JPS58126893A - クロロシランの加水分解法 - Google Patents
クロロシランの加水分解法Info
- Publication number
- JPS58126893A JPS58126893A JP21712082A JP21712082A JPS58126893A JP S58126893 A JPS58126893 A JP S58126893A JP 21712082 A JP21712082 A JP 21712082A JP 21712082 A JP21712082 A JP 21712082A JP S58126893 A JPS58126893 A JP S58126893A
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen chloride
- hydrolysis
- chlorosilane
- water
- anhydrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000007062 hydrolysis Effects 0.000 title claims description 34
- 238000006460 hydrolysis reaction Methods 0.000 title claims description 34
- 239000005046 Chlorosilane Substances 0.000 title claims description 16
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 title claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 11
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical group C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims description 10
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- -1 polysiloxane Polymers 0.000 claims description 9
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 230000003301 hydrolyzing effect Effects 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000001367 organochlorosilanes Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000548 poly(silane) polymer Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33034781A | 1981-12-14 | 1981-12-14 | |
| US330347 | 1989-03-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58126893A true JPS58126893A (ja) | 1983-07-28 |
| JPS6332357B2 JPS6332357B2 (fr) | 1988-06-29 |
Family
ID=23289362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21712082A Granted JPS58126893A (ja) | 1981-12-14 | 1982-12-13 | クロロシランの加水分解法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS58126893A (fr) |
| DE (1) | DE3244500A1 (fr) |
| FR (1) | FR2518099A1 (fr) |
| GB (1) | GB2112407B (fr) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60172991A (ja) * | 1983-12-14 | 1985-09-06 | ゼネラル・エレクトリツク・カンパニイ | クロロシランの加水分解方法 |
| JPH028223A (ja) * | 1988-06-27 | 1990-01-11 | Toshiba Silicone Co Ltd | オルガノクロロシランの加水分解方法 |
| JPH07109354A (ja) * | 1993-08-18 | 1995-04-25 | Shin Etsu Chem Co Ltd | ジメチルポリシロキサンの製造方法 |
| CN1037002C (zh) * | 1993-12-16 | 1998-01-14 | 瓦克化学有限公司 | 制备聚二甲基硅氧烷的方法 |
| US7306504B2 (en) | 2004-07-12 | 2007-12-11 | Spin Master, Ltd. | Transformable toy |
| JP2014501243A (ja) * | 2010-12-17 | 2014-01-20 | ダウ コーニング コーポレーション | ジオルガノジハロシランの製造方法 |
| US9868073B2 (en) | 2006-02-20 | 2018-01-16 | Spin Master Ltd. | Transformable toy |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5191053A (en) * | 1990-11-14 | 1993-03-02 | Dow Corning Corporation | Preparation of polyorganosiloxanes with controlled low-levels of hydroxy substitution |
| EP0561554A1 (fr) * | 1992-03-17 | 1993-09-22 | General Electric Company | Procédé de récupération d'acide chlorhydrique |
| JP3436075B2 (ja) | 1997-05-28 | 2003-08-11 | 信越化学工業株式会社 | オルガノクロロシランの連続加水分解方法 |
| DE10146390B4 (de) * | 2001-09-20 | 2006-08-10 | Wacker Chemie Ag | Abwasserfreie Herstellung von Polyorganosiloxanen |
| DE10340887B4 (de) * | 2003-09-04 | 2005-01-05 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von Disiloxanen |
| US7479567B2 (en) | 2005-03-29 | 2009-01-20 | Dow Corning Corporation | Reactive distillation of chlorosilanes |
| WO2014062255A1 (fr) | 2012-10-16 | 2014-04-24 | Dow Corning Corporation | Procédé de préparation de silahydrocarbylènes halogénés |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2381366A (en) * | 1942-10-29 | 1945-08-07 | Gen Electric | Organo-dihalogenosiloxanes |
| US2483963A (en) * | 1948-11-24 | 1949-10-04 | Dow Corning | Production of organosiloxanes |
| US2758124A (en) * | 1952-04-11 | 1956-08-07 | Gen Electric | Continuous hydrolysis of organohalogenosilanes |
| JPS5231086A (en) * | 1975-08-29 | 1977-03-09 | Union Carbide Corp | Preparation method of circular syloxane |
| US4221691A (en) * | 1979-02-16 | 1980-09-09 | Dow Corning Corporation | Method of hydrolyzing chlorosilanes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1077230A (fr) * | 1952-04-11 | 1954-11-05 | Thomson Houston Comp Francaise | Hydrolyse des organohalogénosilanes en marche continue |
| US2901460A (en) * | 1956-02-07 | 1959-08-25 | Gen Electric | Halosilane hydrolysis with tetrahydrofuran and water |
| US3763212A (en) * | 1972-02-04 | 1973-10-02 | Gen Electric | Hydrolysis of alkylalkenyldichlorosilane |
-
1982
- 1982-11-19 GB GB08233095A patent/GB2112407B/en not_active Expired
- 1982-12-02 DE DE19823244500 patent/DE3244500A1/de not_active Withdrawn
- 1982-12-13 JP JP21712082A patent/JPS58126893A/ja active Granted
- 1982-12-14 FR FR8220922A patent/FR2518099A1/fr not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2381366A (en) * | 1942-10-29 | 1945-08-07 | Gen Electric | Organo-dihalogenosiloxanes |
| US2483963A (en) * | 1948-11-24 | 1949-10-04 | Dow Corning | Production of organosiloxanes |
| US2758124A (en) * | 1952-04-11 | 1956-08-07 | Gen Electric | Continuous hydrolysis of organohalogenosilanes |
| JPS5231086A (en) * | 1975-08-29 | 1977-03-09 | Union Carbide Corp | Preparation method of circular syloxane |
| US4221691A (en) * | 1979-02-16 | 1980-09-09 | Dow Corning Corporation | Method of hydrolyzing chlorosilanes |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60172991A (ja) * | 1983-12-14 | 1985-09-06 | ゼネラル・エレクトリツク・カンパニイ | クロロシランの加水分解方法 |
| JPH028223A (ja) * | 1988-06-27 | 1990-01-11 | Toshiba Silicone Co Ltd | オルガノクロロシランの加水分解方法 |
| JPH0579247B2 (fr) * | 1988-06-27 | 1993-11-01 | Toshiba Silicone | |
| JPH07109354A (ja) * | 1993-08-18 | 1995-04-25 | Shin Etsu Chem Co Ltd | ジメチルポリシロキサンの製造方法 |
| CN1037002C (zh) * | 1993-12-16 | 1998-01-14 | 瓦克化学有限公司 | 制备聚二甲基硅氧烷的方法 |
| US7306504B2 (en) | 2004-07-12 | 2007-12-11 | Spin Master, Ltd. | Transformable toy |
| US7731563B2 (en) | 2004-07-12 | 2010-06-08 | Saucier Aldric J | Transformable toy |
| US9868073B2 (en) | 2006-02-20 | 2018-01-16 | Spin Master Ltd. | Transformable toy |
| US10987604B2 (en) | 2006-02-20 | 2021-04-27 | Spin Master Ltd. | Transformable toy |
| JP2014501243A (ja) * | 2010-12-17 | 2014-01-20 | ダウ コーニング コーポレーション | ジオルガノジハロシランの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2112407A (en) | 1983-07-20 |
| GB2112407B (en) | 1985-06-19 |
| FR2518099A1 (fr) | 1983-06-17 |
| JPS6332357B2 (fr) | 1988-06-29 |
| DE3244500A1 (de) | 1983-06-23 |
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