JPS626486B2 - - Google Patents
Info
- Publication number
- JPS626486B2 JPS626486B2 JP3605578A JP3605578A JPS626486B2 JP S626486 B2 JPS626486 B2 JP S626486B2 JP 3605578 A JP3605578 A JP 3605578A JP 3605578 A JP3605578 A JP 3605578A JP S626486 B2 JPS626486 B2 JP S626486B2
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- diallyl
- group
- dicrotyl
- dimethallyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 claims description 76
- 125000001931 aliphatic group Chemical group 0.000 claims description 33
- 238000004132 cross linking Methods 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 238000002844 melting Methods 0.000 claims description 17
- 230000008018 melting Effects 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 7
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- -1 polyethylene terephthalate Polymers 0.000 description 59
- 150000001875 compounds Chemical class 0.000 description 54
- DSAYAFZWRDYBQY-UHFFFAOYSA-N 2,5-dimethylhexa-1,5-diene Chemical group CC(=C)CCC(C)=C DSAYAFZWRDYBQY-UHFFFAOYSA-N 0.000 description 51
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 25
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 24
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 17
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000005977 Ethylene Substances 0.000 description 13
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 125000000962 organic group Chemical group 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- UCBVELLBUAKUNE-UHFFFAOYSA-N 1,3-bis(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical group C=CCN1C(=O)NC(=O)N(CC=C)C1=O UCBVELLBUAKUNE-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WQVBZJXNXCEFJN-UHFFFAOYSA-N 2-benzoylbenzamide Chemical compound NC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 WQVBZJXNXCEFJN-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- SNDQOBHHPNQOBB-UHFFFAOYSA-N cyclohexene-1-carboxamide Chemical compound NC(=O)C1=CCCCC1 SNDQOBHHPNQOBB-UHFFFAOYSA-N 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- AFJWMGOTLUUGHF-UHFFFAOYSA-N 4,5,6,7-tetrahydroisoindole-1,3-dione Chemical compound C1CCCC2=C1C(=O)NC2=O AFJWMGOTLUUGHF-UHFFFAOYSA-N 0.000 description 2
- VSZARHUCMHICLD-UHFFFAOYSA-N 4,6-bis(prop-2-enoxy)-1h-1,3,5-triazin-2-one Chemical group C=CCOC=1N=C(OCC=C)NC(=O)N=1 VSZARHUCMHICLD-UHFFFAOYSA-N 0.000 description 2
- QHVJZYJNUUACLR-UHFFFAOYSA-N 5-carbamoylbenzene-1,3-dicarboxylic acid Chemical compound NC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QHVJZYJNUUACLR-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KGPFOHIRFCZKEE-UHFFFAOYSA-N O=C(C1=CC=CC=C1)C(C=CC=C1)=C1C(NCCNC(C(C=CC=C1)=C1C(C1=CC=CC=C1)=O)=O)=O Chemical compound O=C(C1=CC=CC=C1)C(C=CC=C1)=C1C(NCCNC(C(C=CC=C1)=C1C(C1=CC=CC=C1)=O)=O)=O KGPFOHIRFCZKEE-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000005336 allyloxy group Chemical group 0.000 description 2
- 150000008365 aromatic ketones Chemical class 0.000 description 2
- 150000007860 aryl ester derivatives Chemical class 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- NQQRXZOPZBKCNF-UHFFFAOYSA-N but-2-enamide Chemical compound CC=CC(N)=O NQQRXZOPZBKCNF-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- ZWUNKULTLYLLTH-UHFFFAOYSA-N cyclohexane-1,4-dicarboxamide Chemical compound NC(=O)C1CCC(C(N)=O)CC1 ZWUNKULTLYLLTH-UHFFFAOYSA-N 0.000 description 2
- UFDHBDMSHIXOKF-UHFFFAOYSA-N cyclohexene-1,2-dicarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- MQNQJAWLPVZCKN-UHFFFAOYSA-N hex-3-enediamide Chemical compound NC(=O)CC=CCC(N)=O MQNQJAWLPVZCKN-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- JXRWDHUZHAWOLC-UHFFFAOYSA-N naphthalene-1,2-dicarboxamide Chemical compound C1=CC=CC2=C(C(N)=O)C(C(=O)N)=CC=C21 JXRWDHUZHAWOLC-UHFFFAOYSA-N 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical group C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 125000005591 trimellitate group Chemical group 0.000 description 2
- OJLABXSUFRIXFL-UHFFFAOYSA-N (2-benzoylphenyl)-phenylmethanone Chemical compound C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1C(=O)C1=CC=CC=C1 OJLABXSUFRIXFL-UHFFFAOYSA-N 0.000 description 1
- JENOLWCGNVWTJN-UHFFFAOYSA-N (3,4-dimethylphenyl)-phenylmethanone Chemical compound C1=C(C)C(C)=CC=C1C(=O)C1=CC=CC=C1 JENOLWCGNVWTJN-UHFFFAOYSA-N 0.000 description 1
- VMFJVWPCRCAWBS-UHFFFAOYSA-N (3-methoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1 VMFJVWPCRCAWBS-UHFFFAOYSA-N 0.000 description 1
- YMDBXBBWNOELNV-UHFFFAOYSA-N (3-methylphenyl)-(4-methylphenyl)methanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC(C)=C1 YMDBXBBWNOELNV-UHFFFAOYSA-N 0.000 description 1
- URBLVRAVOIVZFJ-UHFFFAOYSA-N (3-methylphenyl)-phenylmethanone Chemical compound CC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1 URBLVRAVOIVZFJ-UHFFFAOYSA-N 0.000 description 1
- MFYLRNKOXORIPK-UHFFFAOYSA-N (3-nitrophenyl)-phenylmethanone Chemical compound [O-][N+](=O)C1=CC=CC(C(=O)C=2C=CC=CC=2)=C1 MFYLRNKOXORIPK-UHFFFAOYSA-N 0.000 description 1
- SWFHGTMLYIBPPA-UHFFFAOYSA-N (4-methoxyphenyl)-phenylmethanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 SWFHGTMLYIBPPA-UHFFFAOYSA-N 0.000 description 1
- WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 description 1
- ZYMCBJWUWHHVRX-UHFFFAOYSA-N (4-nitrophenyl)-phenylmethanone Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)C1=CC=CC=C1 ZYMCBJWUWHHVRX-UHFFFAOYSA-N 0.000 description 1
- WYFGTZBRHKBFBD-NSCUHMNNSA-N (e)-pent-3-ene-1,2-diol Chemical compound C\C=C\C(O)CO WYFGTZBRHKBFBD-NSCUHMNNSA-N 0.000 description 1
- PPKPKFIWDXDAGC-IHWYPQMZSA-N (z)-1,2-dichloroprop-1-ene Chemical compound C\C(Cl)=C\Cl PPKPKFIWDXDAGC-IHWYPQMZSA-N 0.000 description 1
- ORTVZLZNOYNASJ-UPHRSURJSA-N (z)-but-2-ene-1,4-diol Chemical compound OC\C=C/CO ORTVZLZNOYNASJ-UPHRSURJSA-N 0.000 description 1
- AHWDQDMGFXRVFB-UHFFFAOYSA-N 1,3,5-trimethyl-1,3,5-triazinane-2,4,6-trione Chemical compound CN1C(=O)N(C)C(=O)N(C)C1=O AHWDQDMGFXRVFB-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- SFQZATJKWJQVBE-UHFFFAOYSA-N 1-(4-methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethoxy]ethanone Chemical compound C1=CC(OC)=CC=C1C(=O)COCC(=O)C1=CC=C(OC)C=C1 SFQZATJKWJQVBE-UHFFFAOYSA-N 0.000 description 1
- YCANAXVBJKNANM-UHFFFAOYSA-N 1-nitroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2[N+](=O)[O-] YCANAXVBJKNANM-UHFFFAOYSA-N 0.000 description 1
- JUNVYDTYJZSTKY-UHFFFAOYSA-N 1-prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonylbenzene Chemical compound C1=CC(OCC=C)=CC=C1S(=O)(=O)C1=CC=C(OCC=C)C=C1 JUNVYDTYJZSTKY-UHFFFAOYSA-N 0.000 description 1
- HQDGDVIFIYRKDR-UHFFFAOYSA-N 2-(cyclohexen-1-yl)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)C1=CCCCC1 HQDGDVIFIYRKDR-UHFFFAOYSA-N 0.000 description 1
- VWRRMTKESSIIKG-UHFFFAOYSA-N 2-[1,1-bis[2-(2-hydroxyethoxy)phenyl]ethyl]propane-1,3-diol cyclohexane Chemical compound C(O)C(C(C)(C1=C(C=CC=C1)OCCO)C1=C(C=CC=C1)OCCO)CO.C1CCCCC1 VWRRMTKESSIIKG-UHFFFAOYSA-N 0.000 description 1
- RMVQMXJLQZQLOJ-UHFFFAOYSA-N 2-[2-[2-carbamoyl-6-(4-nitrobenzoyl)phenyl]ethyl]-3-(4-nitrobenzoyl)benzamide Chemical compound NC(=O)C=1C=CC=C(C(=O)C=2C=CC(=CC=2)[N+]([O-])=O)C=1CCC=1C(C(=O)N)=CC=CC=1C(=O)C1=CC=C([N+]([O-])=O)C=C1 RMVQMXJLQZQLOJ-UHFFFAOYSA-N 0.000 description 1
- JLMYUUPHFXPADU-UHFFFAOYSA-N 2-but-1-enylpropane-1,3-diol Chemical compound CCC=CC(CO)CO JLMYUUPHFXPADU-UHFFFAOYSA-N 0.000 description 1
- DZZAHLOABNWIFA-UHFFFAOYSA-N 2-butoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCCCC)C(=O)C1=CC=CC=C1 DZZAHLOABNWIFA-UHFFFAOYSA-N 0.000 description 1
- FJZNROVGLPJDEE-UHFFFAOYSA-N 2-ethenylbutanedioic acid Chemical compound OC(=O)CC(C=C)C(O)=O FJZNROVGLPJDEE-UHFFFAOYSA-N 0.000 description 1
- DGOCKLWCCHQGRS-UHFFFAOYSA-N 2-ethoxy-1,2,3-triphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(=O)C(C=1C=CC=CC=1)(OCC)CC1=CC=CC=C1 DGOCKLWCCHQGRS-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- ROVLJQDICPLANK-UHFFFAOYSA-N 2-ethoxy-3-hydroxybenzoic acid Chemical compound CCOC1=C(O)C=CC=C1C(O)=O ROVLJQDICPLANK-UHFFFAOYSA-N 0.000 description 1
- CKKQLOUBFINSIB-UHFFFAOYSA-N 2-hydroxy-1,2,2-triphenylethanone Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C(=O)C1=CC=CC=C1 CKKQLOUBFINSIB-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- IMAHLMWOKFATMM-UHFFFAOYSA-N 2-methoxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(C)(OC)C(=O)C1=CC=CC=C1 IMAHLMWOKFATMM-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- UFMBOFGKHIXOTA-UHFFFAOYSA-N 2-methylterephthalic acid Chemical compound CC1=CC(C(O)=O)=CC=C1C(O)=O UFMBOFGKHIXOTA-UHFFFAOYSA-N 0.000 description 1
- ZRVBMNHMJLBKSY-UHFFFAOYSA-N 2-phenacyloxy-1-phenylethanone Chemical compound C=1C=CC=CC=1C(=O)COCC(=O)C1=CC=CC=C1 ZRVBMNHMJLBKSY-UHFFFAOYSA-N 0.000 description 1
- AXYQEGMSGMXGGK-UHFFFAOYSA-N 2-phenoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(=O)C(C=1C=CC=CC=1)OC1=CC=CC=C1 AXYQEGMSGMXGGK-UHFFFAOYSA-N 0.000 description 1
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- GIZSKOXLQJIYIB-UHFFFAOYSA-N 3-azabicyclo[3.2.2]non-6-ene-2,4-dione Chemical compound O=C1NC(=O)C2C=CC1CC2 GIZSKOXLQJIYIB-UHFFFAOYSA-N 0.000 description 1
- XPYBNRVNEZGUOB-UHFFFAOYSA-N 3-benzoyl-2-[10-(2-benzoyl-6-carbamoylphenyl)decyl]benzamide Chemical compound NC(=O)C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1CCCCCCCCCCC=1C(C(=O)N)=CC=CC=1C(=O)C1=CC=CC=C1 XPYBNRVNEZGUOB-UHFFFAOYSA-N 0.000 description 1
- HXWMTLRZAPQPAU-UHFFFAOYSA-N 3-benzoyl-2-[4-(2-benzoyl-6-carbamoylphenyl)butyl]benzamide Chemical compound NC(=O)C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1CCCCC=1C(C(=O)N)=CC=CC=1C(=O)C1=CC=CC=C1 HXWMTLRZAPQPAU-UHFFFAOYSA-N 0.000 description 1
- CQMYRTHVIVMELT-UHFFFAOYSA-N 3-benzoyl-2-[6-(2-benzoyl-6-carbamoylphenyl)hexyl]benzamide Chemical compound NC(=O)C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1CCCCCCC=1C(C(=O)N)=CC=CC=1C(=O)C1=CC=CC=C1 CQMYRTHVIVMELT-UHFFFAOYSA-N 0.000 description 1
- GPIUUMROPXDNRH-UHFFFAOYSA-N 3647-74-3 Chemical compound C1C2C3C(=O)NC(=O)C3C1C=C2 GPIUUMROPXDNRH-UHFFFAOYSA-N 0.000 description 1
- MTMKZABGIQJAEX-UHFFFAOYSA-N 4,4'-sulfonylbis[2-(prop-2-en-1-yl)phenol] Chemical compound C1=C(CC=C)C(O)=CC=C1S(=O)(=O)C1=CC=C(O)C(CC=C)=C1 MTMKZABGIQJAEX-UHFFFAOYSA-N 0.000 description 1
- LFEWXDOYPCWFHR-UHFFFAOYSA-N 4-(4-carboxybenzoyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C=C1 LFEWXDOYPCWFHR-UHFFFAOYSA-N 0.000 description 1
- 125000001999 4-Methoxybenzoyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1OC([H])([H])[H])C(*)=O 0.000 description 1
- AGMBVGXHFCPVIN-UHFFFAOYSA-N 4-acetyl-2-[6-(5-acetyl-2-carbamoylphenyl)hexyl]benzamide Chemical compound CC(=O)C1=CC=C(C(N)=O)C(CCCCCCC=2C(=CC=C(C=2)C(C)=O)C(N)=O)=C1 AGMBVGXHFCPVIN-UHFFFAOYSA-N 0.000 description 1
- ALVQRUKAJHWSIR-UHFFFAOYSA-N 4-benzoylisoindole-1,3-dione Chemical compound C=1C=CC=2C(=O)NC(=O)C=2C=1C(=O)C1=CC=CC=C1 ALVQRUKAJHWSIR-UHFFFAOYSA-N 0.000 description 1
- PWRCOONECNWDBH-UHFFFAOYSA-N 4-prop-2-enoxyphenol Chemical compound OC1=CC=C(OCC=C)C=C1 PWRCOONECNWDBH-UHFFFAOYSA-N 0.000 description 1
- IUQPYUUSZJYMFG-UHFFFAOYSA-N 5-carbamoylbenzene-1,2,4-tricarboxylic acid Chemical compound NC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O IUQPYUUSZJYMFG-UHFFFAOYSA-N 0.000 description 1
- SNULTPQANPFFQH-UHFFFAOYSA-N 6-methoxy-1h-1,3,5-triazine-2,4-dione Chemical compound COC1=NC(=O)NC(=O)N1 SNULTPQANPFFQH-UHFFFAOYSA-N 0.000 description 1
- QNLRSUPDYDUZSS-UHFFFAOYSA-N 9,10-dioxoanthracene-1-carboxamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(=O)N QNLRSUPDYDUZSS-UHFFFAOYSA-N 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- NMEZJSDUZQOPFE-UHFFFAOYSA-N Cyclohex-1-enecarboxylic acid Chemical compound OC(=O)C1=CCCCC1 NMEZJSDUZQOPFE-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical group C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- UGONSFWFTHBIMR-UHFFFAOYSA-N [2-(4-methylbenzoyl)phenyl]-(4-methylphenyl)methanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1C(=O)C1=CC=C(C)C=C1 UGONSFWFTHBIMR-UHFFFAOYSA-N 0.000 description 1
- XWGGXGXGJKTIPG-UHFFFAOYSA-N [2-[2,3-bis(2-benzoylphenoxy)phenoxy]phenyl]-phenylmethanone Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)C(=O)C=3C=CC=CC=3)C=CC=2)OC=2C(=CC=CC=2)C(=O)C=2C=CC=CC=2)C=1C(=O)C1=CC=CC=C1 XWGGXGXGJKTIPG-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- DVDVFJQUNHPDBG-UHFFFAOYSA-N bicyclo[2.2.1]hept-5-ene-2,3-dicarboxamide Chemical compound C1C2C=CC1C(C(=O)N)C2C(N)=O DVDVFJQUNHPDBG-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- FKFVCCPWFITRSN-UHFFFAOYSA-N bis(3,4-dimethylphenyl)methanone Chemical compound C1=C(C)C(C)=CC=C1C(=O)C1=CC=C(C)C(C)=C1 FKFVCCPWFITRSN-UHFFFAOYSA-N 0.000 description 1
- CRMSZGRTWXOBKL-UHFFFAOYSA-N bis(3-methoxyphenyl)methanone Chemical compound COC1=CC=CC(C(=O)C=2C=C(OC)C=CC=2)=C1 CRMSZGRTWXOBKL-UHFFFAOYSA-N 0.000 description 1
- CGXDIDXEMHMPIX-UHFFFAOYSA-N bis(3-methylphenyl)methanone Chemical compound CC1=CC=CC(C(=O)C=2C=C(C)C=CC=2)=C1 CGXDIDXEMHMPIX-UHFFFAOYSA-N 0.000 description 1
- BSDKBWGNIJMCID-UHFFFAOYSA-N bis(3-nitrophenyl)methanone Chemical compound [O-][N+](=O)C1=CC=CC(C(=O)C=2C=C(C=CC=2)[N+]([O-])=O)=C1 BSDKBWGNIJMCID-UHFFFAOYSA-N 0.000 description 1
- RFVHVYKVRGKLNK-UHFFFAOYSA-N bis(4-methoxyphenyl)methanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1 RFVHVYKVRGKLNK-UHFFFAOYSA-N 0.000 description 1
- ZWPWLKXZYNXATK-UHFFFAOYSA-N bis(4-methylphenyl)methanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=C(C)C=C1 ZWPWLKXZYNXATK-UHFFFAOYSA-N 0.000 description 1
- IRFCWUHTGYXRNR-UHFFFAOYSA-N bis(4-nitrophenyl)methanone Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)C1=CC=C([N+]([O-])=O)C=C1 IRFCWUHTGYXRNR-UHFFFAOYSA-N 0.000 description 1
- GGAUUQHSCNMCAU-UHFFFAOYSA-N butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)CC(O)=O GGAUUQHSCNMCAU-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- KKOUIKKXZGHKKK-UHFFFAOYSA-N cyclohex-2-ene-1,1-dicarboxamide Chemical compound NC(=O)C1(C(N)=O)CCCC=C1 KKOUIKKXZGHKKK-UHFFFAOYSA-N 0.000 description 1
- IHLIVAHFDOAPFC-UHFFFAOYSA-N cyclohex-2-ene-1,4-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C=C1 IHLIVAHFDOAPFC-UHFFFAOYSA-N 0.000 description 1
- FDODVZVWGKVMBO-UHFFFAOYSA-N cyclohex-2-ene-1,4-diol Chemical compound OC1CCC(O)C=C1 FDODVZVWGKVMBO-UHFFFAOYSA-N 0.000 description 1
- ILUAAIDVFMVTAU-UHFFFAOYSA-N cyclohex-4-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CC=CCC1C(O)=O ILUAAIDVFMVTAU-UHFFFAOYSA-N 0.000 description 1
- PGWRONZMYLNFAB-UHFFFAOYSA-N cyclohexene-1,2-dicarboxamide Chemical compound NC(=O)C1=C(C(N)=O)CCCC1 PGWRONZMYLNFAB-UHFFFAOYSA-N 0.000 description 1
- WOSVXXBNNCUXMT-UHFFFAOYSA-N cyclopentane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1CC(C(O)=O)C(C(O)=O)C1C(O)=O WOSVXXBNNCUXMT-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- MUPFCCVZEUACLO-UHFFFAOYSA-N hept-2-enamide Chemical compound CCCCC=CC(N)=O MUPFCCVZEUACLO-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- CXAYOCVHDCXPAI-UHFFFAOYSA-N naphthalen-1-yl(phenyl)methanone Chemical compound C=1C=CC2=CC=CC=C2C=1C(=O)C1=CC=CC=C1 CXAYOCVHDCXPAI-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- YIKSWSCMAXXDFK-UHFFFAOYSA-N oct-2-enediamide Chemical compound NC(=O)CCCCC=CC(N)=O YIKSWSCMAXXDFK-UHFFFAOYSA-N 0.000 description 1
- BNTPVRGYUHJFHN-UHFFFAOYSA-N oct-2-enedioic acid Chemical compound OC(=O)CCCCC=CC(O)=O BNTPVRGYUHJFHN-UHFFFAOYSA-N 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- KOVXIYLMAMPQLP-UHFFFAOYSA-N phenyl-(3-phenylphenyl)methanone Chemical compound C=1C=CC(C=2C=CC=CC=2)=CC=1C(=O)C1=CC=CC=C1 KOVXIYLMAMPQLP-UHFFFAOYSA-N 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UGQZLDXDWSPAOM-UHFFFAOYSA-N pyrrolo[3,4-f]isoindole-1,3,5,7-tetrone Chemical compound C1=C2C(=O)NC(=O)C2=CC2=C1C(=O)NC2=O UGQZLDXDWSPAOM-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Treatments Of Macromolecular Shaped Articles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Description
æ¬çºæã¯ããªãšã¹ãã«å®¹åšã®è£œé æ³ãæŽã«è©³ã
ãã¯ãèç±æ§ãéææ§åã³èè¬åæ§ã«åªããããª
ãšã¹ãã«ææãããªã容åšã®è£œé æ³ã«é¢ãããã®
ã§ããã ããªãšã¹ãã«ãæ®ã«ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãã¯ç±å¯å¡æ§ã§ããããã«æº¶èæ圢ãå¯èœã§ãã
ã€ã«ã ãã·ãŒãç¶ã«è£œé ããããããã«äŸãã°é£²
é£åãå粧åãå»è¬åçã®å®¹åšåãã«ã¯å¥œé©ã«æ
æã®åœ¢ç¶ã«äºæ¬¡æ圢ãããããšã¯ããç¥ãããŠã
ãããããããªãšã¹ãã«ã¯äžè¬ã«æº¶èæ圢ã«ãã
åŒåŒµãè¡æçã®æ©æ¢°ç匷床ãéæ床ãèè¬åæ§ç
ã®ããããç¹æ§ãçºçŸã§ãããšãã倧ããªç¹åŸŽã
æãããããããªããã溶èæŒãåºããããããª
ãšã¹ãã«ã®ã·ãŒããæ·±çµãæ圢ããŠåŸããã容åš
ã¯ãé«æž©æã®åçž®ãããããèç±æ§ãäžååã§ã
ãããšãææãããŠãããäŸãã°ããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒãã®ãã€ã«ã åã¯ã·ãŒãããæ·±çµãã§
補é ããã容åšã®å Žåã«ã¯65âã§åçž®ããŠããŸ
ããé«æž©ã§ã®äœ¿çšãã§ããªãæ¬ ç¹ãæããã æ¬çºæè ã¯ãããæ¬ ç¹ã«éã¿éææ€èšã®çµæã
ç±çã«å®å®ãªæ¶æ©å€åã³æ¶æ©åå¿å©å€ã䜿çšããŠ
ããªãšã¹ãã«ããã€ã«ã åã¯ã·ãŒããšããåŸæ¶æ©
åå¿ãèµ·ãããããšããç°¡åãªæ¹æ³ã§æ圢å å·¥æ§
ãæªãããããšãªããèç±æ§ãéææ§åã³èè¬å
æ§ã«åªããããªãšã¹ãã«å®¹åšã補é ããããšãèŠ
ãåºããæ¬çºæã«è³ã€ãã ããªãã¡ãæ¬çºæã¯ç·ç¶ããªãšã¹ãã«ã®ã·ãŒã
åã¯ãã€ã«ã ã該ãã€ã«ã åã¯ã·ãŒãã®äºæ¬¡è»¢ç§»
枩床以äžã®æž©åºŠã«å ç±ããæ·±çµãæ圢ããŠããªãš
ã¹ãã«å®¹åšã補é ããæ¹æ³ã«ãããŠã該ç·ç¶ããª
ãšã¹ãã«ãšããŠããªããŒ100ïœåœã0.01ã0.5åœé
ã®ç·ç¶ããªãšã¹ãã«ã®æº¶èæ¡ä»¶äžã§å®è³ªçã«å®å®
ã§ããèèªæç³»äžé£œååºãšããªããŒ100éééšåœ
ã0.01ã20éééšã®æ¶æ©åå¿å©å€ãšãå«æããã
ãç·ç¶ããªãšã¹ãã«ãçšããäžã€ã·ãŒãåã¯ãã€
ã«ã æ圢以éã®ä»»æã®æ®µéã§è©²ã·ãŒãåã¯ãã€ã«
ã ã«æŽ»æ§ç·ãç §å°ãæ¶æ©åå¿ãèµ·ããããããšã
ç¹åŸŽãšãããªã«ãœã¯ããããšããŒã«äžæº¶è§£å10é
éïŒ ä»¥äžã®æ¶æ©åºŠãæãäžã€éæãªããªãšã¹ãã«
容åšã®è£œé æ³ã§ããã æ¬çºæã«ãããç·ç¶ããªãšã¹ãã«ã¯ã飜åãžã«
ã«ãã³é žé¡ã®äžã€åã¯ãã以äžãšé£œåãžãªãŒã«é¡
ã®äžã€åã¯ãã以äžãšãçµåãããŠéçž®åããã
æ§é ããäž»ãšããŠãªãé«ååç¶ããªããŒãåã¯é£œ
åãªãã·é žé¡ã®äžã€åã¯ãã以äžãéçž®åããã
æ§é ãæããé«ååç¶ããªããŒããããåèšé£œå
ãžã«ã«ãã³é žé¡ãšããŠã¯ããã¬ãã¿ã«é žïŒã€ãœã
ã¿ã«é žïŒã¡ãã«ãã¬ãã¿ã«é žïŒã¡ãã«ã€ãœãã¿ã«
é žïŒããã¿ã¬ã³ãžã«ã«ãã³é žïŒãžããšãã«ãžã«ã«
ãã³é žïŒãžããšããã·ãšã¿ã³ãžã«ã«ãã³é žïŒãžã
ãšãã«ãšãŒãã«ãžã«ã«ãã³é žçã®åŠãè³éŠæãžã«
ã«ãã³é žïŒã³ãã¯é žïŒã¢ãžãã³é žïŒã»ããã³é žïŒ
ããã«ã³ãžã«ã«ãã³é žçã®åŠãèèªæãžã«ã«ãã³
é žïŒãããµããããã¬ãã¿ã«é žã®åŠãèç°æãžã«
ã«ãã³é žçãäŸç€ºããããšãã§ããããŸã飜åãž
ãªãŒã«é¡ãšããŠã¯ããšãã¬ã³ã°ãªã³ãŒã«ïŒãžãšã
ã¬ã³ã°ãªã³ãŒã«ïŒããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒã
ãªãã³ãã«ã°ãªã³ãŒã«ïŒãããµã¡ãã¬ã³ã°ãªã³ãŒ
ã«ïŒãã«ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒã·ã¯ããããµã³ãž
ã¡ãããŒã«ïŒïŒïŒïŒâãã¹ïŒÎ²âããããã·ãšã
ãã·ããšãã«ïŒãããã³ïŒãã€ããããã³ïŒïŒïŒ
ïŒâãã¹ïŒããããã·ããšãã«ïŒãããã³çãäŸ
瀺ããããæŽã«ãŸã飜åãªãã·é žé¡ãšããŠã¯ãε
âãªãã·ã«ããã³é žïŒãªãã·å®æ¯éŠé žïŒãããã
ã·ãšããã·å®æ¯éŠé žçãäŸç€ºãããã ãããé žæååã³ãžãªãŒã«æåããåŸãããç·
ç¶ããªãšã¹ãã«ã®å ·äœäŸãšããŠã¯ãäŸãã°ããªãš
ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒããªããã¬ã³ãã¬ãã¿ã¬
ãŒãïŒããªãšãã¬ã³ããã¿ã¬ãŒãçãæããäºã
åºæ¥ãã äžèšã®ç·ç¶ããªãšã¹ãã«ã¯ããã®è£œé æ³ãšããŠ
ãžã«ã«ãã³é žãçšããçŽæ¥éåæ³ããããã¯è©²ãž
ã«ã«ãã³é žã®ãšã¹ãã«ãã©ã¯ãã³çã®åŠããªãã·
ã«ã«ãã³é žã®èªå°äœãçšãã亀æåå¿æ³çã«ãã
éåæ³ãæããããããå®è³ªçã«ç·ç¶ããªãšã¹ã
ã«ã®ååŠæ§é ãæããã°ããã補é æ³ã®äœåŠãå
ããªããã®ã§ããããŸãããããŠè£œé ããããç·
ç¶ããªãšã¹ãã«ã¯éåäœã®æ¥µéç²åºŠãηããšããŠ
ã¯0.3以äžãæŽã«ã¯0.5以äžã§ããããšã奜ãŸã
ãã æ¬çºæã«ãããŠãäžè¿°ã®ããªãšã¹ãã«ã«ã該ã
ãªãšã¹ãã«ã®æº¶èæ¡ä»¶äžå®è³ªçã«å®å®ãªèèªæç³»
äžé£œååºãå«æããããæ¹æ³ãšããŠã¯ãéåžžã該
èèªæç³»äžé£œååºãšå°ããšãïŒåã®ãšã¹ãã«åœ¢æ
æ§å®èœåºãæããååç©ãæ¶æ©å€ãšããŠå ±éåã
ãããæ¹æ³åã³ïŒåã¯è©²èèªæç³»äžé£œååºãå°ã
ãšãïŒåæããååç©ããã¬ã³ãããããæ¹æ³ãš
ãçšãããããããã§ããªãšã¹ãã«ã®æº¶èæ¡ä»¶äž
å®è³ªçã«å®å®ã§ããããšã¯ãããªãšã¹ãã«ã®æº¶è
ãã枩床äŸãã°ããªãšã¹ãã«ã®èç¹ãã20âé«ã
枩床ã§äžæŽ»æ§ã¬ã¹äžäŸãã°çŽ15åéä¿æããå Žå
èèªæç³»äžé£œååºåå¿æãã¯äžé£œååºãšããªãšã¹
ãã«ãšã®åå¿çãèµ·ãããäžé£œååºãå®å®ã«ååš
ããããšãæå³ããããããæ¡ä»¶ãæºè¶³ããèèª
æç³»äžé£œååºãšããŠã¯éå ±åœ¹ã®èèªæç³»äžé£œååº
ã奜ãŸãããç¹ã«äžèšäžè¬åŒ(i) ã§è¡šããããäºéçµåã«å¯Ÿãαäœã®ççŽ ã«æ°ŽçŽ å
åãå°ããšãïŒåæããéå ±åœ¹ç³»ã®åºãäŸãã°ã¢
ãªã«åºïŒçœ®æã¢ãªã«åºçã奜ãŸããã äžèšäžè¬åŒ(i)ã§è¡šããããåºã«ãããŠãçµåæ
(a)ïŒ(b)ïŒ(c)åã³(d)ã¯æ°ŽçŽ åååã¯ææ©åºãšçµåã
ãŠãããçµåæ(e)ã¯ææ©åºãšçµåããŠããã(a)ïŒ
(b)ïŒ(c)ïŒ(d)åã³(e)ã®çµåæãšçµåããŠããææ©åº
ã¯ç¬ç«ããŠãããããŸãäºãã«çµåããŠç°æ§é ã
圢æããŠããŠãè¯ããç°æ§é ã圢æããå ŽåãåŒ
(i)äžã®äºéçµåã¯ç°æ§é ã®äžéšãæ§æããããšã
å¯èœã§ããããã®éãã®ç°æ§é ã¯èç°ãè€çŽ ç°ç
ã®ç°æ§é ã§ããããããè³éŠæ žã圢æããããšã¯
ãªãã äžèšäžè¬åŒ(i)ã§è¡šããããåºã®æŽã«å¥œãŸããæ§
é ã¯äžèšäžè¬åŒ(ii)ã§è¡šããããã ãäœãåŒäžãR1ïŒR2åã³R3ã¯ãåäžãããã¯
ç°ã€ãŠãããããæ°ŽçŽ åååã³ææ©åºãããªã矀
ããéžã°ããã¡ã³ããŒã瀺ããã åèšäžè¬åŒ(ii)äžãR1ïŒR2åã³R3ã«ã€ããŠãæ
æ©åºã®å¥œãŸããäŸãšããŠã¯ãC1ãC6ã®ã¢ã«ã
ã«ãäžå±€å¥œãŸããã¯C1ãC3ã®ã¢ã«ãã«ãæãã
ããšãã§ãããåŒ(ii)ã§è¡šããããåºãããªãã¡ã¢
ãªã«è¥ããã¯çœ®æã¢ãªã«äžå¥œãŸãããã®ã¯ãã¢ãª
ã«ïŒã¡ã¿ã¢ãªã«åã³ã¯ããã«åºã§ãããç¹ã«å¥œãŸ
ãããã®ã¯ã¢ãªã«åºã§ããã ãããèèªæç³»äžé£œååºãããªãšã¹ãã«äžã«å«
æããããããšã¯è©²èèªæç³»äžé£œååºãæããå
åç©(A)ããããªãšã¹ãã«ã«å ±éååã³ïŒåã¯æ··å
ããããããšã«ãã€ãŠã§ããã該ååç©(A)ãããª
ãšã¹ãã«ã«å ±éåããããå Žåã«ã¯ã該ååç©(A)
ã¯ãå ±éåæ¡ä»¶äžã§å解ãªã©ãçããããšãªãå®
å®ã§ããå¿ èŠãããããŸãè©²å ±éåæ¡ä»¶äžã§å®å®
ãªèèªæç³»äžé£œååºã®ä»ã«ãšã¹ãã«åœ¢ææ§å®èœåº
ïŒäŸãã°ã«ã«ããã·ã«åºïŒæ°Žé žåºçïŒãªããã¯ã
ãªãšã¹ãã«ã®éåæ¡ä»¶äžã§è©²ãšã¹ãã«åœ¢æå®èœåº
ãçæãããããªå®èœåºãå°ããšãïŒåã奜ãŸã
ãã¯ïŒåæããŠããå¿ èŠããããåŸè ã®å®èœåºãš
ããŠã¯ãšããã·åºãäŸç€ºããããšãã§ããããŸã
ååç©(A)ãããªãšã¹ãã«ã«é åããå Žåã«ã¯ã該
ååç©(A)äžã®èèªæç³»äžé£œååºãããªãšã¹ãã«ãš
ã®æº¶èæ··ç·Žäžã§å®å®ã§ããããšã¯å¿è«ã®ããšã該
ååç©(A)èªèº«ãå®å®ã§ããããšã奜ãŸãããåŸã€
ãŠååç©(A)ã溶èãã¬ã³ãããå ŽåãåŸãããçµ
æç©ããªã«ãœã¯ããããšããŒã«ã«35âã§æº¶è§£ããª
ãäžæº¶è§£ç©ãå®è³ªçã«çããããšãªããäžã€ãŸã
ããªãšã¹ãã«ã®æ¥µéç²åºŠãηããèããäœäžããª
ãããšãå¿ èŠã§ããããã€ãŠãåå¿æ§ã®é«ããšã¹
ãã«åœ¢ææ§å®èœåºïŒäŸãã°åå¿æ§ã®é«ããšã¹ã
ã«ïŒåå¿æ§ã®é«ãããããã·ã«åºãåå¿æ§ã®é«ã
ã«ã«ããã·ã«åºçïŒãå«ãŸããååç©ãæŽã«ã¯ã
ãªãšã¹ãã«ã®æº¶è枩床ã§å解ããããã¬ã¹åãã
ãããååç©ã¯ãã¬ã³ãçšååç©ãšããŠå¥œãŸãã
ãªããåŸã€ãŠã¬ã¹åã®ç¹ããã¯ããªãšã¹ãã«ã®æº¶
è枩床ã§ãã®èžæ°å§ã100mmïœä»¥äžãæŽã«ã¯50
mmïœä»¥äžãç¹ã«10mmïœä»¥äžã®ååç©ã奜ãŸã
ãã äžèšäžè¬åŒ(i)ã§ç€ºãããåºãå«æããååç©(A)
ã®å ·äœäŸã以äžã«ãããã å ãããªãšã¹ãã«ãšå ±éåããããå Žåã«ã€ã
ãŠã§ãããããããååç©ã®å¥œãŸãããã®ãšããŠ
ã¯äžè¬åŒ(iii) ã§è¡šããããååç©ãåã³è©²ååç©ã®ãšã¹ãã«åœ¢
ææ§èªå°äœãäŸç€ºããããåèšäžè¬åŒ(iii)ã«ãã
ãŠãR4ïŒR5ïŒR6åã³R7ã¯æ°ŽçŽ åååã¯ææ©åºã§
ããããã®ææ©åºã®äŸãšããŠã¯èèªæåºã奜ãŸã
ãã¯C1ãC6ã®ã¢ã«ãã«åºãäžå±€å¥œãŸããã¯C1ã
C3ã®ã¢ã«ãã«åºïŒèèªæåºã奜ãŸããã¯C5ãC12
ã®ã·ã¯ãã¢ã«ãã«åºçããããããããŸãã
R4ïŒR5ïŒR6åã³R7ã¯
ãã¯ãèç±æ§ãéææ§åã³èè¬åæ§ã«åªããããª
ãšã¹ãã«ææãããªã容åšã®è£œé æ³ã«é¢ãããã®
ã§ããã ããªãšã¹ãã«ãæ®ã«ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãã¯ç±å¯å¡æ§ã§ããããã«æº¶èæ圢ãå¯èœã§ãã
ã€ã«ã ãã·ãŒãç¶ã«è£œé ããããããã«äŸãã°é£²
é£åãå粧åãå»è¬åçã®å®¹åšåãã«ã¯å¥œé©ã«æ
æã®åœ¢ç¶ã«äºæ¬¡æ圢ãããããšã¯ããç¥ãããŠã
ãããããããªãšã¹ãã«ã¯äžè¬ã«æº¶èæ圢ã«ãã
åŒåŒµãè¡æçã®æ©æ¢°ç匷床ãéæ床ãèè¬åæ§ç
ã®ããããç¹æ§ãçºçŸã§ãããšãã倧ããªç¹åŸŽã
æãããããããªããã溶èæŒãåºããããããª
ãšã¹ãã«ã®ã·ãŒããæ·±çµãæ圢ããŠåŸããã容åš
ã¯ãé«æž©æã®åçž®ãããããèç±æ§ãäžååã§ã
ãããšãææãããŠãããäŸãã°ããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒãã®ãã€ã«ã åã¯ã·ãŒãããæ·±çµãã§
補é ããã容åšã®å Žåã«ã¯65âã§åçž®ããŠããŸ
ããé«æž©ã§ã®äœ¿çšãã§ããªãæ¬ ç¹ãæããã æ¬çºæè ã¯ãããæ¬ ç¹ã«éã¿éææ€èšã®çµæã
ç±çã«å®å®ãªæ¶æ©å€åã³æ¶æ©åå¿å©å€ã䜿çšããŠ
ããªãšã¹ãã«ããã€ã«ã åã¯ã·ãŒããšããåŸæ¶æ©
åå¿ãèµ·ãããããšããç°¡åãªæ¹æ³ã§æ圢å å·¥æ§
ãæªãããããšãªããèç±æ§ãéææ§åã³èè¬å
æ§ã«åªããããªãšã¹ãã«å®¹åšã補é ããããšãèŠ
ãåºããæ¬çºæã«è³ã€ãã ããªãã¡ãæ¬çºæã¯ç·ç¶ããªãšã¹ãã«ã®ã·ãŒã
åã¯ãã€ã«ã ã該ãã€ã«ã åã¯ã·ãŒãã®äºæ¬¡è»¢ç§»
枩床以äžã®æž©åºŠã«å ç±ããæ·±çµãæ圢ããŠããªãš
ã¹ãã«å®¹åšã補é ããæ¹æ³ã«ãããŠã該ç·ç¶ããª
ãšã¹ãã«ãšããŠããªããŒ100ïœåœã0.01ã0.5åœé
ã®ç·ç¶ããªãšã¹ãã«ã®æº¶èæ¡ä»¶äžã§å®è³ªçã«å®å®
ã§ããèèªæç³»äžé£œååºãšããªããŒ100éééšåœ
ã0.01ã20éééšã®æ¶æ©åå¿å©å€ãšãå«æããã
ãç·ç¶ããªãšã¹ãã«ãçšããäžã€ã·ãŒãåã¯ãã€
ã«ã æ圢以éã®ä»»æã®æ®µéã§è©²ã·ãŒãåã¯ãã€ã«
ã ã«æŽ»æ§ç·ãç §å°ãæ¶æ©åå¿ãèµ·ããããããšã
ç¹åŸŽãšãããªã«ãœã¯ããããšããŒã«äžæº¶è§£å10é
éïŒ ä»¥äžã®æ¶æ©åºŠãæãäžã€éæãªããªãšã¹ãã«
容åšã®è£œé æ³ã§ããã æ¬çºæã«ãããç·ç¶ããªãšã¹ãã«ã¯ã飜åãžã«
ã«ãã³é žé¡ã®äžã€åã¯ãã以äžãšé£œåãžãªãŒã«é¡
ã®äžã€åã¯ãã以äžãšãçµåãããŠéçž®åããã
æ§é ããäž»ãšããŠãªãé«ååç¶ããªããŒãåã¯é£œ
åãªãã·é žé¡ã®äžã€åã¯ãã以äžãéçž®åããã
æ§é ãæããé«ååç¶ããªããŒããããåèšé£œå
ãžã«ã«ãã³é žé¡ãšããŠã¯ããã¬ãã¿ã«é žïŒã€ãœã
ã¿ã«é žïŒã¡ãã«ãã¬ãã¿ã«é žïŒã¡ãã«ã€ãœãã¿ã«
é žïŒããã¿ã¬ã³ãžã«ã«ãã³é žïŒãžããšãã«ãžã«ã«
ãã³é žïŒãžããšããã·ãšã¿ã³ãžã«ã«ãã³é žïŒãžã
ãšãã«ãšãŒãã«ãžã«ã«ãã³é žçã®åŠãè³éŠæãžã«
ã«ãã³é žïŒã³ãã¯é žïŒã¢ãžãã³é žïŒã»ããã³é žïŒ
ããã«ã³ãžã«ã«ãã³é žçã®åŠãèèªæãžã«ã«ãã³
é žïŒãããµããããã¬ãã¿ã«é žã®åŠãèç°æãžã«
ã«ãã³é žçãäŸç€ºããããšãã§ããããŸã飜åãž
ãªãŒã«é¡ãšããŠã¯ããšãã¬ã³ã°ãªã³ãŒã«ïŒãžãšã
ã¬ã³ã°ãªã³ãŒã«ïŒããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒã
ãªãã³ãã«ã°ãªã³ãŒã«ïŒãããµã¡ãã¬ã³ã°ãªã³ãŒ
ã«ïŒãã«ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒã·ã¯ããããµã³ãž
ã¡ãããŒã«ïŒïŒïŒïŒâãã¹ïŒÎ²âããããã·ãšã
ãã·ããšãã«ïŒãããã³ïŒãã€ããããã³ïŒïŒïŒ
ïŒâãã¹ïŒããããã·ããšãã«ïŒãããã³çãäŸ
瀺ããããæŽã«ãŸã飜åãªãã·é žé¡ãšããŠã¯ãε
âãªãã·ã«ããã³é žïŒãªãã·å®æ¯éŠé žïŒãããã
ã·ãšããã·å®æ¯éŠé žçãäŸç€ºãããã ãããé žæååã³ãžãªãŒã«æåããåŸãããç·
ç¶ããªãšã¹ãã«ã®å ·äœäŸãšããŠã¯ãäŸãã°ããªãš
ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒããªããã¬ã³ãã¬ãã¿ã¬
ãŒãïŒããªãšãã¬ã³ããã¿ã¬ãŒãçãæããäºã
åºæ¥ãã äžèšã®ç·ç¶ããªãšã¹ãã«ã¯ããã®è£œé æ³ãšããŠ
ãžã«ã«ãã³é žãçšããçŽæ¥éåæ³ããããã¯è©²ãž
ã«ã«ãã³é žã®ãšã¹ãã«ãã©ã¯ãã³çã®åŠããªãã·
ã«ã«ãã³é žã®èªå°äœãçšãã亀æåå¿æ³çã«ãã
éåæ³ãæããããããå®è³ªçã«ç·ç¶ããªãšã¹ã
ã«ã®ååŠæ§é ãæããã°ããã補é æ³ã®äœåŠãå
ããªããã®ã§ããããŸãããããŠè£œé ããããç·
ç¶ããªãšã¹ãã«ã¯éåäœã®æ¥µéç²åºŠãηããšããŠ
ã¯0.3以äžãæŽã«ã¯0.5以äžã§ããããšã奜ãŸã
ãã æ¬çºæã«ãããŠãäžè¿°ã®ããªãšã¹ãã«ã«ã該ã
ãªãšã¹ãã«ã®æº¶èæ¡ä»¶äžå®è³ªçã«å®å®ãªèèªæç³»
äžé£œååºãå«æããããæ¹æ³ãšããŠã¯ãéåžžã該
èèªæç³»äžé£œååºãšå°ããšãïŒåã®ãšã¹ãã«åœ¢æ
æ§å®èœåºãæããååç©ãæ¶æ©å€ãšããŠå ±éåã
ãããæ¹æ³åã³ïŒåã¯è©²èèªæç³»äžé£œååºãå°ã
ãšãïŒåæããååç©ããã¬ã³ãããããæ¹æ³ãš
ãçšãããããããã§ããªãšã¹ãã«ã®æº¶èæ¡ä»¶äž
å®è³ªçã«å®å®ã§ããããšã¯ãããªãšã¹ãã«ã®æº¶è
ãã枩床äŸãã°ããªãšã¹ãã«ã®èç¹ãã20âé«ã
枩床ã§äžæŽ»æ§ã¬ã¹äžäŸãã°çŽ15åéä¿æããå Žå
èèªæç³»äžé£œååºåå¿æãã¯äžé£œååºãšããªãšã¹
ãã«ãšã®åå¿çãèµ·ãããäžé£œååºãå®å®ã«ååš
ããããšãæå³ããããããæ¡ä»¶ãæºè¶³ããèèª
æç³»äžé£œååºãšããŠã¯éå ±åœ¹ã®èèªæç³»äžé£œååº
ã奜ãŸãããç¹ã«äžèšäžè¬åŒ(i) ã§è¡šããããäºéçµåã«å¯Ÿãαäœã®ççŽ ã«æ°ŽçŽ å
åãå°ããšãïŒåæããéå ±åœ¹ç³»ã®åºãäŸãã°ã¢
ãªã«åºïŒçœ®æã¢ãªã«åºçã奜ãŸããã äžèšäžè¬åŒ(i)ã§è¡šããããåºã«ãããŠãçµåæ
(a)ïŒ(b)ïŒ(c)åã³(d)ã¯æ°ŽçŽ åååã¯ææ©åºãšçµåã
ãŠãããçµåæ(e)ã¯ææ©åºãšçµåããŠããã(a)ïŒ
(b)ïŒ(c)ïŒ(d)åã³(e)ã®çµåæãšçµåããŠããææ©åº
ã¯ç¬ç«ããŠãããããŸãäºãã«çµåããŠç°æ§é ã
圢æããŠããŠãè¯ããç°æ§é ã圢æããå ŽåãåŒ
(i)äžã®äºéçµåã¯ç°æ§é ã®äžéšãæ§æããããšã
å¯èœã§ããããã®éãã®ç°æ§é ã¯èç°ãè€çŽ ç°ç
ã®ç°æ§é ã§ããããããè³éŠæ žã圢æããããšã¯
ãªãã äžèšäžè¬åŒ(i)ã§è¡šããããåºã®æŽã«å¥œãŸããæ§
é ã¯äžèšäžè¬åŒ(ii)ã§è¡šããããã ãäœãåŒäžãR1ïŒR2åã³R3ã¯ãåäžãããã¯
ç°ã€ãŠãããããæ°ŽçŽ åååã³ææ©åºãããªã矀
ããéžã°ããã¡ã³ããŒã瀺ããã åèšäžè¬åŒ(ii)äžãR1ïŒR2åã³R3ã«ã€ããŠãæ
æ©åºã®å¥œãŸããäŸãšããŠã¯ãC1ãC6ã®ã¢ã«ã
ã«ãäžå±€å¥œãŸããã¯C1ãC3ã®ã¢ã«ãã«ãæãã
ããšãã§ãããåŒ(ii)ã§è¡šããããåºãããªãã¡ã¢
ãªã«è¥ããã¯çœ®æã¢ãªã«äžå¥œãŸãããã®ã¯ãã¢ãª
ã«ïŒã¡ã¿ã¢ãªã«åã³ã¯ããã«åºã§ãããç¹ã«å¥œãŸ
ãããã®ã¯ã¢ãªã«åºã§ããã ãããèèªæç³»äžé£œååºãããªãšã¹ãã«äžã«å«
æããããããšã¯è©²èèªæç³»äžé£œååºãæããå
åç©(A)ããããªãšã¹ãã«ã«å ±éååã³ïŒåã¯æ··å
ããããããšã«ãã€ãŠã§ããã該ååç©(A)ãããª
ãšã¹ãã«ã«å ±éåããããå Žåã«ã¯ã該ååç©(A)
ã¯ãå ±éåæ¡ä»¶äžã§å解ãªã©ãçããããšãªãå®
å®ã§ããå¿ èŠãããããŸãè©²å ±éåæ¡ä»¶äžã§å®å®
ãªèèªæç³»äžé£œååºã®ä»ã«ãšã¹ãã«åœ¢ææ§å®èœåº
ïŒäŸãã°ã«ã«ããã·ã«åºïŒæ°Žé žåºçïŒãªããã¯ã
ãªãšã¹ãã«ã®éåæ¡ä»¶äžã§è©²ãšã¹ãã«åœ¢æå®èœåº
ãçæãããããªå®èœåºãå°ããšãïŒåã奜ãŸã
ãã¯ïŒåæããŠããå¿ èŠããããåŸè ã®å®èœåºãš
ããŠã¯ãšããã·åºãäŸç€ºããããšãã§ããããŸã
ååç©(A)ãããªãšã¹ãã«ã«é åããå Žåã«ã¯ã該
ååç©(A)äžã®èèªæç³»äžé£œååºãããªãšã¹ãã«ãš
ã®æº¶èæ··ç·Žäžã§å®å®ã§ããããšã¯å¿è«ã®ããšã該
ååç©(A)èªèº«ãå®å®ã§ããããšã奜ãŸãããåŸã€
ãŠååç©(A)ã溶èãã¬ã³ãããå ŽåãåŸãããçµ
æç©ããªã«ãœã¯ããããšããŒã«ã«35âã§æº¶è§£ããª
ãäžæº¶è§£ç©ãå®è³ªçã«çããããšãªããäžã€ãŸã
ããªãšã¹ãã«ã®æ¥µéç²åºŠãηããèããäœäžããª
ãããšãå¿ èŠã§ããããã€ãŠãåå¿æ§ã®é«ããšã¹
ãã«åœ¢ææ§å®èœåºïŒäŸãã°åå¿æ§ã®é«ããšã¹ã
ã«ïŒåå¿æ§ã®é«ãããããã·ã«åºãåå¿æ§ã®é«ã
ã«ã«ããã·ã«åºçïŒãå«ãŸããååç©ãæŽã«ã¯ã
ãªãšã¹ãã«ã®æº¶è枩床ã§å解ããããã¬ã¹åãã
ãããååç©ã¯ãã¬ã³ãçšååç©ãšããŠå¥œãŸãã
ãªããåŸã€ãŠã¬ã¹åã®ç¹ããã¯ããªãšã¹ãã«ã®æº¶
è枩床ã§ãã®èžæ°å§ã100mmïœä»¥äžãæŽã«ã¯50
mmïœä»¥äžãç¹ã«10mmïœä»¥äžã®ååç©ã奜ãŸã
ãã äžèšäžè¬åŒ(i)ã§ç€ºãããåºãå«æããååç©(A)
ã®å ·äœäŸã以äžã«ãããã å ãããªãšã¹ãã«ãšå ±éåããããå Žåã«ã€ã
ãŠã§ãããããããååç©ã®å¥œãŸãããã®ãšããŠ
ã¯äžè¬åŒ(iii) ã§è¡šããããååç©ãåã³è©²ååç©ã®ãšã¹ãã«åœ¢
ææ§èªå°äœãäŸç€ºããããåèšäžè¬åŒ(iii)ã«ãã
ãŠãR4ïŒR5ïŒR6åã³R7ã¯æ°ŽçŽ åååã¯ææ©åºã§
ããããã®ææ©åºã®äŸãšããŠã¯èèªæåºã奜ãŸã
ãã¯C1ãC6ã®ã¢ã«ãã«åºãäžå±€å¥œãŸããã¯C1ã
C3ã®ã¢ã«ãã«åºïŒèèªæåºã奜ãŸããã¯C5ãC12
ã®ã·ã¯ãã¢ã«ãã«åºçããããããããŸãã
R4ïŒR5ïŒR6åã³R7ã¯
ãåŒãã§ã
ã€ãŠãããããŸãäºãã«æãã¯ïŒ±è¥ããã¯Qâ²ãš
çµåããŠããŠãè¯ããäžèšïŒ±åã³Qâ²ã¯çŽæ¥çµå
ãæãã¯ïŒäŸ¡ä»¥äžã®ææ©åºã奜ãŸããã¯ïŒäŸ¡ä»¥äž
ã®C1ãC20ã®èèªæåºãïŒäŸ¡ä»¥äžã®C4ãC20ã®è
èªæåºãïŒäŸ¡ä»¥äžã®C6ãC12ã®è³éŠæåºè¥ããã¯
ïŒäŸ¡ä»¥äžã®è€çŽ ç°ãæããåºã瀺ããæŽã«R8å
ã³R9ã¯R4ãR7ãšåãåºããšããR4ãR7ã®å¥œãŸã
ããã®ãšããŠã¯ãæ°ŽçŽ åååã¯ãã¡ãã«åã¯
çµåããŠããŠãè¯ããäžèšïŒ±åã³Qâ²ã¯çŽæ¥çµå
ãæãã¯ïŒäŸ¡ä»¥äžã®ææ©åºã奜ãŸããã¯ïŒäŸ¡ä»¥äž
ã®C1ãC20ã®èèªæåºãïŒäŸ¡ä»¥äžã®C4ãC20ã®è
èªæåºãïŒäŸ¡ä»¥äžã®C6ãC12ã®è³éŠæåºè¥ããã¯
ïŒäŸ¡ä»¥äžã®è€çŽ ç°ãæããåºã瀺ããæŽã«R8å
ã³R9ã¯R4ãR7ãšåãåºããšããR4ãR7ã®å¥œãŸã
ããã®ãšããŠã¯ãæ°ŽçŽ åååã¯ãã¡ãã«åã¯
ãåŒãïŒããã§R8åã³R9ã¯å€«ã
æ°ŽçŽ åååã¯ã¡ãã«ïŒããããããç¹ã«å¥œãŸãã
ã¯æ°ŽçŽ åååã¯
ã¯æ°ŽçŽ åååã¯
ãåŒããæãã
ãã
å°ãäžèšäžè¬åŒ(iii)äžãïœïŒïœïŒnâ²åã³mâ²ã¯ïŒ
åã¯ïŒä»¥äžã®æ°ã§ãããïœã¯ïŒä»¥äžã®æ°ã§ããã
æŽã«ïœïŒïœâ§ïŒã奜ãŸããã¯ïœïŒïœïŒïœïŒnâ²ïŒ
mâ²ïŒïŒïŒã§ããã äžè¿°ããæãããªããã«ãåèšäžè¬åŒ(iii)ã§è¡šã
ãããååç©ã¯âOHåã³ïŒåã¯âCOOHãå°ã
ãšãïŒåã奜ãŸããã¯ïŒåæãããã®ã§ããã ãããååç©ãšããŠã¯ãäŸãã°ïŒâïŒåã¯ïŒ
âïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ãã³é žïŒïŒâ
ïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ãã³
é žïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ãã«ïŒïŒïŒ
âãžã«ã«ãã³é žïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãž
ã«ã«ãã³é žïŒïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ãã³é žïŒïŒâããã³ïŒïŒïŒâïŒåã¯ïŒïŒïŒ
âïŒãžã«ã«ãã³é žïŒïŒâããã³ïŒïŒïŒâãžã«ã«ã
ã³é žïŒïŒâã·ã¯ãããã»ãã«ãšã¿ã³ïŒïŒïŒâãžã«
ã«ãã³é žïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒâãã³ã
ã³âïŒïŒïŒâãžã«ã«ãã³é žïŒã¢ãªã«ãªãã·ïŒåã¯
ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¯ããã«ãªãã·ïŒå®æ¯éŠ
é žïŒïŒâã¢ãªã«âïŒâãªãã·å®æ¯éŠé žïŒïŒâïŒå
ã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ãã³é žïŒïŒ®âã¢ãªã«
ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒããªã¡ãªããé ž
ã€ããçã®åŠãã«ã«ãã³é žé¡åã³ãªãã·ã«ã«ãã³
é žé¡ã䞊ã³ã«ãããã®ãšã¹ãã«åœ¢ææ§èªå°äœïŒäŸ
ãã°ã¡ãã«ïŒãšãã«ïŒãããã«ã®åŠãäœçŽã¢ã«ã
ã«ã®ãšã¹ãã«ïŒããšãã«ãšã¹ãã«ã®åŠãã¢ãªãŒã«
ãšã¹ãã«ïŒé žç¡æ°Žç©çïŒïŒïŒâïŒåã¯ïŒâïŒã·ã¯
ãããã»ã³ïŒïŒïŒâãžã¡ã¿ããŒã«ïŒïŒâïŒåã¯ïŒ
âåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ã¿ããŒ
ã«ïŒïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãž
ã¡ã¿ããŒã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžãªãŒ
ã«ïŒïŒâããã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâïŒïŒâã
ããã«ïŒãããã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâãã³ã
ã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâããã»ã³âïŒâã¡ãã«
ïŒïŒïŒâãžãªãŒã«ïŒïŒâããã³âïŒïŒïŒâãžã¡ã
ã«ïŒïŒïŒâãžãªãŒã«ïŒïŒâã¢ãªã«ãªãã·ããšããŒ
ã«ïŒïŒïŒïŒâãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãž
ã¯ããã«ïŒâïŒïŒïŒâãžãªãã·ãã³ãŒã³ïŒïŒïŒïŒ
âãã¹ãïŒâã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ãã
ã«ïŒâïŒâããããã·ããšãã«ããããã³ïŒãã¹
ïŒïŒâã¢ãªã«âïŒããããã·ããšãã«ïŒã¹ã«ã
ã³ïŒïŒïŒïŒâãã¹ãïŒâã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«
åã¯ã¯ããã«ïŒâïŒâããããã·ãšããã·ããšã
ã«ããããã³ïŒãã¹ïŒïŒâã¢ãªã«âïŒâãããã
ã·ãšããã·ããšãã«ïŒã¹ã«ãã³ã¢ãªã«âãã¹ïŒÎ²
âããããã·ãšãã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒïŒ®ïŒïŒ®
ãžã¢ãªã«âïŒâãªãã·ãã³ãºã¢ããçã®åŠããã
ããã·ååç©é¡ã䞊ã³ã«ãããã®ãšã¹ãã«åœ¢ææ§
èªå°äœïŒäŸãã°äœçŽèèªé žãšã¹ãã«ïŒãªã©ãæã
ãããã æŽã«ãããªãšã¹ãã«ã®éåæ¡ä»¶äžã§åèšäžè¬åŒ
(iii)ã§è¡šããããååç©ã«å€åããå ±éåå¯èœãªå
åç©ãšãªããã®ã®å¥œãŸããäŸãšããŠããã¹ã¢ãªã«
ãªãã·ïŒåã¯ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¡ã¿ã¯ããã«
ãªãã·ïŒãã³ãŒã³ïŒïŒïŒïŒâãã¹ãïŒâã¢ãªã«ãª
ãã·ïŒåã¯ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¯ããã«ãªã
ã·ïŒããšãã«ããããã³ïŒïŒïŒïŒâãã¹ïŒïŒâã¢
ãªã«ãªãã·ããšãã«ïŒã·ã¯ããããµã³ïŒãã¹ïŒïŒ
âã¢ãªã«ãªãã·ããšãã«ïŒã¹ã«ãã³çãæããã
ãã 次ã«ããªãšã¹ãã«ãšãã¬ã³ãå¯èœãªèèªæç³»äž
飜ååºãæããååç©ãšããŠã¯ãåèšäžè¬åŒ(i)ã§
è¡šããããåºãïŒå以äžæããŠãããã®ããåŸè¿°
ãã掻æ§ç·åŠçã«ãããŠããã匷åºãªæ¶æ©æ§é ã
æ圢äœäžã«åŸãããã®ã§å¥œãŸããããã®æ§ãªåå
ç©ãšããŠã¯äžèšã®åŠãååç©ãäŸç€ºãããã ïŒïŒ ã¢ããçµååã³ïŒåã¯ã€ããçµåãæã
ãååç©ïŒ (1) äžèšåŒ(iv)ã§è¡šããããååç©ã Q1ïœïŒžïŒQâ²1AïŒnâ³ïœoâ³ âŠâŠ(iv) äœãåŒ(iv)äžã«ãããŠã ã¯ïŒåèšåŒ(i)ã§è¡šããããæ§é ãæããïŒäŸ¡
ã®åºïŒå¥œãŸããã¯åèšåŒ(ii)ã§è¡šããããã¢ãªã«åº
åã¯çœ®æã¢ãªã«åºïŒ ã¯ïŒâCONR11ïŒããã§R11ã¯æ°ŽçŽ ååãã
ãã¯C1ãC5ã®ã¢ã«ãã«åºïŒïŒ
åã¯ïŒä»¥äžã®æ°ã§ãããïœã¯ïŒä»¥äžã®æ°ã§ããã
æŽã«ïœïŒïœâ§ïŒã奜ãŸããã¯ïœïŒïœïŒïœïŒnâ²ïŒ
mâ²ïŒïŒïŒã§ããã äžè¿°ããæãããªããã«ãåèšäžè¬åŒ(iii)ã§è¡šã
ãããååç©ã¯âOHåã³ïŒåã¯âCOOHãå°ã
ãšãïŒåã奜ãŸããã¯ïŒåæãããã®ã§ããã ãããååç©ãšããŠã¯ãäŸãã°ïŒâïŒåã¯ïŒ
âïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ãã³é žïŒïŒâ
ïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ãã³
é žïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ãã«ïŒïŒïŒ
âãžã«ã«ãã³é žïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãž
ã«ã«ãã³é žïŒïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ãã³é žïŒïŒâããã³ïŒïŒïŒâïŒåã¯ïŒïŒïŒ
âïŒãžã«ã«ãã³é žïŒïŒâããã³ïŒïŒïŒâãžã«ã«ã
ã³é žïŒïŒâã·ã¯ãããã»ãã«ãšã¿ã³ïŒïŒïŒâãžã«
ã«ãã³é žïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒâãã³ã
ã³âïŒïŒïŒâãžã«ã«ãã³é žïŒã¢ãªã«ãªãã·ïŒåã¯
ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¯ããã«ãªãã·ïŒå®æ¯éŠ
é žïŒïŒâã¢ãªã«âïŒâãªãã·å®æ¯éŠé žïŒïŒâïŒå
ã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ãã³é žïŒïŒ®âã¢ãªã«
ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒããªã¡ãªããé ž
ã€ããçã®åŠãã«ã«ãã³é žé¡åã³ãªãã·ã«ã«ãã³
é žé¡ã䞊ã³ã«ãããã®ãšã¹ãã«åœ¢ææ§èªå°äœïŒäŸ
ãã°ã¡ãã«ïŒãšãã«ïŒãããã«ã®åŠãäœçŽã¢ã«ã
ã«ã®ãšã¹ãã«ïŒããšãã«ãšã¹ãã«ã®åŠãã¢ãªãŒã«
ãšã¹ãã«ïŒé žç¡æ°Žç©çïŒïŒïŒâïŒåã¯ïŒâïŒã·ã¯
ãããã»ã³ïŒïŒïŒâãžã¡ã¿ããŒã«ïŒïŒâïŒåã¯ïŒ
âåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ã¿ããŒ
ã«ïŒïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãž
ã¡ã¿ããŒã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžãªãŒ
ã«ïŒïŒâããã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâïŒïŒâã
ããã«ïŒãããã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâãã³ã
ã³ïŒïŒïŒâãžãªãŒã«ïŒïŒâããã»ã³âïŒâã¡ãã«
ïŒïŒïŒâãžãªãŒã«ïŒïŒâããã³âïŒïŒïŒâãžã¡ã
ã«ïŒïŒïŒâãžãªãŒã«ïŒïŒâã¢ãªã«ãªãã·ããšããŒ
ã«ïŒïŒïŒïŒâãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãž
ã¯ããã«ïŒâïŒïŒïŒâãžãªãã·ãã³ãŒã³ïŒïŒïŒïŒ
âãã¹ãïŒâã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ãã
ã«ïŒâïŒâããããã·ããšãã«ããããã³ïŒãã¹
ïŒïŒâã¢ãªã«âïŒããããã·ããšãã«ïŒã¹ã«ã
ã³ïŒïŒïŒïŒâãã¹ãïŒâã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«
åã¯ã¯ããã«ïŒâïŒâããããã·ãšããã·ããšã
ã«ããããã³ïŒãã¹ïŒïŒâã¢ãªã«âïŒâãããã
ã·ãšããã·ããšãã«ïŒã¹ã«ãã³ã¢ãªã«âãã¹ïŒÎ²
âããããã·ãšãã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒïŒ®ïŒïŒ®
ãžã¢ãªã«âïŒâãªãã·ãã³ãºã¢ããçã®åŠããã
ããã·ååç©é¡ã䞊ã³ã«ãããã®ãšã¹ãã«åœ¢ææ§
èªå°äœïŒäŸãã°äœçŽèèªé žãšã¹ãã«ïŒãªã©ãæã
ãããã æŽã«ãããªãšã¹ãã«ã®éåæ¡ä»¶äžã§åèšäžè¬åŒ
(iii)ã§è¡šããããååç©ã«å€åããå ±éåå¯èœãªå
åç©ãšãªããã®ã®å¥œãŸããäŸãšããŠããã¹ã¢ãªã«
ãªãã·ïŒåã¯ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¡ã¿ã¯ããã«
ãªãã·ïŒãã³ãŒã³ïŒïŒïŒïŒâãã¹ãïŒâã¢ãªã«ãª
ãã·ïŒåã¯ã¡ã¿ã¢ãªã«ãªãã·åã¯ã¯ããã«ãªã
ã·ïŒããšãã«ããããã³ïŒïŒïŒïŒâãã¹ïŒïŒâã¢
ãªã«ãªãã·ããšãã«ïŒã·ã¯ããããµã³ïŒãã¹ïŒïŒ
âã¢ãªã«ãªãã·ããšãã«ïŒã¹ã«ãã³çãæããã
ãã 次ã«ããªãšã¹ãã«ãšãã¬ã³ãå¯èœãªèèªæç³»äž
飜ååºãæããååç©ãšããŠã¯ãåèšäžè¬åŒ(i)ã§
è¡šããããåºãïŒå以äžæããŠãããã®ããåŸè¿°
ãã掻æ§ç·åŠçã«ãããŠããã匷åºãªæ¶æ©æ§é ã
æ圢äœäžã«åŸãããã®ã§å¥œãŸããããã®æ§ãªåå
ç©ãšããŠã¯äžèšã®åŠãååç©ãäŸç€ºãããã ïŒïŒ ã¢ããçµååã³ïŒåã¯ã€ããçµåãæã
ãååç©ïŒ (1) äžèšåŒ(iv)ã§è¡šããããååç©ã Q1ïœïŒžïŒQâ²1AïŒnâ³ïœoâ³ âŠâŠ(iv) äœãåŒ(iv)äžã«ãããŠã ã¯ïŒåèšåŒ(i)ã§è¡šããããæ§é ãæããïŒäŸ¡
ã®åºïŒå¥œãŸããã¯åèšåŒ(ii)ã§è¡šããããã¢ãªã«åº
åã¯çœ®æã¢ãªã«åºïŒ ã¯ïŒâCONR11ïŒããã§R11ã¯æ°ŽçŽ ååãã
ãã¯C1ãC5ã®ã¢ã«ãã«åºïŒïŒ
ãåŒãïŒãã
ã§ãR11ã¯äžèšã®éãã§ãäºã€ã®R11ã¯åäžã§ãç°
ã€ãŠããŠãããïŒåã³ââãããªã矀ããéžã°
ããã¡ã³ããŒïŒ Q1ã¯ïŒC2ãC20ã®ïŒãïŒäŸ¡ã®èèªæåºãC4ã
C12ã®ïŒãïŒäŸ¡ã®èèªæåºã
ã€ãŠããŠãããïŒåã³ââãããªã矀ããéžã°
ããã¡ã³ããŒïŒ Q1ã¯ïŒC2ãC20ã®ïŒãïŒäŸ¡ã®èèªæåºãC4ã
C12ã®ïŒãïŒäŸ¡ã®èèªæåºã
ãåŒãïŒãã
ã§R12ã¯æ°ŽçŽ ååãC6ãC12ã®ã¢ãªãŒã«åºãC1ã
C6ã®ã¢ã«ãã«åºãC1ãC6ã®ã¢ã«ãã«ãªãã·åºã
ãããåºãããã¯ããã²ã³ååïŒãããªãïŒãïŒ
䟡ã®åºã
C6ã®ã¢ã«ãã«åºãC1ãC6ã®ã¢ã«ãã«ãªãã·åºã
ãããåºãããã¯ããã²ã³ååïŒãããªãïŒãïŒ
䟡ã®åºã
ãåŒãïŒããã§R12ã¯äž
èšã®éãïŒãããªãïŒãïŒäŸ¡ã®åºåã³
ãåŒããããã§ïŒ¹ã¯ââïŒâ
COâïŒâSO2âïŒâNR11âïŒäœãR11ã¯äžèšãšå
æ§ïŒïŒâïŒCH2CH2ïŒlâ²OâïŒäœãlâ²ã¯ïŒãïŒã®æŽ
æ°ïŒãC2ãC12ã®ã¢ã«ãã¬ã³ãããªã矀ããéžã°
ããã¡ã³ããŒããããªãïŒãïŒäŸ¡ã®åºãããªã矀
ããéžã°ããåºãäžèšã«ãããŠïŒžãââã®å Žå
ã«ã¯Q1ã¯äžèšèèªæåºãããã¯èç°æåºã§ãã
ããšã奜ãŸãããå°ãäžèšèèªæåºãšããŠã¯C2
ãC20ã®ã¢ã«ãã¬ã³åºãåèšäžè¬åŒ(i)ã§è¡šããã
ãæ§é ãæããïŒäŸ¡ã®ãªã¬ãã€ã³æ®åº
æ§ïŒïŒâïŒCH2CH2ïŒlâ²OâïŒäœãlâ²ã¯ïŒãïŒã®æŽ
æ°ïŒãC2ãC12ã®ã¢ã«ãã¬ã³ãããªã矀ããéžã°
ããã¡ã³ããŒããããªãïŒãïŒäŸ¡ã®åºãããªã矀
ããéžã°ããåºãäžèšã«ãããŠïŒžãââã®å Žå
ã«ã¯Q1ã¯äžèšèèªæåºãããã¯èç°æåºã§ãã
ããšã奜ãŸãããå°ãäžèšèèªæåºãšããŠã¯C2
ãC20ã®ã¢ã«ãã¬ã³åºãåèšäžè¬åŒ(i)ã§è¡šããã
ãæ§é ãæããïŒäŸ¡ã®ãªã¬ãã€ã³æ®åº
ãåŒãçã奜ãŸããããŸãèç°æ
åºãšããŠã¯
ãåŒããããªãïŒãïŒäŸ¡ã®åº
ãåŒããããªãïŒãïŒäŸ¡ã®åº
ãåŒããããªã
ïŒãïŒäŸ¡ã®åºçã奜ãŸããäŸç€ºã§ããïŒ
Qâ²1ã¯ïŒçŽæ¥çµååã¯åèšQ1äžã®ïŒäŸ¡ä»¥äžã®åº
ã§ããã奜ãŸããã¯çŽæ¥çµååã¯C1ã5ã®ã¢ã«ã
ã¬ã³åºã§ããã mâ³åã³nâ³ã¯ïŒããããïŒãïŒã®æŽæ°ã§ãmâ³Ã
nâ³â§ïŒã§ããããšã奜ãŸããã ãã®ãããªåŒ(iv)ååç©ã®äŸãšããŠã¯ãäžèšã®åŠ
ãååç©ãäŸç€ºããããšãã§ããã ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãž
ã¯ããã«ïŒã¢ãžãã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã»ãã«ã¢ã
ãïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯
ãžã¯ããã«ïŒãã«ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒãã¬ãã¿ã©ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯
ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã€ãœãã¿ã©ããïŒ
ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯
ããã«ïŒããã¿ã¬ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒãããµããããã¬ãã¿ã©ããïŒïŒ®ïŒNâ²âãž
ã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãžã
ãšããã·ãšã¿ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒNâ²ïŒ
Nâ³âããªã¢ãªã«ïŒåã¯ããªã¡ã¿ã¢ãªã«åã¯ããª
ã¯ããã«ïŒããªã¡ã·ã³é žã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒã¢ãžãã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒã»ãã«ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒãã«ã³ãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒãã¬ãã¿ã©ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒã€ãœãã¿ã©ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒããã¿ã¬ã³ãžã«ã«
ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢
ãªã«åã¯ãžã¯ããã«ïŒãã³ãºã¢ããïŒïŒ®ïŒïŒ®ïŒ
Nâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«
åã¯ããã©ã¯ããã«ïŒãããµããããã¬ãã¿ã©ã
ãïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ãã
ã©ã¡ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒãžããšããã·
ãšã¿ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²ïŒ
Nâ³ïŒNâ³âãããµã¢ãªã«ïŒåã¯ãããµã¡ã¿ã¢ãªã«
åã¯ãããµã¯ããã«ïŒããªã¡ã·ã³é žã¢ããïŒïŒ®ïŒ
ïŒNâ²ïŒNâ²ïŒNâ³ïŒNâ³âãããµã¢ãªã«ïŒåã¯ãã
ãµã¡ã¿ã¢ãªã«åã¯ãããµã¯ããã«ïŒããªã¡ãªãã
é žã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²ïŒNâ³ïŒNâ³ïŒïŒ®ïŒïŒ®
âãªã¯ã¿ã¢ãªã«ïŒåã¯ãªã¯ã¿ã¡ã¿ã¢ãªã«åã¯ãª
ã¯ã¿ã¯ããã«ïŒããã¡ãªããé žã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒããã¡ãªããã€ããïŒïŒ®ïŒNâ²âãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãã³ãŸããš
ãã³âïŒïŒïŒïŒ3â²ïŒ4â²âããã©ã«ã«ãã³é žãã¹ã€
ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«å
ã¯ãžã¯ããã«ïŒãã¿ã³âïŒïŒïŒïŒïŒïŒïŒâããã©
ã«ã«ãã³é žãã¹ã€ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒå
ã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã·ã¯ããã³ã¿ã³
âïŒïŒïŒïŒïŒïŒïŒâããã©ã«ã«ãã³é žãã¹ã€ã
ãïŒãšãã¬ã³ãã³ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢
ãªã«åã¯ïŒ®âã¯ããã«ïŒããªã¡ãªããé žã€ããã
ã¢ããïŒããã©ã¡ãã¬ã³ãã¹ãâã¢ãªã«ïŒåã¯
âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ããã«ïŒããªã¡ãªãã
é žã€ãããã¢ããïŒãããµã¡ãã¬ã³ãã¹ãâã¢
ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ããã«ïŒã
ãªã¡ãªããé žã€ãããã¢ããïŒãã«ã¡ãã¬ã³ãã¹
ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ã
ãã«ïŒããªã¡ãªããé žã€ãããã¢ããïŒããã«ã¡
ãã¬ã³ãã¹ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«å
ã¯ïŒ®âã¯ããã«ïŒããªã¡ãªããé žã€ãããã¢ã
ãïŒ
ã§ããã奜ãŸããã¯çŽæ¥çµååã¯C1ã5ã®ã¢ã«ã
ã¬ã³åºã§ããã mâ³åã³nâ³ã¯ïŒããããïŒãïŒã®æŽæ°ã§ãmâ³Ã
nâ³â§ïŒã§ããããšã奜ãŸããã ãã®ãããªåŒ(iv)ååç©ã®äŸãšããŠã¯ãäžèšã®åŠ
ãååç©ãäŸç€ºããããšãã§ããã ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãž
ã¯ããã«ïŒã¢ãžãã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã»ãã«ã¢ã
ãïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯
ãžã¯ããã«ïŒãã«ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒãã¬ãã¿ã©ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯
ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã€ãœãã¿ã©ããïŒ
ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯
ããã«ïŒããã¿ã¬ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒãããµããããã¬ãã¿ã©ããïŒïŒ®ïŒNâ²âãž
ã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãžã
ãšããã·ãšã¿ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒNâ²ïŒ
Nâ³âããªã¢ãªã«ïŒåã¯ããªã¡ã¿ã¢ãªã«åã¯ããª
ã¯ããã«ïŒããªã¡ã·ã³é žã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒã¢ãžãã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒã»ãã«ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«åã¯
ããã©ã¯ããã«ïŒãã«ã³ãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒãã¬ãã¿ã©ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒã€ãœãã¿ã©ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡
ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒããã¿ã¬ã³ãžã«ã«
ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢
ãªã«åã¯ãžã¯ããã«ïŒãã³ãºã¢ããïŒïŒ®ïŒïŒ®ïŒ
Nâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¡ã¿ã¢ãªã«
åã¯ããã©ã¯ããã«ïŒãããµããããã¬ãã¿ã©ã
ãïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ãã
ã©ã¡ã¿ã¢ãªã«åã¯ããã©ã¯ããã«ïŒãžããšããã·
ãšã¿ã³ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²ïŒ
Nâ³ïŒNâ³âãããµã¢ãªã«ïŒåã¯ãããµã¡ã¿ã¢ãªã«
åã¯ãããµã¯ããã«ïŒããªã¡ã·ã³é žã¢ããïŒïŒ®ïŒ
ïŒNâ²ïŒNâ²ïŒNâ³ïŒNâ³âãããµã¢ãªã«ïŒåã¯ãã
ãµã¡ã¿ã¢ãªã«åã¯ãããµã¯ããã«ïŒããªã¡ãªãã
é žã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²ïŒNâ³ïŒNâ³ïŒïŒ®ïŒïŒ®
âãªã¯ã¿ã¢ãªã«ïŒåã¯ãªã¯ã¿ã¡ã¿ã¢ãªã«åã¯ãª
ã¯ã¿ã¯ããã«ïŒããã¡ãªããé žã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ãã
ã«ïŒããã¡ãªããã€ããïŒïŒ®ïŒNâ²âãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãã³ãŸããš
ãã³âïŒïŒïŒïŒ3â²ïŒ4â²âããã©ã«ã«ãã³é žãã¹ã€
ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«å
ã¯ãžã¯ããã«ïŒãã¿ã³âïŒïŒïŒïŒïŒïŒïŒâããã©
ã«ã«ãã³é žãã¹ã€ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒå
ã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã·ã¯ããã³ã¿ã³
âïŒïŒïŒïŒïŒïŒïŒâããã©ã«ã«ãã³é žãã¹ã€ã
ãïŒãšãã¬ã³ãã³ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢
ãªã«åã¯ïŒ®âã¯ããã«ïŒããªã¡ãªããé žã€ããã
ã¢ããïŒããã©ã¡ãã¬ã³ãã¹ãâã¢ãªã«ïŒåã¯
âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ããã«ïŒããªã¡ãªãã
é žã€ãããã¢ããïŒãããµã¡ãã¬ã³ãã¹ãâã¢
ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ããã«ïŒã
ãªã¡ãªããé žã€ãããã¢ããïŒãã«ã¡ãã¬ã³ãã¹
ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«åã¯ïŒ®âã¯ã
ãã«ïŒããªã¡ãªããé žã€ãããã¢ããïŒããã«ã¡
ãã¬ã³ãã¹ãâã¢ãªã«ïŒåã¯ïŒ®âã¡ã¿ã¢ãªã«å
ã¯ïŒ®âã¯ããã«ïŒããªã¡ãªããé žã€ãããã¢ã
ãïŒ
ãåŒãïŒäœãïŒã¢
ãªã«åã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒïŒïŒ®ïŒNâ²âãž
ã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒããª
ã¡ãªããé žã¢ããã€ããïŒïŒ®ïŒïŒ®ïŒNâ²âããªã¢
ãªã«ïŒåã¯ããªã¡ã¿ã¢ãªã«åã¯ããªã¯ããã«ïŒã
ãªã¡ãªããé žã¢ããã€ããïŒãšãã¬ã³ïŒåã¯ããª
ã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³
åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒïŒâãããã¬ã³ã«ã«ã
ãã·ã¢ããïŒïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯
ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ã
ã¬ã³ïŒãã¹ãïŒâïŒåã¯ïŒâïŒããã³ã«ã«ããã·
ã¢ãããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ãã
ã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬
ã³ïŒãã¹ãïŒâïŒåã¯ïŒâåã¯ïŒâããã³ãã³ã«
ã«ããã·ã¢ãããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³
åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«
ã¡ãã¬ã³ïŒãã¹ãïŒâïŒåã¯ïŒâåã¯ïŒâåã¯ïŒ
âïŒããã»ã³ã«ã«ããã·ã¢ãããïŒïŒ®âã¢ãªã«
ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒïŒâãããã¬ã³
ã«ã«ããã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«å
ã¯ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒããã³ã«ã«ãã
ã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢
ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒâïŒãããã³ã«ã«ã
ãã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿
ã¢ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒâåã¯ïŒâïŒãã
ã»ã³ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâãããã¬ã³ã«
ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¯ã
ãã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒããã³
ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¯
ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒ
âïŒãããã³ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãª
ã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒå
ã¯ïŒâåã¯ïŒâåã¯ïŒâïŒããã»ã³ã«ã«ããã·ã¢
ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯
ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâããã³ïŒïŒïŒ
âãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âãã
ã©ã¢ãªã«ïŒåã¯ããã©ã¯ããã«åã¯ããã©ã¡ã¿ãª
ã«ïŒïŒâïŒåã¯ïŒïŒããã»ã³ïŒïŒïŒâãžã«ã«ãã
ã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒå
ã¯ããã©ã¯ããã«åã¯ããã©ã¡ã¿ãªã«ïŒïŒâãã
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒãšãã¬ã³ïŒåã¯
ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ã
ã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒåã¯ïŒâïŒã·
ã¯ãããã»ã³ã«ã«ããã·ã¢ããïŒãšãã¬ã³ïŒåã¯
ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ã
ã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒåã¯ïŒâïŒã·
ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€ããïŒãšã
ã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯
ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒå
ã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€
ããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ããã©ã¡
ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒã
ã¹ïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€ã
ãïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ããã·ã¢ã
ãïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«
ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡
ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒ
ïŒâãžã«ã«ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ã
ãã«åã¯ã¡ã¿ã¢ãªã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒ
âãžã«ã«ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ãã
ã«åã¯ã¡ã¿ã¢ãªã«ïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒ
âãããã³ïŒïŒïŒâãžã«ã«ããã·ã€ããïŒïŒ®ïŒïŒ®
âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ããã·ã¢ã
ãïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ãã
ã©ã¯ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒ
âïŒã·ã¯ãããã»ã³ïŒïŒïŒãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯
ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒ
ã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯
ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâã·ã¯ãããã»
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯ããã«åã¯ã
ãã©ã¡ã¿ã¢ãªã«ïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒâ
ãããã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãª
ã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢
ããïŒ ïŒïŒ ã·ã¢ãã«é žåã¯ã€ãœã·ã¢ãã«é žã®èªå°
äœïŒ äžèšåŒ(v)åã¯(vi)ã§è¡šããããååç© äœãåŒ(v)ïŒ(vi)äžã«ãããŠè€æ°åã®Aâ²ã¯åäžã§
ãç°ã€ãŠããŠããããäžã€å°ããšãïŒã±ã¯åèšåº
ã§ãã€ãŠãæ®ãã¯åºïŒ¡ãããã¯åèšQ1äžã®äž
䟡ã®åºã§ãããQ2ã¯åèšQ1äžã®ïŒãïŒäŸ¡ã®åºã§
ãããQâ²2ã¯åèšQ1äžã®ïŒäŸ¡ã®åºã§ããããããŠ
ïœã¯ïŒåã¯ïŒã奜ãŸããã¯ïŒãïœã¯ïŒã10ã®æŽ
æ°ãïœã¯ïŒãïŒã®æŽæ°ã§ããã ãã®æ§ãªåŒ(v)ïŒ(vi)ã§ç€ºãããååç©ã®äŸãšããŠ
ã¯ãäžèšã®åŠãååç©ãäŸç€ºããããšãã§ããã ããªã¢ãªã«ïŒåã¯ããªã¯ããã«åã¯ããªã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ã
ãã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã¡ãã«ã€ãœã·ã¢ãã¬ãŒ
ãïŒãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãª
ã«ïŒãšãã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãž
ã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒãã·ã«ã€ãœã·ã¢ãã¬
ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ãã«åã¯ãžã¡ã¿ã¢ã¯ãª
ã«ïŒããã·ã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒããªã¹ãã«ã€ãœã·
ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡
ã¿ã¢ãªã«ïŒã»ãã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«
ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã¹ãã¢ãªã«
ã€ãœã·ã¢ãã¬ãŒãïŒãšãã¬ã³ãã¹ããžã¢ãªã«ïŒå
ã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒ
ããïŒããã©ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯
ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒ
ãããµã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«
åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãã«ã¡
ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡
ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãªãã·ãžãšãã¬
ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãžãªãã·ããªãšãã¬
ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããæ«ç«¯ããžã¢ãªã«ã€ãœã·
ã¢ãã¬ãŒãæ®åºã§ããããªãšãã¬ã³ã¢ãªã«ïŒåã¯
ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã€ãœã·ãã¬ãŒãïŒæ«ç«¯
ããžã¢ãªã«ã€ãœã·ã¢ãã¬ãŒãæ®åºã§ããããªãã
ã©ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ãã
ã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒæ«ç«¯ããžã¢ãªã«ã€ãœã·ã¢
ãã¬ãŒãæ®åºã§ããããªãããµã¡ãã¬ã³ã¢ãªã«
ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã€ãœã·ã¢ãã¬ãŒ
ãïŒæ«ç«¯ããžã¢ãªã«ã€ãœã·ã¢ãã¬ãŒãæ®åºã§ãã
ããªãã«ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯
ããã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒããªã¢ãªã«ïŒåã¯ã
ãªã¡ã¿ã¢ãªã«åã¯ããªã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒ
ãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã¡
ãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«
åã¯ãžã¯ããã«ïŒãšãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãã·ã«ã·ã¢
ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯
ããã«ïŒããã·ã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯
ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒããªã¹ãã«ã·ã¢ã
ã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ã
ãã«ïŒã»ãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡
ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã¹ãã¢ãªã«ã·ã¢ãã¬ãŒ
ãïŒããã©ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¡ã¿
ã¢ãªã«åã¯ãžã¯ããã«ïŒã·ã¢ãã¬ãŒããïŒãããµ
ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯
ãžã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒïŒãã«ã¡ãã¬ã³ãã¹
ããžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒ
ã·ã¢ãã¬ãŒããïŒãªãã·ãžãšãã¬ã³ãã¹ããžã¢ãª
ã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã·ã¢ãã¬
ãŒããïŒãžãªãã·ããªãšãã¬ã³ãã¹ããžã¢ãªã«
ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã·ã¢ãã¬ãŒ
ããïŒæ«ç«¯ããžã¢ãªã«ã·ã¢ãã¬ãŒãæ®åºã§ããã
ãªããã©ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯
ããã«ïŒã·ã¢ãã¬ãŒãïŒæ«ç«¯ããžã¢ãªã«ã·ã¢ãã¬
ãŒãæ®åºã§ããããªãããµã¡ãã¬ã³ã¢ãªã«ïŒåã¯
ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒæ«ç«¯ã
ãžã¢ãªã«ã·ã¢ãã¬ãŒãæ®åºã§ããããªãã«ã¡ãã¬
ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã·ã¢ã
ã¬ãŒãã ãããã®ååç©ã¯ãäŸãã°zh OrganïŒKhimïŒ
ïŒïŒ10ïŒp1742ãïŒïŒ1965ïŒïŒRussïŒãæãã¯J.
Am.soc.ïŒ73p3003ïŒ1951ïŒã«ç€ºãããæ¹æ³ã«ã
ã容æã«åæããããšãã§ããã ïŒïŒ åå¿æ§å®èœåºãæããååç©ïŒäŸãã°å
èšäžè¬åŒ(iii)ã§è¡šããããååç©ãåæãšããŠåŸ
ãããããªããŒïŒ (1) äžèšåŒ(vii)åã¯(viii)ã§è¡šããããããªãšã¹ãã« ãäœãåŒäžãåã³Qâ²2ã¯åèšãããšåãå®çŸ©
ã§ãããQ3ã¯
ã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒããª
ã¡ãªããé žã¢ããã€ããïŒïŒ®ïŒïŒ®ïŒNâ²âããªã¢
ãªã«ïŒåã¯ããªã¡ã¿ã¢ãªã«åã¯ããªã¯ããã«ïŒã
ãªã¡ãªããé žã¢ããã€ããïŒãšãã¬ã³ïŒåã¯ããª
ã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³
åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒïŒâãããã¬ã³ã«ã«ã
ãã·ã¢ããïŒïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯
ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ã
ã¬ã³ïŒãã¹ãïŒâïŒåã¯ïŒâïŒããã³ã«ã«ããã·
ã¢ãããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ãã
ã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬
ã³ïŒãã¹ãïŒâïŒåã¯ïŒâåã¯ïŒâããã³ãã³ã«
ã«ããã·ã¢ãããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³
åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«
ã¡ãã¬ã³ïŒãã¹ãïŒâïŒåã¯ïŒâåã¯ïŒâåã¯ïŒ
âïŒããã»ã³ã«ã«ããã·ã¢ãããïŒïŒ®âã¢ãªã«
ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒïŒâãããã¬ã³
ã«ã«ããã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«å
ã¯ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒããã³ã«ã«ãã
ã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢
ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒâïŒãããã³ã«ã«ã
ãã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿
ã¢ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒâåã¯ïŒâïŒãã
ã»ã³ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâãããã¬ã³ã«
ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¯ã
ãã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒããã³
ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãªã«ïŒåã¯ãžã¯
ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâåã¯ïŒ
âïŒãããã³ã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®âãžã¢ãª
ã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒå
ã¯ïŒâåã¯ïŒâåã¯ïŒâïŒããã»ã³ã«ã«ããã·ã¢
ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯
ãžã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒïŒâããã³ïŒïŒïŒ
âãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âãã
ã©ã¢ãªã«ïŒåã¯ããã©ã¯ããã«åã¯ããã©ã¡ã¿ãª
ã«ïŒïŒâïŒåã¯ïŒïŒããã»ã³ïŒïŒïŒâãžã«ã«ãã
ã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒå
ã¯ããã©ã¯ããã«åã¯ããã©ã¡ã¿ãªã«ïŒïŒâãã
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒãšãã¬ã³ïŒåã¯
ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ã
ã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒåã¯ïŒâïŒã·
ã¯ãããã»ã³ã«ã«ããã·ã¢ããïŒãšãã¬ã³ïŒåã¯
ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯ãããµã¡ã
ã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒåã¯ïŒâïŒã·
ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€ããïŒãšã
ã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ããã©ã¡ãã¬ã³åã¯
ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒãã¹ïŒâïŒå
ã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€
ããïŒãšãã¬ã³ïŒåã¯ããªã¡ãã¬ã³åã¯ããã©ã¡
ãã¬ã³åã¯ãããµã¡ãã¬ã³åã¯ãã«ã¡ãã¬ã³ïŒã
ã¹ïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã€ã
ãïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ããã·ã¢ã
ãïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«
ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡
ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒ
ïŒâãžã«ã«ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ã
ãã«åã¯ã¡ã¿ã¢ãªã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒ
âãžã«ã«ããã·ã€ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ãã
ã«åã¯ã¡ã¿ã¢ãªã«ïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒ
âãããã³ïŒïŒïŒâãžã«ã«ããã·ã€ããïŒïŒ®ïŒïŒ®
âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒ
ïŒâïŒåã¯ïŒâïŒã·ã¯ãããã»ã³ã«ã«ããã·ã¢ã
ãïŒïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ãã
ã©ã¯ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒ
âïŒã·ã¯ãããã»ã³ïŒïŒïŒãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯
ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâïŒåã¯ïŒâïŒ
ã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒ
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯
ããã«åã¯ããã©ã¡ã¿ã¢ãªã«ïŒïŒâã·ã¯ãããã»
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒ®ïŒïŒ®ïŒNâ²ïŒ
Nâ²âããã©ã¢ãªã«ïŒåã¯ããã©ã¯ããã«åã¯ã
ãã©ã¡ã¿ã¢ãªã«ïŒãã·ã¯ããïŒïŒïŒïŒïŒãâïŒâ
ãããã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒ®ïŒ
Nâ²âãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãª
ã«ïŒïŒâã·ã¯ãããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢
ããïŒ ïŒïŒ ã·ã¢ãã«é žåã¯ã€ãœã·ã¢ãã«é žã®èªå°
äœïŒ äžèšåŒ(v)åã¯(vi)ã§è¡šããããååç© äœãåŒ(v)ïŒ(vi)äžã«ãããŠè€æ°åã®Aâ²ã¯åäžã§
ãç°ã€ãŠããŠããããäžã€å°ããšãïŒã±ã¯åèšåº
ã§ãã€ãŠãæ®ãã¯åºïŒ¡ãããã¯åèšQ1äžã®äž
䟡ã®åºã§ãããQ2ã¯åèšQ1äžã®ïŒãïŒäŸ¡ã®åºã§
ãããQâ²2ã¯åèšQ1äžã®ïŒäŸ¡ã®åºã§ããããããŠ
ïœã¯ïŒåã¯ïŒã奜ãŸããã¯ïŒãïœã¯ïŒã10ã®æŽ
æ°ãïœã¯ïŒãïŒã®æŽæ°ã§ããã ãã®æ§ãªåŒ(v)ïŒ(vi)ã§ç€ºãããååç©ã®äŸãšããŠ
ã¯ãäžèšã®åŠãååç©ãäŸç€ºããããšãã§ããã ããªã¢ãªã«ïŒåã¯ããªã¯ããã«åã¯ããªã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ã
ãã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã¡ãã«ã€ãœã·ã¢ãã¬ãŒ
ãïŒãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãª
ã«ïŒãšãã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãž
ã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒãã·ã«ã€ãœã·ã¢ãã¬
ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ãã«åã¯ãžã¡ã¿ã¢ã¯ãª
ã«ïŒããã·ã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯
ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒããªã¹ãã«ã€ãœã·
ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡
ã¿ã¢ãªã«ïŒã»ãã«ã€ãœã·ã¢ãã¬ãŒãïŒãžã¢ãªã«
ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã¹ãã¢ãªã«
ã€ãœã·ã¢ãã¬ãŒãïŒãšãã¬ã³ãã¹ããžã¢ãªã«ïŒå
ã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒ
ããïŒããã©ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯
ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒ
ãããµã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«
åã¯ãžã¡ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãã«ã¡
ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡
ã¿ã¢ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãªãã·ãžãšãã¬
ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããïŒãžãªãã·ããªãšãã¬
ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢
ãªã«ïŒã€ãœã·ã¢ãã¬ãŒããæ«ç«¯ããžã¢ãªã«ã€ãœã·
ã¢ãã¬ãŒãæ®åºã§ããããªãšãã¬ã³ã¢ãªã«ïŒåã¯
ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã€ãœã·ãã¬ãŒãïŒæ«ç«¯
ããžã¢ãªã«ã€ãœã·ã¢ãã¬ãŒãæ®åºã§ããããªãã
ã©ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ãã
ã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒæ«ç«¯ããžã¢ãªã«ã€ãœã·ã¢
ãã¬ãŒãæ®åºã§ããããªãããµã¡ãã¬ã³ã¢ãªã«
ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã€ãœã·ã¢ãã¬ãŒ
ãïŒæ«ç«¯ããžã¢ãªã«ã€ãœã·ã¢ãã¬ãŒãæ®åºã§ãã
ããªãã«ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯
ããã«ïŒã€ãœã·ã¢ãã¬ãŒãïŒããªã¢ãªã«ïŒåã¯ã
ãªã¡ã¿ã¢ãªã«åã¯ããªã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒ
ãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã¡
ãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«
åã¯ãžã¯ããã«ïŒãšãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«
ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒãã·ã«ã·ã¢
ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯
ããã«ïŒããã·ã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯
ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒããªã¹ãã«ã·ã¢ã
ã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ã
ãã«ïŒã»ãã«ã·ã¢ãã¬ãŒãïŒãžã¢ãªã«ïŒåã¯ãžã¡
ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒã¹ãã¢ãªã«ã·ã¢ãã¬ãŒ
ãïŒããã©ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¡ã¿
ã¢ãªã«åã¯ãžã¯ããã«ïŒã·ã¢ãã¬ãŒããïŒãããµ
ã¡ãã¬ã³ãã¹ããžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯
ãžã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒïŒãã«ã¡ãã¬ã³ãã¹
ããžã¢ãªã«ïŒåã¯ãžã¡ã¿ã¢ãªã«åã¯ãžã¯ããã«ïŒ
ã·ã¢ãã¬ãŒããïŒãªãã·ãžãšãã¬ã³ãã¹ããžã¢ãª
ã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã·ã¢ãã¬
ãŒããïŒãžãªãã·ããªãšãã¬ã³ãã¹ããžã¢ãªã«
ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã·ã¢ãã¬ãŒ
ããïŒæ«ç«¯ããžã¢ãªã«ã·ã¢ãã¬ãŒãæ®åºã§ããã
ãªããã©ã¡ãã¬ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯
ããã«ïŒã·ã¢ãã¬ãŒãïŒæ«ç«¯ããžã¢ãªã«ã·ã¢ãã¬
ãŒãæ®åºã§ããããªãããµã¡ãã¬ã³ã¢ãªã«ïŒåã¯
ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã·ã¢ãã¬ãŒãïŒæ«ç«¯ã
ãžã¢ãªã«ã·ã¢ãã¬ãŒãæ®åºã§ããããªãã«ã¡ãã¬
ã³ã¢ãªã«ïŒåã¯ã¡ã¿ã¢ãªã«åã¯ã¯ããã«ïŒã·ã¢ã
ã¬ãŒãã ãããã®ååç©ã¯ãäŸãã°zh OrganïŒKhimïŒ
ïŒïŒ10ïŒp1742ãïŒïŒ1965ïŒïŒRussïŒãæãã¯J.
Am.soc.ïŒ73p3003ïŒ1951ïŒã«ç€ºãããæ¹æ³ã«ã
ã容æã«åæããããšãã§ããã ïŒïŒ åå¿æ§å®èœåºãæããååç©ïŒäŸãã°å
èšäžè¬åŒ(iii)ã§è¡šããããååç©ãåæãšããŠåŸ
ãããããªããŒïŒ (1) äžèšåŒ(vii)åã¯(viii)ã§è¡šããããããªãšã¹ãã« ãäœãåŒäžãåã³Qâ²2ã¯åèšãããšåãå®çŸ©
ã§ãããQ3ã¯
ãåŒãïŒããã§R12ã¯åèšå®
矩ãšåãïŒãããªãïŒãïŒïœïŒïŒïŒäŸ¡ã®åºã
ãåŒãïŒããã§R12ã¯åèšå®çŸ©ãš
åãïŒãããªãïŒãïŒïœïŒïŒïŒäŸ¡ã®åºåã¯
ãåŒããããªãïŒãïŒïœïŒïŒïŒ
䟡ã®åºã§ãããïœã¯ïŒãïŒã®æŽæ°ãïœã¯ïŒåã¯
ïŒãïœã¯ïŒãã倧ããæŽæ°ã§äžã€ïœÃïœâ§ïŒã§ã
ããã ã®ç¹°ãè¿ãåäœãæããããªããŒã§ããã ãããããªããŒã«ãããŠ(vii)ã®ããªããŒã¯ïœïŒïŒ
ã®å ŽåQâ²2ïŒCOOHïŒ2åã¯ãã®ãšã¹ãã«åœ¢ææ§èª
å°äœïŒäŸãã°C1ãC3ã®ã¢ã«ãã«ãšã¹ãã«ãC6ã
C12ã®ã¢ãªãŒã«ãšã¹ãã«ïŒé žããã²ã³åç©ïŒãšã
ïœïŒïŒã®å ŽåCOcl2ïŒCOBr2ïŒãžã¢ãªãŒã«ã«ãŒã
ããŒãçã®ååç©ãšã
ïŒãïœã¯ïŒãã倧ããæŽæ°ã§äžã€ïœÃïœâ§ïŒã§ã
ããã ã®ç¹°ãè¿ãåäœãæããããªããŒã§ããã ãããããªããŒã«ãããŠ(vii)ã®ããªããŒã¯ïœïŒïŒ
ã®å ŽåQâ²2ïŒCOOHïŒ2åã¯ãã®ãšã¹ãã«åœ¢ææ§èª
å°äœïŒäŸãã°C1ãC3ã®ã¢ã«ãã«ãšã¹ãã«ãC6ã
C12ã®ã¢ãªãŒã«ãšã¹ãã«ïŒé žããã²ã³åç©ïŒãšã
ïœïŒïŒã®å ŽåCOcl2ïŒCOBr2ïŒãžã¢ãªãŒã«ã«ãŒã
ããŒãçã®ååç©ãšã
ãåŒãåã¯ãã®ãšã¹
ãã«åœ¢ææ§èªå°äœïŒäŸãã°äœçŽèèªé
žãšã¹ãã«ïŒ
ã¢ã«ã«ãªéå±å¡©çïŒãšãåŸæ¥å ¬ç¥ã®æ¹æ³ã§åå¿ã
ããããšã«ããåŸããããŸã(viii)ã®ããªããŒã¯ïœïŒ
ïŒã®å Žåã
ã¢ã«ã«ãªéå±å¡©çïŒãšãåŸæ¥å ¬ç¥ã®æ¹æ³ã§åå¿ã
ããããšã«ããåŸããããŸã(viii)ã®ããªããŒã¯ïœïŒ
ïŒã®å Žåã
ãåŒãåã¯ãã®ãšã¹ãã«
圢æèªå°äœãããŸãïœïŒïŒã®å Žåã¯
ãåŒãã¯ãã®ãšã¹ãã«åœ¢ææ§èªå°äœãã
åŸæ¥å
¬ç¥ã®æ¹æ³ã§åå¿ãããããšã«ãã€ãŠåŸãã
ãã æ¬çºæã«ãããŠãããããªããŒã®æ«ç«¯ã¯äžèšåŒ
ã§ç€ºããããªããŒã圢æããæåã®æ«ç«¯ã«ãªã
ããåžžæ³ã«ããäŸãã°ã¢ã«ãã«âåã¯ã¢ãªãŒã«â
ãšã¹ãã«ã®åœ¢ã®æ«ç«¯ã«è»¢åããããšã奜ãŸããã ãã®ãããªåŒ(vii)ïŒ(viii)ã®äŸãšããŠã¯ãäžèšã®åŠ
ã
ç¹°ãè¿ãåäœãæããããªããŒãäŸç€ºã§ããã ïŒäœããäžèšååç©äžïŒ¡ã¯ã¢ãªã«åã¯ã¡ã¿ã¢ãª
ã«åã¯ã¯ããã«ã§ãããïŒ ãããã¯æ¯èŒçåå¿ãã«ããããªãšã¹ãã«ã§ã
ãã (2) ããªã¢ãã ããªïŒãšãã¬ã³âïŒâããã³ïŒïŒïŒâãžã«ã«ã
ãã·ã¢ããïŒïŒããªïŒããã©ã¡ãã¬ã³âïŒâãã
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒããªïŒãããµ
ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâã«ã«ããã·ã¢ã
ãïŒïŒããªïŒãã«ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒããªïŒãšãã¬ã³ïŒâïŒå
ã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ã
ãïŒïŒããªïŒããã©ã¡ãã¬ã³ïŒâïŒåã¯ïŒâïŒã
ãã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒããªïŒã
ããµã¡ãã¬ã³ïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒããªïŒãã«ã¡ãã¬ã³ïŒâ
ïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ã
ãïŒ æ¬¡ã«ãå ±éåååã³æ··ååã®äžéçæ§èœãæã
ãååç©ãšããŠã¯ãæ¯èŒçãšã¹ãã«äº€æåå¿ãã
ãããããªãšã¹ãã«ãäŸãã°ããªãšãã¬ã³âïŒâ
ããã³ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒãïŒããªããã©
ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒ
ãïŒããªãšãã¬ã³âïŒâïŒåã¯ïŒâïŒããã»ã³
ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒãïŒããªããã©ã¡ãã¬
ã³âïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ã
ãã·ã¬ãŒãïŒããªâïŒâããã³ã¢ãžããŒãïŒããª
âïŒâããã³ã»ãã±ãŒãïŒããªïŒâïŒåã¯ïŒâå
ã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ãã¬ã³ãã¬
ãã¿ã¬ãŒãïŒããªïŒâåã¯ïŒâåã¯ïŒâïŒã·ã¯ã
ããã»ã³ïŒïŒïŒâãžã¡ãã¬ã³ãã¬ãã¿ã¬ãŒãçã®
åŠãç·ç¶ããªãšã¹ãã«æãã¯ãããšä»çš®é žæåå
ã³ïŒåã¯ã°ãªã³ãŒã«æåãšã®å ±éåäœã§ãã€ãŠã
éå床ã®é«ããã®ïŒäŸãã°æ¥µéç²åºŠ0.4以äžïŒã
äŸç€ºãããããã®ãã®ã¯æº¶èãã¬ã³ãåã³ïŒåã¯
æ圢æã«ããªãšã¹ãã«ãšäžéšåå¿ããŠããå šäœã®
éå床äœäžããããããšãå°ãªãã䜿çšå¯èœã§ã
ãã èèªæç³»äžé£œååºãæããååç©ãšããŠã¯ãæ··
ååã®ååç©ã奜ãŸãããæŽã«ã¯åèšïŒïŒåã¯
ïŒïŒã®ååç©ã奜ãŸãããç¹ã«ïŒïŒã®ååç©
ã奜ãŸãããæŽã«ïŒïŒã®ãã¡ã§ããäžé£œååºã
ïŒå以äžæããååç©ã奜ãŸããã æ¬çºæã«æŒãŠã¯äžèšèèªæç³»äžé£œåååç©ã®äœ¿
çšå²åã¯ãå ±éåã®å Žåã§ããã¬ã³ãã®å Žåã§ã
ããªããŒ100ïœäžèèªæç³»äžé£œååºãšããŠ0.001ã
0.5åœéã§ããã奜ãŸããã¯0.005ã0.3åœéããã
奜ãŸããã¯0.01ã0.1åœéãç¹ã«å¥œãŸããã¯0.01ã
0.05åœéã§ããã æ¬çºæã«ãããŠãããªãšã¹ãã«ã«å«æãããã
ããäžã€ã®æåã¯æ¶æ©åå¿å©å€ã§ããããã®æ¶æ©
åå¿å©å€ãåèšèèªæç³»äžé£œååºãæããååç©
ãšåæ§ã«ããªãšã¹ãã«ã«å ±éååã³ïŒåã¯ãã¬ã³
ãããããããšã«ãã€ãŠããªãšã¹ãã«ã«å«æãã
ãããåŸã€ãŠæ¶æ©åå¿å©å€ãšããŠã¯ããªãšã¹ãã«
ã®æº¶èæ¡ä»¶äžã§å解ããäžã€æ¶æ©åå¿å©å€å¹æã
倱ãæ§ãªåå¿ãèµ·ããªããã®ã奜ãŸãããããã
æ¶æ©åå¿å©å€ãšããŠè³éŠæã±ãã³é¡ããã³ãžã«å
ã³ãã®èªå°äœããã³ãŸã€ã³åã³ãã®èªå°äœãå€æ ž
ããã³é¡çã奜ãŸããæããããããããååç©
ã®ãã¡ããªãšã¹ãã«ã«ãã¬ã³ãå¯èœãªãã®ãšã
ãŠãäŸãã°ãã³ãŸããšãã³ïŒïŒâã¡ãã«ãã³ãŸã
ãšãã³ïŒïŒâããããã³ãŸããšãã³ïŒïŒâã¡ãã«
ãã³ãŸããšãã³ïŒïŒïŒ4â²âãžã¡ãã«ãã³ãŸããšã
ã³ïŒïŒïŒ3â²âãžã¡ãã«ãã³ãŸããšãã³ïŒïŒïŒ4â²â
ãžã¡ãã«ãã³ãŸããšãã³ïŒïŒâããšãã«ãã³ãŸã
ãšãã³ïŒïŒâããšãã«ãã³ãŸããšãã³ïŒïŒïŒ3â²â
ãžããããã³ãŸããšãã³ïŒïŒïŒ4â²âãžããããã³
ãŸããšãã³ïŒïŒâããããã³ãŸããšãã³ïŒïŒâã¡
ããã·ãã³ãŸããšãã³ïŒïŒâã¡ããã·ãã³ãŸããš
ãã³ïŒïŒïŒ4â²âãžã¡ããã·ãã³ãŸããšãã³ïŒïŒïŒ
3â²âãžã¡ããã·ãã³ãŸããšãã³ïŒãã¹ïŒïŒâãžã
ãšãã«ïŒã±ãã³ïŒãã¹ïŒïŒâãžããšãã«ïŒã±ã
ã³ïŒïŒïŒïŒâãžã¡ãã«ãã³ãŸããšãã³ïŒïŒïŒïŒïŒ
3â²ïŒ4â²âããã©ã¡ãã«ãã³ãŸããšãã³ïŒããã©ãŒ
ãºã±ãã³ïŒã¢ã³ãã©ããã³ïŒãããã¢ã³ãã©ãã
ã³ïŒããšãã³ãã©ããã³ïŒã¢ã»ãããšãã³ïŒãã
ããªããšãã³ïŒãã³ãžã«ïŒãã³ãŸã€ã³ïŒãã³ãŸã€
ã³ã¡ãã«ãšãŒãã«ïŒãã³ãŸã€ã³ãšãã«ãšãŒãã«ïŒ
ãã³ãŸã€ã³ãããã«ãšãŒãã«ïŒãã³ãŸã€ã³ããã«
ãšãŒãã«ïŒãã³ãŸã€ã³ããšãã«ãšãŒãã«ïŒÎ±âã¡
ãã«ãã³ãŸã€ã³ã¡ãã«ãšãŒãã«ïŒÎ±âããšãã«ã
ã³ãŸã€ã³ãšãŒãã«ïŒÎ±âãã³ãžã«ãã³ãŸã€ã³ãšã
ã«ãšãŒãã«ïŒãã³ãžã«ãžã¡ãã«ã±ã¿ãŒã«ïŒãã³ãž
ã«ãžãšãã«ã±ã¿ãŒã«ïŒãã³ãžã«ãžãããã«ã±ã¿ãŒ
ã«ïŒãã³ãžã«ãšãã¬ã³ã±ã¿ãŒã«ïŒãã³ãžã«ããªã¡
ãã¬ã³ã±ã¿ãŒã«ïŒãã³ãžã«ããªãã³ãã¬ã³ã±ã¿ãŒ
ã«ïŒãã³ãžã«ãã¹ïŒïŒâã¡ããã·ãšãã«ïŒã±ã¿ãŒ
ã«ïŒãããã«ããšãã«ã±ãã³ïŒãã¹ãããã«ã±ã
ã³ïŒãšãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ
ããã©ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢ã
ãïŒïŒãããµã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢
ããïŒïŒãã«ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢
ããïŒïŒããã«ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãº
ã¢ããïŒïŒãããµã¡ãã¬ã³ãã¹ïŒïŒâã¢ã»ãã«ã
ã³ãºã¢ããïŒïŒãããµã¡ãã¬ã³ãã¹ãïŒïŒâã¡ãã«
ãã³ãŸã€ã«ïŒãã³ãºã¢ãããïŒãšãã¬ã³ãã¹ãïŒïŒ
âããããã³ãŸã€ã«ïŒãã³ãºã¢ãããïŒããã«ã¡
ãã¬ã³ãã¹ãïŒïŒâã¡ããã·ãã³ãŸã€ã«ïŒãã³ãº
ã¢ãããïŒãžãã³ãŸã€ã«ãã³ãŒã³ïŒãã¹ïŒïŒâã¡
ãã«ãã³ãŸã€ã«ïŒãã³ãŒã³ïŒãšãã¬ã³ãã¹ïŒãã³
ãŸã€ã«ããšãã«ãšãŒãã«ïŒïŒãã¹ïŒãã³ãŸã€ã«ã¡
ãã«ïŒãšãŒãã«ïŒããªã¹ïŒãã³ãŸã€ã«ããšãã
ã·ïŒãã³ãŒã³ïŒãã¹ïŒïŒâã¡ããã·ãã³ãŸã€ã«ã¡
ãã«ãšãŒãã«ïŒçãæããããããŸãããã€ãå ¬
éç¹èš±æ现æžç¬¬1769168å·ïŒç¬¬1769853å·ïŒç¬¬
1807297å·ïŒç¬¬1807301å·ïŒç¬¬1919678å·åã³ç¬¬
1949010å·ã«æããããŠããæ¶æ©åå¿å©å€ã®ãã¡
ããªãšã¹ãã«ã®æº¶è§Šäžå®è³ªçã«å®å®ã§ãããã®ã¯
é©å®äœ¿çšåºæ¥ãã ãŸããå ±éåå¯èœãªååç©ãšããŠã¯ãäŸãã°ã
ã³ãŸããšãã³ïŒïŒ4â²âãžã«ã«ãã³é žçãäŸç€ºãã
ãããããæ¶æ©åå¿å©å€ã®ãã¡ããã³ãžã«åã³ã
ã®èªå°äœã奜ãŸãããç¹ã«ãã³ãžã«èªå°äœã掻æ§
ãé«ãã®ã§å¥œãŸããããŸãè³éŠæã±ãã³é¡ã®ãã¡
ãã³ãŸããšãã³æ®åºãïŒå以äžæããååç©ã掻
æ§ãé«ãã®ã§å¥œãŸããã æ¬çºæã«æŒããæ¶æ©åå¿å©å€ã®äœ¿çšéã¯ãããª
ãšã¹ãã«100éééšã«å¯Ÿãã0.01ã20éééšã奜
ãŸããã¯0.05ã10éééšãæŽã«å¥œãŸããã¯0.1ã
ïŒéééšãç¹ã«å¥œãŸããã¯0.1ãïŒéééšã§ã
ãã å°ãæ¬çºæã«ãããŠã¯ãåèšèèªæç³»äžé£œååº
ãšæ¶æ©åå¿å©å€äœçšã®ïŒã€ã®æ©èœãããªãšã¹ãã«
ãæããŠããã°ãããåŸã€ãŠèèªæç³»äžé£œååºã
æããååç©ãšæ¶æ©åå¿å©å€äœçšãæããååç©
ãç°ãªãå Žåã«å¿è«ã®ããšãäžèšïŒçš®é¡ã®æ©èœã
åæã«åããååç©ã§ããã°ïŒçš®é¡ã®ååç©ãã
ãªãšã¹ãã«ã«å ±éååã³ïŒåã¯ãã¬ã³ããããã
ããšã«ããæ¬çºæã®ç®çãéæããããšãã§ã
ãããããïŒçš®é¡ã®æ©èœãæããååç©ãšããŠ
ã¯ãäŸãã°ïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢
ãªã«ïŒãã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ®âã¢ãªã«ïŒå
ã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒã¢ã³ãã©ããã³ã«ã«
ããã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ãããã«åã¯
ã¡ã¿ã¢ãªã«ïŒãã³ãŸã€ã«ãã¿ã«ã€ããïŒïŒ®ïŒïŒ®â
ãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã
ã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒå
ã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒåã¯ãžã¯ããã«
åã¯ãžã¡ã¿ã¢ãªã«ïŒãã³ãŸããšãã³ããã©ã«ã«ã
ãã·ã€ããçãæããããã æ¬çºæã®æ¶æ©ããããªãšã¹ãã«å®¹åšã¯ãäŸãã°
æå®éã®èèªæç³»äžé£œååºãšæ¶æ©åå¿å©å€ãšãå«
æããããªãšã¹ãã«ãã該ããªãšã¹ãã«ã®æº¶èäž
ææã®ãã€ã«ã åã¯ã·ãŒããšãªãã次ãã§è©²ãã€
ã«ã åã¯ã·ãŒããæ·±çµãæ圢ããŠå®¹åšãšãªããäž
ã€ãã€ã«ã åã¯ã·ãŒãæ圢åã®æ®µéã§æ¶æ©åŠçã
æœãããšã«ãã€ãŠåŸããããå ±éåã«ãã€ãŠèèª
æç³»äžé£œååºåã¯æ¶æ©åå¿å©å€ãããªãšã¹ãã«ã«
å«æãããå Žåãéåžžäžè¿°ã®é žæåãã°ãªã³ãŒã«
æååã³å ã«äŸç€ºããåŠãååç©ãåŸæ¥å ¬ç¥ã®æ¹
æ³ã§åå¿ãããããã®å Žåãèèªæç³»äžé£œååºå
ã³ïŒåã¯æ¶æ©åå¿å©å€ãéå°ã«å ±éåããããã
ãªãšã¹ãã«ãäºãäœãããããèèªæç³»äžé£œååº
åã³ïŒåã¯æ¶æ©åå¿å©å€ãå«æããªããåã¯å°å²
åå ±éåããããªãšã¹ãã«ãšæº¶èãã¬ã³ãããã
ãããããããã¹ã¿ãŒãããæ¹åŒã奜ãŸããçšã
ãããã ãŸãããã¬ã³ãã«ãã€ãŠèèªæç³»äžé£œååºå
ã³ïŒåã¯æ¶æ©åå¿å©å€ãããªãšã¹ãã«ã«å«æãã
ããå Žåãéåžžããªãšã¹ãã«ãšèèªæç³»äžé£œååº
ãæããååç©åã³ïŒåã¯æ¶æ©åå¿å©å€ãšäŸãã°
åãã¬ã³ããŒãåãã¬ã³ããŒã®åŠãæ©æ¢°çæ··
åæ段ã§æ··åãã次ãã§ãšã¯ã¹ãã«ãŒããŒã®åŠã
æ··ç·Žæ©ãçšããŠäž¡è ã該ããªãšã¹ãã«ã溶èç¶æ
ãšãªã枩床åã¯ãã以äžã奜ãŸããã¯è©²ããªãšã¹
ãã«ã®èç¹åã¯è©²èç¹ããçŽ60âé«ã枩床ã®ç¯å²
ã§åäžã«ãã¬ã³ãããã 次ã«æº¶èæ圢ã«ããæªæ¶æ©ã®ã·ãŒãåã¯ãã€ã«
ã ãæ圢ããããã®æ圢ã¯ãéåžžããªãšã¹ãã«ã®
èç¹ä»¥äžã奜ãŸããã¯ããªãšã¹ãã«ã®èç¹ã該ã
ãªãšã¹ãã«ã®å解枩床æªæºã奜ãŸããã¯è©²èç¹ã
ãçŽ60âé«ã枩床ãŸã§ã§è¡ãã ããããŠåŸãããã·ãŒãåã¯ãã€ã«ã ãã容åš
ãžã®æ圢ã¯è©²ã·ãŒãåã¯ãã€ã«ã ãåŸæ¥å ¬ç¥ã®ã
ãã«æ·±çµãæåéåã«è£ å¡«ããæžå§åã³ïŒåã¯å
å§äžã§çµã蟌ãããšã«ããéãããããããã®ãš
ãã®æž©åºŠãšããŠã¯è©²ããªãšã¹ãã«çŽ æã®äºæ¬¡è»¢ç§»
ç¹ä¹è³æº¶è枩床ã®éã§ããã®ããããæ¬çºæã§ã¯
ãã€ã«ã åã¯ã·ãŒãæ圢以éã®ä»»æã®æ®µéã§æŽ»æ§
ç·ãç §å°ããããšã«ãã該ããªãšã¹ãã«ã«æ¶æ©å€
åãèµ·ãããããããã«ãã掻æ§ç·ãšã¯æŸå°ç·ã
玫å€ç·çãããããæ¬ä»¶çºæã«ç¹ã«æå¹ãªãã®ã¯
玫å€ç·ã§ãããç §å°ããæéãšããŠã¯ãç·æºã®åŒ·
床ã«å¿ããŠèª¿ç¯ãããã¹ãã§ããããéåžž0.1ã
10æéã奜ãŸããã¯0.5ç§ãïŒæéããã奜ãŸã
ãã¯ïŒç§ã30åãç¹ã«å¥œãŸããã¯10ç§ã10åçšåºŠ
ã§ãããæ¬çºæã«ããã掻æ§ç·ç §å°ã®å ·äœçæ æ§
ã¯æ¬¡ã®éãã§ããã (1) ãã€ã«ã åã¯ã·ãŒãã®æ圢æä¹è³æ圢åŸè©²ã
ã€ã«ã åã¯ã·ãŒãã«æŽ»æ§ç·ãç §å°ãã次ãã§æ·±
çµãæ圢ãè¡ãªãããã®å Žåã«ã¯ãã€ã«ã åã¯
ã·ãŒãã®æº¶è枩床ã¯ããªãšã¹ãã«çŽ æã®æº¶èæž©
床ããé«ããªãåŸåã«ããã (2) ãã€ã«ã åã¯ã·ãŒãã掻æ§ç·ç §å°äžã§æ·±çµã
æ圢ãããããã¯éåã«ãšãã€ãããŸãŸåæã«
è¡ãªãã (3) ãã€ã«ã åã¯ã·ãŒããæ·±çµãæ圢ããåŸã次
ãã§æŽ»æ§ç·ãç §å°ããããã®æã¯ãçµã蟌ãŸã
ããã€ã«ã åã¯ã·ãŒããéåã«ã¯ãããŸãŸã§ã
ããããã¯å®¹åšãšããŠãšãåºããŠããã§ãã
ãã (4) äžèš(1)ã(3)ã®æ¹æ³ãä»»æã«çµåããŠè¡ããã
ã®å Žåã¯ããªãšã¹ãã«çŽ æã®çµæ¶åé åçã®åºŠ
åã«å¿ããŠçµåããããã æå¹ãªå¹æãçºçŸãããçºã«ã¯ãæ¶æ©å€åã®åºŠ
åãã¯éèŠã§ããããã®æ¶æ©åºŠãšããŠã¯ããªãšã¹
ãã«å®¹åšæ圢ç©ã®åçããªã«ãœã¯ããããšããŒã«
ã«æº¶è§£ãããããšããäžæº¶è§£åãå°ãªããšã10é
éïŒ ä»¥äžå¿ èŠã§ããããã奜ãŸããã¯20ééïŒ ä»¥
äžãç¹ã«å¥œãŸããã¯50ééïŒ ä»¥äžã§ããã å°ãæ¬çºæã«ãããŠã¯å®¹åšæ圢äœã«å皮添å å€
äŸãã°ç±å®å®å€ãçè²å€çãé©å®å«æãããŠããŠ
ãããããéææ§ãæããªãããšãå¿ èŠã§ããã æ¬çºæã«ããã°æŽ»æ§ç·ãç §å°ãããšãã容æãª
æ¹æ³ã«ãããåªããèç±æ§ãèè¬åæ§åã³æ©æ¢°ç
ç¹æ§çãæ¹åãããããªãšã¹ãã«å®¹åšãå·¥æ¥çã«
æå©ã«æäŸããããšãåºæ¥ãã 以äžã«å®æœäŸã«ãã説æããã以äžã§ãéšããš
瀺ãããã®ã¯ãããšããããªãéãéééšã瀺
ãããŸã極éç²åºŠã¯ãªã«ãœã¯ããããšããŒã«äž40
âã§æž¬å®ããå€ã§ããã å®æœäŸ ïŒ ã€ãœãã¿ã«é žã15ã¢ã«ïŒ å ±éåããããããªãš
ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒæ¥µéç²åºŠ0.62ïŒ100éšãš
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ãã¬ãã¿ã©ãã
ïŒéšåã³ãã³ãžã«ãšãã¬ã³ã±ã¿ãŒã«ïŒéšãšãå
ãã¬ã³ããŒã§æ··åããã®ã¡ã275âã§æº¶èããã
ãã€ããæŒãåºããæ¥å·ããåãçŽ0.4mmã®é
æãªã·ãŒããåŸãããã®ã·ãŒãã110âã«å ç±ã
ããéæ¿äžã«çœ®ã100Wé«å§æ°Žéç¯ã§15cmã®è·é¢
ããïŒåéç §å°ããããã®ã·ãŒããå圢ã«åæ
ããçŽåŸ40mmãæ·±ã40mmã®åç圢ã®ç空æ圢çšé
åã«è£ 眮ããŠã130âã«å ç±ãã100ããŒã«ã®ç空
ã«ããçµã蟌ã¿ãè¡ããåç圢ç¶ã«æ圢ãããåŸ
ããã容åšã¯ç¡è²éæã§ã以äžã®æž¬å®ãè¡ã€ãã äžæº¶è§£åã®æž¬å®ã¯ãè©Šæ容åšã®åºéš120mgãå
ããšããè©Šéšç®¡äžã§10mlã®ãªã«ãœã¯ããããšããŒ
ã«ãšãšãã«40âã§30åéããæ¯ãšãããåŸãå 容
ç©ãåžåŒéããéç©ãã¢ã»ãã³ã§æŽã也ç¥åŸ
秀éããããšã«ããããŸã容åšã®ç±å€åœ¢æž©åºŠã¯è©Š
æ容åšãå ç±æµŽã«æµžæŒ¬ããŠåœ¢ããããèµ·ããã¯ã
ãã枩床ãèªã¿ãšãããšã«ããè¡ã€ãããã®å®¹åš
ã¯äžæº¶è§£ç©ãšããŠ84mgãäžããåŸã€ãŠäžæº¶è§£åã¯
70ïŒ ã瀺ããããŸãç±å€åœ¢æž©åºŠã¯89âã瀺ããã ããã«å¯ŸããŠïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«
ãã¬ãã¿ã©ã·ãåã³ãã³ãžã«ãžã¡ãã«ã±ã¿ãŒã«ã
å«æãããªãã§äžã€çŽ«å€ç·ãç §å°ãããæ圢枩床
ã80âã«ãã以å€ã¯äžèšãšåæ§ã«æ圢ãè¡ã€ãã
ã®ã¯ãäžæº¶è§£åã¯å šããªããç±å€åœ¢æž©åºŠã70âã®
æž©æ°Žã«æŒ¬ããã ãã§çŽã¡ã«åçž®ããŠããŸã€ãã å®æœäŸ ïŒ ãã¬ãã¿ã«é žãžã¡ãã«194éšïŒãšãã¬ã³ã°ãªã³
ãŒã«130éšåã³ïŒâã·ã¯ãããã»ã³âïŒïŒïŒâãž
ã«ã«ãã³é ž8.5éšãåå¿ããããŠåŸãããªãšã¹ã
ã«ïŒæ¥µéç²åºŠ0.63ïŒ100éšã«ããã³ãžã«ãžã¡ãã«
ã±ã¿ãŒã«ïŒéšãæ··åãã280âã§æº¶èãããã€
ããæŒãåºãæ¥å·ããŠåãçŽ0.4mmã®ã·ãŒããåŸ
ãããã®ã·ãŒããå®æœäŸïŒãšåãããã«éåã«è£
çããã110âã«å ç±ãã玫å€ç·ç §å°ãã¯ããã
ãšåæã«ç空ã«ããçµã蟌ã¿ãã¯ããããç §å°ã¯
2KWæ°Žéã©ã³ãã20cmã®è·é¢ããïŒåéè¡ã€
ããåŸããã容åšã¯ç¡è²éæã§å®æœäŸïŒãšåãäž
溶解åãç±å€åœ¢æž©åºŠã枬å®ãããšãããããã43
ïŒ ïŒ79âã瀺ããã玫å€ç·ãç §å°ããåæ§ã«æ圢
ãããã®ã¯äžæº¶è§£åïŒïŒ ãç±å€åœ¢æž©åºŠã¯62âã§ã
ãã æ¬çºæã«ãããŠãããããªããŒã®æ«ç«¯ã¯äžèšåŒ
ã§ç€ºããããªããŒã圢æããæåã®æ«ç«¯ã«ãªã
ããåžžæ³ã«ããäŸãã°ã¢ã«ãã«âåã¯ã¢ãªãŒã«â
ãšã¹ãã«ã®åœ¢ã®æ«ç«¯ã«è»¢åããããšã奜ãŸããã ãã®ãããªåŒ(vii)ïŒ(viii)ã®äŸãšããŠã¯ãäžèšã®åŠ
ã
ç¹°ãè¿ãåäœãæããããªããŒãäŸç€ºã§ããã ïŒäœããäžèšååç©äžïŒ¡ã¯ã¢ãªã«åã¯ã¡ã¿ã¢ãª
ã«åã¯ã¯ããã«ã§ãããïŒ ãããã¯æ¯èŒçåå¿ãã«ããããªãšã¹ãã«ã§ã
ãã (2) ããªã¢ãã ããªïŒãšãã¬ã³âïŒâããã³ïŒïŒïŒâãžã«ã«ã
ãã·ã¢ããïŒïŒããªïŒããã©ã¡ãã¬ã³âïŒâãã
ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒããªïŒãããµ
ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâã«ã«ããã·ã¢ã
ãïŒïŒããªïŒãã«ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒããªïŒãšãã¬ã³ïŒâïŒå
ã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ã
ãïŒïŒããªïŒããã©ã¡ãã¬ã³ïŒâïŒåã¯ïŒâïŒã
ãã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ããïŒïŒããªïŒã
ããµã¡ãã¬ã³ïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâ
ãžã«ã«ããã·ã¢ããïŒïŒããªïŒãã«ã¡ãã¬ã³ïŒâ
ïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ããã·ã¢ã
ãïŒ æ¬¡ã«ãå ±éåååã³æ··ååã®äžéçæ§èœãæã
ãååç©ãšããŠã¯ãæ¯èŒçãšã¹ãã«äº€æåå¿ãã
ãããããªãšã¹ãã«ãäŸãã°ããªãšãã¬ã³âïŒâ
ããã³ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒãïŒããªããã©
ã¡ãã¬ã³âïŒâããã³ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒ
ãïŒããªãšãã¬ã³âïŒâïŒåã¯ïŒâïŒããã»ã³
ïŒïŒïŒâãžã«ã«ããã·ã¬ãŒãïŒããªããã©ã¡ãã¬
ã³âïŒâïŒåã¯ïŒâïŒããã»ã³ïŒïŒïŒâãžã«ã«ã
ãã·ã¬ãŒãïŒããªâïŒâããã³ã¢ãžããŒãïŒããª
âïŒâããã³ã»ãã±ãŒãïŒããªïŒâïŒåã¯ïŒâå
ã¯ïŒâïŒã·ã¯ãããã»ã³ïŒïŒïŒâãžã¡ãã¬ã³ãã¬
ãã¿ã¬ãŒãïŒããªïŒâåã¯ïŒâåã¯ïŒâïŒã·ã¯ã
ããã»ã³ïŒïŒïŒâãžã¡ãã¬ã³ãã¬ãã¿ã¬ãŒãçã®
åŠãç·ç¶ããªãšã¹ãã«æãã¯ãããšä»çš®é žæåå
ã³ïŒåã¯ã°ãªã³ãŒã«æåãšã®å ±éåäœã§ãã€ãŠã
éå床ã®é«ããã®ïŒäŸãã°æ¥µéç²åºŠ0.4以äžïŒã
äŸç€ºãããããã®ãã®ã¯æº¶èãã¬ã³ãåã³ïŒåã¯
æ圢æã«ããªãšã¹ãã«ãšäžéšåå¿ããŠããå šäœã®
éå床äœäžããããããšãå°ãªãã䜿çšå¯èœã§ã
ãã èèªæç³»äžé£œååºãæããååç©ãšããŠã¯ãæ··
ååã®ååç©ã奜ãŸãããæŽã«ã¯åèšïŒïŒåã¯
ïŒïŒã®ååç©ã奜ãŸãããç¹ã«ïŒïŒã®ååç©
ã奜ãŸãããæŽã«ïŒïŒã®ãã¡ã§ããäžé£œååºã
ïŒå以äžæããååç©ã奜ãŸããã æ¬çºæã«æŒãŠã¯äžèšèèªæç³»äžé£œåååç©ã®äœ¿
çšå²åã¯ãå ±éåã®å Žåã§ããã¬ã³ãã®å Žåã§ã
ããªããŒ100ïœäžèèªæç³»äžé£œååºãšããŠ0.001ã
0.5åœéã§ããã奜ãŸããã¯0.005ã0.3åœéããã
奜ãŸããã¯0.01ã0.1åœéãç¹ã«å¥œãŸããã¯0.01ã
0.05åœéã§ããã æ¬çºæã«ãããŠãããªãšã¹ãã«ã«å«æãããã
ããäžã€ã®æåã¯æ¶æ©åå¿å©å€ã§ããããã®æ¶æ©
åå¿å©å€ãåèšèèªæç³»äžé£œååºãæããååç©
ãšåæ§ã«ããªãšã¹ãã«ã«å ±éååã³ïŒåã¯ãã¬ã³
ãããããããšã«ãã€ãŠããªãšã¹ãã«ã«å«æãã
ãããåŸã€ãŠæ¶æ©åå¿å©å€ãšããŠã¯ããªãšã¹ãã«
ã®æº¶èæ¡ä»¶äžã§å解ããäžã€æ¶æ©åå¿å©å€å¹æã
倱ãæ§ãªåå¿ãèµ·ããªããã®ã奜ãŸãããããã
æ¶æ©åå¿å©å€ãšããŠè³éŠæã±ãã³é¡ããã³ãžã«å
ã³ãã®èªå°äœããã³ãŸã€ã³åã³ãã®èªå°äœãå€æ ž
ããã³é¡çã奜ãŸããæããããããããååç©
ã®ãã¡ããªãšã¹ãã«ã«ãã¬ã³ãå¯èœãªãã®ãšã
ãŠãäŸãã°ãã³ãŸããšãã³ïŒïŒâã¡ãã«ãã³ãŸã
ãšãã³ïŒïŒâããããã³ãŸããšãã³ïŒïŒâã¡ãã«
ãã³ãŸããšãã³ïŒïŒïŒ4â²âãžã¡ãã«ãã³ãŸããšã
ã³ïŒïŒïŒ3â²âãžã¡ãã«ãã³ãŸããšãã³ïŒïŒïŒ4â²â
ãžã¡ãã«ãã³ãŸããšãã³ïŒïŒâããšãã«ãã³ãŸã
ãšãã³ïŒïŒâããšãã«ãã³ãŸããšãã³ïŒïŒïŒ3â²â
ãžããããã³ãŸããšãã³ïŒïŒïŒ4â²âãžããããã³
ãŸããšãã³ïŒïŒâããããã³ãŸããšãã³ïŒïŒâã¡
ããã·ãã³ãŸããšãã³ïŒïŒâã¡ããã·ãã³ãŸããš
ãã³ïŒïŒïŒ4â²âãžã¡ããã·ãã³ãŸããšãã³ïŒïŒïŒ
3â²âãžã¡ããã·ãã³ãŸããšãã³ïŒãã¹ïŒïŒâãžã
ãšãã«ïŒã±ãã³ïŒãã¹ïŒïŒâãžããšãã«ïŒã±ã
ã³ïŒïŒïŒïŒâãžã¡ãã«ãã³ãŸããšãã³ïŒïŒïŒïŒïŒ
3â²ïŒ4â²âããã©ã¡ãã«ãã³ãŸããšãã³ïŒããã©ãŒ
ãºã±ãã³ïŒã¢ã³ãã©ããã³ïŒãããã¢ã³ãã©ãã
ã³ïŒããšãã³ãã©ããã³ïŒã¢ã»ãããšãã³ïŒãã
ããªããšãã³ïŒãã³ãžã«ïŒãã³ãŸã€ã³ïŒãã³ãŸã€
ã³ã¡ãã«ãšãŒãã«ïŒãã³ãŸã€ã³ãšãã«ãšãŒãã«ïŒ
ãã³ãŸã€ã³ãããã«ãšãŒãã«ïŒãã³ãŸã€ã³ããã«
ãšãŒãã«ïŒãã³ãŸã€ã³ããšãã«ãšãŒãã«ïŒÎ±âã¡
ãã«ãã³ãŸã€ã³ã¡ãã«ãšãŒãã«ïŒÎ±âããšãã«ã
ã³ãŸã€ã³ãšãŒãã«ïŒÎ±âãã³ãžã«ãã³ãŸã€ã³ãšã
ã«ãšãŒãã«ïŒãã³ãžã«ãžã¡ãã«ã±ã¿ãŒã«ïŒãã³ãž
ã«ãžãšãã«ã±ã¿ãŒã«ïŒãã³ãžã«ãžãããã«ã±ã¿ãŒ
ã«ïŒãã³ãžã«ãšãã¬ã³ã±ã¿ãŒã«ïŒãã³ãžã«ããªã¡
ãã¬ã³ã±ã¿ãŒã«ïŒãã³ãžã«ããªãã³ãã¬ã³ã±ã¿ãŒ
ã«ïŒãã³ãžã«ãã¹ïŒïŒâã¡ããã·ãšãã«ïŒã±ã¿ãŒ
ã«ïŒãããã«ããšãã«ã±ãã³ïŒãã¹ãããã«ã±ã
ã³ïŒãšãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ
ããã©ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢ã
ãïŒïŒãããµã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢
ããïŒïŒãã«ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãºã¢
ããïŒïŒããã«ã¡ãã¬ã³ãã¹ïŒãã³ãŸã€ã«ãã³ãº
ã¢ããïŒïŒãããµã¡ãã¬ã³ãã¹ïŒïŒâã¢ã»ãã«ã
ã³ãºã¢ããïŒïŒãããµã¡ãã¬ã³ãã¹ãïŒïŒâã¡ãã«
ãã³ãŸã€ã«ïŒãã³ãºã¢ãããïŒãšãã¬ã³ãã¹ãïŒïŒ
âããããã³ãŸã€ã«ïŒãã³ãºã¢ãããïŒããã«ã¡
ãã¬ã³ãã¹ãïŒïŒâã¡ããã·ãã³ãŸã€ã«ïŒãã³ãº
ã¢ãããïŒãžãã³ãŸã€ã«ãã³ãŒã³ïŒãã¹ïŒïŒâã¡
ãã«ãã³ãŸã€ã«ïŒãã³ãŒã³ïŒãšãã¬ã³ãã¹ïŒãã³
ãŸã€ã«ããšãã«ãšãŒãã«ïŒïŒãã¹ïŒãã³ãŸã€ã«ã¡
ãã«ïŒãšãŒãã«ïŒããªã¹ïŒãã³ãŸã€ã«ããšãã
ã·ïŒãã³ãŒã³ïŒãã¹ïŒïŒâã¡ããã·ãã³ãŸã€ã«ã¡
ãã«ãšãŒãã«ïŒçãæããããããŸãããã€ãå ¬
éç¹èš±æ现æžç¬¬1769168å·ïŒç¬¬1769853å·ïŒç¬¬
1807297å·ïŒç¬¬1807301å·ïŒç¬¬1919678å·åã³ç¬¬
1949010å·ã«æããããŠããæ¶æ©åå¿å©å€ã®ãã¡
ããªãšã¹ãã«ã®æº¶è§Šäžå®è³ªçã«å®å®ã§ãããã®ã¯
é©å®äœ¿çšåºæ¥ãã ãŸããå ±éåå¯èœãªååç©ãšããŠã¯ãäŸãã°ã
ã³ãŸããšãã³ïŒïŒ4â²âãžã«ã«ãã³é žçãäŸç€ºãã
ãããããæ¶æ©åå¿å©å€ã®ãã¡ããã³ãžã«åã³ã
ã®èªå°äœã奜ãŸãããç¹ã«ãã³ãžã«èªå°äœã掻æ§
ãé«ãã®ã§å¥œãŸããããŸãè³éŠæã±ãã³é¡ã®ãã¡
ãã³ãŸããšãã³æ®åºãïŒå以äžæããååç©ã掻
æ§ãé«ãã®ã§å¥œãŸããã æ¬çºæã«æŒããæ¶æ©åå¿å©å€ã®äœ¿çšéã¯ãããª
ãšã¹ãã«100éééšã«å¯Ÿãã0.01ã20éééšã奜
ãŸããã¯0.05ã10éééšãæŽã«å¥œãŸããã¯0.1ã
ïŒéééšãç¹ã«å¥œãŸããã¯0.1ãïŒéééšã§ã
ãã å°ãæ¬çºæã«ãããŠã¯ãåèšèèªæç³»äžé£œååº
ãšæ¶æ©åå¿å©å€äœçšã®ïŒã€ã®æ©èœãããªãšã¹ãã«
ãæããŠããã°ãããåŸã€ãŠèèªæç³»äžé£œååºã
æããååç©ãšæ¶æ©åå¿å©å€äœçšãæããååç©
ãç°ãªãå Žåã«å¿è«ã®ããšãäžèšïŒçš®é¡ã®æ©èœã
åæã«åããååç©ã§ããã°ïŒçš®é¡ã®ååç©ãã
ãªãšã¹ãã«ã«å ±éååã³ïŒåã¯ãã¬ã³ããããã
ããšã«ããæ¬çºæã®ç®çãéæããããšãã§ã
ãããããïŒçš®é¡ã®æ©èœãæããååç©ãšããŠ
ã¯ãäŸãã°ïŒ®âã¢ãªã«ïŒåã¯ã¯ããã«åã¯ã¡ã¿ã¢
ãªã«ïŒãã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ®âã¢ãªã«ïŒå
ã¯ã¯ããã«åã¯ã¡ã¿ã¢ãªã«ïŒã¢ã³ãã©ããã³ã«ã«
ããã·ã¢ããïŒïŒ®âã¢ãªã«ïŒåã¯ã¯ãããã«åã¯
ã¡ã¿ã¢ãªã«ïŒãã³ãŸã€ã«ãã¿ã«ã€ããïŒïŒ®ïŒïŒ®â
ãžã¢ãªã«ïŒåã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒã
ã³ãŸã€ã«ãã³ãºã¢ããïŒïŒ®ïŒNâ²âãžã¢ãªã«ïŒå
ã¯ãžã¯ããã«åã¯ãžã¡ã¿ã¢ãªã«ïŒåã¯ãžã¯ããã«
åã¯ãžã¡ã¿ã¢ãªã«ïŒãã³ãŸããšãã³ããã©ã«ã«ã
ãã·ã€ããçãæããããã æ¬çºæã®æ¶æ©ããããªãšã¹ãã«å®¹åšã¯ãäŸãã°
æå®éã®èèªæç³»äžé£œååºãšæ¶æ©åå¿å©å€ãšãå«
æããããªãšã¹ãã«ãã該ããªãšã¹ãã«ã®æº¶èäž
ææã®ãã€ã«ã åã¯ã·ãŒããšãªãã次ãã§è©²ãã€
ã«ã åã¯ã·ãŒããæ·±çµãæ圢ããŠå®¹åšãšãªããäž
ã€ãã€ã«ã åã¯ã·ãŒãæ圢åã®æ®µéã§æ¶æ©åŠçã
æœãããšã«ãã€ãŠåŸããããå ±éåã«ãã€ãŠèèª
æç³»äžé£œååºåã¯æ¶æ©åå¿å©å€ãããªãšã¹ãã«ã«
å«æãããå Žåãéåžžäžè¿°ã®é žæåãã°ãªã³ãŒã«
æååã³å ã«äŸç€ºããåŠãååç©ãåŸæ¥å ¬ç¥ã®æ¹
æ³ã§åå¿ãããããã®å Žåãèèªæç³»äžé£œååºå
ã³ïŒåã¯æ¶æ©åå¿å©å€ãéå°ã«å ±éåããããã
ãªãšã¹ãã«ãäºãäœãããããèèªæç³»äžé£œååº
åã³ïŒåã¯æ¶æ©åå¿å©å€ãå«æããªããåã¯å°å²
åå ±éåããããªãšã¹ãã«ãšæº¶èãã¬ã³ãããã
ãããããããã¹ã¿ãŒãããæ¹åŒã奜ãŸããçšã
ãããã ãŸãããã¬ã³ãã«ãã€ãŠèèªæç³»äžé£œååºå
ã³ïŒåã¯æ¶æ©åå¿å©å€ãããªãšã¹ãã«ã«å«æãã
ããå Žåãéåžžããªãšã¹ãã«ãšèèªæç³»äžé£œååº
ãæããååç©åã³ïŒåã¯æ¶æ©åå¿å©å€ãšäŸãã°
åãã¬ã³ããŒãåãã¬ã³ããŒã®åŠãæ©æ¢°çæ··
åæ段ã§æ··åãã次ãã§ãšã¯ã¹ãã«ãŒããŒã®åŠã
æ··ç·Žæ©ãçšããŠäž¡è ã該ããªãšã¹ãã«ã溶èç¶æ
ãšãªã枩床åã¯ãã以äžã奜ãŸããã¯è©²ããªãšã¹
ãã«ã®èç¹åã¯è©²èç¹ããçŽ60âé«ã枩床ã®ç¯å²
ã§åäžã«ãã¬ã³ãããã 次ã«æº¶èæ圢ã«ããæªæ¶æ©ã®ã·ãŒãåã¯ãã€ã«
ã ãæ圢ããããã®æ圢ã¯ãéåžžããªãšã¹ãã«ã®
èç¹ä»¥äžã奜ãŸããã¯ããªãšã¹ãã«ã®èç¹ã該ã
ãªãšã¹ãã«ã®å解枩床æªæºã奜ãŸããã¯è©²èç¹ã
ãçŽ60âé«ã枩床ãŸã§ã§è¡ãã ããããŠåŸãããã·ãŒãåã¯ãã€ã«ã ãã容åš
ãžã®æ圢ã¯è©²ã·ãŒãåã¯ãã€ã«ã ãåŸæ¥å ¬ç¥ã®ã
ãã«æ·±çµãæåéåã«è£ å¡«ããæžå§åã³ïŒåã¯å
å§äžã§çµã蟌ãããšã«ããéãããããããã®ãš
ãã®æž©åºŠãšããŠã¯è©²ããªãšã¹ãã«çŽ æã®äºæ¬¡è»¢ç§»
ç¹ä¹è³æº¶è枩床ã®éã§ããã®ããããæ¬çºæã§ã¯
ãã€ã«ã åã¯ã·ãŒãæ圢以éã®ä»»æã®æ®µéã§æŽ»æ§
ç·ãç §å°ããããšã«ãã該ããªãšã¹ãã«ã«æ¶æ©å€
åãèµ·ãããããããã«ãã掻æ§ç·ãšã¯æŸå°ç·ã
玫å€ç·çãããããæ¬ä»¶çºæã«ç¹ã«æå¹ãªãã®ã¯
玫å€ç·ã§ãããç §å°ããæéãšããŠã¯ãç·æºã®åŒ·
床ã«å¿ããŠèª¿ç¯ãããã¹ãã§ããããéåžž0.1ã
10æéã奜ãŸããã¯0.5ç§ãïŒæéããã奜ãŸã
ãã¯ïŒç§ã30åãç¹ã«å¥œãŸããã¯10ç§ã10åçšåºŠ
ã§ãããæ¬çºæã«ããã掻æ§ç·ç §å°ã®å ·äœçæ æ§
ã¯æ¬¡ã®éãã§ããã (1) ãã€ã«ã åã¯ã·ãŒãã®æ圢æä¹è³æ圢åŸè©²ã
ã€ã«ã åã¯ã·ãŒãã«æŽ»æ§ç·ãç §å°ãã次ãã§æ·±
çµãæ圢ãè¡ãªãããã®å Žåã«ã¯ãã€ã«ã åã¯
ã·ãŒãã®æº¶è枩床ã¯ããªãšã¹ãã«çŽ æã®æº¶èæž©
床ããé«ããªãåŸåã«ããã (2) ãã€ã«ã åã¯ã·ãŒãã掻æ§ç·ç §å°äžã§æ·±çµã
æ圢ãããããã¯éåã«ãšãã€ãããŸãŸåæã«
è¡ãªãã (3) ãã€ã«ã åã¯ã·ãŒããæ·±çµãæ圢ããåŸã次
ãã§æŽ»æ§ç·ãç §å°ããããã®æã¯ãçµã蟌ãŸã
ããã€ã«ã åã¯ã·ãŒããéåã«ã¯ãããŸãŸã§ã
ããããã¯å®¹åšãšããŠãšãåºããŠããã§ãã
ãã (4) äžèš(1)ã(3)ã®æ¹æ³ãä»»æã«çµåããŠè¡ããã
ã®å Žåã¯ããªãšã¹ãã«çŽ æã®çµæ¶åé åçã®åºŠ
åã«å¿ããŠçµåããããã æå¹ãªå¹æãçºçŸãããçºã«ã¯ãæ¶æ©å€åã®åºŠ
åãã¯éèŠã§ããããã®æ¶æ©åºŠãšããŠã¯ããªãšã¹
ãã«å®¹åšæ圢ç©ã®åçããªã«ãœã¯ããããšããŒã«
ã«æº¶è§£ãããããšããäžæº¶è§£åãå°ãªããšã10é
éïŒ ä»¥äžå¿ èŠã§ããããã奜ãŸããã¯20ééïŒ ä»¥
äžãç¹ã«å¥œãŸããã¯50ééïŒ ä»¥äžã§ããã å°ãæ¬çºæã«ãããŠã¯å®¹åšæ圢äœã«å皮添å å€
äŸãã°ç±å®å®å€ãçè²å€çãé©å®å«æãããŠããŠ
ãããããéææ§ãæããªãããšãå¿ èŠã§ããã æ¬çºæã«ããã°æŽ»æ§ç·ãç §å°ãããšãã容æãª
æ¹æ³ã«ãããåªããèç±æ§ãèè¬åæ§åã³æ©æ¢°ç
ç¹æ§çãæ¹åãããããªãšã¹ãã«å®¹åšãå·¥æ¥çã«
æå©ã«æäŸããããšãåºæ¥ãã 以äžã«å®æœäŸã«ãã説æããã以äžã§ãéšããš
瀺ãããã®ã¯ãããšããããªãéãéééšã瀺
ãããŸã極éç²åºŠã¯ãªã«ãœã¯ããããšããŒã«äž40
âã§æž¬å®ããå€ã§ããã å®æœäŸ ïŒ ã€ãœãã¿ã«é žã15ã¢ã«ïŒ å ±éåããããããªãš
ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒæ¥µéç²åºŠ0.62ïŒ100éšãš
ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«ãã¬ãã¿ã©ãã
ïŒéšåã³ãã³ãžã«ãšãã¬ã³ã±ã¿ãŒã«ïŒéšãšãå
ãã¬ã³ããŒã§æ··åããã®ã¡ã275âã§æº¶èããã
ãã€ããæŒãåºããæ¥å·ããåãçŽ0.4mmã®é
æãªã·ãŒããåŸãããã®ã·ãŒãã110âã«å ç±ã
ããéæ¿äžã«çœ®ã100Wé«å§æ°Žéç¯ã§15cmã®è·é¢
ããïŒåéç §å°ããããã®ã·ãŒããå圢ã«åæ
ããçŽåŸ40mmãæ·±ã40mmã®åç圢ã®ç空æ圢çšé
åã«è£ 眮ããŠã130âã«å ç±ãã100ããŒã«ã®ç空
ã«ããçµã蟌ã¿ãè¡ããåç圢ç¶ã«æ圢ãããåŸ
ããã容åšã¯ç¡è²éæã§ã以äžã®æž¬å®ãè¡ã€ãã äžæº¶è§£åã®æž¬å®ã¯ãè©Šæ容åšã®åºéš120mgãå
ããšããè©Šéšç®¡äžã§10mlã®ãªã«ãœã¯ããããšããŒ
ã«ãšãšãã«40âã§30åéããæ¯ãšãããåŸãå 容
ç©ãåžåŒéããéç©ãã¢ã»ãã³ã§æŽã也ç¥åŸ
秀éããããšã«ããããŸã容åšã®ç±å€åœ¢æž©åºŠã¯è©Š
æ容åšãå ç±æµŽã«æµžæŒ¬ããŠåœ¢ããããèµ·ããã¯ã
ãã枩床ãèªã¿ãšãããšã«ããè¡ã€ãããã®å®¹åš
ã¯äžæº¶è§£ç©ãšããŠ84mgãäžããåŸã€ãŠäžæº¶è§£åã¯
70ïŒ ã瀺ããããŸãç±å€åœ¢æž©åºŠã¯89âã瀺ããã ããã«å¯ŸããŠïŒ®ïŒïŒ®ïŒNâ²ïŒNâ²âããã©ã¢ãªã«
ãã¬ãã¿ã©ã·ãåã³ãã³ãžã«ãžã¡ãã«ã±ã¿ãŒã«ã
å«æãããªãã§äžã€çŽ«å€ç·ãç §å°ãããæ圢枩床
ã80âã«ãã以å€ã¯äžèšãšåæ§ã«æ圢ãè¡ã€ãã
ã®ã¯ãäžæº¶è§£åã¯å šããªããç±å€åœ¢æž©åºŠã70âã®
æž©æ°Žã«æŒ¬ããã ãã§çŽã¡ã«åçž®ããŠããŸã€ãã å®æœäŸ ïŒ ãã¬ãã¿ã«é žãžã¡ãã«194éšïŒãšãã¬ã³ã°ãªã³
ãŒã«130éšåã³ïŒâã·ã¯ãããã»ã³âïŒïŒïŒâãž
ã«ã«ãã³é ž8.5éšãåå¿ããããŠåŸãããªãšã¹ã
ã«ïŒæ¥µéç²åºŠ0.63ïŒ100éšã«ããã³ãžã«ãžã¡ãã«
ã±ã¿ãŒã«ïŒéšãæ··åãã280âã§æº¶èãããã€
ããæŒãåºãæ¥å·ããŠåãçŽ0.4mmã®ã·ãŒããåŸ
ãããã®ã·ãŒããå®æœäŸïŒãšåãããã«éåã«è£
çããã110âã«å ç±ãã玫å€ç·ç §å°ãã¯ããã
ãšåæã«ç空ã«ããçµã蟌ã¿ãã¯ããããç §å°ã¯
2KWæ°Žéã©ã³ãã20cmã®è·é¢ããïŒåéè¡ã€
ããåŸããã容åšã¯ç¡è²éæã§å®æœäŸïŒãšåãäž
溶解åãç±å€åœ¢æž©åºŠã枬å®ãããšãããããã43
ïŒ ïŒ79âã瀺ããã玫å€ç·ãç §å°ããåæ§ã«æ圢
ãããã®ã¯äžæº¶è§£åïŒïŒ ãç±å€åœ¢æž©åºŠã¯62âã§ã
ãè¡šã
ãªãããšãã¬ã³ãã¹ïŒãžã¢ãªã«ã€ãœã·ã¢ãã¬ãŒ
ãïŒãå«ãŸãªããã®ãããã¯ãšãã¬ã³ãã¹ïŒãã³
ãŸã€ã«ãã³ãºã¢ããïŒãå«ãŸãªããã®ããåæ§ã«
æ圢ããè©Šæã«çŽ«å€ç·ç §å°ããŠãç±å€åœ¢æž©åºŠã¯ã
ããã65âãš64âã瀺ãã容æã«åçž®å€åœ¢ãèµ·ã
ããèç±æ§ã®åäžã¯èŠãããªãã€ãã
ãïŒãå«ãŸãªããã®ãããã¯ãšãã¬ã³ãã¹ïŒãã³
ãŸã€ã«ãã³ãºã¢ããïŒãå«ãŸãªããã®ããåæ§ã«
æ圢ããè©Šæã«çŽ«å€ç·ç §å°ããŠãç±å€åœ¢æž©åºŠã¯ã
ããã65âãš64âã瀺ãã容æã«åçž®å€åœ¢ãèµ·ã
ããèç±æ§ã®åäžã¯èŠãããªãã€ãã
Claims (1)
- ïŒ ç·ç¶ããªãšã¹ãã«ã®ã·ãŒãåã¯ãã€ã«ã ã該
ãã€ã«ã åã¯ã·ãŒãã®äºæ¬¡è»¢ç§»æž©åºŠä»¥äžã®æž©åºŠã«
å ç±ããæ·±çµãæ圢ããŠããªãšã¹ãã«å®¹åšã補é
ããæ¹æ³ã«ãããŠã該ç·ç¶ããªãšã¹ãã«ãšããŠã
ãªããŒ100ïœåœã0.01ã0.5åœéã®ç·ç¶ããªãšã¹ã
ã«ã®æº¶èæ¡ä»¶äžã§å®è³ªçã«å®å®ã§ããèèªæç³»äž
飜ååºãšããªããŒ100éééšåœã0.01ã20éééš
ã®æ¶æ©åå¿å©å€ãšãå«æããããç·ç¶ããªãšã¹ã
ã«ãçšããäžã€ã·ãŒãåã¯ãã€ã«ã æ圢以éã®ä»»
æã®æ®µéã§è©²ã·ãŒãåã¯ãã€ã«ã ã«æŽ»æ§ç·ãç §å°
ãæ¶æ©åå¿ãèµ·ããããããšãç¹åŸŽãšãããªã«ãœ
ã¯ããããšããŒã«äžæº¶è§£å10ééïŒ ä»¥äžã®æ¶æ©åºŠ
ãæãäžã€éæãªããªãšã¹ãã«å®¹åšã®è£œé æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3605578A JPS54129056A (en) | 1978-03-30 | 1978-03-30 | Production of polyester vessel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3605578A JPS54129056A (en) | 1978-03-30 | 1978-03-30 | Production of polyester vessel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54129056A JPS54129056A (en) | 1979-10-06 |
| JPS626486B2 true JPS626486B2 (ja) | 1987-02-12 |
Family
ID=12459021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3605578A Granted JPS54129056A (en) | 1978-03-30 | 1978-03-30 | Production of polyester vessel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54129056A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6243188U (ja) * | 1985-09-05 | 1987-03-16 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58169418A (ja) * | 1982-03-29 | 1983-10-05 | 倧è®ãå | éµãéããŠåçŽããåºå®ããããšãã§ãããâãã«ãâ |
-
1978
- 1978-03-30 JP JP3605578A patent/JPS54129056A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6243188U (ja) * | 1985-09-05 | 1987-03-16 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54129056A (en) | 1979-10-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004514518A (ja) | æ¹è¯ãããè質æµææ§ãæããäœæº¶èç²åºŠéæ¶è³ªã³ããªãšã¹ãã« | |
| US4292151A (en) | Process for preparing a cured copolyetherester elastomeric composition | |
| JP2003501532A (ja) | é«ã¬ã©ã¹è»¢ç§»æž©åºŠãäœæº¶èç²åºŠã®éæ¶è³ªã³ããªãšã¹ãã« | |
| JPS626486B2 (ja) | ||
| EP0051220B1 (en) | Thermoplastic copolyester elastomers modified with salts of aliphatic polycarboxylic acid | |
| JPS6157851B2 (ja) | ||
| JP2002505710A (ja) | èå ã®æžå°ãããã³ãžãªãã³å«æããªãšã¹ãã« | |
| JPH06116376A (ja) | éå±æ¿è²Œåããçšå ±éåããªãšã¹ãã«åã³ãã£ã«ã | |
| JP4662633B2 (ja) | ããªïŒïŒïŒïŒâãããã¬ã³ïŒïŒïŒâããã¿ã¬ãŒãïŒã®ãã¬ã³ãç© | |
| EP0088369A2 (en) | Thermoplastic copolyester elastomers modified with salts of phenolic compounds | |
| JP3365450B2 (ja) | é«éå床ããªãšã¹ãã«ã®è£œé æ¹æ³ | |
| JPS6134732B2 (ja) | ||
| JPS6119419B2 (ja) | ||
| JPS6120572B2 (ja) | ||
| JPS6120570B2 (ja) | ||
| JPS6157850B2 (ja) | ||
| JPS6147690B2 (ja) | ||
| JPS6243459B2 (ja) | ||
| JPS621968B2 (ja) | ||
| JP2642129B2 (ja) | çµæ¶æ§ã«åªããã¬ã©ã¹ç¹ç¶åŒ·åããªãšã¹ãã«æš¹èçµæç© | |
| JPH04502480A (ja) | ãã©ã³ã¹âïŒïŒïŒââã¹ãã«ãã³ãžã«ã«ãã³é žããã³ïŒïŒïŒâãããµã³ãžãªãŒã«ããã®ããªãšã¹ãã«ãšããªã«ãŒãããŒãã®é åç© | |
| JPH0362848A (ja) | ããªã¢ãªãŒã¬ãŒãçµæç© | |
| JPS6050585B2 (ja) | æ¹è¯ãããæ§èœãæããã®ã€ | |
| JPS6152178B2 (ja) | ||
| JPS6157853B2 (ja) |