JPS61190540A - ポリプロピレン樹脂組成物の改質方法 - Google Patents
ポリプロピレン樹脂組成物の改質方法Info
- Publication number
- JPS61190540A JPS61190540A JP3026785A JP3026785A JPS61190540A JP S61190540 A JPS61190540 A JP S61190540A JP 3026785 A JP3026785 A JP 3026785A JP 3026785 A JP3026785 A JP 3026785A JP S61190540 A JPS61190540 A JP S61190540A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene resin
- resin composition
- modification
- pref
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 32
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 24
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 24
- 239000011342 resin composition Substances 0.000 title claims abstract description 21
- 238000012986 modification Methods 0.000 title description 7
- 230000004048 modification Effects 0.000 title description 7
- 238000004132 cross linking Methods 0.000 claims abstract description 20
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 abstract description 10
- 229920005989 resin Polymers 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 10
- QRIMLDXJAPZHJE-UHFFFAOYSA-N 2,3-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)CO QRIMLDXJAPZHJE-UHFFFAOYSA-N 0.000 abstract description 5
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004342 Benzoyl peroxide Substances 0.000 abstract description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 7
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- 238000002715 modification method Methods 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000005456 glyceride group Chemical group 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- ZCUBIPKXZDFIFT-UHFFFAOYSA-N (3-hydroxy-2-prop-2-enoyloxypropyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C=C ZCUBIPKXZDFIFT-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical compound CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- YXUGBTHHXGQXPO-UHFFFAOYSA-N 1-tert-butylperoxy-3-(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 YXUGBTHHXGQXPO-UHFFFAOYSA-N 0.000 description 1
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 description 1
- ODMKGMMECQPAAL-UHFFFAOYSA-N 2,5-bis(butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CCCCOOC(C)(C)C#CC(C)(C)OOCCCC ODMKGMMECQPAAL-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3026785A JPS61190540A (ja) | 1985-02-20 | 1985-02-20 | ポリプロピレン樹脂組成物の改質方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3026785A JPS61190540A (ja) | 1985-02-20 | 1985-02-20 | ポリプロピレン樹脂組成物の改質方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61190540A true JPS61190540A (ja) | 1986-08-25 |
| JPH052698B2 JPH052698B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-13 |
Family
ID=12298923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3026785A Granted JPS61190540A (ja) | 1985-02-20 | 1985-02-20 | ポリプロピレン樹脂組成物の改質方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61190540A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03258845A (ja) * | 1990-01-10 | 1991-11-19 | Toyoda Gosei Co Ltd | ポリプロピレン系樹脂組成物およびその成形品 |
| JP2001524565A (ja) * | 1997-11-21 | 2001-12-04 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ポリプロピレンの溶融強度を増強するための押出し方法 |
| JP2013539812A (ja) * | 2010-10-14 | 2013-10-28 | リライアンス、インダストリーズ、リミテッド | 高溶融強度プロピレン系重合体の調製プロセス |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54160449A (en) * | 1978-06-08 | 1979-12-19 | Showa Denko Kk | Polypropylene resin composition having improved adhesiveness |
| JPS58191706A (ja) * | 1982-05-06 | 1983-11-09 | Showa Denko Kk | オレフイン系重合体混合物 |
| JPS59184245A (ja) * | 1983-04-05 | 1984-10-19 | Showa Denko Kk | オレフイン系重合体混合物 |
-
1985
- 1985-02-20 JP JP3026785A patent/JPS61190540A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54160449A (en) * | 1978-06-08 | 1979-12-19 | Showa Denko Kk | Polypropylene resin composition having improved adhesiveness |
| JPS58191706A (ja) * | 1982-05-06 | 1983-11-09 | Showa Denko Kk | オレフイン系重合体混合物 |
| JPS59184245A (ja) * | 1983-04-05 | 1984-10-19 | Showa Denko Kk | オレフイン系重合体混合物 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03258845A (ja) * | 1990-01-10 | 1991-11-19 | Toyoda Gosei Co Ltd | ポリプロピレン系樹脂組成物およびその成形品 |
| JP2001524565A (ja) * | 1997-11-21 | 2001-12-04 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ポリプロピレンの溶融強度を増強するための押出し方法 |
| JP2013539812A (ja) * | 2010-10-14 | 2013-10-28 | リライアンス、インダストリーズ、リミテッド | 高溶融強度プロピレン系重合体の調製プロセス |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH052698B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-13 |
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