JPS61138653A - プロピレン−エチレンランダム共重合体の改質方法 - Google Patents
プロピレン−エチレンランダム共重合体の改質方法Info
- Publication number
- JPS61138653A JPS61138653A JP25927584A JP25927584A JPS61138653A JP S61138653 A JPS61138653 A JP S61138653A JP 25927584 A JP25927584 A JP 25927584A JP 25927584 A JP25927584 A JP 25927584A JP S61138653 A JPS61138653 A JP S61138653A
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- ethylene
- random copolymer
- copolymer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 title abstract description 4
- 238000012986 modification Methods 0.000 title description 8
- 230000004048 modification Effects 0.000 title description 8
- -1 propylene-ethylene Chemical group 0.000 claims abstract description 26
- 229920005604 random copolymer Polymers 0.000 claims abstract description 21
- 239000002667 nucleating agent Substances 0.000 claims abstract description 13
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 12
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005977 Ethylene Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000000155 melt Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 2
- 238000004581 coalescence Methods 0.000 claims 1
- 239000000454 talc Substances 0.000 abstract description 4
- 229910052623 talc Inorganic materials 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 3
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 abstract description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 1
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- VVFNNEKHSFZNKA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-ene Chemical compound CC(C)(C)OOC(C)(C)C=CC(C)(C)OOC(C)(C)C VVFNNEKHSFZNKA-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- SXAQIBFTHXUOHE-UHFFFAOYSA-K aluminum;2-phenylacetate Chemical compound [Al+3].[O-]C(=O)CC1=CC=CC=C1.[O-]C(=O)CC1=CC=CC=C1.[O-]C(=O)CC1=CC=CC=C1 SXAQIBFTHXUOHE-UHFFFAOYSA-K 0.000 description 1
- CSJKPFQJIDMSGF-UHFFFAOYSA-K aluminum;tribenzoate Chemical compound [Al+3].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 CSJKPFQJIDMSGF-UHFFFAOYSA-K 0.000 description 1
- 229940050390 benzoate Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 1
- ZUDYLZOBWIAUPC-UHFFFAOYSA-L disodium;pentanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CCCC([O-])=O ZUDYLZOBWIAUPC-UHFFFAOYSA-L 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940031993 lithium benzoate Drugs 0.000 description 1
- LDJNSLOKTFFLSL-UHFFFAOYSA-M lithium;benzoate Chemical compound [Li+].[O-]C(=O)C1=CC=CC=C1 LDJNSLOKTFFLSL-UHFFFAOYSA-M 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- UDWXLZLRRVQONG-UHFFFAOYSA-M sodium hexanoate Chemical compound [Na+].CCCCCC([O-])=O UDWXLZLRRVQONG-UHFFFAOYSA-M 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- DXIHILNWDOYYCH-UHDJGPCESA-M sodium;(e)-3-phenylprop-2-enoate Chemical compound [Na+].[O-]C(=O)\C=C\C1=CC=CC=C1 DXIHILNWDOYYCH-UHDJGPCESA-M 0.000 description 1
- XTIVBOWLUYDHKE-UHFFFAOYSA-M sodium;cyclohexanecarboxylate Chemical compound [Na+].[O-]C(=O)C1CCCCC1 XTIVBOWLUYDHKE-UHFFFAOYSA-M 0.000 description 1
- QPNSTCMKRGAEFT-UHFFFAOYSA-M sodium;cyclopentanecarboxylate Chemical compound [Na+].[O-]C(=O)C1CCCC1 QPNSTCMKRGAEFT-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25927584A JPS61138653A (ja) | 1984-12-10 | 1984-12-10 | プロピレン−エチレンランダム共重合体の改質方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25927584A JPS61138653A (ja) | 1984-12-10 | 1984-12-10 | プロピレン−エチレンランダム共重合体の改質方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61138653A true JPS61138653A (ja) | 1986-06-26 |
| JPH0513183B2 JPH0513183B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-19 |
Family
ID=17331828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25927584A Granted JPS61138653A (ja) | 1984-12-10 | 1984-12-10 | プロピレン−エチレンランダム共重合体の改質方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61138653A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100668197B1 (ko) * | 2001-04-10 | 2007-01-11 | 삼성토탈 주식회사 | 가공성 및 투명성이 우수한 폴리프로필렌 수지 조성물 |
| CN102391584A (zh) * | 2011-10-12 | 2012-03-28 | 中国石油化工股份有限公司 | 一种高流动性高韧性聚丙烯树脂及其制备方法 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3036308U (ja) * | 1996-09-30 | 1997-04-15 | 株式会社プロネット | 穀類を収納した袋 |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55133962A (en) * | 1979-04-09 | 1980-10-18 | Tokuyama Soda Kk | Filmy laminate |
| JPS5616540A (en) * | 1979-07-19 | 1981-02-17 | Mitsui Petrochem Ind Ltd | Polypropylene composition for injection molding |
| JPS5734924A (en) * | 1980-08-12 | 1982-02-25 | Mitsui Toatsu Chem Inc | Biaxial drawing blow molding method for polypropylene |
| JPS5849737A (ja) * | 1981-09-19 | 1983-03-24 | Mitsubishi Petrochem Co Ltd | 耐γ線照射性を付与したポリオレフイン組成物 |
| JPS58157841A (ja) * | 1982-03-15 | 1983-09-20 | Mitsubishi Petrochem Co Ltd | プロピレン重合体組成物 |
| JPS58165856A (ja) * | 1982-03-27 | 1983-09-30 | テルモ株式会社 | 医療用器具 |
| JPS59117506A (ja) * | 1982-12-24 | 1984-07-06 | Sumitomo Chem Co Ltd | 結晶性プロピレン−α−オレフイン共重合体フイルム |
| JPS59223740A (ja) * | 1983-06-02 | 1984-12-15 | Mitsui Petrochem Ind Ltd | ポリプロピレン組成物の製造方法 |
| JPS60127337A (ja) * | 1983-12-13 | 1985-07-08 | Mitsui Toatsu Chem Inc | 透明なポリプロピレン樹脂製容器 |
| JPS60212442A (ja) * | 1984-04-09 | 1985-10-24 | Mitsui Toatsu Chem Inc | 放射線に安定なポリプロピレン樹脂組成物 |
| JPS60215047A (ja) * | 1984-04-09 | 1985-10-28 | Mitsubishi Petrochem Co Ltd | ポリプロピレン組成物 |
| JPS6173711A (ja) * | 1984-09-19 | 1986-04-15 | Showa Denko Kk | ポリプロピレン系組成物 |
-
1984
- 1984-12-10 JP JP25927584A patent/JPS61138653A/ja active Granted
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55133962A (en) * | 1979-04-09 | 1980-10-18 | Tokuyama Soda Kk | Filmy laminate |
| JPS5616540A (en) * | 1979-07-19 | 1981-02-17 | Mitsui Petrochem Ind Ltd | Polypropylene composition for injection molding |
| JPS5734924A (en) * | 1980-08-12 | 1982-02-25 | Mitsui Toatsu Chem Inc | Biaxial drawing blow molding method for polypropylene |
| JPS5849737A (ja) * | 1981-09-19 | 1983-03-24 | Mitsubishi Petrochem Co Ltd | 耐γ線照射性を付与したポリオレフイン組成物 |
| JPS58157841A (ja) * | 1982-03-15 | 1983-09-20 | Mitsubishi Petrochem Co Ltd | プロピレン重合体組成物 |
| JPS58165856A (ja) * | 1982-03-27 | 1983-09-30 | テルモ株式会社 | 医療用器具 |
| JPS59117506A (ja) * | 1982-12-24 | 1984-07-06 | Sumitomo Chem Co Ltd | 結晶性プロピレン−α−オレフイン共重合体フイルム |
| JPS59223740A (ja) * | 1983-06-02 | 1984-12-15 | Mitsui Petrochem Ind Ltd | ポリプロピレン組成物の製造方法 |
| JPS60127337A (ja) * | 1983-12-13 | 1985-07-08 | Mitsui Toatsu Chem Inc | 透明なポリプロピレン樹脂製容器 |
| JPS60212442A (ja) * | 1984-04-09 | 1985-10-24 | Mitsui Toatsu Chem Inc | 放射線に安定なポリプロピレン樹脂組成物 |
| JPS60215047A (ja) * | 1984-04-09 | 1985-10-28 | Mitsubishi Petrochem Co Ltd | ポリプロピレン組成物 |
| JPS6173711A (ja) * | 1984-09-19 | 1986-04-15 | Showa Denko Kk | ポリプロピレン系組成物 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100668197B1 (ko) * | 2001-04-10 | 2007-01-11 | 삼성토탈 주식회사 | 가공성 및 투명성이 우수한 폴리프로필렌 수지 조성물 |
| CN102391584A (zh) * | 2011-10-12 | 2012-03-28 | 中国石油化工股份有限公司 | 一种高流动性高韧性聚丙烯树脂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0513183B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |