JPS58129030A - 安定ハロゲン化有機ｃｐｄおよび硼素ｃｐｄからなる着色防止性難燃剤 - Google Patents
安定ハロゲン化有機ｃｐｄおよび硼素ｃｐｄからなる着色防止性難燃剤Info
- Publication number
- JPS58129030A JPS58129030A JP58009256A JP925683A JPS58129030A JP S58129030 A JPS58129030 A JP S58129030A JP 58009256 A JP58009256 A JP 58009256A JP 925683 A JP925683 A JP 925683A JP S58129030 A JPS58129030 A JP S58129030A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- flame retardant
- polyphenylene ether
- composition
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims description 47
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 46
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims description 17
- 229910052796 boron Inorganic materials 0.000 title claims description 17
- 239000000203 mixture Substances 0.000 claims description 100
- 229920001955 polyphenylene ether Polymers 0.000 claims description 50
- 239000011342 resin composition Substances 0.000 claims description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 15
- 239000004793 Polystyrene Substances 0.000 claims description 14
- 150000002894 organic compounds Chemical class 0.000 claims description 14
- -1 polyphenylene Polymers 0.000 claims description 14
- 229920002223 polystyrene Polymers 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 11
- DJHWAIPYZDRNMH-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2-bromophenyl)benzene Chemical group BrC1=CC=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br DJHWAIPYZDRNMH-UHFFFAOYSA-N 0.000 claims description 9
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 7
- 238000002845 discoloration Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 125000005843 halogen group Chemical class 0.000 claims description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical group [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000003110 anti-inflammatory effect Effects 0.000 claims description 4
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical group [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- YVVYMSXDQGDASK-UHFFFAOYSA-N 1,2,3-tribromo-4-[2-(2,3,4-tribromophenoxy)ethoxy]benzene Chemical compound BrC1=C(Br)C(Br)=CC=C1OCCOC1=CC=C(Br)C(Br)=C1Br YVVYMSXDQGDASK-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000012779 reinforcing material Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000000805 composite resin Substances 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- GHMDTEDTNDZHTB-UHFFFAOYSA-N tris(2-phenylcyclohexyl) borate Chemical compound C1CCCC(C=2C=CC=CC=2)C1OB(OC1C(CCCC1)C=1C=CC=CC=1)OC1CCCCC1C1=CC=CC=C1 GHMDTEDTNDZHTB-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 150000005826 halohydrocarbons Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002896 organic halogen compounds Chemical class 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- NDRKXFLZSRHAJE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4-tribromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br NDRKXFLZSRHAJE-UHFFFAOYSA-N 0.000 description 1
- UFNIBRDIUNVOMX-UHFFFAOYSA-N 2,4'-dichlorobiphenyl Chemical group C1=CC(Cl)=CC=C1C1=CC=CC=C1Cl UFNIBRDIUNVOMX-UHFFFAOYSA-N 0.000 description 1
- 125000004352 2-phenylcyclohexyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])* 0.000 description 1
- FNWNBFQPCDGOTI-UHFFFAOYSA-N B([O-])([O-])[O-].[Zn+2].BrC1=C(C=CC=C1)C1=C(C(=C(C(=C1Br)Br)Br)Br)Br.B([O-])([O-])[O-].[Zn+2].[Zn+2] Chemical compound B([O-])([O-])[O-].[Zn+2].BrC1=C(C=CC=C1)C1=C(C(=C(C(=C1Br)Br)Br)Br)Br.B([O-])([O-])[O-].[Zn+2].[Zn+2] FNWNBFQPCDGOTI-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- XBJJRSFLZVLCSE-UHFFFAOYSA-N barium(2+);diborate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]B([O-])[O-].[O-]B([O-])[O-] XBJJRSFLZVLCSE-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000834 poly(ferrocenylene) polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/55—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34235582A | 1982-01-25 | 1982-01-25 | |
| US342355 | 1982-01-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58129030A true JPS58129030A (ja) | 1983-08-01 |
| JPH0344106B2 JPH0344106B2 (en, 2012) | 1991-07-04 |
Family
ID=23341481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58009256A Granted JPS58129030A (ja) | 1982-01-25 | 1983-01-21 | 安定ハロゲン化有機ｃｐｄおよび硼素ｃｐｄからなる着色防止性難燃剤 |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0085834B1 (en, 2012) |
| JP (1) | JPS58129030A (en, 2012) |
| DE (1) | DE3371212D1 (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63264652A (ja) * | 1987-04-21 | 1988-11-01 | Kyodo Yakuhin Kk | 臭素系難燃剤含有スチレン系樹脂組成物の熱安定化法 |
| JPH02180969A (ja) * | 1988-10-12 | 1990-07-13 | General Electric Co <Ge> | 難燃性樹脂組成物 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0163032B1 (ko) * | 1989-03-31 | 1999-01-15 | 오노 알버어스 | 난연성 중합체 조성물 |
| NL8901093A (nl) * | 1989-05-01 | 1990-12-03 | Gen Electric | Materiaal dat ten minste 20% polyfenyleenether bevat en dat een kleine hoeveelheid brandvertragend middel en desgewenst een weekmaker en verdere gebruikelijke toevoegsels bevat. |
| AT394370B (de) * | 1990-04-24 | 1992-03-25 | Chemie Linz Gmbh | Verwendung von spirocyclischen borsaeureestern als flammhemmer in kunststoffen, flammhemmend ausgeruestete kunststoffe sowie spirocyclische borsaeureester |
| DE4105924A1 (de) * | 1991-02-26 | 1992-08-27 | Basf Ag | Rauchgasarme thermoplastische formmassen |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49129750A (en, 2012) * | 1973-04-14 | 1974-12-12 | ||
| JPS5162838A (ja) * | 1974-11-29 | 1976-05-31 | Toray Industries | Nannenseijushisoseibutsuno seizohoho |
| JPS5513772A (en) * | 1978-07-14 | 1980-01-30 | Velsicol Chemical Corp | Flame resistant composition of improved polystyrene plastic |
| JPS57153035A (en) * | 1981-02-18 | 1982-09-21 | Basf Ag | Self-extinguishing thermoplastic forming material |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919356A (en) * | 1968-12-09 | 1975-11-11 | Borg Warner | Halogenated norbornene-methanonaphthalene derivatives and their applications |
| DE2063051A1 (de) * | 1970-12-22 | 1972-07-13 | Bayer | Schwer entflammbares Gummihaar |
| BE795744A (fr) * | 1972-02-23 | 1973-06-18 | Velsicol Chemical Corp | Compositions retardatrices d'inflammation |
| DE2316204B2 (de) * | 1973-03-31 | 1981-04-16 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von 1,2-1,3- oder 1,4 - Bis - (brommethyl) - tetrachlorbenzolen und deren Verwendung als Flammschutzmittel |
| US3897387A (en) * | 1973-05-23 | 1975-07-29 | Shaughnessy James D O | Fire retardant agent |
| US4144288A (en) * | 1978-01-20 | 1979-03-13 | Pennwalt Corporation | Sodium tetraborate pentahydrate as a smoke suppressant for styrenic resins |
-
1983
- 1983-01-12 DE DE8383100202T patent/DE3371212D1/de not_active Expired
- 1983-01-12 EP EP83100202A patent/EP0085834B1/en not_active Expired
- 1983-01-21 JP JP58009256A patent/JPS58129030A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49129750A (en, 2012) * | 1973-04-14 | 1974-12-12 | ||
| JPS5162838A (ja) * | 1974-11-29 | 1976-05-31 | Toray Industries | Nannenseijushisoseibutsuno seizohoho |
| JPS5513772A (en) * | 1978-07-14 | 1980-01-30 | Velsicol Chemical Corp | Flame resistant composition of improved polystyrene plastic |
| JPS57153035A (en) * | 1981-02-18 | 1982-09-21 | Basf Ag | Self-extinguishing thermoplastic forming material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63264652A (ja) * | 1987-04-21 | 1988-11-01 | Kyodo Yakuhin Kk | 臭素系難燃剤含有スチレン系樹脂組成物の熱安定化法 |
| JPH02180969A (ja) * | 1988-10-12 | 1990-07-13 | General Electric Co <Ge> | 難燃性樹脂組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0085834B1 (en) | 1987-04-29 |
| JPH0344106B2 (en, 2012) | 1991-07-04 |
| DE3371212D1 (en) | 1987-06-04 |
| EP0085834A1 (en) | 1983-08-17 |
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