JPS62178259A

JPS62178259A - ハロゲン化銀写真感光材料

ハロゲン化銀写真感光材料

Info

Publication number: JPS62178259A
Authority: JP; Japan
Prior art keywords: group; silver halide; general formula; alkyl group; groups
Prior art date: 1986-01-31
Legal status : Granted

Application number

JP2098186A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0581025B2 (cs

Inventor

Masao Sasaki

正男佐々木

Kaoru Onodera

薫小野寺

Current Assignee

Konica Minolta Inc

Original Assignee

Konica Minolta Inc

Priority date

1986-01-31

Filing date

1986-01-31

Publication date

1987-08-05

1986-01-31 Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc

1986-01-31 Priority to JP2098186A priority Critical patent/JPS62178259A/ja

1987-08-05 Publication of JPS62178259A publication Critical patent/JPS62178259A/ja

1993-11-11 Publication of JPH0581025B2 publication Critical patent/JPH0581025B2/ja

Status Granted legal-status Critical Current

Links

-1 Silver halide Chemical class 0.000 title claims description 242
229910052709 silver Inorganic materials 0.000 title claims description 109
239000004332 silver Substances 0.000 title claims description 109
239000000463 material Substances 0.000 title claims description 53
125000000217 alkyl group Chemical group 0.000 claims abstract description 100
239000000839 emulsion Substances 0.000 claims abstract description 80
125000003118 aryl group Chemical group 0.000 claims abstract description 44
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 41
125000005843 halogen group Chemical group 0.000 claims abstract description 34
239000003795 chemical substances by application Substances 0.000 claims abstract description 23
238000006243 chemical reaction Methods 0.000 claims abstract description 12
150000001875 compounds Chemical class 0.000 claims description 51
125000003545 alkoxy group Chemical group 0.000 claims description 32
125000004432 carbon atom Chemical group C* 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 11
125000004104 aryloxy group Chemical group 0.000 claims description 10
125000004414 alkyl thio group Chemical group 0.000 claims description 6
125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 5
125000004391 aryl sulfonyl group Chemical group 0.000 claims description 5
125000005110 aryl thio group Chemical group 0.000 claims description 5
125000004429 atom Chemical group 0.000 claims description 5
238000005562 fading Methods 0.000 abstract description 22
239000007800 oxidant agent Substances 0.000 abstract description 2
230000001590 oxidative effect Effects 0.000 abstract description 2
230000007547 defect Effects 0.000 abstract 1
125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 1
239000010410 layer Substances 0.000 description 81
125000001424 substituent group Chemical group 0.000 description 38
239000000975 dye Substances 0.000 description 33
238000000034 method Methods 0.000 description 33
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 31
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 30
238000009835 boiling Methods 0.000 description 29
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 28
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 27
239000003960 organic solvent Substances 0.000 description 26
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 21
238000011161 development Methods 0.000 description 19
235000013339 cereals Nutrition 0.000 description 18
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 18
239000000084 colloidal system Substances 0.000 description 17
238000012545 processing Methods 0.000 description 17
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 16
239000000203 mixture Substances 0.000 description 16
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 15
125000003342 alkenyl group Chemical group 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
238000011282 treatment Methods 0.000 description 14
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 13
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 13
229910052801 chlorine Inorganic materials 0.000 description 12
239000006185 dispersion Substances 0.000 description 12
150000003839 salts Chemical class 0.000 description 12
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 11
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 11
230000000052 comparative effect Effects 0.000 description 11
125000000962 organic group Chemical group 0.000 description 11
239000002245 particle Substances 0.000 description 11
238000000576 coating method Methods 0.000 description 10
125000000623 heterocyclic group Chemical group 0.000 description 10
125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
108010010803 Gelatin Proteins 0.000 description 9
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
239000002253 acid Substances 0.000 description 9
125000004422 alkyl sulphonamide group Chemical group 0.000 description 9
238000004061 bleaching Methods 0.000 description 9
239000011248 coating agent Substances 0.000 description 9
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 9
229920000159 gelatin Polymers 0.000 description 9
239000008273 gelatin Substances 0.000 description 9
235000019322 gelatine Nutrition 0.000 description 9
235000011852 gelatine desserts Nutrition 0.000 description 9
239000000047 product Substances 0.000 description 9
238000005406 washing Methods 0.000 description 9
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 8
125000004421 aryl sulphonamide group Chemical group 0.000 description 8
125000004093 cyano group Chemical group *C#N 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
238000012360 testing method Methods 0.000 description 8
125000000304 alkynyl group Chemical group 0.000 description 7
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 7
125000001309 chloro group Chemical group Cl* 0.000 description 7
229910052731 fluorine Inorganic materials 0.000 description 7
230000001976 improved effect Effects 0.000 description 7
125000001624 naphthyl group Chemical group 0.000 description 7
230000008569 process Effects 0.000 description 7
230000001235 sensitizing effect Effects 0.000 description 7
238000003860 storage Methods 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
206010070834 Sensitisation Diseases 0.000 description 6
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
125000004453 alkoxycarbonyl group Chemical group 0.000 description 6
125000003277 amino group Chemical group 0.000 description 6
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
239000007844 bleaching agent Substances 0.000 description 6
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
229910052794 bromium Inorganic materials 0.000 description 6
239000013078 crystal Substances 0.000 description 6
125000000753 cycloalkyl group Chemical group 0.000 description 6
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
239000011737 fluorine Substances 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 6
125000004433 nitrogen atom Chemical group N* 0.000 description 6
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
230000008313 sensitization Effects 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical group NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
150000007513 acids Chemical class 0.000 description 5
125000005153 alkyl sulfamoyl group Chemical group 0.000 description 5
235000019445 benzyl alcohol Nutrition 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
230000006866 deterioration Effects 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 5
239000002904 solvent Substances 0.000 description 5
125000000565 sulfonamide group Chemical group 0.000 description 5
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
125000002252 acyl group Chemical group 0.000 description 4
125000004423 acyloxy group Chemical group 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 4
HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 4
239000003921 oil Substances 0.000 description 4
230000003287 optical effect Effects 0.000 description 4
125000004430 oxygen atom Chemical group O* 0.000 description 4
WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 4
229910000027 potassium carbonate Inorganic materials 0.000 description 4
235000011181 potassium carbonates Nutrition 0.000 description 4
125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical group NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 4
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 4
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 4
125000004434 sulfur atom Chemical group 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
229910052724 xenon Inorganic materials 0.000 description 4
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
JKRNNIGZNCVVHA-UHFFFAOYSA-N 2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;trimethylazanium Chemical compound C[NH+](C)C.C[NH+](C)C.C[NH+](C)C.C[NH+](C)C.[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JKRNNIGZNCVVHA-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 3
125000004442 acylamino group Chemical group 0.000 description 3
239000000654 additive Substances 0.000 description 3
125000005129 aryl carbonyl group Chemical group 0.000 description 3
125000005161 aryl oxy carbonyl group Chemical group 0.000 description 3
125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 3
150000001721 carbon Chemical group 0.000 description 3
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
230000002542 deteriorative effect Effects 0.000 description 3
230000001804 emulsifying effect Effects 0.000 description 3
125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 3
125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 3
239000007788 liquid Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
QWOKKHXWFDAJCZ-UHFFFAOYSA-N octane-1-sulfonamide Chemical group CCCCCCCCS(N)(=O)=O QWOKKHXWFDAJCZ-UHFFFAOYSA-N 0.000 description 3
150000007524 organic acids Chemical class 0.000 description 3
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
235000011118 potassium hydroxide Nutrition 0.000 description 3
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 3
235000019252 potassium sulphite Nutrition 0.000 description 3
230000005070 ripening Effects 0.000 description 3
230000035945 sensitivity Effects 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QMHAHUAQAJVBIW-UHFFFAOYSA-N [methyl(sulfamoyl)amino]methane Chemical group CN(C)S(N)(=O)=O QMHAHUAQAJVBIW-UHFFFAOYSA-N 0.000 description 2
239000006096 absorbing agent Substances 0.000 description 2
229960000583 acetic acid Drugs 0.000 description 2
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
230000002411 adverse Effects 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
239000003513 alkali Substances 0.000 description 2
125000003282 alkyl amino group Chemical group 0.000 description 2
125000004448 alkyl carbonyl group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
125000003368 amide group Chemical group 0.000 description 2
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
239000002216 antistatic agent Substances 0.000 description 2
125000001769 aryl amino group Chemical group 0.000 description 2
KHBQMWCZKVMBLN-IDEBNGHGSA-N benzenesulfonamide Chemical group NS(=O)(=O)[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 KHBQMWCZKVMBLN-IDEBNGHGSA-N 0.000 description 2
125000004744 butyloxycarbonyl group Chemical group 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 2
229920002301 cellulose acetate Polymers 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
PBHVCRIXMXQXPD-UHFFFAOYSA-N chembl2369102 Chemical compound C1=CC(S(=O)(=O)O)=CC=C1C(C1=CC=C(N1)C(C=1C=CC(=CC=1)S(O)(=O)=O)=C1C=CC(=N1)C(C=1C=CC(=CC=1)S(O)(=O)=O)=C1C=CC(N1)=C1C=2C=CC(=CC=2)S(O)(=O)=O)=C2N=C1C=C2 PBHVCRIXMXQXPD-UHFFFAOYSA-N 0.000 description 2
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
239000000470 constituent Substances 0.000 description 2
125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 2
125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 2
125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 2
238000002845 discoloration Methods 0.000 description 2
230000005611 electricity Effects 0.000 description 2
125000004705 ethylthio group Chemical group C(C)S* 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
230000026030 halogenation Effects 0.000 description 2
238000005658 halogenation reaction Methods 0.000 description 2
230000006872 improvement Effects 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
239000004816 latex Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 2
125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 2
239000012046 mixed solvent Substances 0.000 description 2
150000002780 morpholines Chemical class 0.000 description 2
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000007764 o/w emulsion Substances 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
125000005499 phosphonyl group Chemical group 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
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