JPS5842737A - ガリウムの回収方法 - Google Patents
ガリウムの回収方法Info
- Publication number
- JPS5842737A JPS5842737A JP14135081A JP14135081A JPS5842737A JP S5842737 A JPS5842737 A JP S5842737A JP 14135081 A JP14135081 A JP 14135081A JP 14135081 A JP14135081 A JP 14135081A JP S5842737 A JPS5842737 A JP S5842737A
- Authority
- JP
- Japan
- Prior art keywords
- gallium
- ion exchange
- exchange resin
- resin
- chelating ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims description 50
- 229910052733 gallium Inorganic materials 0.000 title claims description 50
- 238000000034 method Methods 0.000 title claims description 20
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 25
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 25
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 24
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 17
- 239000012266 salt solution Substances 0.000 claims description 15
- 238000011084 recovery Methods 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 12
- 239000011347 resin Substances 0.000 abstract description 8
- 229920005989 resin Polymers 0.000 abstract description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 4
- 125000000524 functional group Chemical group 0.000 abstract description 4
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004131 Bayer process Methods 0.000 abstract description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229910001679 gibbsite Inorganic materials 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- -1 ethylenehexamine Chemical class 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910000497 Amalgam Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 101000984186 Homo sapiens Leukocyte immunoglobulin-like receptor subfamily B member 4 Proteins 0.000 description 1
- 102100025578 Leukocyte immunoglobulin-like receptor subfamily B member 4 Human genes 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 150000002258 gallium Chemical class 0.000 description 1
- 150000002259 gallium compounds Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910000474 mercury oxide Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14135081A JPS5842737A (ja) | 1981-09-07 | 1981-09-07 | ガリウムの回収方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14135081A JPS5842737A (ja) | 1981-09-07 | 1981-09-07 | ガリウムの回収方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5842737A true JPS5842737A (ja) | 1983-03-12 |
| JPH0121212B2 JPH0121212B2 (enrdf_load_stackoverflow) | 1989-04-20 |
Family
ID=15289920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14135081A Granted JPS5842737A (ja) | 1981-09-07 | 1981-09-07 | ガリウムの回収方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5842737A (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5852450A (ja) * | 1981-09-19 | 1983-03-28 | Sumitomo Chem Co Ltd | ガリウムの回収方法 |
| JPS59169932A (ja) * | 1983-03-15 | 1984-09-26 | Sumitomo Chem Co Ltd | ガリウムの捕集方法 |
| DE3413081A1 (de) * | 1983-04-07 | 1984-10-11 | Dowa Mining Co. Ltd., Tokyo | Verfahren zur selektiven abtrennung und konzentrierung von gallium und/oder indium aus loesungen mit einem niedrigen gehalt an diesen metallen und einem hohen gehalt an anderen metallionen |
| JPS59186208U (ja) * | 1983-05-31 | 1984-12-11 | 株式会社 寺岡精工 | ラベル貼付装置 |
| JPS6070023U (ja) * | 1983-10-19 | 1985-05-17 | 横河電機株式会社 | 低周波励磁方式の電磁流量計 |
| JPS61111652A (ja) * | 1984-11-05 | 1986-05-29 | Shikatoo Sangyo Kk | 乾燥牛肉の製造法 |
| JPS6355117A (ja) * | 1986-08-26 | 1988-03-09 | Agency Of Ind Science & Technol | ガリウム及びインジウムの分別回収方法 |
| US4999171A (en) * | 1987-04-03 | 1991-03-12 | Sumitomo Chemical Co. Ltd. | Process for recovery of gallium by chelate resin |
| CN101875004A (zh) * | 2010-06-23 | 2010-11-03 | 西安蓝晓科技有限公司 | 一种吸附镓专用螯合树脂、其制备方法及其应用 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04305252A (ja) * | 1991-01-22 | 1992-10-28 | Nippon Steel Corp | 押し潰し型金属担体の製造方法 |
-
1981
- 1981-09-07 JP JP14135081A patent/JPS5842737A/ja active Granted
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5852450A (ja) * | 1981-09-19 | 1983-03-28 | Sumitomo Chem Co Ltd | ガリウムの回収方法 |
| JPS59169932A (ja) * | 1983-03-15 | 1984-09-26 | Sumitomo Chem Co Ltd | ガリウムの捕集方法 |
| DE3413081A1 (de) * | 1983-04-07 | 1984-10-11 | Dowa Mining Co. Ltd., Tokyo | Verfahren zur selektiven abtrennung und konzentrierung von gallium und/oder indium aus loesungen mit einem niedrigen gehalt an diesen metallen und einem hohen gehalt an anderen metallionen |
| JPS59186208U (ja) * | 1983-05-31 | 1984-12-11 | 株式会社 寺岡精工 | ラベル貼付装置 |
| JPS6070023U (ja) * | 1983-10-19 | 1985-05-17 | 横河電機株式会社 | 低周波励磁方式の電磁流量計 |
| JPS61111652A (ja) * | 1984-11-05 | 1986-05-29 | Shikatoo Sangyo Kk | 乾燥牛肉の製造法 |
| JPS6355117A (ja) * | 1986-08-26 | 1988-03-09 | Agency Of Ind Science & Technol | ガリウム及びインジウムの分別回収方法 |
| US4999171A (en) * | 1987-04-03 | 1991-03-12 | Sumitomo Chemical Co. Ltd. | Process for recovery of gallium by chelate resin |
| CN101875004A (zh) * | 2010-06-23 | 2010-11-03 | 西安蓝晓科技有限公司 | 一种吸附镓专用螯合树脂、其制备方法及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0121212B2 (enrdf_load_stackoverflow) | 1989-04-20 |
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