JPS60161312A - 一過硫酸カリウム組成物及びその安定化方法 - Google Patents
一過硫酸カリウム組成物及びその安定化方法Info
- Publication number
- JPS60161312A JPS60161312A JP59275016A JP27501684A JPS60161312A JP S60161312 A JPS60161312 A JP S60161312A JP 59275016 A JP59275016 A JP 59275016A JP 27501684 A JP27501684 A JP 27501684A JP S60161312 A JPS60161312 A JP S60161312A
- Authority
- JP
- Japan
- Prior art keywords
- crystals
- mother liquor
- acid
- magnesium
- basic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims description 15
- 230000000087 stabilizing effect Effects 0.000 title claims 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 title description 2
- 239000013078 crystal Substances 0.000 claims abstract description 70
- 150000002681 magnesium compounds Chemical class 0.000 claims abstract description 20
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 19
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 17
- 238000002844 melting Methods 0.000 claims abstract description 14
- 230000008018 melting Effects 0.000 claims abstract description 14
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 5
- 238000003860 storage Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 10
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 4
- 229910001868 water Inorganic materials 0.000 abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 26
- 239000011541 reaction mixture Substances 0.000 abstract description 18
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 abstract description 15
- 235000014380 magnesium carbonate Nutrition 0.000 abstract description 14
- 150000003112 potassium compounds Chemical class 0.000 abstract description 11
- 230000003472 neutralizing effect Effects 0.000 abstract description 6
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 abstract description 6
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract description 5
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 abstract description 4
- 229910000343 potassium bisulfate Inorganic materials 0.000 abstract description 4
- 235000012254 magnesium hydroxide Nutrition 0.000 abstract description 2
- 235000012245 magnesium oxide Nutrition 0.000 abstract description 2
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 abstract 1
- 239000012452 mother liquor Substances 0.000 description 51
- 239000000047 product Substances 0.000 description 29
- 239000002253 acid Substances 0.000 description 26
- 238000002425 crystallisation Methods 0.000 description 25
- 230000008025 crystallization Effects 0.000 description 25
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 21
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 17
- 239000001301 oxygen Substances 0.000 description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 15
- 239000002002 slurry Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000006386 neutralization reaction Methods 0.000 description 12
- 235000011149 sulphuric acid Nutrition 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- 235000011118 potassium hydroxide Nutrition 0.000 description 7
- 238000005119 centrifugation Methods 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 235000011151 potassium sulphates Nutrition 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910003650 H2SO6 Inorganic materials 0.000 description 2
- 229910019440 Mg(OH) Inorganic materials 0.000 description 2
- 239000012425 OXONE® Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000011736 potassium bicarbonate Substances 0.000 description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- RSRJCYZEMGBMDE-UHFFFAOYSA-J [K+].[K+].[K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O.[O-]S(=O)(=O)OOS([O-])(=O)=O Chemical compound [K+].[K+].[K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O.[O-]S(=O)(=O)OOS([O-])(=O)=O RSRJCYZEMGBMDE-UHFFFAOYSA-J 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- ILRLTAZWFOQHRT-UHFFFAOYSA-N potassium;sulfuric acid Chemical compound [K].OS(O)(=O)=O ILRLTAZWFOQHRT-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
- C01B15/08—Peroxysulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Control And Other Processes For Unpacking Of Materials (AREA)
- Developing Agents For Electrophotography (AREA)
- Electroluminescent Light Sources (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Cosmetics (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56700783A | 1983-12-30 | 1983-12-30 | |
| US567007 | 1983-12-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60161312A true JPS60161312A (ja) | 1985-08-23 |
| JPH053409B2 JPH053409B2 (https=) | 1993-01-14 |
Family
ID=24265365
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59275016A Granted JPS60161312A (ja) | 1983-12-30 | 1984-12-28 | 一過硫酸カリウム組成物及びその安定化方法 |
| JP59275014A Granted JPS60161311A (ja) | 1983-12-30 | 1984-12-28 | 一過硫酸カリウム組成物及びその製造法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59275014A Granted JPS60161311A (ja) | 1983-12-30 | 1984-12-28 | 一過硫酸カリウム組成物及びその製造法 |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0149329B1 (https=) |
| JP (2) | JPS60161312A (https=) |
| AT (1) | ATE74879T1 (https=) |
| AU (1) | AU583805B2 (https=) |
| BR (1) | BR8406753A (https=) |
| CA (1) | CA1216413A (https=) |
| DE (1) | DE3485660D1 (https=) |
| ES (1) | ES539101A0 (https=) |
| FI (1) | FI76772C (https=) |
| MX (1) | MX162449A (https=) |
| NZ (1) | NZ210659A (https=) |
| PT (1) | PT79784B (https=) |
| ZA (1) | ZA8410078B (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009210906A (ja) * | 2008-03-05 | 2009-09-17 | Tomoegawa Paper Co Ltd | 光ファイバ集合体 |
| JP2009539740A (ja) * | 2006-06-02 | 2009-11-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 一過硫酸カリウム溶液 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5139763A (en) * | 1991-03-06 | 1992-08-18 | E. I. Du Pont De Nemours And Company | Class of stable potassium monopersulfate compositions |
| DE19503900C1 (de) * | 1995-02-07 | 1995-11-23 | Degussa | Verfahren zur Herstellung des Kaliumperoxomonosulfat-Tripelsalzes 2 KHSO¶5¶ . KHSO¶4¶ . K¶2¶SO¶4¶ |
| US6818142B2 (en) * | 2003-03-31 | 2004-11-16 | E. I. Du Pont De Nemours And Company | Potassium hydrogen peroxymonosulfate solutions |
| KR102952337B1 (ko) | 2021-04-02 | 2026-04-14 | 삼성전자주식회사 | 안테나 레이돔 및 이를 포함하는 전자 장치 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE577377A (https=) * | 1956-02-03 | |||
| BE572175A (https=) * | 1957-10-31 | |||
| BE572176A (https=) * | 1957-10-31 | |||
| BE543812A (https=) * | 1958-01-03 | |||
| US3041139A (en) * | 1960-06-24 | 1962-06-26 | Du Pont | Method of preparing monopersulfate composition containing the triple salt khso4?k2so4?2khso5 |
| DE1225619B (de) * | 1961-06-23 | 1966-09-29 | Air Liquide | Verfahren zur Herstellung eines an Kaliummonopersulfat reichen Salzgemisches |
-
1984
- 1984-12-05 AT AT84308461T patent/ATE74879T1/de not_active IP Right Cessation
- 1984-12-05 EP EP84308461A patent/EP0149329B1/en not_active Expired - Lifetime
- 1984-12-05 DE DE8484308461T patent/DE3485660D1/de not_active Expired - Lifetime
- 1984-12-20 NZ NZ210659A patent/NZ210659A/en unknown
- 1984-12-20 CA CA000470662A patent/CA1216413A/en not_active Expired
- 1984-12-27 ZA ZA8410078A patent/ZA8410078B/xx unknown
- 1984-12-27 AU AU37142/84A patent/AU583805B2/en not_active Ceased
- 1984-12-27 BR BR8406753A patent/BR8406753A/pt not_active IP Right Cessation
- 1984-12-27 ES ES539101A patent/ES539101A0/es active Granted
- 1984-12-28 JP JP59275016A patent/JPS60161312A/ja active Granted
- 1984-12-28 FI FI845150A patent/FI76772C/fi active IP Right Grant
- 1984-12-28 PT PT79784A patent/PT79784B/pt unknown
- 1984-12-28 MX MX203924A patent/MX162449A/es unknown
- 1984-12-28 JP JP59275014A patent/JPS60161311A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009539740A (ja) * | 2006-06-02 | 2009-11-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 一過硫酸カリウム溶液 |
| JP2009210906A (ja) * | 2008-03-05 | 2009-09-17 | Tomoegawa Paper Co Ltd | 光ファイバ集合体 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0149329B1 (en) | 1992-04-15 |
| PT79784A (en) | 1985-01-01 |
| BR8406753A (pt) | 1985-10-22 |
| JPH053409B2 (https=) | 1993-01-14 |
| JPH053408B2 (https=) | 1993-01-14 |
| DE3485660D1 (de) | 1992-05-21 |
| ES8603966A1 (es) | 1986-01-01 |
| FI845150L (fi) | 1985-07-01 |
| EP0149329A3 (en) | 1987-09-30 |
| PT79784B (en) | 1987-01-05 |
| NZ210659A (en) | 1987-03-31 |
| FI76772B (fi) | 1988-08-31 |
| JPS60161311A (ja) | 1985-08-23 |
| AU583805B2 (en) | 1989-05-11 |
| AU3714284A (en) | 1985-07-04 |
| ZA8410078B (en) | 1986-08-27 |
| ES539101A0 (es) | 1986-01-01 |
| MX162449A (es) | 1991-05-10 |
| ATE74879T1 (de) | 1992-05-15 |
| FI845150A0 (fi) | 1984-12-28 |
| CA1216413A (en) | 1987-01-13 |
| EP0149329A2 (en) | 1985-07-24 |
| FI76772C (fi) | 1988-12-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |