JPH0819140B2 - シラアルカン類の製造方法 - Google Patents
シラアルカン類の製造方法Info
- Publication number
- JPH0819140B2 JPH0819140B2 JP3262501A JP26250191A JPH0819140B2 JP H0819140 B2 JPH0819140 B2 JP H0819140B2 JP 3262501 A JP3262501 A JP 3262501A JP 26250191 A JP26250191 A JP 26250191A JP H0819140 B2 JPH0819140 B2 JP H0819140B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- silicon
- copper
- chloromethyl
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 87
- 229910052710 silicon Inorganic materials 0.000 claims description 37
- 239000010703 silicon Substances 0.000 claims description 37
- 239000010949 copper Substances 0.000 claims description 34
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 24
- 229910052802 copper Inorganic materials 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- AZFVLHQDIIJLJG-UHFFFAOYSA-N chloromethylsilane Chemical compound [SiH3]CCl AZFVLHQDIIJLJG-UHFFFAOYSA-N 0.000 claims description 10
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 9
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 9
- 229940045803 cuprous chloride Drugs 0.000 claims description 9
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- DLNFKXNUGNBIOM-UHFFFAOYSA-N methyl(silylmethyl)silane Chemical compound C[SiH2]C[SiH3] DLNFKXNUGNBIOM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- PSEWTUNXEVEVDW-UHFFFAOYSA-N bis(methylsilylmethyl)silane Chemical compound C[SiH2]C[SiH2]C[SiH2]C PSEWTUNXEVEVDW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 34
- 239000007858 starting material Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 239000002994 raw material Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000003756 stirring Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000005481 NMR spectroscopy Methods 0.000 description 7
- ITKVLPYNJQOCPW-UHFFFAOYSA-N chloro-(chloromethyl)-dimethylsilane Chemical compound C[Si](C)(Cl)CCl ITKVLPYNJQOCPW-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- OOCUOKHIVGWCTJ-UHFFFAOYSA-N chloromethyl(trimethyl)silane Chemical compound C[Si](C)(C)CCl OOCUOKHIVGWCTJ-UHFFFAOYSA-N 0.000 description 4
- JAYBZWYBCUJLNQ-UHFFFAOYSA-N dichloro-(chloromethyl)-methylsilane Chemical compound C[Si](Cl)(Cl)CCl JAYBZWYBCUJLNQ-UHFFFAOYSA-N 0.000 description 4
- ASYNIOWQODCHKJ-UHFFFAOYSA-N dichloro-bis[[chloro(dimethyl)silyl]methyl]silane Chemical compound C[Si](C)(Cl)C[Si](Cl)(Cl)C[Si](C)(C)Cl ASYNIOWQODCHKJ-UHFFFAOYSA-N 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- GJIIJSWYRBEOCZ-UHFFFAOYSA-N trichloro-[[chloro(dimethyl)silyl]methyl]silane Chemical compound C[Si](C)(Cl)C[Si](Cl)(Cl)Cl GJIIJSWYRBEOCZ-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- -1 silane compound Chemical class 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ABVUXBPCPLBFHM-UHFFFAOYSA-N trichloro-[[dichloro(methyl)silyl]methyl]silane Chemical compound C[Si](Cl)(Cl)C[Si](Cl)(Cl)Cl ABVUXBPCPLBFHM-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- WOKKVRNACWFIBX-UHFFFAOYSA-N CC(C)([SiH2][Si](Cl)(Cl)Cl)Cl Chemical compound CC(C)([SiH2][Si](Cl)(Cl)Cl)Cl WOKKVRNACWFIBX-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229910018594 Si-Cu Inorganic materials 0.000 description 1
- 229910008465 Si—Cu Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- FEJIRWLJFCIPJX-UHFFFAOYSA-N dichloro-bis(trimethylsilylmethyl)silane Chemical compound C[Si](C)(C)C[Si](Cl)(Cl)C[Si](C)(C)C FEJIRWLJFCIPJX-UHFFFAOYSA-N 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- JOTSLPSOZKUZIU-UHFFFAOYSA-N trichloro(trimethylsilylmethyl)silane Chemical compound C[Si](C)(C)C[Si](Cl)(Cl)Cl JOTSLPSOZKUZIU-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/123—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-halogen linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR91001055A KR940007416B1 (en) | 1991-01-22 | 1991-01-22 | Process for the preparation of silaalkane |
| KR1055/1991 | 1991-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06340676A JPH06340676A (ja) | 1994-12-13 |
| JPH0819140B2 true JPH0819140B2 (ja) | 1996-02-28 |
Family
ID=19310168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3262501A Expired - Fee Related JPH0819140B2 (ja) | 1991-01-22 | 1991-09-17 | シラアルカン類の製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5075477A (enExample) |
| JP (1) | JPH0819140B2 (enExample) |
| KR (1) | KR940007416B1 (enExample) |
| DE (1) | DE4111822C1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940010290B1 (ko) * | 1991-12-24 | 1994-10-22 | 한국과학기술연구원 | 비스실릴메탄 및 그들의 제조방법 |
| KR940010291B1 (ko) * | 1992-01-23 | 1994-10-22 | 한국과학기술연구원 | 비스실릴알칸 및 그들의 제조방법 |
| KR950002860B1 (ko) * | 1992-06-13 | 1995-03-27 | 한국과학기술연구원 | 클로로알켄닐실란들과그제조방법 |
| US5296624A (en) * | 1992-11-25 | 1994-03-22 | Huls America, Inc. | Preparation of sterically-hindered organosilanes |
| KR950011359B1 (ko) * | 1993-02-18 | 1995-10-02 | 한국과학기술연구원 | I-아릴-i-[알파-(트리아졸릴)알킬]-i-실라시클로알칸 및 이들의 제조방법 |
| KR970010592B1 (ko) * | 1993-12-01 | 1997-06-28 | 한국과학기술연구원 | 2-아릴프로필히드로겐폴리실록산 형태의 실리콘 오일 및 그의 제조방법 |
| KR0141464B1 (ko) * | 1993-12-01 | 1998-07-01 | 김은영 | 알릴알킬실란 화합물 및 그의 제조방법 |
| KR970010593B1 (ko) * | 1993-12-01 | 1997-06-28 | 한국과학기술연구원 | 2-아릴프로필알킬폴리실록산 형태의 실리콘 오일 및 그의 제조방법 |
| KR0134564B1 (ko) * | 1993-12-07 | 1998-04-20 | 김은영 | 알릴알킬실록산과 디오르가노실록산 공중합 형태의 실리콘 오일 및 그 제조 방법 |
| US5399740A (en) * | 1993-12-10 | 1995-03-21 | Korea Institute Of Science And Technology | Tris(silyl)methanes and their preparation methods |
| US5527938A (en) * | 1994-07-19 | 1996-06-18 | Korea Institute Of Science And Technology | (2-arylpropyl)silanes and preparation methods thereof |
| US6730802B2 (en) | 2002-07-09 | 2004-05-04 | Starfire Systems, Inc. | Silicon carbide precursor |
| KR20050024721A (ko) * | 2003-09-01 | 2005-03-11 | 삼성전자주식회사 | 신규 실록산계 수지 및 이를 이용한 반도체 층간 절연막 |
| JP2008060117A (ja) * | 2006-08-29 | 2008-03-13 | Konica Minolta Holdings Inc | 有機薄膜トランジスタ及びその製造方法 |
| KR100928942B1 (ko) * | 2008-05-26 | 2009-11-30 | 제이에스아이실리콘주식회사 | 직선형이나 고리형의 트리실라알칸의 제조방법 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2511812A (en) * | 1947-07-01 | 1950-06-13 | Alkylsilahydrocabbons | |
| US3527781A (en) * | 1967-09-01 | 1970-09-08 | Dow Corning | Disilacyclobutanes |
| GB1575890A (en) * | 1978-03-31 | 1980-10-01 | Thorn Electrical Ind Ltd | Heating of dosing capsule |
| US5026893A (en) * | 1990-06-11 | 1991-06-25 | Lubricating Specialties Company | Polysilahydrocarbon lubricants |
-
1991
- 1991-01-22 KR KR91001055A patent/KR940007416B1/ko not_active Expired - Fee Related
- 1991-04-11 DE DE4111822A patent/DE4111822C1/de not_active Expired - Lifetime
- 1991-05-08 US US07/697,165 patent/US5075477A/en not_active Expired - Lifetime
- 1991-09-17 JP JP3262501A patent/JPH0819140B2/ja not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| Ｊ．ＧＥＮ．ＣＨＥＭ．ＵＳＳＲ，４２（１９７２），１３５４−１３５７． |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4111822C1 (enExample) | 1992-04-02 |
| KR920014821A (ko) | 1992-08-25 |
| JPH06340676A (ja) | 1994-12-13 |
| KR940007416B1 (en) | 1994-08-18 |
| US5075477A (en) | 1991-12-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |