JPWO2016051612A1 - 真空成形用シート用前駆体、真空成形用シートおよびその製造方法、ならびに成形品の製造方法 - Google Patents
真空成形用シート用前駆体、真空成形用シートおよびその製造方法、ならびに成形品の製造方法 Download PDFInfo
- Publication number
- JPWO2016051612A1 JPWO2016051612A1 JP2016551469A JP2016551469A JPWO2016051612A1 JP WO2016051612 A1 JPWO2016051612 A1 JP WO2016051612A1 JP 2016551469 A JP2016551469 A JP 2016551469A JP 2016551469 A JP2016551469 A JP 2016551469A JP WO2016051612 A1 JPWO2016051612 A1 JP WO2016051612A1
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- vacuum forming
- thermoplastic resin
- inorganic substance
- substance powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007666 vacuum forming Methods 0.000 title claims abstract description 106
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 34
- 239000002243 precursor Substances 0.000 title claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 70
- 239000000126 substance Substances 0.000 claims abstract description 58
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 48
- 239000004610 Internal Lubricant Substances 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims description 46
- 230000008569 process Effects 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 23
- 238000005452 bending Methods 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 238000001125 extrusion Methods 0.000 claims description 11
- 238000007493 shaping process Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000008431 aliphatic amides Chemical class 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000000047 product Substances 0.000 description 23
- 239000002245 particle Substances 0.000 description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- -1 polyethylene terephthalate Polymers 0.000 description 12
- 238000004898 kneading Methods 0.000 description 10
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 235000019359 magnesium stearate Nutrition 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- 241001149900 Fusconaia subrotunda Species 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- LZFOPEXOUVTGJS-ONEGZZNKSA-N trans-sinapyl alcohol Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O LZFOPEXOUVTGJS-ONEGZZNKSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- NZADFKWJIQWGNZ-UHFFFAOYSA-N (2-ethylphenyl) diphenyl phosphate Chemical compound CCC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 NZADFKWJIQWGNZ-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N (R)-alpha-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- GJDRKHHGPHLVNI-UHFFFAOYSA-N 2,6-ditert-butyl-4-(diethoxyphosphorylmethyl)phenol Chemical compound CCOP(=O)(OCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 GJDRKHHGPHLVNI-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- IORUEKDKNHHQAL-UHFFFAOYSA-N [2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenyl] prop-2-enoate Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)OC(=O)C=C)=C1O IORUEKDKNHHQAL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- LZFOPEXOUVTGJS-UHFFFAOYSA-N cis-sinapyl alcohol Natural products COC1=CC(C=CCO)=CC(OC)=C1O LZFOPEXOUVTGJS-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 229940096386 coconut alcohol Drugs 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- WGOROJDSDNILMB-UHFFFAOYSA-N octatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O WGOROJDSDNILMB-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- OOZBTDPWFHJVEK-UHFFFAOYSA-N tris(2-nonylphenyl) phosphate Chemical compound CCCCCCCCCC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC OOZBTDPWFHJVEK-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/02—Combined thermoforming and manufacture of the preform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0019—Combinations of extrusion moulding with other shaping operations combined with shaping by flattening, folding or bending
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/10—Forming by pressure difference, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/02—Bending or folding
- B29C53/04—Bending or folding of plates or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/02—Bending or folding
- B29C53/04—Bending or folding of plates or sheets
- B29C53/046—Bending or folding of plates or sheets using centrifugal force
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0011—Combinations of extrusion moulding with other shaping operations combined with compression moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/065—HDPE, i.e. high density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
- B29K2509/02—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
表1に記載したようなメルトマスフローレイト(MFR)の高密度ポリエステル樹脂と、平均粒子径(d50)が2.2μmで、粒子径45μm以上の粒子を含有しない炭酸カルシウム粉末とを、質量比が20:80となるように調節し、さらにマグネシウムステアレートを両原料に対し1、3、5質量%となるように配合した。上記混合物を、Tダイを備えた小型二軸混練押出成形機(テクノベル製)により設定温度220℃で混練し、直接成形してシート(平均厚さ200μm)を作成した。
メルトマスフローレイトが0.8g/10分の高密度ポリエチレン樹脂と、実施例1で用いた炭酸カルシウム粉末とを表2に示す所定の質量比となるように調節するとともに、前記両原料総量100質量部に対し、マグネシウムステアレートを3質量部となるように配合する。上記原料について、実施例1と同様にして、直接法成形を行った。ダイス出口から成形シートを引取ロール(90℃)に引き取り後、直ちに巻取ロール(30℃)に巻き取り、その際の引取ロールおとよび巻取ロールの回転速度をそれぞれ1.75m/minに設定した。得られた真空成形用シートの平均厚さは、200μmであった。
高密度ポリエチレン樹脂と炭酸カルシウム粉末とを、表2の配合比で混合するほかは、実施例2,3,4と同様にしてシートを成形し、平均厚さ200μmの真空成形用シートを得た。
上で得た真空成形用シートから、シート製造時の搬送方向(MD方向)、およびそれに直交する方向(TD方向)を長辺とする、幅15mmの短冊状の試験片を切り出し、1000Nのロードセルを取り付けた引張試験機((株)A&D製)を用い、120℃において、引張速度500mm/分の条件で引張試験を行い、フィルム破断時における強度および伸張率を測定した。
本明細書において、メルトマスフローレイトの値は、JIS K7210:1999「プラスチック−熱可塑性プラスチックのメルトマスフローレート(MFR)」(但し、試験温度190℃)により測定される値を意味する。
高密度ポリエチレン樹脂(メルトマスフローレイト=0.8g/10分)と平均粒子径(d=50)が2.2μmで、粒子径45μm以上の粒子を含有しない炭酸カルシウム粉末を、質量比45:55となるように調節し、さらにマグネシウムステアレートを両原料に対し3質量%となるように配合して、Tダイを備え付けた同方向回転式二軸押出成形機を用いて混合し混練を行い、直接成形して厚みが400μmの真空成形用シートを作成した。
実施例4と同条件で作成した厚さ400μmの真空成形用シートを実施例4と同じ真空成形機により同一条件で、深さ73mmのテスト用金型を用いて成形した。成形物は該金型を十分に再現しており、結果は良好であった。
12 固形物体
Claims (12)
- 熱可塑性樹脂、無機物質粉末および内部滑剤を含有し、前記熱可塑性樹脂と前記無機物質粉末とが、質量比で55:45〜30:70の範囲で含まれる、真空成形用シート。
- シート製造時のシートの搬送方向と直交する方向(TD方向)および搬送方向(MD方向)において、JIS K7127−1999に準拠して測定された120℃における伸長率がいずれも20%以上である、請求項1に記載の真空成形用シート。
- 前記内部滑剤が、脂肪酸、金属石鹸、脂肪族アミド、およびアルコールの脂肪族エステルからなる群から選択される一種以上を含む、請求項1または2に記載の真空成形用シート。
- 前記内部滑剤が、前記熱可塑性樹脂および前記無機物質粉末の総量100質量部に対し、0.5〜5.0質量部含有される、請求項1〜3いずれか1項に記載の真空成形用シート。
- 熱可塑性樹脂、無機物質粉末および内部滑剤を含有し、前記熱可塑性樹脂と前記無機物質粉末とが、質量比で55:45〜30:70の範囲で含まれる混練物からなる、真空成形用シート用前駆体。
- 熱可塑性樹脂、無機物質粉末、および内部滑剤を含有し、前記熱可塑性樹脂と前記無機物質粉末とが質量比で55:45〜30:70の範囲で含まれる混練物をシート状に成形して成形シートとする成形工程を含む、真空成形用シートの製造方法。
- 前記混練物が、請求項5に記載の真空成形用シート用前駆体を含む、請求項6に記載の真空成形用シートの製造方法。
- 前記成形工程が、二軸押出成形機を用いて混練された前記混練物を押出成形する工程を含む、請求項6に記載の真空成形用シートの製造方法。
- 前記成形シートを搬送方向に移動させる途中で、前記成形シートの表面に固体物体を押し付け、その当接部分において前記成形シートを折り曲げた状態にすることにより、前記成形シートの内部に作用する応力を発生させる曲げ処理工程を有する、請求項6〜8いずれか1項に記載の真空成形用シートの製造方法。
- 前記混練物が、前記熱可塑性樹脂および前記無機物質粉末の総量100質量部に対し、前記内部滑剤を0.5〜5.0質量部含有する、請求項6〜9いずれか1項に記載の真空成形用シートの製造方法。
- 請求項1〜4いずれか1項に記載の真空成形用シートに、真空成形加工により形状を賦形する、成形品の製造方法。
- 前記熱可塑性樹脂に対する前記無機物質粉末の含有量(質量比)が、50/50以上である請求項11に記載の成形品の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014198488 | 2014-09-29 | ||
JP2014198488 | 2014-09-29 | ||
PCT/JP2014/082308 WO2016051612A1 (ja) | 2014-09-29 | 2014-12-05 | 真空成形用シート用前駆体、真空成形用シートおよびその製造方法、ならびに成形品の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2016051612A1 true JPWO2016051612A1 (ja) | 2017-08-17 |
JP6675530B2 JP6675530B2 (ja) | 2020-04-01 |
Family
ID=55629694
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016551469A Active JP6675530B2 (ja) | 2014-09-29 | 2014-12-05 | 真空成形用シート用前駆体、真空成形用シートおよびその製造方法、ならびに成形品の製造方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20170217078A1 (ja) |
EP (1) | EP3202551A4 (ja) |
JP (1) | JP6675530B2 (ja) |
KR (1) | KR20170061138A (ja) |
CN (1) | CN106715082B (ja) |
BR (1) | BR112017006105A2 (ja) |
MA (1) | MA40139B1 (ja) |
PH (1) | PH12017500573A1 (ja) |
RU (1) | RU2674949C2 (ja) |
WO (1) | WO2016051612A1 (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109311183A (zh) * | 2016-08-12 | 2019-02-05 | 株式会社Tbm | 树脂成型体的制造方法、树脂成型用颗粒的制造方法及提高平滑性的方法 |
JP6614667B2 (ja) * | 2016-11-17 | 2019-12-04 | 株式会社Tbm | ペレットを製造する方法、樹脂成形体の製造方法、及びペレット |
JP6765118B2 (ja) * | 2016-11-17 | 2020-10-07 | 株式会社Tbm | シートの製造方法、樹脂成形体の製造方法及びシート |
CN113459484A (zh) * | 2021-06-30 | 2021-10-01 | 江西沃格光电股份有限公司 | 一种真空成型方法 |
CN113968693A (zh) * | 2021-10-28 | 2022-01-25 | 江苏阿路美格新材料股份有限公司 | 一种防火芯材及制造方法 |
Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS575735A (en) * | 1980-06-16 | 1982-01-12 | Karupu Kogyo Kk | Resin composition for vacuum molding |
JPH05279507A (ja) * | 1992-03-31 | 1993-10-26 | Ajinomoto Co Inc | フィラー入りプラスチック発泡体及び発泡シート並びに発泡容器 |
JPH06155689A (ja) * | 1992-11-25 | 1994-06-03 | Idemitsu Petrochem Co Ltd | 積層体及びそれを用いた容器 |
JPH09327857A (ja) * | 1996-06-07 | 1997-12-22 | Oji Yuka Synthetic Paper Co Ltd | 不透明性に優れた樹脂フィルムの製造方法 |
JPH11228777A (ja) * | 1998-02-10 | 1999-08-24 | Daicel Chem Ind Ltd | シート成形用樹脂組成物及び容器成形用シート |
JPH11293074A (ja) * | 1998-04-14 | 1999-10-26 | Achilles Corp | 塩化ビニル系樹脂組成物 |
JP2001026047A (ja) * | 1998-11-30 | 2001-01-30 | Sekisui Chem Co Ltd | 熱可塑性樹脂押出成形体の製造方法及び熱可塑性樹脂押出成形体 |
JP2003225981A (ja) * | 2002-02-01 | 2003-08-12 | Toyobo Co Ltd | 多層ポリエステル系シ−ト、フイルム、およびそれからなる成形品 |
JP2003295767A (ja) * | 2002-02-04 | 2003-10-15 | Yupo Corp | インモールド成形用ラベル |
JP2003305816A (ja) * | 2002-04-16 | 2003-10-28 | Toyobo Co Ltd | 多層ポリエステル系シ−ト、フイルム、およびそれからなる成形品 |
JP2004501237A (ja) * | 2000-05-25 | 2004-01-15 | ゼネラル・エレクトリック・カンパニイ | スチレン重合体、共重合体又はブレンドを含む組成物及び物品 |
JP2004351747A (ja) * | 2003-05-29 | 2004-12-16 | Sumitomo Bakelite Co Ltd | 硬質塩化ビニール樹脂シート及びその製造方法 |
JP2011032297A (ja) * | 2009-07-29 | 2011-02-17 | Nippon Carbide Ind Co Inc | アクリル樹脂系脆質フィルム |
JP2012218338A (ja) * | 2011-04-12 | 2012-11-12 | Sekisui Chem Co Ltd | 耐燃焼性成形体の製造方法 |
JP2013010931A (ja) * | 2011-05-31 | 2013-01-17 | Tbm Co Ltd | 無機物質粉末高配合薄膜シートの製造方法 |
WO2014109267A1 (ja) * | 2013-01-11 | 2014-07-17 | 株式会社Tbm | 加工用薄膜材料 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2657272A1 (de) * | 1976-12-17 | 1978-06-29 | Huels Chemische Werke Ag | Thermoplastische massen |
US6211501B1 (en) * | 1998-03-20 | 2001-04-03 | Fort James Corporation | Thermoformed polypropylene mineral-filled microwaveable containers having food contact compatible olfactory properties and process for their manufacture |
US7223806B2 (en) * | 2001-03-14 | 2007-05-29 | Sumitomo Chemical Company, Limited | Manufacturing method of film-like materials of resin and film-like materials of resin |
DE102005060401A1 (de) * | 2005-12-15 | 2007-06-21 | Degussa Gmbh | Lagerstabile Beschichtungszusammensetzung für eine abriebfeste und witterungsbeständige Ausstattung glatter anorganischer Oberflächen mit "Easy-to-clean"-Eigenschaften |
US8383704B2 (en) * | 2008-10-03 | 2013-02-26 | Honda Motor Co., Ltd. | Process for producing molded propylene polymer product containing fibrous inorganic filler |
DE102010001787A1 (de) * | 2010-02-10 | 2011-08-11 | Sgl Carbon Se, 65203 | Verfahren zur Herstellung eines Formteils aus einem Kohlenstoffwerkstoff unter Verwendung von wiederverwerteten Carbonfasern |
JP6155689B2 (ja) * | 2013-02-22 | 2017-07-05 | 株式会社ニコン | 認証装置及び認証方法 |
-
2014
- 2014-12-05 CN CN201480082127.0A patent/CN106715082B/zh not_active Expired - Fee Related
- 2014-12-05 JP JP2016551469A patent/JP6675530B2/ja active Active
- 2014-12-05 MA MA40139A patent/MA40139B1/fr unknown
- 2014-12-05 BR BR112017006105A patent/BR112017006105A2/pt active Search and Examination
- 2014-12-05 EP EP14902939.9A patent/EP3202551A4/en not_active Withdrawn
- 2014-12-05 WO PCT/JP2014/082308 patent/WO2016051612A1/ja active Application Filing
- 2014-12-05 RU RU2017112992A patent/RU2674949C2/ru not_active IP Right Cessation
- 2014-12-05 KR KR1020177009452A patent/KR20170061138A/ko not_active Application Discontinuation
- 2014-12-05 US US15/515,429 patent/US20170217078A1/en not_active Abandoned
-
2017
- 2017-03-27 PH PH12017500573A patent/PH12017500573A1/en unknown
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS575735A (en) * | 1980-06-16 | 1982-01-12 | Karupu Kogyo Kk | Resin composition for vacuum molding |
JPH05279507A (ja) * | 1992-03-31 | 1993-10-26 | Ajinomoto Co Inc | フィラー入りプラスチック発泡体及び発泡シート並びに発泡容器 |
JPH06155689A (ja) * | 1992-11-25 | 1994-06-03 | Idemitsu Petrochem Co Ltd | 積層体及びそれを用いた容器 |
JPH09327857A (ja) * | 1996-06-07 | 1997-12-22 | Oji Yuka Synthetic Paper Co Ltd | 不透明性に優れた樹脂フィルムの製造方法 |
JPH11228777A (ja) * | 1998-02-10 | 1999-08-24 | Daicel Chem Ind Ltd | シート成形用樹脂組成物及び容器成形用シート |
JPH11293074A (ja) * | 1998-04-14 | 1999-10-26 | Achilles Corp | 塩化ビニル系樹脂組成物 |
JP2001026047A (ja) * | 1998-11-30 | 2001-01-30 | Sekisui Chem Co Ltd | 熱可塑性樹脂押出成形体の製造方法及び熱可塑性樹脂押出成形体 |
JP2004501237A (ja) * | 2000-05-25 | 2004-01-15 | ゼネラル・エレクトリック・カンパニイ | スチレン重合体、共重合体又はブレンドを含む組成物及び物品 |
JP2003225981A (ja) * | 2002-02-01 | 2003-08-12 | Toyobo Co Ltd | 多層ポリエステル系シ−ト、フイルム、およびそれからなる成形品 |
JP2003295767A (ja) * | 2002-02-04 | 2003-10-15 | Yupo Corp | インモールド成形用ラベル |
JP2003305816A (ja) * | 2002-04-16 | 2003-10-28 | Toyobo Co Ltd | 多層ポリエステル系シ−ト、フイルム、およびそれからなる成形品 |
JP2004351747A (ja) * | 2003-05-29 | 2004-12-16 | Sumitomo Bakelite Co Ltd | 硬質塩化ビニール樹脂シート及びその製造方法 |
JP2011032297A (ja) * | 2009-07-29 | 2011-02-17 | Nippon Carbide Ind Co Inc | アクリル樹脂系脆質フィルム |
JP2012218338A (ja) * | 2011-04-12 | 2012-11-12 | Sekisui Chem Co Ltd | 耐燃焼性成形体の製造方法 |
JP2013010931A (ja) * | 2011-05-31 | 2013-01-17 | Tbm Co Ltd | 無機物質粉末高配合薄膜シートの製造方法 |
WO2014109267A1 (ja) * | 2013-01-11 | 2014-07-17 | 株式会社Tbm | 加工用薄膜材料 |
Also Published As
Publication number | Publication date |
---|---|
CN106715082B (zh) | 2020-05-08 |
US20170217078A1 (en) | 2017-08-03 |
MA40139B1 (fr) | 2018-05-31 |
WO2016051612A1 (ja) | 2016-04-07 |
RU2674949C2 (ru) | 2018-12-13 |
RU2017112992A (ru) | 2018-11-08 |
KR20170061138A (ko) | 2017-06-02 |
BR112017006105A2 (pt) | 2017-12-19 |
MA40139A1 (fr) | 2017-12-29 |
CN106715082A (zh) | 2017-05-24 |
PH12017500573A1 (en) | 2017-08-30 |
RU2017112992A3 (ja) | 2018-11-08 |
JP6675530B2 (ja) | 2020-04-01 |
EP3202551A1 (en) | 2017-08-09 |
EP3202551A4 (en) | 2018-06-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR102365289B1 (ko) | 무기 물질 분말 배합 열가소성 수지 조성물 및 성형품 | |
JP6675530B2 (ja) | 真空成形用シート用前駆体、真空成形用シートおよびその製造方法、ならびに成形品の製造方法 | |
JP2013010931A5 (ja) | ||
JP6492269B2 (ja) | フィラー含有プラスチックシートの製造方法 | |
JP2013227549A (ja) | ポリスチレン系樹脂発泡シート、及び、積層発泡シート | |
WO2018150599A1 (ja) | フィラメント及びその製造方法 | |
JP6765118B2 (ja) | シートの製造方法、樹脂成形体の製造方法及びシート | |
JP6334247B2 (ja) | 再生フィラー含有プラスチックシート及びその製造方法 | |
JP3623681B2 (ja) | 三層共押出方式で得られる厚み25〜250ミクロン二軸延伸ポリプロピレン(bopp)パール光沢合成紙の製造方法 | |
JP6614667B2 (ja) | ペレットを製造する方法、樹脂成形体の製造方法、及びペレット | |
JP6347718B2 (ja) | 表皮材被覆発泡粒子成形体 | |
CN112644121A (zh) | 一种bopp半消光转移膜及其制备方法 | |
CN109486027A (zh) | 一种可快速冲压汽车材料及其制备方法 | |
RU2663060C1 (ru) | Изделие, содержащее полимолочную кислоту и наполнитель | |
JP6783480B2 (ja) | シート状樹脂成形体の製造方法 | |
JP2011037132A (ja) | 表面形状転写樹脂シートの製造方法 | |
JP2019202421A (ja) | ポリプロピレン系積層フィルム | |
JP2009001674A (ja) | 熱可塑性樹脂組成物発泡成形体及びその製造方法 | |
JP2020023055A (ja) | 積層シート、積層シートの製造方法及び成形体 | |
JP2005254675A (ja) | 真空成形用樹脂シート及びその製造方法並びに樹脂成形品 | |
JP2001322164A (ja) | ポリプロピレン系樹脂発泡シートの成形方法及び発泡容器 | |
JPS62237972A (ja) | 極微細な凹凸模様を有し触感良好な軟質塩化ビニル系樹脂フイルムの製造法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20171003 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180807 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180918 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190305 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20191001 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20191030 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20191108 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20191126 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20191225 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6675530 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |