JPH11513819A - 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品 - Google Patents

微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品

Info

Publication number
JPH11513819A
JPH11513819A JP9516592A JP51659297A JPH11513819A JP H11513819 A JPH11513819 A JP H11513819A JP 9516592 A JP9516592 A JP 9516592A JP 51659297 A JP51659297 A JP 51659297A JP H11513819 A JPH11513819 A JP H11513819A
Authority
JP
Japan
Prior art keywords
layer
microspheres
exposed lens
retroreflective
lens retroreflective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP9516592A
Other languages
English (en)
Japanese (ja)
Other versions
JPH11513819A5 (enExample
Inventor
ジー． ビリングスレー，ブリトン
ジェイ． フレミング，ロバート
Original Assignee
ミネソタ マイニング アンド マニュファクチャリング カンパニー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ミネソタ マイニング アンド マニュファクチャリング カンパニー filed Critical ミネソタ マイニング アンド マニュファクチャリング カンパニー
Publication of JPH11513819A publication Critical patent/JPH11513819A/ja
Publication of JPH11513819A5 publication Critical patent/JPH11513819A5/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
  • Road Signs Or Road Markings (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Outerwear In General, And Traditional Japanese Garments (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
JP9516592A 1995-10-26 1996-09-11 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品 Withdrawn JPH11513819A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/548,578 1995-10-26
US08/548,578 US5812317A (en) 1995-10-26 1995-10-26 Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
PCT/US1996/014448 WO1997015848A1 (en) 1995-10-26 1996-09-11 Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2007241525A Division JP2008096995A (ja) 1995-10-26 2007-09-18 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品

Publications (2)

Publication Number Publication Date
JPH11513819A true JPH11513819A (ja) 1999-11-24
JPH11513819A5 JPH11513819A5 (enExample) 2004-10-21

Family

ID=24189470

Family Applications (3)

Application Number Title Priority Date Filing Date
JP9516592A Withdrawn JPH11513819A (ja) 1995-10-26 1996-09-11 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品
JP2007241525A Pending JP2008096995A (ja) 1995-10-26 2007-09-18 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品
JP2010025581A Withdrawn JP2010156987A (ja) 1995-10-26 2010-02-08 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品

Family Applications After (2)

Application Number Title Priority Date Filing Date
JP2007241525A Pending JP2008096995A (ja) 1995-10-26 2007-09-18 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品
JP2010025581A Withdrawn JP2010156987A (ja) 1995-10-26 2010-02-08 微小球層および反射層の間に配置されるポリマー中間層を有する露出レンズ再帰反射製品

Country Status (8)

Country Link
US (1) US5812317A (enExample)
EP (1) EP0857311B1 (enExample)
JP (3) JPH11513819A (enExample)
KR (1) KR100400909B1 (enExample)
CN (1) CN1120378C (enExample)
CA (1) CA2234605C (enExample)
DE (1) DE69630804T2 (enExample)
WO (1) WO1997015848A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003502706A (ja) * 1999-06-17 2003-01-21 スリーエム イノベイティブ プロパティズ カンパニー ポリマーに共有結合された染料を含有する着色層を有する再帰反射物品
JP2005274983A (ja) * 2004-03-25 2005-10-06 Unitika Sparklite Kk 着色再帰反射媒体中間体とその製造方法および熱転写方法
JP2013531809A (ja) * 2010-05-25 2013-08-08 スリーエム イノベイティブ プロパティズ カンパニー 露出レンズ型再帰反射性物品

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10153701A (ja) 1996-11-19 1998-06-09 Minnesota Mining & Mfg Co <3M> 再帰性反射シート
US6159537A (en) * 1997-08-01 2000-12-12 3M Innovative Properties Company Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer
US6365262B1 (en) * 1998-10-20 2002-04-02 3M Innovative Properties Company Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same
US6247818B1 (en) * 1998-10-20 2001-06-19 3M Innovative Properties Company Method for making retroreflective elements having enhanced retroreflectivity under dry and/or wet conditions
US6172810B1 (en) 1999-02-26 2001-01-09 3M Innovative Properties Company Retroreflective articles having polymer multilayer reflective coatings
US6503564B1 (en) * 1999-02-26 2003-01-07 3M Innovative Properties Company Method of coating microstructured substrates with polymeric layer(s), allowing preservation of surface feature profile
ATE285588T1 (de) * 1999-06-17 2005-01-15 3M Innovative Properties Co Retroreflektierender gegenstand mit einer farbigen schicht, die reflektierende blättchen und einen kovalent an ein polymer gebundenen farbstoff enthält
US6548164B1 (en) * 1999-06-30 2003-04-15 3M Innovative Properties Company Removable sheeting
KR20010016784A (ko) * 1999-08-03 2001-03-05 최병대 광택 및 반사 특성이 우수한 도금 미소 유리구슬, 그 제조방법
US6696126B1 (en) 1999-08-12 2004-02-24 The United States Of America As Represented By The Secretary Of The Navy Visual-tactile signage
US6966660B1 (en) * 1999-10-15 2005-11-22 3M Innovative Properties Company Article exhibiting dry and wet retroreflectivity
US6416188B1 (en) 2000-04-11 2002-07-09 3M Innovative Properties Company Dielectric mirror retroreflective appliques having excellent repetitive laundering performance
US7540671B2 (en) * 2003-11-17 2009-06-02 Olympus Corporation Variable-power optical system and electronic device using same
US7247386B2 (en) 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
US20050137266A1 (en) * 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements
US7140741B2 (en) * 2003-12-30 2006-11-28 3M Innovative Properties Company Color shifting retroreflector and method of making same
US20050208093A1 (en) 2004-03-22 2005-09-22 Thierry Glauser Phosphoryl choline coating compositions
US20060026731A1 (en) * 2004-08-04 2006-02-09 Reemay, Inc. High visibility fabric and safety vest
US7195360B2 (en) * 2004-12-28 2007-03-27 3M Innovative Properties Company Prismatic retroreflective article and method
CN100526917C (zh) * 2004-12-28 2009-08-12 3M创新有限公司 具有含氟或含硅的棱镜的棱镜式逆向反射制品
US7391569B2 (en) * 2004-12-29 2008-06-24 3M Innovative Properties Company Projection system including intrinsic polarizer
US7453634B2 (en) * 2005-03-07 2008-11-18 Avery Dennison Corporation Discontinuous or variable thickness gain modification coating for projection film and method for making same
US7842374B2 (en) * 2006-07-28 2010-11-30 3M Innovative Properties Company Retroreflective article comprising a copolyester ether composition layer and method of making same
US8701441B2 (en) 2006-08-21 2014-04-22 3M Innovative Properties Company Method of making inorganic, metal oxide spheres using microstructured molds
US8120854B2 (en) * 2006-12-28 2012-02-21 3M Innovative Properties Company Interference films having acrylamide layer and method of making same
US7547105B2 (en) * 2007-07-16 2009-06-16 3M Innovative Properties Company Prismatic retroreflective article with cross-linked image layer and method of making same
EP2419243A1 (en) * 2009-04-17 2012-02-22 3M Innovative Properties Company Metal particle transfer article, metal modified substrate, and method of making and using the same
TW201315598A (zh) * 2012-10-18 2013-04-16 Cing Wai Kung Mau Company 反光物品製程
US20160096195A1 (en) * 2013-05-24 2016-04-07 3M Innovative Properties Company Bead-coated sheet
EP3060946A1 (en) 2013-10-24 2016-08-31 3M Innovative Properties Company Retroreflective articles with anti-staining properties
CN105940325A (zh) * 2014-01-31 2016-09-14 3M创新有限公司 彩色回射制品
CN106029363B (zh) 2014-02-13 2018-01-16 3M创新有限公司 双重固化耐污微球体制品
CN106415336B (zh) 2014-04-30 2020-12-04 3M创新有限公司 防污回射制品
US10197714B2 (en) 2014-05-09 2019-02-05 3M Innovative Properties Company Colored retroreflective articles
EP3140683B1 (en) * 2014-05-09 2025-10-29 3M Innovative Properties Company Retroreflective articles
CN106459352B (zh) * 2014-06-16 2020-01-14 3M创新有限公司 具有耐洗性珠粘结层的回射制品
WO2016039820A1 (en) 2014-09-10 2016-03-17 3M Innovative Properties Company Exposed lens retroreflective articles comprising a self-assembled dielectric mirror
JP6760929B2 (ja) 2014-09-30 2020-09-23 スリーエム イノベイティブ プロパティズ カンパニー 再帰反射性着色物品
US10345495B2 (en) 2014-12-30 2019-07-09 3M Innovative Properties Company Stain resistant retroreflective articles
CN108430638B (zh) 2015-12-22 2021-06-08 3M创新有限公司 用于样品分配的杆-槽膜
CN108431576B (zh) * 2015-12-28 2020-09-15 3M创新有限公司 用于样本分配的料筒
US11413846B2 (en) 2016-03-30 2022-08-16 3M Innovative Properties Company Article featuring a predetermined pattern of randomly distributed microspheres and methods of making the same
CN106560734A (zh) * 2016-06-01 2017-04-12 杭州飞像科技有限公司 空中成像元件在提词器中的应用及提词器
US11493674B2 (en) * 2017-10-27 2022-11-08 3M Innovative Properties Company Retroreflective article comprising embedded reflective layers
CN108130746B (zh) * 2017-12-28 2020-07-03 浙江宏成建材有限公司 一种建筑用长效型高分子防水卷材及其制备方法
WO2020136567A1 (en) * 2018-12-27 2020-07-02 3M Innovative Properties Company Retroreflective articles containing adhesive compositions including styrenic block co-polymers
WO2020217220A1 (en) * 2019-04-25 2020-10-29 3M Innovative Properties Company Retroreflective article comprising multiple locally-laminated layers

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2326634A (en) * 1941-12-26 1943-08-10 Minnesota Mining & Mfg Reflex light reflector
US2379702A (en) * 1943-01-23 1945-07-03 Minnesota Mining & Mfg Reflex light reflector
US2440584A (en) * 1944-06-19 1948-04-27 Minnesota Mining & Mfg Lenticular reflex reflector sheet and method of making the same
US3190178A (en) * 1961-06-29 1965-06-22 Minnesota Mining & Mfg Reflex-reflecting sheeting
US3573954A (en) * 1967-07-05 1971-04-06 Nihon Koken Co Ltd Reflex-reflectors and method for the manufacture thereof
US3700305A (en) * 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
JPS5483392A (en) * 1977-12-15 1979-07-03 Unitika Ltd Method of transferring glass bead
US4367920A (en) * 1979-10-01 1983-01-11 Minnesota Mining And Manufacturing Company Retroflective sheeting
JPS60128401A (ja) * 1983-12-15 1985-07-09 Ide Kogyo Kk 再帰反射模様物の製造方法
JPS619601A (ja) * 1984-06-25 1986-01-17 Hitachi Ltd 光学レンズ
WO1992019993A1 (en) * 1991-05-08 1992-11-12 Minnesota Mining And Manufacturing Company Launderable retroreflective applique
US5200262A (en) * 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements
US5344705A (en) * 1993-05-05 1994-09-06 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
US5503906A (en) * 1993-05-05 1996-04-02 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
US5514441A (en) * 1994-09-30 1996-05-07 Avery Dennison Corporation Retroreflective sheeting with improved topcoat
CA2204516C (en) * 1994-11-23 2006-08-15 Minnesota Mining And Manufacturing Company Retroreflective article containing a polyether polyurethane binder layer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003502706A (ja) * 1999-06-17 2003-01-21 スリーエム イノベイティブ プロパティズ カンパニー ポリマーに共有結合された染料を含有する着色層を有する再帰反射物品
JP2005274983A (ja) * 2004-03-25 2005-10-06 Unitika Sparklite Kk 着色再帰反射媒体中間体とその製造方法および熱転写方法
JP2013531809A (ja) * 2010-05-25 2013-08-08 スリーエム イノベイティブ プロパティズ カンパニー 露出レンズ型再帰反射性物品

Also Published As

Publication number Publication date
CA2234605A1 (en) 1997-05-01
WO1997015848A1 (en) 1997-05-01
CN1120378C (zh) 2003-09-03
DE69630804D1 (de) 2003-12-24
JP2010156987A (ja) 2010-07-15
US5812317A (en) 1998-09-22
JP2008096995A (ja) 2008-04-24
CA2234605C (en) 2008-01-29
KR19990066974A (ko) 1999-08-16
CN1200813A (zh) 1998-12-02
EP0857311A1 (en) 1998-08-12
EP0857311B1 (en) 2003-11-19
KR100400909B1 (ko) 2004-03-24
DE69630804T2 (de) 2004-09-23

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