JPS58125246A - レ−ザ記録媒体 - Google Patents
レ−ザ記録媒体Info
- Publication number
- JPS58125246A JPS58125246A JP57007426A JP742682A JPS58125246A JP S58125246 A JPS58125246 A JP S58125246A JP 57007426 A JP57007426 A JP 57007426A JP 742682 A JP742682 A JP 742682A JP S58125246 A JPS58125246 A JP S58125246A
- Authority
- JP
- Japan
- Prior art keywords
- recording medium
- substrate
- laser
- cyanine dye
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2472—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes cyanine
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
- G11B7/2535—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins polyesters, e.g. PET, PETG or PEN
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
本発明はシアニン系色素薄膜を有するレーザ記録媒体に
関する。さらに詳しくは、レーザビームによシ直接記碌
し反射光の変化によって情報再生を行う方法（いわゆる
光ディスク）Ｋ用いられるレーザ記録媒体に関する。
関する。さらに詳しくは、レーザビームによシ直接記碌
し反射光の変化によって情報再生を行う方法（いわゆる
光ディスク）Ｋ用いられるレーザ記録媒体に関する。
従来、色素薄膜を記録層として適用した光学的メモリ媒
体は知られている（例えば、特開昭５６１６９４８号公
報）。すなわち、この種の光学的メモリ媒体は基板と色
素薄膜記録層との間に金属反射膜を設け、記録層の側か
ら記録層の光吸収率が極大を示す波長のレーザビームを
集光照射して情報を記録再生するものである。しかしな
がら、かかるメモリ媒体においては色素記録層の保饅が
困難であるため記録層に付着した小ゴミなど罠よって情
報の記録再生ｊ（誤沙を生じやすいことおよび、反射型
光学メモリ媒体として利用するためＫは金属反射膜が必
要で高松媒体の構成が複雑になるという問題がある。
体は知られている（例えば、特開昭５６１６９４８号公
報）。すなわち、この種の光学的メモリ媒体は基板と色
素薄膜記録層との間に金属反射膜を設け、記録層の側か
ら記録層の光吸収率が極大を示す波長のレーザビームを
集光照射して情報を記録再生するものである。しかしな
がら、かかるメモリ媒体においては色素記録層の保饅が
困難であるため記録層に付着した小ゴミなど罠よって情
報の記録再生ｊ（誤沙を生じやすいことおよび、反射型
光学メモリ媒体として利用するためＫは金属反射膜が必
要で高松媒体の構成が複雑になるという問題がある。
しかる釦、本発明者は上記問題を解決する１つの方策と
して、記録層としてシアニン系色素単層膜を使用しかつ
記録層の保護が容易にできるように透明基板側より記録
および再生用レーザ光を照射して情報の記録および再生
が可能な反射型光学的メモリ媒体を先虻提案した。
して、記録層としてシアニン系色素単層膜を使用しかつ
記録層の保護が容易にできるように透明基板側より記録
および再生用レーザ光を照射して情報の記録および再生
が可能な反射型光学的メモリ媒体を先虻提案した。
しかし、シアニン系色素は一般に退色し易いことから記
録媒体として十分満足のいくものではなかった。そこで
、本発明者はさらに改良を重ねた結果シアニン系色素の
うちから特定のものを選択使用し且つそれを担持する基
板材料の材質を特定すること釦よりシアニン系色素の退
色性を補填し上記光学的メモリ媒体の保存性をさらに向
上できることを知見し本発明の完成に至った。
録媒体として十分満足のいくものではなかった。そこで
、本発明者はさらに改良を重ねた結果シアニン系色素の
うちから特定のものを選択使用し且つそれを担持する基
板材料の材質を特定すること釦よりシアニン系色素の退
色性を補填し上記光学的メモリ媒体の保存性をさらに向
上できることを知見し本発明の完成に至った。
本発明は保存性およびＳ／′Ｎ（ｃハ）比がさらに改良
され且つＨｅ−Ｎθレーザないし半導体レーザのような
安価なレーザにより記録再生可能なレーザ記録媒体を提
供することを目的とする。
され且つＨｅ−Ｎθレーザないし半導体レーザのような
安価なレーザにより記録再生可能なレーザ記録媒体を提
供することを目的とする。
すなわち１本発明のレーザ記録媒体はプラスチック基板
上に一般式！ （式中、Ｒはアルキル基を表わ（７そしてＸは〕・ロゲ
ンを表わす）で表わされるシアニン系色素の薄膜を有す
るものであろう 本発明では選択使用される上記一般式■のシアニン色素
との関係を特に考慮して基板材料としてプラスチックを
使用することが肝要である。
上に一般式！ （式中、Ｒはアルキル基を表わ（７そしてＸは〕・ロゲ
ンを表わす）で表わされるシアニン系色素の薄膜を有す
るものであろう 本発明では選択使用される上記一般式■のシアニン色素
との関係を特に考慮して基板材料としてプラスチックを
使用することが肝要である。
ガラス板忙は色素の退色促進作用が大きく本発明のレー
ザ記録媒体の基板とし【は不適当である。本発明で使用
される代表的なプラスチックとしては塩化ビニル樹脂、
酢酸ヒニル樹脂、アクリル樹脂、メタクリル樹脂、ポリ
エステル樹脂、ニトロセルロース、ポリエチレン樹脂、
、ｅリプロピレン樹脂、ポリアミド樹脂、ポリスチレン
樹脂、ポリカーボネート樹脂、エポキシ樹脂などがあげ
られるが、アクリル樹脂が特に好ましい。
ザ記録媒体の基板とし【は不適当である。本発明で使用
される代表的なプラスチックとしては塩化ビニル樹脂、
酢酸ヒニル樹脂、アクリル樹脂、メタクリル樹脂、ポリ
エステル樹脂、ニトロセルロース、ポリエチレン樹脂、
、ｅリプロピレン樹脂、ポリアミド樹脂、ポリスチレン
樹脂、ポリカーボネート樹脂、エポキシ樹脂などがあげ
られるが、アクリル樹脂が特に好ましい。
本発明のレーザ記録媒体に適用されるレーザ光は使用色
素の吸収波長に応じて選択する必要があるが比較的安価
なＨｅ−Ｎθレーザまたは半導体レーザが好ましい。
素の吸収波長に応じて選択する必要があるが比較的安価
なＨｅ−Ｎθレーザまたは半導体レーザが好ましい。
本発明におけるシアニン色素薄膜は一般忙プラスチック
基板上にシアニン色素溶液を１０００Ａ以下の厚さで塗
布（回転塗布機などを用いて）し乾燥することによって
容易に形成することができる。
基板上にシアニン色素溶液を１０００Ａ以下の厚さで塗
布（回転塗布機などを用いて）し乾燥することによって
容易に形成することができる。
次に、本発明のレーザ記録媒体の構成および情報の記録
再生法を添付図面について説明すると、第１図に示すよ
うに色素膜１Ｉ１１はプラスチック基板２の上に形成さ
れレーザ記録媒体３を構成する。また、図示のように同
一構成の２枚の記録媒体３．３を色素薄膜同志を対向し
て配置することＫよシ色素薄膜１は外気と遮断され、ゴ
ミの付着、キズの発生、有害カスとの接触から保護でき
るため保存性は著しく向上する。この際、色素膜ＩＰ１
はプラスチック基板２によって保慢されるので記録情報
が物理的化学的作用杷よって損われることがないうレー
ザビーム４は集光レンズ５によって集光され基板２を通
して照射され、光吸収反射性の色素膜１を除去、分解す
ることＫより記録が行なわれる。情報の再生は色素膜１
の有無によって生ずる反射光の差を検出することによっ
て行なわれる。反射光の検出にはプラスチック基板２を
通して行なうことが実用上都合がよい。
再生法を添付図面について説明すると、第１図に示すよ
うに色素膜１Ｉ１１はプラスチック基板２の上に形成さ
れレーザ記録媒体３を構成する。また、図示のように同
一構成の２枚の記録媒体３．３を色素薄膜同志を対向し
て配置することＫよシ色素薄膜１は外気と遮断され、ゴ
ミの付着、キズの発生、有害カスとの接触から保護でき
るため保存性は著しく向上する。この際、色素膜ＩＰ１
はプラスチック基板２によって保慢されるので記録情報
が物理的化学的作用杷よって損われることがないうレー
ザビーム４は集光レンズ５によって集光され基板２を通
して照射され、光吸収反射性の色素膜１を除去、分解す
ることＫより記録が行なわれる。情報の再生は色素膜１
の有無によって生ずる反射光の差を検出することによっ
て行なわれる。反射光の検出にはプラスチック基板２を
通して行なうことが実用上都合がよい。
以下に比較例と共に実施例を掲げて本発明をさらに説明
するが、これに限定されるものではない。実施例および
比較例忙おいては以下の構造式で表わされるシアニン色
素の中から以下の表に示すものを選択使用してその結果
を検討した。
するが、これに限定されるものではない。実施例および
比較例忙おいては以下の構造式で表わされるシアニン色
素の中から以下の表に示すものを選択使用してその結果
を検討した。
Ａ、−（（’ＪＩ＝ＣＨ−）ｙ ＣＨ＝Ａ２記碌媒体記
録定のシアニン色素をジクロルメタ／に溶解しこの溶液
を回転塗布機によって所定の基板（厚さ１１Ｉｌ）上に
約３００Ｘの厚さで塗布し乾燥することによって作製し
た。シアニン色素は日本感光色素研究所のものを用い、
Ｈｅ −Ｎ・レーザの波長６３３ｎｍから半導体レーザ
の波長３０（ｌｎｍＫ吸収のある色素を選んだ。射光寿
命は戸外の１Ａｏの照射光を受ける場所に保存されたと
きの値で示し℃あシ、光学濃度が初期値の８０−まで低
下するに要した時間であられした。
録定のシアニン色素をジクロルメタ／に溶解しこの溶液
を回転塗布機によって所定の基板（厚さ１１Ｉｌ）上に
約３００Ｘの厚さで塗布し乾燥することによって作製し
た。シアニン色素は日本感光色素研究所のものを用い、
Ｈｅ −Ｎ・レーザの波長６３３ｎｍから半導体レーザ
の波長３０（ｌｎｍＫ吸収のある色素を選んだ。射光寿
命は戸外の１Ａｏの照射光を受ける場所に保存されたと
きの値で示し℃あシ、光学濃度が初期値の８０−まで低
下するに要した時間であられした。
射光テストには５４０００ルツクスのタングステン光を
３５±３℃の条件で照射する促進試験方法を用いた。そ
れらの結果を以下の表Ｋまとめて示すっ Ｃ２１（５Ｉ Ｃ２”５分光特性 ８１８ ５３ １８ 五５ ジクロル
メタン８１７ ５２ １８ ６．７８１６
５２ １０ ５．６ メタノール６５
０ １１ ２０ ２．１シアニン色素の種
類 分光特性 アクリル ８００ ４４ １２ ０．７３
ジクロルメタン６９５ ３０ ３４ ０
．２５ガラス ８２５ ３３ ０．１５ガラス
８１８ ５５ １８ ０．６７本発明の寮施例忙おいて
作製した記録媒体ＫＨｅ−Ｎ、ｅレーザから半導体レー
ザの波長を照射したところ、強い吸収と反射を示し反射
型の書込読出の可能な光デイスク媒体として適している
ことがわかった。また、本発明の記録媒体ＫＯ，５ＭＨ
２のキャリヤ信号とじ３ ｍＷ ｆ） Ｈｅ−Ｎｅレー
ザを１．６μｍＪ／（集光照射で記録し再生信号をスＲ
クトラムアナライザで測定したところスキャンニングフ
ィルターのバンド＠ ３０ ＫＨｚの条件におけるＣ／
Ｎが５５ｄＢであった。一方従来から知られている記録
媒体であるＴｅを１■厚のアクリル板に３００Ｘの厚さ
で蒸着したもの忙同−条件で記録し再生したところＣ／
′Ｎが４５ｄＢであった。なお記録再生にはアクリル基
板からレーザビームな照射し念。
３５±３℃の条件で照射する促進試験方法を用いた。そ
れらの結果を以下の表Ｋまとめて示すっ Ｃ２１（５Ｉ Ｃ２”５分光特性 ８１８ ５３ １８ 五５ ジクロル
メタン８１７ ５２ １８ ６．７８１６
５２ １０ ５．６ メタノール６５
０ １１ ２０ ２．１シアニン色素の種
類 分光特性 アクリル ８００ ４４ １２ ０．７３
ジクロルメタン６９５ ３０ ３４ ０
．２５ガラス ８２５ ３３ ０．１５ガラス
８１８ ５５ １８ ０．６７本発明の寮施例忙おいて
作製した記録媒体ＫＨｅ−Ｎ、ｅレーザから半導体レー
ザの波長を照射したところ、強い吸収と反射を示し反射
型の書込読出の可能な光デイスク媒体として適している
ことがわかった。また、本発明の記録媒体ＫＯ，５ＭＨ
２のキャリヤ信号とじ３ ｍＷ ｆ） Ｈｅ−Ｎｅレー
ザを１．６μｍＪ／（集光照射で記録し再生信号をスＲ
クトラムアナライザで測定したところスキャンニングフ
ィルターのバンド＠ ３０ ＫＨｚの条件におけるＣ／
Ｎが５５ｄＢであった。一方従来から知られている記録
媒体であるＴｅを１■厚のアクリル板に３００Ｘの厚さ
で蒸着したもの忙同−条件で記録し再生したところＣ／
′Ｎが４５ｄＢであった。なお記録再生にはアクリル基
板からレーザビームな照射し念。
上述したようにして構成された本発明のレーザ記録媒体
は以下の効果を奏する。
は以下の効果を奏する。
（１）基板をプラスチック基板にすることによりガラス
基板に比べて退色寿命が５倍長くなった。
基板に比べて退色寿命が５倍長くなった。
（２） シアニン系色素の中からト記一般式■の化合
物を特定的忙選択することＫより、他のシアニン色素に
比べて特異的忙退色寿命が長くなった。
物を特定的忙選択することＫより、他のシアニン色素に
比べて特異的忙退色寿命が長くなった。
（３）色素膜をうすくすること忙より記録時の投じんの
発生および記録孔の周辺の乱れを防止できることからＣ
外が極めて高くなった。
発生および記録孔の周辺の乱れを防止できることからＣ
外が極めて高くなった。
添付図面は本発明のレーザ記録媒体の基本構成を示す断
面図である。 １・・・色票薄膜、２・・・プラスチック基板、５・・
・記録媒体、４・・・レーザビーム、５・・・集光レン
ズ。
面図である。 １・・・色票薄膜、２・・・プラスチック基板、５・・
・記録媒体、４・・・レーザビーム、５・・・集光レン
ズ。
Claims (1)
- 【特許請求の範囲】 プラスチック基板上九一般式 （式中、Ｒはアルキル基を表わしそしてＸは）１０ゲン
を表わす）で表わされるシアニン系色素の薄膜を有する
ことを特徴とする、レーザ記像媒体。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57007426A JPS58125246A (ja) | 1982-01-22 | 1982-01-22 | レ−ザ記録媒体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57007426A JPS58125246A (ja) | 1982-01-22 | 1982-01-22 | レ−ザ記録媒体 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58125246A true JPS58125246A (ja) | 1983-07-26 |
Family
ID=11665532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57007426A Granted JPS58125246A (ja) | 1982-01-22 | 1982-01-22 | レ−ザ記録媒体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58125246A (ja) |
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| JPS60187948A (ja) * | 1984-03-06 | 1985-09-25 | Ricoh Co Ltd | 光学的情報記憶媒体 |
| JPH0553636B2 (ja) * | 1984-10-26 | 1993-08-10 | Ricoh Kk | |
| JPS61102292A (ja) * | 1984-10-26 | 1986-05-20 | Ricoh Co Ltd | 光情報記録媒体 |
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| WO2013145949A1 (ja) | 2012-03-29 | 2013-10-03 | 富士フイルム株式会社 | 平版印刷版原版、及びその印刷方法 |
| EP2644379A1 (en) | 2012-03-30 | 2013-10-02 | FUJIFILM Corporation | Method of producing a planographic printing plate |
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