JPS6314740B2 - - Google Patents
Info
- Publication number
- JPS6314740B2 JPS6314740B2 JP57011866A JP1186682A JPS6314740B2 JP S6314740 B2 JPS6314740 B2 JP S6314740B2 JP 57011866 A JP57011866 A JP 57011866A JP 1186682 A JP1186682 A JP 1186682A JP S6314740 B2 JPS6314740 B2 JP S6314740B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- weight
- parts
- temperature
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 claims description 37
- 239000000178 monomer Substances 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- 229920002554 vinyl polymer Polymers 0.000 claims description 18
- 229920000578 graft copolymer Polymers 0.000 claims description 17
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 15
- -1 N-substituted phenylmaleimide Chemical class 0.000 claims description 12
- 229920001971 elastomer Polymers 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000011342 resin composition Substances 0.000 claims description 8
- 229920005992 thermoplastic resin Polymers 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 238000002156 mixing Methods 0.000 description 10
- 238000005979 thermal decomposition reaction Methods 0.000 description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical class O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000003949 imides Chemical group 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1186682A JPS58129043A (ja) | 1982-01-29 | 1982-01-29 | 熱可塑性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1186682A JPS58129043A (ja) | 1982-01-29 | 1982-01-29 | 熱可塑性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58129043A JPS58129043A (ja) | 1983-08-01 |
| JPS6314740B2 true JPS6314740B2 (fr) | 1988-04-01 |
Family
ID=11789635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1186682A Granted JPS58129043A (ja) | 1982-01-29 | 1982-01-29 | 熱可塑性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58129043A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6342748U (fr) * | 1986-09-03 | 1988-03-22 |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58206657A (ja) * | 1982-05-26 | 1983-12-01 | Denki Kagaku Kogyo Kk | 熱可塑性樹脂組成物 |
| JPH0764963B2 (ja) * | 1983-08-24 | 1995-07-12 | 電気化学工業株式会社 | 熱可塑性樹脂組成物 |
| JPS6191239A (ja) * | 1983-09-12 | 1986-05-09 | アトランテイツク・リツチフイ−ルド・カンパニ− | ポリマ−アロイ |
| US4663390A (en) * | 1983-10-03 | 1987-05-05 | Atlantic Richfield Company | Methylmethacrylate/phenylmaleimide copolymer and styrene/maleic anhydride copolymer containing polymer alloys |
| JPS60155255A (ja) * | 1984-01-23 | 1985-08-15 | Denki Kagaku Kogyo Kk | 熱可塑性樹脂組成物のメツキ品 |
| JPS60181155A (ja) * | 1984-02-28 | 1985-09-14 | Denki Kagaku Kogyo Kk | 耐摩耗性にすぐれた熱可塑性樹脂組成物 |
| JPS60184546A (ja) * | 1984-03-05 | 1985-09-20 | Denki Kagaku Kogyo Kk | 発泡成形用熱可塑性樹脂組成物 |
| JPS60212450A (ja) * | 1984-04-05 | 1985-10-24 | Denki Kagaku Kogyo Kk | ランプハウジング部品成形物 |
| WO1986004337A1 (fr) * | 1985-01-17 | 1986-07-31 | Mitsubishi Rayon Co., Ltd. | Procede de production d'un copolymere de maleimide, et resine thermoplastique preparee a l'aide dudit copolymere |
| JPS61174247A (ja) * | 1985-01-29 | 1986-08-05 | Mitsubishi Rayon Co Ltd | 耐熱性および耐衝撃性熱可塑性樹脂組成物 |
| JPS61179252A (ja) * | 1985-02-04 | 1986-08-11 | Mitsubishi Rayon Co Ltd | 耐熱性および耐衝撃性にすぐれた熱可塑性樹脂組成物 |
| CA1272321A (fr) * | 1985-08-27 | 1990-07-31 | Mune Iwamoto | Resine de copolymere disperse de caoutchouc |
| JPH0651742B2 (ja) * | 1985-10-17 | 1994-07-06 | 電気化学工業株式会社 | 光学機器部品成形物 |
| JPH0794586B2 (ja) * | 1987-06-03 | 1995-10-11 | 株式会社日本触媒 | 耐熱分解性の改良されたメタクリル系樹脂組成物 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1213061A (en) * | 1964-04-21 | 1970-11-18 | Ici Ltd | Copolymers of acrylonitrile (and/or methacrylonitrile) aromatic olefine and n-aryl maleimide |
| US3766142A (en) * | 1964-04-21 | 1973-10-16 | Ici Ltd | Acrylonitrile copolymers |
| JPS53117050A (en) * | 1977-03-19 | 1978-10-13 | Bayer Ag | Thermoplastic molding composition |
| JPS5798536A (en) * | 1980-12-11 | 1982-06-18 | Mitsubishi Monsanto Chem Co | Heat-resistant resin composition |
| JPS57125242A (en) * | 1981-01-28 | 1982-08-04 | Denki Kagaku Kogyo Kk | Thermoplastic resin composition |
| JPS57125241A (en) * | 1981-01-28 | 1982-08-04 | Denki Kagaku Kogyo Kk | Heat-resistant resin composition |
| JPS57167341A (en) * | 1981-04-08 | 1982-10-15 | Asahi Chem Ind Co Ltd | Thermoplastic resin composition |
-
1982
- 1982-01-29 JP JP1186682A patent/JPS58129043A/ja active Granted
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1213061A (en) * | 1964-04-21 | 1970-11-18 | Ici Ltd | Copolymers of acrylonitrile (and/or methacrylonitrile) aromatic olefine and n-aryl maleimide |
| US3652726A (en) * | 1964-04-21 | 1972-03-28 | Ici Ltd | Thermoplastic compositions |
| US3766142A (en) * | 1964-04-21 | 1973-10-16 | Ici Ltd | Acrylonitrile copolymers |
| JPS53117050A (en) * | 1977-03-19 | 1978-10-13 | Bayer Ag | Thermoplastic molding composition |
| US4204047A (en) * | 1977-03-19 | 1980-05-20 | Bayer Aktiengesellschaft | Thermoplastic moulding composition |
| JPS5798536A (en) * | 1980-12-11 | 1982-06-18 | Mitsubishi Monsanto Chem Co | Heat-resistant resin composition |
| JPS57125242A (en) * | 1981-01-28 | 1982-08-04 | Denki Kagaku Kogyo Kk | Thermoplastic resin composition |
| JPS57125241A (en) * | 1981-01-28 | 1982-08-04 | Denki Kagaku Kogyo Kk | Heat-resistant resin composition |
| JPS57167341A (en) * | 1981-04-08 | 1982-10-15 | Asahi Chem Ind Co Ltd | Thermoplastic resin composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6342748U (fr) * | 1986-09-03 | 1988-03-22 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58129043A (ja) | 1983-08-01 |
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