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000011068 load Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 230000000877 morphologic Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862676043P | 2018-05-24 | 2018-05-24 | |
| US62/676,043 | 2018-05-24 | ||
| US16/418,438 US10886523B2 (en) | 2018-05-24 | 2019-05-21 | Electroplating lithiated transition metal oxides using low purity starting precursors |
| US16/418,438 | 2019-05-21 | ||
| PCT/US2019/033632 WO2019226840A1 (en) | 2018-05-24 | 2019-05-23 | Electroplating lithiated transition metal oxides using low purity starting precursors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2021524986A JP2021524986A (ja) | 2021-09-16 |
| JPWO2019226840A5 true JPWO2019226840A5 (zh) | 2022-05-20 |
| JP7191125B2 JP7191125B2 (ja) | 2022-12-16 |
Family
ID=68613523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020564835A Active JP7191125B2 (ja) | 2018-05-24 | 2019-05-23 | 低純度出発前駆体を使用するリチオ化遷移金属酸化物の電気めっき |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10886523B2 (zh) |
| EP (1) | EP3814554A4 (zh) |
| JP (1) | JP7191125B2 (zh) |
| KR (1) | KR102639011B1 (zh) |
| CN (1) | CN112135931B (zh) |
| CL (1) | CL2020003009A1 (zh) |
| MX (1) | MX2020012504A (zh) |
| WO (1) | WO2019226840A1 (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102370723B1 (ko) * | 2014-07-22 | 2022-03-04 | 제리온 어드밴스드 배터리 코퍼레이션 | 리튬화 전이 금속 산화물 |
| US20190100850A1 (en) | 2017-10-03 | 2019-04-04 | Xerion Advanced Battery Corporation | Electroplating Transitional Metal Oxides |
| WO2019126196A1 (en) | 2017-12-22 | 2019-06-27 | Lyten, Inc. | Structured composite materials |
| CN111653767B (zh) * | 2020-02-27 | 2021-10-01 | 乳源东阳光磁性材料有限公司 | 一种高镍多晶三元正极材料的洗涤工艺及制备方法 |
| US11339481B1 (en) * | 2021-08-06 | 2022-05-24 | Lithium Ark Holding B.V. | Production of lithium hydroxide and lithium carbonate |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3060009B2 (ja) * | 1997-11-12 | 2000-07-04 | 東京工業大学長 | 複合酸化物膜の製造方法、金属複合体、複合酸化物膜及び機能性導電材料 |
| US6623886B2 (en) * | 1999-12-29 | 2003-09-23 | Kimberly-Clark Worldwide, Inc. | Nickel-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries |
| FR2863276B1 (fr) * | 2003-12-09 | 2006-01-20 | Snecma Moteurs | Procede de colmatage exempt de chrome hexavalent applicable apres anodisation sulfurique d'alliages d'aluminium, solution de colmatage utilisee dans ce procede et article traite issu d'un tel procede |
| US9065139B2 (en) | 2009-02-04 | 2015-06-23 | National Institute Of Advanced Industrial Science And Technology | Fiber electrode for lithium secondary battery, fabrication method therefor, and lithium secondary battery including fiber electrode |
| GB2500163B (en) * | 2011-08-18 | 2016-02-24 | Nexeon Ltd | Method |
| KR101542052B1 (ko) * | 2012-04-17 | 2015-08-05 | 주식회사 엘지화학 | 리튬 이차전지용 전극의 제조 방법 및 이를 사용하여 제조되는 전극 |
| TW201405920A (zh) | 2012-05-29 | 2014-02-01 | Clariant Canada Inc | 製備晶形電極材料的方法及由之獲致的材料 |
| WO2014004817A2 (en) * | 2012-06-27 | 2014-01-03 | Precursor Energetics, Inc. | Processes and compositions for multi-transition metalcontaining cathode materials using molecular precursors |
| JP5630669B2 (ja) * | 2012-06-29 | 2014-11-26 | トヨタ自動車株式会社 | リチウム二次電池 |
| MX2015002323A (es) * | 2012-08-27 | 2015-06-05 | Nippon Steel & Sumitomo Metal Corp | Material activo de electrodo negativo. |
| JP6120263B2 (ja) | 2012-11-09 | 2017-04-26 | 国立研究開発法人産業技術総合研究所 | 電解析出法を利用するリチウム二次電池用ファイバー正極の製造方法 |
| FR3002482B1 (fr) * | 2013-02-25 | 2015-05-29 | Commissariat Energie Atomique | Procede de realisation de couches minces structurees en 3d |
| US20140272580A1 (en) * | 2013-03-15 | 2014-09-18 | Perfect Lithium Corp | Complexometric Precursor Formulation Methodology For Industrial Production Of Fine And Ultrafine Powders And Nanopowders Of Layered Lithium Mixed metal Oxides For Battery Applications |
| US9531004B2 (en) * | 2013-12-23 | 2016-12-27 | GM Global Technology Operations LLC | Multifunctional hybrid coatings for electrodes made by atomic layer deposition techniques |
| GB201400277D0 (en) * | 2014-01-08 | 2014-02-26 | Ilika Technologies Ltd | Vapour deposition method for preparing crystalline lithium-containing compounds |
| CN106660795B (zh) * | 2014-05-26 | 2019-07-26 | 约翰森·马瑟公开有限公司 | 产生LiMXO4的方法和其产物 |
| KR102370723B1 (ko) * | 2014-07-22 | 2022-03-04 | 제리온 어드밴스드 배터리 코퍼레이션 | 리튬화 전이 금속 산화물 |
-
2019
- 2019-05-21 US US16/418,438 patent/US10886523B2/en active Active
- 2019-05-23 KR KR1020207034380A patent/KR102639011B1/ko active IP Right Grant
- 2019-05-23 CN CN201980033467.7A patent/CN112135931B/zh active Active
- 2019-05-23 WO PCT/US2019/033632 patent/WO2019226840A1/en unknown
- 2019-05-23 EP EP19806757.1A patent/EP3814554A4/en active Pending
- 2019-05-23 MX MX2020012504A patent/MX2020012504A/es unknown
- 2019-05-23 JP JP2020564835A patent/JP7191125B2/ja active Active
-
2020
- 2020-11-19 CL CL2020003009A patent/CL2020003009A1/es unknown
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