JPS6225700B2 - - Google Patents
Info
- Publication number
- JPS6225700B2 JPS6225700B2 JP22798983A JP22798983A JPS6225700B2 JP S6225700 B2 JPS6225700 B2 JP S6225700B2 JP 22798983 A JP22798983 A JP 22798983A JP 22798983 A JP22798983 A JP 22798983A JP S6225700 B2 JPS6225700 B2 JP S6225700B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- units
- copolymer
- matrix polymer
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 claims description 30
- 239000011342 resin composition Substances 0.000 claims description 28
- 239000011159 matrix material Substances 0.000 claims description 27
- 229920000642 polymer Polymers 0.000 claims description 27
- 229920000578 graft copolymer Polymers 0.000 claims description 26
- -1 aromatic vinyl compound Chemical class 0.000 claims description 21
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 15
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000005060 rubber Substances 0.000 claims description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000005062 Polybutadiene Substances 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- MEBONNVPKOBPEA-UHFFFAOYSA-N 1,1,2-trimethylcyclohexane Chemical compound CC1CCCCC1(C)C MEBONNVPKOBPEA-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000010556 emulsion polymerization method Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical group CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical group CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 150000001733 carboxylic acid esters Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22798983A JPS60120734A (ja) | 1983-12-02 | 1983-12-02 | 透明な耐熱耐衝撃性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22798983A JPS60120734A (ja) | 1983-12-02 | 1983-12-02 | 透明な耐熱耐衝撃性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60120734A JPS60120734A (ja) | 1985-06-28 |
| JPS6225700B2 true JPS6225700B2 (fr) | 1987-06-04 |
Family
ID=16869417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22798983A Granted JPS60120734A (ja) | 1983-12-02 | 1983-12-02 | 透明な耐熱耐衝撃性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60120734A (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY124925A (en) | 2000-07-26 | 2006-07-31 | Toray Industries | Rubber-reinforced styrene transparent resin composition and method of producing the same |
| EP1602688B1 (fr) | 2003-03-12 | 2010-05-19 | Toray Industries, Inc. | Composition de resine thermoplastique, article moule, et film |
| JP4984419B2 (ja) * | 2004-04-16 | 2012-07-25 | 東レ株式会社 | 樹脂成形品 |
| JP5902880B2 (ja) * | 2006-11-10 | 2016-04-13 | 株式会社カネカ | （メタ）アクリル樹脂組成物、イミド化（メタ）アクリル樹脂組成物、およびそれらを成形してなるフィルム |
| CN113943469A (zh) * | 2020-07-17 | 2022-01-18 | 中国石油天然气股份有限公司 | 改性聚甲基丙烯酸甲酯树脂及其制备方法和制备用组合物 |
-
1983
- 1983-12-02 JP JP22798983A patent/JPS60120734A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60120734A (ja) | 1985-06-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4605699A (en) | Thermoplastic molding compositions containing polycarbonate and an acrylate graft copolymer | |
| JP5599973B2 (ja) | 改良された低光沢性を示す塊状重合されたゴム改質モノビニリデン芳香族共重合体組成物 | |
| US4631307A (en) | Heat-resistant high impact styrene resin, process for production thereof, and resin composition comprising said styrene resin | |
| EP0218229B1 (fr) | Composition de résine thermoplastique et son procédé de préparation | |
| JPS6314740B2 (fr) | ||
| JPS62106915A (ja) | ポリ塩化ビニル用透明性、衝撃性改善剤 | |
| JPS58217501A (ja) | 新規共重合体 | |
| KR20150123709A (ko) | 내열성 스티렌계 공중합체 및 이를 포함하는 스티렌계 수지 조성물 | |
| JPS6225700B2 (fr) | ||
| CN107709455B (zh) | 热塑性树脂组合物和由该组合物制造的模制品 | |
| JPH0320348A (ja) | 高度の耐老化性を有する重合体混合物 | |
| JPS6313453B2 (fr) | ||
| EP0284428A2 (fr) | Copolymère greffé et composition de résine à base de styrène | |
| JP2524367B2 (ja) | 残存ブタジエン含量を低滅させたａｂｓ成形用組成物 | |
| US4937286A (en) | Thermoplastic moulding compositions | |
| JPH07718B2 (ja) | 重合体組成物 | |
| FR2750995A1 (fr) | Composition de resine contenant du caoutchouc et composition de resine de styrene la contenant | |
| JP4610966B2 (ja) | 耐熱性ゴム変性スチレン系樹脂組成物 | |
| JPH0559124B2 (fr) | ||
| JP2005068427A (ja) | ゴム変性スチレン系樹脂組成物 | |
| JP3386532B2 (ja) | 熱可塑性樹脂組成物 | |
| JPH06145455A (ja) | 熱可塑性樹脂組成物 | |
| JPS6056742B2 (ja) | 樹脂組成物 | |
| JPH0613635B2 (ja) | ポリカーボネート系樹脂組成物の製造方法 | |
| KR100461524B1 (ko) | 내스팀성이우수한열가소성수지조성물 |