JPS6126022B2 - - Google Patents
Info
- Publication number
- JPS6126022B2 JPS6126022B2 JP55109843A JP10984380A JPS6126022B2 JP S6126022 B2 JPS6126022 B2 JP S6126022B2 JP 55109843 A JP55109843 A JP 55109843A JP 10984380 A JP10984380 A JP 10984380A JP S6126022 B2 JPS6126022 B2 JP S6126022B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- measurement electrode
- solid electrolyte
- oxygen sensor
- fired
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005259 measurement Methods 0.000 claims description 137
- 239000001301 oxygen Substances 0.000 claims description 96
- 229910052760 oxygen Inorganic materials 0.000 claims description 96
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 78
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 78
- 239000007784 solid electrolyte Substances 0.000 claims description 70
- 239000007789 gas Substances 0.000 claims description 43
- 238000007740 vapor deposition Methods 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 35
- 229910052697 platinum Inorganic materials 0.000 claims description 33
- 239000011195 cermet Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 28
- 238000010304 firing Methods 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- 239000012528 membrane Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000010030 laminating Methods 0.000 claims description 7
- 230000000873 masking effect Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 32
- -1 oxygen ion Chemical class 0.000 description 16
- 238000004544 sputter deposition Methods 0.000 description 13
- 238000007733 ion plating Methods 0.000 description 11
- 239000011241 protective layer Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 238000010586 diagram Methods 0.000 description 9
- 238000007738 vacuum evaporation Methods 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000007650 screen-printing Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000003411 electrode reaction Methods 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 238000005240 physical vapour deposition Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000000992 sputter etching Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000007750 plasma spraying Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018967 Pt—Rh Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052839 forsterite Inorganic materials 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10984380A JPS5734447A (en) | 1980-08-12 | 1980-08-12 | Production of film structure oxygen sensor element |
| GB8122272A GB2081908B (en) | 1980-08-12 | 1981-07-20 | Method of producing solid electrolyte oxygen sensing element of laminated structure with measuring electrode partially deposited from vapour phase |
| FR8115553A FR2488692B1 (fr) | 1980-08-12 | 1981-08-11 | Procede de production d'un element captant l'oxygene a electrolyte solide de structure feuilletee avec electrode externe deposee en phase vapeur |
| DE19813131927 DE3131927A1 (de) | 1980-08-12 | 1981-08-12 | "verfahren zur herstellung eines festkoerperelektrolytsauerstofffuehlerelementes mit lamellenstruktur, dessen aeussere elektrode aus der dampfphase niedergeschlagen ist." |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10984380A JPS5734447A (en) | 1980-08-12 | 1980-08-12 | Production of film structure oxygen sensor element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5734447A JPS5734447A (en) | 1982-02-24 |
| JPS6126022B2 true JPS6126022B2 (enrdf_load_stackoverflow) | 1986-06-18 |
Family
ID=14520600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10984380A Granted JPS5734447A (en) | 1980-08-12 | 1980-08-12 | Production of film structure oxygen sensor element |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5734447A (enrdf_load_stackoverflow) |
| DE (1) | DE3131927A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2488692B1 (enrdf_load_stackoverflow) |
| GB (1) | GB2081908B (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08207951A (ja) * | 1991-06-06 | 1996-08-13 | Yoshiko Tanabe | 開口容器缶の蓋体 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS608361A (ja) * | 1983-06-29 | 1985-01-17 | Shin Etsu Chem Co Ltd | 縮合型シリコ−ンゴム組成物 |
| GB2183042B (en) * | 1985-09-27 | 1989-09-20 | Ngk Spark Plug Co | Air/fuel ratio sensor |
| DE3715275A1 (de) * | 1987-05-08 | 1988-11-17 | Licentia Gmbh | Verfahren und vorrichtung zur erzeugung eines vom sauerstoffgehalt in gasen abhaengigen steuersignals |
| JPH0752171B2 (ja) * | 1987-05-30 | 1995-06-05 | 日本碍子株式会社 | 電気化学的素子 |
| DE3833073A1 (de) * | 1988-09-29 | 1990-04-05 | Siemens Ag | Sauerstoffpartialdruck-sonde, insbesondere lambda-sonde |
| DE3834987A1 (de) * | 1988-10-14 | 1990-04-19 | Bosch Gmbh Robert | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
| JP3467814B2 (ja) * | 1993-01-22 | 2003-11-17 | 株式会社デンソー | 酸素濃度検出装置 |
| EP0859228A3 (en) * | 1997-02-17 | 1999-02-10 | Hitachi, Ltd. | Electrochemical analyzing apparatus |
| DE10121889C2 (de) * | 2001-05-05 | 2003-07-24 | Bosch Gmbh Robert | Sensorelement |
| JP3673501B2 (ja) * | 2002-02-05 | 2005-07-20 | 京セラ株式会社 | 酸素センサ素子 |
| DE102012207761A1 (de) * | 2012-05-09 | 2013-11-14 | Continental Automotive Gmbh | Sensorelement |
| JP6274554B2 (ja) * | 2013-11-25 | 2018-02-07 | 株式会社Ｓｏｋｅｎ | ガスセンサ素子、及びガスセンサ |
| DE102014226718A1 (de) * | 2014-12-19 | 2016-06-23 | Continental Automotive Gmbh | Verfahren zum Betreiben eines Sauerstoffsensors |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| JPS5339791A (en) * | 1976-09-22 | 1978-04-11 | Nissan Motor | Oxygen sensor |
| JPS5348594A (en) * | 1976-10-14 | 1978-05-02 | Nissan Motor | Oxygen sensor |
| DE2718907C2 (de) * | 1977-04-28 | 1984-04-12 | Robert Bosch Gmbh, 7000 Stuttgart | Meßfühler zur Bestimmung des Sauerstoffgehalts in Abgasen |
| JPS54151089A (en) * | 1978-05-18 | 1979-11-27 | Nissan Motor | Solid electrolyte paste |
| JPS5692447A (en) * | 1979-12-26 | 1981-07-27 | Nissan Motor Co Ltd | Production of film-structure oxygen sensor element |
-
1980
- 1980-08-12 JP JP10984380A patent/JPS5734447A/ja active Granted
-
1981
- 1981-07-20 GB GB8122272A patent/GB2081908B/en not_active Expired
- 1981-08-11 FR FR8115553A patent/FR2488692B1/fr not_active Expired
- 1981-08-12 DE DE19813131927 patent/DE3131927A1/de not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08207951A (ja) * | 1991-06-06 | 1996-08-13 | Yoshiko Tanabe | 開口容器缶の蓋体 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2081908B (en) | 1984-05-10 |
| FR2488692A1 (fr) | 1982-02-19 |
| FR2488692B1 (fr) | 1985-07-26 |
| GB2081908A (en) | 1982-02-24 |
| JPS5734447A (en) | 1982-02-24 |
| DE3131927A1 (de) | 1982-05-27 |
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