JPS59193921A - ポリエステルの製造法 - Google Patents
ポリエステルの製造法Info
- Publication number
- JPS59193921A JPS59193921A JP6833283A JP6833283A JPS59193921A JP S59193921 A JPS59193921 A JP S59193921A JP 6833283 A JP6833283 A JP 6833283A JP 6833283 A JP6833283 A JP 6833283A JP S59193921 A JPS59193921 A JP S59193921A
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- glycol
- ester
- acid
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 80
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 51
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 34
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- -1 glycol ester Chemical class 0.000 claims abstract description 20
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 abstract description 36
- 239000000835 fiber Substances 0.000 abstract description 30
- 238000006243 chemical reaction Methods 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 9
- 125000000217 alkyl group Chemical group 0.000 abstract description 4
- 230000001588 bifunctional effect Effects 0.000 abstract description 3
- 150000002334 glycols Chemical class 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000002074 melt spinning Methods 0.000 abstract 1
- 238000009987 spinning Methods 0.000 description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 18
- 239000000654 additive Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 7
- 238000005809 transesterification reaction Methods 0.000 description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- BBYDXOIZLAWGSL-UHFFFAOYSA-N 4-fluorobenzoic acid Chemical compound OC(=O)C1=CC=C(F)C=C1 BBYDXOIZLAWGSL-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 2
- ADCUEPOHPCPMCE-UHFFFAOYSA-N 4-cyanobenzoic acid Chemical group OC(=O)C1=CC=C(C#N)C=C1 ADCUEPOHPCPMCE-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 238000010036 direct spinning Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229940071125 manganese acetate Drugs 0.000 description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000007039 two-step reaction Methods 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- TUXYZHVUPGXXQG-UHFFFAOYSA-N 4-bromobenzoic acid Chemical compound OC(=O)C1=CC=C(Br)C=C1 TUXYZHVUPGXXQG-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- QEZIKGQWAWNWIR-UHFFFAOYSA-N antimony(3+) antimony(5+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Sb+3].[Sb+5] QEZIKGQWAWNWIR-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6833283A JPS59193921A (ja) | 1983-04-20 | 1983-04-20 | ポリエステルの製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6833283A JPS59193921A (ja) | 1983-04-20 | 1983-04-20 | ポリエステルの製造法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1430484A Division JPS6084326A (ja) | 1984-01-31 | 1984-01-31 | ポリエステル及びその製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59193921A true JPS59193921A (ja) | 1984-11-02 |
| JPH0379372B2 JPH0379372B2 (enrdf_load_stackoverflow) | 1991-12-18 |
Family
ID=13370771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6833283A Granted JPS59193921A (ja) | 1983-04-20 | 1983-04-20 | ポリエステルの製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59193921A (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61115931A (ja) * | 1984-11-09 | 1986-06-03 | Teijin Ltd | 制電性ポリエステル組成物の製造方法 |
| JPS61181823A (ja) * | 1985-01-30 | 1986-08-14 | ヘキスト・セラニーズ・コーポレーション | 押出吹込成形に適した改良変性ｐｅｔポリマーおよびコポリマー |
| JPH01132823A (ja) * | 1987-11-11 | 1989-05-25 | Teijin Ltd | ポリエステル繊維の製造法 |
| JPH01234419A (ja) * | 1988-03-14 | 1989-09-19 | Kanebo Ltd | 低吸水性ポリエステル樹脂 |
| WO2016158790A1 (ja) * | 2015-03-31 | 2016-10-06 | 株式会社Adeka | 樹脂用改質剤およびこれを用いた樹脂組成物 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5226593A (en) * | 1975-08-25 | 1977-02-28 | Toyobo Co Ltd | Process for preparing arylene ester polymers |
| JPS54137095A (en) * | 1978-04-10 | 1979-10-24 | Celanese Corp | Polyethylene terephthalate for extrusion |
| JPS55104317A (en) * | 1979-02-01 | 1980-08-09 | Goodyear Tire & Rubber | End group blocked polyester and its manufacture |
| JPS59161426A (ja) * | 1983-03-07 | 1984-09-12 | Teijin Ltd | ポリエステルの製造方法 |
-
1983
- 1983-04-20 JP JP6833283A patent/JPS59193921A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5226593A (en) * | 1975-08-25 | 1977-02-28 | Toyobo Co Ltd | Process for preparing arylene ester polymers |
| JPS54137095A (en) * | 1978-04-10 | 1979-10-24 | Celanese Corp | Polyethylene terephthalate for extrusion |
| JPS55104317A (en) * | 1979-02-01 | 1980-08-09 | Goodyear Tire & Rubber | End group blocked polyester and its manufacture |
| JPS59161426A (ja) * | 1983-03-07 | 1984-09-12 | Teijin Ltd | ポリエステルの製造方法 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61115931A (ja) * | 1984-11-09 | 1986-06-03 | Teijin Ltd | 制電性ポリエステル組成物の製造方法 |
| JPS61181823A (ja) * | 1985-01-30 | 1986-08-14 | ヘキスト・セラニーズ・コーポレーション | 押出吹込成形に適した改良変性ｐｅｔポリマーおよびコポリマー |
| JPH01132823A (ja) * | 1987-11-11 | 1989-05-25 | Teijin Ltd | ポリエステル繊維の製造法 |
| JPH01234419A (ja) * | 1988-03-14 | 1989-09-19 | Kanebo Ltd | 低吸水性ポリエステル樹脂 |
| WO2016158790A1 (ja) * | 2015-03-31 | 2016-10-06 | 株式会社Adeka | 樹脂用改質剤およびこれを用いた樹脂組成物 |
| JPWO2016158790A1 (ja) * | 2015-03-31 | 2018-02-01 | 株式会社Adeka | 樹脂用改質剤およびこれを用いた樹脂組成物 |
| US10208161B2 (en) | 2015-03-31 | 2019-02-19 | Adeka Corporation | Resin modifier and resin composition using same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0379372B2 (enrdf_load_stackoverflow) | 1991-12-18 |
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