JP6730433B2 - 乳化組成物及びそれを用いる化粧料 - Google Patents
乳化組成物及びそれを用いる化粧料 Download PDFInfo
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- JP6730433B2 JP6730433B2 JP2018526401A JP2018526401A JP6730433B2 JP 6730433 B2 JP6730433 B2 JP 6730433B2 JP 2018526401 A JP2018526401 A JP 2018526401A JP 2018526401 A JP2018526401 A JP 2018526401A JP 6730433 B2 JP6730433 B2 JP 6730433B2
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- oil
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- 239000005453 ketone based solvent Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 229940114937 microcrystalline wax Drugs 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229940042472 mineral oil Drugs 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- 229940051866 mouthwash Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 239000004590 silicone sealant Substances 0.000 description 1
- 231100000245 skin permeability Toxicity 0.000 description 1
- 231100000438 skin toxicity Toxicity 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
しかし、かかる組成物は、調製直後には乳化状態にあっても、その乳化状態を安定に維持できないことがあった。よって、従来、シリコーンオイルを含む組成物の乳化状態を保つためには、界面活性剤の配合量を増やしたり、シリコーンオイルや油性成分の量を減らしたり、水相の粘度を上げたりするといった方法がとられてきた。しかしこの様な方法では、刺激性が増したり、組成物構成に制限が生じたりするといった問題があった。
そこで本発明は、乳化状態が安定的に維持されている乳化組成物、及び当該乳化組成物を含む化粧料を提供することを目的とする。
以下、本発明を示す。
Xは、ロイシン残基、イソロイシン残基、及びバリン残基からなる群より選択されるアミノ酸残基を示し;
R1はC9−18アルキル基を示す]
Xは、ロイシン残基、イソロイシン残基、及びバリン残基からなる群より選択されるアミノ酸残基を示し;
R1はC9−18アルキル基を示す]
定されるものではない。
表1に示すシリコーンオイルを試験管に2g入れ、更に、界面活性剤水溶液、具体的には、サーファクチンナトリウム水溶液又はドデシル硫酸ナトリウム水溶液を2g加え、試験管ミキサーを用いて常温で1分間攪拌して混合物を得た。なお、界面活性剤水溶液の濃度は、最終濃度が25mMになるように調整した。また、使用したシリコーンオイルは、いずれも信越シリコーン社製の製品である。
乳化指数(%)=[(乳化相の高さ)/(全体の高さ)]×100
サーファクチンナトリウムを用いた結果を図1に示し、ドデシル硫酸ナトリウムを用いた結果を図2に示す。なお、図1中、「SF」はサーファクチンナトリウムを示し、図2中、「SDS」はドデシル硫酸ナトリウムを示す。
しかし、アミノ変性シリコーンオイル(製品名「KF−8004」)に限っては、ドデシル硫酸ナトリウムでも当初は乳化可能であっても、静置により直ぐに分液してしまうのに対して、サーファクチンナトリウムを用いれば、乳化状態が比較的安定的に持続することが明らかとなった。このように、アミノ変性シリコーンオイルの乳化には、サーファクチンナトリウムが適する傾向が認められた。
上記実施例1において、各界面活性剤の最終濃度を1/50である0.5mMに変更した以外は同様にして、実験を行った。サーファクチンナトリウムを用いた結果を図3に示し、ドデシル硫酸ナトリウムを用いた結果を図4に示す。
アミノ変性シリコーンオイル(製品名「KF−8004」)の場合、当初はドデシル硫酸ナトリウムでも乳化効果が認められたが、乳化状態は安定ではなく、経時的に分離してしまった。
一方、サーファクチンナトリウムを配合した場合には、乳化状態が徐々に解消されていく傾向は認められたものの、その程度はドデシル硫酸ナトリウムに比べると明らかに低かった。以上の通り、界面活性剤濃度を低減した場合においても、アミノ変性シリコーンオイルの乳化には、サーファクチンナトリウムが適する傾向が認められた。
表2に示すアミノ変性シリコーンオイルを使用した以外は実施例1と同様にして、実験を行った。結果を図5に示す。
更に、上記実施例3において、混合物全体に対する界面活性剤の濃度を0.5mMに低減した以外は同様にして実験を行った。結果を図6に示す。
Claims (4)
- アミノ変性シリコーンオイル、水系溶媒、及び、下記式(I)で表されるサーファクチンを含む乳化組成物であって、前記乳化組成物において界面活性剤は全て、下記式(I)で表されるサーファクチンである乳化組成物。
Xは、ロイシン残基、イソロイシン残基、及びバリン残基からなる群より選択されるアミノ酸残基を示し;
R1はC9−18アルキル基を示す] - 更に油性成分を含む請求項1に記載の乳化組成物。
- 前記乳化組成物全体に対する前記サーファクチンの濃度が0.1mM以上、50mM以下である請求項1又は2に記載の乳化組成物。
- 請求項1〜3のいずれかに記載の乳化組成物のみからなる化粧料。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016133023 | 2016-07-05 | ||
JP2016133023 | 2016-07-05 | ||
PCT/JP2017/024552 WO2018008653A1 (ja) | 2016-07-05 | 2017-07-04 | 乳化組成物及びそれを用いる化粧料 |
Publications (2)
Publication Number | Publication Date |
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JPWO2018008653A1 JPWO2018008653A1 (ja) | 2019-03-14 |
JP6730433B2 true JP6730433B2 (ja) | 2020-07-29 |
Family
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JP2018526401A Active JP6730433B2 (ja) | 2016-07-05 | 2017-07-04 | 乳化組成物及びそれを用いる化粧料 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20190133896A1 (ja) |
EP (1) | EP3459521A4 (ja) |
JP (1) | JP6730433B2 (ja) |
CN (1) | CN109414391A (ja) |
WO (1) | WO2018008653A1 (ja) |
Families Citing this family (4)
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JP7048480B2 (ja) | 2018-12-19 | 2022-04-05 | 信越化学工業株式会社 | マイクロエマルション組成物及びその硬化物、並びに、それを含んだ化粧料 |
EP3808792B1 (en) | 2019-10-17 | 2024-07-03 | Kaneka Belgium N.V. | Aqueous emulsion of polyether having at least one reactive silyl group |
JP7250725B2 (ja) | 2020-04-24 | 2023-04-03 | 信越化学工業株式会社 | マイクロエマルション組成物並びにそれを含んだ化粧料 |
WO2023230628A2 (en) * | 2022-05-26 | 2023-11-30 | Ruby Bio Inc. | Emulsifiers formed from polyol esters of fatty acids |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4185087A (en) * | 1977-12-28 | 1980-01-22 | Union Carbide Corporation | Hair conditioning compositions containing dialkylamino hydroxy organosilicon compounds and their derivatives |
JPS5863750A (ja) * | 1981-10-12 | 1983-04-15 | Asahi Denka Kogyo Kk | シリコ−ン油乳化乃至可溶化物 |
EP1414389A1 (en) * | 2001-08-10 | 2004-05-06 | Showa Denko K.K. | Oily thickened gel-like composition, emulsified composition using the composition, and preparation method thereof |
WO2005089708A1 (en) * | 2004-03-24 | 2005-09-29 | Showa Denko K.K. | Oil-in-water emulsified composition, and external preparation for skin and cosmetics using the composition |
JP4536562B2 (ja) * | 2005-03-24 | 2010-09-01 | 昭和電工株式会社 | 乳化した毛髪処理用薬剤 |
DE102005037800A1 (de) * | 2005-08-03 | 2007-02-08 | Coty Deutschland Gmbh | Kosmetische Emulsion |
US7923014B2 (en) * | 2007-02-12 | 2011-04-12 | The Board Of Regents Of The University Of Texas System | Expression and purification of HIP/PAP and uses therefor |
JP5702918B2 (ja) * | 2009-06-01 | 2015-04-15 | ホーユー株式会社 | 毛髪化粧料組成物 |
JP2011026281A (ja) * | 2009-07-29 | 2011-02-10 | Toyobo Co Ltd | バイオサーファクタントを用いた毛髪化粧料 |
JP2011225453A (ja) * | 2010-04-15 | 2011-11-10 | Toyobo Co Ltd | 皮膚化粧料 |
MX2014005404A (es) * | 2011-11-04 | 2014-06-23 | Unilever Nv | Composicion cosmetica. |
US8597670B2 (en) * | 2011-12-07 | 2013-12-03 | Avon Products, Inc. | Wash resistant compositions containing aminosilicone |
JP6276785B2 (ja) * | 2013-02-28 | 2018-02-07 | 花王株式会社 | 半永久的直毛化のための組成物及びプロセス |
US9717676B2 (en) * | 2013-07-26 | 2017-08-01 | The Procter & Gamble Company | Amino silicone nanoemulsion |
-
2017
- 2017-07-04 EP EP17824256.6A patent/EP3459521A4/en active Pending
- 2017-07-04 JP JP2018526401A patent/JP6730433B2/ja active Active
- 2017-07-04 CN CN201780041907.4A patent/CN109414391A/zh active Pending
- 2017-07-04 WO PCT/JP2017/024552 patent/WO2018008653A1/ja unknown
-
2018
- 2018-12-27 US US16/233,781 patent/US20190133896A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
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EP3459521A4 (en) | 2019-04-24 |
JPWO2018008653A1 (ja) | 2019-03-14 |
US20190133896A1 (en) | 2019-05-09 |
EP3459521A1 (en) | 2019-03-27 |
CN109414391A (zh) | 2019-03-01 |
WO2018008653A1 (ja) | 2018-01-11 |
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