JPWO2015133455A1 - 臨界ミセル濃度の低減方法および界面活性剤組成物 - Google Patents
臨界ミセル濃度の低減方法および界面活性剤組成物 Download PDFInfo
- Publication number
- JPWO2015133455A1 JPWO2015133455A1 JP2016506489A JP2016506489A JPWO2015133455A1 JP WO2015133455 A1 JPWO2015133455 A1 JP WO2015133455A1 JP 2016506489 A JP2016506489 A JP 2016506489A JP 2016506489 A JP2016506489 A JP 2016506489A JP WO2015133455 A1 JPWO2015133455 A1 JP WO2015133455A1
- Authority
- JP
- Japan
- Prior art keywords
- sfna
- mol
- anionic surfactant
- surfactant
- cyclic lipopeptide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000693 micelle Substances 0.000 title claims abstract description 63
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 56
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 76
- 239000003876 biosurfactant Substances 0.000 claims abstract description 65
- 108010028921 Lipopeptides Proteins 0.000 claims abstract description 62
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 62
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 51
- AFWTZXXDGQBIKW-UHFFFAOYSA-N C14 surfactin Natural products CCCCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 AFWTZXXDGQBIKW-UHFFFAOYSA-N 0.000 claims description 29
- NJGWOFRZMQRKHT-UHFFFAOYSA-N surfactin Natural products CC(C)CCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-UHFFFAOYSA-N 0.000 claims description 29
- NJGWOFRZMQRKHT-WGVNQGGSSA-N surfactin C Chemical compound CC(C)CCCCCCCCC[C@@H]1CC(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-WGVNQGGSSA-N 0.000 claims description 29
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 11
- 125000000539 amino acid group Chemical group 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004711 α-olefin Substances 0.000 claims description 8
- OCUSNPIJIZCRSZ-ZTZWCFDHSA-N (2s)-2-amino-3-methylbutanoic acid;(2s)-2-amino-4-methylpentanoic acid;(2s,3s)-2-amino-3-methylpentanoic acid Chemical compound CC(C)[C@H](N)C(O)=O.CC[C@H](C)[C@H](N)C(O)=O.CC(C)C[C@H](N)C(O)=O OCUSNPIJIZCRSZ-ZTZWCFDHSA-N 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 description 56
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 37
- 229910052708 sodium Inorganic materials 0.000 description 31
- 239000011734 sodium Substances 0.000 description 31
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 30
- 230000000694 effects Effects 0.000 description 30
- 238000005259 measurement Methods 0.000 description 28
- 239000000758 substrate Substances 0.000 description 24
- 239000000047 product Substances 0.000 description 19
- 108010069514 Cyclic Peptides Proteins 0.000 description 12
- 102000001189 Cyclic Peptides Human genes 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 8
- 229910021642 ultra pure water Inorganic materials 0.000 description 8
- 239000012498 ultrapure water Substances 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 150000004996 alkyl benzenes Chemical class 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- 150000005215 alkyl ethers Chemical class 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 108090000765 processed proteins & peptides Proteins 0.000 description 4
- 229940032094 squalane Drugs 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 238000000089 atomic force micrograph Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- LWHQXUODFPPQTL-UHFFFAOYSA-M sodium;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate Chemical compound [Na+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LWHQXUODFPPQTL-UHFFFAOYSA-M 0.000 description 3
- QYEWAEAWMXRMHB-YFTUCIGFSA-N (4r)-5-[[(3s,6r,9s,12r,15s,18r,21r,22r)-3-[(2s)-butan-2-yl]-6,12-bis(hydroxymethyl)-22-methyl-9,15-bis(2-methylpropyl)-2,5,8,11,14,17,20-heptaoxo-18-propan-2-yl-1-oxa-4,7,10,13,16,19-hexazacyclodocos-21-yl]amino]-4-[[(2s)-2-[[(3r)-3-hydroxydecanoyl]amino] Chemical compound CCCCCCC[C@@H](O)CC(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CCC(O)=O)C(=O)N[C@@H]1[C@@H](C)OC(=O)[C@H]([C@@H](C)CC)NC(=O)[C@@H](CO)NC(=O)[C@H](CC(C)C)NC(=O)[C@@H](CO)NC(=O)[C@H](CC(C)C)NC(=O)[C@@H](C(C)C)NC1=O QYEWAEAWMXRMHB-YFTUCIGFSA-N 0.000 description 2
- ZTOKUMPYMPKCFX-CZNUEWPDSA-N (E)-17-[(2R,3R,4S,5S,6R)-6-(acetyloxymethyl)-3-[(2S,3R,4S,5S,6R)-6-(acetyloxymethyl)-3,4,5-trihydroxyoxan-2-yl]oxy-4,5-dihydroxyoxan-2-yl]oxyoctadec-9-enoic acid Chemical compound OC(=O)CCCCCCC/C=C/CCCCCCC(C)O[C@@H]1O[C@H](COC(C)=O)[C@@H](O)[C@H](O)[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](COC(C)=O)O1 ZTOKUMPYMPKCFX-CZNUEWPDSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000015227 regulation of liquid surface tension Effects 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 229940082004 sodium laurate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QYEWAEAWMXRMHB-UHFFFAOYSA-N 8-Angeloyl-8alpha-4,9-Muuroladiene-1,8-diol Natural products CCCCCCCC(O)CC(=O)NC(CC(C)C)C(=O)NC(CCC(O)=O)C(=O)NC1C(C)OC(=O)C(C(C)CC)NC(=O)C(CO)NC(=O)C(CC(C)C)NC(=O)C(CO)NC(=O)C(CC(C)C)NC(=O)C(C(C)C)NC1=O QYEWAEAWMXRMHB-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- HXMCERBOSXQYRH-KSVGBCIHSA-N Arthrofactin Chemical compound CCCCCCCC1CC(=O)N[C@H](CC(C)C)C(=O)N[C@H](CC(O)=O)C(=O)N[C@H]([C@H](C)O)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CO)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CO)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CC(O)=O)C(=O)O1 HXMCERBOSXQYRH-KSVGBCIHSA-N 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 108010066374 arthrofactin Proteins 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000551 dentifrice Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 210000002257 embryonic structure Anatomy 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SBWGZAXBCCNRTM-CTHBEMJXSA-N n-methyl-n-[(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl]octanamide Chemical compound CCCCCCCC(=O)N(C)C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SBWGZAXBCCNRTM-CTHBEMJXSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 1
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000035935 pregnancy Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- MVHWMCQWFWUXEE-GEEYTBSJSA-M sodium;(e)-hexadec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCC\C=C\S([O-])(=O)=O MVHWMCQWFWUXEE-GEEYTBSJSA-M 0.000 description 1
- WYMNMGKBGAKXHR-UHFFFAOYSA-M sodium;3-hydroxyoctadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(O)CCS([O-])(=O)=O WYMNMGKBGAKXHR-UHFFFAOYSA-M 0.000 description 1
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 210000004291 uterus Anatomy 0.000 description 1
- 108010067142 viscosin Proteins 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/16—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing nitrogen, e.g. nitro-, nitroso-, azo-compounds, nitriles, cyanates
- A61K47/18—Amines; Amides; Ureas; Quaternary ammonium compounds; Amino acids; Oligopeptides having up to five amino acids
- A61K47/183—Amino acids, e.g. glycine, EDTA or aspartame
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/20—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing sulfur, e.g. dimethyl sulfoxide [DMSO], docusate, sodium lauryl sulfate or aminosulfonic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/30—Macromolecular organic or inorganic compounds, e.g. inorganic polyphosphates
- A61K47/42—Proteins; Polypeptides; Degradation products thereof; Derivatives thereof, e.g. albumin, gelatin or zein
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
- A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/30—Proteins; Protein hydrolysates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/02—Alkyl sulfonates or sulfuric acid ester salts derived from monohydric alcohols
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Birds (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- General Chemical & Material Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Dermatology (AREA)
- Pest Control & Pesticides (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Mycology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Peptides Or Proteins (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Cosmetics (AREA)
- Oral & Maxillofacial Surgery (AREA)
Abstract
Description
上記陰イオン界面活性剤に環状リポペプチドバイオサーファクタントを組み合わせて使用することを特徴とする方法。
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す]
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す]
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す]
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す]
Xとしてのアミノ酸残基は、L体でもD体でもよいが、L体が好ましい。
洗浄剤に配合される主要なアニオン性界面活性剤である直鎖アルキルベンゼンスルホン酸ナトリウム(LAS)に対する、サーファクチンナトリウム(SFNa)による使用量低減効果を、表面張力測定により検証した。具体的には、まず、バイヤル瓶にLASまたはSFNaと超純水を加え、スターラーで撹拌することにより溶解させ、10mM水溶液を調製した。これら溶液を所定の割合で混合した後、さらに超純水を加えて混合水溶液を希釈した各水溶液を得た。当該各水溶液をシャーレーへ移し変えて一昼夜静置し、高機能表面張力計(協和界面科学社製,「DY−500」)を用い、25℃で表面張力の濃度依存性を測定した。結果を図1に示す。
次に、LASと同様に主要な陰イオン界面活性剤であるドデシル硫酸ナトリウム(SDS)に対するサーファクチンナトリウム(SFNa)による使用量低減効果を、表面張力測定により検証した。具体的には、LASの代わりにSDSを用いたこと以外は上記実施例1と同様にして、SDS単独水溶液、SDS/SFNa混合水溶液およびSFNa単独水溶液を調製し、表面張力を測定した。結果を図3に示す。
次に、LASおよびSDSと同様に、主要な非イオン界面活性剤であるポリオキシエチレンアルキルエーテル(POE−AE)に対するサーファクチンナトリウム(SFNa)による使用量低減効果を、表面張力測定により検証した。具体的には、LASまたはSDSの代わりにPOE−AE(日本乳化剤株式会社製「NEWCOL2308」)を用いたこと以外は上記実施例1および実施例2と同様にして、POE−AE単独水溶液、POE−AE/SFNa混合水溶液およびSFNa単独水溶液を調製し、表面張力を測定した。結果を図5に示す。
バイヤル瓶にSFNaと超純水を1mMになるように測りとり、スターラーで攪拌することにより溶解させた。この溶液を、パスツールピペットを用いてマイカ基板上に一滴滴下して、室温で風乾させた。SFNaが配向したマイカ基板の表面形状を原子間力顕微鏡(セイコーインスツル社製「SPI4000」)によって観察した。その結果を図7に示す。図7(1)中、写真の下のスケールは、写真中の色と縦方向の高さとの関係を示す。
SFNaの濃度が1mM(1000ppm)になるようにSFNaと超純水をバイヤル瓶に測りとり、スターラーで攪拌することにより溶解させた。この溶液を、パスツールピペットを用いてSUS基板上(日造精密研磨株式会社製,「SUS304」,精密研磨処理品)に一滴滴下して、デシケーター内で乾燥させた。SUS基板の表面形状を原子間力顕微鏡(セイコーインスツル社製「SPI4000」)を用い、タッピングモードによって観察した。また、比較のため、SFNa溶液で処理する前のSUS基板も同様に観察した。SUS基板の原子間力顕微鏡写真を図8に、SFNa溶液で処理したSUS基板の原子間力顕微鏡を図9に示す。なお、図8,9中、各写真の下のスケールは、写真中の色と縦方向の高さとの関係を示す。
SFNaの濃度が0.025mM(25ppm)、0.0125mM(12.5ppm)または0.008mM(8ppm)になるようにSFNaと超純水をバイヤル瓶に測りとり、スターラーで攪拌することにより溶解させた。各溶液を、パスツールピペットを用いてSUS基板上(日造精密研磨株式会社製,「SUS304」,精密研磨処理品)に一滴滴下して、デシケーター内で乾燥させた。各基板の表面を、上記参考例3と同様に原子間力顕微鏡を使ってタッピングモードにより観察し、写真を撮影した。各写真を図10(1)〜(3)に示す。なお、図10中、各写真の下のスケールは、写真中の色と縦方向の高さとの関係を示す。
上記実施例1で用いた直鎖アルキルベンゼンスルホン酸ナトリウム(LAS)および上記実施例2で用いたドデシル硫酸ナトリウム(SDS)と同様に、環境への影響が懸念されている陰イオン界面活性剤であるペルフルオロオクタン酸ナトリウム(PFOSNa)に対するサーファクチンナトリウム(SFNa)による使用量低減効果を、表面張力測定により検証した。
ラウリン酸ナトリウム(LaNa)に対するサーファクチンナトリウム(SFNa)による使用量低減効果を、表面張力測定により検証した。具体的には、LaNa(和光純薬工業株式会社製)を用い、LaNa単独の場合と、LaNaに対してSFNaをモル比で9:1(10mol%)、99:1(1mol%)、または999:1(0.1mol%)の割合で添加した場合の水溶液の表面張力を測定した。結果を図13に示す。
直鎖アルキルベンゼンスルホン酸ナトリウム(LAS)にサーファクチンナトリウム(SFNa)を添加した系において、低濃度におけるミセル形成を実際に確認した。具体的には、上記実施例1と同様に、LAS単独、およびLASに対してSFNaをモル比で9:1(10mol%)の割合で添加した各種水溶液を調製した。光散乱光度計(大塚電子社製,製品名「DLS−7000」)を用い、得られた各種濃度の水溶液の散乱光強度を測定した。その際、光源にはArレーザー(λ=488nm)を用い、散乱角度は90度に設定した。なお、得られた散乱光強度と溶媒である超純水の散乱光強度の比、相対散乱光強度を濃度に対してプロットした結果を図14に示す。
直鎖アルキルベンゼンスルホン酸ナトリウム(LAS)にサーファクチンナトリウム(SFNa)を添加した系において、低濃度におけるスクアランの乳化能を検証した。具体的には、上記実施例1と同様に、LAS単独、SFNa単独、およびLASに対してSFNaをモル比で9:1(10mol%)の割合で添加した全濃度が1.5×10-5Mの水溶液を調製した。また、対照として、界面活性剤を添加しない超純水のみも準備した。これら水溶液または超純水1mLとスクアラン(和光純薬工業株式会社製)3mLを試験菅中に測りとり、ボルテックスミキサーで1分間撹拌した。これらの溶液を25℃で1日静置し目視観察した結果を図15に示す。
Claims (13)
- 陰イオン界面活性剤の臨界ミセル濃度を低減する方法であって、
上記陰イオン界面活性剤に環状リポペプチドバイオサーファクタントを組み合わせて使用することを特徴とする方法。 - 上記環状リポペプチドバイオサーファクタントとして、下記式(I)で表されるサーファクチンまたはその塩を用いる請求項1に記載の方法。
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す] - 上記陰イオン界面活性剤として、直鎖アルキルベンゼンスルホン酸塩、アルファオレフィンスルホン酸塩またはアルキル硫酸塩を用いる請求項1または2に記載の方法。
- 上記陰イオン界面活性剤と上記環状リポペプチドバイオサーファクタントの合計に対して、上記環状リポペプチドバイオサーファクタントを0.1mol%以上用いる請求項1〜3のいずれかに記載の方法。
- 陰イオン界面活性剤および環状リポペプチドバイオサーファクタントを含むことを特徴とする界面活性剤組成物。
- 上記環状リポペプチドバイオサーファクタントが、下記式(I)で表されるサーファクチンまたはその塩である請求項5に記載の界面活性剤組成物。
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す] - 上記陰イオン界面活性剤が、直鎖アルキルベンゼンスルホン酸塩、アルファオレフィンスルホン酸塩またはアルキル硫酸塩である請求項5または6に記載の界面活性剤組成物。
- 上記陰イオン界面活性剤と上記環状リポペプチドバイオサーファクタントの合計に対して、上記環状リポペプチドバイオサーファクタントを0.1mol%以上含む請求項5〜7のいずれかに記載の界面活性剤組成物。
- さらに水を含む請求項5〜8のいずれかに記載の界面活性剤組成物。
- 陰イオン界面活性剤の臨界ミセル濃度を低減するための環状リポペプチドバイオサーファクタントの使用。
- 上記環状リポペプチドバイオサーファクタントが下記式(I)で表されるサーファクチンまたはその塩である請求項10に記載の使用。
[式中、
Xは、ロイシン、イソロイシンおよびバリンから選択されるアミノ酸残基を示し;
R1はC9-18アルキル基を示す] - 上記陰イオン界面活性剤が、直鎖アルキルベンゼンスルホン酸塩、アルファオレフィンスルホン酸塩またはアルキル硫酸塩である請求項10または11に記載の使用。
- 上記陰イオン界面活性剤と上記環状リポペプチドバイオサーファクタントの合計に対して、上記環状リポペプチドバイオサーファクタントを0.1mol%以上用いる請求項10〜12のいずれかに記載の使用。
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014043060 | 2014-03-05 | ||
JP2014043060 | 2014-03-05 | ||
JP2014118831 | 2014-06-09 | ||
JP2014118831 | 2014-06-09 | ||
JP2014152647 | 2014-07-28 | ||
JP2014152647 | 2014-07-28 | ||
PCT/JP2015/056167 WO2015133455A1 (ja) | 2014-03-05 | 2015-03-03 | 臨界ミセル濃度の低減方法および界面活性剤組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2015133455A1 true JPWO2015133455A1 (ja) | 2017-04-06 |
JP6555595B2 JP6555595B2 (ja) | 2019-08-07 |
Family
ID=54055261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016506489A Active JP6555595B2 (ja) | 2014-03-05 | 2015-03-03 | 臨界ミセル濃度の低減方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9868097B2 (ja) |
EP (1) | EP3115104B1 (ja) |
JP (1) | JP6555595B2 (ja) |
CN (1) | CN106068158B (ja) |
WO (1) | WO2015133455A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6954895B2 (ja) * | 2016-04-11 | 2021-10-27 | 株式会社カネカ | 過脂肪剤およびパーソナルケア組成物 |
JP2018127513A (ja) * | 2017-02-06 | 2018-08-16 | メルク、パテント、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツングMerck Patent GmbH | 半導体水溶性組成物、およびその使用 |
JP2018177851A (ja) * | 2017-04-04 | 2018-11-15 | 日華化学株式会社 | 精練剤組成物及び繊維製品の製造方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000327591A (ja) * | 1998-05-29 | 2000-11-28 | Showa Denko Kk | 皮膚外用剤用界面活性剤及びそれを含有する皮膚外用剤 |
JP2004027133A (ja) * | 2002-06-28 | 2004-01-29 | Showa Denko Kk | 液晶パネル用洗浄剤組成物 |
JP2004149446A (ja) * | 2002-10-30 | 2004-05-27 | Nonogawa Shoji Kk | 皮膚洗浄料 |
JP2009275177A (ja) * | 2008-05-16 | 2009-11-26 | Lion Corp | 洗浄剤組成物 |
JP2011236347A (ja) * | 2010-05-11 | 2011-11-24 | Miyoshi Oil & Fat Co Ltd | ノニオン型界面活性剤 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1196469C (zh) * | 1998-05-29 | 2005-04-13 | 昭和电工株式会社 | 用于皮肤外用制剂的表面活性剂以及含有该表面活性剂的皮肤外用制剂 |
KR20070115980A (ko) * | 2005-02-28 | 2007-12-06 | 카네카 코포레이션 | 응고 라텍스 입자의 제조 방법 |
GB0623838D0 (en) * | 2006-11-29 | 2007-01-10 | Malvern Cosmeceutics Ltd | Novel compositions |
CN101041846A (zh) * | 2007-01-29 | 2007-09-26 | 中国科学院等离子体物理研究所 | 新型脂肽类生物表面活性剂surfactin的制备方法及用途 |
US8540902B2 (en) * | 2010-01-13 | 2013-09-24 | CNano Technology Limited | Carbon nanotube based pastes |
MX2014003280A (es) * | 2011-09-20 | 2014-05-13 | Procter & Gamble | Composiciones detergentes que comprenden sistemas surfactantes sostenibles que comprenden surfactantes derivados de isoprenoides. |
CN102580609A (zh) * | 2011-12-29 | 2012-07-18 | 华东理工大学 | 一种表面活性剂及其制备方法 |
JP6308593B2 (ja) * | 2013-03-25 | 2018-04-11 | 株式会社カネカ | シリコーン汚染物を洗浄するための洗浄剤 |
WO2015022936A1 (ja) * | 2013-08-12 | 2015-02-19 | 株式会社カネカ | 界面活性剤組成物 |
BR112016027807B1 (pt) * | 2014-05-28 | 2021-09-28 | Bayer Cropscience Lp. | Composições fungicidas e seus método de produção, bem como métodos para controle e tratamento de doenças fúngicas e bacterianas em plantas, planta ou parte de planta e semente |
US9364413B2 (en) * | 2014-07-31 | 2016-06-14 | Umo International Co., Ltd. | Method for anti-aging treatment by surfactin in cosmetics via enhancing sirtuin |
-
2015
- 2015-03-03 CN CN201580011571.8A patent/CN106068158B/zh active Active
- 2015-03-03 US US15/121,630 patent/US9868097B2/en active Active
- 2015-03-03 WO PCT/JP2015/056167 patent/WO2015133455A1/ja active Application Filing
- 2015-03-03 EP EP15757734.7A patent/EP3115104B1/en active Active
- 2015-03-03 JP JP2016506489A patent/JP6555595B2/ja active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000327591A (ja) * | 1998-05-29 | 2000-11-28 | Showa Denko Kk | 皮膚外用剤用界面活性剤及びそれを含有する皮膚外用剤 |
JP2004027133A (ja) * | 2002-06-28 | 2004-01-29 | Showa Denko Kk | 液晶パネル用洗浄剤組成物 |
JP2004149446A (ja) * | 2002-10-30 | 2004-05-27 | Nonogawa Shoji Kk | 皮膚洗浄料 |
JP2009275177A (ja) * | 2008-05-16 | 2009-11-26 | Lion Corp | 洗浄剤組成物 |
JP2011236347A (ja) * | 2010-05-11 | 2011-11-24 | Miyoshi Oil & Fat Co Ltd | ノニオン型界面活性剤 |
Non-Patent Citations (3)
Title |
---|
ONAIZI, S.A. ET AL.: "Micellization and interfacial behavior of a synthetic surfactant-biosurfactant mixture", COLLOIDS AND SURFACES A: PHYSICOCHEM. ENG. ASPECTS, vol. 415, JPN6015022409, 2012, pages 388 - 393, XP055223104, ISSN: 0003952494, DOI: 10.1016/j.colsurfa.2012.09.014 * |
YONEDA, T. ET AL.: "Surfactin Sodium Salt: An Excellent Bio-Surfactant for Cosmetics", JOURNAL OF COSMETIC SCIENCE, vol. 52, no. 2, JPN6015022410, 2001, pages 153 - 154, XP008184248, ISSN: 0003952495 * |
YONEDA, T. ET AL.: "サーファクチンナトリウム:新規機能性バイオサーファクタントの開発", FRAGRANCE JOURNAL, vol. 29, no. 12, JPN6015022413, 2001, pages 93 - 97, ISSN: 0003952496 * |
Also Published As
Publication number | Publication date |
---|---|
CN106068158B (zh) | 2018-06-08 |
EP3115104B1 (en) | 2019-04-24 |
EP3115104A1 (en) | 2017-01-11 |
US9868097B2 (en) | 2018-01-16 |
JP6555595B2 (ja) | 2019-08-07 |
EP3115104A4 (en) | 2017-08-23 |
US20160361698A1 (en) | 2016-12-15 |
WO2015133455A1 (ja) | 2015-09-11 |
CN106068158A (zh) | 2016-11-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5154931B2 (ja) | 低pH構造化界面活性剤組成物 | |
JP3522752B2 (ja) | 界面活性剤混合物 | |
JP5328032B2 (ja) | 洗浄剤組成物 | |
CN112533575B (zh) | 在含有疏水改性或非疏水改性的阴离子聚合物的清洁液中增强的保湿剂沉积 | |
JP6555595B2 (ja) | 臨界ミセル濃度の低減方法 | |
US20170056851A1 (en) | Inorganic nanoparticle dispersion liquid and method for producing same | |
JPWO2018052084A1 (ja) | ゲル状組成物、並びにそれを用いた皮膚外用剤及び化粧料 | |
JP6730433B2 (ja) | 乳化組成物及びそれを用いる化粧料 | |
CN104204177A (zh) | 低voc含量的无水清洗剂及用其浸渍的制品 | |
JP5125333B2 (ja) | ゲル化剤、ゲル状組成物及びその利用 | |
JP2019214564A (ja) | 可溶化皮膚洗浄剤組成物 | |
WO2015022936A1 (ja) | 界面活性剤組成物 | |
WO2015022944A1 (ja) | 界面自由エネルギーの低減方法と界面自由エネルギーが低減された組成物 | |
JP2009057515A (ja) | ゲル化剤、ゲル状組成物及びその利用 | |
JP5191026B2 (ja) | 洗浄剤組成物 | |
CA2723560C (en) | Substantially surfactant free in-shower gel compositions comprising hydrophilic and hydrophobic benefit agents and methods of enhancing deposition | |
JP2005097616A (ja) | 両性界面活性剤の高濃縮化水溶液 | |
JP2008031162A (ja) | 皮膚用洗浄剤組成物 | |
TW201809246A (zh) | 利用伸展鏈界面活性劑之組合增加溶解度 | |
JP2017197494A (ja) | バイオサーファクタントを含むことを特徴とする乳化物 | |
JP2003277791A (ja) | ゲル状洗浄剤組成物 | |
KR20150059580A (ko) | 액체 세제 조성물 | |
JP2006160964A (ja) | 研磨剤含有洗浄剤 | |
WO2021122647A1 (en) | High viscosity elastic gels and uses therefor | |
JP2010043231A (ja) | ゲル化剤及びゲル状組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180119 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180119 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20181207 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190108 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190301 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190423 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190524 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190611 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190627 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6555595 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |