JPH0578384B2 - - Google Patents

Info

Publication number

JPH0578384B2

JPH0578384B2 JP62325584A JP32558487A JPH0578384B2 JP H0578384 B2 JPH0578384 B2 JP H0578384B2 JP 62325584 A JP62325584 A JP 62325584A JP 32558487 A JP32558487 A JP 32558487A JP H0578384 B2 JPH0578384 B2 JP H0578384B2

Authority

JP

Japan

Prior art keywords

catalyst

activated alumina

weight

nickel oxide

exhaust gas

Prior art date

1987-12-24

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

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• 239000003054 catalyst Substances 0.000 claims description 48
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 35
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
• GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 21
• 239000007789 gas Substances 0.000 claims description 20
• 229910000480 nickel oxide Inorganic materials 0.000 claims description 18
• 239000010948 rhodium Substances 0.000 claims description 18
• 229910000420 cerium oxide Inorganic materials 0.000 claims description 13
• 229910000510 noble metal Inorganic materials 0.000 claims description 13
• BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 13
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
• 229910052697 platinum Inorganic materials 0.000 claims description 8
• 229910052703 rhodium Inorganic materials 0.000 claims description 7
• 239000000203 mixture Substances 0.000 claims description 6
• 238000000746 purification Methods 0.000 claims description 6
• MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 5
• RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
• 229910052763 palladium Inorganic materials 0.000 claims description 4
• 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 3
• CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 2
• 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 2
• 230000019086 sulfide ion homeostasis Effects 0.000 claims 1
• MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
• 238000000034 method Methods 0.000 description 7
• 239000000843 powder Substances 0.000 description 7
• 239000002002 slurry Substances 0.000 description 7
• 229910052815 sulfur oxide Inorganic materials 0.000 description 7
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
• 239000007864 aqueous solution Substances 0.000 description 6
• 229910002091 carbon monoxide Inorganic materials 0.000 description 6
• 239000000446 fuel Substances 0.000 description 6
• 229930195733 hydrocarbon Natural products 0.000 description 6
• 150000002430 hydrocarbons Chemical class 0.000 description 6
• 238000002485 combustion reaction Methods 0.000 description 5
• 230000000052 comparative effect Effects 0.000 description 5
• 230000000694 effects Effects 0.000 description 5
• 238000006722 reduction reaction Methods 0.000 description 5
• 238000011156 evaluation Methods 0.000 description 4
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
• GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
• 238000005259 measurement Methods 0.000 description 3
• 229910017604 nitric acid Inorganic materials 0.000 description 3
• 238000011160 research Methods 0.000 description 3
• VXNYVYJABGOSBX-UHFFFAOYSA-N rhodium(3+);trinitrate Chemical compound [Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VXNYVYJABGOSBX-UHFFFAOYSA-N 0.000 description 3
• YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
• 239000003153 chemical reaction reagent Substances 0.000 description 2
• 239000011248 coating agent Substances 0.000 description 2
• 238000000576 coating method Methods 0.000 description 2
• 238000001035 drying Methods 0.000 description 2
• 229910052759 nickel Inorganic materials 0.000 description 2
• 238000007254 oxidation reaction Methods 0.000 description 2
• 239000000243 solution Substances 0.000 description 2
• 238000001179 sorption measurement Methods 0.000 description 2
• 150000003464 sulfur compounds Chemical class 0.000 description 2
• RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
• 229910018590 Ni(NO3)2-6H2O Inorganic materials 0.000 description 1
• 229910018967 Pt—Rh Inorganic materials 0.000 description 1
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
• FQRNHGHJKMFHQN-UHFFFAOYSA-N [Pt].[O-][N+](=O)N[N+]([O-])=O Chemical compound [Pt].[O-][N+](=O)N[N+]([O-])=O FQRNHGHJKMFHQN-UHFFFAOYSA-N 0.000 description 1
• 238000002835 absorbance Methods 0.000 description 1
• 239000000654 additive Substances 0.000 description 1
• 230000000996 additive effect Effects 0.000 description 1
• 230000002411 adverse Effects 0.000 description 1
• 239000006255 coating slurry Substances 0.000 description 1
• 229910052878 cordierite Inorganic materials 0.000 description 1
• JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
• 239000006185 dispersion Substances 0.000 description 1
• 238000010304 firing Methods 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 230000001771 impaired effect Effects 0.000 description 1
• 238000011068 loading method Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 229960000907 methylthioninium chloride Drugs 0.000 description 1
• KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 229910052717 sulfur Inorganic materials 0.000 description 1
• 239000011593 sulfur Substances 0.000 description 1
• XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
• 238000010998 test method Methods 0.000 description 1
• 238000012360 testing method Methods 0.000 description 1
• 229930192474 thiophene Natural products 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
• 238000001238 wet grinding Methods 0.000 description 1