JPS6243921B2 - - Google Patents
Info
- Publication number
- JPS6243921B2 JPS6243921B2 JP56125838A JP12583881A JPS6243921B2 JP S6243921 B2 JPS6243921 B2 JP S6243921B2 JP 56125838 A JP56125838 A JP 56125838A JP 12583881 A JP12583881 A JP 12583881A JP S6243921 B2 JPS6243921 B2 JP S6243921B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- methanol
- reaction
- gas
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 82
- 239000003054 catalyst Substances 0.000 claims description 64
- 238000006243 chemical reaction Methods 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 19
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000000629 steam reforming Methods 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 238000000746 purification Methods 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 238000005336 cracking Methods 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 230000000694 effects Effects 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001651 catalytic steam reforming of methanol Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000013529 heat transfer fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE0/201707A BE884720A (fr) | 1980-08-11 | 1980-08-11 | Procede de reformage de methanol et dispositif mis en oeuvre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5756302A JPS5756302A (en) | 1982-04-03 |
| JPS6243921B2 true JPS6243921B2 (fr) | 1987-09-17 |
Family
ID=3843353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56125838A Granted JPS5756302A (en) | 1980-08-11 | 1981-08-11 | Metal reforming method and device |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5756302A (fr) |
| BE (1) | BE884720A (fr) |
| FR (1) | FR2490615B1 (fr) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59141404A (ja) * | 1983-02-02 | 1984-08-14 | Mitsubishi Heavy Ind Ltd | 液体水素の製造法 |
| JPS59141405A (ja) * | 1983-02-02 | 1984-08-14 | Mitsubishi Heavy Ind Ltd | 液体水素の製造方法 |
| JPS59152205A (ja) * | 1983-02-14 | 1984-08-30 | Mitsubishi Gas Chem Co Inc | メタノ−ルの水蒸気改質法 |
| JPS59184706A (ja) * | 1983-04-05 | 1984-10-20 | Marutani Kakoki Kk | メタノ−ルより水素を製造する方法 |
| DE3314932A1 (de) * | 1983-04-25 | 1984-10-25 | Conoco Inc., Stamford, Conn. | Methanolspaltung unter verwendung eines kupfer-chrom-mangan-katalysators |
| JPH07177B2 (ja) * | 1984-10-05 | 1995-01-11 | 川崎重工業株式会社 | メタノ−ル・スチ−ムリフォ−ミング用触媒の製造方法 |
| FR2572380B2 (fr) * | 1984-10-30 | 1990-05-04 | Catalysts Chemical Europ | Procede de reformage de methanol et dispositif de mise en oeuvre |
| JPS61197401A (ja) * | 1985-02-21 | 1986-09-01 | Mitsubishi Kakoki Kaisha Ltd | メタノ−ル接触分解方法 |
| DE3528858C2 (de) * | 1985-08-12 | 1997-01-23 | Caloric Anlagenbau Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas durch Spaltung von Kohlenwasserstoffen |
| GB8521953D0 (en) * | 1985-09-04 | 1985-10-09 | Johnson Matthey Plc | Catalytic hydrogen generator |
| FR2622563B1 (fr) * | 1987-10-29 | 1990-02-16 | Azote & Prod Chim | Procede de reformage de methanol impur et dispositif de mise en oeuvre |
| JPH07116517A (ja) * | 1993-10-29 | 1995-05-09 | Takeshi Masumoto | メタノール改質用触媒およびその製造方法並びにメタノールの改質法 |
| US6583084B2 (en) | 2000-07-18 | 2003-06-24 | Mitsui Chemicals, Inc. | Catalyst for steam reforming of methanol and method for producing hydrogen therewith |
| JP2002079101A (ja) * | 2000-09-08 | 2002-03-19 | Hiroshima Industrial Technology Organization | メタノール水蒸気改質用触媒前駆体並びにメタノール水蒸気改質用触媒及びその製造方法 |
| JP4199593B2 (ja) * | 2003-05-26 | 2008-12-17 | 本田技研工業株式会社 | 純水素製造装置 |
| AU2006332008C1 (en) * | 2005-12-21 | 2014-02-20 | Virent, Inc. | Catalysts and methods for reforming oxygenated compounds |
| CA2647653C (fr) * | 2006-03-24 | 2014-11-25 | Wisconsin Alumni Research Foundation | Procede de production d'un biocombustible qui integre la chaleur issue de reactions de formation de liaisons carbone-carbone pour alimenter des reactions de gazeification de biomasse |
| CN100420517C (zh) * | 2006-05-26 | 2008-09-24 | 西南化工研究设计院 | 甲醇水蒸汽重整制氢用铜基催化剂的还原方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231995A (en) * | 1975-09-08 | 1977-03-10 | Nissan Motor Co Ltd | Gas generator |
| JPS52156194A (en) * | 1976-06-22 | 1977-12-26 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS54124003A (en) * | 1978-03-04 | 1979-09-26 | Metallgesellschaft Ag | Production of fuel gas |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3179500A (en) * | 1961-04-24 | 1965-04-20 | Thompson Ramo Wooldridge Inc | Hydrogen generation and purification system |
| DE1667721A1 (de) * | 1967-12-15 | 1971-06-24 | Siemens Ag | Verfahren zur Herstellung von Wasserstoff |
| US3469944A (en) * | 1968-05-13 | 1969-09-30 | Joseph P Bocard | Process and apparatus for the manufacture of hydrogen for fuel cells |
| DE2220617A1 (de) * | 1972-04-27 | 1973-11-15 | Metallgesellschaft Ag | Verfahren zur herstellung von wasserstoff |
| DE2641113C2 (de) * | 1976-09-13 | 1982-07-22 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Erzeugung eines methanhaltigen Heizgases durch katalytische Umsetzung von Methanol mit Wasserdampf |
| AT372669B (de) * | 1976-09-13 | 1983-11-10 | Metallgesellschaft Ag | Verfahren zur erzeugung eines methanhaltigen heizgases |
| DE2711991B2 (de) * | 1977-03-18 | 1980-10-23 | Caloric Gesellschaft Fuer Apparatebau Mbh, 8032 Graefelfing | Verfahren zur direkten Gewinnung eines aus Wasserstoff und Kohlenmonoxid bestehenden Gasgemisches |
| EP0021736B1 (fr) * | 1979-06-27 | 1985-12-04 | Imperial Chemical Industries Plc | Procédé catalytique utilisant du monoxyde de carbone et de l'hydrogène |
-
1980
- 1980-08-11 BE BE0/201707A patent/BE884720A/fr not_active IP Right Cessation
-
1981
- 1981-08-03 FR FR8115015A patent/FR2490615B1/fr not_active Expired
- 1981-08-11 JP JP56125838A patent/JPS5756302A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231995A (en) * | 1975-09-08 | 1977-03-10 | Nissan Motor Co Ltd | Gas generator |
| JPS52156194A (en) * | 1976-06-22 | 1977-12-26 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS54124003A (en) * | 1978-03-04 | 1979-09-26 | Metallgesellschaft Ag | Production of fuel gas |
Also Published As
| Publication number | Publication date |
|---|---|
| BE884720A (fr) | 1981-02-11 |
| JPS5756302A (en) | 1982-04-03 |
| FR2490615B1 (fr) | 1985-10-11 |
| FR2490615A1 (fr) | 1982-03-26 |
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