JPS6241782B2 - - Google Patents
Info
- Publication number
- JPS6241782B2 JPS6241782B2 JP57137450A JP13745082A JPS6241782B2 JP S6241782 B2 JPS6241782 B2 JP S6241782B2 JP 57137450 A JP57137450 A JP 57137450A JP 13745082 A JP13745082 A JP 13745082A JP S6241782 B2 JPS6241782 B2 JP S6241782B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- zeolite
- weight
- alkali metal
- exchanged
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 94
- 239000010457 zeolite Substances 0.000 claims description 56
- 229910021536 Zeolite Inorganic materials 0.000 claims description 53
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 53
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 25
- 229910052782 aluminium Inorganic materials 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 22
- 238000001354 calcination Methods 0.000 claims description 19
- 238000005342 ion exchange Methods 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 13
- 239000004927 clay Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 11
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 8
- 238000001694 spray drying Methods 0.000 claims description 8
- -1 ammonium ions Chemical class 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 description 21
- 239000000243 solution Substances 0.000 description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 16
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 15
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 15
- 235000011130 ammonium sulphate Nutrition 0.000 description 15
- 229910052570 clay Inorganic materials 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 10
- 239000002002 slurry Substances 0.000 description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 238000005336 cracking Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 150000002500 ions Chemical group 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical group [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- RKFMOTBTFHXWCM-UHFFFAOYSA-M [AlH2]O Chemical compound [AlH2]O RKFMOTBTFHXWCM-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- UPDATVKGFTVGQJ-UHFFFAOYSA-N sodium;azane Chemical compound N.[Na+] UPDATVKGFTVGQJ-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29117881A | 1981-08-10 | 1981-08-10 | |
| US291178 | 1994-08-16 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1028805A Division JPH01266853A (ja) | 1981-08-10 | 1989-02-09 | 触媒の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5836637A JPS5836637A (ja) | 1983-03-03 |
| JPS6241782B2 true JPS6241782B2 (pt) | 1987-09-04 |
Family
ID=23119212
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57137450A Granted JPS5836637A (ja) | 1981-08-10 | 1982-08-09 | 触媒の製造法 |
| JP62006268A Pending JPS62265389A (ja) | 1981-08-10 | 1987-01-16 | 炭化水素のクラツキング法 |
| JP1028805A Pending JPH01266853A (ja) | 1981-08-10 | 1989-02-09 | 触媒の製法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62006268A Pending JPS62265389A (ja) | 1981-08-10 | 1987-01-16 | 炭化水素のクラツキング法 |
| JP1028805A Pending JPH01266853A (ja) | 1981-08-10 | 1989-02-09 | 触媒の製法 |
Country Status (10)
| Country | Link |
|---|---|
| JP (3) | JPS5836637A (pt) |
| AU (1) | AU563268B2 (pt) |
| BE (1) | BE894074A (pt) |
| BR (1) | BR8204542A (pt) |
| DE (1) | DE3229071A1 (pt) |
| FR (1) | FR2510906B1 (pt) |
| GB (1) | GB2109696B (pt) |
| IT (1) | IT1152490B (pt) |
| MX (1) | MX156975A (pt) |
| NL (1) | NL8203099A (pt) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4458023A (en) * | 1981-08-10 | 1984-07-03 | W. R. Grace & Co. | Catalyst manufacture |
| US4810369A (en) * | 1987-05-07 | 1989-03-07 | Union Oil Company Of California | Process for the catalytic cracking of feedstocks containing high levels of nitrogen |
| WO2003004444A1 (en) | 2001-07-02 | 2003-01-16 | Exxonmobil Chemical Patents Inc. | Inhibiting catalyst coke formation in the manufacture of an olefin |
| US6872680B2 (en) | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| US7271123B2 (en) | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
| JP5185943B2 (ja) | 2006-11-13 | 2013-04-17 | アルベマール・ネーザーランズ・ベー・ブイ | Ｆｃｃ触媒の製造方法 |
| DE102006058632A1 (de) * | 2006-12-13 | 2008-06-19 | Albemarle Netherlands B.V. | Verfahren zur Herstellung eines FCC-Katalysators |
| JP4859766B2 (ja) * | 2007-06-22 | 2012-01-25 | 日揮触媒化成株式会社 | 流動接触分解触媒の製造方法 |
| JP5084560B2 (ja) * | 2008-02-29 | 2012-11-28 | 日揮触媒化成株式会社 | 流動接触分解触媒及びその製造方法 |
| TWI611014B (zh) * | 2012-07-23 | 2018-01-11 | Ｗ Ｒ 康格雷氏公司 | 經鎂穩定之極低蘇打催化裂解觸媒及其形成方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3425956A (en) * | 1964-03-26 | 1969-02-04 | Grace W R & Co | Process for preparing molecular sieve containing cracking catalysts |
| US3393156A (en) * | 1965-09-20 | 1968-07-16 | Union Oil Co | Pelleted zeolite compositions |
| US3632835A (en) * | 1969-02-25 | 1972-01-04 | Universal Oil Prod Co | Hydrocarbon isomerization process |
| CA967136A (en) * | 1969-07-28 | 1975-05-06 | Apparao T. Lengade | Hydrocarbon conversion catalyst |
| DE2036321A1 (de) * | 1970-07-22 | 1972-01-27 | Fa August Bilstein, 5828 Ennepetal | Kippverriegelung fur Dreh Kipp Fenster, Türen o dgl |
| DE2602416A1 (de) * | 1976-01-23 | 1977-07-28 | Basf Ag | Verfahren zur herstellung von basische aluminiumchloride als bindemittel enthaltenden zeolithformlingen |
-
1982
- 1982-08-03 MX MX193877A patent/MX156975A/es unknown
- 1982-08-03 BR BR8204542A patent/BR8204542A/pt unknown
- 1982-08-04 NL NL8203099A patent/NL8203099A/nl not_active Application Discontinuation
- 1982-08-04 DE DE19823229071 patent/DE3229071A1/de not_active Withdrawn
- 1982-08-04 AU AU86739/82A patent/AU563268B2/en not_active Ceased
- 1982-08-06 IT IT8222781A patent/IT1152490B/it active
- 1982-08-06 GB GB08222744A patent/GB2109696B/en not_active Expired
- 1982-08-09 JP JP57137450A patent/JPS5836637A/ja active Granted
- 1982-08-09 FR FR8213883A patent/FR2510906B1/fr not_active Expired
- 1982-08-10 BE BE0/208782A patent/BE894074A/fr not_active IP Right Cessation
-
1987
- 1987-01-16 JP JP62006268A patent/JPS62265389A/ja active Pending
-
1989
- 1989-02-09 JP JP1028805A patent/JPH01266853A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE3229071A1 (de) | 1983-02-24 |
| NL8203099A (nl) | 1983-03-01 |
| AU8673982A (en) | 1984-12-20 |
| JPH01266853A (ja) | 1989-10-24 |
| FR2510906A1 (fr) | 1983-02-11 |
| GB2109696A (en) | 1983-06-08 |
| IT8222781A0 (it) | 1982-08-06 |
| IT1152490B (it) | 1986-12-31 |
| BR8204542A (pt) | 1983-07-26 |
| JPS62265389A (ja) | 1987-11-18 |
| JPS5836637A (ja) | 1983-03-03 |
| MX156975A (es) | 1988-10-18 |
| AU563268B2 (en) | 1987-07-02 |
| GB2109696B (en) | 1985-03-27 |
| BE894074A (fr) | 1982-12-01 |
| FR2510906B1 (fr) | 1986-12-12 |
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