JPS6133179B2 - - Google Patents
Info
- Publication number
- JPS6133179B2 JPS6133179B2 JP52120147A JP12014777A JPS6133179B2 JP S6133179 B2 JPS6133179 B2 JP S6133179B2 JP 52120147 A JP52120147 A JP 52120147A JP 12014777 A JP12014777 A JP 12014777A JP S6133179 B2 JPS6133179 B2 JP S6133179B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- dye
- layer
- diffusion
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims description 126
- -1 silver halide Chemical class 0.000 claims description 68
- 229910052709 silver Inorganic materials 0.000 claims description 66
- 239000004332 silver Substances 0.000 claims description 66
- 239000000839 emulsion Substances 0.000 claims description 58
- 238000009792 diffusion process Methods 0.000 claims description 51
- 239000000463 material Substances 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 238000012546 transfer Methods 0.000 claims description 17
- 125000001424 substituent group Chemical group 0.000 claims description 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 9
- 239000002243 precursor Substances 0.000 claims description 8
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 8
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 125000000623 heterocyclic group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000004442 acylamino group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 3
- 125000004663 dialkyl amino group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 125000000732 arylene group Chemical group 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 239000010410 layer Substances 0.000 description 126
- 239000000975 dye Substances 0.000 description 85
- 238000011161 development Methods 0.000 description 47
- 238000007254 oxidation reaction Methods 0.000 description 22
- 239000000047 product Substances 0.000 description 22
- 230000003647 oxidation Effects 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000012545 processing Methods 0.000 description 18
- 239000011230 binding agent Substances 0.000 description 17
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 15
- 230000002378 acidificating effect Effects 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- 239000000049 pigment Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000000979 retarding effect Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000012463 white pigment Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 238000005266 casting Methods 0.000 description 5
- 238000005859 coupling reaction Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 206010070834 Sensitisation Diseases 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229940125904 compound 1 Drugs 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000000967 suction filtration Methods 0.000 description 4
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 3
- TXQAZWIBPGKHOX-UHFFFAOYSA-N 1H-indol-3-amine Chemical class C1=CC=C2C(N)=CNC2=C1 TXQAZWIBPGKHOX-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 125000001041 indolyl group Chemical group 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000007363 ring formation reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 3
- 229940124530 sulfonamide Drugs 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- GAMPNQJDUFQVQO-UHFFFAOYSA-N acetic acid;phthalic acid Chemical compound CC(O)=O.OC(=O)C1=CC=CC=C1C(O)=O GAMPNQJDUFQVQO-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-M phthalate(1-) Chemical compound OC(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-M 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-M succinate(1-) Chemical compound OC(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-M 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- AOSZTAHDEDLTLQ-AZKQZHLXSA-N (1S,2S,4R,8S,9S,11S,12R,13S,19S)-6-[(3-chlorophenyl)methyl]-12,19-difluoro-11-hydroxy-8-(2-hydroxyacetyl)-9,13-dimethyl-6-azapentacyclo[10.8.0.02,9.04,8.013,18]icosa-14,17-dien-16-one Chemical compound C([C@@H]1C[C@H]2[C@H]3[C@]([C@]4(C=CC(=O)C=C4[C@@H](F)C3)C)(F)[C@@H](O)C[C@@]2([C@@]1(C1)C(=O)CO)C)N1CC1=CC=CC(Cl)=C1 AOSZTAHDEDLTLQ-AZKQZHLXSA-N 0.000 description 1
- CYXJEHCKVOQFOV-UHFFFAOYSA-N (4-amino-2-methylphenyl) hydrogen sulfate Chemical compound CC1=CC(N)=CC=C1OS(O)(=O)=O CYXJEHCKVOQFOV-UHFFFAOYSA-N 0.000 description 1
- NCNYEGJDGNOYJX-NSCUHMNNSA-N (e)-2,3-dibromo-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Br)=C(/Br)C=O NCNYEGJDGNOYJX-NSCUHMNNSA-N 0.000 description 1
- NCYNKWQXFADUOZ-UHFFFAOYSA-N 1,1-dioxo-2,1$l^{6}-benzoxathiol-3-one Chemical compound C1=CC=C2C(=O)OS(=O)(=O)C2=C1 NCYNKWQXFADUOZ-UHFFFAOYSA-N 0.000 description 1
- LAHRGLSDDYENEO-UHFFFAOYSA-N 1-(4-pyrrolidin-1-ylphenyl)pyrrolidine Chemical compound C1CCCN1C1=CC=C(N2CCCC2)C=C1 LAHRGLSDDYENEO-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- CJAOGUFAAWZWNI-UHFFFAOYSA-N 1-n,1-n,4-n,4-n-tetramethylbenzene-1,4-diamine Chemical compound CN(C)C1=CC=C(N(C)C)C=C1 CJAOGUFAAWZWNI-UHFFFAOYSA-N 0.000 description 1
- AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical compound SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 description 1
- IKQCSJBQLWJEPU-UHFFFAOYSA-N 2,5-dihydroxybenzenesulfonic acid Chemical compound OC1=CC=C(O)C(S(O)(=O)=O)=C1 IKQCSJBQLWJEPU-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- JHKKTXXMAQLGJB-UHFFFAOYSA-N 2-(methylamino)phenol Chemical compound CNC1=CC=CC=C1O JHKKTXXMAQLGJB-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- OEDQNDJKBBYAHI-UHFFFAOYSA-N 2-ethenyl-1-methyl-2h-pyridine Chemical compound CN1C=CC=CC1C=C OEDQNDJKBBYAHI-UHFFFAOYSA-N 0.000 description 1
- CBHTTYDJRXOHHL-UHFFFAOYSA-N 2h-triazolo[4,5-c]pyridazine Chemical compound N1=NC=CC2=C1N=NN2 CBHTTYDJRXOHHL-UHFFFAOYSA-N 0.000 description 1
- FZLLHXXADRILOZ-UHFFFAOYSA-N 3-(5-sulfanylidene-2h-tetrazol-1-yl)benzoic acid Chemical compound OC(=O)C1=CC=CC(N2C(N=NN2)=S)=C1 FZLLHXXADRILOZ-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- AJKLCDRWGVLVSH-UHFFFAOYSA-N 4,4-bis(hydroxymethyl)-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(CO)(CO)CN1C1=CC=CC=C1 AJKLCDRWGVLVSH-UHFFFAOYSA-N 0.000 description 1
- SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- LJCWONGJFPCTTL-UHFFFAOYSA-N 4-hydroxyphenylglycine Chemical compound OC(=O)C(N)C1=CC=C(O)C=C1 LJCWONGJFPCTTL-UHFFFAOYSA-N 0.000 description 1
- DWAQDRSOVMLGRQ-UHFFFAOYSA-N 5-methoxyindole Chemical compound COC1=CC=C2NC=CC2=C1 DWAQDRSOVMLGRQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229940126657 Compound 17 Drugs 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- NVXLIZQNSVLKPO-UHFFFAOYSA-N Glucosereductone Chemical compound O=CC(O)C=O NVXLIZQNSVLKPO-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- HCUARRIEZVDMPT-UHFFFAOYSA-N Indole-2-carboxylic acid Chemical class C1=CC=C2NC(C(=O)O)=CC2=C1 HCUARRIEZVDMPT-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- LWVVNNZRDBXOQL-AATRIKPKSA-O [(e)-3-(dimethylamino)prop-2-enyl]-dimethylazanium Chemical compound CN(C)\C=C\C[NH+](C)C LWVVNNZRDBXOQL-AATRIKPKSA-O 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- OONCXKMPLHTLBM-UHFFFAOYSA-N acetic acid;pentanedioic acid Chemical compound CC(O)=O.OC(=O)CCCC(O)=O OONCXKMPLHTLBM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 235000016720 allyl isothiocyanate Nutrition 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229960001748 allylthiourea Drugs 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- ISLGHAYMGURDSU-UHFFFAOYSA-N aminomethanesulfinic acid Chemical class NCS(O)=O ISLGHAYMGURDSU-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical group C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical group C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Chemical group 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- QQXQAEWRSVZPJM-UHFFFAOYSA-N ethyl 1h-indole-2-carboxylate Chemical class C1=CC=C2NC(C(=O)OCC)=CC2=C1 QQXQAEWRSVZPJM-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- FBPFZTCFMRRESA-UHFFFAOYSA-N hexane-1,2,3,4,5,6-hexol Chemical compound OCC(O)C(O)C(O)C(O)CO FBPFZTCFMRRESA-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 125000005597 hydrazone group Chemical group 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002731 mercury compounds Chemical class 0.000 description 1
- XCGQJCSSCTYHDV-UHFFFAOYSA-N mercury(1+);sulfane Chemical compound S.[Hg+] XCGQJCSSCTYHDV-UHFFFAOYSA-N 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N methanesulfonic acid Substances CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- MXWHMTNPTTVWDM-NXOFHUPFSA-N mitoguazone Chemical class NC(N)=N\N=C(/C)\C=N\N=C(N)N MXWHMTNPTTVWDM-NXOFHUPFSA-N 0.000 description 1
- PKDBSOOYVOEUQR-UHFFFAOYSA-N mucobromic acid Natural products OC1OC(=O)C(Br)=C1Br PKDBSOOYVOEUQR-UHFFFAOYSA-N 0.000 description 1
- UICBCXONCUFSOI-UHFFFAOYSA-N n'-phenylacetohydrazide Chemical compound CC(=O)NNC1=CC=CC=C1 UICBCXONCUFSOI-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical group 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/30—Indoles; Hydrogenated indoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to carbon atoms of the hetero ring
- C07D209/42—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/08—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds
- G03C8/10—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds of dyes or their precursors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/156—Precursor compound
- Y10S430/159—Development dye releaser, DDR
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Indole Compounds (AREA)
Description
æ¬çºæã¯ãæææ¡æ£è»¢åæ³ã«ããã«ã©ãŒåçç»
åã圢æãããæ¹æ³ã®ããã«é©åœãªãæ°èŠãªèæ¡
æ£æ³ïŒéæ¡æ£æ³ïŒææäŸäžååç©ïŒdyeâ
providing compoundsïŒãå«ãåçææã«é¢ãã
ãã®ã§ããã æææ¡æ£è»¢åæ³ãå©çšããŠã«ã©ãŒåçç»åã圢
æãããæ¹æ³ãšããŠãçš®ã ã®æ¹æ³ãæ¢ã«å ¬ç¥ã§ã
ããã次ã®æ¹æ³ãçŸåšéèŠèŠãããŠãããããªã
ã¡ãææäŸäžååç©ãèæ¡æ£æ§ç©è³ªã®åœ¢ã§åçå±€
å ã«å ¥ããçŸåæäœå®æœäžã«è©²èæ¡æ£æ§ææäŸäž
ååç©ãå解ããŠããããæ¡æ£æ§ææïŒãŸãã¯æ
æåé§äœïŒãé¢è±ãããŠç»åã®åœ¢ã®éãã«ååžã
ãããããç»ååå ¥å±€ã®æ¹ã«ç§»ãããšãããªãæ¹
æ³ãéèŠèŠãããŠããã ãã®ãããªæ¹æ³ã®ããã«ãé©åœãªææäŸäžåå
ç©ã®äŸã«ã¯ãç¬åœç¹èš±ç¬¬1095115å·æ现æžã«èšèŒ
ã®éæ¡æ£æ§ã«ã©ãŒã«ããã©ãŒããããããããã®
ã«ã©ãŒã«ããã©ãŒã¯çŸåæäœå®æœäžã«ç¬¬ïŒè³éŠæ
ã¢ãã³ç³»çºè²çŸåè¬ååç©ã®é žåçæç©ãšåå¿
ãããã®ã«ã©ãŒã«ãããªã³ã°åå¿ã«ããçããæ
æãããã¯ãåãã€ãŠçæãããææãïŒãã¬ã
ãªãŒã ãææïŒãæ¡æ£æ§ç©è³ªã®åœ¢ã§æŸåºãããã
ãã®ç®çã«é©ããçŸåè¬ååç©ã®éžæç¯å²ã¯ãå¿
è«çºè²çŸåè¬é¡ã®ã¿ã«éããããããïŒã€ã®é©åœ
ãªææäŸäžååç©ã¯ãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
1930215å·ã«èšèŒã®èæ¡æ£æ§ååç©ã§ããããã
ãã®ååç©ã¯ãäºãã圢æãããæææ®åºïŒãã®
æ®åºèªäœã¯æœåšçæ¡æ£æ§ãæããïŒãå«ããã®ã§
ãã€ãŠããã®æ®åºã¯é¢è±å¯èœããã©ãŸã³åºãä»ã
ãŠå¥ã®èæ¡æ£æ§æ®åºã«çµåããŠããããã®ååç©
ã¯ã«ã©ãŒã«ããã©ãŒãšã¯ã¿ãªãåŸãªããã®ã§ã
ããå¿ èŠãªåèšã®æ¡æ£æ§æææ®åºãé¢è±ãåŸãäœ
çšãæããçŸåè¬ååç©ã¯ã決ããŠåèšã®åžžçšçº
è²çŸåè¬ã®ã¿ã«éå®ããããã®ã§ã¯ãªããçœé»çš
çŸåè¬ïŒããšãã°ããã«ãã³ãŒã«ïŒããŸãå¿è«äœ¿
çšã§ããã ç¹å®ã®åºãå«ãéæ¡æ£æ§æè²ååç©ãç¬åœç¹èš±
å ¬éå ¬å ±ç¬¬1772929å·ã«é瀺ãããŠããããã®å
åç©ã¯çŸåæäœå®æœäžã«é žåéç°åå¿ãè¡ãªãã
æ¡æ£æ§ã®ãåãã€ãŠåœ¢æãããæææ®åºããé¢è±
ãããäžèšç¬åœå ¬éå ¬å ±ã«èšèŒã®ååç©ã¯ãïŒã€
ã®çš®é¡ã«åé¡ã§ãããïŒã€ã®ã°ã«ãŒãã«å±ããå
åç©ã¯ãçŸåã®ããã«åžžçšçºè²çŸåè¬ååç©ãå¿
èŠãšãããã®ã§ãã€ãŠãããªãã¡ããã¯äžèšçºè²
çŸåè¬ã®é žåçæç©ãšã«ãããªã³ã°åå¿ãè¡ãªã€
ãŠãæ¡æ£æ§ã®ãåãã€ãŠåœ¢æãããæææ®åºã
ããå ¶åŸã®éç°åå¿ã«ããæŸåºãåŸããã®ã§ã
ããããïŒã€ã®ã°ã«ãŒãã«å±ããååç©ã¯ããã
ã²ã³åéçŸåè¬ãæ§æãããã®ã§ãã€ãŠããã®é ž
åçæç©ã¯ãä»ã®çŸåè¬ååç©ã®äžååšäžã«ãã
ãŠããéç°åå¿ãè¡ãªããæ¡æ£æ§ææãæŸåºãåŸ
ããã®ã§ããã æåŸã«ãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2242762å·ã«èšèŒ
ã®èæ¡æ£æ§ææäŸäžååç©ã«ã€ããŠèª¬æãããã
ããã®ååç©ã¯ã¹ã«ãã³ã¢ããããšããŒã«ããã³
ã¹ã«ãã³ã¢ããã¢ããªã³ã§ããããããã®ååç©
ã¯çŸåæã«é žåçæç©ãšãªã€ããšãã«ãçŸåè¬ã®
ã¢ã«ã«ãªã«ããå解ãããéé¢ã¹ã«ãã¢ã¢ã€ã«åº
ããã€æ¡æ£æ§ææãæŸåºããã äžèšã®å ¬ç¥ææäŸäžååç©ã¯ãã¹ãŠãã¬ç»å圢
æçšååç©ã§ãããããªãã¡ïŒãã¬äœæçšã®ïŒåžž
çšããã²ã³åéä¹³å€ã䜿çšããå Žåã«ãçŸåã«ã
ãçãããã¬çšéç»åã®åœ¢ã®éãã«ååžããç¶æ
ã§ãæ¡æ£æ§ææãé¢è±ããã®ã§ããããããã€
ãŠãããžã®ææç»åã®çæã®ããã«ã¯ãçŽæ¥ããž
çšããã²ã³åéä¹³å€ã䜿çšããã¯ãŸãã¯é©åœãªãª
ããŒãµã«ããã»ã¹ãè¡ãªãããšãå¿ èŠã§ããã ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2505248å·ã«ã¯ãæææ¡æ£
æ³ã®ããã®èæ¡æ£æ§ææäŸäžååç©ãšããŠäœ¿çšã§
ããïŒâã¢ããã€ã³ããŒã«èªå°äœãèšèŒãããŠã
ãããã®ååç©ïŒååç©17ïŒã¯ãã€ã³ããŒã«ç°ã®
ïŒâäœçœ®ã«ã¢ã«ã³ãã·çœ®æããšãã«åºãæããã
ã®ã§ããããããã®å ¬ç¥ååç©ãçšããããšã«ã
ããç»åã®åœ¢ã®éãã®ã«ã©ãŒè»¢åïŒææ転åïŒã
å®æœã§ããããã©ãããããã®ååç©ã¯ãã«ã©ãŒ
ã®ãã¶ãã«é¢ããŠäžæºè¶³ãªãã®ã§ãã€ãã ãããã€ãŠæ¬çºæã®ç®çã¯ãå åãªåå¿æ§ãšã
å åãªå®å®æ§ãšãè¯å¥œãªã«ã©ãŒè»¢åæ§ãšãé«ãæ
床ãšãæãããã€ãã¶ããéåžžã«å°ãªãæ°èŠãªè
æ¡æ£æ§ææäŸäžååç©ãæäŸããããšã§ããã ããªãã¡æ¬çºæã¯ãå°ãªããšãïŒã€ã®æå æ§ã
ãã²ã³åéä¹³å€å±€ãšã該局ã«ä»éããèæ¡æ£ææ
äŸäžååç©ãšãæããåçææã«ç»å圢æé²å ã
è¡ãªãããã®ææäŸäžååç©ã®é žåçæç©ã¯ã¢ã«
ã«ãªæ§çŸåè¬åªè³ªäžã§æ¡æ£æ§ææãé¢è±ãåŸãã
ã®ã§ããã該åçææãããã²ã³åéçŸåè¬ã§çŸ
åãããã®çŸåè¬ã®é žåçæç©ã¯åèšææäŸäžå
åç©ãé žåãåŸããã®ã§ãã€ãŠããã®é žååå¿ã®
çµæãåèšææäŸäžååç©ãåèšçŸåè¬ã®ã¢ã«ã«
ãªã«ããå解ããããã®å解ã«ããé¢è±ããæ¡æ£
æ§ææã¯ãç»åã®åœ¢ã®éãã«ååžããç¶æ ã§ååš
ããããã«ãªãããšãå å«ããåçåŠçæææ¡æ£
転åæ¹æ³ã®ããã®åçææã«ãããŠãåèšéæ¡æ£
æ§ææäŸäžååç©ãæ¬¡åŒ ãæããååç©ã§ããããšãç¹åŸŽãšããåçææ
ã«é¢ãããã®ã§ããããã ãäžåŒã«ãããŠãã¯
åèšSO2åºã«çŽæ¥ã«çµåããŠããããŸãã¯ä»åšåº
ãä»ããŠçµåããŠããæææ®åºãŸãã¯ææåé§
äœæ®åºãè¡šããã ã¯ãççŽ ååãïŒâïŒåæããã¢ã«ãã¬ã³åº
ïŒãŸãã¯ã¢ã«ããªãã³åºïŒãã¢ãªãŒã¬ã³åºãŸãã¯è€
çŽ ç°åŒåºã®åŠãä»åšåºãè¡šãããããããŠãã®ä»
åšåºïŒºã¯åèšåºïŒžã«çŽæ¥ã«çµåããŠããããŸãã¯
ââãââãâSO2âãâNRâïŒããã«ïŒ²ïŒæ°Ž
çŽ ãŸãã¯ã¢ã«ãã«åºïŒãâCOâãâCOâNHâãŸã
ã¯âSO2âNHâãä»ããŠçµåããŠãããã®ã§ã
ãã ã¯ãçž®åãã³ãŒã³ç°ãå®æãããã®ã«å¿ èŠãª
åºãè¡šãããããããŠãã®çž®åãã³ãŒã³ç°ã¯çœ®æ
åºãïŒãŸãã¯ãã以äžãã€ãŠããŠãããã R1ã¯âOR2ãâSR2ãŸãã¯
åã圢æãããæ¹æ³ã®ããã«é©åœãªãæ°èŠãªèæ¡
æ£æ³ïŒéæ¡æ£æ³ïŒææäŸäžååç©ïŒdyeâ
providing compoundsïŒãå«ãåçææã«é¢ãã
ãã®ã§ããã æææ¡æ£è»¢åæ³ãå©çšããŠã«ã©ãŒåçç»åã圢
æãããæ¹æ³ãšããŠãçš®ã ã®æ¹æ³ãæ¢ã«å ¬ç¥ã§ã
ããã次ã®æ¹æ³ãçŸåšéèŠèŠãããŠãããããªã
ã¡ãææäŸäžååç©ãèæ¡æ£æ§ç©è³ªã®åœ¢ã§åçå±€
å ã«å ¥ããçŸåæäœå®æœäžã«è©²èæ¡æ£æ§ææäŸäž
ååç©ãå解ããŠããããæ¡æ£æ§ææïŒãŸãã¯æ
æåé§äœïŒãé¢è±ãããŠç»åã®åœ¢ã®éãã«ååžã
ãããããç»ååå ¥å±€ã®æ¹ã«ç§»ãããšãããªãæ¹
æ³ãéèŠèŠãããŠããã ãã®ãããªæ¹æ³ã®ããã«ãé©åœãªææäŸäžåå
ç©ã®äŸã«ã¯ãç¬åœç¹èš±ç¬¬1095115å·æ现æžã«èšèŒ
ã®éæ¡æ£æ§ã«ã©ãŒã«ããã©ãŒããããããããã®
ã«ã©ãŒã«ããã©ãŒã¯çŸåæäœå®æœäžã«ç¬¬ïŒè³éŠæ
ã¢ãã³ç³»çºè²çŸåè¬ååç©ã®é žåçæç©ãšåå¿
ãããã®ã«ã©ãŒã«ãããªã³ã°åå¿ã«ããçããæ
æãããã¯ãåãã€ãŠçæãããææãïŒãã¬ã
ãªãŒã ãææïŒãæ¡æ£æ§ç©è³ªã®åœ¢ã§æŸåºãããã
ãã®ç®çã«é©ããçŸåè¬ååç©ã®éžæç¯å²ã¯ãå¿
è«çºè²çŸåè¬é¡ã®ã¿ã«éããããããïŒã€ã®é©åœ
ãªææäŸäžååç©ã¯ãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
1930215å·ã«èšèŒã®èæ¡æ£æ§ååç©ã§ããããã
ãã®ååç©ã¯ãäºãã圢æãããæææ®åºïŒãã®
æ®åºèªäœã¯æœåšçæ¡æ£æ§ãæããïŒãå«ããã®ã§
ãã€ãŠããã®æ®åºã¯é¢è±å¯èœããã©ãŸã³åºãä»ã
ãŠå¥ã®èæ¡æ£æ§æ®åºã«çµåããŠããããã®ååç©
ã¯ã«ã©ãŒã«ããã©ãŒãšã¯ã¿ãªãåŸãªããã®ã§ã
ããå¿ èŠãªåèšã®æ¡æ£æ§æææ®åºãé¢è±ãåŸãäœ
çšãæããçŸåè¬ååç©ã¯ã決ããŠåèšã®åžžçšçº
è²çŸåè¬ã®ã¿ã«éå®ããããã®ã§ã¯ãªããçœé»çš
çŸåè¬ïŒããšãã°ããã«ãã³ãŒã«ïŒããŸãå¿è«äœ¿
çšã§ããã ç¹å®ã®åºãå«ãéæ¡æ£æ§æè²ååç©ãç¬åœç¹èš±
å ¬éå ¬å ±ç¬¬1772929å·ã«é瀺ãããŠããããã®å
åç©ã¯çŸåæäœå®æœäžã«é žåéç°åå¿ãè¡ãªãã
æ¡æ£æ§ã®ãåãã€ãŠåœ¢æãããæææ®åºããé¢è±
ãããäžèšç¬åœå ¬éå ¬å ±ã«èšèŒã®ååç©ã¯ãïŒã€
ã®çš®é¡ã«åé¡ã§ãããïŒã€ã®ã°ã«ãŒãã«å±ããå
åç©ã¯ãçŸåã®ããã«åžžçšçºè²çŸåè¬ååç©ãå¿
èŠãšãããã®ã§ãã€ãŠãããªãã¡ããã¯äžèšçºè²
çŸåè¬ã®é žåçæç©ãšã«ãããªã³ã°åå¿ãè¡ãªã€
ãŠãæ¡æ£æ§ã®ãåãã€ãŠåœ¢æãããæææ®åºã
ããå ¶åŸã®éç°åå¿ã«ããæŸåºãåŸããã®ã§ã
ããããïŒã€ã®ã°ã«ãŒãã«å±ããååç©ã¯ããã
ã²ã³åéçŸåè¬ãæ§æãããã®ã§ãã€ãŠããã®é ž
åçæç©ã¯ãä»ã®çŸåè¬ååç©ã®äžååšäžã«ãã
ãŠããéç°åå¿ãè¡ãªããæ¡æ£æ§ææãæŸåºãåŸ
ããã®ã§ããã æåŸã«ãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2242762å·ã«èšèŒ
ã®èæ¡æ£æ§ææäŸäžååç©ã«ã€ããŠèª¬æãããã
ããã®ååç©ã¯ã¹ã«ãã³ã¢ããããšããŒã«ããã³
ã¹ã«ãã³ã¢ããã¢ããªã³ã§ããããããã®ååç©
ã¯çŸåæã«é žåçæç©ãšãªã€ããšãã«ãçŸåè¬ã®
ã¢ã«ã«ãªã«ããå解ãããéé¢ã¹ã«ãã¢ã¢ã€ã«åº
ããã€æ¡æ£æ§ææãæŸåºããã äžèšã®å ¬ç¥ææäŸäžååç©ã¯ãã¹ãŠãã¬ç»å圢
æçšååç©ã§ãããããªãã¡ïŒãã¬äœæçšã®ïŒåžž
çšããã²ã³åéä¹³å€ã䜿çšããå Žåã«ãçŸåã«ã
ãçãããã¬çšéç»åã®åœ¢ã®éãã«ååžããç¶æ
ã§ãæ¡æ£æ§ææãé¢è±ããã®ã§ããããããã€
ãŠãããžã®ææç»åã®çæã®ããã«ã¯ãçŽæ¥ããž
çšããã²ã³åéä¹³å€ã䜿çšããã¯ãŸãã¯é©åœãªãª
ããŒãµã«ããã»ã¹ãè¡ãªãããšãå¿ èŠã§ããã ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2505248å·ã«ã¯ãæææ¡æ£
æ³ã®ããã®èæ¡æ£æ§ææäŸäžååç©ãšããŠäœ¿çšã§
ããïŒâã¢ããã€ã³ããŒã«èªå°äœãèšèŒãããŠã
ãããã®ååç©ïŒååç©17ïŒã¯ãã€ã³ããŒã«ç°ã®
ïŒâäœçœ®ã«ã¢ã«ã³ãã·çœ®æããšãã«åºãæããã
ã®ã§ããããããã®å ¬ç¥ååç©ãçšããããšã«ã
ããç»åã®åœ¢ã®éãã®ã«ã©ãŒè»¢åïŒææ転åïŒã
å®æœã§ããããã©ãããããã®ååç©ã¯ãã«ã©ãŒ
ã®ãã¶ãã«é¢ããŠäžæºè¶³ãªãã®ã§ãã€ãã ãããã€ãŠæ¬çºæã®ç®çã¯ãå åãªåå¿æ§ãšã
å åãªå®å®æ§ãšãè¯å¥œãªã«ã©ãŒè»¢åæ§ãšãé«ãæ
床ãšãæãããã€ãã¶ããéåžžã«å°ãªãæ°èŠãªè
æ¡æ£æ§ææäŸäžååç©ãæäŸããããšã§ããã ããªãã¡æ¬çºæã¯ãå°ãªããšãïŒã€ã®æå æ§ã
ãã²ã³åéä¹³å€å±€ãšã該局ã«ä»éããèæ¡æ£ææ
äŸäžååç©ãšãæããåçææã«ç»å圢æé²å ã
è¡ãªãããã®ææäŸäžååç©ã®é žåçæç©ã¯ã¢ã«
ã«ãªæ§çŸåè¬åªè³ªäžã§æ¡æ£æ§ææãé¢è±ãåŸãã
ã®ã§ããã該åçææãããã²ã³åéçŸåè¬ã§çŸ
åãããã®çŸåè¬ã®é žåçæç©ã¯åèšææäŸäžå
åç©ãé žåãåŸããã®ã§ãã€ãŠããã®é žååå¿ã®
çµæãåèšææäŸäžååç©ãåèšçŸåè¬ã®ã¢ã«ã«
ãªã«ããå解ããããã®å解ã«ããé¢è±ããæ¡æ£
æ§ææã¯ãç»åã®åœ¢ã®éãã«ååžããç¶æ ã§ååš
ããããã«ãªãããšãå å«ããåçåŠçæææ¡æ£
転åæ¹æ³ã®ããã®åçææã«ãããŠãåèšéæ¡æ£
æ§ææäŸäžååç©ãæ¬¡åŒ ãæããååç©ã§ããããšãç¹åŸŽãšããåçææ
ã«é¢ãããã®ã§ããããã ãäžåŒã«ãããŠãã¯
åèšSO2åºã«çŽæ¥ã«çµåããŠããããŸãã¯ä»åšåº
ãä»ããŠçµåããŠããæææ®åºãŸãã¯ææåé§
äœæ®åºãè¡šããã ã¯ãççŽ ååãïŒâïŒåæããã¢ã«ãã¬ã³åº
ïŒãŸãã¯ã¢ã«ããªãã³åºïŒãã¢ãªãŒã¬ã³åºãŸãã¯è€
çŽ ç°åŒåºã®åŠãä»åšåºãè¡šãããããããŠãã®ä»
åšåºïŒºã¯åèšåºïŒžã«çŽæ¥ã«çµåããŠããããŸãã¯
ââãââãâSO2âãâNRâïŒããã«ïŒ²ïŒæ°Ž
çŽ ãŸãã¯ã¢ã«ãã«åºïŒãâCOâãâCOâNHâãŸã
ã¯âSO2âNHâãä»ããŠçµåããŠãããã®ã§ã
ãã ã¯ãçž®åãã³ãŒã³ç°ãå®æãããã®ã«å¿ èŠãª
åºãè¡šãããããããŠãã®çž®åãã³ãŒã³ç°ã¯çœ®æ
åºãïŒãŸãã¯ãã以äžãã€ãŠããŠãããã R1ã¯âOR2ãâSR2ãŸãã¯
ãåŒããè¡šã
ãã
R2ã¯æ°ŽçŽ ãè¡šããããããã¯ççŽ ååãïŒâ
22åæããã¢ã«ãã«åºïŒããšãã°ã¡ãã«åºããšã
ã«åºãã€ãœãããã«åºãïœâãªã¯ã¿ãã·ã«åºïŒã
ã·ã¯ãã¢ã«ãã«åºïŒããšãã°ã·ã¯ãããã·ã«
åºïŒãã¢ãªãŒã«åºïŒããšãã°ããšãã«åºïŒãè¡šã
ããåèšã®ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºããã³
ã¢ãªãŒã«åºã¯çœ®æåºããã€ãŠããŠããããããšã
ã°ãåèšã¢ã«ãã«åºã¯ããããã·ã«åºãã¢ã«ã³ã
ã·åºãã¢ããã·åºãããã²ã³ãã«ã«ããã·ã«åºãŸ
ãã¯ã¹ã«ãåºã§çœ®æãããŠããŠããããåèšã¢ãª
ãŒã«åºã¯ããã²ã³ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºã
ãžã¢ã«ãã«ã¢ããåºãã¢ã·ã«ã¢ããåºãã«ã«ãã
ã·ã«åºãŸãã¯ã¹ã«ãåºã§çœ®æãããŠããŠãããã R3ã¯åèšR2ã®å®çŸ©ã®ãšããã§è¿°ã¹ãåºã®ãã
ãããè¡šããããããã¯R3ã¯ãèèªæãŸãã¯è³
éŠæã«ã«ãã³é žãŸãã¯ã¹ã«ãã³é žããå°ãããã¢
ã·ã«åºãè¡šããã R4ã¯æ°ŽçŽ ãè¡šããããããã¯ççŽ ååãïŒâ
22åæããé眮æãŸãã¯çœ®æã¢ã«ãã«åºãè¡šã
ãã åºïŒ¹ã«ããå®æãããåèšçž®åãã³ãŒã³ç°ã¯ã
ïŒãŸãã¯ãã以äžã®çœ®æåºããã€ãŠããŠãããã
ããšãã°æ¬¡ã®çœ®æåºããã€ãŠããŠãããïŒããã²
ã³ããšãã°å¡©çŽ ãèçŽ ïŒççŽ ååæ°22åãŸã§ã®ã¢
ã«ãã«åºããšãã°ã¡ãã«åºãããã«åºããããµã
ã·ã«åºïŒã¢ãªãŒã«åºããšãã°ããšãã«åºïŒãã®ã¢
ãªãŒã«åºã¯çœ®æåºããã€ãŠããŠããããããããŠ
該眮æåºã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒããã²
ã³ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ã
ãåºãã¢ã·ã«ã¢ããåºïŒïŒã¢ã«ã¢ã«ãã«åºããšã
ã°ãã³ãžã«åºïŒã·ã¯ãã¢ã«ãã«åºããšãã°ã·ã¯ã
ããã·ã«åºïŒã¢ã«ã³ãã·åºããšãã°ã¡ããã·åºã
ãšããã·åºãããã·ã«ãªãã·åºããããµãã·ã«ãª
ãã·åºïŒã¢ã«ã¢ã«ã³ãã·åºããšãã°ãã³ãžã«ãªã
ã·åºãã¢ã·ã«ã¢ããåºãŸãã¯ã¢ã·ã«åºïŒãã®ã¢ã·
ã«åºã¯ãèèªæãŸãã¯è³éŠæã«ã«ãã³é žãŸãã¯ã¹
ã«ãã³é žããå°ããããã®ã§ãã€ãŠããïŒïŒã·ã¢
ãåºãã¹ã«ãåºãã«ã«ããã·ã«åºãã¹ã«ãã¢ã¢ã€
ã«åºãã«ã«ãã¢ã€ã«åºïŒãã®ã«ã«ãã¢ã€ã«åºãŸã
ã¯ã¹ã«ãã¢ã¢ã€ã«åºã®çªçŽ ååäžã®ïŒãŸãã¯ãã
以äžã®æ°ŽçŽ ååã¯ä»»æçã«çœ®æãããŠããŠãã
ããããšãã°ã¢ã«ãã«åºã§çœ®æãããŠããŠãã
ãïŒïŒãŸãã¯ãçž®ååçŽ ç°ïŒisocyclic ringïŒãŸ
ãã¯è€çŽ ç°ãå®æãããã®ã«å¿ èŠãªååãŸãã¯å
åå£ã åºïŒ¹ã«ããå®æãããåèšçž®åãã³ãŒã³ç°ãã
ãã€ãã®çœ®æåºããã€ãã®ã§ããå Žåã«ã¯ããã
ãã®çœ®æåºã¯å šéšåäžã§ããå¿ èŠã¯ãªãã æ¬çºæã«ä¿ãææäŸäžååç©ããå®å šãªååã
ïŒã€ã³ã¿ã¯ãååïŒãšããŠååšãããšãã«ã¯ãå
çå±€ãéããŠæ¡æ£ãããã®ã§ãã€ãŠã¯ãªããªãã
ãšãç解ãããã¹ãã§ããããã®ç®çã®ããã«ã
ãã®ååç©ã¯èæ¡æ£æ§ä»äžçšæ®åºããããšãã°æ®
åºR1ã®äžã«æãããããã¯ãã«ããå®æãã
ãåèšçž®åãã³ãŒã³ç°äžã®çœ®æåºã®äžã«æããã®
ã§ããã ã«ããå®æãããåèšçž®åãã³ãŒã³ç°äžã®çœ®
æåºãããã¯R1ãé·éã¢ã«ãã«åºãå«ãŸãªãã
ã®ã§ããå ŽåãããåèšææäŸäžååç©ã¯å åãª
èæ¡æ£æ§ãä¿æã§ããã®ã§ããããªããªãã°ãã®
ååããåèšæææ®åºã®å¯žæ³ã«å¿ããŠå å倧圢ã®
ãã®ã«ããããšãã§ããããã§ããããããã¯ã
å å倧圢ã®èæ¡æ£æ§ä»äžçšæ®åºãé©åœã«éžæãã
ããšã«ããããã®ææäŸäžååç©ã«å åãªèæ¡æ£
æ§ãäžããããšãã§ããã èæ¡æ£æ§ä»äžçšæ®åºãšã¯ãåçææã«åžžçšãã
ã芪氎æ§ã³ãã€ãäžã§æ¬çºæã®ååç©ãèæ¡æ£æ§
ç©è³ªã®åœ¢ã§ååšãåŸãããã«ããããã«ã該åå
ç©äžã«æ¿å ¥ãããæ®åºã®ããšã§ããããã®ç®çã®
ããã«çšããããæ®åºã¯ãææ©æ®åºã§ããããšã
奜ãŸããããã®ãããªææ©æ®åºã¯äžè¬ã«ãçŽéç¶
ãŸãã¯åæç¶èèªæåºãå«ããã®ã§ããããåçŽ
ç°åŒåºãè€çŽ ç°åŒåºãŸãã¯è³éŠæã®åºïŒãããã®
åºã¯äžè¬ã«ççŽ ååãïŒâ20åæãããã®ã§ãã€
ãŠããïŒãå«ããã®ã§ãã€ãŠãããããã®æ®åº
ã¯ãååäžã®ãæ®ãã®éšåãã«çŽæ¥ãŸãã¯éæ¥ã«
çµåããŠãããã®ã§ãã€ãŠãããéæ¥çµåã®å Žå
ã«ã¯ãããšãã°æ¬¡ã®ä»åšåºã®ãããããä»ããŠçµ
åããŠãããã®ã§ãã€ãŠããïŒâNHCOâã
NHSO2âãâNRâïŒããã«ïŒ²ã¯æ°ŽçŽ ãŸãã¯ã¢ã«ã
ã«åºãè¡šããïŒãââãââãâSO2âãããã
ã®èæ¡æ£æ§ä»äžçšæ®åºã¯ãåèšã®åºã®ä»ã«ããã
ã«æ°Žæº¶æ§ä»äžåºãå«æãåŸããã®äŸã«ã¯ã¹ã«ã
åºãã«ã«ããã·ã«åºããããããããã®æ°Žæº¶æ§ä»
äžåºã¯ã¢ããªã³ã®åœ¢ã§ååšããŠããŠããããæ¡æ£
æ§ïŒãŸãã¯èæ¡æ£æ§ïŒã¯è©²ååç©ã®ååã®å¯žæ³ã«
å·Šå³ããããã®ã§ãããããååå šäœãå å倧ã
ããã®ã§ãããšãã«ã¯ãèæ¡æ£æ§ä»äžçšæ®åºãšã
ãŠãæ¯èŒççãåºãçšããã ãã§å åã§ããå Žå
ãããåŸãã åèšæææ®åºã¯ååãšããŠãä»»æã®çš®é¡ã®ææ
ã®æ®åºã§ããåŸãããã ãããã®æææ®åºã¯ãæ
å ææå ã®åçå±€ãééããŠç»ååå ¥å±€ã«å°éã
ãã«å åãªæ¡æ£æ§ãæãããã®ã§ãªããã°ãªããª
ãããã®ç®çã®ããã«ããã®æææ®åºã«ïŒãŸãã¯
ãã以äžã®æ°Žæº¶æ§ä»äžåºãçµåãããŠããããšã
ã§ãããé©åœãªæ°Žæº¶æ§ä»äžåºã®äŸã«ã¯æ¬¡ã®ãã®ã
ãããããïŒã«ã«ããã·ã«åºãã¹ã«ãåºãã¹ã«ã
ã³ã¢ããåºãã¹ã«ãã¢ã¢ã€ã«åºãèèªæãŸãã¯è³
éŠæã®ããããã·ã«åºããã®ã¹ã«ãã¢ã¢ã€ã«åº
ã¯ãææäŸäžååç©ã®å解åå¿çµäºåŸã«ãææå
åã«ããªã倧ããã¢ã«ã«ãªåªè³ªäžæ¡æ£æ§ãä»äžã
åŸããã®ã§ãããããå¥ã®æ°Žæº¶æ§ä»äžåºãè¿œå ç
ã«ååšãããããšã¯å¿ ããããå¿ èŠã§ã¯ãªããæ¬
çºæã«ç¹ã«é©åœãªææã®äŸã«ã¯æ¬¡ã®ãã®ãããã
ããïŒã¢ãŸææãã¢ãŸã¡ãã³ææãã¢ã³ã¹ã©ãã
ã³ææããã¿ãã·ã¢ãã³ææãã€ã³ãžãŽã€ãæ
æãããªããšãã«ã¡ã¿ã³ææãéå±é¯äœææãæ
è²éå±é¯äœã åèšææåé§äœïŒãã¬ã«ãŒãµãŒïŒæ®åºãšã¯ãå
çåŠçå·¥çšäžã®åžžçšåŠç段éã«ãããŠããããã¯
è¿œå çåŠç段éã«ãããŠãé žåã«ããããããã¯
ã«ãããªã³ã°ã«ããããããã¯é¹žåçã«ããçºè²
ç³»å ã§ã®å©è²åºïŒå©è²å£ïŒã®éé¢ïŒããªãã¡å©è²
å£ãéé¢ããŠããããçºè²å£ã«å ããããšïŒã«ã
ããææã«å€æãåŸãååç©ã®æ®åºã®ããšã§ã
ãããã®å Žåã®ææå é§äœã¯ãªãŠãŠã³ææã§ãã€
ãŠãããããããã¯ãåçåŠçå®æœäžã«ä»ã®ææ
ã«å€æãããææãŸãã¯ã«ããã©ãŒã§ãã€ãŠãã
ãããæææ®åºããšãææå é§äœããšãåºå¥ãã
ããšãéèŠãªäºé ã§ãªããšãã«ã¯ãææå é§äœæ®
åºãçšèªãæææ®åºãã®äžã«å«ããŠè«ããã®ã䟿
å©ã§ããã®ã§ã以äžã®èšèŒã§ã¯çšèªãæææ®åºã
ãäžèšã®åºãæå³ã§çšããããšã«ãããæ¬çºæã«
ä¿ãé©åœãªææäŸäžååç©ã®äŸã«ã¯ã次ã®ãã®ã
ãããããã åèšã€ã³ããŒã«åºäžã®çž®åãã³ãŒã³ç°ã«ãã眮
æåºãŸãã¯R1ãïŒäŸ¡åºïŒããšãã°R1â²ãR2â²ïŒã§ã
ãå Žåã«ã¯ãããã¯ïŒåã®ã€ã³ããŒã«ç°ãã€ãªã
ãã®ã§ãã€ãŠããããããšãã°äžèšã®åŠããã®ã§
ããåŸãã ãŸã㯠ææäŸäžååç©ïŒã®è£œé ãã«ãšã³200mläžã§ïŒâã¡ããã·ã€ã³ããŒã«â
ïŒâã«ã«ãã³é žãšãã«ãšã¹ãã«21.9ïœããªã¯ã¿ã
ã·ã«ã¢ãã³29.6ïœãšæ··åãããã«ãšã³50mlãçå»
ãããã50âã«å·åŽããåŸã«ã30ïŒ ãããªãŠã ã¡
ãã¬ãŒã溶液ã3.65mlæ·»å ããåå¿æ··åç©ãéæµ
äžã«ïŒæéç ®æ²žãããåå¿æ··åç©ããŸã ç·©ããã¡
ã«ãããã«å ç±ããããšãªãã¡ã¿ããŒã«ã475ml
滎äžãããåå¿æ··åç©ãå ¶åŸã«ïŒâã«å·åŽããç
ããçµæ¶ïŒã¯ãªã¹ã¿ãªãŒãªãŒãïŒãåžåŒéã«ã
ãåé¢ããã¡ã¿ããŒã«200mlã§æŽæµããã也ç¥æ
äœå®æœåŸã«ã次åŒãæããååç©ã37.2ïœåŸã
ãããåç84ïŒ ïŒçè«å€åºæºïŒèç¹139â142âã ç©åãªå ç±ãè¡ãªããªããæ°·é ¢é ž375mlã«åå
ç©37.2ïœã溶解ãã宀枩ã«å·åŽãããããŠïŒæ
éãèŠããŠäºç¡é žãããªãŠã 7.6ïœãå°ãã¥ã€æ·»
å ãããæ¹æãããã«ïŒæéç¶ãã次ãã§åå¿æ··
åç©ã40âã«çæéå ç±ããæ²æ®¿ååç©ããåžåŒ
éå®æœæã«äžå±€å®¹æã«åé¢ãåŸã圢ã®ãã®ãã«
ããã20âã«å·åŽããåŸã«ãåå¿æ··åç©ã«åžåŒ
éãè¡ãªã€ãŠæ²æ®¿ãåé¢ãããã®æ²æ®¿ãæŽæµã
ããæŽæµã¯ãæåã¯æ°·é ¢é žãçšããŠè¡ãªãã次ã
ã§å€§éã®æ°ŽãçšããŠè¡ãªã€ããæŽæµåŸã«ä¹Ÿç¥ã
ãã次åŒãæããååç©ã39.6ïœåŸããããå
ç99.7ïŒ ïŒçè«å€åºæºïŒã ååç©ïŒ39.6ïœïŒã现ãããµãããééã
ããã¡ã¿ããŒã«370ïœäžã«çããæ¹æäžã«æå ¥ã
ãããã®çµæåŸãããã¹ã©ãªãŒäžã«ããããªãŠã
ãžããªãã€ãïŒäºäºããªã³é žãããªãŠã ïŒ41ïœã®
氎溶液ïŒæ°Žã®éã¯165mlïŒãæ¥éã«æå ¥ãããã®
æ··åç©ã60â65âã®æž©åºŠã«ïŒæéç¶æããããã
ãå ¶åŸã«20âã«å·åŽããæ®çç©ãåžåŒéã«ãã
åé¢ããïŒïŒ ãããªãŠã ãžããªãã€ã溶液600ml
ã§æŽæµããã也ç¥åŸã«ã次åŒãæããååç©ã
36ïœåŸããããåç91ïŒ ïŒçè«å€åºæºïŒã ååç©ãã¯ãããã«ã 50mläžã«å ¥ããŠæ¹æ
ããããªãžã³ïŒmlãæ·»å ãã次ãã§æ¬¡åŒãæã
ãææã¹ã«ãã¯ãã©ã€ã5.5ïœãæ·»å ããã ãã®æ··å液ãïŒæéæ¹æãããã¡ã¿ããŒã«ã
150mlæ·»å ããæ¹æãããã«ïŒæéç¶ãããæ²æ®¿
ããææãåžåŒéã«ããåé¢ããã也ç¥åŸã«å
åç©ã4.4ïœåŸãããããã®ååç©ã次ã®æ¹æ³
ã«åŸã€ãŠç²Ÿè£œãããããªãã¡ããããæããã¯ã
ããã«ã 50mlã«æº¶è§£ãã次ãã§ã¡ã¿ããŒã«ã100
mlæ·»å ãããã®æ··åç©ãïŒæ©äžæŸçœ®ããããã®æ
éã®éã«æ¶åºããååç©ãåžåŒéã«ããåé¢
ããã¡ã¿ããŒã«ã§æŽæµãã也ç¥ãããææäŸäžå
åç©ã2.8ïœåŸããããåç33ïŒ ïŒçè«å€åº
æºïŒã é眮æã€ã³ããŒã«âïŒâã«ã«ãã³é žãšãã«ãšã¹
ãã«ããã³çš®ã ã®çœ®æã€ã³ããŒã«âïŒâã«ã«ãã³
é žãšã¹ãã«ãæ¢ã«æç®ã«èšèŒãããŠããŠå ¬ç¥ã§ã
ããããšãã°ãJ.Chem.Soc.ãã1965幎床ã第
7185é â第7193é ã«ããããŒã¹âãã©ãŠã³ããã³
ãã€ã«ãããã®è«æã«èšèŒãããŠããã®ã§ãæ¬çº
æã«ä¿ãææäŸäžååç©ã¯ãã®å ¬ç¥è£œæ³ãšåæ§ãª
æ¹æ³ã«åŸã€ãŠè£œé ã§ããã®ã§ããã æ¬çºæã«ä¿ãååç©ã®è£œé ã®ããã«ãå¥ã®è£œæ³
ãçšããããšãå¿è«å¯èœã§ãããããšãã°ãé©åœ
ãªã€ã³ããŒã«èªå°äœããžã¢ãŸããŠã å¡©ãšã«ããã«
ããã次ãã§å ¬ç¥æ¹æ³ã«åŸã€ãŠç°å æäœãè¡ãªã€
ãŠã察å¿ããïŒâã¢ããã€ã³ããŒã«ã«éå ããã
ããŠææã¹ã«ãã¯ãã©ã€ããšåå¿ãããããšã«ã
ãæ¬çºæã®ååç©ãçæãããããšãããªã補æ³
ãçšããããšãå¯èœã§ããã æ¬çºæã«ä¿ãææäŸäžååç©ã¯ä»»æã®åžžæ³ã«åŸ
ã€ãŠåçå±€äœæçšãã€ã¹ãã³ã°æ¶²äžã«å ¥ããããš
ãã§ããããã®ãã€ã¹ãã³ã°æ¶²ïŒåœãã®è©²ææ
äŸäžååç©ã®äœ¿çšéã¯ãæ¯èŒçåºãç¯å²å ã§çš®ã
å€ããããšãã§ãããåã ã®å Žåã«ãããæé©æ¿
床ïŒäœ¿çšéïŒã¯ç°¡åãªè©Šéšã«ãã容æã«æ±ºå®ã§ã
ããããšãã°ããã€ã¹ãã³ã°æ¶²ïŒåœã該ææäŸ
äžååç©ãïŒâ80ïœå¥œãŸããã¯20â40ïœäœ¿çšã§ã
ããææå¹æãåŸãããã«ãèæ¡æ£æ§ææäŸäžå
åç©ãšããã²ã³åéãšã®éã«é©åãªäœçœ®çé¢ä¿ã
æ£ç¢ºã«ä¿ã€ããšãå¿ èŠã§ãããããã®é¢ä¿ã¯ãå
åšãã氎溶æ§ä»äžåºãå©çšããŠåèšèæ¡æ£æ§åå
ç©ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ã«æº¶è§£ãããã®æ°Žæº¶æ¶²ãã
ã€ã¹ãã³ã°æ¶²ã«å°å ¥ããããšçã®æäœãè¡ãªãã
ãšã«ããã確å®ã«ç¶æã§ããããããã¯ãåèšè
æ¡æ£æ§ææäŸäžååç©ãå ¬ç¥ä¹³åæ¹æ³ã®ãããã
ã«åŸã€ãŠåçå±€ã«å°å ¥ããŠãããããã®ãããªæ¹
æ³ã¯ãããšãã°æ¬¡ã®æç®ã«èšèŒãããŠããïŒè±åœ
ç¹èš±ç¬¬791219å·ã第1099414å·ã第1099415å·ã第
1099416å·ããã³ç¬¬1099417å·æ现æžãããïŒã€ã®
æ¹æ³ã¯ãææäŸäžååç©ã®æ°Žæ§åæ£æ¶²ãäœããã
ãããã€ã¹ãã³ã°æ¶²ã«æ·»å ããããšã§ããããã®
ç®çã®ããã«æ¬¡ã®æäœãè¡ãªãããšãã§ãããã
ãªãã¡ãåèšææäŸäžååç©ã®æ°Žæ§ã¹ã©ãªãŒã«åŸ®
现åããªã³ã°ãè¡ãªãããã®ããªã³ã°ã¯ãããšã
ã°ã·ã€ãŒããµã³ãïŒè§ã°ã€ã圢ã®ç ç²ãããªã
ç ïŒã®ååšäžã«çããæ¹æãè¡ãªãããšã«ããã
ãããã¯è¶ é³æ³¢ãçšããŠå®æœã§ããããããã¯ã
æ¬çºæã®ããïŒã€ã®å ·äœäŸã«åŸã€ãŠãããšãã°ã
åçå±€äžã«åèšææäŸäžååç©ããã€ã¯ãã«ãã»
ã«ã®åœ¢ã§ããã²ã³åéãšäžç·ã«ããã€å¿ èŠã«å¿ã
ãŠçŸåè¬ãšãäžç·ã«å°å ¥ããããšãæå©ãªæ¹æ³ã§
ãããããã«ããã®ãããªå Žåã«ã¯ãå¢æ床ã®çž
ç°ãªãïŒçš®ãŸãã¯ãã以äžã®æå æ§ããã²ã³åé
ä¹³å€ãšé©åœãªåèšèæ¡æ£æ§ååç©ãšãäžç·ã«ã
ãŠãããããæ··åç²ä¹³å€ïŒmixed grain
emulsionsïŒã®åœ¢ã§ïŒæã®åçå±€ã«æ·»å ããããš
ãå¯èœã§ãããããããŠãã®æè¡ã¯ããšãã°ç±³åœ
ç¹èš±ç¬¬2698794å·æ现æžçã«èšèŒãããŠãããã
ã®èæ¡æ£æ§ææäŸäžååç©ã¯æå å±€ãŸãã¯ãã®é£
ãã®å±€ã®äžã«å ¥ããããšãã§ãããããšãã°ãã·
ã¢ã³ææäŸäžååç©ã¯èµ€æå±€ã«ä»éãããããšã
ã§ããããŒã³ã¿ææäŸäžååç©ã¯ç·æå±€ã«ä»éã
ããããšãã§ããé»è²ïŒã€ãšããŒïŒææäŸäžåå
ç©ã¯éæå±€ã«ä»éãããããšãã§ããã ããã«çšèªãä»éãããä»éãããã¯ãããã²ã³
åéä¹³å€ãšææäŸäžååç©ãšãé 眮ããã«ãã
ãããããã®çžäºã€ã³ã¿ã©ã¯ã·ãšã³ã®çµæãšã
ãŠãçæéç»åãšæŸåºæ¡æ£æ§ææã®ååžç¶æ ãšã®
éã«ãç»åã®åœ¢ã®éãã®å¯Ÿå¿æ§ã確ç«ããåŸãã
ãã«ãåèšä¹³å€ãšåèšååç©ãšãé 眮ããããš
ïŒãŸãé 眮ããããšïŒãæå³ããã ä»éãããã¹ãææäŸäžååç©ã¯ãããã²ã³å
éä¹³å€å±€èªèº«ã®äžã«å ¥ãããããããã¯è©²ããã²
ã³åéä¹³å€å±€ã®é£ãã®å±€ã®äžã«å ¥ããã®ã奜ãŸã
ããããããŠãã®é£æ¥å±€ã¯ãé²å æã®å ¥å°å ç·ã®
æ¹åããã¿ãŠãåèšããã²ã³åéä¹³å€å±€ã®åŸæ¹ã«
é 眮ããã®ã奜ãŸãããéç»åçæçŸåå®æœæ
ã«ãæ¬çºæã«ä¿ãææäŸäžååç©ãçŸåè¬ã®é žå
çæç©ã«ããç»åã®åœ¢ã®éãã«é žåããããããŠ
çŸåè¬ã®ã¢ã«ã«ãªãŸãã¯æŽ»æ§åå€ïŒã¢ã¯ãããŒã¿
ãŒïŒã®äœçšäžã«å解åå¿ãèµ·ããæææ®åºãæ¡æ£
æ§ææã¹ã«ãã³ã¢ããïŒéé¢ã¹ã«ãã¢ã¢ã€ã«åºã
æãããã®ïŒã®åœ¢ã§éé¢ããããã®çŸåã®ããã«
åžžçšçŸåè¬ã䜿çšã§ããããã ããã®çŸåè¬ã¯ã
ãããé žåçæç©ã«ãªã€ããšãã«ãæ¬çºæã«ä¿ã
ææäŸäžååç©ãé žåãåŸããã®ã§ãªããã°ãªã
ãªãã é©åœãªçŸåè¬ã®äŸã«ã¯æ¬¡ã®ãã®ããããããã ãã€ããããã³ã âã¡ãã«ã¢ããããšããŒã«ã ïŒâããšãã«âïŒâãã©ãŸãªãã³ã ïŒâããšãã«âïŒã»ïŒâãžã¡ãã«âïŒâãã©ãŸ
ãªãã³ã ïŒâããšãã«âïŒâã¡ãã«âïŒâããããã·ã¡
ãã«âïŒâãã©ãŸãªãã³ã ïŒâããšãã«âïŒã»ïŒâãã¹âããããã·ã¡ã
ã«âïŒâãã©ãŸãªãã³ã ã¢ããããšããŒã«ã ã»ïŒ®âãžãšãã«âïœâããšãã¬ã³ãžã¢ãã³ã âãšãã«ââããããã·ãšãã«âïœâããš
ãã¬ã³ãžã¢ãã³ã ïŒâã¡ãã«âã»ïŒ®âãžãšãã«âïœâããšãã¬
ã³ãžã¢ãã³ã ã»ïŒ®ã»Nâ²ã»Nâ²âããã©ã¢ã«ãã«âïœâããš
ãã¬ã³ãžã¢ãã³ããšãã°ããã©ã¡ãã«âïœâããš
ãã¬ã³ãžã¢ãã³ãããªãšãã«ã¹ã«ãããã«âïœâ
ããšãã¬ã³ãžã¢ãã³ãïŒã»ïŒâãã¹âãããªãžã
ãã³ãŒã³ã ã¬ãã¯ãã³ã æ¬çºææ¹æ³ã«ãããŠçŸåè¬ãéžæããå Žåãã
ã®çŸåè¬ã¯ã«ã©ãŒçŸåè¬ã®ã¿ã«éå®ããããã®ã§
ã¯ãªããåžžçšçœé»çŸå液ããŸã䜿çšã§ããããšã«
泚ç®ãããããããã¯æå©ãªããšã§ããããªããª
ãã°åŸè ã¯å€è²åŸåã®äœããã®ã§ããããã§ã
ãã ãã®çŸå液ã¯ãã«ã©ãŒåçææäžã®åçå±€ã®äž
ã«å«ãŸããããšãå¯èœã§ããããã®å Žåã«ã¯ãã
ãã¯ã¢ã«ã«ãªæ§æŽ»æ§åå€æº¶æ¶²ã«ãã掻æ§åã§ã
ãããããã¯ãããã¯ã¢ã«ã«ãªæ§åŠç液ãŸãã¯ã
ãŒã¹ãäžã«å ¥ããŠããããæ¬çºæã«ä¿ãææäŸäž
ååç©ã¯ããèªäœçŸåè¬ãšããŠã®æ§è³ªããæãã
ãããæå Žåã«ã¯è£å©çŸåè¬ã®äœ¿çšãçç¥ã§ã
ãããã®ãããªå Žåã«ã¯ããã®ææäŸäžååç©ã¯
çŸåå¯èœããã²ã³åéã«ããçŽæ¥ã«é åãããã®
ã§ããã çŸåå®æœæã«æŸåºãããæ¡æ£æ§ææã¯ç»åã®åœ¢
ã®éãã«ååžããç¶æ ã§ååšãããããã®ååžç¶
æ ã¯çŸåéç»åã®ååžç¶æ ã«äžèŽãããã®ã§ãã
ãããããžã®ã«ã©ãŒè»¢ååã®çæã®ããã«ã¯ãçŽ
æ¥ããžçšããã²ã³åéä¹³å€ãå¿ èŠã§ãããããã
ã¯ããã¬çšã®åžžçšä¹³å€ã䜿çšããå Žåã«ã¯ãé©åœ
ãªãªããŒãµã«çŸååŠçãè¡ãªãå¿ èŠãããã ãã®ç®çã®ããã«é©åœãªãªããŒãµã«çŸåæ¹æ³ã¯
éå¡©æ¡æ£æ³ã§ãããåžžçšã«ã©ãŒã«ããã©ãŒã䜿çš
ããŠéå¡©æ¡æ£æ³ã«ããåçåŠçãªããŒãµã«æäœã
è¡ãªã€ãŠããžã«ã©ãŒç»åãçæãããæ¹æ³ã¯ãã
ãšãã°ç±³åœç¹èš±ç¬¬2763800å·æ现æžã«èšèŒãããŠ
ããããã®å ¬ç¥æ¹æ³ã«ãããŠãã«ã©ãŒã«ããã©ãŒ
ã®ä»£ãã«åèšææäŸäžååç©ã䜿çšããå Žåã«
ã¯ãæææ¡æ£è»¢åæ³ã®ããã«é©åœãªæå èŠçŽ ïŒæ
å ææïŒãåŸãããã§ãããããã®çš®ã®æå èŠçŽ
ã¯ãããšãã°ãæå æ§ããã²ã³åéä¹³å€å±€ãšãã
ãã«ä»éãããã€ã³ããŒå±€ãšã®çµåãããå°ãªã
ãšãïŒã€æãããã€ãç©ççŸåçšçŸåæ žãšåèšæ
æäŸäžååç©ãšãå«ããã®ã§ããã çŸåæäœå®æœæã«ãæå æ§ããã²ã³åéä¹³å€å±€
äžã®é²å éšã®ããã²ã³åéãååŠçã«çŸåãã
ããéé²å éšã®ããã²ã³åéã¯ãããã²ã³åé溶
åªã«ããä»éãã€ã³ããŒå±€ïŒçŸåæ žãå«ãå±€ïŒã«
移ãããããã§ç©ççã«çŸåããããç©çççŸè±¡
ãçŸåè¬ã®ååšäžã«å®æœãããããŠè©²çŸåè¬ã®é ž
åçæç©ãšããã®å±€ã«ååšããææäŸäžååç©ãš
ã®åå¿ã®çµæãšããŠãæ¡æ£æ§ææãæŸåºãããã
ãã«ãªã€ãŠããå Žåã«ã¯ããã®çŸåã®çµæãšã
ãŠã該æ¡æ£æ§ææãç»åã®åœ¢ã®éãã«ååžããç¶
æ ã§ååšããããã«ãªãããããŠè©²æ¡æ£æ§ææã¯
ç»ååå ¥å±€ã®æ¹ã«ç§»ãããããã§ããžã«ã©ãŒç»å
ãçæã§ããã çŸåæå¶å€ãç»åã®åœ¢ã®éãã«ååžããç¶æ ã§
æŸåºãåŸãååç©ãçšããŠãªããŒãµã«çŸåæäœã
è¡ãªãå Žåã«ã¯ããæå æ§ããã²ã³åéä¹³å€å±€ã
ãšããåèšææäŸäžååç©ãå«ã¿ãã€é²å ããã«
çŸåãåŸã第ïŒä¹³å€å±€ããšã®çµåããããå°ãªã
ãšãïŒã€æããæå æ§èŠçŽ ã䜿çšã§ããããã®æ
å æ§ããã²ã³åéä¹³å€å±€ã¯ãããšãã°ãçºè²çŸå
è¬ã®é žåçæç©ãšã®åå¿ã«ããçŸåæå¶ç©è³ªãæŸ
åºãåŸããããªæçš®ã®ååç©ã®ååšäžã«ãçºè²çŸ
åè¬ã«ããçŸåã§ããããã®æå å±€äžã§ç»åã®åœ¢
ã®éãã«æŸåºãããçŸåæå¶ç©è³ªã¯ãé²å ããªã
ãŠãçŸåã§ããé£æ¥ä¹³å€å±€ã®æ¹ã«æ¡æ£ãããããŠ
ããã¯ããã§ç»å圢æçŸåãæå¶ãããé²å ããª
ããŠãçŸåã§ããä¹³å€å±€ã®äžã®éæå¶åºåïŒããž
åºåïŒã¯ãæ®åçŸåè¬ã§çŸåãããããããŠè©²çŸ
åè¬ã®é žåçæç©ã¯å ¶åŸã«æ¬çºæã«ä¿ãéæ¡æ£æ§
ææäŸäžååç©ãšåå¿ã§ãããã®ã§ãã€ãŠããã®
åå¿ã«ããæ¡æ£æ§ææãæŸåºããããããŠè©²ææ
ã¯ç»åã®åœ¢ã®éãã«ç»ååå ¥å±€ã«ç§»ãããã®ã§ã
ããçºè²çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããçŸå
æå¶ç©è³ªãæŸåºãåŸãååç©ã®å¥œãŸããäŸã«ã¯ã
å ¬ç¥ã®DIRã«ããã©ãŒïŒçŸåæå¶å€æŸåºæ§ã«ãã
ã©ãŒïŒããããããããã®DIRã«ããã©ãŒã¯ãã«
ãããªã³ã°äœçœ®ã«é¢è±å¯èœæå¶å€æ®åºãå«ãã«ã©
ãŒã«ããã©ãŒã§ããããã®åã®DIRã«ããã©ãŒã¯
ããšãã°ç±³åœç¹èš±ç¬¬3227554å·æ现æžçã«èšèŒã
ããŠããã çºè²çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããçŸåæ
å¶ç©è³ªãæŸåºãåŸãããïŒã€ã®çš®é¡ã®ååç©ã¯ã
ç±³åœç¹èš±ç¬¬3632345å·æ现æžçã«èšèŒã®ååç©ã§
ãããããã¯ã«ã©ãŒã«ããã©ãŒã§ã¯ãªããããªã
ã¡ããã¯ãçŸåæå¶ç©è³ªã®æŸåºã®ãšãã«ææãç
æãããã®ã§ã¯ãªããç¬åœç¹èš±ç¬¬1229389å·æ现
æžã«ã¯ã奜ãŸããã¯çœ®æåºãæããèæ¡æ£æ§ãã€
ããããã³ååç©ãèšèŒãããŠããããããã¯ã
çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããé žåãããŠã
察å¿ããããã³ååç©ã«ãªãããã€çŸåæå¶äœçš
ãæããã¡ã«ã«ãã¿ã³ååç©ãæŸåºãããã®ã§ã
ãããããã€ãŠããã®ãã€ããããã³ååç©ã¯äž
èšã®æ¹æ³ã«äœ¿çšãåŸããã®ã§ããã æ¬çºæã«äœ¿çšãããçŽæ¥ããžããã²ã³åéä¹³å€
ã¯ãååãšããŠã次ã®æ§è³ªãæããä»»æã®ããã²
ã³åéä¹³å€ã§ãã€ãŠãããããªãã¡ãåçŽ
ïŒSimpleïŒçŸåã®ãšãã«ããžã®éç»åãçãã
ãããã€çŸåè¬ã®é žåçæç©ããç»åã®åœ¢ã®éã
ã«ååžããç¶æ ã§çæãããããšãã§ãããããª
ããã²ã³åéä¹³å€ã䜿çšã§ããã®ã§ããããã®çš®
ã®ããã²ã³åéä¹³å€ã®äŸã«ã¯ãé²å ãŸãã¯ååŠç
åŠçã«ããçŸåå¯èœãã¶ããçãããããŠãã®ã
ã¶ãããæçš®ã®æ¡ä»¶äžã§ã¯ç»å圢æé²å å®æœäž
ã«ãç»åã®åœ¢ã®éãã«æ¶æ» ã§ãããããªååŒã®ã
ãã²ã³åéä¹³å€ãããããããããªãã¡ãã®ãã¶
ãã¯éé²å éšã§ã¯ç¶æãããã®ã§ãå ¶åŸã®çŸåæ
äœã«ããçŽæ¥ããžéç»åãçããããããã€ãŠã
ãã®çŽæ¥ããžçšããã²ã³åéä¹³å€ã«æ¬çºæã®ææ
äŸäžååç©ãä»éããããšãã«ã¯ãæ¡æ£æ§ææã
åèšéç»åã®åœ¢ã®éãååžããç¶æ ã§ååšããã
ãã«ãªãã æ¬çºæã«ãããŠæå©ã«äœ¿çšã§ããããïŒã€ã®çš®
é¡ã®çŽæ¥ããžçšããã²ã³åéä¹³å€ã¯ãããããç¡
ãã¶ãåçŽæ¥ããžçšããã²ã³åéä¹³å€ã§ãã€ãŠã
ããã¯ãäž»ãšããŠããã²ã³åéç²åã®å éšã«ãå
ã«æããéšåããæãããã®ã§ããããã®ä¹³å€ã«
ç»å圢æé²å ãè¡ãªã€ãå Žåã«ã¯ãäž»ãšããŠãã
ã²ã³åéç²åã®å éšã«æœåãçããã ããããªããããã®ãããªç¡ãã¶ãåçŽæ¥ããž
çšããã²ã³åéä¹³å€ã®çŸåãããã¶ããçºçãã
ãããªæ¡ä»¶ã®ããšã§å®æœããå Žåã«ã¯ããã¶ãã
äž»ãšããŠéé²å éšã«çãããããŠçŸåã®çµæãã
ãžã®éç»åãçããããã®ç¡ãã¶ãåããžçšãã
ã²ã³åéä¹³å€ã®ç¹åŸŽã¯ãé²å åŸã®è©Šæã次ã®çµæ
ã®ä»£è¡šçãªè¡šé¢çŸåè¬ïŒ ïœâããããã·ããšãã«ã°ãªã·ã³ 10ïœ çé žãããªãŠã ïŒçµæ¶ïŒ 100ïœ æ°Ž æ®éš å š é 1000ml ã§çŸåããå Žåã«ã¯ã奜ãŸããã¯éç»åãçããª
ãããŸãã¯éåžžã«äœæ¿åºŠã®éç»åãçããã®ã¿ã§
ãããäžæ¹ã次ã®çµæã®å æ žçŸåè¬ïŒ ãã€ããããã³ 15ïœ ã¢ãã¡ãã«âïœâã¢ããããšããŒã«ãµã«ããšãŒã
15ïœ äºç¡«é žãããªãŠã ïŒç¡æ°Žç©ïŒ 50ïœ èåã«ãªãŠã 10ïœ æ°Žé žåãããªãŠã 25ïœ ããªç¡«é žãããªãŠã ïŒçµæ¶ïŒ 20ïœ æ°Ž æ®éš å š é 1000ml ã§çŸåããå Žåã«ã¯ãå åã«æ¿ãéç»åãçãã
ããšã§ããã ç»å圢æé²å å®æœåŸã®ç¡ãã¶ãåçŽæ¥ããžçšä¹³
å€ã®åèšã®åŠãéžæçãã¶ãçææäœã¯ãçŸåå®
æœåãŸãã¯å®æœäžã«è©²ä¹³å€ããã¶ãçæå€
ïŒfogging agentïŒã§åŠçããããšã«ããå®æœã§ã
ããé©åœãªãã¶ãçæå€ã¯ãããã©ãžã³ãŸãã¯çœ®
æããã©ãžã³ã®åŠãéå å€ã§ããããã®ããšã¯ã
ç±³åœç¹èš±ç¬¬3227552å·æ现æžçã«è©³çŽ°ã«èšèŒãã
ãŠããã ç¡ãã¶ãåçŽæ¥ããžçšä¹³å€ã®äŸã«ã¯ãããã²ã³
åéç²åã®å éšã«ããã®ããä¹³å€ïŒç±³åœç¹èš±ç¬¬
2592250å·æ现æžïŒïŒããã³å±€ç¶ç²åæ§é ãæã
ãããã²ã³åéä¹³å€ïŒç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
2308239å·ïŒãããããããã ãããã®ä¹³å€ã¯ãããšãã°ãã®ååŠçæå·¥çšã«
ãããŠç¡«é»ååç©ïŒããšãã°ã¢ãªã«ã€ãœããªã·ã¢
ããŒããã¢ãªã«ããªå°¿çŽ ãããªç¡«é žãããªãŠã
çïŒãæ·»å ããããšã«ããååŠå¢æã§ããããŸã
ååŠå¢æå€ãšããŠéå å€ãçšããããšãå¯èœã§ã
ãããã®äŸã«ã¯ãã«ã®ãŒç¹èš±ç¬¬493464å·ããã³ç¬¬
568687å·æ现æžçã«èšèŒã®ååç©ããããããã
ãŸããããªã¢ãã³ïŒããšãã°ãžãšãã¬ã³ããªã¢ã
ã³ïŒãã¢ããã¡ã¿ã³ã¹ã«ãã€ã³é žèªå°äœïŒãã«ã®
ãŒç¹èš±ç¬¬547323å·æ现æžçïŒã䜿çšã§ããã éãçœéããã©ãžãŠã ãã€ãªãžãŠã ãã«ãããŠ
ã ãŸãã¯ããžãŠã ã®åŠã貎éå±ããã³ãã®ååç©
ããŸãååŠå¢æå€ãšããŠäœ¿çšã§ããããã®ååŠå¢
ææ¹æ³ã¯ããšãã°æ¬¡ã®ææžã«èšèŒãããŠããïŒ
ãZ.Wiss.Phot.ã第46巻第65é â第72é ïŒ1951
幎ïŒã«æ²èŒãããŠããR.ã³ã¹ããŠã¹ããŒã®è«
æã ãã®ä¹³å€ã¯ãŸã次ã®å¢æå€ã§ãå¢æã§ããïŒã
ãªã¢ã«ãã¬ã³ãªããµã€ãèªå°äœãããšãã°ååé
1000â20000ã®ããªãšãã¬ã³ãªããµã€ãïŒã¢ã«ã
ã¬ã³ãªããµã€ããšèèªæã¢ã«ã³ãŒã«ãã°ãªã³ãŒ
ã«ãããã·ããŒã«ã®ç°åè±æ°Žçæç©ãã¢ã«ãã«çœ®
æããšããŒã«ãèèªæã«ã«ãã³é žãèèªæã¢ã
ã³ãèèªæãžã¢ãã³ãã¢ããçãšã®çž®åçæç©ã
ãã®çž®åçæç©ã®ååéã¯å°ãªããšã700ã奜ãŸ
ããã¯1000以äžã§ãããç¹å¥ãªå¹æãåŸããã
ã«ããããã®å¢æå€ãçµåãããŠçšããããšãå¿
è«å¯èœã§ããïŒããšãã°ãã«ã®ãŒç¹èš±ç¬¬537278å·
æ现æžãè±åœç¹èš±ç¬¬727982å·æ现æžçïŒã ãã®ä¹³å€ã«å åŠå¢æïŒã¹ãã¯ãã«å¢æïŒãè¡ãª
ãããšãå¯èœã§ããããã®ç®çã®ããã«ããšãã°
次ã®å¢æå€ã䜿çšã§ããïŒæ®éã®ã¢ãã¡ãã³ãŸã
ã¯ããªã¡ãã³ææããšãã°é žæ§ãŸãã¯å¡©åºæ§ã·ã¢
ãã³ãããã·ã¢ãã³ãã¹ãã¬ããã·ã¢ãã³ãã¡ã
ã·ã¢ãã³ããªããœããŒã«ããããªããœããŒã«ãã¹
ããªã«ææããã³ä»ã®ææïŒäžæ žåãŸãã¯å€æ žå
ã¡ãã³ææããšãã°ããŒãã·ã¢ãã³ãããªã·ã¢ã
ã³ãå å«ããïŒããã®çš®ã®å¢æå€ã¯ããšãã°æ¬¡ã®
æç®ã«èšèŒãããŠããïŒF.M.ããŒããŒèã®æžç±
ãã¶ïŒã·ã¢ãã³ïŒãã€ãºïŒã¢ã³ãïŒãªã¬ãŒãã
ãïŒã³ã³ããŠã³ãºãïŒ1964幎ïŒãã€ã³ã¿ãŒãµã€ãšã³
ã¹ïŒãããªã·ã€ãŒãºïŒãžãšã³ïŒãŠã€ãªãŒïŒã¢ã³
ãïŒãµã³ãºïŒããŠãŒãšãŒã¯ã ãã®ä¹³å€ã¯åžžçšå®å®å€ãå«æãåŸããããããŠ
ãã®ãããªå®å®å€ã®äŸã«ã¯æ¬¡ã®ãã®ããããã
ãïŒè³éŠç°ãŸãã¯è€çŽ ç°ãæããæ°Žéå«æå極æ§
ååç©ãŸãã¯å¡©åååç©ããšãã°ã¡ã«ã«ããããª
ã¢ãŸãŒã«ïŒåçŽæ°Žéååç©ïŒã¹ã«ãããŠã æ°Žéè€
å¡©ïŒä»ã®æ°Žéååç©ãã¢ã¶ã€ã³ãã³ããŸãé©åœãª
å®å®å€ã§ãããããã©âããã³ãã³ã¿âã¢ã¶ã€ã³
ãã³ã奜ãŸããããããŠãããããã·ã«åºãŸãã¯
ã¢ããåºã§çœ®æãããŠããã¢ã¶ã€ã³ãã³ãç¹ã«å¥œ
ãŸããããã®çš®ã®ååç©ã¯ããšãã°æ¬¡ã®æç®ã«èš
èŒãããŠããïŒãZ.Wiss.Phot.ã第47巻第ïŒé â
第27é ïŒ1952幎ïŒã«æ²èŒãããŠãããã¢ã®è«æã
ä»ã®é©åœãªå®å®å€ã®äŸã«ã¯è€çŽ ç°åŒã¡ã«ã«ããå
åç©ããšãã°ããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ïŒ
第ïŒçŽãã³ãŸãã¢ãŸãŒã«èªå°äœïŒãã³ãŸããªã¢ãŸ
ãŒã«ã ãã®åçå±€ã«äœ¿çšããããã€ã³ããŒã¯ãŒã©ãã³
ã§ããããšã奜ãŸãããããŒã©ãã³ãŸãã¯ãã®äž
éšã®ä»£ãã«ä»ã®å€©ç¶ãŸãã¯åæãã€ã³ããŒã䜿çš
ããããšãã§ãããé©åœãªå€©ç¶ãã€ã³ããŒã®äŸã«
ã¯ã¢ã«ã®ã³é žããã³ãã®èªå°äœïŒããšãã°å¡©ããš
ã¹ãã«ãã¢ããïŒïŒã»ã«ããŒãºèªå°äœããšãã°ã«
ã«ããã·ã¡ãã«ã»ã«ããŒãºãã¢ã«ãã«ã»ã«ããŒãº
ïŒããšãã°ããããã·ãšãã«ã»ã«ããŒãºïŒïŒæŸ±ç²
ãŸãã¯ãã®èªå°äœïŒããšãã°ãšãŒãã«ããšã¹ã
ã«ïŒïŒã«ã©ã²ããŒããé©åœãªåæãã€ã³ããŒã®äŸ
ã«ã¯æ¬¡ã®ãã®ããããããïŒããªããã«ã¢ã«ã³ãŒ
ã«ãéšåçã«é¹žåãããããªããã«ã¢ã»ããŒãã
ããªããã«ãããªãã³ããã³ãã®é¡äŒŒç©ã ãã®åçå±€ã¯åžžæ³ã«åŸã€ãŠç¡¬èåïŒç¡¬åïŒã§
ããããããŠã䜿çšã§ãã硬èå€ã®äŸã«ã¯æ¬¡ã®ã
ã®ããããããïŒãã«ã ã¢ã«ãããïŒã«ã«ããã·
åºãæããããã²ã³çœ®æã¢ã«ãããããšãã°ã ã³
ããã é žïŒãžã±ãã³ïŒã¡ã¿ã³ã¹ã«ãã³é žã¹ã«ãã³
é žãšã¹ãã«ïŒãžã¢ã«ãããã æ¬çºæã«åŸã€ãæææ¡æ£è»¢åæ³ã®å®æœæ¹æ³ã«ã€
ããŠè©³çŽ°ã«èª¬æãããïŒãŸãã¯ãã以äžã®ããã²
ã³åéä¹³å€å±€ãšãããã«ä»éããéæ¡æ£æ§ææäŸ
äžååç©ãšãæããæå æ§èŠçŽ ã䜿çšããããã
ã«ãç»ååå ¥èŠçŽ ãã䜿çšããããã®ç»ååå ¥èŠ
çŽ ã§ã¯ãç»åã®åœ¢ã®éãã«ããã«ç§»ãããæ¡æ£æ§
ææã«ãããææã®ã«ã©ãŒç»åãçæã§ãããã
ã«ãªã€ãŠãããçŸåæäœå®æœæã«ãããŠããã®å®
æœæéã®ãã¡ã®å°ãªããšãæäžå®ã®æéã®éã¯å
èšæå æ§èŠçŽ ãšåèšç»ååå ¥èŠçŽ ãšãå¯çãããª
ããã°ãªããªãããããã«ãã€ãŠãçŸåã«ããç
ããæ¡æ£æ§ææãç»åã®åœ¢ã®éãã«ååžããç¶æ
ã§åèšç»ååå ¥èŠçŽ ã®æ¹ã«ç§»ãããšãã§ããã®ã§
ããããã®å¯çã¯ãçŸåæäœéå§åŸã«è¡ãããšã
ã§ãããŸãã¯çŸåæäœéå§åã«ããè¡ãããšãã§
ããããã®ç¬¬ïŒçªç®ã®æäœã¯ãããšãã°ããã®æ
ææ¡æ£è»¢åæ³ã«äœ¿çšãããåçææããæå æ§èŠ
çŽ ãšç»ååå ¥èŠçŽ ãšãäžç·ã«ãªã€ãŠåäœãŠããã
ã®åœ¢ã«ãªã€ãŠãããããªåçææã§ããå Žåçã«
è¡ããããã®ã§ããããã®åäœãŠãããã¯ã以äž
ã§ã¯ãã¢ãã·ãŒãææããšç§°ããããšã«ãããã
ã®ã¢ãã·ãŒãææã¯çŸåå®æœåŸã«ãããŠããåäœ
ãŠããããšããŠæ®ããããªãã¡ãææ転åå·¥çšçµ
äºåŸã«ãããŠããæå æ§èŠçŽ ãšç»ååå ¥èŠçŽ ãšã®
çžäºåé¢ã¯è¡ãããªãã®ã§ããããã®ãããªæäœ
ã®å®æœæ¹æ³ã¯ãããšãã°ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
2019430å·çã«èšèŒãããŠããã æ¬çºæã«ä¿ãæææ¡æ£è»¢åæ³ãå®æœããã®ã«é©
ããã¢ãã·ãŒãææã®äŸã«ã¯ãäžèšã®åçå±€ãæ
ãããã®ããããããã (1) éæãªæ¯æå±€ (2) ç»ååå ¥å±€ (3) é®å å±€ (4) å°ãªããšãïŒã€ã®æå æ§ããã²ã³åéä¹³å€å±€
ãšããã«ä»éããå°ãªããšãïŒã€ã®èæ¡æ£æ§æ
æäŸäžååç©ãšãæããæå æ§èŠçŽ (5) ã¬ã¿ãŒãžã³ã°å±€ (6) é žæ§éåäœå±€ (7) éææ¯æå±€ ãã®ã¢ãã·ãŒãææã¯æ¬¡ã®åŠã圢æã§ãããçž
ç°ãªãïŒã€ã®éšæãããªãã¡æå æ§éšæïŒå±€ç¶èŠ
çŽ ïŒâïŒïŒãšã«ããŒã·ãŒãïŒå±€ç¶èŠçŽ ïŒâïŒïŒãš
ã®ïŒã€ã®éšæãå¥ã ã«äœãã次ãã§ãã®ïŒã€ã®éš
æããã®æŽ»æ§é¢ãäºãã«åããåãããã«ããŠäž
ç·ã«ããçžäºã«æ¥çãããããææãªãã°ãæå®
éïŒæ£ç¢ºã«æž¬å®ãããéïŒã®åŠç液ãæ£ç¢ºã«åèš
ã®ïŒã€ã®éšæã®éã®ç©ºéã«äŸçµŠããããã«ããã®
ïŒã€ã®éšæã®éã«ã¹ããŒãµãŒã¹ããªãããä»åšã
ããããšãå¯èœã§ãããå±€ç¶èŠçŽ ïŒããã³ïŒã¯äž
åç³»ãæ§æãããã®ã§ãããããã®å±€ç¶èŠçŽ ïŒã
ãã³ïŒã®ä»£ãã«ããããã¯ãããã®èŠçŽ ã«å ã
ãŠããããšåæ§ãªèŠçŽ ãæ¯æå±€ãšæå æ§éšæäžã®
ç»ååå ¥å±€ãšã®éã«é 眮ããããšãå¯èœã§ããã
ãã ããã®å Žåã«ã¯ããã®ïŒã€ã®å±€ç¶èŠçŽ ã®é å
é åºãéã«ããªããã°ãªããªãã åèšã®æå æ§éšæãšã«ããŒã·ãŒããšã®éã®å°ç¹
ã«åŠç液ãäŸçµŠããããã«é©åœãªäŸçµŠæ段ãèšã
ãããšãã§ãããã®äŸçµŠæ段ã¯ãããšãã°ãè£ã
ããšã«ãããå£ããããã§ãã容åšã®åœ¢ã®ãã®ã§
ãã€ãŠããããã®å®¹åšã¯åèšã¢ãã·ãŒãææã®åŽ
éšã«é 眮ã§ãããããŠãããã«æ©æ¢°åãå ãããš
ãã«ããã®å®¹åšããå 容ç©ïŒåŠç液ïŒãåºãŠãã
ã®ã¢ãã·ãŒãææäžã§äºãã«é£æ¥ããïŒã€ã®å±€ã®
éã®æå®ã®å°ç¹ã«è©²å 容ç©ãäŸçµŠã§ããããã«ãª
ã€ãŠãããã®ã§ããåŸãã æ¬çºæã«ä¿ãåçææã®å¿ é èŠä»¶ã®ïŒã€ã¯ãæ
å æ§ããã²ã³åéä¹³å€å±€ãšãããã«ä»éããèæ¡
æ£æ§ææäŸäžååç©ãšãæããæå æ§èŠçŽ ãé 眮
ããããšã§ããïŒã¢ãã¯ã転åæ³ã®å ŽåïŒããã®
èæ¡æ£æ§ææäŸäžååç©ã¯åèšæå æ§ããã²ã³å
éä¹³å€å±€ã®é£ãã®å±€ã«ååšãããŠããããããã
ã¯è©²ããã²ã³åéä¹³å€å±€èªäœã®äžã«ååšãããŠã
ãããåŸè ã®å Žåã«ã¯ããã®ææäŸäžååç©ã®äž»
åžå éšã®æ³¢é·ãããã²ã³åéä¹³å€å±€ã®äž»æå æ³¢é·
ã«äžèŽããªãããã«ããããã«ãç»åææïŒã€ã¡
ãŒãžãã€ïŒã®è²ãé©åœã«éžã¶ã®ã奜ãŸããã ããããªããããªãªãžãã«ã®è²ãšæ¬åœã«åãè²
ã®å€è²è»¢åç»åãäœæããå Žåã«ã¯ãææäŸäžå
åç©ãšããã«ä»éããæå æ§ããã²ã³åéä¹³å€å±€
ãšã®çµåãããïŒçµæããæå æ§èŠçŽ ã䜿çšãã
ãããŠäžè¬ã«è©²ææäŸäžååç©ã®åžå éšã®æ³¢é·ç¯
å²ãã該ååç©ã«äŒŽãããã²ã³åéä¹³å€å±€ã®ã¹ã
ã¯ãã«æ床ã®æ³¢é·ç¯å²ã«å®è³ªçã«äžèŽããããã«
ããªããã°ãªããªããæ床ãã§ããã ãé«ããã
ããã«å¿ èŠãªåææ¡ä»¶ã¯ããã®çºè²ææã®çµåã
ãã¯ãåèšããã²ã³åéä¹³å€ã®åŸæ¹ã®ïŒé²å æã®
å ¥å°å ç·ã®æ¹ååºæºïŒå¥åã®ãã€ã³ããŒå±€ã®äžã«
é 眮ãã¹ãã§ãããšããããšã§ããã å¿è«ãããã²ã³åéä¹³å€ã®çŸåæã«çããçŸå
è¬ã®é žåçæç©ã¯ãä»éããææäŸäžååç©ã®ã¿
ã«äœçšãããã®ã§ããã¹ãã§ããããããã€ãŠã
çŸåè¬ã®é žåçæç©ããä»éé¢ä¿ã®ãªãåçå±€ã®
æ¹ã«æ¡æ£ããã®ãé²ãããã«ãæå æ§èŠçŽ ã®äžã«
é¢éå±€ïŒæ¡æ£é²æ¢å±€ïŒãèšããã®ãäžè¬ã«æå©ã§
ããã ãã®é¢éå±€ã¯ãããšãã°ãçŸåè¬ã®é žåçæç©
ãšé©åã«åå¿ãåŸãç©è³ªãå«æãåŸãã該ç©è³ªã®
äŸã«ã¯èæ¡æ£æ§ãã€ããããã³èªå°äœããããã
ãããŸãã䜿çšãããçŸåè¬ãçºè²çŸåè¬ã§ãã
å Žåã«ã¯ãåèšç©è³ªãšããŠèæ¡æ£æ§ã«ã©ãŒã«ãã
ã©ãŒã䜿çšã§ããããããã€ãŠæ¬çºæã®å¥œãŸãã
å ·äœäŸã§ã¯ã次ã®çŽ¯å±€æ§é ãæããæå æ§èŠçŽ ã
䜿çšãããã®ã§ããïŒåå±€ãäžããäžã«åãã€ãŠ
é çªã«ç€ºãïŒã éææ§ããã²ã³åéä¹³å€å±€ æ¡æ£æ§é»è²ææãæŸåºãåŸãèæ¡æ£æ§ååç©ã
å«ãå±€ é¢éå±€ ç·è²å¢æããã²ã³åéä¹³å€å±€ æ¡æ£æ§ããŒã³ã¿ææãæŸåºãåŸãèæ¡æ£æ§åå
ç©ãå«ãå±€ é¢éå±€ èµ€è²å¢æããã²ã³åéä¹³å€å±€ æ¡æ£æ§ã·ã¢ã³ææãæŸåºãåŸãèæ¡æ£æ§ååç©
ãå«ãå±€ ãããã®ããã²ã³åéä¹³å€å±€ã®é åé åºãå€ã
ãããšãå¿è«å¯èœã§ãããããã®å Žåã«ã¯ãçºè²
ç³»ãæããä»éå±€ã®é åé åºãå€ããåèšã®ä»é
é¢ä¿ã確å®ã«ä¿ã€ããã«ããªããã°ãªããªãã æå æ§èŠçŽ ã®äžåŽã«é 眮ãããé®å å±€ã¯ãæ°Žæ§
ã¢ã«ã«ãªåŠç液ãééã§ãããããã€ãŠæ¡æ£æ§æ
æããééã§ãããã®ã§ãããããã¯ïŒã€ã®åœ¹å²
ãæãã第ïŒã®åœ¹å²ã¯ããã®åçææããçŸååŸ
ã«æå æ§éšæã®äžã®éæãªæ¯æå±€ãéããŠèŠããš
ãã«ãããžã«ã©ãŒè»¢ååã®ã¿ãèŠããããã«ãçŸ
ååŸã«ãå ã®ãªãªãžãã«æå æ§èŠçŽ ã®äžã«æ®ã€ãŠ
ããç»åéïŒã€ã¡ãŒãžã·ã«ããŒïŒãããã³ãã¬ã«
ã©ãŒãšããŠæ®ã€ãŠããææäŸäžååç©ããé èœã
ãããšã§ããã第ïŒã®åœ¹å²ã¯ç»ååå ¥å±€ã®åŽéš
ïŒåºéšïŒããå ç·ãæå æ§èŠçŽ ã«å ¥ãããšãé²ã
ããšã§ããããã®ã¢ãã·ãŒãææãé²å åŸã«ãã
ããããããªãã«ã¡ã©äžã«ååšãããšãã«ãã¢ã«
ã«ãªæ§ã®åŠççšå€ãšæ¥è§Šããã次ãã§ã«ã¡ã©ãã
åŒåºããŠã«ã¡ã©ã®å€åŽã§çŸåããæäœãè¡ãå Žå
ã«ã¯ãäžèšã®é®å æ段ãç¹ã«éèŠãšãªãã å åãªé®å æ§ãæãããæ¡æ£æ§ææã¯ééãã
ããããªåçå±€ã¯ãããšãã°ãç¡æ©ãŸãã¯ææ©æ
è²é¡æ奜ãŸããã¯é»è²é¡æã®æžæ¿æ¶²ïŒããšãã°ã«
ãŒãã³ãã©ãã¯ããŒã©ãã³æ¶²çã®é©åœãªãã€ã³ã
ãŒäžã«å ¥ããŠäœã€ãæžæ¿æ¶²ïŒãçšããŠè£œé ã§ã
ããçŸåæäœå®æœäžã¯å åãªé®å æ§ãä¿ã€ãã
ã«ãã«ãŒãã³ãã©ãã¯ã10â90ééïŒ ïŒä¹Ÿç¥æé
éåºæºïŒå«ãåã0.5ãïŒÎŒã®å±€ãèšããã®ãäž
è¬ã«å¥œãŸããããã®é¡æã®ç²ååŸã¯æŠããŠéèšç
çã§ãããã0.5ÎŒãå®è³ªçã«è¶ããªãå€ã§ãã
ããšã奜ãŸããã åèšé®å å±€ã«ã¯ãé»è²é¡æå±€ã«å ããŠãçœè²é¡
æå±€ãã該é»è²é¡æå±€ã®ããäžåŽã«é 眮ããã®ã
奜ãŸããããã®çœè²é¡æå±€ã®ç®çã¯ãé»è²å±€ãèŠ
ãé ãããšãããã³ç»åã®ããã®çœè²ããã¯ã°ã©
ãŠã³ããæäŸããããšã§ããããã®ç®çã®ããã«
ä»»æã®çœè²é¡æã䜿çšã§ããããã ããã®çœè²é¡
æã¯ãé床ã«åããªãåãã«ãããŠãå åãªé èœ
åããã€ãã®ã§ãªããã°ãªããªããé©åœãªçœè²é¡
æã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒç¡«é žããªãŠ
ã ãé žåäºéãé žåãã¿ã³ãé žåçªçŽ ãé žåã¢ã«
ãããŠã ãé žåãžã«ã³ããŠã ãã¹ãã¢ãªã³é žããª
ãŠã ãã«ãªãªã³ãçœè²é¡æå±€äœææã®æ¡ä»¶ïŒãã€
ã³ããŒãæ¿åºŠãç²ååŸïŒã¯ãåèšé»è²é¡æå±€äœæ
æã®å Žåãšå®è³ªçã«åãã§ãããçœè²é¡æå±€ã®å
ã¿ã¯ãç»åã®ããã¯ã°ã©ãŠã³ããšããŠææããã
çœè²åºŠã®å€ã«å¿ããŠçš®ã å€ããããšãã§ãããã
ã®å±€åã¯ïŒâ20ÎŒã«ããã®ãäžè¬ã«å¥œãŸããã æ¬çºæã«ä¿ãã¢ãã·ãŒãææã®äžã«é®å å±€ãé
眮ãã代ãã«ãæå æ§èŠçŽ ãšç»ååå ¥å±€ãšã®éã«
é®å 局圢æçšæ段ãèšããããšãå¯èœã§ãããã
ãšãã°ãäžéæåå€ïŒé¡æïŒãå«ã容åšã®åœ¢ã®å
èšæ段ãã¢ãã·ãŒãææã®åŽéšã«é 眮ããããšã
ã§ããããã®å Žåã«ã¯ã該容åšã«æ©æ¢°åãå ãã
ãšãã«å®¹åšããå 容ç©ãæŸåºãããåèšã®ïŒã€ã®
å±€ã®éã«å ¥ããæ¢è¿°ã®çš®é¡ã®é¡æå±€ã圢æã§ãã
ã®ã§ããã ç»ååå ¥å±€ã¯ãæ¡æ£æ§ææãå®çãããããã®
ææçšåªæå€ïŒã¢ã«ãã³ãïŒå«æãã€ã³ããŒãã
å®è³ªçã«ãªããã®ã§ããã é žæ§ææçšåªæå€ã¯ãé·é第ïŒã¢ã³ã¢ããŠã â
ãŸãã¯âãã¹ãããŠã ååç©ããããã¯ç¬¬ïŒã¹ã«
ãããŠã ååç©ã§ããããšã奜ãŸããããã®å ·äœ
äŸã¯ãç±³åœç¹èš±ç¬¬3271147å·ããã³ç¬¬3271148å·æ
现æžçã«èšèŒãããŠããããŸããé žæ§ææãšã®å
å¿ã«ããé£æº¶æ§ååç©ã圢æãåŸãæçš®ã®éå±å¡©
ããã³ãã®ããããã·ãååç©ã䜿çšã§ãããã
ã®ææåªæå€ã¯ãåèšç»ååå ¥å±€ã®äžã®åžžçšèŠªæ°Ž
æ§ãã€ã³ããŒã®ãã¡ã®ããããïŒããšãã°ãŒã©ã
ã³ãããªããã«ãããªãã³ããããã¯å®å šã«ãŸã
ã¯éšåçã«å æ°Žå解ãããã»ã«ããŒãºãšã¹ãã«ïŒ
ã®äžã«åæ£ãããŠäœ¿çšã§ãããæçš®ã®ãã€ã³ããŒ
ã¯åªæå€ãšããŠã®æ©èœããæãåŸããã®ã§ãã€
ãŠããã®ãããªãã€ã³ããŒã®äŸã«ã¯æ¬¡ã®ãã®ãã
ããããïŒããã«ã¢ã«ã³ãŒã«ããã³ïŒ®âããã«â
ãããªãã³ãšã®å ±éåäœãŸãã¯éåäœæ··åç©ïŒã
ãšãã°ãç¬åœç¹èš±å ¬åå ¬å ±ç¬¬1130284å·çã«èšèŒ
ã®ãã®ïŒïŒå¡©åºæ§ç¬¬ïŒçŽçªçŽ ååç©ã®éåäœãã
ãšãã°ïŒ®âã¡ãã«âïŒâããã«ããªãžã³ã®éåäœ
ïŒç±³åœç¹èš±ç¬¬484430å·æ现æžçïŒããªãäžèšä»¥å€ã®
é©åœãªåªæäœçšä¿æãã€ã³ããŒã®äŸã«ã¯ã¢ã·ã«ã¹
ãã¬ã³éåäœã®ã°ã¢ãã«ããã©ãŸã³èªå°äœïŒç¬åœ
ç¹èš±å ¬éå ¬å ±ç¬¬2009498å·çïŒãããããããã
ãããªãããæåŸã«è¿°ã¹ãåªæäœçšä¿æãã€ã³ã
ãŒã«ã¯ãäžè¬ã«ä»ã®ãã€ã³ããŒïŒããšãã°ãŒã©ã
ã³ïŒãæ·»å ãããã§ãããã æ¬çºæã«ä¿ãåèšã¢ãã·ãŒãææã«äœ¿çšããã
éæãªæ¯æå±€ã¯ãåçåéã«ãããŠæ £çšãããŠã
ãéæãªæ¯æå±€ã§ãã€ãŠãããããšãã°ã»ã«ããŒ
ãºãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããª
ã«ãŒãããŒããŸãã¯ä»ã®ãã€ã«ã 圢ææ§éåäœã
ããªãèå±€ç©ïŒãã€ã«ã ïŒã§ãã€ãŠãããåèšã®
ã¢ã«ã«ãªæ§åŠçå€ïŒprocessing massïŒã«ããã
ã®æå ææã®PHãæ¯èŒçé«ãå€ïŒçŽ11â14ïŒã«ãª
ããçŸåãè¡ããããã€ç»åã®åœ¢ã®éãã®æææ¡
æ£ãè¡ãããããã®ãããªé«PHå€ã®ãšãã«ã¯ææ
ããã³ç»åãããŸãå®å®ã§ã¯ãªãããšãèŠåºãã
ãããããã€ãŠãçŸåå®äºåŸã«ã¯æå ææã®PHå€
ãäžæ§ãŸãã¯åŒ±é žæ§åŽã®å€ã«èª¿ç¯ããªããã°ãªã
ãªãããã®èª¿ç¯ã®ããã«ãåžžæ³ã«åŸã€ãŠãçŸåæ
äœå®æœäžã«ã¯åèšã¢ã«ã«ãªæ§åŠçå€ã«ã¯åŸã ã«ã
ãæ¥è¿ããªãé žæ§éåäœå±€ããã®æå ææå ã«èš
ããããšãã§ãããããã«äœ¿çšãããçšèªãé žæ§
éåäœå±€ãã¯ãé žåºïŒå¥œãŸããã¯ã¹ã«ãåºãã«ã«
ããã·ã«åºïŒãæããéåäœååç©ãå«æããã
ã€ã³ããŒå±€ãæå³ããããã®é žåºã¯ã¢ã«ã«ãªæ§åŠ
çå€äžã®ã«ããªã³ãšåå¿ãã該åŠçå€ã®PHãäœäž
ããããå¿è«ãã®éåäœååç©ïŒããã³ãã®äžã®
é žåºïŒã¯èæ¡æ£æ§ç©è³ªã®åœ¢ã§äžèšå±€ã«æ·»å ãã
ãããã®é žæ§éåäœã¯ãå€ãã®å Žåã«ãããŠã»ã«
ããŒãºãŸãã¯ããªããã«ååç©ã®èªå°äœã§ãã
ããä»ã®éåäœååç©ã䜿çšã§ãããé©åœãªé žæ§
éåäœã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒéé¢ã«ã«
ããã·ã«åºãæããã»ã«ããŒãºèªå°äœãããšãã°
éé¢ã«ã«ããã·ã«åºãæããã»ã«ããŒãºãžã«ã«ã
ã³é žã»ããšã¹ãã«ïŒããšãã°ã»ã«ããŒãºã¢ã»ããŒ
ãæ°ŽçŽ ãã¿ã¬ãŒããã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ã°
ã«ã¿ã¬ãŒãããšãã«ã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ãµ
ã¯ã·ããŒããã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ãµã¯ã·ã
ãŒãæ°ŽçŽ ãã¿ã¬ãŒãïŒïŒãžã«ã«ãã³é žç¡æ°Žç©ãŸã
ã¯ã¹ã«ãã³é žç¡æ°Žç©ïŒããšãã°ãïœâã¹ã«ãå®æ¯
éŠé žç¡æ°Žç©ïŒã§å€æ§ãããã»ã«ããŒã¹ãšãŒãã«ã
ãã³ã»ã«ããŒãºãšã¹ãã«ïŒã«ã«ããã·ã¡ãã«ã»ã«
ããŒãºïŒããªã¹ãã¬ã³ã¹ã«ãã³é žïŒããªããã«æ°Ž
çŽ ãã¿ã¬ãŒãïŒããªããã«ã¢ã»ããŒãæ°ŽçŽ ãã¿ã¬
ãŒãïŒããªã¢ã¯ãªã«é žïŒã«ã«ããã·ã«åºãŸãã¯ã¹
ã«ãåºã§çœ®æãããã¢ã«ãããïŒããšãã°ïœâã
ïœâãŸãã¯ïœâãã³ãºã¢ã«ãããã¹ã«ãã³é žãŸã
ã¯âã«ã«ãã³é žïŒãšããªããã«ã¢ã«ã³ãŒã«ãšãã
å°ãããã¢ã»ã¿ãŒã«ïŒéšåçã«ãšã¹ãã«åããã
ãšãã¬ã³ïŒãã¬ã€ã³é žç¡æ°Žç©å ±éåäœïŒéšåçã«
ãšã¹ãã«åãããã¡ãã«ããã«ãšãŒãã«ïŒãã¬ã€
ã³é žç¡æ°Žç©å ±éåäœã ãã®é žæ§éåäœå±€ã¯ãã¢ã«ã«ãªæ§åŠçå€ã®PHå€
ã11â14ïŒããšã®å€ïŒãã倧äœäžæ§å€ãŸãã¯åŸ®é ž
æ§åŽã®å€ïŒPHïŒâïŒïŒã«æçµçã«äœäžãããã®ã«
å åãªéã®é žåºãå«ããã®ã§ãªããã°ãªããªãã
PHå€äœäžã®ãšãã®æéé 延ïŒã¿ã€ã ãã¬ã€ïŒå¹æ
ã確ä¿ããããã«ããã®é žæ§éåäœå±€ããããã
ã¬ã¿ãŒãžã³ã°å±€ã§è¢«èŠããããšãã§ããããã®ã¬
ã¿ãŒãžã³ã°å±€ã¯ã¢ã«ã«ãªäžééå±€ã®ïŒçš®ã§ãã€
ãŠããã®å±€ã¯ãã¢ã«ã«ãªã«å¯ŸããŠäžæŽ»å šãªéåäœ
ïŒããšãã°ããªããã«ã¢ã«ã³ãŒã«ããŸãã¯éšåç
ã«ã¢ã»ã¿ãŒã«åãããããªããã«ã¢ã«ã³ãŒã«ïŒã
ããªããã®ã§ããããšã奜ãŸãããPHå€äœäžã®ãš
ãã®æéé 延ã®åºŠåã¯ããã®ã¬ã¿ãŒãžã³ã°å±€ã®å
ã¿ããã³çµæãé©åœã«éžã¶ããšã«ããå ·åãã調
ç¯ã§ãããæ°ããåã®ééç¹æ§ãæããéåäœã
å«ãããªã€ãŒå±€ããããšãã°æ¬¡ã®æç®ã«èšèŒãã
ãŠããïŒç±³åœç¹èš±åºé¡ç¬¬633801å·æ现æžïŒåºé¡æ¥
1975幎10æ20æ¥ïŒãè±åœç¹èš±åºé¡ç¬¬44909175å·æ
现æžãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2455762å·ã ãã®ãããªé žæ§éåäœå±€ãšã¬ã¿ãŒãžã³ã°å±€ãšã®
çµåãããäžåç³»ããšç§°ããããããã¯ããšãã°
ç¬åœç¹èš±ç¬¬1285310å·æ现æžçã«èšèŒãããŠã
ããæ¬çºæã«ä¿ãåçææã¯ãã®ãããªå±€ã®çµå
ããå«ãããšãã§ãããããŠããã¯ãããšãã°æ
å æ§éšæã®äžã®éæãªæ¯æå±€ãšç»ååå ¥å±€ãšã®é
ã«é 眮ã§ããã åèšã®PHå€äœäžãé 延ãããããã®ããïŒã€ã®
æ¹æ³ã¯ãé žæ§éåäœãšã¬ã¿ãŒãžã³ã°å±€ãšãããªã
äžåç³»ãåèšã«ããŒã·ãŒãäžã«èšããããšã§ã
ããå¿è«ãã®ïŒã€ã®å±€ã¯ãã¢ã«ã«ãªæ§åŠçå€äžã®
ã¢ã«ã«ãªãé žæ§éåäœã«å°éããåã«ã¬ã¿ãŒãžã³
ã°å±€ãå ãééããªããã°ãªããªããšããæ¡ä»¶ã
ã¿ããããã«é åããªããã°ãªããªãã æ¬çºæã«ä¿ãæææ¡æ£è»¢åæ³ã¯é©åœãªèªå·±çŸå
åã«ã¡ã©ã®äžã§ããŸã該ã«ã¡ã©ãçšããŠæå©ã«å®
æœã§ãããã®ã§ããããã®ã«ã¡ã©ã«ã¯ãæå æ§èŠ
çŽ ã®é²å æäœå®æœåŸã«é®å çšåŠç液ãæå æ§èŠçŽ
ãšã«ããŒã·ãŒããšã®éã®å°ç¹ã«äŸçµŠããŠãæå æ§
èŠçŽ ãé®å ããïŒé éšããã®å ç·ãå ¥ããªããã
ã«ããïŒè£ 眮ãèšçœ®ã§ããããã®ãããªã«ã¡ã©ã«
ã¯ïŒå¯Ÿã®ã¹ã¯ã€ãºããŒã©ãŒãèšãããã®ããŒã©ãŒ
ãä»ããŠåèšã¢ãã·ãŒãææãåŒåºãããããã«
ãããããŠããã®ã¢ãã·ãŒãææã®åŽéšã«å®¹åšã
èšãããã®å®¹åšãç ŽããŠå£ãéããå 容ç©ããã®
ã¢ãã·ãŒãäžã®æå®ã®å±€éå°ç¹ã«äŸçµŠããããã
ã«ããã®ã奜ãŸããã æå æ§èŠçŽ ã¯ãã¹ã¯ã€ãºããŒã©ãŒééåŸã«ã¯ã
ãã®äž¡åŽã¯é®å å±€ã«ããä¿è·ãããäžææã®é²å
ãè¡ãããªãããã«ãªã€ãŠããããããã®æå æ§
èŠçŽ ã¯çŸåæäœéå§çŽåŸã«ã«ã¡ã©ããåŒåºãããš
ãã§ããã åèšã¢ãã·ãŒãææã®ç»å圢æé²å ãè¡ã€ãåŸ
ã«è©²ææã«çŸååŠçãè¡ãããã«ãæå æ§èŠçŽ ã
ã¢ã«ã«ãªæ§åŠç液ïŒæ°Žæº¶æ¶²ïŒãšæ¥è§Šãããããã
ã«ãã€ãŠãç»å圢æé²å å®æœåŸã®ããã²ã³åéä¹³
å€å±€ãçŸåè¬ååç©ã®ååšäžã«çŸåãããããã®
çŸåã«ããçããããžã®éç»åã®åœ¢ã«äžèŽãã圢
ã§ãçŸåè¬ååç©ã®é žåçæç©ããç»åã®åœ¢ã«å
åžããç¶æ ã§çããããã®é žåçæç©ãåèšã®ä»
éææäŸäžååç©ãé žåãããããŠè©²ææäŸäžå
åç©ã®é žåçæç©ã掻æ§åå€ã®ã¢ã«ã«ãªãšåå¿ã
ãŠãæ¡æ£æ§ææãæŸåºããã®ã§ããã ãã®æ°Žæ§ã¢ã«ã«ãªåŠç液ã¯ããããã·ãšãã«ã»
ã«ããŒãºçã®ç²åºŠäžæå€ãå«æãåŸãããŸã該åŠ
ç液ã¯ãå ¬ç¥ã®çŸåä¿é²å€ãå®å®å€ãé塩溶åªã
ãã¶ãçæå€ïŒãã¶ãå€ïŒãé žåé²æ¢å€ããã³ä»
ã®æ·»å å€ããå«æãåŸãã äŸ ïŒ æ¬çºæã«ä¿ãåçææã®æå æ§èŠçŽ ããæ¯æå±€
ã§ããéæãªããªãšã¹ãã«ãã€ã«ã®äžã«äžèšã®å±€
ãé 次çæãããããšã«ãã補é ããããªããäž
èšã®è¬å€ã®äœ¿çšéã¯ãïŒm2åœãã®äœ¿çšéã§ããã (1) ãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒã400ïœãš
âã¢ã«ãã«âãžãšã¿ããŒã«ã¢ãã³150ïœãšãš
ãã¯ãããããªã³90ïœãšã®å ±éåäœïŒç¬åœç¹èš±
å ¬éå ¬å ±ç¬¬2631521å·ã®å®æœäŸïŒåç §ïŒ5.71ïœ
ãšããŒã©ãã³5.8ïœãšãå«ãåªæå€å«æå±€ (2) äºé žåãã¿ã³27ïœãšãŒã©ãã³2.7ïœãšãå«ã
åå°å±€ (3) ã«ãŒãã³ãã©ãã¯1.85ïœãšãŒã©ãã³ïŒïœãšã
å«ãã«ãŒãã³ãã©ãã¯å±€ (4) ååç©ïŒïŒ0.45ïœïŒãšãŒã©ãã³0.75ïœãšãã
ãªãææå±€ (5) ïŒâïŒ3â²âã«ã«ããã·âããšãã«ïŒâïŒâã¡ã«
ã«ããâããã©ãŸãŒã«ïŒmgãšããªã¯ã¿ãã·ã«â
ãã€ããããã³ã¹ã«ãã³é ž66mgãšãã¢ã»ãã«ã
ãšãã«ããã©ãžã³ïŒmgãšããŒã©ãã³1.3ïœãšã
å«ãç¡ãã¶ãåçŽæ¥ããžçšãšãŒãã¯ããèåé
ä¹³å€ïŒé䜿çšé2.63ïœïŒãå«ãå¢æä¹³å€å±€ (6) ãŒã©ãã³2.6ïœãããªãä¿è·å±€ ã¹ããªããã®åœ¢ã®äžèšæå æ§èŠçŽ ããé段ãã
ã³ãä»ããŠé²å ããããã®æå æ§èŠçŽ ã®äž¡åŽç«¯ã«
åã¿180ÎŒã®ã¹ããŒãµã¹ããªãããïŒã€åä»ãã
ãã€ããŒã¹ãç¶çŸåè¬ãå«ãè¢ïŒè£ãããšãã§ã
ããã®ïŒããã®äžç«¯ã«åä»ããåŸã«ããã®æå æ§
èŠçŽ ãããªãšã¹ãã«ã§èŠã€ããããããŠåŸããã
çµç«äœããïŒå¯Ÿã®ã¹ã¯ã€ãºããŒã©ãŒã®éã®ããã
ãééãããããã«ãã€ãŠããŒã¹ãç¶çŸåè¬ãæ
å æ§èŠçŽ ãšã«ããŒã·ãŒããšã®éã«å°ç¹ã«äŸçµŠã
ããããã§äœ¿çšãããçŸåè¬ã¯æ¬¡ã®çµæãæãã
ãã®ã§ãã€ãã æ°Žé žåã«ãªãŠã 20 ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10 ml ãã©ãã«ã ã¢ã«ããã ïŒ ïœ ãã³ãããªã¢ãŸãŒã« ïŒ ïœ ã¢ã¹ã³ã«ãã³é ž 0.25ïœ ïŒâããããã·ã¡ãã«âïŒâã¡ãã«âããšããã³
1.3 ïœ ãã€ããããã³ 0.1 ïœ ããããã·ãšãã«ã»ã«ããŒãº 30 ïœ æ°Ž æ® éš å š é 1000 ml çŸåã10åéè¡ã€ãåŸã«ç»åä¿æèŠçŽ ãåé¢
ãããããŠãããã«ãªãä»ããŠããããŒã¹ããé€
å»ãããéæãªåºäœãéããŠããžã®ããŒã³ã¿å¯èŠ
åãçãããåèšäºé žåãã¿ã³å±€ã¯ç»åã®ããã¯
ã°ã©ãŠã³ããšããŠåœ¹ç«ã€ãã®ã§ãã€ãã äŸ ïŒ äŸïŒã®å Žåãšåæ§ãªæäœãè¡ã€ãããæ€åºŠã¯ã
å±€ïŒäžã®ååç©ïŒã®ä»£ãã«ååç©ïŒâïŒãïŒãïŒ
ããã³æ¯èŒå¯Ÿç §çšååç©âãçšãããäŸïŒã®
å Žåãšåæ§ãªåŠçãè¡ã€ãåŸã«ãããžã®ããŒã³
ã¿ãé»è²ãŸãã¯ã·ã¢ã³ææ転ååãããããåŸã
ããããã®å®éšããã³ååç©ïŒãçšããæ¢è¿°ã®å®
éšã®çµæãåŸèšã®è¡šã«ç€ºããããã®çµæããæã
ããªããã«ãæ¬çºæã«ä¿ãååç©ã®äœ¿çšã«ããã
ã¶ãå€Dminãå®è³ªçã«æ¹åã§ããã®ã§ããã ã¢ã©ãã¢æ°åã§ç€ºããææååç©ã¯æ¬çºæã«ä¿
ãååç©ã§ãããããŒãæ°åã§ç€ºããææååç©
ã¯å¯Ÿç §ååç©ã§ãã€ãŠããã®ååŠåŒã¯è¡šã®åŸã«èš
èŒãããŠãããå¯Ÿç §ææãããããã³
ã¯ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2505248å·èšèŒã®æ¹æ³ã«ã
ãåŸããããã®ã§ãããå¯Ÿç §ææãããã³
ã¯ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2242762å·èšèŒã®æ¹æ³ã«ã
ãåŸããããã®ã§ããã
22åæããã¢ã«ãã«åºïŒããšãã°ã¡ãã«åºããšã
ã«åºãã€ãœãããã«åºãïœâãªã¯ã¿ãã·ã«åºïŒã
ã·ã¯ãã¢ã«ãã«åºïŒããšãã°ã·ã¯ãããã·ã«
åºïŒãã¢ãªãŒã«åºïŒããšãã°ããšãã«åºïŒãè¡šã
ããåèšã®ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºããã³
ã¢ãªãŒã«åºã¯çœ®æåºããã€ãŠããŠããããããšã
ã°ãåèšã¢ã«ãã«åºã¯ããããã·ã«åºãã¢ã«ã³ã
ã·åºãã¢ããã·åºãããã²ã³ãã«ã«ããã·ã«åºãŸ
ãã¯ã¹ã«ãåºã§çœ®æãããŠããŠããããåèšã¢ãª
ãŒã«åºã¯ããã²ã³ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºã
ãžã¢ã«ãã«ã¢ããåºãã¢ã·ã«ã¢ããåºãã«ã«ãã
ã·ã«åºãŸãã¯ã¹ã«ãåºã§çœ®æãããŠããŠãããã R3ã¯åèšR2ã®å®çŸ©ã®ãšããã§è¿°ã¹ãåºã®ãã
ãããè¡šããããããã¯R3ã¯ãèèªæãŸãã¯è³
éŠæã«ã«ãã³é žãŸãã¯ã¹ã«ãã³é žããå°ãããã¢
ã·ã«åºãè¡šããã R4ã¯æ°ŽçŽ ãè¡šããããããã¯ççŽ ååãïŒâ
22åæããé眮æãŸãã¯çœ®æã¢ã«ãã«åºãè¡šã
ãã åºïŒ¹ã«ããå®æãããåèšçž®åãã³ãŒã³ç°ã¯ã
ïŒãŸãã¯ãã以äžã®çœ®æåºããã€ãŠããŠãããã
ããšãã°æ¬¡ã®çœ®æåºããã€ãŠããŠãããïŒããã²
ã³ããšãã°å¡©çŽ ãèçŽ ïŒççŽ ååæ°22åãŸã§ã®ã¢
ã«ãã«åºããšãã°ã¡ãã«åºãããã«åºããããµã
ã·ã«åºïŒã¢ãªãŒã«åºããšãã°ããšãã«åºïŒãã®ã¢
ãªãŒã«åºã¯çœ®æåºããã€ãŠããŠããããããããŠ
該眮æåºã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒããã²
ã³ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ã
ãåºãã¢ã·ã«ã¢ããåºïŒïŒã¢ã«ã¢ã«ãã«åºããšã
ã°ãã³ãžã«åºïŒã·ã¯ãã¢ã«ãã«åºããšãã°ã·ã¯ã
ããã·ã«åºïŒã¢ã«ã³ãã·åºããšãã°ã¡ããã·åºã
ãšããã·åºãããã·ã«ãªãã·åºããããµãã·ã«ãª
ãã·åºïŒã¢ã«ã¢ã«ã³ãã·åºããšãã°ãã³ãžã«ãªã
ã·åºãã¢ã·ã«ã¢ããåºãŸãã¯ã¢ã·ã«åºïŒãã®ã¢ã·
ã«åºã¯ãèèªæãŸãã¯è³éŠæã«ã«ãã³é žãŸãã¯ã¹
ã«ãã³é žããå°ããããã®ã§ãã€ãŠããïŒïŒã·ã¢
ãåºãã¹ã«ãåºãã«ã«ããã·ã«åºãã¹ã«ãã¢ã¢ã€
ã«åºãã«ã«ãã¢ã€ã«åºïŒãã®ã«ã«ãã¢ã€ã«åºãŸã
ã¯ã¹ã«ãã¢ã¢ã€ã«åºã®çªçŽ ååäžã®ïŒãŸãã¯ãã
以äžã®æ°ŽçŽ ååã¯ä»»æçã«çœ®æãããŠããŠãã
ããããšãã°ã¢ã«ãã«åºã§çœ®æãããŠããŠãã
ãïŒïŒãŸãã¯ãçž®ååçŽ ç°ïŒisocyclic ringïŒãŸ
ãã¯è€çŽ ç°ãå®æãããã®ã«å¿ èŠãªååãŸãã¯å
åå£ã åºïŒ¹ã«ããå®æãããåèšçž®åãã³ãŒã³ç°ãã
ãã€ãã®çœ®æåºããã€ãã®ã§ããå Žåã«ã¯ããã
ãã®çœ®æåºã¯å šéšåäžã§ããå¿ èŠã¯ãªãã æ¬çºæã«ä¿ãææäŸäžååç©ããå®å šãªååã
ïŒã€ã³ã¿ã¯ãååïŒãšããŠååšãããšãã«ã¯ãå
çå±€ãéããŠæ¡æ£ãããã®ã§ãã€ãŠã¯ãªããªãã
ãšãç解ãããã¹ãã§ããããã®ç®çã®ããã«ã
ãã®ååç©ã¯èæ¡æ£æ§ä»äžçšæ®åºããããšãã°æ®
åºR1ã®äžã«æãããããã¯ãã«ããå®æãã
ãåèšçž®åãã³ãŒã³ç°äžã®çœ®æåºã®äžã«æããã®
ã§ããã ã«ããå®æãããåèšçž®åãã³ãŒã³ç°äžã®çœ®
æåºãããã¯R1ãé·éã¢ã«ãã«åºãå«ãŸãªãã
ã®ã§ããå ŽåãããåèšææäŸäžååç©ã¯å åãª
èæ¡æ£æ§ãä¿æã§ããã®ã§ããããªããªãã°ãã®
ååããåèšæææ®åºã®å¯žæ³ã«å¿ããŠå å倧圢ã®
ãã®ã«ããããšãã§ããããã§ããããããã¯ã
å å倧圢ã®èæ¡æ£æ§ä»äžçšæ®åºãé©åœã«éžæãã
ããšã«ããããã®ææäŸäžååç©ã«å åãªèæ¡æ£
æ§ãäžããããšãã§ããã èæ¡æ£æ§ä»äžçšæ®åºãšã¯ãåçææã«åžžçšãã
ã芪氎æ§ã³ãã€ãäžã§æ¬çºæã®ååç©ãèæ¡æ£æ§
ç©è³ªã®åœ¢ã§ååšãåŸãããã«ããããã«ã該åå
ç©äžã«æ¿å ¥ãããæ®åºã®ããšã§ããããã®ç®çã®
ããã«çšããããæ®åºã¯ãææ©æ®åºã§ããããšã
奜ãŸããããã®ãããªææ©æ®åºã¯äžè¬ã«ãçŽéç¶
ãŸãã¯åæç¶èèªæåºãå«ããã®ã§ããããåçŽ
ç°åŒåºãè€çŽ ç°åŒåºãŸãã¯è³éŠæã®åºïŒãããã®
åºã¯äžè¬ã«ççŽ ååãïŒâ20åæãããã®ã§ãã€
ãŠããïŒãå«ããã®ã§ãã€ãŠãããããã®æ®åº
ã¯ãååäžã®ãæ®ãã®éšåãã«çŽæ¥ãŸãã¯éæ¥ã«
çµåããŠãããã®ã§ãã€ãŠãããéæ¥çµåã®å Žå
ã«ã¯ãããšãã°æ¬¡ã®ä»åšåºã®ãããããä»ããŠçµ
åããŠãããã®ã§ãã€ãŠããïŒâNHCOâã
NHSO2âãâNRâïŒããã«ïŒ²ã¯æ°ŽçŽ ãŸãã¯ã¢ã«ã
ã«åºãè¡šããïŒãââãââãâSO2âãããã
ã®èæ¡æ£æ§ä»äžçšæ®åºã¯ãåèšã®åºã®ä»ã«ããã
ã«æ°Žæº¶æ§ä»äžåºãå«æãåŸããã®äŸã«ã¯ã¹ã«ã
åºãã«ã«ããã·ã«åºããããããããã®æ°Žæº¶æ§ä»
äžåºã¯ã¢ããªã³ã®åœ¢ã§ååšããŠããŠããããæ¡æ£
æ§ïŒãŸãã¯èæ¡æ£æ§ïŒã¯è©²ååç©ã®ååã®å¯žæ³ã«
å·Šå³ããããã®ã§ãããããååå šäœãå å倧ã
ããã®ã§ãããšãã«ã¯ãèæ¡æ£æ§ä»äžçšæ®åºãšã
ãŠãæ¯èŒççãåºãçšããã ãã§å åã§ããå Žå
ãããåŸãã åèšæææ®åºã¯ååãšããŠãä»»æã®çš®é¡ã®ææ
ã®æ®åºã§ããåŸãããã ãããã®æææ®åºã¯ãæ
å ææå ã®åçå±€ãééããŠç»ååå ¥å±€ã«å°éã
ãã«å åãªæ¡æ£æ§ãæãããã®ã§ãªããã°ãªããª
ãããã®ç®çã®ããã«ããã®æææ®åºã«ïŒãŸãã¯
ãã以äžã®æ°Žæº¶æ§ä»äžåºãçµåãããŠããããšã
ã§ãããé©åœãªæ°Žæº¶æ§ä»äžåºã®äŸã«ã¯æ¬¡ã®ãã®ã
ãããããïŒã«ã«ããã·ã«åºãã¹ã«ãåºãã¹ã«ã
ã³ã¢ããåºãã¹ã«ãã¢ã¢ã€ã«åºãèèªæãŸãã¯è³
éŠæã®ããããã·ã«åºããã®ã¹ã«ãã¢ã¢ã€ã«åº
ã¯ãææäŸäžååç©ã®å解åå¿çµäºåŸã«ãææå
åã«ããªã倧ããã¢ã«ã«ãªåªè³ªäžæ¡æ£æ§ãä»äžã
åŸããã®ã§ãããããå¥ã®æ°Žæº¶æ§ä»äžåºãè¿œå ç
ã«ååšãããããšã¯å¿ ããããå¿ èŠã§ã¯ãªããæ¬
çºæã«ç¹ã«é©åœãªææã®äŸã«ã¯æ¬¡ã®ãã®ãããã
ããïŒã¢ãŸææãã¢ãŸã¡ãã³ææãã¢ã³ã¹ã©ãã
ã³ææããã¿ãã·ã¢ãã³ææãã€ã³ãžãŽã€ãæ
æãããªããšãã«ã¡ã¿ã³ææãéå±é¯äœææãæ
è²éå±é¯äœã åèšææåé§äœïŒãã¬ã«ãŒãµãŒïŒæ®åºãšã¯ãå
çåŠçå·¥çšäžã®åžžçšåŠç段éã«ãããŠããããã¯
è¿œå çåŠç段éã«ãããŠãé žåã«ããããããã¯
ã«ãããªã³ã°ã«ããããããã¯é¹žåçã«ããçºè²
ç³»å ã§ã®å©è²åºïŒå©è²å£ïŒã®éé¢ïŒããªãã¡å©è²
å£ãéé¢ããŠããããçºè²å£ã«å ããããšïŒã«ã
ããææã«å€æãåŸãååç©ã®æ®åºã®ããšã§ã
ãããã®å Žåã®ææå é§äœã¯ãªãŠãŠã³ææã§ãã€
ãŠãããããããã¯ãåçåŠçå®æœäžã«ä»ã®ææ
ã«å€æãããææãŸãã¯ã«ããã©ãŒã§ãã€ãŠãã
ãããæææ®åºããšãææå é§äœããšãåºå¥ãã
ããšãéèŠãªäºé ã§ãªããšãã«ã¯ãææå é§äœæ®
åºãçšèªãæææ®åºãã®äžã«å«ããŠè«ããã®ã䟿
å©ã§ããã®ã§ã以äžã®èšèŒã§ã¯çšèªãæææ®åºã
ãäžèšã®åºãæå³ã§çšããããšã«ãããæ¬çºæã«
ä¿ãé©åœãªææäŸäžååç©ã®äŸã«ã¯ã次ã®ãã®ã
ãããããã åèšã€ã³ããŒã«åºäžã®çž®åãã³ãŒã³ç°ã«ãã眮
æåºãŸãã¯R1ãïŒäŸ¡åºïŒããšãã°R1â²ãR2â²ïŒã§ã
ãå Žåã«ã¯ãããã¯ïŒåã®ã€ã³ããŒã«ç°ãã€ãªã
ãã®ã§ãã€ãŠããããããšãã°äžèšã®åŠããã®ã§
ããåŸãã ãŸã㯠ææäŸäžååç©ïŒã®è£œé ãã«ãšã³200mläžã§ïŒâã¡ããã·ã€ã³ããŒã«â
ïŒâã«ã«ãã³é žãšãã«ãšã¹ãã«21.9ïœããªã¯ã¿ã
ã·ã«ã¢ãã³29.6ïœãšæ··åãããã«ãšã³50mlãçå»
ãããã50âã«å·åŽããåŸã«ã30ïŒ ãããªãŠã ã¡
ãã¬ãŒã溶液ã3.65mlæ·»å ããåå¿æ··åç©ãéæµ
äžã«ïŒæéç ®æ²žãããåå¿æ··åç©ããŸã ç·©ããã¡
ã«ãããã«å ç±ããããšãªãã¡ã¿ããŒã«ã475ml
滎äžãããåå¿æ··åç©ãå ¶åŸã«ïŒâã«å·åŽããç
ããçµæ¶ïŒã¯ãªã¹ã¿ãªãŒãªãŒãïŒãåžåŒéã«ã
ãåé¢ããã¡ã¿ããŒã«200mlã§æŽæµããã也ç¥æ
äœå®æœåŸã«ã次åŒãæããååç©ã37.2ïœåŸã
ãããåç84ïŒ ïŒçè«å€åºæºïŒèç¹139â142âã ç©åãªå ç±ãè¡ãªããªããæ°·é ¢é ž375mlã«åå
ç©37.2ïœã溶解ãã宀枩ã«å·åŽãããããŠïŒæ
éãèŠããŠäºç¡é žãããªãŠã 7.6ïœãå°ãã¥ã€æ·»
å ãããæ¹æãããã«ïŒæéç¶ãã次ãã§åå¿æ··
åç©ã40âã«çæéå ç±ããæ²æ®¿ååç©ããåžåŒ
éå®æœæã«äžå±€å®¹æã«åé¢ãåŸã圢ã®ãã®ãã«
ããã20âã«å·åŽããåŸã«ãåå¿æ··åç©ã«åžåŒ
éãè¡ãªã€ãŠæ²æ®¿ãåé¢ãããã®æ²æ®¿ãæŽæµã
ããæŽæµã¯ãæåã¯æ°·é ¢é žãçšããŠè¡ãªãã次ã
ã§å€§éã®æ°ŽãçšããŠè¡ãªã€ããæŽæµåŸã«ä¹Ÿç¥ã
ãã次åŒãæããååç©ã39.6ïœåŸããããå
ç99.7ïŒ ïŒçè«å€åºæºïŒã ååç©ïŒ39.6ïœïŒã现ãããµãããééã
ããã¡ã¿ããŒã«370ïœäžã«çããæ¹æäžã«æå ¥ã
ãããã®çµæåŸãããã¹ã©ãªãŒäžã«ããããªãŠã
ãžããªãã€ãïŒäºäºããªã³é žãããªãŠã ïŒ41ïœã®
氎溶液ïŒæ°Žã®éã¯165mlïŒãæ¥éã«æå ¥ãããã®
æ··åç©ã60â65âã®æž©åºŠã«ïŒæéç¶æããããã
ãå ¶åŸã«20âã«å·åŽããæ®çç©ãåžåŒéã«ãã
åé¢ããïŒïŒ ãããªãŠã ãžããªãã€ã溶液600ml
ã§æŽæµããã也ç¥åŸã«ã次åŒãæããååç©ã
36ïœåŸããããåç91ïŒ ïŒçè«å€åºæºïŒã ååç©ãã¯ãããã«ã 50mläžã«å ¥ããŠæ¹æ
ããããªãžã³ïŒmlãæ·»å ãã次ãã§æ¬¡åŒãæã
ãææã¹ã«ãã¯ãã©ã€ã5.5ïœãæ·»å ããã ãã®æ··å液ãïŒæéæ¹æãããã¡ã¿ããŒã«ã
150mlæ·»å ããæ¹æãããã«ïŒæéç¶ãããæ²æ®¿
ããææãåžåŒéã«ããåé¢ããã也ç¥åŸã«å
åç©ã4.4ïœåŸãããããã®ååç©ã次ã®æ¹æ³
ã«åŸã€ãŠç²Ÿè£œãããããªãã¡ããããæããã¯ã
ããã«ã 50mlã«æº¶è§£ãã次ãã§ã¡ã¿ããŒã«ã100
mlæ·»å ãããã®æ··åç©ãïŒæ©äžæŸçœ®ããããã®æ
éã®éã«æ¶åºããååç©ãåžåŒéã«ããåé¢
ããã¡ã¿ããŒã«ã§æŽæµãã也ç¥ãããææäŸäžå
åç©ã2.8ïœåŸããããåç33ïŒ ïŒçè«å€åº
æºïŒã é眮æã€ã³ããŒã«âïŒâã«ã«ãã³é žãšãã«ãšã¹
ãã«ããã³çš®ã ã®çœ®æã€ã³ããŒã«âïŒâã«ã«ãã³
é žãšã¹ãã«ãæ¢ã«æç®ã«èšèŒãããŠããŠå ¬ç¥ã§ã
ããããšãã°ãJ.Chem.Soc.ãã1965幎床ã第
7185é â第7193é ã«ããããŒã¹âãã©ãŠã³ããã³
ãã€ã«ãããã®è«æã«èšèŒãããŠããã®ã§ãæ¬çº
æã«ä¿ãææäŸäžååç©ã¯ãã®å ¬ç¥è£œæ³ãšåæ§ãª
æ¹æ³ã«åŸã€ãŠè£œé ã§ããã®ã§ããã æ¬çºæã«ä¿ãååç©ã®è£œé ã®ããã«ãå¥ã®è£œæ³
ãçšããããšãå¿è«å¯èœã§ãããããšãã°ãé©åœ
ãªã€ã³ããŒã«èªå°äœããžã¢ãŸããŠã å¡©ãšã«ããã«
ããã次ãã§å ¬ç¥æ¹æ³ã«åŸã€ãŠç°å æäœãè¡ãªã€
ãŠã察å¿ããïŒâã¢ããã€ã³ããŒã«ã«éå ããã
ããŠææã¹ã«ãã¯ãã©ã€ããšåå¿ãããããšã«ã
ãæ¬çºæã®ååç©ãçæãããããšãããªã補æ³
ãçšããããšãå¯èœã§ããã æ¬çºæã«ä¿ãææäŸäžååç©ã¯ä»»æã®åžžæ³ã«åŸ
ã€ãŠåçå±€äœæçšãã€ã¹ãã³ã°æ¶²äžã«å ¥ããããš
ãã§ããããã®ãã€ã¹ãã³ã°æ¶²ïŒåœãã®è©²ææ
äŸäžååç©ã®äœ¿çšéã¯ãæ¯èŒçåºãç¯å²å ã§çš®ã
å€ããããšãã§ãããåã ã®å Žåã«ãããæé©æ¿
床ïŒäœ¿çšéïŒã¯ç°¡åãªè©Šéšã«ãã容æã«æ±ºå®ã§ã
ããããšãã°ããã€ã¹ãã³ã°æ¶²ïŒåœã該ææäŸ
äžååç©ãïŒâ80ïœå¥œãŸããã¯20â40ïœäœ¿çšã§ã
ããææå¹æãåŸãããã«ãèæ¡æ£æ§ææäŸäžå
åç©ãšããã²ã³åéãšã®éã«é©åãªäœçœ®çé¢ä¿ã
æ£ç¢ºã«ä¿ã€ããšãå¿ èŠã§ãããããã®é¢ä¿ã¯ãå
åšãã氎溶æ§ä»äžåºãå©çšããŠåèšèæ¡æ£æ§åå
ç©ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ã«æº¶è§£ãããã®æ°Žæº¶æ¶²ãã
ã€ã¹ãã³ã°æ¶²ã«å°å ¥ããããšçã®æäœãè¡ãªãã
ãšã«ããã確å®ã«ç¶æã§ããããããã¯ãåèšè
æ¡æ£æ§ææäŸäžååç©ãå ¬ç¥ä¹³åæ¹æ³ã®ãããã
ã«åŸã€ãŠåçå±€ã«å°å ¥ããŠãããããã®ãããªæ¹
æ³ã¯ãããšãã°æ¬¡ã®æç®ã«èšèŒãããŠããïŒè±åœ
ç¹èš±ç¬¬791219å·ã第1099414å·ã第1099415å·ã第
1099416å·ããã³ç¬¬1099417å·æ现æžãããïŒã€ã®
æ¹æ³ã¯ãææäŸäžååç©ã®æ°Žæ§åæ£æ¶²ãäœããã
ãããã€ã¹ãã³ã°æ¶²ã«æ·»å ããããšã§ããããã®
ç®çã®ããã«æ¬¡ã®æäœãè¡ãªãããšãã§ãããã
ãªãã¡ãåèšææäŸäžååç©ã®æ°Žæ§ã¹ã©ãªãŒã«åŸ®
现åããªã³ã°ãè¡ãªãããã®ããªã³ã°ã¯ãããšã
ã°ã·ã€ãŒããµã³ãïŒè§ã°ã€ã圢ã®ç ç²ãããªã
ç ïŒã®ååšäžã«çããæ¹æãè¡ãªãããšã«ããã
ãããã¯è¶ é³æ³¢ãçšããŠå®æœã§ããããããã¯ã
æ¬çºæã®ããïŒã€ã®å ·äœäŸã«åŸã€ãŠãããšãã°ã
åçå±€äžã«åèšææäŸäžååç©ããã€ã¯ãã«ãã»
ã«ã®åœ¢ã§ããã²ã³åéãšäžç·ã«ããã€å¿ èŠã«å¿ã
ãŠçŸåè¬ãšãäžç·ã«å°å ¥ããããšãæå©ãªæ¹æ³ã§
ãããããã«ããã®ãããªå Žåã«ã¯ãå¢æ床ã®çž
ç°ãªãïŒçš®ãŸãã¯ãã以äžã®æå æ§ããã²ã³åé
ä¹³å€ãšé©åœãªåèšèæ¡æ£æ§ååç©ãšãäžç·ã«ã
ãŠãããããæ··åç²ä¹³å€ïŒmixed grain
emulsionsïŒã®åœ¢ã§ïŒæã®åçå±€ã«æ·»å ããããš
ãå¯èœã§ãããããããŠãã®æè¡ã¯ããšãã°ç±³åœ
ç¹èš±ç¬¬2698794å·æ现æžçã«èšèŒãããŠãããã
ã®èæ¡æ£æ§ææäŸäžååç©ã¯æå å±€ãŸãã¯ãã®é£
ãã®å±€ã®äžã«å ¥ããããšãã§ãããããšãã°ãã·
ã¢ã³ææäŸäžååç©ã¯èµ€æå±€ã«ä»éãããããšã
ã§ããããŒã³ã¿ææäŸäžååç©ã¯ç·æå±€ã«ä»éã
ããããšãã§ããé»è²ïŒã€ãšããŒïŒææäŸäžåå
ç©ã¯éæå±€ã«ä»éãããããšãã§ããã ããã«çšèªãä»éãããä»éãããã¯ãããã²ã³
åéä¹³å€ãšææäŸäžååç©ãšãé 眮ããã«ãã
ãããããã®çžäºã€ã³ã¿ã©ã¯ã·ãšã³ã®çµæãšã
ãŠãçæéç»åãšæŸåºæ¡æ£æ§ææã®ååžç¶æ ãšã®
éã«ãç»åã®åœ¢ã®éãã®å¯Ÿå¿æ§ã確ç«ããåŸãã
ãã«ãåèšä¹³å€ãšåèšååç©ãšãé 眮ããããš
ïŒãŸãé 眮ããããšïŒãæå³ããã ä»éãããã¹ãææäŸäžååç©ã¯ãããã²ã³å
éä¹³å€å±€èªèº«ã®äžã«å ¥ãããããããã¯è©²ããã²
ã³åéä¹³å€å±€ã®é£ãã®å±€ã®äžã«å ¥ããã®ã奜ãŸã
ããããããŠãã®é£æ¥å±€ã¯ãé²å æã®å ¥å°å ç·ã®
æ¹åããã¿ãŠãåèšããã²ã³åéä¹³å€å±€ã®åŸæ¹ã«
é 眮ããã®ã奜ãŸãããéç»åçæçŸåå®æœæ
ã«ãæ¬çºæã«ä¿ãææäŸäžååç©ãçŸåè¬ã®é žå
çæç©ã«ããç»åã®åœ¢ã®éãã«é žåããããããŠ
çŸåè¬ã®ã¢ã«ã«ãªãŸãã¯æŽ»æ§åå€ïŒã¢ã¯ãããŒã¿
ãŒïŒã®äœçšäžã«å解åå¿ãèµ·ããæææ®åºãæ¡æ£
æ§ææã¹ã«ãã³ã¢ããïŒéé¢ã¹ã«ãã¢ã¢ã€ã«åºã
æãããã®ïŒã®åœ¢ã§éé¢ããããã®çŸåã®ããã«
åžžçšçŸåè¬ã䜿çšã§ããããã ããã®çŸåè¬ã¯ã
ãããé žåçæç©ã«ãªã€ããšãã«ãæ¬çºæã«ä¿ã
ææäŸäžååç©ãé žåãåŸããã®ã§ãªããã°ãªã
ãªãã é©åœãªçŸåè¬ã®äŸã«ã¯æ¬¡ã®ãã®ããããããã ãã€ããããã³ã âã¡ãã«ã¢ããããšããŒã«ã ïŒâããšãã«âïŒâãã©ãŸãªãã³ã ïŒâããšãã«âïŒã»ïŒâãžã¡ãã«âïŒâãã©ãŸ
ãªãã³ã ïŒâããšãã«âïŒâã¡ãã«âïŒâããããã·ã¡
ãã«âïŒâãã©ãŸãªãã³ã ïŒâããšãã«âïŒã»ïŒâãã¹âããããã·ã¡ã
ã«âïŒâãã©ãŸãªãã³ã ã¢ããããšããŒã«ã ã»ïŒ®âãžãšãã«âïœâããšãã¬ã³ãžã¢ãã³ã âãšãã«ââããããã·ãšãã«âïœâããš
ãã¬ã³ãžã¢ãã³ã ïŒâã¡ãã«âã»ïŒ®âãžãšãã«âïœâããšãã¬
ã³ãžã¢ãã³ã ã»ïŒ®ã»Nâ²ã»Nâ²âããã©ã¢ã«ãã«âïœâããš
ãã¬ã³ãžã¢ãã³ããšãã°ããã©ã¡ãã«âïœâããš
ãã¬ã³ãžã¢ãã³ãããªãšãã«ã¹ã«ãããã«âïœâ
ããšãã¬ã³ãžã¢ãã³ãïŒã»ïŒâãã¹âãããªãžã
ãã³ãŒã³ã ã¬ãã¯ãã³ã æ¬çºææ¹æ³ã«ãããŠçŸåè¬ãéžæããå Žåãã
ã®çŸåè¬ã¯ã«ã©ãŒçŸåè¬ã®ã¿ã«éå®ããããã®ã§
ã¯ãªããåžžçšçœé»çŸå液ããŸã䜿çšã§ããããšã«
泚ç®ãããããããã¯æå©ãªããšã§ããããªããª
ãã°åŸè ã¯å€è²åŸåã®äœããã®ã§ããããã§ã
ãã ãã®çŸå液ã¯ãã«ã©ãŒåçææäžã®åçå±€ã®äž
ã«å«ãŸããããšãå¯èœã§ããããã®å Žåã«ã¯ãã
ãã¯ã¢ã«ã«ãªæ§æŽ»æ§åå€æº¶æ¶²ã«ãã掻æ§åã§ã
ãããããã¯ãããã¯ã¢ã«ã«ãªæ§åŠç液ãŸãã¯ã
ãŒã¹ãäžã«å ¥ããŠããããæ¬çºæã«ä¿ãææäŸäž
ååç©ã¯ããèªäœçŸåè¬ãšããŠã®æ§è³ªããæãã
ãããæå Žåã«ã¯è£å©çŸåè¬ã®äœ¿çšãçç¥ã§ã
ãããã®ãããªå Žåã«ã¯ããã®ææäŸäžååç©ã¯
çŸåå¯èœããã²ã³åéã«ããçŽæ¥ã«é åãããã®
ã§ããã çŸåå®æœæã«æŸåºãããæ¡æ£æ§ææã¯ç»åã®åœ¢
ã®éãã«ååžããç¶æ ã§ååšãããããã®ååžç¶
æ ã¯çŸåéç»åã®ååžç¶æ ã«äžèŽãããã®ã§ãã
ãããããžã®ã«ã©ãŒè»¢ååã®çæã®ããã«ã¯ãçŽ
æ¥ããžçšããã²ã³åéä¹³å€ãå¿ èŠã§ãããããã
ã¯ããã¬çšã®åžžçšä¹³å€ã䜿çšããå Žåã«ã¯ãé©åœ
ãªãªããŒãµã«çŸååŠçãè¡ãªãå¿ èŠãããã ãã®ç®çã®ããã«é©åœãªãªããŒãµã«çŸåæ¹æ³ã¯
éå¡©æ¡æ£æ³ã§ãããåžžçšã«ã©ãŒã«ããã©ãŒã䜿çš
ããŠéå¡©æ¡æ£æ³ã«ããåçåŠçãªããŒãµã«æäœã
è¡ãªã€ãŠããžã«ã©ãŒç»åãçæãããæ¹æ³ã¯ãã
ãšãã°ç±³åœç¹èš±ç¬¬2763800å·æ现æžã«èšèŒãããŠ
ããããã®å ¬ç¥æ¹æ³ã«ãããŠãã«ã©ãŒã«ããã©ãŒ
ã®ä»£ãã«åèšææäŸäžååç©ã䜿çšããå Žåã«
ã¯ãæææ¡æ£è»¢åæ³ã®ããã«é©åœãªæå èŠçŽ ïŒæ
å ææïŒãåŸãããã§ãããããã®çš®ã®æå èŠçŽ
ã¯ãããšãã°ãæå æ§ããã²ã³åéä¹³å€å±€ãšãã
ãã«ä»éãããã€ã³ããŒå±€ãšã®çµåãããå°ãªã
ãšãïŒã€æãããã€ãç©ççŸåçšçŸåæ žãšåèšæ
æäŸäžååç©ãšãå«ããã®ã§ããã çŸåæäœå®æœæã«ãæå æ§ããã²ã³åéä¹³å€å±€
äžã®é²å éšã®ããã²ã³åéãååŠçã«çŸåãã
ããéé²å éšã®ããã²ã³åéã¯ãããã²ã³åé溶
åªã«ããä»éãã€ã³ããŒå±€ïŒçŸåæ žãå«ãå±€ïŒã«
移ãããããã§ç©ççã«çŸåããããç©çççŸè±¡
ãçŸåè¬ã®ååšäžã«å®æœãããããŠè©²çŸåè¬ã®é ž
åçæç©ãšããã®å±€ã«ååšããææäŸäžååç©ãš
ã®åå¿ã®çµæãšããŠãæ¡æ£æ§ææãæŸåºãããã
ãã«ãªã€ãŠããå Žåã«ã¯ããã®çŸåã®çµæãšã
ãŠã該æ¡æ£æ§ææãç»åã®åœ¢ã®éãã«ååžããç¶
æ ã§ååšããããã«ãªãããããŠè©²æ¡æ£æ§ææã¯
ç»ååå ¥å±€ã®æ¹ã«ç§»ãããããã§ããžã«ã©ãŒç»å
ãçæã§ããã çŸåæå¶å€ãç»åã®åœ¢ã®éãã«ååžããç¶æ ã§
æŸåºãåŸãååç©ãçšããŠãªããŒãµã«çŸåæäœã
è¡ãªãå Žåã«ã¯ããæå æ§ããã²ã³åéä¹³å€å±€ã
ãšããåèšææäŸäžååç©ãå«ã¿ãã€é²å ããã«
çŸåãåŸã第ïŒä¹³å€å±€ããšã®çµåããããå°ãªã
ãšãïŒã€æããæå æ§èŠçŽ ã䜿çšã§ããããã®æ
å æ§ããã²ã³åéä¹³å€å±€ã¯ãããšãã°ãçºè²çŸå
è¬ã®é žåçæç©ãšã®åå¿ã«ããçŸåæå¶ç©è³ªãæŸ
åºãåŸããããªæçš®ã®ååç©ã®ååšäžã«ãçºè²çŸ
åè¬ã«ããçŸåã§ããããã®æå å±€äžã§ç»åã®åœ¢
ã®éãã«æŸåºãããçŸåæå¶ç©è³ªã¯ãé²å ããªã
ãŠãçŸåã§ããé£æ¥ä¹³å€å±€ã®æ¹ã«æ¡æ£ãããããŠ
ããã¯ããã§ç»å圢æçŸåãæå¶ãããé²å ããª
ããŠãçŸåã§ããä¹³å€å±€ã®äžã®éæå¶åºåïŒããž
åºåïŒã¯ãæ®åçŸåè¬ã§çŸåãããããããŠè©²çŸ
åè¬ã®é žåçæç©ã¯å ¶åŸã«æ¬çºæã«ä¿ãéæ¡æ£æ§
ææäŸäžååç©ãšåå¿ã§ãããã®ã§ãã€ãŠããã®
åå¿ã«ããæ¡æ£æ§ææãæŸåºããããããŠè©²ææ
ã¯ç»åã®åœ¢ã®éãã«ç»ååå ¥å±€ã«ç§»ãããã®ã§ã
ããçºè²çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããçŸå
æå¶ç©è³ªãæŸåºãåŸãååç©ã®å¥œãŸããäŸã«ã¯ã
å ¬ç¥ã®DIRã«ããã©ãŒïŒçŸåæå¶å€æŸåºæ§ã«ãã
ã©ãŒïŒããããããããã®DIRã«ããã©ãŒã¯ãã«
ãããªã³ã°äœçœ®ã«é¢è±å¯èœæå¶å€æ®åºãå«ãã«ã©
ãŒã«ããã©ãŒã§ããããã®åã®DIRã«ããã©ãŒã¯
ããšãã°ç±³åœç¹èš±ç¬¬3227554å·æ现æžçã«èšèŒã
ããŠããã çºè²çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããçŸåæ
å¶ç©è³ªãæŸåºãåŸãããïŒã€ã®çš®é¡ã®ååç©ã¯ã
ç±³åœç¹èš±ç¬¬3632345å·æ现æžçã«èšèŒã®ååç©ã§
ãããããã¯ã«ã©ãŒã«ããã©ãŒã§ã¯ãªããããªã
ã¡ããã¯ãçŸåæå¶ç©è³ªã®æŸåºã®ãšãã«ææãç
æãããã®ã§ã¯ãªããç¬åœç¹èš±ç¬¬1229389å·æ现
æžã«ã¯ã奜ãŸããã¯çœ®æåºãæããèæ¡æ£æ§ãã€
ããããã³ååç©ãèšèŒãããŠããããããã¯ã
çŸåè¬ã®é žåçæç©ãšã®åå¿ã«ããé žåãããŠã
察å¿ããããã³ååç©ã«ãªãããã€çŸåæå¶äœçš
ãæããã¡ã«ã«ãã¿ã³ååç©ãæŸåºãããã®ã§ã
ãããããã€ãŠããã®ãã€ããããã³ååç©ã¯äž
èšã®æ¹æ³ã«äœ¿çšãåŸããã®ã§ããã æ¬çºæã«äœ¿çšãããçŽæ¥ããžããã²ã³åéä¹³å€
ã¯ãååãšããŠã次ã®æ§è³ªãæããä»»æã®ããã²
ã³åéä¹³å€ã§ãã€ãŠãããããªãã¡ãåçŽ
ïŒSimpleïŒçŸåã®ãšãã«ããžã®éç»åãçãã
ãããã€çŸåè¬ã®é žåçæç©ããç»åã®åœ¢ã®éã
ã«ååžããç¶æ ã§çæãããããšãã§ãããããª
ããã²ã³åéä¹³å€ã䜿çšã§ããã®ã§ããããã®çš®
ã®ããã²ã³åéä¹³å€ã®äŸã«ã¯ãé²å ãŸãã¯ååŠç
åŠçã«ããçŸåå¯èœãã¶ããçãããããŠãã®ã
ã¶ãããæçš®ã®æ¡ä»¶äžã§ã¯ç»å圢æé²å å®æœäž
ã«ãç»åã®åœ¢ã®éãã«æ¶æ» ã§ãããããªååŒã®ã
ãã²ã³åéä¹³å€ãããããããããªãã¡ãã®ãã¶
ãã¯éé²å éšã§ã¯ç¶æãããã®ã§ãå ¶åŸã®çŸåæ
äœã«ããçŽæ¥ããžéç»åãçããããããã€ãŠã
ãã®çŽæ¥ããžçšããã²ã³åéä¹³å€ã«æ¬çºæã®ææ
äŸäžååç©ãä»éããããšãã«ã¯ãæ¡æ£æ§ææã
åèšéç»åã®åœ¢ã®éãååžããç¶æ ã§ååšããã
ãã«ãªãã æ¬çºæã«ãããŠæå©ã«äœ¿çšã§ããããïŒã€ã®çš®
é¡ã®çŽæ¥ããžçšããã²ã³åéä¹³å€ã¯ãããããç¡
ãã¶ãåçŽæ¥ããžçšããã²ã³åéä¹³å€ã§ãã€ãŠã
ããã¯ãäž»ãšããŠããã²ã³åéç²åã®å éšã«ãå
ã«æããéšåããæãããã®ã§ããããã®ä¹³å€ã«
ç»å圢æé²å ãè¡ãªã€ãå Žåã«ã¯ãäž»ãšããŠãã
ã²ã³åéç²åã®å éšã«æœåãçããã ããããªããããã®ãããªç¡ãã¶ãåçŽæ¥ããž
çšããã²ã³åéä¹³å€ã®çŸåãããã¶ããçºçãã
ãããªæ¡ä»¶ã®ããšã§å®æœããå Žåã«ã¯ããã¶ãã
äž»ãšããŠéé²å éšã«çãããããŠçŸåã®çµæãã
ãžã®éç»åãçããããã®ç¡ãã¶ãåããžçšãã
ã²ã³åéä¹³å€ã®ç¹åŸŽã¯ãé²å åŸã®è©Šæã次ã®çµæ
ã®ä»£è¡šçãªè¡šé¢çŸåè¬ïŒ ïœâããããã·ããšãã«ã°ãªã·ã³ 10ïœ çé žãããªãŠã ïŒçµæ¶ïŒ 100ïœ æ°Ž æ®éš å š é 1000ml ã§çŸåããå Žåã«ã¯ã奜ãŸããã¯éç»åãçããª
ãããŸãã¯éåžžã«äœæ¿åºŠã®éç»åãçããã®ã¿ã§
ãããäžæ¹ã次ã®çµæã®å æ žçŸåè¬ïŒ ãã€ããããã³ 15ïœ ã¢ãã¡ãã«âïœâã¢ããããšããŒã«ãµã«ããšãŒã
15ïœ äºç¡«é žãããªãŠã ïŒç¡æ°Žç©ïŒ 50ïœ èåã«ãªãŠã 10ïœ æ°Žé žåãããªãŠã 25ïœ ããªç¡«é žãããªãŠã ïŒçµæ¶ïŒ 20ïœ æ°Ž æ®éš å š é 1000ml ã§çŸåããå Žåã«ã¯ãå åã«æ¿ãéç»åãçãã
ããšã§ããã ç»å圢æé²å å®æœåŸã®ç¡ãã¶ãåçŽæ¥ããžçšä¹³
å€ã®åèšã®åŠãéžæçãã¶ãçææäœã¯ãçŸåå®
æœåãŸãã¯å®æœäžã«è©²ä¹³å€ããã¶ãçæå€
ïŒfogging agentïŒã§åŠçããããšã«ããå®æœã§ã
ããé©åœãªãã¶ãçæå€ã¯ãããã©ãžã³ãŸãã¯çœ®
æããã©ãžã³ã®åŠãéå å€ã§ããããã®ããšã¯ã
ç±³åœç¹èš±ç¬¬3227552å·æ现æžçã«è©³çŽ°ã«èšèŒãã
ãŠããã ç¡ãã¶ãåçŽæ¥ããžçšä¹³å€ã®äŸã«ã¯ãããã²ã³
åéç²åã®å éšã«ããã®ããä¹³å€ïŒç±³åœç¹èš±ç¬¬
2592250å·æ现æžïŒïŒããã³å±€ç¶ç²åæ§é ãæã
ãããã²ã³åéä¹³å€ïŒç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
2308239å·ïŒãããããããã ãããã®ä¹³å€ã¯ãããšãã°ãã®ååŠçæå·¥çšã«
ãããŠç¡«é»ååç©ïŒããšãã°ã¢ãªã«ã€ãœããªã·ã¢
ããŒããã¢ãªã«ããªå°¿çŽ ãããªç¡«é žãããªãŠã
çïŒãæ·»å ããããšã«ããååŠå¢æã§ããããŸã
ååŠå¢æå€ãšããŠéå å€ãçšããããšãå¯èœã§ã
ãããã®äŸã«ã¯ãã«ã®ãŒç¹èš±ç¬¬493464å·ããã³ç¬¬
568687å·æ现æžçã«èšèŒã®ååç©ããããããã
ãŸããããªã¢ãã³ïŒããšãã°ãžãšãã¬ã³ããªã¢ã
ã³ïŒãã¢ããã¡ã¿ã³ã¹ã«ãã€ã³é žèªå°äœïŒãã«ã®
ãŒç¹èš±ç¬¬547323å·æ现æžçïŒã䜿çšã§ããã éãçœéããã©ãžãŠã ãã€ãªãžãŠã ãã«ãããŠ
ã ãŸãã¯ããžãŠã ã®åŠã貎éå±ããã³ãã®ååç©
ããŸãååŠå¢æå€ãšããŠäœ¿çšã§ããããã®ååŠå¢
ææ¹æ³ã¯ããšãã°æ¬¡ã®ææžã«èšèŒãããŠããïŒ
ãZ.Wiss.Phot.ã第46巻第65é â第72é ïŒ1951
幎ïŒã«æ²èŒãããŠããR.ã³ã¹ããŠã¹ããŒã®è«
æã ãã®ä¹³å€ã¯ãŸã次ã®å¢æå€ã§ãå¢æã§ããïŒã
ãªã¢ã«ãã¬ã³ãªããµã€ãèªå°äœãããšãã°ååé
1000â20000ã®ããªãšãã¬ã³ãªããµã€ãïŒã¢ã«ã
ã¬ã³ãªããµã€ããšèèªæã¢ã«ã³ãŒã«ãã°ãªã³ãŒ
ã«ãããã·ããŒã«ã®ç°åè±æ°Žçæç©ãã¢ã«ãã«çœ®
æããšããŒã«ãèèªæã«ã«ãã³é žãèèªæã¢ã
ã³ãèèªæãžã¢ãã³ãã¢ããçãšã®çž®åçæç©ã
ãã®çž®åçæç©ã®ååéã¯å°ãªããšã700ã奜ãŸ
ããã¯1000以äžã§ãããç¹å¥ãªå¹æãåŸããã
ã«ããããã®å¢æå€ãçµåãããŠçšããããšãå¿
è«å¯èœã§ããïŒããšãã°ãã«ã®ãŒç¹èš±ç¬¬537278å·
æ现æžãè±åœç¹èš±ç¬¬727982å·æ现æžçïŒã ãã®ä¹³å€ã«å åŠå¢æïŒã¹ãã¯ãã«å¢æïŒãè¡ãª
ãããšãå¯èœã§ããããã®ç®çã®ããã«ããšãã°
次ã®å¢æå€ã䜿çšã§ããïŒæ®éã®ã¢ãã¡ãã³ãŸã
ã¯ããªã¡ãã³ææããšãã°é žæ§ãŸãã¯å¡©åºæ§ã·ã¢
ãã³ãããã·ã¢ãã³ãã¹ãã¬ããã·ã¢ãã³ãã¡ã
ã·ã¢ãã³ããªããœããŒã«ããããªããœããŒã«ãã¹
ããªã«ææããã³ä»ã®ææïŒäžæ žåãŸãã¯å€æ žå
ã¡ãã³ææããšãã°ããŒãã·ã¢ãã³ãããªã·ã¢ã
ã³ãå å«ããïŒããã®çš®ã®å¢æå€ã¯ããšãã°æ¬¡ã®
æç®ã«èšèŒãããŠããïŒF.M.ããŒããŒèã®æžç±
ãã¶ïŒã·ã¢ãã³ïŒãã€ãºïŒã¢ã³ãïŒãªã¬ãŒãã
ãïŒã³ã³ããŠã³ãºãïŒ1964幎ïŒãã€ã³ã¿ãŒãµã€ãšã³
ã¹ïŒãããªã·ã€ãŒãºïŒãžãšã³ïŒãŠã€ãªãŒïŒã¢ã³
ãïŒãµã³ãºïŒããŠãŒãšãŒã¯ã ãã®ä¹³å€ã¯åžžçšå®å®å€ãå«æãåŸããããããŠ
ãã®ãããªå®å®å€ã®äŸã«ã¯æ¬¡ã®ãã®ããããã
ãïŒè³éŠç°ãŸãã¯è€çŽ ç°ãæããæ°Žéå«æå極æ§
ååç©ãŸãã¯å¡©åååç©ããšãã°ã¡ã«ã«ããããª
ã¢ãŸãŒã«ïŒåçŽæ°Žéååç©ïŒã¹ã«ãããŠã æ°Žéè€
å¡©ïŒä»ã®æ°Žéååç©ãã¢ã¶ã€ã³ãã³ããŸãé©åœãª
å®å®å€ã§ãããããã©âããã³ãã³ã¿âã¢ã¶ã€ã³
ãã³ã奜ãŸããããããŠãããããã·ã«åºãŸãã¯
ã¢ããåºã§çœ®æãããŠããã¢ã¶ã€ã³ãã³ãç¹ã«å¥œ
ãŸããããã®çš®ã®ååç©ã¯ããšãã°æ¬¡ã®æç®ã«èš
èŒãããŠããïŒãZ.Wiss.Phot.ã第47巻第ïŒé â
第27é ïŒ1952幎ïŒã«æ²èŒãããŠãããã¢ã®è«æã
ä»ã®é©åœãªå®å®å€ã®äŸã«ã¯è€çŽ ç°åŒã¡ã«ã«ããå
åç©ããšãã°ããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ïŒ
第ïŒçŽãã³ãŸãã¢ãŸãŒã«èªå°äœïŒãã³ãŸããªã¢ãŸ
ãŒã«ã ãã®åçå±€ã«äœ¿çšããããã€ã³ããŒã¯ãŒã©ãã³
ã§ããããšã奜ãŸãããããŒã©ãã³ãŸãã¯ãã®äž
éšã®ä»£ãã«ä»ã®å€©ç¶ãŸãã¯åæãã€ã³ããŒã䜿çš
ããããšãã§ãããé©åœãªå€©ç¶ãã€ã³ããŒã®äŸã«
ã¯ã¢ã«ã®ã³é žããã³ãã®èªå°äœïŒããšãã°å¡©ããš
ã¹ãã«ãã¢ããïŒïŒã»ã«ããŒãºèªå°äœããšãã°ã«
ã«ããã·ã¡ãã«ã»ã«ããŒãºãã¢ã«ãã«ã»ã«ããŒãº
ïŒããšãã°ããããã·ãšãã«ã»ã«ããŒãºïŒïŒæŸ±ç²
ãŸãã¯ãã®èªå°äœïŒããšãã°ãšãŒãã«ããšã¹ã
ã«ïŒïŒã«ã©ã²ããŒããé©åœãªåæãã€ã³ããŒã®äŸ
ã«ã¯æ¬¡ã®ãã®ããããããïŒããªããã«ã¢ã«ã³ãŒ
ã«ãéšåçã«é¹žåãããããªããã«ã¢ã»ããŒãã
ããªããã«ãããªãã³ããã³ãã®é¡äŒŒç©ã ãã®åçå±€ã¯åžžæ³ã«åŸã€ãŠç¡¬èåïŒç¡¬åïŒã§
ããããããŠã䜿çšã§ãã硬èå€ã®äŸã«ã¯æ¬¡ã®ã
ã®ããããããïŒãã«ã ã¢ã«ãããïŒã«ã«ããã·
åºãæããããã²ã³çœ®æã¢ã«ãããããšãã°ã ã³
ããã é žïŒãžã±ãã³ïŒã¡ã¿ã³ã¹ã«ãã³é žã¹ã«ãã³
é žãšã¹ãã«ïŒãžã¢ã«ãããã æ¬çºæã«åŸã€ãæææ¡æ£è»¢åæ³ã®å®æœæ¹æ³ã«ã€
ããŠè©³çŽ°ã«èª¬æãããïŒãŸãã¯ãã以äžã®ããã²
ã³åéä¹³å€å±€ãšãããã«ä»éããéæ¡æ£æ§ææäŸ
äžååç©ãšãæããæå æ§èŠçŽ ã䜿çšããããã
ã«ãç»ååå ¥èŠçŽ ãã䜿çšããããã®ç»ååå ¥èŠ
çŽ ã§ã¯ãç»åã®åœ¢ã®éãã«ããã«ç§»ãããæ¡æ£æ§
ææã«ãããææã®ã«ã©ãŒç»åãçæã§ãããã
ã«ãªã€ãŠãããçŸåæäœå®æœæã«ãããŠããã®å®
æœæéã®ãã¡ã®å°ãªããšãæäžå®ã®æéã®éã¯å
èšæå æ§èŠçŽ ãšåèšç»ååå ¥èŠçŽ ãšãå¯çãããª
ããã°ãªããªãããããã«ãã€ãŠãçŸåã«ããç
ããæ¡æ£æ§ææãç»åã®åœ¢ã®éãã«ååžããç¶æ
ã§åèšç»ååå ¥èŠçŽ ã®æ¹ã«ç§»ãããšãã§ããã®ã§
ããããã®å¯çã¯ãçŸåæäœéå§åŸã«è¡ãããšã
ã§ãããŸãã¯çŸåæäœéå§åã«ããè¡ãããšãã§
ããããã®ç¬¬ïŒçªç®ã®æäœã¯ãããšãã°ããã®æ
ææ¡æ£è»¢åæ³ã«äœ¿çšãããåçææããæå æ§èŠ
çŽ ãšç»ååå ¥èŠçŽ ãšãäžç·ã«ãªã€ãŠåäœãŠããã
ã®åœ¢ã«ãªã€ãŠãããããªåçææã§ããå Žåçã«
è¡ããããã®ã§ããããã®åäœãŠãããã¯ã以äž
ã§ã¯ãã¢ãã·ãŒãææããšç§°ããããšã«ãããã
ã®ã¢ãã·ãŒãææã¯çŸåå®æœåŸã«ãããŠããåäœ
ãŠããããšããŠæ®ããããªãã¡ãææ転åå·¥çšçµ
äºåŸã«ãããŠããæå æ§èŠçŽ ãšç»ååå ¥èŠçŽ ãšã®
çžäºåé¢ã¯è¡ãããªãã®ã§ããããã®ãããªæäœ
ã®å®æœæ¹æ³ã¯ãããšãã°ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬
2019430å·çã«èšèŒãããŠããã æ¬çºæã«ä¿ãæææ¡æ£è»¢åæ³ãå®æœããã®ã«é©
ããã¢ãã·ãŒãææã®äŸã«ã¯ãäžèšã®åçå±€ãæ
ãããã®ããããããã (1) éæãªæ¯æå±€ (2) ç»ååå ¥å±€ (3) é®å å±€ (4) å°ãªããšãïŒã€ã®æå æ§ããã²ã³åéä¹³å€å±€
ãšããã«ä»éããå°ãªããšãïŒã€ã®èæ¡æ£æ§æ
æäŸäžååç©ãšãæããæå æ§èŠçŽ (5) ã¬ã¿ãŒãžã³ã°å±€ (6) é žæ§éåäœå±€ (7) éææ¯æå±€ ãã®ã¢ãã·ãŒãææã¯æ¬¡ã®åŠã圢æã§ãããçž
ç°ãªãïŒã€ã®éšæãããªãã¡æå æ§éšæïŒå±€ç¶èŠ
çŽ ïŒâïŒïŒãšã«ããŒã·ãŒãïŒå±€ç¶èŠçŽ ïŒâïŒïŒãš
ã®ïŒã€ã®éšæãå¥ã ã«äœãã次ãã§ãã®ïŒã€ã®éš
æããã®æŽ»æ§é¢ãäºãã«åããåãããã«ããŠäž
ç·ã«ããçžäºã«æ¥çãããããææãªãã°ãæå®
éïŒæ£ç¢ºã«æž¬å®ãããéïŒã®åŠç液ãæ£ç¢ºã«åèš
ã®ïŒã€ã®éšæã®éã®ç©ºéã«äŸçµŠããããã«ããã®
ïŒã€ã®éšæã®éã«ã¹ããŒãµãŒã¹ããªãããä»åšã
ããããšãå¯èœã§ãããå±€ç¶èŠçŽ ïŒããã³ïŒã¯äž
åç³»ãæ§æãããã®ã§ãããããã®å±€ç¶èŠçŽ ïŒã
ãã³ïŒã®ä»£ãã«ããããã¯ãããã®èŠçŽ ã«å ã
ãŠããããšåæ§ãªèŠçŽ ãæ¯æå±€ãšæå æ§éšæäžã®
ç»ååå ¥å±€ãšã®éã«é 眮ããããšãå¯èœã§ããã
ãã ããã®å Žåã«ã¯ããã®ïŒã€ã®å±€ç¶èŠçŽ ã®é å
é åºãéã«ããªããã°ãªããªãã åèšã®æå æ§éšæãšã«ããŒã·ãŒããšã®éã®å°ç¹
ã«åŠç液ãäŸçµŠããããã«é©åœãªäŸçµŠæ段ãèšã
ãããšãã§ãããã®äŸçµŠæ段ã¯ãããšãã°ãè£ã
ããšã«ãããå£ããããã§ãã容åšã®åœ¢ã®ãã®ã§
ãã€ãŠããããã®å®¹åšã¯åèšã¢ãã·ãŒãææã®åŽ
éšã«é 眮ã§ãããããŠãããã«æ©æ¢°åãå ãããš
ãã«ããã®å®¹åšããå 容ç©ïŒåŠç液ïŒãåºãŠãã
ã®ã¢ãã·ãŒãææäžã§äºãã«é£æ¥ããïŒã€ã®å±€ã®
éã®æå®ã®å°ç¹ã«è©²å 容ç©ãäŸçµŠã§ããããã«ãª
ã€ãŠãããã®ã§ããåŸãã æ¬çºæã«ä¿ãåçææã®å¿ é èŠä»¶ã®ïŒã€ã¯ãæ
å æ§ããã²ã³åéä¹³å€å±€ãšãããã«ä»éããèæ¡
æ£æ§ææäŸäžååç©ãšãæããæå æ§èŠçŽ ãé 眮
ããããšã§ããïŒã¢ãã¯ã転åæ³ã®å ŽåïŒããã®
èæ¡æ£æ§ææäŸäžååç©ã¯åèšæå æ§ããã²ã³å
éä¹³å€å±€ã®é£ãã®å±€ã«ååšãããŠããããããã
ã¯è©²ããã²ã³åéä¹³å€å±€èªäœã®äžã«ååšãããŠã
ãããåŸè ã®å Žåã«ã¯ããã®ææäŸäžååç©ã®äž»
åžå éšã®æ³¢é·ãããã²ã³åéä¹³å€å±€ã®äž»æå æ³¢é·
ã«äžèŽããªãããã«ããããã«ãç»åææïŒã€ã¡
ãŒãžãã€ïŒã®è²ãé©åœã«éžã¶ã®ã奜ãŸããã ããããªããããªãªãžãã«ã®è²ãšæ¬åœã«åãè²
ã®å€è²è»¢åç»åãäœæããå Žåã«ã¯ãææäŸäžå
åç©ãšããã«ä»éããæå æ§ããã²ã³åéä¹³å€å±€
ãšã®çµåãããïŒçµæããæå æ§èŠçŽ ã䜿çšãã
ãããŠäžè¬ã«è©²ææäŸäžååç©ã®åžå éšã®æ³¢é·ç¯
å²ãã該ååç©ã«äŒŽãããã²ã³åéä¹³å€å±€ã®ã¹ã
ã¯ãã«æ床ã®æ³¢é·ç¯å²ã«å®è³ªçã«äžèŽããããã«
ããªããã°ãªããªããæ床ãã§ããã ãé«ããã
ããã«å¿ èŠãªåææ¡ä»¶ã¯ããã®çºè²ææã®çµåã
ãã¯ãåèšããã²ã³åéä¹³å€ã®åŸæ¹ã®ïŒé²å æã®
å ¥å°å ç·ã®æ¹ååºæºïŒå¥åã®ãã€ã³ããŒå±€ã®äžã«
é 眮ãã¹ãã§ãããšããããšã§ããã å¿è«ãããã²ã³åéä¹³å€ã®çŸåæã«çããçŸå
è¬ã®é žåçæç©ã¯ãä»éããææäŸäžååç©ã®ã¿
ã«äœçšãããã®ã§ããã¹ãã§ããããããã€ãŠã
çŸåè¬ã®é žåçæç©ããä»éé¢ä¿ã®ãªãåçå±€ã®
æ¹ã«æ¡æ£ããã®ãé²ãããã«ãæå æ§èŠçŽ ã®äžã«
é¢éå±€ïŒæ¡æ£é²æ¢å±€ïŒãèšããã®ãäžè¬ã«æå©ã§
ããã ãã®é¢éå±€ã¯ãããšãã°ãçŸåè¬ã®é žåçæç©
ãšé©åã«åå¿ãåŸãç©è³ªãå«æãåŸãã該ç©è³ªã®
äŸã«ã¯èæ¡æ£æ§ãã€ããããã³èªå°äœããããã
ãããŸãã䜿çšãããçŸåè¬ãçºè²çŸåè¬ã§ãã
å Žåã«ã¯ãåèšç©è³ªãšããŠèæ¡æ£æ§ã«ã©ãŒã«ãã
ã©ãŒã䜿çšã§ããããããã€ãŠæ¬çºæã®å¥œãŸãã
å ·äœäŸã§ã¯ã次ã®çŽ¯å±€æ§é ãæããæå æ§èŠçŽ ã
䜿çšãããã®ã§ããïŒåå±€ãäžããäžã«åãã€ãŠ
é çªã«ç€ºãïŒã éææ§ããã²ã³åéä¹³å€å±€ æ¡æ£æ§é»è²ææãæŸåºãåŸãèæ¡æ£æ§ååç©ã
å«ãå±€ é¢éå±€ ç·è²å¢æããã²ã³åéä¹³å€å±€ æ¡æ£æ§ããŒã³ã¿ææãæŸåºãåŸãèæ¡æ£æ§åå
ç©ãå«ãå±€ é¢éå±€ èµ€è²å¢æããã²ã³åéä¹³å€å±€ æ¡æ£æ§ã·ã¢ã³ææãæŸåºãåŸãèæ¡æ£æ§ååç©
ãå«ãå±€ ãããã®ããã²ã³åéä¹³å€å±€ã®é åé åºãå€ã
ãããšãå¿è«å¯èœã§ãããããã®å Žåã«ã¯ãçºè²
ç³»ãæããä»éå±€ã®é åé åºãå€ããåèšã®ä»é
é¢ä¿ã確å®ã«ä¿ã€ããã«ããªããã°ãªããªãã æå æ§èŠçŽ ã®äžåŽã«é 眮ãããé®å å±€ã¯ãæ°Žæ§
ã¢ã«ã«ãªåŠç液ãééã§ãããããã€ãŠæ¡æ£æ§æ
æããééã§ãããã®ã§ãããããã¯ïŒã€ã®åœ¹å²
ãæãã第ïŒã®åœ¹å²ã¯ããã®åçææããçŸååŸ
ã«æå æ§éšæã®äžã®éæãªæ¯æå±€ãéããŠèŠããš
ãã«ãããžã«ã©ãŒè»¢ååã®ã¿ãèŠããããã«ãçŸ
ååŸã«ãå ã®ãªãªãžãã«æå æ§èŠçŽ ã®äžã«æ®ã€ãŠ
ããç»åéïŒã€ã¡ãŒãžã·ã«ããŒïŒãããã³ãã¬ã«
ã©ãŒãšããŠæ®ã€ãŠããææäŸäžååç©ããé èœã
ãããšã§ããã第ïŒã®åœ¹å²ã¯ç»ååå ¥å±€ã®åŽéš
ïŒåºéšïŒããå ç·ãæå æ§èŠçŽ ã«å ¥ãããšãé²ã
ããšã§ããããã®ã¢ãã·ãŒãææãé²å åŸã«ãã
ããããããªãã«ã¡ã©äžã«ååšãããšãã«ãã¢ã«
ã«ãªæ§ã®åŠççšå€ãšæ¥è§Šããã次ãã§ã«ã¡ã©ãã
åŒåºããŠã«ã¡ã©ã®å€åŽã§çŸåããæäœãè¡ãå Žå
ã«ã¯ãäžèšã®é®å æ段ãç¹ã«éèŠãšãªãã å åãªé®å æ§ãæãããæ¡æ£æ§ææã¯ééãã
ããããªåçå±€ã¯ãããšãã°ãç¡æ©ãŸãã¯ææ©æ
è²é¡æ奜ãŸããã¯é»è²é¡æã®æžæ¿æ¶²ïŒããšãã°ã«
ãŒãã³ãã©ãã¯ããŒã©ãã³æ¶²çã®é©åœãªãã€ã³ã
ãŒäžã«å ¥ããŠäœã€ãæžæ¿æ¶²ïŒãçšããŠè£œé ã§ã
ããçŸåæäœå®æœäžã¯å åãªé®å æ§ãä¿ã€ãã
ã«ãã«ãŒãã³ãã©ãã¯ã10â90ééïŒ ïŒä¹Ÿç¥æé
éåºæºïŒå«ãåã0.5ãïŒÎŒã®å±€ãèšããã®ãäž
è¬ã«å¥œãŸããããã®é¡æã®ç²ååŸã¯æŠããŠéèšç
çã§ãããã0.5ÎŒãå®è³ªçã«è¶ããªãå€ã§ãã
ããšã奜ãŸããã åèšé®å å±€ã«ã¯ãé»è²é¡æå±€ã«å ããŠãçœè²é¡
æå±€ãã該é»è²é¡æå±€ã®ããäžåŽã«é 眮ããã®ã
奜ãŸããããã®çœè²é¡æå±€ã®ç®çã¯ãé»è²å±€ãèŠ
ãé ãããšãããã³ç»åã®ããã®çœè²ããã¯ã°ã©
ãŠã³ããæäŸããããšã§ããããã®ç®çã®ããã«
ä»»æã®çœè²é¡æã䜿çšã§ããããã ããã®çœè²é¡
æã¯ãé床ã«åããªãåãã«ãããŠãå åãªé èœ
åããã€ãã®ã§ãªããã°ãªããªããé©åœãªçœè²é¡
æã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒç¡«é žããªãŠ
ã ãé žåäºéãé žåãã¿ã³ãé žåçªçŽ ãé žåã¢ã«
ãããŠã ãé žåãžã«ã³ããŠã ãã¹ãã¢ãªã³é žããª
ãŠã ãã«ãªãªã³ãçœè²é¡æå±€äœææã®æ¡ä»¶ïŒãã€
ã³ããŒãæ¿åºŠãç²ååŸïŒã¯ãåèšé»è²é¡æå±€äœæ
æã®å Žåãšå®è³ªçã«åãã§ãããçœè²é¡æå±€ã®å
ã¿ã¯ãç»åã®ããã¯ã°ã©ãŠã³ããšããŠææããã
çœè²åºŠã®å€ã«å¿ããŠçš®ã å€ããããšãã§ãããã
ã®å±€åã¯ïŒâ20ÎŒã«ããã®ãäžè¬ã«å¥œãŸããã æ¬çºæã«ä¿ãã¢ãã·ãŒãææã®äžã«é®å å±€ãé
眮ãã代ãã«ãæå æ§èŠçŽ ãšç»ååå ¥å±€ãšã®éã«
é®å 局圢æçšæ段ãèšããããšãå¯èœã§ãããã
ãšãã°ãäžéæåå€ïŒé¡æïŒãå«ã容åšã®åœ¢ã®å
èšæ段ãã¢ãã·ãŒãææã®åŽéšã«é 眮ããããšã
ã§ããããã®å Žåã«ã¯ã該容åšã«æ©æ¢°åãå ãã
ãšãã«å®¹åšããå 容ç©ãæŸåºãããåèšã®ïŒã€ã®
å±€ã®éã«å ¥ããæ¢è¿°ã®çš®é¡ã®é¡æå±€ã圢æã§ãã
ã®ã§ããã ç»ååå ¥å±€ã¯ãæ¡æ£æ§ææãå®çãããããã®
ææçšåªæå€ïŒã¢ã«ãã³ãïŒå«æãã€ã³ããŒãã
å®è³ªçã«ãªããã®ã§ããã é žæ§ææçšåªæå€ã¯ãé·é第ïŒã¢ã³ã¢ããŠã â
ãŸãã¯âãã¹ãããŠã ååç©ããããã¯ç¬¬ïŒã¹ã«
ãããŠã ååç©ã§ããããšã奜ãŸããããã®å ·äœ
äŸã¯ãç±³åœç¹èš±ç¬¬3271147å·ããã³ç¬¬3271148å·æ
现æžçã«èšèŒãããŠããããŸããé žæ§ææãšã®å
å¿ã«ããé£æº¶æ§ååç©ã圢æãåŸãæçš®ã®éå±å¡©
ããã³ãã®ããããã·ãååç©ã䜿çšã§ãããã
ã®ææåªæå€ã¯ãåèšç»ååå ¥å±€ã®äžã®åžžçšèŠªæ°Ž
æ§ãã€ã³ããŒã®ãã¡ã®ããããïŒããšãã°ãŒã©ã
ã³ãããªããã«ãããªãã³ããããã¯å®å šã«ãŸã
ã¯éšåçã«å æ°Žå解ãããã»ã«ããŒãºãšã¹ãã«ïŒ
ã®äžã«åæ£ãããŠäœ¿çšã§ãããæçš®ã®ãã€ã³ããŒ
ã¯åªæå€ãšããŠã®æ©èœããæãåŸããã®ã§ãã€
ãŠããã®ãããªãã€ã³ããŒã®äŸã«ã¯æ¬¡ã®ãã®ãã
ããããïŒããã«ã¢ã«ã³ãŒã«ããã³ïŒ®âããã«â
ãããªãã³ãšã®å ±éåäœãŸãã¯éåäœæ··åç©ïŒã
ãšãã°ãç¬åœç¹èš±å ¬åå ¬å ±ç¬¬1130284å·çã«èšèŒ
ã®ãã®ïŒïŒå¡©åºæ§ç¬¬ïŒçŽçªçŽ ååç©ã®éåäœãã
ãšãã°ïŒ®âã¡ãã«âïŒâããã«ããªãžã³ã®éåäœ
ïŒç±³åœç¹èš±ç¬¬484430å·æ现æžçïŒããªãäžèšä»¥å€ã®
é©åœãªåªæäœçšä¿æãã€ã³ããŒã®äŸã«ã¯ã¢ã·ã«ã¹
ãã¬ã³éåäœã®ã°ã¢ãã«ããã©ãŸã³èªå°äœïŒç¬åœ
ç¹èš±å ¬éå ¬å ±ç¬¬2009498å·çïŒãããããããã
ãããªãããæåŸã«è¿°ã¹ãåªæäœçšä¿æãã€ã³ã
ãŒã«ã¯ãäžè¬ã«ä»ã®ãã€ã³ããŒïŒããšãã°ãŒã©ã
ã³ïŒãæ·»å ãããã§ãããã æ¬çºæã«ä¿ãåèšã¢ãã·ãŒãææã«äœ¿çšããã
éæãªæ¯æå±€ã¯ãåçåéã«ãããŠæ £çšãããŠã
ãéæãªæ¯æå±€ã§ãã€ãŠãããããšãã°ã»ã«ããŒ
ãºãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããª
ã«ãŒãããŒããŸãã¯ä»ã®ãã€ã«ã 圢ææ§éåäœã
ããªãèå±€ç©ïŒãã€ã«ã ïŒã§ãã€ãŠãããåèšã®
ã¢ã«ã«ãªæ§åŠçå€ïŒprocessing massïŒã«ããã
ã®æå ææã®PHãæ¯èŒçé«ãå€ïŒçŽ11â14ïŒã«ãª
ããçŸåãè¡ããããã€ç»åã®åœ¢ã®éãã®æææ¡
æ£ãè¡ãããããã®ãããªé«PHå€ã®ãšãã«ã¯ææ
ããã³ç»åãããŸãå®å®ã§ã¯ãªãããšãèŠåºãã
ãããããã€ãŠãçŸåå®äºåŸã«ã¯æå ææã®PHå€
ãäžæ§ãŸãã¯åŒ±é žæ§åŽã®å€ã«èª¿ç¯ããªããã°ãªã
ãªãããã®èª¿ç¯ã®ããã«ãåžžæ³ã«åŸã€ãŠãçŸåæ
äœå®æœäžã«ã¯åèšã¢ã«ã«ãªæ§åŠçå€ã«ã¯åŸã ã«ã
ãæ¥è¿ããªãé žæ§éåäœå±€ããã®æå ææå ã«èš
ããããšãã§ãããããã«äœ¿çšãããçšèªãé žæ§
éåäœå±€ãã¯ãé žåºïŒå¥œãŸããã¯ã¹ã«ãåºãã«ã«
ããã·ã«åºïŒãæããéåäœååç©ãå«æããã
ã€ã³ããŒå±€ãæå³ããããã®é žåºã¯ã¢ã«ã«ãªæ§åŠ
çå€äžã®ã«ããªã³ãšåå¿ãã該åŠçå€ã®PHãäœäž
ããããå¿è«ãã®éåäœååç©ïŒããã³ãã®äžã®
é žåºïŒã¯èæ¡æ£æ§ç©è³ªã®åœ¢ã§äžèšå±€ã«æ·»å ãã
ãããã®é žæ§éåäœã¯ãå€ãã®å Žåã«ãããŠã»ã«
ããŒãºãŸãã¯ããªããã«ååç©ã®èªå°äœã§ãã
ããä»ã®éåäœååç©ã䜿çšã§ãããé©åœãªé žæ§
éåäœã®äŸã«ã¯æ¬¡ã®ãã®ããããããïŒéé¢ã«ã«
ããã·ã«åºãæããã»ã«ããŒãºèªå°äœãããšãã°
éé¢ã«ã«ããã·ã«åºãæããã»ã«ããŒãºãžã«ã«ã
ã³é žã»ããšã¹ãã«ïŒããšãã°ã»ã«ããŒãºã¢ã»ããŒ
ãæ°ŽçŽ ãã¿ã¬ãŒããã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ã°
ã«ã¿ã¬ãŒãããšãã«ã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ãµ
ã¯ã·ããŒããã»ã«ããŒãºã¢ã»ããŒãæ°ŽçŽ ãµã¯ã·ã
ãŒãæ°ŽçŽ ãã¿ã¬ãŒãïŒïŒãžã«ã«ãã³é žç¡æ°Žç©ãŸã
ã¯ã¹ã«ãã³é žç¡æ°Žç©ïŒããšãã°ãïœâã¹ã«ãå®æ¯
éŠé žç¡æ°Žç©ïŒã§å€æ§ãããã»ã«ããŒã¹ãšãŒãã«ã
ãã³ã»ã«ããŒãºãšã¹ãã«ïŒã«ã«ããã·ã¡ãã«ã»ã«
ããŒãºïŒããªã¹ãã¬ã³ã¹ã«ãã³é žïŒããªããã«æ°Ž
çŽ ãã¿ã¬ãŒãïŒããªããã«ã¢ã»ããŒãæ°ŽçŽ ãã¿ã¬
ãŒãïŒããªã¢ã¯ãªã«é žïŒã«ã«ããã·ã«åºãŸãã¯ã¹
ã«ãåºã§çœ®æãããã¢ã«ãããïŒããšãã°ïœâã
ïœâãŸãã¯ïœâãã³ãºã¢ã«ãããã¹ã«ãã³é žãŸã
ã¯âã«ã«ãã³é žïŒãšããªããã«ã¢ã«ã³ãŒã«ãšãã
å°ãããã¢ã»ã¿ãŒã«ïŒéšåçã«ãšã¹ãã«åããã
ãšãã¬ã³ïŒãã¬ã€ã³é žç¡æ°Žç©å ±éåäœïŒéšåçã«
ãšã¹ãã«åãããã¡ãã«ããã«ãšãŒãã«ïŒãã¬ã€
ã³é žç¡æ°Žç©å ±éåäœã ãã®é žæ§éåäœå±€ã¯ãã¢ã«ã«ãªæ§åŠçå€ã®PHå€
ã11â14ïŒããšã®å€ïŒãã倧äœäžæ§å€ãŸãã¯åŸ®é ž
æ§åŽã®å€ïŒPHïŒâïŒïŒã«æçµçã«äœäžãããã®ã«
å åãªéã®é žåºãå«ããã®ã§ãªããã°ãªããªãã
PHå€äœäžã®ãšãã®æéé 延ïŒã¿ã€ã ãã¬ã€ïŒå¹æ
ã確ä¿ããããã«ããã®é žæ§éåäœå±€ããããã
ã¬ã¿ãŒãžã³ã°å±€ã§è¢«èŠããããšãã§ããããã®ã¬
ã¿ãŒãžã³ã°å±€ã¯ã¢ã«ã«ãªäžééå±€ã®ïŒçš®ã§ãã€
ãŠããã®å±€ã¯ãã¢ã«ã«ãªã«å¯ŸããŠäžæŽ»å šãªéåäœ
ïŒããšãã°ããªããã«ã¢ã«ã³ãŒã«ããŸãã¯éšåç
ã«ã¢ã»ã¿ãŒã«åãããããªããã«ã¢ã«ã³ãŒã«ïŒã
ããªããã®ã§ããããšã奜ãŸãããPHå€äœäžã®ãš
ãã®æéé 延ã®åºŠåã¯ããã®ã¬ã¿ãŒãžã³ã°å±€ã®å
ã¿ããã³çµæãé©åœã«éžã¶ããšã«ããå ·åãã調
ç¯ã§ãããæ°ããåã®ééç¹æ§ãæããéåäœã
å«ãããªã€ãŒå±€ããããšãã°æ¬¡ã®æç®ã«èšèŒãã
ãŠããïŒç±³åœç¹èš±åºé¡ç¬¬633801å·æ现æžïŒåºé¡æ¥
1975幎10æ20æ¥ïŒãè±åœç¹èš±åºé¡ç¬¬44909175å·æ
现æžãç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2455762å·ã ãã®ãããªé žæ§éåäœå±€ãšã¬ã¿ãŒãžã³ã°å±€ãšã®
çµåãããäžåç³»ããšç§°ããããããã¯ããšãã°
ç¬åœç¹èš±ç¬¬1285310å·æ现æžçã«èšèŒãããŠã
ããæ¬çºæã«ä¿ãåçææã¯ãã®ãããªå±€ã®çµå
ããå«ãããšãã§ãããããŠããã¯ãããšãã°æ
å æ§éšæã®äžã®éæãªæ¯æå±€ãšç»ååå ¥å±€ãšã®é
ã«é 眮ã§ããã åèšã®PHå€äœäžãé 延ãããããã®ããïŒã€ã®
æ¹æ³ã¯ãé žæ§éåäœãšã¬ã¿ãŒãžã³ã°å±€ãšãããªã
äžåç³»ãåèšã«ããŒã·ãŒãäžã«èšããããšã§ã
ããå¿è«ãã®ïŒã€ã®å±€ã¯ãã¢ã«ã«ãªæ§åŠçå€äžã®
ã¢ã«ã«ãªãé žæ§éåäœã«å°éããåã«ã¬ã¿ãŒãžã³
ã°å±€ãå ãééããªããã°ãªããªããšããæ¡ä»¶ã
ã¿ããããã«é åããªããã°ãªããªãã æ¬çºæã«ä¿ãæææ¡æ£è»¢åæ³ã¯é©åœãªèªå·±çŸå
åã«ã¡ã©ã®äžã§ããŸã該ã«ã¡ã©ãçšããŠæå©ã«å®
æœã§ãããã®ã§ããããã®ã«ã¡ã©ã«ã¯ãæå æ§èŠ
çŽ ã®é²å æäœå®æœåŸã«é®å çšåŠç液ãæå æ§èŠçŽ
ãšã«ããŒã·ãŒããšã®éã®å°ç¹ã«äŸçµŠããŠãæå æ§
èŠçŽ ãé®å ããïŒé éšããã®å ç·ãå ¥ããªããã
ã«ããïŒè£ 眮ãèšçœ®ã§ããããã®ãããªã«ã¡ã©ã«
ã¯ïŒå¯Ÿã®ã¹ã¯ã€ãºããŒã©ãŒãèšãããã®ããŒã©ãŒ
ãä»ããŠåèšã¢ãã·ãŒãææãåŒåºãããããã«
ãããããŠããã®ã¢ãã·ãŒãææã®åŽéšã«å®¹åšã
èšãããã®å®¹åšãç ŽããŠå£ãéããå 容ç©ããã®
ã¢ãã·ãŒãäžã®æå®ã®å±€éå°ç¹ã«äŸçµŠããããã
ã«ããã®ã奜ãŸããã æå æ§èŠçŽ ã¯ãã¹ã¯ã€ãºããŒã©ãŒééåŸã«ã¯ã
ãã®äž¡åŽã¯é®å å±€ã«ããä¿è·ãããäžææã®é²å
ãè¡ãããªãããã«ãªã€ãŠããããããã®æå æ§
èŠçŽ ã¯çŸåæäœéå§çŽåŸã«ã«ã¡ã©ããåŒåºãããš
ãã§ããã åèšã¢ãã·ãŒãææã®ç»å圢æé²å ãè¡ã€ãåŸ
ã«è©²ææã«çŸååŠçãè¡ãããã«ãæå æ§èŠçŽ ã
ã¢ã«ã«ãªæ§åŠç液ïŒæ°Žæº¶æ¶²ïŒãšæ¥è§Šãããããã
ã«ãã€ãŠãç»å圢æé²å å®æœåŸã®ããã²ã³åéä¹³
å€å±€ãçŸåè¬ååç©ã®ååšäžã«çŸåãããããã®
çŸåã«ããçããããžã®éç»åã®åœ¢ã«äžèŽãã圢
ã§ãçŸåè¬ååç©ã®é žåçæç©ããç»åã®åœ¢ã«å
åžããç¶æ ã§çããããã®é žåçæç©ãåèšã®ä»
éææäŸäžååç©ãé žåãããããŠè©²ææäŸäžå
åç©ã®é žåçæç©ã掻æ§åå€ã®ã¢ã«ã«ãªãšåå¿ã
ãŠãæ¡æ£æ§ææãæŸåºããã®ã§ããã ãã®æ°Žæ§ã¢ã«ã«ãªåŠç液ã¯ããããã·ãšãã«ã»
ã«ããŒãºçã®ç²åºŠäžæå€ãå«æãåŸãããŸã該åŠ
ç液ã¯ãå ¬ç¥ã®çŸåä¿é²å€ãå®å®å€ãé塩溶åªã
ãã¶ãçæå€ïŒãã¶ãå€ïŒãé žåé²æ¢å€ããã³ä»
ã®æ·»å å€ããå«æãåŸãã äŸ ïŒ æ¬çºæã«ä¿ãåçææã®æå æ§èŠçŽ ããæ¯æå±€
ã§ããéæãªããªãšã¹ãã«ãã€ã«ã®äžã«äžèšã®å±€
ãé 次çæãããããšã«ãã補é ããããªããäž
èšã®è¬å€ã®äœ¿çšéã¯ãïŒm2åœãã®äœ¿çšéã§ããã (1) ãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒã400ïœãš
âã¢ã«ãã«âãžãšã¿ããŒã«ã¢ãã³150ïœãšãš
ãã¯ãããããªã³90ïœãšã®å ±éåäœïŒç¬åœç¹èš±
å ¬éå ¬å ±ç¬¬2631521å·ã®å®æœäŸïŒåç §ïŒ5.71ïœ
ãšããŒã©ãã³5.8ïœãšãå«ãåªæå€å«æå±€ (2) äºé žåãã¿ã³27ïœãšãŒã©ãã³2.7ïœãšãå«ã
åå°å±€ (3) ã«ãŒãã³ãã©ãã¯1.85ïœãšãŒã©ãã³ïŒïœãšã
å«ãã«ãŒãã³ãã©ãã¯å±€ (4) ååç©ïŒïŒ0.45ïœïŒãšãŒã©ãã³0.75ïœãšãã
ãªãææå±€ (5) ïŒâïŒ3â²âã«ã«ããã·âããšãã«ïŒâïŒâã¡ã«
ã«ããâããã©ãŸãŒã«ïŒmgãšããªã¯ã¿ãã·ã«â
ãã€ããããã³ã¹ã«ãã³é ž66mgãšãã¢ã»ãã«ã
ãšãã«ããã©ãžã³ïŒmgãšããŒã©ãã³1.3ïœãšã
å«ãç¡ãã¶ãåçŽæ¥ããžçšãšãŒãã¯ããèåé
ä¹³å€ïŒé䜿çšé2.63ïœïŒãå«ãå¢æä¹³å€å±€ (6) ãŒã©ãã³2.6ïœãããªãä¿è·å±€ ã¹ããªããã®åœ¢ã®äžèšæå æ§èŠçŽ ããé段ãã
ã³ãä»ããŠé²å ããããã®æå æ§èŠçŽ ã®äž¡åŽç«¯ã«
åã¿180ÎŒã®ã¹ããŒãµã¹ããªãããïŒã€åä»ãã
ãã€ããŒã¹ãç¶çŸåè¬ãå«ãè¢ïŒè£ãããšãã§ã
ããã®ïŒããã®äžç«¯ã«åä»ããåŸã«ããã®æå æ§
èŠçŽ ãããªãšã¹ãã«ã§èŠã€ããããããŠåŸããã
çµç«äœããïŒå¯Ÿã®ã¹ã¯ã€ãºããŒã©ãŒã®éã®ããã
ãééãããããã«ãã€ãŠããŒã¹ãç¶çŸåè¬ãæ
å æ§èŠçŽ ãšã«ããŒã·ãŒããšã®éã«å°ç¹ã«äŸçµŠã
ããããã§äœ¿çšãããçŸåè¬ã¯æ¬¡ã®çµæãæãã
ãã®ã§ãã€ãã æ°Žé žåã«ãªãŠã 20 ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10 ml ãã©ãã«ã ã¢ã«ããã ïŒ ïœ ãã³ãããªã¢ãŸãŒã« ïŒ ïœ ã¢ã¹ã³ã«ãã³é ž 0.25ïœ ïŒâããããã·ã¡ãã«âïŒâã¡ãã«âããšããã³
1.3 ïœ ãã€ããããã³ 0.1 ïœ ããããã·ãšãã«ã»ã«ããŒãº 30 ïœ æ°Ž æ® éš å š é 1000 ml çŸåã10åéè¡ã€ãåŸã«ç»åä¿æèŠçŽ ãåé¢
ãããããŠãããã«ãªãä»ããŠããããŒã¹ããé€
å»ãããéæãªåºäœãéããŠããžã®ããŒã³ã¿å¯èŠ
åãçãããåèšäºé žåãã¿ã³å±€ã¯ç»åã®ããã¯
ã°ã©ãŠã³ããšããŠåœ¹ç«ã€ãã®ã§ãã€ãã äŸ ïŒ äŸïŒã®å Žåãšåæ§ãªæäœãè¡ã€ãããæ€åºŠã¯ã
å±€ïŒäžã®ååç©ïŒã®ä»£ãã«ååç©ïŒâïŒãïŒãïŒ
ããã³æ¯èŒå¯Ÿç §çšååç©âãçšãããäŸïŒã®
å Žåãšåæ§ãªåŠçãè¡ã€ãåŸã«ãããžã®ããŒã³
ã¿ãé»è²ãŸãã¯ã·ã¢ã³ææ転ååãããããåŸã
ããããã®å®éšããã³ååç©ïŒãçšããæ¢è¿°ã®å®
éšã®çµæãåŸèšã®è¡šã«ç€ºããããã®çµæããæã
ããªããã«ãæ¬çºæã«ä¿ãååç©ã®äœ¿çšã«ããã
ã¶ãå€Dminãå®è³ªçã«æ¹åã§ããã®ã§ããã ã¢ã©ãã¢æ°åã§ç€ºããææååç©ã¯æ¬çºæã«ä¿
ãååç©ã§ãããããŒãæ°åã§ç€ºããææååç©
ã¯å¯Ÿç §ååç©ã§ãã€ãŠããã®ååŠåŒã¯è¡šã®åŸã«èš
èŒãããŠãããå¯Ÿç §ææãããããã³
ã¯ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2505248å·èšèŒã®æ¹æ³ã«ã
ãåŸããããã®ã§ãããå¯Ÿç §ææãããã³
ã¯ç¬åœç¹èš±å ¬éå ¬å ±ç¬¬2242762å·èšèŒã®æ¹æ³ã«ã
ãåŸããããã®ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æææ¡æ£è»¢åæ¹æ³ã®ããã®åçææã«ãã
ãŠãå°ãªããšãïŒã€ã®æå æ§ããã²ã³åéä¹³å€å±€
ãšãããã«ä»éãã次åŒã®èæ¡æ£æ§ææäŸäžåå
ç© ãããã«ïŒžã¯ãåèšSO2åºã«çŽæ¥ã«ä»ããŠããã
ãŸãã¯ä»åšåºïŒºãä»ããŠä»ããŠããææãŸãã¯æ
æåé§äœã®æ®åºãè¡šããã ã¯åèšæ®åºïŒžã«çŽç·ä»ããŠããããŸãã¯â
âãââãâSO2âãâNRâïŒããã«ïŒ²ïŒæ°ŽçŽ ãŸ
ãã¯ã¢ã«ãã«åºïŒãâCOâãâCOâNHâãŸãã¯â
SO2âNHâåºãä»ããŠä»ããŠããã¢ã«ãã¬ã³
åºãã¢ãªãŒã¬ã³åºãŸãã¯è€çŽ ç°åŒåºãè¡šããã ã¯ãçž®åãã³ãŒã³ç°ãå®æãããããã«å¿ èŠ
ãªæ®åºãè¡šãããããããŠãã®çž®åãã³ãŒã³ç°ã¯
ïŒãŸãã¯ãã以äžã®çœ®æåºããã€ãŠããŠãããã
R1ã¯âOR2ãââR2ãŸã㯠ãè¡šããã ïŒR2ã¯æ°ŽçŽ ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãŸã
ã¯ã¢ãªãŒã«åºãè¡šãããããããŠãã®ã¢ã«ãã«
åºãã·ã¯ãã¢ã«ãã«åºããã³ã¢ãªãŒã«åºã¯çœ®æåº
ããã€ãŠããŠãããã R3ã¯åèšR2ã®å®çŸ©ã§è¿°ã¹ãåºãè¡šããããã
ãã¯R3ã¯ãèèªæãŸãã¯è³éŠæã«ã«ãã³é žããŸ
ãã¯ã¹ã«ãã³é žããå°ãããã¢ã·ã«åºãè¡šããã R4ã¯æ°ŽçŽ ãããã¯é眮æãŸãã¯çœ®æã¢ã«ãã«
åºãè¡šããïŒ ãã€R1ããã³ïŒãŸãã¯ïŒ¹ã«ããå®æãããå
èšçž®åãã³ãŒã³ç°äžã®çœ®æåºã¯ãèæ¡æ£æ§ä»äžçš
æ®åºã§ããããŸãã¯èæ¡æ£æ§ä»äžçšæ®åºãå«ãã
ã®ã§ããã ãšãå«ããã®ã§ããããšãç¹åŸŽãšããåçææã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åçææã«ãã
ãŠããççŽ ååãïŒâïŒåå«ãã¢ã«ãã¬ã³åºã§
ããããšãç¹åŸŽãšããåçææã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé ã«èšèŒã®
åçææã«ãããŠãR2ãççŽ ååãïŒâ22åæ
ããã¢ã«ãã«åºã§ããããšãç¹åŸŽãšããåçæ
æã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé ã«èšèŒã®
åçææã«ãããŠãR4ãççŽ ååãïŒã22åæ
ããã¢ã«ãã«åºã§ããããšãç¹åŸŽãšããåçæ
æã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¯å²ç¬¬ïŒé â第ïŒé ã®ããã
ãã«èšèŒã®åçææã«ãããŠãã«ããå®æãã
ãåèšçž®åãã³ãŒã³ç°ããäžèšã®çœ®æåºãïŒåãŸ
ãã¯ãã以äžå«ããã®ã§ãããããããŠãããã®
眮æåºã¯åäžãŸãã¯çžç°ãªããã®ã§ãã€ãŠããã
ãšãç¹åŸŽãšããåçææïŒããã²ã³ãã¢ã«ãã«åº
ïŒççŽ åå22å以äžã®ãã®ïŒãã¢ãªãŒã«åºãã¢ã©ã«
ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã¢ã©
ã«ã³ãã·åºãããããã·ã«åºããžã¢ã«ãã«ã¢ãã
åºãã¢ã·ã«ã¢ããåºãã¢ã·ã«åºãã·ã¢ãåºãã¹ã«
ãåºãã«ã«ããã·ã«åºãã¹ã«ãã¢ã¢ã€ã«åºãã«ã«
ãã¢ã€ã«åºãçž®åççŽ ç°ãŸãã¯è€çŽ ç°ãå®æãã
ãã®ã«å¿ èŠãªæ®åºã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åçææã«ãã
ãŠãã«ããå®æãããåèšçž®åãã³ãŒã³ç°ãã
ã¡ããã·åºãŸãã¯ãšããã·åºã§çœ®æããããã®ã§
ããããšãç¹åŸŽãšããåçææã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé â第ïŒé ã®ããããã«
èšèŒã®åçææã«ãããŠãåèšèæ¡æ£æ§ææäŸäž
ååç©ãåèšæå æ§ããã²ã³åéä¹³å€äžã«æ··å ¥ã
ãŠããããŸãã¯åèšããã²ã³åéä¹³å€å±€ã®é£ãã®
å±€ã«æ··å ¥ããŠããããšãç¹åŸŽãšããåçææã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2645656A DE2645656C2 (de) | 1976-10-09 | 1976-10-09 | Photographisches FarbdiffusionsÃŒbertragungsverfahren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5346730A JPS5346730A (en) | 1978-04-26 |
| JPS6133179B2 true JPS6133179B2 (ja) | 1986-07-31 |
Family
ID=5990067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12014777A Granted JPS5346730A (en) | 1976-10-09 | 1977-10-07 | Photographic dye diffusion transfer process |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4179291A (ja) |
| JP (1) | JPS5346730A (ja) |
| BE (1) | BE859303A (ja) |
| CA (1) | CA1115580A (ja) |
| DE (1) | DE2645656C2 (ja) |
| FR (1) | FR2367305A1 (ja) |
| GB (1) | GB1581388A (ja) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2811720A1 (de) * | 1978-03-17 | 1979-09-27 | Agfa Gevaert Ag | Photographisches diffusionsuebertragungsverfahren zur herstellung farbiger bilder |
| JPS5785055A (en) * | 1980-11-18 | 1982-05-27 | Konishiroku Photo Ind Co Ltd | Silver halide photographic recording material |
| JPS57210338A (en) * | 1981-06-19 | 1982-12-23 | Konishiroku Photo Ind Co Ltd | Silver halide photographic material |
| JPS5837646A (ja) * | 1981-08-31 | 1983-03-04 | Konishiroku Photo Ind Co Ltd | ã«ã©â転ååã®åœ¢ææ¹æ³ |
| EP0143424B1 (en) | 1983-11-25 | 1990-06-27 | Fuji Photo Film Co., Ltd. | Heat-developable light-sensitive materials |
| DE3778363D1 (de) | 1987-09-11 | 1992-05-21 | Agfa Gevaert Nv | Polymerisches phosphoniumbeizmittel und photographisches element, das dieses enthaelt. |
| JPH08146577A (ja) | 1994-11-25 | 1996-06-07 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©ãŒæå ææ |
| JP4022271B2 (ja) | 1995-10-31 | 2007-12-12 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ãã©ãŸãªã«ã¢ãŸããšããŒã«è²çŽ |
| DE602007008940D1 (de) | 2006-12-07 | 2010-10-14 | Agfa Gevaert Nv | InformationstrÀgervorlÀufer und damit hergestellter informationstrÀger |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2505248C2 (de) * | 1975-02-07 | 1982-11-25 | Agfa-Gevaert Ag, 5090 Leverkusen | Photographisches FarbdiffusionsÃŒbertragungsverfahren und farbphotographisches Aufzeichnungsmaterial fÃŒr das DiffusionsÃŒbertragungsverfahren |
-
1976
- 1976-10-09 DE DE2645656A patent/DE2645656C2/de not_active Expired
-
1977
- 1977-10-03 BE BE1008417A patent/BE859303A/xx not_active IP Right Cessation
- 1977-10-04 US US05/839,374 patent/US4179291A/en not_active Expired - Lifetime
- 1977-10-07 FR FR7730320A patent/FR2367305A1/fr active Granted
- 1977-10-07 GB GB41805/77A patent/GB1581388A/en not_active Expired
- 1977-10-07 CA CA288,365A patent/CA1115580A/en not_active Expired
- 1977-10-07 JP JP12014777A patent/JPS5346730A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1581388A (en) | 1980-12-10 |
| JPS5346730A (en) | 1978-04-26 |
| FR2367305B1 (ja) | 1983-12-09 |
| CA1115580A (en) | 1982-01-05 |
| FR2367305A1 (fr) | 1978-05-05 |
| DE2645656C2 (de) | 1986-08-07 |
| BE859303A (nl) | 1978-04-03 |
| DE2645656A1 (de) | 1978-04-13 |
| US4179291A (en) | 1979-12-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4619884A (en) | Photographic products employing nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds capable of releasing photographically useful groups | |
| CA1076106A (en) | Photographic dye diffusion transfer process | |
| JPS6212911B2 (ja) | ||
| EP0059269A2 (en) | Photographic elements containing blocked dyes or blocked dye releasing compounds and processes for using them | |
| JPS6133179B2 (ja) | ||
| US4369243A (en) | Photographic recording material for diffusion processes and useful non-diffusing sulfilimine compounds | |
| US4198235A (en) | Dye diffusion transfer process employing compounds that release sulfonamide dye providing radicals | |
| US4149892A (en) | Color diffusion transfer photographic elements | |
| JPS5914739B2 (ja) | ã«ã©âæ¡æ£è»¢åæ³ | |
| JPH0138297B2 (ja) | ||
| US4195992A (en) | Photographic dye diffusion transfer process | |
| US4139383A (en) | Dye diffusion transfer employing pyridine azo dye | |
| US4110113A (en) | Sulfonamido dye releaser in photographic dye diffusion transfer | |
| JPS6136218B2 (ja) | ||
| US4810615A (en) | Colour photographic recording material containing a dye releasing compound for cyan dyes and a colour image produced with these dyes | |
| JP3150346B2 (ja) | ç»åèšé²ææ | |
| JPS628778B2 (ja) | ||
| GB1593728A (en) | Photographic light-sensitive sheet material for the colour diffusion transfer process | |
| US4171220A (en) | Photographic dye diffusion transfer process | |
| US4381339A (en) | Photographic recording material and non-diffusing compounds to be used in the material which contains a photographically active group which can be split off | |
| JPH0124294B2 (ja) | ||
| JPS5914740B2 (ja) | æ¡æ£è»¢åçšåçææ | |
| JPH11504975A (ja) | è²æäŸååç© | |
| JPS6136219B2 (ja) | ||
| JPS6144301B2 (ja) |