CN1120378C - 含有位于微球层和反射层之间的聚合物中间层的暴露式透镜逆向反射制品 - Google Patents

含有位于微球层和反射层之间的聚合物中间层的暴露式透镜逆向反射制品 Download PDF

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Publication number
CN1120378C
CN1120378C CN96197884A CN96197884A CN1120378C CN 1120378 C CN1120378 C CN 1120378C CN 96197884 A CN96197884 A CN 96197884A CN 96197884 A CN96197884 A CN 96197884A CN 1120378 C CN1120378 C CN 1120378C
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CN
China
Prior art keywords
layer
microsphere
exposed lens
microspheres
reflective products
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Expired - Fee Related
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CN96197884A
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English (en)
Chinese (zh)
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CN1200813A (zh
Inventor
B·G·比林斯利
R·J·弗莱明
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3M Co
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3M Co
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Publication of CN1200813A publication Critical patent/CN1200813A/zh
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Publication of CN1120378C publication Critical patent/CN1120378C/zh
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Outerwear In General, And Traditional Japanese Garments (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Road Signs Or Road Markings (AREA)
CN96197884A 1995-10-26 1996-09-11 含有位于微球层和反射层之间的聚合物中间层的暴露式透镜逆向反射制品 Expired - Fee Related CN1120378C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/548,578 US5812317A (en) 1995-10-26 1995-10-26 Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
US08/548,578 1995-10-26

Publications (2)

Publication Number Publication Date
CN1200813A CN1200813A (zh) 1998-12-02
CN1120378C true CN1120378C (zh) 2003-09-03

Family

ID=24189470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96197884A Expired - Fee Related CN1120378C (zh) 1995-10-26 1996-09-11 含有位于微球层和反射层之间的聚合物中间层的暴露式透镜逆向反射制品

Country Status (8)

Country Link
US (1) US5812317A (enExample)
EP (1) EP0857311B1 (enExample)
JP (3) JPH11513819A (enExample)
KR (1) KR100400909B1 (enExample)
CN (1) CN1120378C (enExample)
CA (1) CA2234605C (enExample)
DE (1) DE69630804T2 (enExample)
WO (1) WO1997015848A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106459352A (zh) * 2014-06-16 2017-02-22 3M创新有限公司 具有耐洗性珠粘结层的回射制品
CN106574993A (zh) * 2014-05-09 2017-04-19 3M创新有限公司 回射制品

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JPH10153701A (ja) 1996-11-19 1998-06-09 Minnesota Mining & Mfg Co <3M> 再帰性反射シート
US6159537A (en) * 1997-08-01 2000-12-12 3M Innovative Properties Company Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer
US6365262B1 (en) 1998-10-20 2002-04-02 3M Innovative Properties Company Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same
US6247818B1 (en) * 1998-10-20 2001-06-19 3M Innovative Properties Company Method for making retroreflective elements having enhanced retroreflectivity under dry and/or wet conditions
US6503564B1 (en) 1999-02-26 2003-01-07 3M Innovative Properties Company Method of coating microstructured substrates with polymeric layer(s), allowing preservation of surface feature profile
US6172810B1 (en) 1999-02-26 2001-01-09 3M Innovative Properties Company Retroreflective articles having polymer multilayer reflective coatings
US6361850B1 (en) * 1999-06-17 2002-03-26 3M Innovative Properties Company Retroreflective article having a colored layer containing a dye covalently bonded to a polymer
CN1179219C (zh) * 1999-06-17 2004-12-08 3M创新有限公司 带有含逆向反射薄片和与聚合物共价键合的染料的着色层的逆向反射制品
US6548164B1 (en) * 1999-06-30 2003-04-15 3M Innovative Properties Company Removable sheeting
KR20010016784A (ko) * 1999-08-03 2001-03-05 최병대 광택 및 반사 특성이 우수한 도금 미소 유리구슬, 그 제조방법
US6696126B1 (en) 1999-08-12 2004-02-24 The United States Of America As Represented By The Secretary Of The Navy Visual-tactile signage
US6966660B1 (en) * 1999-10-15 2005-11-22 3M Innovative Properties Company Article exhibiting dry and wet retroreflectivity
US6416188B1 (en) 2000-04-11 2002-07-09 3M Innovative Properties Company Dielectric mirror retroreflective appliques having excellent repetitive laundering performance
US7540671B2 (en) * 2003-11-17 2009-06-02 Olympus Corporation Variable-power optical system and electronic device using same
US7247386B2 (en) 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
US20050137266A1 (en) * 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements
WO2005066667A1 (en) * 2003-12-30 2005-07-21 3M Innovative Properties Company Color shifting retroreflector and method of making same
US20050208093A1 (en) 2004-03-22 2005-09-22 Thierry Glauser Phosphoryl choline coating compositions
JP2005274983A (ja) * 2004-03-25 2005-10-06 Unitika Sparklite Kk 着色再帰反射媒体中間体とその製造方法および熱転写方法
US20060026731A1 (en) * 2004-08-04 2006-02-09 Reemay, Inc. High visibility fabric and safety vest
US7195360B2 (en) * 2004-12-28 2007-03-27 3M Innovative Properties Company Prismatic retroreflective article and method
KR20130008643A (ko) * 2004-12-28 2013-01-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 불소- 또는 규소-함유 프리즘을 갖는 프리즘 역반사 물품
US7391569B2 (en) * 2004-12-29 2008-06-24 3M Innovative Properties Company Projection system including intrinsic polarizer
US7453634B2 (en) * 2005-03-07 2008-11-18 Avery Dennison Corporation Discontinuous or variable thickness gain modification coating for projection film and method for making same
US7842374B2 (en) * 2006-07-28 2010-11-30 3M Innovative Properties Company Retroreflective article comprising a copolyester ether composition layer and method of making same
US8701441B2 (en) 2006-08-21 2014-04-22 3M Innovative Properties Company Method of making inorganic, metal oxide spheres using microstructured molds
US8120854B2 (en) * 2006-12-28 2012-02-21 3M Innovative Properties Company Interference films having acrylamide layer and method of making same
US7547105B2 (en) * 2007-07-16 2009-06-16 3M Innovative Properties Company Prismatic retroreflective article with cross-linked image layer and method of making same
EP2419243A1 (en) * 2009-04-17 2012-02-22 3M Innovative Properties Company Metal particle transfer article, metal modified substrate, and method of making and using the same
EP2577365B1 (en) 2010-05-25 2021-02-17 3M Innovative Properties Company Exposed lens retroreflective article
TW201315598A (zh) * 2012-10-18 2013-04-16 Cing Wai Kung Mau Company 反光物品製程
WO2014190017A1 (en) * 2013-05-24 2014-11-27 3M Innovative Properties Company Bead-coated sheet
CN105814462B (zh) 2013-10-24 2019-02-22 3M创新有限公司 具有防沾污性质的回射制品
EP3968063A1 (en) * 2014-01-31 2022-03-16 3M Innovative Properties Company Colored retroreflective articles
EP3105048B1 (en) 2014-02-13 2021-06-16 3M Innovative Properties Company Dual cure stain resistant microsphere articles
CN106415336B (zh) 2014-04-30 2020-12-04 3M创新有限公司 防污回射制品
EP3140684A1 (en) 2014-05-09 2017-03-15 3M Innovative Properties Company Colored retroreflective articles
WO2016039820A1 (en) 2014-09-10 2016-03-17 3M Innovative Properties Company Exposed lens retroreflective articles comprising a self-assembled dielectric mirror
US10845514B2 (en) 2014-09-30 2020-11-24 3M Innovative Properties Company Retroreflective colored articles
US10345495B2 (en) 2014-12-30 2019-07-09 3M Innovative Properties Company Stain resistant retroreflective articles
US11207690B2 (en) 2015-12-22 2021-12-28 3M Innovative Properties Company Stem-well films for sample partitioning
US11035760B2 (en) 2015-12-28 2021-06-15 3M Innovative Properties Company Cartridges for sample partitioning
JP6972006B2 (ja) 2016-03-30 2021-11-24 スリーエム イノベイティブ プロパティズ カンパニー ランダムに分散された微小球の所定のパターンを主とする物品及びその製造方法
CN106560734A (zh) * 2016-06-01 2017-04-12 杭州飞像科技有限公司 空中成像元件在提词器中的应用及提词器
CN111263902A (zh) * 2017-10-27 2020-06-09 3M创新有限公司 包括嵌入反射层的回射制品
CN108130746B (zh) * 2017-12-28 2020-07-03 浙江宏成建材有限公司 一种建筑用长效型高分子防水卷材及其制备方法
US20220056320A1 (en) * 2018-12-27 2022-02-24 3M Innovative Properties Company Retroreflective articles containing adhesive compositions including styrenic block co-polymers
EP3959550A4 (en) * 2019-04-25 2023-01-18 3M Innovative Properties Company RETRO-REFLECTIVE ARTICLE INCLUDING MULTIPLE LOCALLY LAMINATED LAYERS

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605461A (en) * 1983-12-15 1986-08-12 Ide Idustries Limited Method of transferring a retroreflective pattern onto a fabric
US5200262A (en) * 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements
US5283101A (en) * 1991-05-08 1994-02-01 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with binder layer comprising electron-beam cured polymer

Family Cites Families (13)

* Cited by examiner, † Cited by third party
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US2326634A (en) * 1941-12-26 1943-08-10 Minnesota Mining & Mfg Reflex light reflector
US2379702A (en) * 1943-01-23 1945-07-03 Minnesota Mining & Mfg Reflex light reflector
US2440584A (en) * 1944-06-19 1948-04-27 Minnesota Mining & Mfg Lenticular reflex reflector sheet and method of making the same
US3190178A (en) * 1961-06-29 1965-06-22 Minnesota Mining & Mfg Reflex-reflecting sheeting
US3573954A (en) * 1967-07-05 1971-04-06 Nihon Koken Co Ltd Reflex-reflectors and method for the manufacture thereof
US3700305A (en) * 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
JPS5483392A (en) * 1977-12-15 1979-07-03 Unitika Ltd Method of transferring glass bead
US4367920A (en) * 1979-10-01 1983-01-11 Minnesota Mining And Manufacturing Company Retroflective sheeting
JPS619601A (ja) * 1984-06-25 1986-01-17 Hitachi Ltd 光学レンズ
US5344705A (en) * 1993-05-05 1994-09-06 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
US5503906A (en) * 1993-05-05 1996-04-02 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
US5514441A (en) * 1994-09-30 1996-05-07 Avery Dennison Corporation Retroreflective sheeting with improved topcoat
CN1119672C (zh) * 1994-11-23 2003-08-27 美国3M公司 含有聚醚聚氨酯粘合剂层的反光制品及其制造方法和用途

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605461A (en) * 1983-12-15 1986-08-12 Ide Idustries Limited Method of transferring a retroreflective pattern onto a fabric
US5283101A (en) * 1991-05-08 1994-02-01 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with binder layer comprising electron-beam cured polymer
US5200262A (en) * 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106574993A (zh) * 2014-05-09 2017-04-19 3M创新有限公司 回射制品
TWI657269B (zh) * 2014-05-09 2019-04-21 3M Innovative Properties Company 反光物品
CN106574993B (zh) * 2014-05-09 2022-07-12 3M创新有限公司 回射制品
CN106459352A (zh) * 2014-06-16 2017-02-22 3M创新有限公司 具有耐洗性珠粘结层的回射制品

Also Published As

Publication number Publication date
JP2008096995A (ja) 2008-04-24
CN1200813A (zh) 1998-12-02
KR100400909B1 (ko) 2004-03-24
KR19990066974A (ko) 1999-08-16
CA2234605A1 (en) 1997-05-01
DE69630804T2 (de) 2004-09-23
CA2234605C (en) 2008-01-29
US5812317A (en) 1998-09-22
JPH11513819A (ja) 1999-11-24
EP0857311B1 (en) 2003-11-19
DE69630804D1 (de) 2003-12-24
EP0857311A1 (en) 1998-08-12
JP2010156987A (ja) 2010-07-15
WO1997015848A1 (en) 1997-05-01

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GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030903

Termination date: 20140911

EXPY Termination of patent right or utility model