JPH0528721B2 - - Google Patents
Info
- Publication number
- JPH0528721B2 JPH0528721B2 JP63115930A JP11593088A JPH0528721B2 JP H0528721 B2 JPH0528721 B2 JP H0528721B2 JP 63115930 A JP63115930 A JP 63115930A JP 11593088 A JP11593088 A JP 11593088A JP H0528721 B2 JPH0528721 B2 JP H0528721B2
- Authority
- JP
- Japan
- Prior art keywords
- beads
- catalyst
- vitreous
- filling material
- polymerizable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 157
- 239000011324 bead Substances 0.000 claims description 151
- 239000003054 catalyst Substances 0.000 claims description 76
- 238000000034 method Methods 0.000 claims description 45
- 239000000945 filler Substances 0.000 claims description 43
- 229920000642 polymer Polymers 0.000 claims description 32
- 238000011049 filling Methods 0.000 claims description 28
- 239000011159 matrix material Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 18
- 150000002978 peroxides Chemical class 0.000 claims description 16
- 238000012856 packing Methods 0.000 claims description 15
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 11
- 239000000834 fixative Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- -1 methoxysilyl groups Chemical group 0.000 claims description 9
- 150000002902 organometallic compounds Chemical class 0.000 claims description 8
- 239000002685 polymerization catalyst Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 238000005530 etching Methods 0.000 claims description 7
- 150000001844 chromium Chemical class 0.000 claims description 5
- 239000011256 inorganic filler Substances 0.000 claims description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 150000004756 silanes Chemical class 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 150000003608 titanium Chemical class 0.000 claims description 4
- 229920006305 unsaturated polyester Polymers 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 description 42
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 13
- 229910000077 silane Inorganic materials 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 239000004342 Benzoyl peroxide Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 238000002310 reflectometry Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- LDDQLRUQCUTJBB-UHFFFAOYSA-O azanium;hydrofluoride Chemical compound [NH4+].F LDDQLRUQCUTJBB-UHFFFAOYSA-O 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000003100 immobilizing effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002991 molded plastic Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU86880A LU86880A1 (fr) | 1987-05-14 | 1987-05-14 | Microbilles de verre destinees a etre mises en contact avec des matieres polymerisables;procede de traitement de microbilles de verre pour les rendre aptes a un tel usage et procede de polymerisation faisant appel a de telles microbilles |
| LU86880 | 1987-05-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63309429A JPS63309429A (ja) | 1988-12-16 |
| JPH0528721B2 true JPH0528721B2 (it) | 1993-04-27 |
Family
ID=19730925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63115930A Granted JPS63309429A (ja) | 1987-05-14 | 1988-05-11 | 充填材料を含有するポリマーマトリツクス形成方法、かく形成されたポリマーマトリツクス及びポリマーマトリツクス用充填材料 |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS63309429A (it) |
| AT (1) | AT398575B (it) |
| BE (1) | BE1000981A5 (it) |
| DE (1) | DE3816038A1 (it) |
| DK (1) | DK174215B1 (it) |
| ES (1) | ES2006989A6 (it) |
| FR (1) | FR2615195B1 (it) |
| GB (1) | GB2208078B (it) |
| IT (1) | IT1219264B (it) |
| LU (1) | LU86880A1 (it) |
| NL (1) | NL190583C (it) |
| PT (1) | PT87463B (it) |
| SE (1) | SE470133B (it) |
| ZA (1) | ZA883383B (it) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3910105A1 (de) * | 1989-03-29 | 1990-10-04 | Hilti Ag | Fuellstoffbeschichtung |
| FR2699694B1 (fr) * | 1992-12-21 | 1995-01-20 | Thomson Csf | Dispositif rétroréflecteur et système d'identification. |
| GB2273923B (en) * | 1993-01-04 | 1996-09-25 | Glaverbel | Apparatus for the distribution of particulate material upon a surface |
| US5370818A (en) * | 1993-05-28 | 1994-12-06 | Potters Industries, Inc. | Free-flowing catalyst coated beads for curing polyester resin |
| US6908954B2 (en) * | 2000-08-09 | 2005-06-21 | Brushstrokes Fine Art Inc. | Coating composition for artistic reproductions |
| TR201411519A2 (tr) | 2014-09-30 | 2016-04-21 | Tuerkiye Bilimsel Ve Teknolojik Arastirma Kurumu Tuebitak | Yol çizgi boyalarında retroreflektif malzeme olarak kullanılan cam kürelerin doğal bir ürün olan kil ile kaplanarak yüzey özelliklerinin iyileştirilmesi. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5525400A (en) * | 1978-08-04 | 1980-02-23 | Elkem Spigerverket As | Preparation of thermal hardening fiber reinforcing plastic |
| JPS5573524A (en) * | 1978-11-30 | 1980-06-03 | Dainippon Ink & Chem Inc | Production of reinforced plastic |
| JPS5796822A (en) * | 1980-12-08 | 1982-06-16 | Hitachi Chem Co Ltd | Manufacture of prepreg sheet |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD74344A (it) * | ||||
| US2897732A (en) * | 1955-12-22 | 1959-08-04 | Baltimore Paint & Color Works | Highway marker comprising unsaturated alkyd resin and glass beads and method of making same |
| FR1461257A (fr) * | 1964-12-23 | 1966-12-10 | Ici Ltd | Compositions polymères thermoplastiques contenant des matières de charge minérales |
| US3429855A (en) * | 1966-08-29 | 1969-02-25 | Allied Chem | Novel organic polyol compositions and filled non-cellular polyurethanes prepared therefrom |
| DE1595441A1 (de) * | 1966-08-31 | 1970-07-16 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Polybuten-1 mit verbesserten Eigenschaften |
| BE701284A (it) * | 1967-07-12 | 1967-12-18 | ||
| US3519594A (en) * | 1967-11-09 | 1970-07-07 | Amicon Corp | Coated asbestos and method of making and using same |
| US3640920A (en) * | 1969-05-21 | 1972-02-08 | Atlas Chem Ind | Rigid low-density filled cellular polyurethanes |
| DE2363012C3 (de) * | 1973-12-19 | 1979-11-15 | Peter Dipl.-Ing. Dr.-Ing. 7418 Metzingen Eyerer | Verfahren zum Herstellen eines Kunststoffes durch chemische Reaktion |
| US4170589A (en) * | 1978-02-22 | 1979-10-09 | Union Carbide Corporation | Catalytic polymerization of ethylene with supported chromium [II] catalyst in the presence of a phenolic antioxidant |
| JPS5529522A (en) * | 1978-08-23 | 1980-03-01 | Inst Khim Fiz An Sssr | Method of forming polymer coating |
| GB8508093D0 (en) * | 1985-03-28 | 1985-05-01 | Glaverbel | Modifying wettability of glass beads |
| JPS61252216A (ja) * | 1985-04-19 | 1986-11-10 | Mitsubishi Petrochem Co Ltd | 複合樹脂の製造法 |
-
1987
- 1987-05-14 LU LU86880A patent/LU86880A1/fr unknown
-
1988
- 1988-05-06 IT IT67411/88A patent/IT1219264B/it active
- 1988-05-06 FR FR888806334A patent/FR2615195B1/fr not_active Expired - Lifetime
- 1988-05-06 GB GB8810801A patent/GB2208078B/en not_active Expired - Lifetime
- 1988-05-09 SE SE8801750A patent/SE470133B/sv not_active IP Right Cessation
- 1988-05-10 AT AT0122788A patent/AT398575B/de not_active IP Right Cessation
- 1988-05-10 DE DE3816038A patent/DE3816038A1/de active Granted
- 1988-05-10 BE BE8800536A patent/BE1000981A5/fr not_active IP Right Cessation
- 1988-05-11 JP JP63115930A patent/JPS63309429A/ja active Granted
- 1988-05-12 ES ES8801918A patent/ES2006989A6/es not_active Expired
- 1988-05-12 PT PT87463A patent/PT87463B/pt not_active IP Right Cessation
- 1988-05-13 DK DK198802650A patent/DK174215B1/da not_active IP Right Cessation
- 1988-05-13 NL NL8801249A patent/NL190583C/xx not_active IP Right Cessation
- 1988-05-13 ZA ZA883383A patent/ZA883383B/xx unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5525400A (en) * | 1978-08-04 | 1980-02-23 | Elkem Spigerverket As | Preparation of thermal hardening fiber reinforcing plastic |
| JPS5573524A (en) * | 1978-11-30 | 1980-06-03 | Dainippon Ink & Chem Inc | Production of reinforced plastic |
| JPS5796822A (en) * | 1980-12-08 | 1982-06-16 | Hitachi Chem Co Ltd | Manufacture of prepreg sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3816038A1 (de) | 1988-12-08 |
| PT87463B (pt) | 1992-09-30 |
| ATA122788A (de) | 1994-05-15 |
| NL190583B (nl) | 1993-12-01 |
| DK265088A (da) | 1988-11-15 |
| GB2208078B (en) | 1991-07-03 |
| DK265088D0 (da) | 1988-05-13 |
| FR2615195B1 (fr) | 1992-01-10 |
| IT1219264B (it) | 1990-05-03 |
| JPS63309429A (ja) | 1988-12-16 |
| DK174215B1 (da) | 2002-09-23 |
| DE3816038C2 (it) | 1992-01-02 |
| LU86880A1 (fr) | 1989-01-19 |
| SE470133B (sv) | 1993-11-15 |
| SE8801750L (sv) | 1988-11-15 |
| IT8867411A0 (it) | 1988-05-06 |
| NL8801249A (nl) | 1988-12-01 |
| BE1000981A5 (fr) | 1989-05-30 |
| FR2615195A1 (fr) | 1988-11-18 |
| NL190583C (nl) | 1994-05-02 |
| ES2006989A6 (es) | 1989-05-16 |
| AT398575B (de) | 1994-12-27 |
| ZA883383B (it) | 1988-11-14 |
| GB2208078A (en) | 1989-02-22 |
| GB8810801D0 (en) | 1988-06-08 |
| PT87463A (pt) | 1989-05-31 |
| SE8801750D0 (sv) | 1988-05-09 |
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