JPS6328299B2 - - Google Patents
Info
- Publication number
- JPS6328299B2 JPS6328299B2 JP54164348A JP16434879A JPS6328299B2 JP S6328299 B2 JPS6328299 B2 JP S6328299B2 JP 54164348 A JP54164348 A JP 54164348A JP 16434879 A JP16434879 A JP 16434879A JP S6328299 B2 JPS6328299 B2 JP S6328299B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- substituted
- unsubstituted
- general formula
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 7
- 239000000084 colloidal system Substances 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 230000001804 emulsifying effect Effects 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 125000004442 acylamino group Chemical group 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 125000004414 alkyl thio group Chemical group 0.000 claims description 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 2
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims description 2
- 125000005110 aryl thio group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- -1 silver halide Chemical class 0.000 description 70
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 18
- 239000010410 layer Substances 0.000 description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 15
- 108010010803 Gelatin Proteins 0.000 description 14
- 239000000975 dye Substances 0.000 description 14
- 229920000159 gelatin Polymers 0.000 description 14
- 239000008273 gelatin Substances 0.000 description 14
- 235000019322 gelatine Nutrition 0.000 description 14
- 235000011852 gelatine desserts Nutrition 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 229910052709 silver Inorganic materials 0.000 description 9
- 239000004332 silver Substances 0.000 description 9
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000001235 sensitizing effect Effects 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 235000019439 ethyl acetate Nutrition 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 206010070834 Sensitisation Diseases 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000001246 colloidal dispersion Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000001043 yellow dye Substances 0.000 description 3
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical compound C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 2
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- 125000000335 thiazolyl group Chemical group 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Substances C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- YUTUUOJFXIMELV-UHFFFAOYSA-N 2-Hydroxy-2-(2-methoxy-2-oxoethyl)butanedioic acid Chemical compound COC(=O)CC(O)(C(O)=O)CC(O)=O YUTUUOJFXIMELV-UHFFFAOYSA-N 0.000 description 1
- PYBSFPTVHNWRRC-UHFFFAOYSA-N 2-ethoxy-4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCOC1=CC(N(CC)CC)=CC=C1N PYBSFPTVHNWRRC-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- YTEPJDDAQWIJEP-UHFFFAOYSA-N 4-n,4-n-diethyl-2,6-dimethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC(C)=C(N)C(C)=C1 YTEPJDDAQWIJEP-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- UJUCBOIXAMPUQL-UHFFFAOYSA-N 7-aminothieno[2,3-b]pyrazine-6-carboxylic acid Chemical compound C1=CN=C2C(N)=C(C(O)=O)SC2=N1 UJUCBOIXAMPUQL-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 1
- HCVBQXINVUFVCE-UHFFFAOYSA-N Citronensaeure-beta-methylester Natural products COC(=O)C(O)(CC(O)=O)CC(O)=O HCVBQXINVUFVCE-UHFFFAOYSA-N 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- IJFPVINAQGWBRJ-UHFFFAOYSA-N Diisooctyl phthalate Chemical compound CC(C)CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC(C)C IJFPVINAQGWBRJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical class NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940067597 azelate Drugs 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- JWARINFCJPFHFA-UHFFFAOYSA-N butyl bis(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCCCC)OCC(CC)CCCC JWARINFCJPFHFA-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- CJYAHFDVLLKRNX-UHFFFAOYSA-N dibutyl 2-ethylhexyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCC(CC)CCCC CJYAHFDVLLKRNX-UHFFFAOYSA-N 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- FGTZUGRWBPELAH-UHFFFAOYSA-N dibutyl hexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCC)OCCCC FGTZUGRWBPELAH-UHFFFAOYSA-N 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- DQLJOCWRWFJZMD-UHFFFAOYSA-N dihexyl phenyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OC1=CC=CC=C1 DQLJOCWRWFJZMD-UHFFFAOYSA-N 0.000 description 1
- 150000002027 dodecanoic acid esters Chemical class 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- YBSWYHAWMOPART-UHFFFAOYSA-N dodecyl diethyl phosphate Chemical compound CCCCCCCCCCCCOP(=O)(OCC)OCC YBSWYHAWMOPART-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- NPKFETRYYSUTEC-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 NPKFETRYYSUTEC-UHFFFAOYSA-N 0.000 description 1
- 125000004708 n-butylthio group Chemical group C(CCC)S* 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000006678 phenoxycarbonyl group Chemical group 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical class OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- MCSKRVKAXABJLX-UHFFFAOYSA-N pyrazolo[3,4-d]triazole Chemical compound N1=NN=C2N=NC=C21 MCSKRVKAXABJLX-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003329 sebacic acid derivatives Chemical class 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- QJAVUVZBMMXBRO-UHFFFAOYSA-N tripentyl phosphate Chemical compound CCCCCOP(=O)(OCCCCC)OCCCCC QJAVUVZBMMXBRO-UHFFFAOYSA-N 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
- G03C7/39212—Carbocyclic
- G03C7/39216—Carbocyclic with OH groups
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ãããã²ã³åéã«ã©ãŒåçæå
ææã®
ã«ã©ãŒçŸåã®éã«çããè²ã«ããªããã³æ··è²ãé²
æ¢ãããå®å®ãªãã€ããããã³èªå°äœã®ä¹³ååæ£
ç©ãå«ãã«ã©ãŒåçæå ææã«é¢ãããã®ã§ã
ãã ã«ã©ãŒåçæå ææã«ãããŠãè³éŠæ第äžçŽã¢
ãã³ååç©ãçšããŠãé²å ãããããã²ã³åéç²
åãçŸåããçæããè³éŠæ第äžçŽã¢ãã³ååç©
ã®é žåçæç©ãšã«ãã©ãŒãšã®åå¿ã«ããè²çŽ åã
圢æããããããšãç¥ãããŠããã ãã®æ¹æ³ã«ãããŠã¯ãéåžžã·ã¢ã³ãããŒã³ã¿ã
ã€ãšããŒã®è²çŽ ç»åã圢æããããã«ããããã
ããšããŒã«ãŸãã¯ããããŒã«ç³»ã«ãã©ãŒïŒïŒâã
ã©ãŸãã³ããã©ãŸãªããã³ãã€ãããŸãŒã«ããã©
ãŸãããªã¢ãŸãŒã«ãã€ã³ããŸãã³ãŸãã¯ã·ã¢ãã¢
ã»ãã«ç³»ã«ãã©ãŒïŒã¢ã·ã«ã¢ã»ãã¢ãããŸãã¯ãž
ãã³ãŸã€ã«ã¡ã¿ã³ç³»ã«ãã©ãŒãçšããããŠããã
ãããã®ã«ãã©ãŒã¯ããã²ã³åéä¹³å€å±€äžã«æ·»å
ããæ¹æ³ãšçŸå液äžã«æ·»å ããæ¹æ³ãšãç¥ãããŠ
ããã ãããã®æ¹æ³ã§ã«ã©ãŒåçæå ææãã«ã©ãŒçŸ
åããéã«ã¯ãè²ã«ããªããã³æ··è²ãšããæãŸã
ããªãçŸè±¡ãæ¹ãèµ·ãããŠãããåŸæ¥æ³ã§ã¯ãã
ããè²ã«ããªããã³æ··è²ãé²æ¢ããããã«ãã€ã
ãããã³ç³»ååç©ãã«ã©ãŒåçæå ææã®æ§æå±€
ã®äœããã®å±€äžã«å«æãããŠãããäŸãã°ãç±³åœ
ç¹èš±ç¬¬2336327å·ãå第2360290å·ãå第2384658
å·ãå第2675531å·ãå第2728659å·ãå第
2732300å·ãå第3700453å·åå ¬å ±ãªã©ã«èšèŒãã
ãŠããã ãããããããŸã§ã®æ¹æ³ã§ã¯è²ã«ããªããã³æ··
è²é²æ¢ã«é©çšããããã€ããããã³èªå°äœãå«æ
ããæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ãå®å®ã§ãªããç¹
ã«æ°åæ¥éã®çµæä¿åã§ã¯çµæ¶ã®æåºãçããã
æãã¯åŸ®çŽ°ãªç¶æ ã§æ²¹æ»Žãååšããªããªã€ããã
ãããšãå€ãããã®ãããã€ããããã³èªå°äœã®
è²ã«ããªããã³æ··è²ã«å¯Ÿããååãªå¹æãçºæ®ã
ãããããšãã§ããªãããšãããããããã®æ¬ ç¹
ãæ¹è¯ããããã«ããããŸã§ããã€ãã®æ¹æ³ãæ
æ¡ãããŠãããããããã®æ¹æ³ã§ã¯äžèšæ¬ ç¹ãæ¹
è¯ããã«ã¯ååãªæ¹æ³ãšã¯èšããªããäŸãã°ãã
ã€ããããã³èªå°äœãäºçš®ä»¥äžäœµçšããããšã«ã
ã€ãŠæåºãé²æ¢ããæ¹æ³ãææ¡ãããŠããããå
åãªãã®ã§ã¯ãªãããŸãé«æ²žç¹ææ©æº¶åªã®äœ¿çšé
ãå¢å€§ãããããšã«ããå®å®ãªæ°Žäžæ²¹æ»Žåã³ãã€
ãåæ£ç©ã調補ããæ¹æ³ãç¥ãããŠãããããã
ããŸãååãªãã®ãšã¯èšããªãã æ¬çºæã®ç®çã¯ããã€ããããã³èªå°äœãå«æ
ããå®å®ãªæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ãæäŸãã
ããšã«ããã æ¬çºæã®å¥ã®ç®çã¯ãã«ã©ãŒçŸåã®éã«çãã
è²ã«ããªããã³æ··è²ãæå¹ã«é²æ¢ããã«ã©ãŒåç
æå ææãæäŸããããšã«ããã æ¬çºæã®ãããç®çã¯ãäžèšäžè¬åŒããã§ç€º
ããããã€ããããã³èªå°äœãäžèšäžè¬åŒãã
ã§ç€ºãããé«æ²žç¹ææ©æº¶åªãçšããŠæº¶è§£ããŠåŸã
ãã溶液ã芪氎æ§ã³ãã€ã液äžã«ä¹³åãããããš
ã«ãã圢æãããæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£æ¶²ã調
補ãããããã³ãã€ãåæ£æ¶²ãã«ã©ãŒåçæå æ
æã®æ§æå±€ã®å°ãªããšãïŒå±€ã«é©çšããããšã«ã
ãéæãããã äžè¬åŒãã åŒäžãR1ããã³R2ã¯ãæ°ŽçŽ ååã眮æè¥ãã
ã¯é眮æã®ã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«åºããšã
ã«åºãïœâãããã«åºãïœâãããã«åºãïœâã
ãã«åºãïœâããã«åºãïœâã¢ãã«åºãïœâã¢ã
ã«åºãïœâãªã¯ãã«åºãïœâããã·ã«åºãïœâãª
ã¯ã¿ãã·ã«åºãªã©ã§ç¹ã«ççŽ æ°ïŒã32ã®ã¢ã«ãã«
åºã奜ãŸããããã®ä»ã«ïŒâã¡ããã·ãšãã«åºã
ïŒâããšãã«ãšãã«åºããã³ãžã«åºãïŒâã·ã¢ã
ãããã«åºãªã©ãæããããšãã§ãããïŒã眮æè¥
ããã¯é眮æã®ã¢ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«
åºããªã¯ããã«åºããªã¬ã€ã«åºãªã©ã§ççŽ æ°ïŒã
32ã®ã¢ã«ã±ãã«åºã奜ãŸãããïŒã眮æè¥ããã¯é
眮æã®ã¢ãªãŒã«åºïŒäŸãã°ãããšãã«åºãããªã«
åºãïŒâïœâããã«ããšãã«åºããããã«åºãª
ã©ïŒã眮æè¥ããã¯é眮æã®ã¢ã·ã«åºïŒäŸãã°ã
ã¢ã»ãã«åºããªã¯ã¿ãã€ã«åºãªã©ïŒã眮æè¥ãã
ã¯é眮æã®ã·ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã·ã¯ãã
ãã·ã«åºãã·ã¯ããã³ãã«åºãªã©ïŒãŸãã¯çœ®æè¥
ããã¯é眮æã®å«çªçŽ è€çŽ ç°ïŒäŸãã°ãã€ãããŸ
ãªã«åºãããªã«åºãããªãžã«åºãããªã¢ãžãã«
åºããã¢ãŸãªã«åºãïŒïŒïŒâãžâããã·ã«âïŒâ
ãããã·ããšããã·ïŒâïŒïŒïŒïŒïŒâããªã¢ãžã
ã«åºãªã©ïŒã瀺ãã R3ãR4ãR5ããã³R6ã¯ãæ°ŽçŽ ååãããã²ã³
ååïŒäŸãã°ãå¡©çŽ ååãèçŽ ååãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«
åºããšãã«åºãïœâãããã«åºãïœâãããã«
åºãïœâããã«åºãïœâããã«åºãïœâãªã¯ãã«
åºãïœâããã·ã«åºãªã©ã§ãç¹ã«ççŽ æ°ïŒã32ã®
ã¢ã«ãã«åºã奜ãŸããããã®ä»ã«ããã³ãžã«åºã
ã¢ã«ã³ãã·ã¢ã«ãã«åºãïŒâããšãã«ãšãã«åºã
ïŒâããããã·âïŒâã¡ãã«ãšãã«åºãïŒïŒïŒïŒ
âãžâããããã·âïŒâïœâããã«ïŒãã³ãžã«åº
ãªã©ãæããããšãã§ãããïŒçœ®æè¥ããã¯é眮
æã®ã¢ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«åºããªã¯ãã
ã«åºãªã©ã§ç¹ã«ççŽ æ°ïŒã32ã®ã¢ã«ã±ãã«åºã奜
ãŸãããïŒã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«åºïŒäŸ
ãã°ãããšãã«åºãããªã«åºããããã«åºãã¡ã
ãã·ããšãã«åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã·
ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã·ã¯ãããã·ã«åºãã·
ã¯ããã³ãã«åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã¢
ã«ã³ãã·åºïŒäŸãã°ãã¡ããã·åºããããã·åºã
ããã·ã«ãªãã·åºããšããã·ã¡ããã·åºãããšã
ãã·ã¡ããã·åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã¢
ã«ãã«ããªåºïŒäŸãã°ãã¡ãã«ããªåºãïœâãã
ã«ããªåºãïœâããã·ã«ããªåºãªã©ïŒã眮æè¥ã
ãã¯é眮æã®ã¢ãªãŒã«ããªåºïŒäŸãã°ãããšãã«
ããªåºãã¡ãã«ããšãã«ããªåºããžã¡ãã«ããšã
ã«ããªåºãªã©ïŒã眮æè¥ããã¯é眮æã®å«çªçŽ è€
çŽ ç°ããªåºïŒäŸãã°ãå«çªçŽ è€çŽ ç°ãšããŠã¯ãã
ã©ãŸãªã«åºããã¢ãŸãªã«åºãªã©ã奜ãŸãããïŒã眮
æè¥ããã¯é眮æã®ã¢ãªãŒã«ãªãã·åºïŒäŸãã°ã
ããšããã·åºãã¡ãã«ããšããã·åºãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã·ã«åºïŒäŸãã°ãã¢ã»ãã«
åºããªã¯ã¿ãã€ã«åºãã©ãŠãã€ã«åºãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»
ãã«ã¢ããåºããªã¯ã¿ãã€ã«ã¢ããåºãã©ãŠãã€
ã«ã¢ããåºããã³ãŸã€ã«ã¢ããåºãªã©ïŒã眮æè¥
ããã¯é眮æã®ã¢ã«ãã«ã¢ããåºïŒäŸãã°ãã¡ã
ã«ã¢ããåºããžãšãã«ã¢ããåºãïœâãªã¯ãã«ã¢
ããåºããžãã·ã«ã¢ããåºãªã©ïŒã眮æè¥ããã¯
é眮æã®ã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ãã¡ã
ãã·ã«ã«ããã«åºããšããã·ã«ã«ããã«åºããã³
ãžã«ãªãã·ã«ã«ããã«åºãªã©ïŒã眮æè¥ããã¯é
眮æã®ã¢ãªãŒã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ãã
ãšããã·ã«ã«ããã«åºãã¡ãã«ããšããã·ã«ã«ã
ãã«åºããšãã«ããšããã·ã«ã«ããã«åºãªã©ïŒã
ã«ã«ãã¢ã€ã«åºïŒäŸãã°ãã¡ãã«ã«ã«ãã¢ã€ã«
åºããžããã«ã«ã«ãã¢ã€ã«åºããªã¯ã¿ãã·ã«ã«ã«
ãã¢ã€ã«åºãããšãã«ã«ã«ãã¢ã€ã«åºãªã©ïŒãŸã
ã¯ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ãã¡ãã«ã¹ã«ãã¢ã¢
ã€ã«åºããªã¯ã¿ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãªã©ïŒã
瀺ããäœããR3ãR4ãR5ããã³R6ãåæã«æ°ŽçŽ
ååã§ããæãR1ãšR2ã¯åæã«æ°ŽçŽ ååã§ãã
ããšã¯ãªãããŸããR2ãšR4ã§çœ®æè¥ããã¯ïŒå¡
ãŸãã¯ïŒå¡ç°ã圢æããŠãããã äžè¬åŒãã åŒäžãR7ããã³R8ã¯ã¢ã«ãã«åºïŒäŸãã°ããš
ãã«åºãïœâããã«åºãïœâããã«åºãïœâã¢ã
ã«åºãïœâããã·ã«åºãïŒâãšãã«ããã·ã«åºã
ïœâããã«åºãªã©ïŒããR9ã¯ã¢ã«ãã«åºïŒäŸã
ã°ããšãã«åºãïœâããã«åºãïœâãããã«åºã
ïœâã¢ãã«åºãïœâããã·ã«åºãïŒâãšãã«ãã
ã·ã«åºãªã©ïŒãŸãã¯çœ®æè¥ããã¯é眮æã®ã¢ãªãŒ
ã«åºïŒäŸãã°ãããšãã«åºãïŒïŒïŒâãžâïœâã
ãã«ããšãã«åºãªã©ïŒã瀺ããäœããR7ãR8ã
ãã³R9ã®ïŒã€ã®æ®åºã«å«ãŸããççŽ æ°ã®åã14
ãã30ãŸã§ã§ããã åèšäžè¬åŒã§ç€ºãããååç©ã®å ·äœäŸãäžèšã«
瀺ãã åèšäžè¬åŒããã§ç€ºãããååç©ã®å ·äœäŸã
äžèšã«ç€ºãã ååç©äŸ ïŒâïŒïŒ ãªã³é žãžãšãã«ããã·ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžããã«ããã·ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žããªâïœâã¢ãã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã«âïŒïŒâãšã
ã«ããã·ã«ïŒã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã·ã«âïœâã¢ã
ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žããªâïœâããã·ã«ã»ãšã¹ã
ã« ïŒâïŒïŒ ãªã³é žãžâïœâããã«âïœâãªã¯ã
ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžãšãã«ã»ïŒïŒïŒïŒïŒâãžâ
ïœâããã«ããšãã«ïŒã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã·ã«ã»ããšã
ã«ã»ãšã¹ãã« ïŒâ10ïŒ ãªã³é žãžâïœâããã·ã«ã»ãªã«ãã¯
ã¬ãžã«ã»ãšã¹ãã« ïŒâ11ïŒ ãªã³é žãã¹âïŒïŒâãšãã«ããã·ã«ïŒ
âïœâããã«ã»ãšã¹ãã« ïŒâ12ïŒ ãªã³é žããªâïœâããã«ã»ãšã¹ãã« ïŒâ13ïŒ ãªã³é žããªïŒïŒâãšãã«ããã·
ã«ïŒã»ãšã¹ãã« ïŒâ14ïŒ ãªã³é žãžâïœâããã«ã»ïŒïŒâïœâ
ãã³ã¿ãã·ã«ããšãã«ïŒã»ãšã¹ãã« ïŒâ15ïŒ ãªã³é žãžâïœâããã·ã«ã»ïŒïŒâïœ
âããã«ããšãã«ïŒã»ãšã¹ãã« ïŒâ16ïŒ ãªã³é žããªãã·ã«ã»ãšã¹ãã« ïŒâ17ïŒ ãªã³é žããªããã·ã«ã»ãšã¹ãã« äžè¬ã«ãæ··è²ã¯ã«ã©ãŒçŸåã®éãæªåå¿ã®çŸå
äž»è¬é žåäœãä»å±€ãžæ¡æ£ããããšã«ããçããã
ã®ãšèããããŠããããæ¬çºæã¯ãããæ··è²ãæ
å¹ã«é²æ¢ããããšãã§ãããããè²ã«ããªã®çºç
ããæå¹ã«é²æ¢ããããšãã§ãããä»äžã€ã®ç¹åŸŽ
ãšããŠã¯ããã€ããããã³èªå°äœãå«ãæ°Žäžæ²¹æ»Ž
ååæ£åãåæ¥éã®çµæä¿åã«ãããŠæ¥µããŠå®å®
ããŠããããšã§ããã æ¬çºæã«ä¿ãåèšäžè¬åŒããããã³ããã§
瀺ãããååç©ã®äœ¿çšåçãšããŠã¯ãåè ïŒéš
ïŒééïŒã«å¯ŸããŠåŸè 0.1ã10éšïŒééïŒã§ãã
ãã奜ãŸããã¯ïŒãïŒéšïŒééïŒã§ããã æ¬çºæã«ä¿ãæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ã調補
ããã«éããŠã沞ç¹175â以äžã®å ¬ç¥ã®é«æ²žç¹æº¶
åªãåæ£ç©ã®å®å®æ§ãæããªãç¯å²ã§æ··å ¥ããã
ããšãå¯èœã§ãããå ¬ç¥ã®é«æ²žç¹æº¶åªã®äŸãšããŠ
ã¯ããã¿ãŒã«é žãžãšãã«ããã¿ãŒã«é žãžããã«ã
ãã¿ãŒã«é žãžãããã«ããã¿ãŒã«é žã€ãœãªã¯ãã«
ã®åŠããã¿ãŒã«é žãšã¹ãã«é¡ãã¢ãžãã³é žãžãšã
ã«ãã¢ãžãã³é žãžããã«ã®åŠãã¢ãžãã³é žãšã¹ã
ã«é¡ãã¯ãšã³é žã¡ãã«ãã¯ãšã³é žããã«ã®åŠãã¯
ãšã³é žãšã¹ãã«é¡ãã¢ãŒã¬ã³é žãžãšãã«ãã¢ãŒã¬
ã³é žã€ãœãªã¯ãã«ã®åŠãã¢ãŒã¬ã³é žãšã¹ãã«é¡ã
ã©ãŠãªã³é žãšãã«ãã©ãŠãªã³é žããã«ã®åŠãã©ãŠ
ãªã³é žãšã¹ãã«é¡ãã»ããã³é žãšãã«ã®åŠãã»ã
ãã³é žãšã¹ãã«é¡ãã«ããªã³é žãšãã«ã®åŠãã«ã
ãªã³é žãšãã«ãã¢ã»ãã³ãã¯é žãšãã«ã®åŠãã³ã
ã¯é žãšã¹ãã«é¡ããã®ä»ãµãªãã«é žãšã¹ãã«é¡ã
ããªã¹ãã³é žãšã¹ãã«é¡ãããšãã«é ¢é žãšã¹ãã«
é¡ãé ç³é žãšã¹ãã«é¡ãçªé žãšã¹ãã«é¡ãé«çŽã¢
ã«ã³ãŒã«é¡ãªã©ãæããããšãã§ããããŸããå
æ£ç©ã調補ããéã«ã¯åæ£å©å€ãšããŠã¢ããªã³ç³»
çé¢æŽ»æ§å€ãéã€ãªã³ç³»çé¢æŽ»æ§å€ãåç¬ãŸãã¯
çµåããŠå©çšããããšãã§ããã代衚çãªçé¢æŽ»
æ§å€ãšããŠã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é žå¡©ã
ã¢ã«ãã«ç¡«é žãšã¹ãã«å¡©é¡ãã¢ã«ãã«ã¹ã«ãã³ã
ã¯é žå¡©ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«
é¡ããœã«ãã¿ã³èèªé žãšã¹ãã«é¡ãããªãªãã·ãš
ãã¬ã³ãœã«ãã¿ã³èèªé žãšã¹ãã«é¡ãªã©ãæãã
ããã æ¬çºæã«ä¿ãåæ£ç©ã®ä»£è¡šçãªèª¿è£œæ³ã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬2360290å·ãå第2728659å·åå ¬å ±ãª
ã©ã«èšèŒã®æ¹æ³ãçšããããšãã§ãããŸãç±³åœç¹
蚱第3573050å·å ¬å ±ãªã©ã«èšèŒãããŠããããã«
ã¢ã»ãã³ããšã¿ããŒã«ãã¡ãã«ã¢ã»ããŒãããšã
ã«ã¢ã»ããŒããããã«ã¢ã»ããŒãã®åŠãäœæ²žç¹æº¶
åªãè£å©æº¶åªãšããŠçµåããŠçšããããšãã§ã
ãã ãŸããæ¬çºæã«ä¿ãåæ£ç©ã調補ããéã«é©çš
ããã芪氎æ§ã³ãã€ããšããŠã¯ãéåžžã®ã¢ã«ã«ãª
åŠçãŒã©ãã³ãé žåŠçãŒã©ãã³ã®ä»ã«ãã¿ãŒã«å
ãŒã©ãã³ã®åŠãå€æ§ãŒã©ãã³ããŸãã«ãŒã€ã³ãã»
ã«ããŒãºèªå°äœãªã©ã®å€©ç¶ç©ããã®å å·¥åããã
ã«ã¯ããªããã«ã¢ã«ã³ãŒã«ãããªããã«ãããªã
ã³ãããªã¢ã¯ãªã«ã¢ãã€ãã®åŠãåæãã€ã³ããŒ
ãåç¬ãŸãã¯çµåããŠäœ¿çšã§ããã æ¬çºæã«ä¿ãã«ã©ãŒåçæå ææã«çšããããš
ã®ã§ããã€ãšããŒã«ãã©ãŒãšããŠã¯ãã³ãŸã€ã«ã¢
ã»ãã¢ããªãåããããªã«ã¢ã»ãã¢ããªãåããž
ãã³ãŸã€ã«ã¡ã¿ã³åæãã¯ã«ãããªã³äœã®ççŽ å
åãã«ãããªã³åå¿æã«é¢è±ããããšãã§ãã眮
æåºã§çœ®æãããŠããïŒåœéåã«ãã©ãŒããããŒ
ã³ã¿ã«ãã©ãŒãšããŠã¯ïŒâãã©ãŸãã³ç³»ããã©ãŸ
ããªã¢ãŸãŒã«ç³»ããã©ãŸãªããã³ãã€ãããŸãŒã«
ç³»ãã€ã³ããŸãã³ç³»ãã·ã¢ãã¢ã»ãã«ç³»æãã¯ã«
ãããªã³äœã®ççŽ ååãã«ãããªã³ã°åå¿æã«é¢
è±ããããšãã§ãã眮æåºã§çœ®æãããŠããïŒåœ
éåã«ãã©ãŒãããŸãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ã
ãšããŒã«ç³»ãããããŒã«ç³»æãã¯ã«ãããªã³äœã®
ççŽ ååãã«ãããªã³ã°åå¿æã«é¢è±ããããšã
ã§ãã眮æåºã§çœ®æãããŠããïŒåœéåã«ãã©ãŒ
ãæããããšãã§ããã æ¬çºæã«ä¿ãã«ã©ãŒåçæå ææã«çšãã代衚
çãªã€ãšããŒã«ãã©ãŒã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3046129å·ãå第3277155å·ãå第3408194å·ãå
第3447928å·ã西ç¬å ¬éç¹èš±å ¬å ±ç¬¬2057941å·ãç¹
éæ47â26133å·ãå48â29432å·ãå第48â
66834å·ãå第66835å·ãå48â94432å·ãå49â
1229å·ãå49â10736å·åå ¬å ±ãªã©ã«èšèŒãããŠ
ãããããŒã³ã¿ãŒã«ãã©ãŒã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3684514å·ãè±åœç¹èš±ç¬¬1183515å·ãç¹å ¬æ40â
6031å·ãå40â6035å·ãå44â15754å·ãç¹éæ
49â29639å·ãå49â53437å·ãå49â117034å·ã
å49â123033å·ãå50â108925å·ãå50â159334
å·åå ¬å ±ãªã©ãã·ã¢ã³ã«ãã©ãŒã¯ããäŸãã°ç±³åœ
ç¹èš±ç¬¬2423730å·ãå第2801171ãç¹å ¬æ49â
16056å·åå ¬å ±ãªã©ã«èšèŒãããŠããã æ¬çºæã®å®æœã«éããŠçšããããããã²ã³åé
ä¹³å€ã¯ãæå ææã®ç®çã«å¿ããŠåŸæ¥å ¬ç¥ã®åçš®
ã®ä¹³å€ããéžæããããšãã§ãããäŸãã°ãå¡©å
éãå¡©èåéãèåéãå¡©èæ²åéãªã©ãæãã
ãããããã®ä¹³å€ã¯ç¡«é»å¢ææ³ãéå å¢ææ³ãé
å¢ææ³ãªã©ã®å ¬ç¥ã®ååŠå¢ææ³ãé©çšããŠãã
ãããŸãããããã®ä¹³å€ã«ã¯ç®çã«å¿ããŠããžãŠ
ã ãã€ãªãžãŠã ãã¿ãªãŠã ããªããŠã ãã«ãããŠ
ã ãäºéãéãªã©ã®éå±ã€ãªã³ãå«æããŠããŠã
ããããŸãããªå°¿çŽ é¡ãããªãžãŠã å¡©ãããªã¢ãŸ
ãŒã«é¡ãããã©ãŸãŒã«é¡ãã€ãããŸãŒã«é¡ãæ žé ž
ãªã©ã®åŠãæ¶ç調æŽå€ãå«æããŠããŠãããã ãŸããæ¬çºæã§çšããããã²ã³åéåçä¹³å€ã«
ã¯ããæ¥æ¬åçåŠäŒèªã25ãP34ã40ãP113ã117
ïŒ1960ïŒããããªãã°ã©ãã€ãã¯ãµã€ãšã³ã¹ ã¢
ã³ã ãšã³ãžãã¢ãªã³ã°ãïŒãP268ã271ïŒ1959ïŒ
ã«ç€ºãããŠãããããªã«ããªé²æ¢å€ãå®å®å€ãçš
ããããŠãããããŸãã芪氎æ§ã³ãã€ãå±€ã¯åçš®
ã®æ¶æ©å€ã«ãã€ãŠç¡¬åãããããšãã§ãããå ·äœ
çãªç¡¬åå€ãšããŠã¯ãããã«ã¹ã«ãã³é žããšãã¬
ã³ã€ãã³åã掻æ§ããã²ã³ãæããããªã¢ãžã³
åããã«ã ã¢ã«ããããã°ãªãªãã¶ãŒã«ãã ã³ã¯
ãã«é žãªã©ãåç¬æãã¯çµåããŠçšããããšãã§
ããããã®ä»ã玫å€ç·åžåå€ãå¯å¡å€ãåªæå€ã
垯é»é²æ¢å€ãã€ã©ãžãšãŒã·ãšã³é²æ¢å€ããã¬ãŒã·
ãšã³é²æ¢å€ãæé žåå€ãªã©ãå«æããããšãã§ã
ãã æ¬çºæã®ã«ã©ãŒåçæå ææã«çšããããéæ
æ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§ä¹³å€ã¯ãããã
ãææã®æå æ³¢é·æã«æå æ§ãä»äžããããã«ã
é©åœãªå¢æè²çŽ ãçšããŠå åŠå¢æããããå¢æè²
çŽ ãšããŠã¯çš®ã ã®ãã®ãçšããããšãã§ãããŸã
ããããå¢æè²çŽ ãïŒçš®æãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããéææ§ä¹³å€ã«çšãããå¢æ
è²çŽ ãšããŠã¯ãè±åœç¹èš±ç¬¬424599å·ãç±³åœç¹èš±ç¬¬
2108485å·ãç¹éæ51â80224å·åå ¬å ±ãªã©ã«èšèŒ
ã®ãã®ãæããããšãã§ããç·ææ§ä¹³å€ã«çšãã
ãå¢æè²çŽ ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬1939201
å·ãå第2072908å·ãå第2739149å·ãå第
2945763å·ãè±åœç¹èš±ç¬¬505079å·åå ¬å ±ãªã©ã«èš
èŒã®ãã®ãæããããšãã§ãããŸãèµ€ææ§ä¹³å€ã«
çšãããå¢æè²çŽ ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
2269234å·ãå第2270378å·ãå第2442710å·ãå
第2454629å·ãå第2776280å·åå ¬å ±ãªã©ã«èšèŒã®
ãã®ãæããããšãã§ããã æ¬çºæã®ã«ã©ãŒåçæå ææã®æ¯æäœãšããŠ
ã¯ãåçš®ã®æ¯æäœãçšãããããäŸãã°ãç¡é žã»
ã«ããŒã¹ãã€ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«
ã ãããªã¹ãã¬ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã ã®
åŠããã€ã«ã é¡ããã©ã€ã¿çŽãαâããªãªã¬ãã€
ã³ããªããŒç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ã
ãšãã¬ã³ããã³ã³ããªããŒãªã©ã§è¢«èŠãããŠãã
ãã©ã€ã¿çŽãã¬ã©ã¹é¡ãªã©ãçšããããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯ãé²å åŸãè³éŠ
æ第ïŒçŽã¢ãã³ç³»çŸåè¬ç¹ã«ïŒ°âããšãã¬ã³ãžã¢
ãã³ç³»ã«ã©ãŒçŸåè¬ãå«ãçŸå液ã§ã«ã©ãŒçŸåã
ãããã®åŸè±éåŠçãããŠéæ¡æ£æ§è²çŽ åã®ã¿ã
圢æããã代衚çãªçŸåè¬ã®äŸãšããŠïŒâã¢ãã
âïŒâãšããã·âïŒïŒ®âãžãšãã«ã¢ããªã³ãïŒ
âã¢ããâïŒïŒïŒâãžã¡ãã«âïŒïŒ®âãžãšãã«
ã¢ããªã³ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«
ââïŒÎ²âããããã·ãšãã«ïŒã¢ããªã³ãïŒâ
ã¢ããâïŒâã¡ãã«âïŒïŒ®âãžãšãã«ã¢ããª
ã³ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢ããªã³ãª
ã©ãæããããšãã§ãããã«ã©ãŒçŸå液ã¯ããã®
ä»éåžžçšããããæ·»å å€ãäŸãã°ã¢ã«ã«ãªéå±ã®
äºç¡«é žå¡©ãçé žå¡©ãéäºç¡«é žå¡©ãèåç©ãæ²å
ç©ããã³ãžã«ã¢ã«ã³ãŒã«ãªã©ãå«ãããšãã§ã
ããæŒçœæ¶²ã¯èµ€è¡å¡©ãéã¯ãã é žå¡©ããšãã¬ã³ãž
ã¢ãã³ããã©é ¢é žéïŒïŒé¯é žãªã©ã®å ¬ç¥ã®æŒçœ
å€ãç·ãŠçšããããšãã§ãããããã«æŒçœå·¥çšãš
å®çå·¥çšãšãäžæµŽã§è¡ãªãããšãã§ããããã®æ§
ãªæŒçœå®ç液ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3582322å·å ¬
å ±ãªã©ã«èšèŒãããŠããã 以äžãæ¬çºæãå ·äœçã«èª¬æããããã«å®æœäŸ
ãæããŠè©³è¿°ããã å®æœäŸ ïŒ 0.5ïœã®åèšäŸç€ºååç©ïŒâïŒïŒããããã
ãžããã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒã
ããã³åèšäŸç€ºååç©ïŒâïŒïŒã®ãªã³é žãžâïœ
âããã«âïœâãªã¯ãã«ã»ãšã¹ãã«ã«æ·»å ããŠã
ãå ç±æº¶è§£ãããã®åŸããããã®æº¶æ¶²ã15âã§ïŒ
æéãïŒæéããã³24æéæŸçœ®ãããã®æã®æåº
ç¶æ ã芳å¯ããããããã®çµæãäžèšç¬¬ïŒè¡šã«ç€º
ãã
ã«ã©ãŒçŸåã®éã«çããè²ã«ããªããã³æ··è²ãé²
æ¢ãããå®å®ãªãã€ããããã³èªå°äœã®ä¹³ååæ£
ç©ãå«ãã«ã©ãŒåçæå ææã«é¢ãããã®ã§ã
ãã ã«ã©ãŒåçæå ææã«ãããŠãè³éŠæ第äžçŽã¢
ãã³ååç©ãçšããŠãé²å ãããããã²ã³åéç²
åãçŸåããçæããè³éŠæ第äžçŽã¢ãã³ååç©
ã®é žåçæç©ãšã«ãã©ãŒãšã®åå¿ã«ããè²çŽ åã
圢æããããããšãç¥ãããŠããã ãã®æ¹æ³ã«ãããŠã¯ãéåžžã·ã¢ã³ãããŒã³ã¿ã
ã€ãšããŒã®è²çŽ ç»åã圢æããããã«ããããã
ããšããŒã«ãŸãã¯ããããŒã«ç³»ã«ãã©ãŒïŒïŒâã
ã©ãŸãã³ããã©ãŸãªããã³ãã€ãããŸãŒã«ããã©
ãŸãããªã¢ãŸãŒã«ãã€ã³ããŸãã³ãŸãã¯ã·ã¢ãã¢
ã»ãã«ç³»ã«ãã©ãŒïŒã¢ã·ã«ã¢ã»ãã¢ãããŸãã¯ãž
ãã³ãŸã€ã«ã¡ã¿ã³ç³»ã«ãã©ãŒãçšããããŠããã
ãããã®ã«ãã©ãŒã¯ããã²ã³åéä¹³å€å±€äžã«æ·»å
ããæ¹æ³ãšçŸå液äžã«æ·»å ããæ¹æ³ãšãç¥ãããŠ
ããã ãããã®æ¹æ³ã§ã«ã©ãŒåçæå ææãã«ã©ãŒçŸ
åããéã«ã¯ãè²ã«ããªããã³æ··è²ãšããæãŸã
ããªãçŸè±¡ãæ¹ãèµ·ãããŠãããåŸæ¥æ³ã§ã¯ãã
ããè²ã«ããªããã³æ··è²ãé²æ¢ããããã«ãã€ã
ãããã³ç³»ååç©ãã«ã©ãŒåçæå ææã®æ§æå±€
ã®äœããã®å±€äžã«å«æãããŠãããäŸãã°ãç±³åœ
ç¹èš±ç¬¬2336327å·ãå第2360290å·ãå第2384658
å·ãå第2675531å·ãå第2728659å·ãå第
2732300å·ãå第3700453å·åå ¬å ±ãªã©ã«èšèŒãã
ãŠããã ãããããããŸã§ã®æ¹æ³ã§ã¯è²ã«ããªããã³æ··
è²é²æ¢ã«é©çšããããã€ããããã³èªå°äœãå«æ
ããæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ãå®å®ã§ãªããç¹
ã«æ°åæ¥éã®çµæä¿åã§ã¯çµæ¶ã®æåºãçããã
æãã¯åŸ®çŽ°ãªç¶æ ã§æ²¹æ»Žãååšããªããªã€ããã
ãããšãå€ãããã®ãããã€ããããã³èªå°äœã®
è²ã«ããªããã³æ··è²ã«å¯Ÿããååãªå¹æãçºæ®ã
ãããããšãã§ããªãããšãããããããã®æ¬ ç¹
ãæ¹è¯ããããã«ããããŸã§ããã€ãã®æ¹æ³ãæ
æ¡ãããŠãããããããã®æ¹æ³ã§ã¯äžèšæ¬ ç¹ãæ¹
è¯ããã«ã¯ååãªæ¹æ³ãšã¯èšããªããäŸãã°ãã
ã€ããããã³èªå°äœãäºçš®ä»¥äžäœµçšããããšã«ã
ã€ãŠæåºãé²æ¢ããæ¹æ³ãææ¡ãããŠããããå
åãªãã®ã§ã¯ãªãããŸãé«æ²žç¹ææ©æº¶åªã®äœ¿çšé
ãå¢å€§ãããããšã«ããå®å®ãªæ°Žäžæ²¹æ»Žåã³ãã€
ãåæ£ç©ã調補ããæ¹æ³ãç¥ãããŠãããããã
ããŸãååãªãã®ãšã¯èšããªãã æ¬çºæã®ç®çã¯ããã€ããããã³èªå°äœãå«æ
ããå®å®ãªæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ãæäŸãã
ããšã«ããã æ¬çºæã®å¥ã®ç®çã¯ãã«ã©ãŒçŸåã®éã«çãã
è²ã«ããªããã³æ··è²ãæå¹ã«é²æ¢ããã«ã©ãŒåç
æå ææãæäŸããããšã«ããã æ¬çºæã®ãããç®çã¯ãäžèšäžè¬åŒããã§ç€º
ããããã€ããããã³èªå°äœãäžèšäžè¬åŒãã
ã§ç€ºãããé«æ²žç¹ææ©æº¶åªãçšããŠæº¶è§£ããŠåŸã
ãã溶液ã芪氎æ§ã³ãã€ã液äžã«ä¹³åãããããš
ã«ãã圢æãããæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£æ¶²ã調
補ãããããã³ãã€ãåæ£æ¶²ãã«ã©ãŒåçæå æ
æã®æ§æå±€ã®å°ãªããšãïŒå±€ã«é©çšããããšã«ã
ãéæãããã äžè¬åŒãã åŒäžãR1ããã³R2ã¯ãæ°ŽçŽ ååã眮æè¥ãã
ã¯é眮æã®ã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«åºããšã
ã«åºãïœâãããã«åºãïœâãããã«åºãïœâã
ãã«åºãïœâããã«åºãïœâã¢ãã«åºãïœâã¢ã
ã«åºãïœâãªã¯ãã«åºãïœâããã·ã«åºãïœâãª
ã¯ã¿ãã·ã«åºãªã©ã§ç¹ã«ççŽ æ°ïŒã32ã®ã¢ã«ãã«
åºã奜ãŸããããã®ä»ã«ïŒâã¡ããã·ãšãã«åºã
ïŒâããšãã«ãšãã«åºããã³ãžã«åºãïŒâã·ã¢ã
ãããã«åºãªã©ãæããããšãã§ãããïŒã眮æè¥
ããã¯é眮æã®ã¢ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«
åºããªã¯ããã«åºããªã¬ã€ã«åºãªã©ã§ççŽ æ°ïŒã
32ã®ã¢ã«ã±ãã«åºã奜ãŸãããïŒã眮æè¥ããã¯é
眮æã®ã¢ãªãŒã«åºïŒäŸãã°ãããšãã«åºãããªã«
åºãïŒâïœâããã«ããšãã«åºããããã«åºãª
ã©ïŒã眮æè¥ããã¯é眮æã®ã¢ã·ã«åºïŒäŸãã°ã
ã¢ã»ãã«åºããªã¯ã¿ãã€ã«åºãªã©ïŒã眮æè¥ãã
ã¯é眮æã®ã·ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã·ã¯ãã
ãã·ã«åºãã·ã¯ããã³ãã«åºãªã©ïŒãŸãã¯çœ®æè¥
ããã¯é眮æã®å«çªçŽ è€çŽ ç°ïŒäŸãã°ãã€ãããŸ
ãªã«åºãããªã«åºãããªãžã«åºãããªã¢ãžãã«
åºããã¢ãŸãªã«åºãïŒïŒïŒâãžâããã·ã«âïŒâ
ãããã·ããšããã·ïŒâïŒïŒïŒïŒïŒâããªã¢ãžã
ã«åºãªã©ïŒã瀺ãã R3ãR4ãR5ããã³R6ã¯ãæ°ŽçŽ ååãããã²ã³
ååïŒäŸãã°ãå¡©çŽ ååãèçŽ ååãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«
åºããšãã«åºãïœâãããã«åºãïœâãããã«
åºãïœâããã«åºãïœâããã«åºãïœâãªã¯ãã«
åºãïœâããã·ã«åºãªã©ã§ãç¹ã«ççŽ æ°ïŒã32ã®
ã¢ã«ãã«åºã奜ãŸããããã®ä»ã«ããã³ãžã«åºã
ã¢ã«ã³ãã·ã¢ã«ãã«åºãïŒâããšãã«ãšãã«åºã
ïŒâããããã·âïŒâã¡ãã«ãšãã«åºãïŒïŒïŒïŒ
âãžâããããã·âïŒâïœâããã«ïŒãã³ãžã«åº
ãªã©ãæããããšãã§ãããïŒçœ®æè¥ããã¯é眮
æã®ã¢ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«åºããªã¯ãã
ã«åºãªã©ã§ç¹ã«ççŽ æ°ïŒã32ã®ã¢ã«ã±ãã«åºã奜
ãŸãããïŒã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«åºïŒäŸ
ãã°ãããšãã«åºãããªã«åºããããã«åºãã¡ã
ãã·ããšãã«åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã·
ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã·ã¯ãããã·ã«åºãã·
ã¯ããã³ãã«åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã¢
ã«ã³ãã·åºïŒäŸãã°ãã¡ããã·åºããããã·åºã
ããã·ã«ãªãã·åºããšããã·ã¡ããã·åºãããšã
ãã·ã¡ããã·åºãªã©ïŒã眮æè¥ããã¯é眮æã®ã¢
ã«ãã«ããªåºïŒäŸãã°ãã¡ãã«ããªåºãïœâãã
ã«ããªåºãïœâããã·ã«ããªåºãªã©ïŒã眮æè¥ã
ãã¯é眮æã®ã¢ãªãŒã«ããªåºïŒäŸãã°ãããšãã«
ããªåºãã¡ãã«ããšãã«ããªåºããžã¡ãã«ããšã
ã«ããªåºãªã©ïŒã眮æè¥ããã¯é眮æã®å«çªçŽ è€
çŽ ç°ããªåºïŒäŸãã°ãå«çªçŽ è€çŽ ç°ãšããŠã¯ãã
ã©ãŸãªã«åºããã¢ãŸãªã«åºãªã©ã奜ãŸãããïŒã眮
æè¥ããã¯é眮æã®ã¢ãªãŒã«ãªãã·åºïŒäŸãã°ã
ããšããã·åºãã¡ãã«ããšããã·åºãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã·ã«åºïŒäŸãã°ãã¢ã»ãã«
åºããªã¯ã¿ãã€ã«åºãã©ãŠãã€ã«åºãªã©ïŒã眮æ
è¥ããã¯é眮æã®ã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»
ãã«ã¢ããåºããªã¯ã¿ãã€ã«ã¢ããåºãã©ãŠãã€
ã«ã¢ããåºããã³ãŸã€ã«ã¢ããåºãªã©ïŒã眮æè¥
ããã¯é眮æã®ã¢ã«ãã«ã¢ããåºïŒäŸãã°ãã¡ã
ã«ã¢ããåºããžãšãã«ã¢ããåºãïœâãªã¯ãã«ã¢
ããåºããžãã·ã«ã¢ããåºãªã©ïŒã眮æè¥ããã¯
é眮æã®ã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ãã¡ã
ãã·ã«ã«ããã«åºããšããã·ã«ã«ããã«åºããã³
ãžã«ãªãã·ã«ã«ããã«åºãªã©ïŒã眮æè¥ããã¯é
眮æã®ã¢ãªãŒã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ãã
ãšããã·ã«ã«ããã«åºãã¡ãã«ããšããã·ã«ã«ã
ãã«åºããšãã«ããšããã·ã«ã«ããã«åºãªã©ïŒã
ã«ã«ãã¢ã€ã«åºïŒäŸãã°ãã¡ãã«ã«ã«ãã¢ã€ã«
åºããžããã«ã«ã«ãã¢ã€ã«åºããªã¯ã¿ãã·ã«ã«ã«
ãã¢ã€ã«åºãããšãã«ã«ã«ãã¢ã€ã«åºãªã©ïŒãŸã
ã¯ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ãã¡ãã«ã¹ã«ãã¢ã¢
ã€ã«åºããªã¯ã¿ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãªã©ïŒã
瀺ããäœããR3ãR4ãR5ããã³R6ãåæã«æ°ŽçŽ
ååã§ããæãR1ãšR2ã¯åæã«æ°ŽçŽ ååã§ãã
ããšã¯ãªãããŸããR2ãšR4ã§çœ®æè¥ããã¯ïŒå¡
ãŸãã¯ïŒå¡ç°ã圢æããŠãããã äžè¬åŒãã åŒäžãR7ããã³R8ã¯ã¢ã«ãã«åºïŒäŸãã°ããš
ãã«åºãïœâããã«åºãïœâããã«åºãïœâã¢ã
ã«åºãïœâããã·ã«åºãïŒâãšãã«ããã·ã«åºã
ïœâããã«åºãªã©ïŒããR9ã¯ã¢ã«ãã«åºïŒäŸã
ã°ããšãã«åºãïœâããã«åºãïœâãããã«åºã
ïœâã¢ãã«åºãïœâããã·ã«åºãïŒâãšãã«ãã
ã·ã«åºãªã©ïŒãŸãã¯çœ®æè¥ããã¯é眮æã®ã¢ãªãŒ
ã«åºïŒäŸãã°ãããšãã«åºãïŒïŒïŒâãžâïœâã
ãã«ããšãã«åºãªã©ïŒã瀺ããäœããR7ãR8ã
ãã³R9ã®ïŒã€ã®æ®åºã«å«ãŸããççŽ æ°ã®åã14
ãã30ãŸã§ã§ããã åèšäžè¬åŒã§ç€ºãããååç©ã®å ·äœäŸãäžèšã«
瀺ãã åèšäžè¬åŒããã§ç€ºãããååç©ã®å ·äœäŸã
äžèšã«ç€ºãã ååç©äŸ ïŒâïŒïŒ ãªã³é žãžãšãã«ããã·ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžããã«ããã·ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žããªâïœâã¢ãã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã«âïŒïŒâãšã
ã«ããã·ã«ïŒã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã·ã«âïœâã¢ã
ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žããªâïœâããã·ã«ã»ãšã¹ã
ã« ïŒâïŒïŒ ãªã³é žãžâïœâããã«âïœâãªã¯ã
ã«ã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžãšãã«ã»ïŒïŒïŒïŒïŒâãžâ
ïœâããã«ããšãã«ïŒã»ãšã¹ãã« ïŒâïŒïŒ ãªã³é žãžâïœâããã·ã«ã»ããšã
ã«ã»ãšã¹ãã« ïŒâ10ïŒ ãªã³é žãžâïœâããã·ã«ã»ãªã«ãã¯
ã¬ãžã«ã»ãšã¹ãã« ïŒâ11ïŒ ãªã³é žãã¹âïŒïŒâãšãã«ããã·ã«ïŒ
âïœâããã«ã»ãšã¹ãã« ïŒâ12ïŒ ãªã³é žããªâïœâããã«ã»ãšã¹ãã« ïŒâ13ïŒ ãªã³é žããªïŒïŒâãšãã«ããã·
ã«ïŒã»ãšã¹ãã« ïŒâ14ïŒ ãªã³é žãžâïœâããã«ã»ïŒïŒâïœâ
ãã³ã¿ãã·ã«ããšãã«ïŒã»ãšã¹ãã« ïŒâ15ïŒ ãªã³é žãžâïœâããã·ã«ã»ïŒïŒâïœ
âããã«ããšãã«ïŒã»ãšã¹ãã« ïŒâ16ïŒ ãªã³é žããªãã·ã«ã»ãšã¹ãã« ïŒâ17ïŒ ãªã³é žããªããã·ã«ã»ãšã¹ãã« äžè¬ã«ãæ··è²ã¯ã«ã©ãŒçŸåã®éãæªåå¿ã®çŸå
äž»è¬é žåäœãä»å±€ãžæ¡æ£ããããšã«ããçããã
ã®ãšèããããŠããããæ¬çºæã¯ãããæ··è²ãæ
å¹ã«é²æ¢ããããšãã§ãããããè²ã«ããªã®çºç
ããæå¹ã«é²æ¢ããããšãã§ãããä»äžã€ã®ç¹åŸŽ
ãšããŠã¯ããã€ããããã³èªå°äœãå«ãæ°Žäžæ²¹æ»Ž
ååæ£åãåæ¥éã®çµæä¿åã«ãããŠæ¥µããŠå®å®
ããŠããããšã§ããã æ¬çºæã«ä¿ãåèšäžè¬åŒããããã³ããã§
瀺ãããååç©ã®äœ¿çšåçãšããŠã¯ãåè ïŒéš
ïŒééïŒã«å¯ŸããŠåŸè 0.1ã10éšïŒééïŒã§ãã
ãã奜ãŸããã¯ïŒãïŒéšïŒééïŒã§ããã æ¬çºæã«ä¿ãæ°Žäžæ²¹æ»Žåã³ãã€ãåæ£ç©ã調補
ããã«éããŠã沞ç¹175â以äžã®å ¬ç¥ã®é«æ²žç¹æº¶
åªãåæ£ç©ã®å®å®æ§ãæããªãç¯å²ã§æ··å ¥ããã
ããšãå¯èœã§ãããå ¬ç¥ã®é«æ²žç¹æº¶åªã®äŸãšããŠ
ã¯ããã¿ãŒã«é žãžãšãã«ããã¿ãŒã«é žãžããã«ã
ãã¿ãŒã«é žãžãããã«ããã¿ãŒã«é žã€ãœãªã¯ãã«
ã®åŠããã¿ãŒã«é žãšã¹ãã«é¡ãã¢ãžãã³é žãžãšã
ã«ãã¢ãžãã³é žãžããã«ã®åŠãã¢ãžãã³é žãšã¹ã
ã«é¡ãã¯ãšã³é žã¡ãã«ãã¯ãšã³é žããã«ã®åŠãã¯
ãšã³é žãšã¹ãã«é¡ãã¢ãŒã¬ã³é žãžãšãã«ãã¢ãŒã¬
ã³é žã€ãœãªã¯ãã«ã®åŠãã¢ãŒã¬ã³é žãšã¹ãã«é¡ã
ã©ãŠãªã³é žãšãã«ãã©ãŠãªã³é žããã«ã®åŠãã©ãŠ
ãªã³é žãšã¹ãã«é¡ãã»ããã³é žãšãã«ã®åŠãã»ã
ãã³é žãšã¹ãã«é¡ãã«ããªã³é žãšãã«ã®åŠãã«ã
ãªã³é žãšãã«ãã¢ã»ãã³ãã¯é žãšãã«ã®åŠãã³ã
ã¯é žãšã¹ãã«é¡ããã®ä»ãµãªãã«é žãšã¹ãã«é¡ã
ããªã¹ãã³é žãšã¹ãã«é¡ãããšãã«é ¢é žãšã¹ãã«
é¡ãé ç³é žãšã¹ãã«é¡ãçªé žãšã¹ãã«é¡ãé«çŽã¢
ã«ã³ãŒã«é¡ãªã©ãæããããšãã§ããããŸããå
æ£ç©ã調補ããéã«ã¯åæ£å©å€ãšããŠã¢ããªã³ç³»
çé¢æŽ»æ§å€ãéã€ãªã³ç³»çé¢æŽ»æ§å€ãåç¬ãŸãã¯
çµåããŠå©çšããããšãã§ããã代衚çãªçé¢æŽ»
æ§å€ãšããŠã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é žå¡©ã
ã¢ã«ãã«ç¡«é žãšã¹ãã«å¡©é¡ãã¢ã«ãã«ã¹ã«ãã³ã
ã¯é žå¡©ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«
é¡ããœã«ãã¿ã³èèªé žãšã¹ãã«é¡ãããªãªãã·ãš
ãã¬ã³ãœã«ãã¿ã³èèªé žãšã¹ãã«é¡ãªã©ãæãã
ããã æ¬çºæã«ä¿ãåæ£ç©ã®ä»£è¡šçãªèª¿è£œæ³ã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬2360290å·ãå第2728659å·åå ¬å ±ãª
ã©ã«èšèŒã®æ¹æ³ãçšããããšãã§ãããŸãç±³åœç¹
蚱第3573050å·å ¬å ±ãªã©ã«èšèŒãããŠããããã«
ã¢ã»ãã³ããšã¿ããŒã«ãã¡ãã«ã¢ã»ããŒãããšã
ã«ã¢ã»ããŒããããã«ã¢ã»ããŒãã®åŠãäœæ²žç¹æº¶
åªãè£å©æº¶åªãšããŠçµåããŠçšããããšãã§ã
ãã ãŸããæ¬çºæã«ä¿ãåæ£ç©ã調補ããéã«é©çš
ããã芪氎æ§ã³ãã€ããšããŠã¯ãéåžžã®ã¢ã«ã«ãª
åŠçãŒã©ãã³ãé žåŠçãŒã©ãã³ã®ä»ã«ãã¿ãŒã«å
ãŒã©ãã³ã®åŠãå€æ§ãŒã©ãã³ããŸãã«ãŒã€ã³ãã»
ã«ããŒãºèªå°äœãªã©ã®å€©ç¶ç©ããã®å å·¥åããã
ã«ã¯ããªããã«ã¢ã«ã³ãŒã«ãããªããã«ãããªã
ã³ãããªã¢ã¯ãªã«ã¢ãã€ãã®åŠãåæãã€ã³ããŒ
ãåç¬ãŸãã¯çµåããŠäœ¿çšã§ããã æ¬çºæã«ä¿ãã«ã©ãŒåçæå ææã«çšããããš
ã®ã§ããã€ãšããŒã«ãã©ãŒãšããŠã¯ãã³ãŸã€ã«ã¢
ã»ãã¢ããªãåããããªã«ã¢ã»ãã¢ããªãåããž
ãã³ãŸã€ã«ã¡ã¿ã³åæãã¯ã«ãããªã³äœã®ççŽ å
åãã«ãããªã³åå¿æã«é¢è±ããããšãã§ãã眮
æåºã§çœ®æãããŠããïŒåœéåã«ãã©ãŒããããŒ
ã³ã¿ã«ãã©ãŒãšããŠã¯ïŒâãã©ãŸãã³ç³»ããã©ãŸ
ããªã¢ãŸãŒã«ç³»ããã©ãŸãªããã³ãã€ãããŸãŒã«
ç³»ãã€ã³ããŸãã³ç³»ãã·ã¢ãã¢ã»ãã«ç³»æãã¯ã«
ãããªã³äœã®ççŽ ååãã«ãããªã³ã°åå¿æã«é¢
è±ããããšãã§ãã眮æåºã§çœ®æãããŠããïŒåœ
éåã«ãã©ãŒãããŸãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ã
ãšããŒã«ç³»ãããããŒã«ç³»æãã¯ã«ãããªã³äœã®
ççŽ ååãã«ãããªã³ã°åå¿æã«é¢è±ããããšã
ã§ãã眮æåºã§çœ®æãããŠããïŒåœéåã«ãã©ãŒ
ãæããããšãã§ããã æ¬çºæã«ä¿ãã«ã©ãŒåçæå ææã«çšãã代衚
çãªã€ãšããŒã«ãã©ãŒã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3046129å·ãå第3277155å·ãå第3408194å·ãå
第3447928å·ã西ç¬å ¬éç¹èš±å ¬å ±ç¬¬2057941å·ãç¹
éæ47â26133å·ãå48â29432å·ãå第48â
66834å·ãå第66835å·ãå48â94432å·ãå49â
1229å·ãå49â10736å·åå ¬å ±ãªã©ã«èšèŒãããŠ
ãããããŒã³ã¿ãŒã«ãã©ãŒã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3684514å·ãè±åœç¹èš±ç¬¬1183515å·ãç¹å ¬æ40â
6031å·ãå40â6035å·ãå44â15754å·ãç¹éæ
49â29639å·ãå49â53437å·ãå49â117034å·ã
å49â123033å·ãå50â108925å·ãå50â159334
å·åå ¬å ±ãªã©ãã·ã¢ã³ã«ãã©ãŒã¯ããäŸãã°ç±³åœ
ç¹èš±ç¬¬2423730å·ãå第2801171ãç¹å ¬æ49â
16056å·åå ¬å ±ãªã©ã«èšèŒãããŠããã æ¬çºæã®å®æœã«éããŠçšããããããã²ã³åé
ä¹³å€ã¯ãæå ææã®ç®çã«å¿ããŠåŸæ¥å ¬ç¥ã®åçš®
ã®ä¹³å€ããéžæããããšãã§ãããäŸãã°ãå¡©å
éãå¡©èåéãèåéãå¡©èæ²åéãªã©ãæãã
ãããããã®ä¹³å€ã¯ç¡«é»å¢ææ³ãéå å¢ææ³ãé
å¢ææ³ãªã©ã®å ¬ç¥ã®ååŠå¢ææ³ãé©çšããŠãã
ãããŸãããããã®ä¹³å€ã«ã¯ç®çã«å¿ããŠããžãŠ
ã ãã€ãªãžãŠã ãã¿ãªãŠã ããªããŠã ãã«ãããŠ
ã ãäºéãéãªã©ã®éå±ã€ãªã³ãå«æããŠããŠã
ããããŸãããªå°¿çŽ é¡ãããªãžãŠã å¡©ãããªã¢ãŸ
ãŒã«é¡ãããã©ãŸãŒã«é¡ãã€ãããŸãŒã«é¡ãæ žé ž
ãªã©ã®åŠãæ¶ç調æŽå€ãå«æããŠããŠãããã ãŸããæ¬çºæã§çšããããã²ã³åéåçä¹³å€ã«
ã¯ããæ¥æ¬åçåŠäŒèªã25ãP34ã40ãP113ã117
ïŒ1960ïŒããããªãã°ã©ãã€ãã¯ãµã€ãšã³ã¹ ã¢
ã³ã ãšã³ãžãã¢ãªã³ã°ãïŒãP268ã271ïŒ1959ïŒ
ã«ç€ºãããŠãããããªã«ããªé²æ¢å€ãå®å®å€ãçš
ããããŠãããããŸãã芪氎æ§ã³ãã€ãå±€ã¯åçš®
ã®æ¶æ©å€ã«ãã€ãŠç¡¬åãããããšãã§ãããå ·äœ
çãªç¡¬åå€ãšããŠã¯ãããã«ã¹ã«ãã³é žããšãã¬
ã³ã€ãã³åã掻æ§ããã²ã³ãæããããªã¢ãžã³
åããã«ã ã¢ã«ããããã°ãªãªãã¶ãŒã«ãã ã³ã¯
ãã«é žãªã©ãåç¬æãã¯çµåããŠçšããããšãã§
ããããã®ä»ã玫å€ç·åžåå€ãå¯å¡å€ãåªæå€ã
垯é»é²æ¢å€ãã€ã©ãžãšãŒã·ãšã³é²æ¢å€ããã¬ãŒã·
ãšã³é²æ¢å€ãæé žåå€ãªã©ãå«æããããšãã§ã
ãã æ¬çºæã®ã«ã©ãŒåçæå ææã«çšããããéæ
æ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§ä¹³å€ã¯ãããã
ãææã®æå æ³¢é·æã«æå æ§ãä»äžããããã«ã
é©åœãªå¢æè²çŽ ãçšããŠå åŠå¢æããããå¢æè²
çŽ ãšããŠã¯çš®ã ã®ãã®ãçšããããšãã§ãããŸã
ããããå¢æè²çŽ ãïŒçš®æãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããéææ§ä¹³å€ã«çšãããå¢æ
è²çŽ ãšããŠã¯ãè±åœç¹èš±ç¬¬424599å·ãç±³åœç¹èš±ç¬¬
2108485å·ãç¹éæ51â80224å·åå ¬å ±ãªã©ã«èšèŒ
ã®ãã®ãæããããšãã§ããç·ææ§ä¹³å€ã«çšãã
ãå¢æè²çŽ ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬1939201
å·ãå第2072908å·ãå第2739149å·ãå第
2945763å·ãè±åœç¹èš±ç¬¬505079å·åå ¬å ±ãªã©ã«èš
èŒã®ãã®ãæããããšãã§ãããŸãèµ€ææ§ä¹³å€ã«
çšãããå¢æè²çŽ ãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
2269234å·ãå第2270378å·ãå第2442710å·ãå
第2454629å·ãå第2776280å·åå ¬å ±ãªã©ã«èšèŒã®
ãã®ãæããããšãã§ããã æ¬çºæã®ã«ã©ãŒåçæå ææã®æ¯æäœãšããŠ
ã¯ãåçš®ã®æ¯æäœãçšãããããäŸãã°ãç¡é žã»
ã«ããŒã¹ãã€ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«
ã ãããªã¹ãã¬ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã ã®
åŠããã€ã«ã é¡ããã©ã€ã¿çŽãαâããªãªã¬ãã€
ã³ããªããŒç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ã
ãšãã¬ã³ããã³ã³ããªããŒãªã©ã§è¢«èŠãããŠãã
ãã©ã€ã¿çŽãã¬ã©ã¹é¡ãªã©ãçšããããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯ãé²å åŸãè³éŠ
æ第ïŒçŽã¢ãã³ç³»çŸåè¬ç¹ã«ïŒ°âããšãã¬ã³ãžã¢
ãã³ç³»ã«ã©ãŒçŸåè¬ãå«ãçŸå液ã§ã«ã©ãŒçŸåã
ãããã®åŸè±éåŠçãããŠéæ¡æ£æ§è²çŽ åã®ã¿ã
圢æããã代衚çãªçŸåè¬ã®äŸãšããŠïŒâã¢ãã
âïŒâãšããã·âïŒïŒ®âãžãšãã«ã¢ããªã³ãïŒ
âã¢ããâïŒïŒïŒâãžã¡ãã«âïŒïŒ®âãžãšãã«
ã¢ããªã³ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«
ââïŒÎ²âããããã·ãšãã«ïŒã¢ããªã³ãïŒâ
ã¢ããâïŒâã¡ãã«âïŒïŒ®âãžãšãã«ã¢ããª
ã³ãïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢ããªã³ãª
ã©ãæããããšãã§ãããã«ã©ãŒçŸå液ã¯ããã®
ä»éåžžçšããããæ·»å å€ãäŸãã°ã¢ã«ã«ãªéå±ã®
äºç¡«é žå¡©ãçé žå¡©ãéäºç¡«é žå¡©ãèåç©ãæ²å
ç©ããã³ãžã«ã¢ã«ã³ãŒã«ãªã©ãå«ãããšãã§ã
ããæŒçœæ¶²ã¯èµ€è¡å¡©ãéã¯ãã é žå¡©ããšãã¬ã³ãž
ã¢ãã³ããã©é ¢é žéïŒïŒé¯é žãªã©ã®å ¬ç¥ã®æŒçœ
å€ãç·ãŠçšããããšãã§ãããããã«æŒçœå·¥çšãš
å®çå·¥çšãšãäžæµŽã§è¡ãªãããšãã§ããããã®æ§
ãªæŒçœå®ç液ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3582322å·å ¬
å ±ãªã©ã«èšèŒãããŠããã 以äžãæ¬çºæãå ·äœçã«èª¬æããããã«å®æœäŸ
ãæããŠè©³è¿°ããã å®æœäŸ ïŒ 0.5ïœã®åèšäŸç€ºååç©ïŒâïŒïŒããããã
ãžããã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒã
ããã³åèšäŸç€ºååç©ïŒâïŒïŒã®ãªã³é žãžâïœ
âããã«âïœâãªã¯ãã«ã»ãšã¹ãã«ã«æ·»å ããŠã
ãå ç±æº¶è§£ãããã®åŸããããã®æº¶æ¶²ã15âã§ïŒ
æéãïŒæéããã³24æéæŸçœ®ãããã®æã®æåº
ç¶æ ã芳å¯ããããããã®çµæãäžèšç¬¬ïŒè¡šã«ç€º
ãã
ãè¡šã
äžèšè¡šããå€ããšãããæ¬çºæè©ŠæïŒãã¹ãNo.
ïŒãïŒïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.ïŒãïŒïŒã«èŒ
ã¹ãçµæã«ããã溶液ã®å®å®æ§ãåªããŠããã å®æœäŸ ïŒ åèšå®æœäŸïŒã§çšããäŸç€ºååç©ïŒâïŒïŒã«
代ããŠãããããåèšäŸç€ºååç©ïŒâïŒïŒãïŒ
âïŒïŒãïŒâ21ïŒãïŒâ25ïŒããã³ïŒâ33ïŒã
䜿çšããå Žåã«ã€ããŠããå®æœäŸïŒãšåæ§ã®ãã¹
ããç¹°ãè¿ãããšãããå®æœäŸïŒãšåæ§ã®çµæã
åŸãããã å®æœäŸ ïŒ åèšäŸç€ºååç©ïŒâïŒïŒã0.5ïœã¥ã€ïŒçš®ç§€
éããããããã«ã€ããŠãžããã«ãã¿ã¬ãŒãïŒml
ãšãšãã«ã¢ã»ããŒãïŒmlãããªã¯ã¬ãžã«ãã¹ããš
ãŒãïŒmlãšãšãã«ã¢ã»ããŒãïŒmlããã³åèšäŸç€º
ååç©ïŒâïŒïŒïŒmlãšãšãã«ã¢ã»ããŒãïŒmlã®
æ··å溶åªã«æº¶è§£ããããããããããã®æº¶æ¶²ãïŒ
ïŒ ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãœãŒã氎溶液ãïŒ
c.c.å«ãïŒïŒ ãŒã©ãã³æ°Žæº¶æ¶²20mläžã«æ³šå ¥ããäºå
æ¹æã®åŸãè¶ é³æ³¢åæ£ãããŠæ°Žäžæ²¹æ»Žååæ£ç©ã
åŸããããã«ããããã®åæ£ç©äžã«å«æããŠãã
ãšãã«ã¢ã»ããŒãããšããã¬ãŒã¿ãŒã«ããé€å»ã
ãŠåè©Šæã調補ããã åè©Šæã15âã§24æéã168æéã360æéãã
ã³720æéçµæãããããããã®çµææ¡ä»¶äžã«ã
ããæåºç¶æ ãé¡åŸ®é¡ã«ãã€ãŠèŠ³å¯ãããããã
ã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ïŒãïŒïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.ïŒãïŒïŒã«èŒ
ã¹ãçµæã«ããã溶液ã®å®å®æ§ãåªããŠããã å®æœäŸ ïŒ åèšå®æœäŸïŒã§çšããäŸç€ºååç©ïŒâïŒïŒã«
代ããŠãããããåèšäŸç€ºååç©ïŒâïŒïŒãïŒ
âïŒïŒãïŒâ21ïŒãïŒâ25ïŒããã³ïŒâ33ïŒã
䜿çšããå Žåã«ã€ããŠããå®æœäŸïŒãšåæ§ã®ãã¹
ããç¹°ãè¿ãããšãããå®æœäŸïŒãšåæ§ã®çµæã
åŸãããã å®æœäŸ ïŒ åèšäŸç€ºååç©ïŒâïŒïŒã0.5ïœã¥ã€ïŒçš®ç§€
éããããããã«ã€ããŠãžããã«ãã¿ã¬ãŒãïŒml
ãšãšãã«ã¢ã»ããŒãïŒmlãããªã¯ã¬ãžã«ãã¹ããš
ãŒãïŒmlãšãšãã«ã¢ã»ããŒãïŒmlããã³åèšäŸç€º
ååç©ïŒâïŒïŒïŒmlãšãšãã«ã¢ã»ããŒãïŒmlã®
æ··å溶åªã«æº¶è§£ããããããããããã®æº¶æ¶²ãïŒ
ïŒ ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãœãŒã氎溶液ãïŒ
c.c.å«ãïŒïŒ ãŒã©ãã³æ°Žæº¶æ¶²20mläžã«æ³šå ¥ããäºå
æ¹æã®åŸãè¶ é³æ³¢åæ£ãããŠæ°Žäžæ²¹æ»Žååæ£ç©ã
åŸããããã«ããããã®åæ£ç©äžã«å«æããŠãã
ãšãã«ã¢ã»ããŒãããšããã¬ãŒã¿ãŒã«ããé€å»ã
ãŠåè©Šæã調補ããã åè©Šæã15âã§24æéã168æéã360æéãã
ã³720æéçµæãããããããã®çµææ¡ä»¶äžã«ã
ããæåºç¶æ ãé¡åŸ®é¡ã«ãã€ãŠèŠ³å¯ãããããã
ã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ããšãŒã
12 äŸç€º â â â â³
(âïŒ)
(è¡šäžãâã¯ãæåºãªããããâ³ã¯ããããã«æ
åºãããÃã¯ãå šé¢æåºãããããã瀺ãã)
äžèšè¡šããå€ããšãããæ¬çºæè©ŠæïŒãã¹ãNo.
12ïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.10ã11ïŒã«èŒã¹ãŠçµ
æã«ãããåæ£å®å®æ§ãåªããŠããã å®æœäŸ ïŒ ããªãšãã¬ã³ã©ãããŒãçŽæ¯æäœäžã«äžèšæ§æ
ããæã被èŠå±€ãé 次å¡èšããã«ã©ãŒåçæå æ
æã調補ããã 第ïŒå±€ïŒã€ãšããŒã«ãã©ãŒ ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æããé
ææ§æ²èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åžéã¯
0.6ïœïŒm2 第ïŒå±€ïŒãŒã©ãã³äžéå±€ïŒãŒã©ãã³å¡åžéã¯1.0
ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒããŒã³ã¿ã«ãã©ãŒ ãããªã¯ã¬ãžã«ãã¹ããšãŒãã«æº¶è§£ãããã®ã
éåžžã®æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æ
ããç·ææ§å¡©èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åž
éã¯0.4ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒçŽ«å€ç·åžåå€ãšã㊠ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æãããŒ
ã©ãã³äžéå±€ïŒçŽ«å€ç·åžåå€ã®å¡åžéã¯0.5
ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒã·ã¢ã³ã«ãã©ãŒ ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æããèµ€
ææ§å¡©èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åžéã¯
0.4ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒãŒã©ãã³ä¿è·å±€ïŒãŒã©ãã³å¡åžéã¯1.2
ïœïŒm2ïŒ ããã«ãäžèšç¬¬ïŒè¡šã«ç€ºãåŠãåèšã«ã©ãŒåç
æå ææã®å±€äžã«åèšå®æœäŸïŒã®ãã¹ãNo.12ã§çš
ãã24æéçµæåŸã®æ°Žäžæ²¹æ»Žååæ£ç©ã第ïŒè¡šã«
瀺ãæ·»å éã§å«æãããããšã«ãã€ãŠåœ¢æããã
å±€ãæããã«ã©ãŒåçæå ææã調補ããããŸã
æ¯èŒè©ŠæãšããŠãå®æœäŸïŒã®ãã¹ãNo.12ã§çšãã
åæ£ç©ã«ä»£ããŠãããããå®æœäŸïŒã®ãã¹ãNo.
10ããã¹ãNo.11ã§çšãã24æéçµæåŸã®åæ£ç©ã
é©çšãã以å€ã¯ãäžèšãšåæ§ã«ããŠã«ã©ãŒåçæ
å ææã調補ããã 次ãã§ãåã«ã©ãŒåçæå ææã«é£ç¶å æ¥ãçš
ããŠé²å ããäžèšåŠæ¹ã«åŸã€ãŠåŠçããã åŠçå·¥çš åŠç枩床 åŠçæé ïŒ ã«ã©ãŒçŸå 32â ïŒå30ç§ ïŒ æŒçœå®ç ã ïŒå30ç§ ïŒ æ°ŽæŽ 28â ïŒå ïŒ å®å® 30â ïŒå ïŒ ãªã³ã¹ åžžæž© 10ç§ ã«ã©ãŒçŸåã¯äžèšã«ã©ãŒçŸå液ããæŒçœå®çã¯
äžèšæŒçœå®ç液ãããŸãå®å®ã¯äžèšå®å®å液ãçš
ããã ã«ã©ãŒçŸå液 ãžã¢ããââãšãã«ââïŒÎ²âã¡ãã«ã¹ã«ã
ã³ã¢ãããšãã«ïŒâïœâãã«ã€ãžã³âã»ã¹ããµã«
ããšãŒã ïŒïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 14ïœ ç¡æ°Žçé žãããªãŠã 30ïœ ç¡æ°Žäºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.4ïœ å¡©åãããªãŠã 0.3ïœ ç¡«é žç¬¬ïŒé 0.1ïœ æ°Žãå ããŠ å šéïŒãšãã æŒçœå®ç液 ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéïŒïŒïŒãããªãŠ
ã 50ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã ïŒïœ ç¡æ°Žçé žãããªãŠã 0.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 10ïœ ããªç¡«é žã¢ã³ã¢ããŠã 120ïœ æ°Žãå ããŠ å šéïŒãšãã å®å®å液 é ¢é žãããªãŠã ïŒïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã ïŒïœ ãã«ã ã¢ã«ãããïŒ30ïŒ æ¶²ïŒ 80ïœ æ°Žãå ããŠ å šéïŒãšãã ãªããã«ã©ãŒçŸå液ã¯ã調液åŸ70âã§24æéå
æž©ããåŸã«äœ¿çšããããã®çç±ã¯ã匷å¶çã«ç¹æ§
å·®ãæ確åããããã§ããã åŸãããå€è²ã«ã©ãŒç»åããã«ããªããã³æ··è²
ã枬å®ããããããã®çµæã第ïŒè¡šã«ç€ºãããªã
è¡šäžãã¯ã€ãšããŒè²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ããŒ
ã³ã¿è²çŽ ã®æ¿åºŠå€ããã¯ããŒã³ã¿è²çŽ æ¿åºŠ
ïŒ2.00ïŒéšã§ã®ã€ãšããŒè²çŽ ã®æ¿åºŠå€ããã¯ã
ãŒã³ã¿è²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ã·ã¢ã³è²çŽ ã®æ¿åºŠ
å€ãããŸãã¯ã·ã¢ã³è²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ã
ãŒã³ã¿è²çŽ ã®æ¿åºŠå€ããããã瀺ãã
12 äŸç€º â â â â³
(âïŒ)
(è¡šäžãâã¯ãæåºãªããããâ³ã¯ããããã«æ
åºãããÃã¯ãå šé¢æåºãããããã瀺ãã)
äžèšè¡šããå€ããšãããæ¬çºæè©ŠæïŒãã¹ãNo.
12ïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.10ã11ïŒã«èŒã¹ãŠçµ
æã«ãããåæ£å®å®æ§ãåªããŠããã å®æœäŸ ïŒ ããªãšãã¬ã³ã©ãããŒãçŽæ¯æäœäžã«äžèšæ§æ
ããæã被èŠå±€ãé 次å¡èšããã«ã©ãŒåçæå æ
æã調補ããã 第ïŒå±€ïŒã€ãšããŒã«ãã©ãŒ ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æããé
ææ§æ²èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åžéã¯
0.6ïœïŒm2 第ïŒå±€ïŒãŒã©ãã³äžéå±€ïŒãŒã©ãã³å¡åžéã¯1.0
ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒããŒã³ã¿ã«ãã©ãŒ ãããªã¯ã¬ãžã«ãã¹ããšãŒãã«æº¶è§£ãããã®ã
éåžžã®æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æ
ããç·ææ§å¡©èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åž
éã¯0.4ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒçŽ«å€ç·åžåå€ãšã㊠ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æãããŒ
ã©ãã³äžéå±€ïŒçŽ«å€ç·åžåå€ã®å¡åžéã¯0.5
ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒã·ã¢ã³ã«ãã©ãŒ ããžããã«ãã¿ã¬ãŒãã«æº¶è§£ãããã®ãéåžžã®
æ¹æ³ã«ãã€ãŠä¹³ååæ£ããåæ£ç©ãå«æããèµ€
ææ§å¡©èåéãŒã©ãã³ä¹³å€å±€ïŒéã®å¡åžéã¯
0.4ïœïŒm2ïŒ ç¬¬ïŒå±€ïŒãŒã©ãã³ä¿è·å±€ïŒãŒã©ãã³å¡åžéã¯1.2
ïœïŒm2ïŒ ããã«ãäžèšç¬¬ïŒè¡šã«ç€ºãåŠãåèšã«ã©ãŒåç
æå ææã®å±€äžã«åèšå®æœäŸïŒã®ãã¹ãNo.12ã§çš
ãã24æéçµæåŸã®æ°Žäžæ²¹æ»Žååæ£ç©ã第ïŒè¡šã«
瀺ãæ·»å éã§å«æãããããšã«ãã€ãŠåœ¢æããã
å±€ãæããã«ã©ãŒåçæå ææã調補ããããŸã
æ¯èŒè©ŠæãšããŠãå®æœäŸïŒã®ãã¹ãNo.12ã§çšãã
åæ£ç©ã«ä»£ããŠãããããå®æœäŸïŒã®ãã¹ãNo.
10ããã¹ãNo.11ã§çšãã24æéçµæåŸã®åæ£ç©ã
é©çšãã以å€ã¯ãäžèšãšåæ§ã«ããŠã«ã©ãŒåçæ
å ææã調補ããã 次ãã§ãåã«ã©ãŒåçæå ææã«é£ç¶å æ¥ãçš
ããŠé²å ããäžèšåŠæ¹ã«åŸã€ãŠåŠçããã åŠçå·¥çš åŠç枩床 åŠçæé ïŒ ã«ã©ãŒçŸå 32â ïŒå30ç§ ïŒ æŒçœå®ç ã ïŒå30ç§ ïŒ æ°ŽæŽ 28â ïŒå ïŒ å®å® 30â ïŒå ïŒ ãªã³ã¹ åžžæž© 10ç§ ã«ã©ãŒçŸåã¯äžèšã«ã©ãŒçŸå液ããæŒçœå®çã¯
äžèšæŒçœå®ç液ãããŸãå®å®ã¯äžèšå®å®å液ãçš
ããã ã«ã©ãŒçŸå液 ãžã¢ããââãšãã«ââïŒÎ²âã¡ãã«ã¹ã«ã
ã³ã¢ãããšãã«ïŒâïœâãã«ã€ãžã³âã»ã¹ããµã«
ããšãŒã ïŒïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© ïŒïœ ãã³ãžã«ã¢ã«ã³ãŒã« 14ïœ ç¡æ°Žçé žãããªãŠã 30ïœ ç¡æ°Žäºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.4ïœ å¡©åãããªãŠã 0.3ïœ ç¡«é žç¬¬ïŒé 0.1ïœ æ°Žãå ããŠ å šéïŒãšãã æŒçœå®ç液 ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéïŒïŒïŒãããªãŠ
ã 50ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã ïŒïœ ç¡æ°Žçé žãããªãŠã 0.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã 10ïœ ããªç¡«é žã¢ã³ã¢ããŠã 120ïœ æ°Žãå ããŠ å šéïŒãšãã å®å®å液 é ¢é žãããªãŠã ïŒïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒãããªãŠã ïŒïœ ãã«ã ã¢ã«ãããïŒ30ïŒ æ¶²ïŒ 80ïœ æ°Žãå ããŠ å šéïŒãšãã ãªããã«ã©ãŒçŸå液ã¯ã調液åŸ70âã§24æéå
æž©ããåŸã«äœ¿çšããããã®çç±ã¯ã匷å¶çã«ç¹æ§
å·®ãæ確åããããã§ããã åŸãããå€è²ã«ã©ãŒç»åããã«ããªããã³æ··è²
ã枬å®ããããããã®çµæã第ïŒè¡šã«ç€ºãããªã
è¡šäžãã¯ã€ãšããŒè²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ããŒ
ã³ã¿è²çŽ ã®æ¿åºŠå€ããã¯ããŒã³ã¿è²çŽ æ¿åºŠ
ïŒ2.00ïŒéšã§ã®ã€ãšããŒè²çŽ ã®æ¿åºŠå€ããã¯ã
ãŒã³ã¿è²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ã·ã¢ã³è²çŽ ã®æ¿åºŠ
å€ãããŸãã¯ã·ã¢ã³è²çŽ æ¿åºŠïŒ2.00ïŒéšã§ã®ã
ãŒã³ã¿è²çŽ ã®æ¿åºŠå€ããããã瀺ãã
ãè¡šã
ã®æ·»å é
ãè¡šã
ã®æ·»å é
ãè¡šã
ã®æ·»å é
äžèšè¡šããå€ããšãããæ¬çºæè©ŠæïŒãã¹ãNo.
14ã19ïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.20ã31ïŒã«èŒã¹
ãŠãã«ããªçºçããã³æ··è²ãæ¹åãããŠããã
äžèšè¡šããå€ããšãããæ¬çºæè©ŠæïŒãã¹ãNo.
14ã19ïŒã¯ãæ¯èŒè©ŠæïŒãã¹ãNo.20ã31ïŒã«èŒã¹
ãŠãã«ããªçºçããã³æ··è²ãæ¹åãããŠããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšäžè¬åŒããã§ç€ºããããã€ããããã³
èªå°äœãäžèšäžè¬åŒããã§ç€ºãããé«æ²žç¹ææ©
溶åªãçšããŠæº¶è§£ããŠåŸããã溶液ã芪氎æ§ã³ã
ã€ã液äžã«ä¹³åãããããšã«ãã圢æãããæ°Žäž
油滎åã³ãã€ãåæ£æ¶²ãæ¯æäœäžã®å¡åžå±€ã®å°ãª
ããšãïŒå±€äžã«å«æãããŠæãããšãç¹åŸŽãšãã
ã«ã©ãŒåçæå ææã äžè¬åŒãã ïŒåŒäžãR1ããã³R2ã¯ãæ°ŽçŽ ååã眮æè¥ãã
ã¯é眮æã®ã¢ã«ãã«åºã眮æè¥ããã¯é眮æã®ã¢
ã«ã±ãã«åºã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«åºã
眮æè¥ããã¯é眮æã®ã¢ã·ã«åºã眮æè¥ããã¯é
眮æã®ã·ã¯ãã¢ã«ãã«åºãŸãã¯çœ®æè¥ããã¯é眮
æã®å«çªçŽ è€çŽ ç°åºã瀺ããR3ãR4ãR5ããã³
R6ã¯ãæ°ŽçŽ ååãããã²ã³ååã眮æè¥ããã¯
é眮æã®ã¢ã«ãã«åºã眮æè¥ããã¯é眮æã®ã¢ã«
ã±ãã«åºã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«åºã眮
æè¥ããã¯é眮æã®ã·ã¯ãã¢ã«ãã«åºã眮æè¥ã
ãã¯é眮æã®ã¢ã«ã³ãã·åºã眮æè¥ããã¯é眮æ
ã®ã¢ã«ãã«ããªåºã眮æè¥ããã¯é眮æã®ã¢ãªãŒ
ã«ããªåºã眮æè¥ããã¯é眮æã®å«çªçŽ è€çŽ ç°ã
ãªåºã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«ãªãã·åºã
眮æè¥ããã¯é眮æã®ã¢ã·ã«åã眮æè¥ããã¯é
眮æã®ã¢ã·ã«ã¢ããåºã眮æè¥ããã¯é眮æã®ã¢
ã«ãã«ã¢ããåºã眮æè¥ããã¯é眮æã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºã眮æè¥ããã¯é眮æã®ã¢ãªãŒã«
ãªãã·ã«ã«ããã«åºãã«ã«ãã¢ã€ã«åºãŸãã¯ã¹ã«
ãã¢ã¢ã€ã«åºã瀺ããäœããR3ãR4ãR5ããã³
R6ãåæã«æ°ŽçŽ ååã§ããæãR1ãšR2ã¯åæã«
æ°ŽçŽ ååã§ããããšã¯ãªãããŸããR2ãšR4ã§çœ®
æè¥ããã¯é眮æã®ïŒå¡ãŸãã¯ïŒå¡ç°ã圢æããŠ
ããããïŒ äžè¬åŒãã ïŒåŒäžãR7ããã³R8ã¯ã¢ã«ãã«åºããR9ã¯ã¢ã«
ãã«åºãŸãã¯çœ®æè¥ããã¯é眮æã®ã¢ãªãŒã«åºã
瀺ããäœããR7ãR8ããã³R9ã®ïŒã€ã®æ®åºã«å«
ãŸããççŽ æ°ã®åã14ãã30ãŸã§ã§ãããïŒ
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16434879A JPS5687040A (en) | 1979-12-18 | 1979-12-18 | Color photographic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16434879A JPS5687040A (en) | 1979-12-18 | 1979-12-18 | Color photographic material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5687040A JPS5687040A (en) | 1981-07-15 |
| JPS6328299B2 true JPS6328299B2 (ja) | 1988-06-08 |
Family
ID=15791452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16434879A Granted JPS5687040A (en) | 1979-12-18 | 1979-12-18 | Color photographic material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5687040A (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61158330A (ja) * | 1984-12-28 | 1986-07-18 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPH0612422B2 (ja) * | 1985-05-13 | 1994-02-16 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| JPS62161150A (ja) * | 1986-01-08 | 1987-07-17 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JP2640236B2 (ja) * | 1987-12-11 | 1997-08-13 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææ |
| JP2528350B2 (ja) * | 1988-08-31 | 1996-08-28 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | çŽæ¥ããžã«ã©âåçæå ææ |
| JP2557695B2 (ja) * | 1988-09-28 | 1996-11-27 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | çŽæ¥ããžã«ã©ãŒåçæå ææ |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4832727A (ja) * | 1971-08-30 | 1973-05-02 |
-
1979
- 1979-12-18 JP JP16434879A patent/JPS5687040A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4832727A (ja) * | 1971-08-30 | 1973-05-02 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5687040A (en) | 1981-07-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4421845A (en) | Silver halide photographic light-sensitive material | |
| DE2818919A1 (de) | Farbphotographisches, lichtempfindliches material | |
| JPH0518101B2 (ja) | ||
| JP3283917B2 (ja) | ããŒã³ã¿ã«ãã©ãŒãæå¶å€æŸåºã«ãã©ãŒåã³ã«ã«ãã³ã¢ããååç©ãå«æããã«ã©ãŒåçææ | |
| EP0192471B1 (en) | Silver halide color photographic material | |
| EP0157363B1 (en) | Silver halide photografic material | |
| JPS6328299B2 (ja) | ||
| EP0102839B1 (en) | Silver halide color photographic light-sensitive material | |
| JPS6147415B2 (ja) | ||
| JPH0120415B2 (ja) | ||
| US4268617A (en) | Color photographic light-sensitive material | |
| JPS6335970B2 (ja) | ||
| JPS6029937B2 (ja) | ã«ã©âåçæå ææã®è²åå®å®åæ³ | |
| US5731133A (en) | Process for the production of a chromogenically developed color photographic image using a compound capable of reacting with primary aromatic amines | |
| JPS5817946B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS5950977B2 (ja) | ã«ã©âåçæå ææ | |
| JP2816492B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS6410061B2 (ja) | ||
| JPH05241297A (ja) | è€çŽ ç°çªçŽ æ·»å å€ãå«ãã§æãçµæç©åã³ãããã®ååšäžã«ãããç»åçŸåæ¹æ³ | |
| JPS6255651B2 (ja) | ||
| JPS6289960A (ja) | ããã²ã³åéæå ææ | |
| JPH01124843A (ja) | ããã²ã³åéåçæå ææ | |
| JPS6157619B2 (ja) | ||
| JPS5847702B2 (ja) | ã«ã©âã·ã€ã·ã³ã«ã³ã³ãŠã¶ã€ãªãšãŠ | |
| JPH02103032A (ja) | é«æ床ã§ã«ããªã®çºçãå°ãªãããã€ä¿åå®å®æ§ã«åªããããã²ã³åéåçæå ææ |