JPH0469952B2 - - Google Patents
Info
- Publication number
- JPH0469952B2 JPH0469952B2 JP61186960A JP18696086A JPH0469952B2 JP H0469952 B2 JPH0469952 B2 JP H0469952B2 JP 61186960 A JP61186960 A JP 61186960A JP 18696086 A JP18696086 A JP 18696086A JP H0469952 B2 JPH0469952 B2 JP H0469952B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum phthalocyanine
- weight
- degrees
- water
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HUVXQFBFIFIDDU-UHFFFAOYSA-N aluminum phthalocyanine Chemical group [Al+3].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 HUVXQFBFIFIDDU-UHFFFAOYSA-N 0.000 claims description 42
- 108091008695 photoreceptors Proteins 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 17
- 230000004580 weight loss Effects 0.000 claims description 10
- 238000000862 absorption spectrum Methods 0.000 claims description 8
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000003960 organic solvent Substances 0.000 description 18
- 239000013078 crystal Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 9
- 238000000859 sublimation Methods 0.000 description 9
- 230000008022 sublimation Effects 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- 238000007740 vapor deposition Methods 0.000 description 5
- LCQDONOHGZLBOL-UHFFFAOYSA-N 2,6-dimethoxyanthracene-9,10-diol Chemical compound C1=C(OC)C=CC2=C(O)C3=CC(OC)=CC=C3C(O)=C21 LCQDONOHGZLBOL-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- JPOXNPPZZKNXOV-UHFFFAOYSA-N bromochloromethane Chemical compound ClCBr JPOXNPPZZKNXOV-UHFFFAOYSA-N 0.000 description 4
- SOGXWMAAMKKQCB-UHFFFAOYSA-M chloroalumane Chemical compound Cl[AlH2] SOGXWMAAMKKQCB-UHFFFAOYSA-M 0.000 description 4
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004431 polycarbonate resin Substances 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- AVGQTJUPLKNPQP-UHFFFAOYSA-N 1,1,1-trichloropropane Chemical compound CCC(Cl)(Cl)Cl AVGQTJUPLKNPQP-UHFFFAOYSA-N 0.000 description 1
- JFJWVJAVVIQZRT-UHFFFAOYSA-N 2-phenyl-1,3-dihydropyrazole Chemical class C1C=CNN1C1=CC=CC=C1 JFJWVJAVVIQZRT-UHFFFAOYSA-N 0.000 description 1
- MNFZZNNFORDXSV-UHFFFAOYSA-N 4-(diethylamino)benzaldehyde Chemical compound CCN(CC)C1=CC=C(C=O)C=C1 MNFZZNNFORDXSV-UHFFFAOYSA-N 0.000 description 1
- YGBCLRRWZQSURU-UHFFFAOYSA-N 4-[(diphenylhydrazinylidene)methyl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C=NN(C=1C=CC=CC=1)C1=CC=CC=C1 YGBCLRRWZQSURU-UHFFFAOYSA-N 0.000 description 1
- JDUKORYFKBOOBJ-UHFFFAOYSA-N 4-[2-[3-[4-(diethylamino)phenyl]-1,3-dihydropyrazol-2-yl]ethenyl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C=CN1C(C=2C=CC(=CC=2)N(CC)CC)C=CN1 JDUKORYFKBOOBJ-UHFFFAOYSA-N 0.000 description 1
- UZGVMZRBRRYLIP-UHFFFAOYSA-N 4-[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NN=C(C=2C=CC(=CC=2)N(CC)CC)O1 UZGVMZRBRRYLIP-UHFFFAOYSA-N 0.000 description 1
- PCFMUWBCZZUMRX-UHFFFAOYSA-N 9,10-Dihydroxyanthracene Chemical compound C1=CC=C2C(O)=C(C=CC=C3)C3=C(O)C2=C1 PCFMUWBCZZUMRX-UHFFFAOYSA-N 0.000 description 1
- 229910016523 CuKa Inorganic materials 0.000 description 1
- 239000004420 Iupilon Substances 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- QLNFINLXAKOTJB-UHFFFAOYSA-N [As].[Se] Chemical class [As].[Se] QLNFINLXAKOTJB-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- -1 hydrazone compounds Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- JGOAZQAXRONCCI-SDNWHVSQSA-N n-[(e)-benzylideneamino]aniline Chemical compound C=1C=CC=CC=1N\N=C\C1=CC=CC=C1 JGOAZQAXRONCCI-SDNWHVSQSA-N 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0696—Phthalocyanines
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯ãç¹å®ããããã¿ãã·ã¢ãã³çµæ¶ãã
ã³ãããé»è·çºçå€ãšããŠçšããé»ååççšæå
äœã«ä¿ããã®ã§ããã æ¬çºæã®ç®çã¯ãé»è·çºçèœãåªããé»è·çºç
å€ãšããŠæå¹ãªå€æ§ãããå¡©çŽ åã¢ã«ãããŠã ã
ã¿ãã·ã¢ãã³çµæ¶ãæäŸããããšãããã³ããã
é»è·çºçå€ãšãé»è·ç§»åå€ãšçµåããæ§èœã®åªã
ãé»ååççšæå äœãæäŸããããšã«ããã ïŒåŸæ¥ã®æè¡ïŒ é»ååççšæå äœã¯ã«ãŒã«ãœã³ã®çºæ以æ¥ãå€
ãã®æå äœãéçºãããè€åæ©ãåç補çãããª
ã³ã¿ãªã©å€ãã®åéã«ãããŠäœ¿çšãããŠãããç¹
ã«æè¿ããªã³ã¿åéãžã®å±éãèããããã®ãã¡
ç¹ã«åå°äœã¬ãŒã¶ãŒã®å æºã«é©åãããšå ±ã«ãä»
ã®å æºãäŸãã°ãçºå ãã€ãªãŒããHeïŒNeã¬ã¹
ã¬ãŒã¶ãŒã®å æºã«é©åãããããªå€ç®çé»ååç
çšæå äœãèŠæãããŠããã ãã®ãããªèŠæã«å¿ããæå äœãšããŠãç¡æ©ç³»
ããã³ææ©ç³»ã®åçš®ã®æå äœãèæ¡ãããŠããã
ç¡æ©ç³»æå äœãšããŠã¯ãã¢ã¢ã«ãã¢ã¹ã·ãªã³ã³ã
ã»ã¬ã³âãã«ã«ååç©ãã»ã¬ã³âç çŽ ååç©ãªã©
ãç¥ãããŠãããææ©ç³»æå äœãšããŠã¯ãé»è·çº
çå€ãšããŠãã¿ãã·ã¢ãã³é¡ãçž®åå€ç°ååç©ã
ã¢ãŸç³»é¡æããã³ä»ã®è²çŽ é¡ãªã©ã䜿çšãããã
ãšçš®ã ã®é»è·ç§»åå€ãšãçµåãããã®ãç¥ãããŠ
ããã ãããã®æå äœã®ãã¡ãç¹ã«åå°äœã¬ãŒã¶ãŒã®
å æºã«é©åããããã«ã¯ãåå°äœã¬ãŒã¶ãŒå ãå¹
çããåžåããé»è·çºççã®åªããé»è·çºçå€ã
èŠæ±ãããã ææ©å é»å°äœã®äžã€ã§ãããã¿ãã·ã¢ãã³é¡
ã¯ãä»ã®å é»å°äœã«æ¯ã¹åžåæ³¢é·ãé·æ³¢é·ãŸã§äŒž
ã³ãŠãããé»è·çºçèœãåªããŠããããšããå®çš
åã®äŸãå€ãã ãã¿ãã·ã¢ãã³é¡ãçšããæå äœã«ãããŠç¹ã«
泚ç®ãã¹ãããšã¯ããã¿ãã·ã¢ãã³é¡ãé»è·çºç
å€ãšããŠäœ¿çšããéã«ã¯ããããç¹å®ã®çµæ¶äœã®
圢ã§äœ¿çšããããšã§ããã äŸãã°ãåãã¡ã¿ã«ããªãŒãã¿ãã·ã¢ãã³ã䜿
çšããã«ããç¹å ¬æ49â4338å·ã«è¿°ã¹ãããŠãã
ãããªïŒžåãããç¹éæ58â182639å·ã«ç€ºãããŠ
ãããããªÏãηåãããã«ã¯J.phys. ChemïŒ
27ã3230ïŒ1968ïŒã«è¿°ã¹ãããŠããαãβåãªã©
æ§ã ãªçµæ¶åãç¥ãããŠããããŸããé ãã¿ãã·
ã¢ãã³ã«ã€ããŠããç¹å ¬æ52â1667å·ã«è¿°ã¹ãã
ãŠããεåãããã«ã¯ãαãβãγãÏãÏãÏ
ãªã©ã®çµæ¶åãç¥ãããŠããããã®çµæ¶åã®éã
ãå é»å°æ§ã«éããããããããšãç¥ãããŠã
ãããã®ããããã¿ãã·ã¢ãã³é¡ãæå äœã®é»è·
çºçå€ãšããŠäœ¿çšããã«ã¯ããã®çµæ¶æ§é ãæ£ç¢º
ã«ç¹å®ããæå¹ãªçµæ¶æ§é ãå«ãŸãããã¿ãã·ã¢
ãã³ã䜿çšããªããã°ãªããªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ æ¬çºæè ãã¯ãå ã«ã¯ãã«ã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ããªããé»è·çºçå€ãšããé»ååççš
æå äœã«ã€ããŠæ€èšããçµæã該ãã¿ãã·ã¢ãã³
ã¯ããããèžçèèã®ãŸãŸããããã¯æè¯ç²Ÿè£œã
ã埮ç²åã®åæ£å¡èã®ãŸãŸã§ã¯é»è·çºçèœãäœ
ãããã¿ãã·ã¢ãã³ã«å¯Ÿã芪åæ§ã®ãã溶å€ãäŸ
ãã°ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ãé ¢é ž
ãšãã«ãšã¹ãã«ãã¡ãã«ãšãã«ã±ãã³çã®æº¶å€äž
ã§åŠçããããšã«ãããç¹ç°ã®ïŒžç·åæããã€ã¯
ãã«ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã¯ããªããåŸã
ããããã極ããŠåªããé»è·çºçèœã瀺ãããšã
èŠãåºããïŒç¹éæ58â209748å·ïŒã ããããå®éã«ãã®ãããªæäœãè¡ãªã€ãŠåŸã
ããæå äœã®æ§èœã¯éåžžã«ãã©ãããå€ããç¹æ§
ããªããªãäžå®ããªãã®ãå®æ ã§ãã€ãããŸãã
åæžé²å æ床ãé«ããã®ããæ®çé»äœïŒE1ïŒïŒïŒ
ãé«ããå®éã«å°åããæã«ãã¶ããçãããšã
ãæ¬ ç¹ããã€ãã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ æ¬çºæè ãã¯ãäžèšæ¬ ç¹ãæ¹è¯ããããéææ€
èšããçµæã該ãã¿ãã·ã¢ãã³ã®é»è·çºçèœã¯ã
åã«çµæ¶åã®ã¿ã«ããåŸããããã®ã§ã¯ãªãããš
ãçºèŠããé»è·çºçå€ãšããŠæå¹ãª AlC32N8H(17-X)ClXïŒïœïŒ1.0ã3.0ïŒã§ç€ºãããå¡©
çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®æ°ããå€æ§çµ
æ¶äœã®éçºã«æåããæ¬çºæãå®æããã«å°ã€
ãã ããªãã¡ãæ¬çºæè ãã¯ãå¡©çŽ åã¢ã«ãããŠã
ãã¿ãã·ã¢ãã³ã®çµæ¶åãããããšãªããããã®
çµæ¶äžã«å«ãŸãã140âã§ã®æ®çºæåéãéèŠãª
åãã瀺ãããšãèŠãåºãããã®æ®çºæåéãšæ
å äœç¹æ§ã®é¢ä¿ã詳现ã«æ€èšããçµæãç±å€©ç§€ã§
æ¯åïŒâã§ææž©ããæã®140âãã220âãŸã§ã®é
éæžå°çãä»èŸŒã¿ééã®6.0±0.5ïŒ ã®æãå§ããŠ
åªããé»è·çºçå€ãšããŠäœçšããããšãèŠãåº
ããããã«ããã®æ®çºæåéã¯ãåŠçãè¡ãªãæ
æ©æº¶å€äžã®æ°Žåéã«ããã³ã³ãããŒã«ã§ããããš
ãèŠãåºããæ¬çºæãå®æããã«å°ã€ãã®ã§ã
ãã æ¬çºæã«çšããããAlC32N8H(17-X)ClXïŒïœïŒ
1.0ã3.0ïŒã§ç€ºãããå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ããªã«ããã¿ããžãããªã«ãšå¡©åã¢ã«
ãããŠã ãç¡æº¶åªã§å ç±äžã«çž®ååå¿ãèµ·ãã
ãã容æã«åæããããšãã§ããããã®ããã«ã
ãŠåŸãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ãææ©æº¶å€ããã³æ°Žã«ããæŽæµãç¹°ãè¿ããŠç²Ÿ
補ããããã«ãæè¯ç²Ÿè£œã«ãã埮éã®äžçŽç©ãé€
å»ãããã®ãçšãããæ¬çºæã«ãããç¹å®ã®å¡©çŽ
åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãé»è·çºçå€ãšã
ãŠçšããã«ã¯ãæè¯ç²Ÿè£œã«ããåŸããããããã
ã¯èžçã«ããåŸãããå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ãææ©æº¶å€ã«ããåŠçããããšã«ãã€ãŠ
åŸãããAlC32N8H(17-X)ClXã«ãããŠïœïŒ1.0ãã
ïœïŒ3.0ã®éã§ããã®å¹æã«å·®ã¯èŠãããªãã ããã§ã溶å€åŠçã«çšããææ©æº¶å€ã¯ãå¡©çŽ å
ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã«å¯ŸããŠèŠªåæ§ã¯ã
ããã溶解床ãããŸãé«ããªã溶å€ãäŸãã°ãã
ã«ãšã³ããã·ã¬ã³ãé ¢é žãšãã«ããžã¯ãã«ã¡ã¿
ã³ãã¯ãããã«ã ãã¯ãã«ããã ã¡ã¿ã³ãããã
ãšã¿ã³çãããã溶解床ãé«ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãããã©ããããã©ã³çã¯ãå¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³ã溶解ããæå¹ãªçµæ¶åãš
ãªããªããã奜ãŸãããªããããã«ã溶å€åŠçã«
çšããææ©æº¶å€ã«ã¯ãå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ïŒåååœãïŒåå以äžã®æ°Žã溶解ããç¶
æ ã§å«ãŸããããã«ã溶å€éããã³å¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³éã調æŽãã溶å€åŠçãè¡
ãªãã 次ã«ãæå äœã®äœæã«ã€ããŠè©³çŽ°ã«è¿°ã¹ãã ææ©æº¶å€ã«ããåŠçãããå¡©çŽ åã¢ã«ãããŠã
ãã¿ãã·ã¢ãã³ã¯ãææ©æº¶å€ã«å«ãŸããæ°Žåéã«
ãããããªãããã®ïŒžç·åæå³ã¯ç¬¬ïŒå³ã«ç€ºãã
ãã«ã2Ξ±0.2床ã6.7床ã11.2床ã16.7床ã25.6床
ã«åŒ·ãåæããŒã¯ãèŠãããæè¯ç²Ÿè£œãããã®ã
ãçµæ¶åãå€åããããšã瀺ããããããããåŠ
çãè¡ãªãææ©æº¶å€äžã«å«ãŸããæ°Žåéããå¡©çŽ
åã¢ã«ãããŠã ãã¢ãã·ã¢ãã³ïŒååã«å¯ŸãïŒå
åæªæºã«ããå Žåã¯ããã¿ãã·ã¢ãã³ãç±å€©ç§€
ãã»ã€ã³ãŒé»åå·¥æ¥(æ ª)補TGïŒDTA30ãã«ããæ¯
åïŒâã§ææž©ããæã®140âãã220âãŸã§ã®éé
æžå°çããä»èŸŒã¿ééã®6.0±0.5ïŒ æªæºã§ããã
æå äœãšããŠé«æ§èœãåŸãããªããå¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒåå以äžã®
æ°Žãææ©æº¶å€ã«å«ãŸããŠæº¶å€åŠçãããæã®ã¿ã
ç±å€©ç§€ã§æ¯åïŒâã§ææž©ããæã®140âãã220â
ãŸã§ã®ééæžå°çããä»èŸŒã¿ééã®6.0±0.5ïŒ ã«
ãªããæå äœãšããŠé«æ§èœãåŸãããã ããã§ãææ©æº¶å€ã«å«ãŸããæ°Žã¯ãå¡©çŽ åã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒåå以äž
å¿ èŠã§ãããããã®éãææ©æº¶å€ã®é£œåæ°Žåé以
äžãšãªãã氎滎ãšããŠååšããŠãå¹æã¯ãªããæ°Ž
åéã溶å€ã®é£œåæ°Žåéãè¶ ããªãããã«æº¶å€é
ããã³åŠçãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢
ãã³ã®éã調æŽããããã®ããã«ããŠæº¶å€åŠçã
è¡ãªããšãç±å€©ç§€ã§æ¯åïŒâã§ææž©ããæã®140
âãã220âãŸã§ã®ééæžå°çãä»èŸŒã¿ééã®6.5
ïŒ ãè¶ ãããã®ã¯çæããªãã 次ã«ãå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®æ
æ©æº¶å€ã«ããåŠçæ¡ä»¶ã«ã€ããŠæ€èšãããåå°äœ
ã¬ãŒã¶ãŒå æºïŒ750ã850nïœïŒã«é©åããæå äœ
ãåŸãã«ã¯ãé»è·çºçå±€ãåå°äœã¬ãŒã¶ãŒå ãå¹
çããåžåããå¿ èŠãããããããã€ãŠãé»è·çº
çå€ãšããŠã®å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ã750ã850nïœã§ã®åžå 床ã倧ããå¿ èŠãã
ãããã®ç¯å²ã«å¯èŠåžåã¹ãã¯ãã«ã®æ¥µå€§åžåã
æããããšã奜ãŸããã ãã®ãããªå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ãçšãã溶å€ããã®å«æ°Žéãæéããã³æž©åºŠã
å¶åŸ¡ããããšã«ããåŸããããäŸãã°ãå¡©çŽ åã¢
ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒååã®
æ°Žãå«ãã¯ãããã«ã ããã«ãšã³ããã·ã¬ã³ããž
ã¯ãã«ãšã¿ã³ãã¯ãã«ããã ã¡ã¿ã³ãçšããèžç
ã«ããåŸãããç¡å®åœ¢å¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ãåŠçããå Žåã¯ã宀枩ã§30åé浞挬ã
ãŠããŸããæè¯ç²Ÿè£œããå¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ç²æ«ãåŠçããå Žåã¯ãããŒã«ãã«äž
ã§ææ©æº¶å€ãšãšãã«å®€æž©ã§10æé以äžåŠçããã
ãšã«ããåŸãããã ããã§ãææ©æº¶å€åŠçã®ãããã«æ°Žã®ã¿ã§åŠç
ãè¡ãªã€ãå Žåã«ããç±å€©ç§€ã§æ¯åïŒâã§ææž©ã
ãæã®140âãã220âãŸã§ã®ééæžå°çããä»èŸŒ
ã¿ééã®6.0±0.5ïŒ ã®ãã®ãåŸããããŸããç·
åæå³ã第ïŒå³ã«ç€ºãããã«ãææ©æº¶å€åŠçãè¡
ãªã€ããã®ãšåããã®ãåŸããããããã®å¯èŠåž
åã¹ãã¯ãã«ã¯ç¬¬ïŒå³ã«ç€ºãããã«ã650nïœã«
極倧åžåã瀺ãã800nïœã§ã®åžå 床ãéåžžã«å°
ãããªããããæå äœã«ããæã800nïœã§ã®æ
床ã¯éåžžã«äœã奜ãŸãããªãã æ¬çºæã®å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã
é»è·çºçå±€ãšããŠçšããã«ã¯ãå°é»æ§åºæ¿äžã«é»
è·çºçå±€ãèšããããå°é»æ§åºæ¿ãšããŠã¯ãã¢ã«
ãããŠã ãé ãããã±ã«ãäºéãéãã€ã³ãžãŠã
çã®å°é»æ§éå±ãçšããããšãã§ããããŸããè
ã¡ã¢ãªãŒæ§ãæ¹åããç®çã§ãå°é»æ§åºæ¿äžã«ã
ãªããã«ã¢ã«ã³ãŒã«ãçµåå€ãšããé žåäºéå±€ãŸ
ãã¯ã¡ã¿ããŒã«å¯æº¶æ§ããªã¢ããå±€ã1ÎŒïœä»¥äž
ã®åãã§èšããŠãããã é»è·çºçå±€ãšããŠã®å¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ãèžçã«ããå Žåã¯ãå°é»æ§åºæ¿ãžã®
èžçã«ããåŸãããç¡å®åœ¢å¡©çŽ åã¢ã«ãããŠã ã
ã¿ãã·ã¢ãã³ããäžã«è¿°ã¹ãææ©æº¶å€ã«æµžæŒ¬ãã
ããšã«ããåŸãããããŸãã埮ç²ååããŠçšãã
å Žåã«ã¯ãæè¯ç²Ÿè£œããå¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ç²æ«ãããŒã«ãã«ãçšããäžã§è¿°ã¹ã
ææ©æº¶å€äžã§ç²ç ããããšã«ããåŸããããã®ãŸ
ãŸãããŸãã¯ã¢ã¯ãªã«æš¹èãã¹ãã¬ã³æš¹èãã¢ã«
ãããæš¹èãããªãšã¹ãã«æš¹èãããªã¢ããæš¹
èãããªã«ãŒãããŒãæš¹èãªã©ã®çµçå€ã溶å€ãš
å ±ã«å°é»æ§åºæ¿äžã«æº¶æ¶²å¡åžããŠãé»è·çºçå±€ãš
ããããšãã§ããããã®éã®çµçå€ã®äœ¿çšéã¯ã
ç¹ã«å¶éã¯ãªãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·
ã¢ãã³100éééšã«å¯Ÿã20éééšãªãã200éééš
ã§äœ¿çšããããããŠããã®éã®é»è·çºçå±€ã®åã
ã¯ãèžçã«ããäœæããå Žåã¯200ã1000â«ã溶
液å¡åžã®å Žåã¯ä¹Ÿç¥åã¿ã0.02ã5ÎŒïœãšãªããã
ã«å¡åžããã®ãæãŸããã 次ã«ãäžèšã®ããã«äœæããå¡©çŽ åã¢ã«ãããŠ
ã ãã¿ãã·ã¢ãã³é»è·çºçå±€ã®äžã«ãé»è·ç§»åå±€
ãç©å±€ããŠæå äœãšããããç©å±€ããé»è·ç§»åå±€
ã¯ãé»è·çºçå±€ã§çºçããé»è·ãæå äœè¡šé¢ãžç§»
åãããå±€ã§ãã€ãŠãé»è·çºçå±€ã®æå æ³¢é·é å
ã®å ã«å¯ŸããŠééæ§ã§ããããšãå¿ èŠã§ãããã
ãã«ãæé©ãªæå äœãåŸãã«ã¯ãé»è·ç§»åå±€ãé»
è·çºçå±€éã®ãšãã«ã®ãŒã¬ãã«ïŒã€ãªã³åããã³
ã·ã€ã«ãé»å芪ååãªã©ïŒãé©åã«é©åãããå¿
èŠããããé»è·ç§»åå€åäœãŸãã¯ãããçµåå€æš¹
èäžã«æº¶è§£ãåæ£ããã圢ã§çšããããã åç¬ã®ç§»åå€ãšããŠã¯ãïŒïŒïŒâãžã¡ããã·â
ïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãžã«ã«ãã³
é žããåŸãããããªãšã¹ãã«ãïŒïŒïŒâãžã¡ãã
ã·âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãžãã
ã²ã³ååç©ããåŸãããããªãšãŒãã«ãããªãã
ã«ã«ã«ããŸãŒã«ã䜿çšã§ãããçµåå€æš¹èäžã«å
æ£ããŠçšãã移åå€ãšããŠã¯ãïŒïŒïŒïŒïŒïŒ10â
ããã©ã€ãœããããã·ã¢ã³ãã©ã»ã³ã®ãããªã¢ã³
ãã©ã»ã³èªå°äœãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«
ãªã©ã®ãªããµãžã¢ãŸãŒã«é¡ãïŒâããšãã«âïŒâ
ïŒïœâãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïœâãžãš
ãã«ã¢ããããšãã«ïŒâãã©ãŸãªã³çã®ãã©ãŸãª
ã³èªå°äœãïŒâïŒãžãšãã«ã¢ããïŒã¹ããªã«âïŒ
âã¢ã³ãã©ã»ã³çã®ã¹ããªã«ååç©ãïœâãžãšã
ã«ã¢ãããã³ãºã¢ã«ãããâïŒãžããšãã«ããã©
ãŸã³ïŒçã®ããã©ãŸã³ç³»ååç©ãçšããããšãã§
ããã ãŸãã移åå€ã®çµåå€æš¹èãšããŠã¯ãããªå¡©å
ããã«ãããªã«ãŒãããŒããããªã¹ãã¬ã³ãããª
ãšã¹ãã«ãã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœãããª
ãŠã¬ã¿ã³ããšããã·æš¹èçãæãããããçµåå€
æš¹èã®éã¯ã移åå€100éééšã«å¯Ÿã60ã200éé
éšã§äœ¿çšããããããŠããã®éã®é»è·ç§»åå±€ã®å
ãã¯ç¹ã«å¶éã¯ãªãããå容é»äœãšã®é¢ä¿ããïŒ
ã20ÎŒïœãé©åœã§ããã ïŒå®æœäŸïŒ 以äžå®æœäŸã«ãããæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ãããšãšãã«ãæ¯èŒäŸãæ²ããã å®æœäŸ ïŒ æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H15.6Cl0.4ã§ç€º
ãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒéé
éšãš0.5éééšã®æ°ŽïŒå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ïŒååã«å¯ŸãïŒååã®æ°ŽïŒãå«ãã¯ãã
ãã«ã 563éééšããç空也ç¥ãããã©ã¹ããŒã«
ãã«ã«çªçŽ äžã§å¯å°ãã宀枩ã§10æéç²ç ããã
åŸãããåæ£æ¶²ã®ãã¡ïŒéééšã¯åãïŒmmã®éæ
ç³è±æ¿äžã«æ»Žäžãå¡åžãã15éééšã¯çªçŽ æ°æµäž
ã§é¢šä¹Ÿããããã«60âã§12æéç空也ç¥ãè¡ãª
ããå¯èŠåžåã¹ãã¯ãã«ããã³ç±å€©ç§€ã®æž¬å®è©Šæ
ãšãããå¯èŠåžåã¹ãã¯ãã«ã¯ãæ¥ç«èªèšåå å
床èš330ã«ãã500ã900nïœã®åžåã¹ãã¯ãã«ã
枬å®ãããç±å€©ç§€ã¯ã»ã€ã³ãŒé»åå·¥æ¥(æ ª)補ã瀺差
ç±ç±ééåæ枬å®è£ 眮TGïŒDTA30ãçšããã¢ã«
ãŽã³æ°æµäžãæ¯åïŒâã®é床ã§30âãã300âãŸ
ã§ææž©ãã第ïŒå³ã«ç€ºãããã«å®æœããŠã140â
ãã220âãŸã§ã®ééæžå°çã枬å®ãããåŸãã
ãçµæã第ïŒè¡šã«èšèŒããã ããã«ãåŸãããåæ£å¡æ¶²ã®æ®ã550éééšã«ã
ã¢ã¯ãªã«æš¹èïŒã¢ã¯ãªãã€ãã¯ïŒ¡â801ã倧æ¥æ¬
ã€ã³ã補ïŒïŒéééšã溶解ãããã®å¡æ¶²ãåã
100ÎŒïœã®ã¢ã«ãã·ãŒãäžã«ã也ç¥èåã0.1ÎŒïœã«
ãªãããã«æµžæŒ¬å¡å·¥ãã100âã§ïŒæé也ç¥ãé»
è·çºçå±€ãšããããã®äžã«ãïŒïŒïŒâãžã¡ããã·
âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšããã«ã³
äºé žããåŸãããããªãšã¹ãã«100éééšãããª
ã¯ãã«ãããã³700éééšã«å ã90âã«å ç±ããŠ
åäžã«ãã溶液ãã也ç¥èåã15ÎŒïœãšãªããã
ã«å ç±å¡åžãã100âã§ïŒæé也ç¥ããŠé»è·ç§»å
å±€ãšããæå äœãäœæããã æå äœã®ç¹æ§è©äŸ¡ã¯ãå·å£é»æ©è£œSP428åè©Šéš
æ©ãçšããŠãæå äœãšâ5.5KVã§ã³ãã垯é»ãã
å é3.84ÎŒWïŒcm2ã®800nïœå ãç §å°ããè¡šé¢é»äœ
ã1/2ãŸã§æžå°ããæéããåæžé²å ãšãã«ã®ãŒ
ïŒïŒïŒïŒïŒïŒÎŒJïŒcm2ïŒãæ±ããããã«ãè¡šé¢é»
äœã1/5ãŸã§æžå°ããæéããïŒïŒïŒïŒïŒïŒÎŒJïŒ
cm2ïŒãæ±ãããåŸãããçµæã第ïŒè¡šã«èšèŒã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã ã®ä»£ãã«0.56éééšã®æ°Žãå«ãã¯ããã
ã«ã 563éééšãçšããã»ãã¯ãå®æœäŸïŒãšåæ§
ã«è¡ãªã€ããåŸãããçµæã第ïŒè¡šã第ïŒè¡šã«èš
èŒããã æ¯èŒäŸïŒãïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã ã®ä»£ãã«ãåã ãæ¯èŒäŸïŒïŒ0.12éééš
ã®æ°ŽïŒAlClC32N8H15.6Cl0.4ã§ç€ºãããå¡©çŽ åã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯Ÿã0.5ååã®
æ°ŽïŒãæ¯èŒäŸïŒïŒ0.24éééšã®æ°ŽïŒåïŒååã®
æ°ŽïŒãæ¯èŒäŸïŒïŒ0.35éééšã®æ°ŽïŒå1.5ååã®
æ°ŽïŒãå«ãã¯ãããã«ã 563éééšãçšããä»ã¯ã
å®æœäŸïŒãšåæ§ã«è¡ãªã€ããåŸãããçµæã第ïŒ
è¡šã第ïŒè¡šã«èšèŒããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã 563éééšã®ä»£ãã«èžçæ°Ž563éééšãçš
ããä»ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããåŸããã
çµæã第ïŒè¡šã第ïŒè¡šã«èšèŒããã ãè¡šã ãè¡šã ãªãã€ãããšãè¡šããã
ããã«ãå®éã«å°åãè¡ãªã€ããšãããæ¯èŒäŸ
ïŒãïŒã§ã¯ïŒ¥ïŒïŒïŒïŒïŒã倧ãããããçœå°ã«ã
ã¶ããçããããå®æœäŸïŒããã³å®æœäŸïŒã«ãã
ãŠã¯ããã¶ãã®ãªãç»åãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãåºæ¿ã«ã¢ã«ãã·ãŒãã®ä»£ã
ã«å ±éé«ãã€ãã³ïŒæ±ã¬è£œCM4001ïŒãã¡ã¿ããŒ
ã«ã«æº¶è§£ããŠïŒééïŒ ã®æº¶æ¶²ãšãã100ÎŒïœã®ã¢
ã«ãã·ãŒãã«æµžæŒ¬å¡å·¥ãã0.8ÎŒïœã®ä¹Ÿç¥å¡èãèš
ãããã®ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãª
ã€ããåŸãããæå äœç¹æ§ã¯ã以äžã®ãšããã§ã
ã€ãã è¡šé¢é»äœ 575V ïŒïŒïŒïŒïŒ 0.67ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.6ÎŒJïŒcm2 å®æœäŸ ïŒ ä¹Ÿç¥èå0.05ÎŒïœã®å ±éåãã€ãã³ïŒæ±æå©ã¬
補CM40D1ïŒå±€ãèšããåã100ÎŒïœã®ã¢ã«ãã·ãŒ
ãäžã«ãAlClC32N8H15.6Cl0.4ã§ç€ºãããå¡©çŽ åã¢
ã«ãããŠã ãã¿ãã·ã¢ãã³ã10-5torrã§èžçãã
åã500â«ã®èžçèãåŸããèžçèãæ°Ž500ppmã
å«ããã«ãšã³50mlã«å®€æž©ã§ïŒåé浞挬ããé»è·çº
çå±€ãäœæããããã®äžã«å®æœäŸïŒãšåæ§ã«ã
ïŒïŒïŒâãžã¡ããã·âïŒïŒ10âãžããããã·ã¢ã³
ãã©ã»ã³ãšããã«ã³äºé žããåŸãããããªãšã¹ã
ã«ãé»è·ç§»åå±€ãšããŠèšããæå äœãäœæããã
åŸãããæå äœã®ç¹æ§ã¯ã以äžã®ãšããã§ãã€
ãã è¡šé¢é»äœ 600V ïŒïŒïŒïŒïŒ 0.50ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.2ÎŒJïŒcm2 æ¯èŒäŸ ïŒ å®æœäŸïŒã«äœ¿çšããæ°Ž500ppmãå«ããã«ãšã³
ã«ä»£ãæ°Ž5ppmãå«ããã«ãšã³50mlãçšãã以å€
ã¯ãå®æœäŸïŒãšåæ§ã«ããŠæå äœãäœæãããåŸ
ãããæå äœã®ç¹æ§ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 600V ïŒïŒïŒïŒïŒ 0.51ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 2.1ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«äœ¿çšããé»è·ç§»åå±€ïŒïŒïŒâãžã¡ã
ãã·âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãã
ã«ã³äºé žãããªãããªãšã¹ãã«ã«ä»£ããïŒïŒïŒïŒ
ïŒïŒ10âããã©ã€ãœããããã·ã¢ã³ãã©ã»ã³10é
ééšãããªã«ãŒãããŒãæš¹èããŠãŒããã³ïŒ¥â
2000ãïŒäžè±ã¬ã¹ååŠç€Ÿè£œïŒ10éééšãïŒïŒïŒâ
ãžã¯ãã«ãšã¿ã³400éééšãããªã溶液ãå¡åžãã
ç空也ç¥ãã也ç¥èå10ÎŒïœã®é»è·ç§»åå±€ã圢æ
ããŠæå äœãäœæããããã®æå äœã®ç¹æ§ã¯ã次
ã®ãšããã§ãã€ãã è¡šé¢é»äœ 540V ïŒïŒïŒïŒïŒ 0.85ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.9ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«äœ¿çšããé»æ°è·åå±€ïŒïŒïŒâãžã¡ã
ãã·âïŒïŒ10âãžãããã·ã¢ã³ãã©ã»ã³ãšããã«
ã³äºé žãããªãããªãšã¹ãã«ã«ä»£ããïœâãžãšã
ã«ã¢ãããã³ãºã¢ã«ãããâïŒãžããšãã«ããã©
ãŸã³ïŒ10éééšãããªã«ãŒãããŒãæš¹èããã³ã©
ã€ãâ1250ãïŒåžäººåæ瀟補ïŒ10éééšãïŒïŒ
ïŒâãžã¯ãã«ãšã¿ã³400éééšãããªã溶液ãå¡
åžããç空也ç¥ãã也ç¥èå12ÎŒïœã®é»è·ç§»åå±€
ã圢æããæå äœãäœæããããã®æå äœã®ç¹æ§
ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ  ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.50ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãAlClC32N8H15.6Cl0.4ã§ç€ºã
ããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®ä»£ãã«
æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H16ã§ç€ºããã
å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãçšãã以å€
ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããå¯èŠåžåã¹ãã¯
ãã«ãšã®æ¥µå€§åžåæ³¢é·ã¯760nïœã§ããããŸãã
ç±å€©ç§€ã§æž¬å®ãããšãããä»èŸŒã¿éé16.6mgã®
æã140âãã220âãŸã§ã®æžå°ééã¯0.98mgãšãª
ããééæžå°çã¯5.90ïŒ ã§ãã€ãããŸãããã®æ
å äœç¹æ§ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 580V ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.6ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠAlClC32N8H15.6Cl0.4ã§ç€ºãã
ãå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®ä»£ãã«ã
æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H14.2Cl1.8ã§ç€ºã
ããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãçšãã
以å€ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããå¯èŠåžåã¹
ãã¯ãã«ã®æ¥µå€§åžåæ³¢é·ã¯840nïœã§ããããŸãã
ç±å€©ç§€ã§æž¬å®ãããšãããä»èŸŒã¿éé18.8mgã®
æã140âãã220âãŸã§ã®æžå°ééã¯1.04mgãšãª
ããééæžå°çã¯5.53ïŒ ã§ãã€ãããŸãããã®æ
å äœç¹æ§ã¯ä»¥äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 610V ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.7ÎŒJïŒcm2 ïŒçºæã®å¹æïŒ æ¬çºæã«ããã°ãé»è·çºçå€ãšããŠæå¹ãªã¯ã
ã«ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ããã³ã¯ãã«ã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ã¯ããªãã®æ°ããå€æ§çµ
æ¶äœã®éçºã«ãããåŸæ¥ã®æå äœã«ãããæ§èœã®
ãã©ããããªããå°åããæã«ãã¶ããçããã
ãšããªããæå äœãšããŠé«æ§èœãåŸãããã
ã³ãããé»è·çºçå€ãšããŠçšããé»ååççšæå
äœã«ä¿ããã®ã§ããã æ¬çºæã®ç®çã¯ãé»è·çºçèœãåªããé»è·çºç
å€ãšããŠæå¹ãªå€æ§ãããå¡©çŽ åã¢ã«ãããŠã ã
ã¿ãã·ã¢ãã³çµæ¶ãæäŸããããšãããã³ããã
é»è·çºçå€ãšãé»è·ç§»åå€ãšçµåããæ§èœã®åªã
ãé»ååççšæå äœãæäŸããããšã«ããã ïŒåŸæ¥ã®æè¡ïŒ é»ååççšæå äœã¯ã«ãŒã«ãœã³ã®çºæ以æ¥ãå€
ãã®æå äœãéçºãããè€åæ©ãåç補çãããª
ã³ã¿ãªã©å€ãã®åéã«ãããŠäœ¿çšãããŠãããç¹
ã«æè¿ããªã³ã¿åéãžã®å±éãèããããã®ãã¡
ç¹ã«åå°äœã¬ãŒã¶ãŒã®å æºã«é©åãããšå ±ã«ãä»
ã®å æºãäŸãã°ãçºå ãã€ãªãŒããHeïŒNeã¬ã¹
ã¬ãŒã¶ãŒã®å æºã«é©åãããããªå€ç®çé»ååç
çšæå äœãèŠæãããŠããã ãã®ãããªèŠæã«å¿ããæå äœãšããŠãç¡æ©ç³»
ããã³ææ©ç³»ã®åçš®ã®æå äœãèæ¡ãããŠããã
ç¡æ©ç³»æå äœãšããŠã¯ãã¢ã¢ã«ãã¢ã¹ã·ãªã³ã³ã
ã»ã¬ã³âãã«ã«ååç©ãã»ã¬ã³âç çŽ ååç©ãªã©
ãç¥ãããŠãããææ©ç³»æå äœãšããŠã¯ãé»è·çº
çå€ãšããŠãã¿ãã·ã¢ãã³é¡ãçž®åå€ç°ååç©ã
ã¢ãŸç³»é¡æããã³ä»ã®è²çŽ é¡ãªã©ã䜿çšãããã
ãšçš®ã ã®é»è·ç§»åå€ãšãçµåãããã®ãç¥ãããŠ
ããã ãããã®æå äœã®ãã¡ãç¹ã«åå°äœã¬ãŒã¶ãŒã®
å æºã«é©åããããã«ã¯ãåå°äœã¬ãŒã¶ãŒå ãå¹
çããåžåããé»è·çºççã®åªããé»è·çºçå€ã
èŠæ±ãããã ææ©å é»å°äœã®äžã€ã§ãããã¿ãã·ã¢ãã³é¡
ã¯ãä»ã®å é»å°äœã«æ¯ã¹åžåæ³¢é·ãé·æ³¢é·ãŸã§äŒž
ã³ãŠãããé»è·çºçèœãåªããŠããããšããå®çš
åã®äŸãå€ãã ãã¿ãã·ã¢ãã³é¡ãçšããæå äœã«ãããŠç¹ã«
泚ç®ãã¹ãããšã¯ããã¿ãã·ã¢ãã³é¡ãé»è·çºç
å€ãšããŠäœ¿çšããéã«ã¯ããããç¹å®ã®çµæ¶äœã®
圢ã§äœ¿çšããããšã§ããã äŸãã°ãåãã¡ã¿ã«ããªãŒãã¿ãã·ã¢ãã³ã䜿
çšããã«ããç¹å ¬æ49â4338å·ã«è¿°ã¹ãããŠãã
ãããªïŒžåãããç¹éæ58â182639å·ã«ç€ºãããŠ
ãããããªÏãηåãããã«ã¯J.phys. ChemïŒ
27ã3230ïŒ1968ïŒã«è¿°ã¹ãããŠããαãβåãªã©
æ§ã ãªçµæ¶åãç¥ãããŠããããŸããé ãã¿ãã·
ã¢ãã³ã«ã€ããŠããç¹å ¬æ52â1667å·ã«è¿°ã¹ãã
ãŠããεåãããã«ã¯ãαãβãγãÏãÏãÏ
ãªã©ã®çµæ¶åãç¥ãããŠããããã®çµæ¶åã®éã
ãå é»å°æ§ã«éããããããããšãç¥ãããŠã
ãããã®ããããã¿ãã·ã¢ãã³é¡ãæå äœã®é»è·
çºçå€ãšããŠäœ¿çšããã«ã¯ããã®çµæ¶æ§é ãæ£ç¢º
ã«ç¹å®ããæå¹ãªçµæ¶æ§é ãå«ãŸãããã¿ãã·ã¢
ãã³ã䜿çšããªããã°ãªããªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ æ¬çºæè ãã¯ãå ã«ã¯ãã«ã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ããªããé»è·çºçå€ãšããé»ååççš
æå äœã«ã€ããŠæ€èšããçµæã該ãã¿ãã·ã¢ãã³
ã¯ããããèžçèèã®ãŸãŸããããã¯æè¯ç²Ÿè£œã
ã埮ç²åã®åæ£å¡èã®ãŸãŸã§ã¯é»è·çºçèœãäœ
ãããã¿ãã·ã¢ãã³ã«å¯Ÿã芪åæ§ã®ãã溶å€ãäŸ
ãã°ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ãé ¢é ž
ãšãã«ãšã¹ãã«ãã¡ãã«ãšãã«ã±ãã³çã®æº¶å€äž
ã§åŠçããããšã«ãããç¹ç°ã®ïŒžç·åæããã€ã¯
ãã«ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã¯ããªããåŸã
ããããã極ããŠåªããé»è·çºçèœã瀺ãããšã
èŠãåºããïŒç¹éæ58â209748å·ïŒã ããããå®éã«ãã®ãããªæäœãè¡ãªã€ãŠåŸã
ããæå äœã®æ§èœã¯éåžžã«ãã©ãããå€ããç¹æ§
ããªããªãäžå®ããªãã®ãå®æ ã§ãã€ãããŸãã
åæžé²å æ床ãé«ããã®ããæ®çé»äœïŒE1ïŒïŒïŒ
ãé«ããå®éã«å°åããæã«ãã¶ããçãããšã
ãæ¬ ç¹ããã€ãã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ æ¬çºæè ãã¯ãäžèšæ¬ ç¹ãæ¹è¯ããããéææ€
èšããçµæã該ãã¿ãã·ã¢ãã³ã®é»è·çºçèœã¯ã
åã«çµæ¶åã®ã¿ã«ããåŸããããã®ã§ã¯ãªãããš
ãçºèŠããé»è·çºçå€ãšããŠæå¹ãª AlC32N8H(17-X)ClXïŒïœïŒ1.0ã3.0ïŒã§ç€ºãããå¡©
çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®æ°ããå€æ§çµ
æ¶äœã®éçºã«æåããæ¬çºæãå®æããã«å°ã€
ãã ããªãã¡ãæ¬çºæè ãã¯ãå¡©çŽ åã¢ã«ãããŠã
ãã¿ãã·ã¢ãã³ã®çµæ¶åãããããšãªããããã®
çµæ¶äžã«å«ãŸãã140âã§ã®æ®çºæåéãéèŠãª
åãã瀺ãããšãèŠãåºãããã®æ®çºæåéãšæ
å äœç¹æ§ã®é¢ä¿ã詳现ã«æ€èšããçµæãç±å€©ç§€ã§
æ¯åïŒâã§ææž©ããæã®140âãã220âãŸã§ã®é
éæžå°çãä»èŸŒã¿ééã®6.0±0.5ïŒ ã®æãå§ããŠ
åªããé»è·çºçå€ãšããŠäœçšããããšãèŠãåº
ããããã«ããã®æ®çºæåéã¯ãåŠçãè¡ãªãæ
æ©æº¶å€äžã®æ°Žåéã«ããã³ã³ãããŒã«ã§ããããš
ãèŠãåºããæ¬çºæãå®æããã«å°ã€ãã®ã§ã
ãã æ¬çºæã«çšããããAlC32N8H(17-X)ClXïŒïœïŒ
1.0ã3.0ïŒã§ç€ºãããå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ããªã«ããã¿ããžãããªã«ãšå¡©åã¢ã«
ãããŠã ãç¡æº¶åªã§å ç±äžã«çž®ååå¿ãèµ·ãã
ãã容æã«åæããããšãã§ããããã®ããã«ã
ãŠåŸãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ãææ©æº¶å€ããã³æ°Žã«ããæŽæµãç¹°ãè¿ããŠç²Ÿ
補ããããã«ãæè¯ç²Ÿè£œã«ãã埮éã®äžçŽç©ãé€
å»ãããã®ãçšãããæ¬çºæã«ãããç¹å®ã®å¡©çŽ
åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãé»è·çºçå€ãšã
ãŠçšããã«ã¯ãæè¯ç²Ÿè£œã«ããåŸããããããã
ã¯èžçã«ããåŸãããå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ãææ©æº¶å€ã«ããåŠçããããšã«ãã€ãŠ
åŸãããAlC32N8H(17-X)ClXã«ãããŠïœïŒ1.0ãã
ïœïŒ3.0ã®éã§ããã®å¹æã«å·®ã¯èŠãããªãã ããã§ã溶å€åŠçã«çšããææ©æº¶å€ã¯ãå¡©çŽ å
ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã«å¯ŸããŠèŠªåæ§ã¯ã
ããã溶解床ãããŸãé«ããªã溶å€ãäŸãã°ãã
ã«ãšã³ããã·ã¬ã³ãé ¢é žãšãã«ããžã¯ãã«ã¡ã¿
ã³ãã¯ãããã«ã ãã¯ãã«ããã ã¡ã¿ã³ãããã
ãšã¿ã³çãããã溶解床ãé«ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãããã©ããããã©ã³çã¯ãå¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³ã溶解ããæå¹ãªçµæ¶åãš
ãªããªããã奜ãŸãããªããããã«ã溶å€åŠçã«
çšããææ©æº¶å€ã«ã¯ãå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ïŒåååœãïŒåå以äžã®æ°Žã溶解ããç¶
æ ã§å«ãŸããããã«ã溶å€éããã³å¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³éã調æŽãã溶å€åŠçãè¡
ãªãã 次ã«ãæå äœã®äœæã«ã€ããŠè©³çŽ°ã«è¿°ã¹ãã ææ©æº¶å€ã«ããåŠçãããå¡©çŽ åã¢ã«ãããŠã
ãã¿ãã·ã¢ãã³ã¯ãææ©æº¶å€ã«å«ãŸããæ°Žåéã«
ãããããªãããã®ïŒžç·åæå³ã¯ç¬¬ïŒå³ã«ç€ºãã
ãã«ã2Ξ±0.2床ã6.7床ã11.2床ã16.7床ã25.6床
ã«åŒ·ãåæããŒã¯ãèŠãããæè¯ç²Ÿè£œãããã®ã
ãçµæ¶åãå€åããããšã瀺ããããããããåŠ
çãè¡ãªãææ©æº¶å€äžã«å«ãŸããæ°Žåéããå¡©çŽ
åã¢ã«ãããŠã ãã¢ãã·ã¢ãã³ïŒååã«å¯ŸãïŒå
åæªæºã«ããå Žåã¯ããã¿ãã·ã¢ãã³ãç±å€©ç§€
ãã»ã€ã³ãŒé»åå·¥æ¥(æ ª)補TGïŒDTA30ãã«ããæ¯
åïŒâã§ææž©ããæã®140âãã220âãŸã§ã®éé
æžå°çããä»èŸŒã¿ééã®6.0±0.5ïŒ æªæºã§ããã
æå äœãšããŠé«æ§èœãåŸãããªããå¡©çŽ åã¢ã«ã
ããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒåå以äžã®
æ°Žãææ©æº¶å€ã«å«ãŸããŠæº¶å€åŠçãããæã®ã¿ã
ç±å€©ç§€ã§æ¯åïŒâã§ææž©ããæã®140âãã220â
ãŸã§ã®ééæžå°çããä»èŸŒã¿ééã®6.0±0.5ïŒ ã«
ãªããæå äœãšããŠé«æ§èœãåŸãããã ããã§ãææ©æº¶å€ã«å«ãŸããæ°Žã¯ãå¡©çŽ åã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒåå以äž
å¿ èŠã§ãããããã®éãææ©æº¶å€ã®é£œåæ°Žåé以
äžãšãªãã氎滎ãšããŠååšããŠãå¹æã¯ãªããæ°Ž
åéã溶å€ã®é£œåæ°Žåéãè¶ ããªãããã«æº¶å€é
ããã³åŠçãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢
ãã³ã®éã調æŽããããã®ããã«ããŠæº¶å€åŠçã
è¡ãªããšãç±å€©ç§€ã§æ¯åïŒâã§ææž©ããæã®140
âãã220âãŸã§ã®ééæžå°çãä»èŸŒã¿ééã®6.5
ïŒ ãè¶ ãããã®ã¯çæããªãã 次ã«ãå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®æ
æ©æº¶å€ã«ããåŠçæ¡ä»¶ã«ã€ããŠæ€èšãããåå°äœ
ã¬ãŒã¶ãŒå æºïŒ750ã850nïœïŒã«é©åããæå äœ
ãåŸãã«ã¯ãé»è·çºçå±€ãåå°äœã¬ãŒã¶ãŒå ãå¹
çããåžåããå¿ èŠãããããããã€ãŠãé»è·çº
çå€ãšããŠã®å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ã750ã850nïœã§ã®åžå 床ã倧ããå¿ èŠãã
ãããã®ç¯å²ã«å¯èŠåžåã¹ãã¯ãã«ã®æ¥µå€§åžåã
æããããšã奜ãŸããã ãã®ãããªå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³
ã¯ãçšãã溶å€ããã®å«æ°Žéãæéããã³æž©åºŠã
å¶åŸ¡ããããšã«ããåŸããããäŸãã°ãå¡©çŽ åã¢
ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯ŸãïŒååã®
æ°Žãå«ãã¯ãããã«ã ããã«ãšã³ããã·ã¬ã³ããž
ã¯ãã«ãšã¿ã³ãã¯ãã«ããã ã¡ã¿ã³ãçšããèžç
ã«ããåŸãããç¡å®åœ¢å¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ãåŠçããå Žåã¯ã宀枩ã§30åé浞挬ã
ãŠããŸããæè¯ç²Ÿè£œããå¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ç²æ«ãåŠçããå Žåã¯ãããŒã«ãã«äž
ã§ææ©æº¶å€ãšãšãã«å®€æž©ã§10æé以äžåŠçããã
ãšã«ããåŸãããã ããã§ãææ©æº¶å€åŠçã®ãããã«æ°Žã®ã¿ã§åŠç
ãè¡ãªã€ãå Žåã«ããç±å€©ç§€ã§æ¯åïŒâã§ææž©ã
ãæã®140âãã220âãŸã§ã®ééæžå°çããä»èŸŒ
ã¿ééã®6.0±0.5ïŒ ã®ãã®ãåŸããããŸããç·
åæå³ã第ïŒå³ã«ç€ºãããã«ãææ©æº¶å€åŠçãè¡
ãªã€ããã®ãšåããã®ãåŸããããããã®å¯èŠåž
åã¹ãã¯ãã«ã¯ç¬¬ïŒå³ã«ç€ºãããã«ã650nïœã«
極倧åžåã瀺ãã800nïœã§ã®åžå 床ãéåžžã«å°
ãããªããããæå äœã«ããæã800nïœã§ã®æ
床ã¯éåžžã«äœã奜ãŸãããªãã æ¬çºæã®å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã
é»è·çºçå±€ãšããŠçšããã«ã¯ãå°é»æ§åºæ¿äžã«é»
è·çºçå±€ãèšããããå°é»æ§åºæ¿ãšããŠã¯ãã¢ã«
ãããŠã ãé ãããã±ã«ãäºéãéãã€ã³ãžãŠã
çã®å°é»æ§éå±ãçšããããšãã§ããããŸããè
ã¡ã¢ãªãŒæ§ãæ¹åããç®çã§ãå°é»æ§åºæ¿äžã«ã
ãªããã«ã¢ã«ã³ãŒã«ãçµåå€ãšããé žåäºéå±€ãŸ
ãã¯ã¡ã¿ããŒã«å¯æº¶æ§ããªã¢ããå±€ã1ÎŒïœä»¥äž
ã®åãã§èšããŠãããã é»è·çºçå±€ãšããŠã®å¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ã¯ãèžçã«ããå Žåã¯ãå°é»æ§åºæ¿ãžã®
èžçã«ããåŸãããç¡å®åœ¢å¡©çŽ åã¢ã«ãããŠã ã
ã¿ãã·ã¢ãã³ããäžã«è¿°ã¹ãææ©æº¶å€ã«æµžæŒ¬ãã
ããšã«ããåŸãããããŸãã埮ç²ååããŠçšãã
å Žåã«ã¯ãæè¯ç²Ÿè£œããå¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ç²æ«ãããŒã«ãã«ãçšããäžã§è¿°ã¹ã
ææ©æº¶å€äžã§ç²ç ããããšã«ããåŸããããã®ãŸ
ãŸãããŸãã¯ã¢ã¯ãªã«æš¹èãã¹ãã¬ã³æš¹èãã¢ã«
ãããæš¹èãããªãšã¹ãã«æš¹èãããªã¢ããæš¹
èãããªã«ãŒãããŒãæš¹èãªã©ã®çµçå€ã溶å€ãš
å ±ã«å°é»æ§åºæ¿äžã«æº¶æ¶²å¡åžããŠãé»è·çºçå±€ãš
ããããšãã§ããããã®éã®çµçå€ã®äœ¿çšéã¯ã
ç¹ã«å¶éã¯ãªãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·
ã¢ãã³100éééšã«å¯Ÿã20éééšãªãã200éééš
ã§äœ¿çšããããããŠããã®éã®é»è·çºçå±€ã®åã
ã¯ãèžçã«ããäœæããå Žåã¯200ã1000â«ã溶
液å¡åžã®å Žåã¯ä¹Ÿç¥åã¿ã0.02ã5ÎŒïœãšãªããã
ã«å¡åžããã®ãæãŸããã 次ã«ãäžèšã®ããã«äœæããå¡©çŽ åã¢ã«ãããŠ
ã ãã¿ãã·ã¢ãã³é»è·çºçå±€ã®äžã«ãé»è·ç§»åå±€
ãç©å±€ããŠæå äœãšããããç©å±€ããé»è·ç§»åå±€
ã¯ãé»è·çºçå±€ã§çºçããé»è·ãæå äœè¡šé¢ãžç§»
åãããå±€ã§ãã€ãŠãé»è·çºçå±€ã®æå æ³¢é·é å
ã®å ã«å¯ŸããŠééæ§ã§ããããšãå¿ èŠã§ãããã
ãã«ãæé©ãªæå äœãåŸãã«ã¯ãé»è·ç§»åå±€ãé»
è·çºçå±€éã®ãšãã«ã®ãŒã¬ãã«ïŒã€ãªã³åããã³
ã·ã€ã«ãé»å芪ååãªã©ïŒãé©åã«é©åãããå¿
èŠããããé»è·ç§»åå€åäœãŸãã¯ãããçµåå€æš¹
èäžã«æº¶è§£ãåæ£ããã圢ã§çšããããã åç¬ã®ç§»åå€ãšããŠã¯ãïŒïŒïŒâãžã¡ããã·â
ïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãžã«ã«ãã³
é žããåŸãããããªãšã¹ãã«ãïŒïŒïŒâãžã¡ãã
ã·âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãžãã
ã²ã³ååç©ããåŸãããããªãšãŒãã«ãããªãã
ã«ã«ã«ããŸãŒã«ã䜿çšã§ãããçµåå€æš¹èäžã«å
æ£ããŠçšãã移åå€ãšããŠã¯ãïŒïŒïŒïŒïŒïŒ10â
ããã©ã€ãœããããã·ã¢ã³ãã©ã»ã³ã®ãããªã¢ã³
ãã©ã»ã³èªå°äœãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«
ãªã©ã®ãªããµãžã¢ãŸãŒã«é¡ãïŒâããšãã«âïŒâ
ïŒïœâãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïœâãžãš
ãã«ã¢ããããšãã«ïŒâãã©ãŸãªã³çã®ãã©ãŸãª
ã³èªå°äœãïŒâïŒãžãšãã«ã¢ããïŒã¹ããªã«âïŒ
âã¢ã³ãã©ã»ã³çã®ã¹ããªã«ååç©ãïœâãžãšã
ã«ã¢ãããã³ãºã¢ã«ãããâïŒãžããšãã«ããã©
ãŸã³ïŒçã®ããã©ãŸã³ç³»ååç©ãçšããããšãã§
ããã ãŸãã移åå€ã®çµåå€æš¹èãšããŠã¯ãããªå¡©å
ããã«ãããªã«ãŒãããŒããããªã¹ãã¬ã³ãããª
ãšã¹ãã«ãã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœãããª
ãŠã¬ã¿ã³ããšããã·æš¹èçãæãããããçµåå€
æš¹èã®éã¯ã移åå€100éééšã«å¯Ÿã60ã200éé
éšã§äœ¿çšããããããŠããã®éã®é»è·ç§»åå±€ã®å
ãã¯ç¹ã«å¶éã¯ãªãããå容é»äœãšã®é¢ä¿ããïŒ
ã20ÎŒïœãé©åœã§ããã ïŒå®æœäŸïŒ 以äžå®æœäŸã«ãããæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ãããšãšãã«ãæ¯èŒäŸãæ²ããã å®æœäŸ ïŒ æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H15.6Cl0.4ã§ç€º
ãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒéé
éšãš0.5éééšã®æ°ŽïŒå¡©çŽ åã¢ã«ãããŠã ãã¿ã
ã·ã¢ãã³ïŒååã«å¯ŸãïŒååã®æ°ŽïŒãå«ãã¯ãã
ãã«ã 563éééšããç空也ç¥ãããã©ã¹ããŒã«
ãã«ã«çªçŽ äžã§å¯å°ãã宀枩ã§10æéç²ç ããã
åŸãããåæ£æ¶²ã®ãã¡ïŒéééšã¯åãïŒmmã®éæ
ç³è±æ¿äžã«æ»Žäžãå¡åžãã15éééšã¯çªçŽ æ°æµäž
ã§é¢šä¹Ÿããããã«60âã§12æéç空也ç¥ãè¡ãª
ããå¯èŠåžåã¹ãã¯ãã«ããã³ç±å€©ç§€ã®æž¬å®è©Šæ
ãšãããå¯èŠåžåã¹ãã¯ãã«ã¯ãæ¥ç«èªèšåå å
床èš330ã«ãã500ã900nïœã®åžåã¹ãã¯ãã«ã
枬å®ãããç±å€©ç§€ã¯ã»ã€ã³ãŒé»åå·¥æ¥(æ ª)補ã瀺差
ç±ç±ééåæ枬å®è£ 眮TGïŒDTA30ãçšããã¢ã«
ãŽã³æ°æµäžãæ¯åïŒâã®é床ã§30âãã300âãŸ
ã§ææž©ãã第ïŒå³ã«ç€ºãããã«å®æœããŠã140â
ãã220âãŸã§ã®ééæžå°çã枬å®ãããåŸãã
ãçµæã第ïŒè¡šã«èšèŒããã ããã«ãåŸãããåæ£å¡æ¶²ã®æ®ã550éééšã«ã
ã¢ã¯ãªã«æš¹èïŒã¢ã¯ãªãã€ãã¯ïŒ¡â801ã倧æ¥æ¬
ã€ã³ã補ïŒïŒéééšã溶解ãããã®å¡æ¶²ãåã
100ÎŒïœã®ã¢ã«ãã·ãŒãäžã«ã也ç¥èåã0.1ÎŒïœã«
ãªãããã«æµžæŒ¬å¡å·¥ãã100âã§ïŒæé也ç¥ãé»
è·çºçå±€ãšããããã®äžã«ãïŒïŒïŒâãžã¡ããã·
âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšããã«ã³
äºé žããåŸãããããªãšã¹ãã«100éééšãããª
ã¯ãã«ãããã³700éééšã«å ã90âã«å ç±ããŠ
åäžã«ãã溶液ãã也ç¥èåã15ÎŒïœãšãªããã
ã«å ç±å¡åžãã100âã§ïŒæé也ç¥ããŠé»è·ç§»å
å±€ãšããæå äœãäœæããã æå äœã®ç¹æ§è©äŸ¡ã¯ãå·å£é»æ©è£œSP428åè©Šéš
æ©ãçšããŠãæå äœãšâ5.5KVã§ã³ãã垯é»ãã
å é3.84ÎŒWïŒcm2ã®800nïœå ãç §å°ããè¡šé¢é»äœ
ã1/2ãŸã§æžå°ããæéããåæžé²å ãšãã«ã®ãŒ
ïŒïŒïŒïŒïŒïŒÎŒJïŒcm2ïŒãæ±ããããã«ãè¡šé¢é»
äœã1/5ãŸã§æžå°ããæéããïŒïŒïŒïŒïŒïŒÎŒJïŒ
cm2ïŒãæ±ãããåŸãããçµæã第ïŒè¡šã«èšèŒã
ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã ã®ä»£ãã«0.56éééšã®æ°Žãå«ãã¯ããã
ã«ã 563éééšãçšããã»ãã¯ãå®æœäŸïŒãšåæ§
ã«è¡ãªã€ããåŸãããçµæã第ïŒè¡šã第ïŒè¡šã«èš
èŒããã æ¯èŒäŸïŒãïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã ã®ä»£ãã«ãåã ãæ¯èŒäŸïŒïŒ0.12éééš
ã®æ°ŽïŒAlClC32N8H15.6Cl0.4ã§ç€ºãããå¡©çŽ åã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯Ÿã0.5ååã®
æ°ŽïŒãæ¯èŒäŸïŒïŒ0.24éééšã®æ°ŽïŒåïŒååã®
æ°ŽïŒãæ¯èŒäŸïŒïŒ0.35éééšã®æ°ŽïŒå1.5ååã®
æ°ŽïŒãå«ãã¯ãããã«ã 563éééšãçšããä»ã¯ã
å®æœäŸïŒãšåæ§ã«è¡ãªã€ããåŸãããçµæã第ïŒ
è¡šã第ïŒè¡šã«èšèŒããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠã0.5éééšã®æ°Žãå«ãã¯ã
ããã«ã 563éééšã®ä»£ãã«èžçæ°Ž563éééšãçš
ããä»ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããåŸããã
çµæã第ïŒè¡šã第ïŒè¡šã«èšèŒããã ãè¡šã ãè¡šã ãªãã€ãããšãè¡šããã
ããã«ãå®éã«å°åãè¡ãªã€ããšãããæ¯èŒäŸ
ïŒãïŒã§ã¯ïŒ¥ïŒïŒïŒïŒïŒã倧ãããããçœå°ã«ã
ã¶ããçããããå®æœäŸïŒããã³å®æœäŸïŒã«ãã
ãŠã¯ããã¶ãã®ãªãç»åãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãåºæ¿ã«ã¢ã«ãã·ãŒãã®ä»£ã
ã«å ±éé«ãã€ãã³ïŒæ±ã¬è£œCM4001ïŒãã¡ã¿ããŒ
ã«ã«æº¶è§£ããŠïŒééïŒ ã®æº¶æ¶²ãšãã100ÎŒïœã®ã¢
ã«ãã·ãŒãã«æµžæŒ¬å¡å·¥ãã0.8ÎŒïœã®ä¹Ÿç¥å¡èãèš
ãããã®ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãª
ã€ããåŸãããæå äœç¹æ§ã¯ã以äžã®ãšããã§ã
ã€ãã è¡šé¢é»äœ 575V ïŒïŒïŒïŒïŒ 0.67ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.6ÎŒJïŒcm2 å®æœäŸ ïŒ ä¹Ÿç¥èå0.05ÎŒïœã®å ±éåãã€ãã³ïŒæ±æå©ã¬
補CM40D1ïŒå±€ãèšããåã100ÎŒïœã®ã¢ã«ãã·ãŒ
ãäžã«ãAlClC32N8H15.6Cl0.4ã§ç€ºãããå¡©çŽ åã¢
ã«ãããŠã ãã¿ãã·ã¢ãã³ã10-5torrã§èžçãã
åã500â«ã®èžçèãåŸããèžçèãæ°Ž500ppmã
å«ããã«ãšã³50mlã«å®€æž©ã§ïŒåé浞挬ããé»è·çº
çå±€ãäœæããããã®äžã«å®æœäŸïŒãšåæ§ã«ã
ïŒïŒïŒâãžã¡ããã·âïŒïŒ10âãžããããã·ã¢ã³
ãã©ã»ã³ãšããã«ã³äºé žããåŸãããããªãšã¹ã
ã«ãé»è·ç§»åå±€ãšããŠèšããæå äœãäœæããã
åŸãããæå äœã®ç¹æ§ã¯ã以äžã®ãšããã§ãã€
ãã è¡šé¢é»äœ 600V ïŒïŒïŒïŒïŒ 0.50ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.2ÎŒJïŒcm2 æ¯èŒäŸ ïŒ å®æœäŸïŒã«äœ¿çšããæ°Ž500ppmãå«ããã«ãšã³
ã«ä»£ãæ°Ž5ppmãå«ããã«ãšã³50mlãçšãã以å€
ã¯ãå®æœäŸïŒãšåæ§ã«ããŠæå äœãäœæãããåŸ
ãããæå äœã®ç¹æ§ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 600V ïŒïŒïŒïŒïŒ 0.51ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 2.1ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«äœ¿çšããé»è·ç§»åå±€ïŒïŒïŒâãžã¡ã
ãã·âïŒïŒ10âãžããããã·ã¢ã³ãã©ã»ã³ãšãã
ã«ã³äºé žãããªãããªãšã¹ãã«ã«ä»£ããïŒïŒïŒïŒ
ïŒïŒ10âããã©ã€ãœããããã·ã¢ã³ãã©ã»ã³10é
ééšãããªã«ãŒãããŒãæš¹èããŠãŒããã³ïŒ¥â
2000ãïŒäžè±ã¬ã¹ååŠç€Ÿè£œïŒ10éééšãïŒïŒïŒâ
ãžã¯ãã«ãšã¿ã³400éééšãããªã溶液ãå¡åžãã
ç空也ç¥ãã也ç¥èå10ÎŒïœã®é»è·ç§»åå±€ã圢æ
ããŠæå äœãäœæããããã®æå äœã®ç¹æ§ã¯ã次
ã®ãšããã§ãã€ãã è¡šé¢é»äœ 540V ïŒïŒïŒïŒïŒ 0.85ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.9ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«äœ¿çšããé»æ°è·åå±€ïŒïŒïŒâãžã¡ã
ãã·âïŒïŒ10âãžãããã·ã¢ã³ãã©ã»ã³ãšããã«
ã³äºé žãããªãããªãšã¹ãã«ã«ä»£ããïœâãžãšã
ã«ã¢ãããã³ãºã¢ã«ãããâïŒãžããšãã«ããã©
ãŸã³ïŒ10éééšãããªã«ãŒãããŒãæš¹èããã³ã©
ã€ãâ1250ãïŒåžäººåæ瀟補ïŒ10éééšãïŒïŒ
ïŒâãžã¯ãã«ãšã¿ã³400éééšãããªã溶液ãå¡
åžããç空也ç¥ãã也ç¥èå12ÎŒïœã®é»è·ç§»åå±€
ã圢æããæå äœãäœæããããã®æå äœã®ç¹æ§
ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ  ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.50ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãAlClC32N8H15.6Cl0.4ã§ç€ºã
ããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®ä»£ãã«
æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H16ã§ç€ºããã
å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãçšãã以å€
ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããå¯èŠåžåã¹ãã¯
ãã«ãšã®æ¥µå€§åžåæ³¢é·ã¯760nïœã§ããããŸãã
ç±å€©ç§€ã§æž¬å®ãããšãããä»èŸŒã¿éé16.6mgã®
æã140âãã220âãŸã§ã®æžå°ééã¯0.98mgãšãª
ããééæžå°çã¯5.90ïŒ ã§ãã€ãããŸãããã®æ
å äœç¹æ§ã¯ã以äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 580V ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.6ÎŒJïŒcm2 å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠAlClC32N8H15.6Cl0.4ã§ç€ºãã
ãå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®ä»£ãã«ã
æè¯ç²Ÿè£œããŠåŸãããAlClC32N8H14.2Cl1.8ã§ç€ºã
ããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ãçšãã
以å€ã¯ãå®æœäŸïŒãšåæ§ã«è¡ãªã€ããå¯èŠåžåã¹
ãã¯ãã«ã®æ¥µå€§åžåæ³¢é·ã¯840nïœã§ããããŸãã
ç±å€©ç§€ã§æž¬å®ãããšãããä»èŸŒã¿éé18.8mgã®
æã140âãã220âãŸã§ã®æžå°ééã¯1.04mgãšãª
ããééæžå°çã¯5.53ïŒ ã§ãã€ãããŸãããã®æ
å äœç¹æ§ã¯ä»¥äžã®ãšããã§ãã€ãã è¡šé¢é»äœ 610V ïŒïŒïŒïŒïŒ 0.70ÎŒJïŒcm2 ïŒïŒïŒïŒïŒ 1.7ÎŒJïŒcm2 ïŒçºæã®å¹æïŒ æ¬çºæã«ããã°ãé»è·çºçå€ãšããŠæå¹ãªã¯ã
ã«ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ããã³ã¯ãã«ã¢ã«
ãããŠã ãã¿ãã·ã¢ãã³ã¯ããªãã®æ°ããå€æ§çµ
æ¶äœã®éçºã«ãããåŸæ¥ã®æå äœã«ãããæ§èœã®
ãã©ããããªããå°åããæã«ãã¶ããçããã
ãšããªããæå äœãšããŠé«æ§èœãåŸãããã
第ïŒå³ã¯AlClC32N8H15.6Cl0.4ã§ç€ºãããå¡©çŽ å
ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®CuKaç·ãç·æºãš
ããŠçšãããšãã®ïŒžç·åæã¹ãã¯ãã«ã第ïŒå³ã¯
å¯èŠåžåã¹ãã¯ãã«ã§ãå³äžÎ±ã¯æè¯ç²Ÿè£œããã®
ã¿ã§ææ©æº¶å€åŠçãæœããªãå ŽåïŒæ¯èŒåïŒãïœ
ã¯å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯Ÿ
ããŠïŒååã®æ°Žãå«æããææ©æº¶å€ã§åŠçãæœã
ãå ŽåïŒæ¬çºæïŒãïœã¯å¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ãæ°Žã®ã¿ã§åŠçãæœããå ŽåïŒæ¯èŒ
äŸïŒã瀺ãã第ïŒå³ã¯å®æœäŸïŒã®ç±å€©ç§€ã®æž¬å®çµ
æã瀺ãã°ã©ãã§ããã
ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã®CuKaç·ãç·æºãš
ããŠçšãããšãã®ïŒžç·åæã¹ãã¯ãã«ã第ïŒå³ã¯
å¯èŠåžåã¹ãã¯ãã«ã§ãå³äžÎ±ã¯æè¯ç²Ÿè£œããã®
ã¿ã§ææ©æº¶å€åŠçãæœããªãå ŽåïŒæ¯èŒåïŒãïœ
ã¯å¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ïŒååã«å¯Ÿ
ããŠïŒååã®æ°Žãå«æããææ©æº¶å€ã§åŠçãæœã
ãå ŽåïŒæ¬çºæïŒãïœã¯å¡©çŽ åã¢ã«ãããŠã ãã¿
ãã·ã¢ãã³ãæ°Žã®ã¿ã§åŠçãæœããå ŽåïŒæ¯èŒ
äŸïŒã瀺ãã第ïŒå³ã¯å®æœäŸïŒã®ç±å€©ç§€ã®æž¬å®çµ
æã瀺ãã°ã©ãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§åºæ¿äžã«é»è·çºçå±€ããã³é»è·ç§»åå±€
ãç©å±€ããç©å±€åé»ååççšæå äœã«ãããŠãé»
è·çºçå€ãã¢ã«ãããŠã ãã¿ãã·ã¢ãã³èªå°äœã§
ããããã®ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³èªå°äœã (a) ç±å€©ç§€ã§æ¯åïŒâã§ææž©ããæã®140âãã
220âãŸã§ã®ééæžå°çãä»èŸŒã¿ééã®6.0±
0.5ïŒ ã§ãã〠(b) ç·åæã¹ãã¯ãã«ã«ãããŠãã©ãã¯è§ïŒ2Ξ
±0.2床ïŒã6.7床ã11.2床ã16.7床ã25.6床ã«åŒ·
ãåæããŒã¯ãæã (c) å¯èŠåžåã¹ãã¯ãã«ã«ãããŠ750nïœãã
850nïœã®éã«æ¥µå€§åžåãæããããšãç¹åŸŽãš
ããé»ååççšæå äœã ïŒ ã¢ã«ãããŠã ãã¿ãã·ã¢ãã³èªå°äœã AlC32N8H(17-X)ClXïŒïœïŒ1.0ã3.0ïŒ ã§ç€ºãããå¡©çŽ åã¢ã«ãããŠã ãã¿ãã·ã¢ãã³ã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®é»ååççšæå
äœã
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18696086A JPS6343155A (ja) | 1986-08-11 | 1986-08-11 | ãã¿ãã·ã¢ãã³ååç©ãçšããé»ååççšæå äœ |
CA000524715A CA1279787C (en) | 1985-12-06 | 1986-12-05 | Electrophotographic photoconductor using phthalocyanine compound |
US06/938,482 US4732832A (en) | 1985-12-06 | 1986-12-05 | Electrophotographic photoconductor using aluminum phthalocyanine compound in charge generating layer |
EP86309500A EP0228202B1 (en) | 1985-12-06 | 1986-12-05 | Electrophotographic photoconductor using phthalocyanine compound |
DE8686309500T DE3671548D1 (de) | 1985-12-06 | 1986-12-05 | Elektrophotographischer photoleiter auf der basis einer phthalocyaninverbindung. |
AU66140/86A AU584262B2 (en) | 1985-12-06 | 1986-12-05 | Electrophotographic photoconductor using phthalocyanine compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18696086A JPS6343155A (ja) | 1986-08-11 | 1986-08-11 | ãã¿ãã·ã¢ãã³ååç©ãçšããé»ååççšæå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6343155A JPS6343155A (ja) | 1988-02-24 |
JPH0469952B2 true JPH0469952B2 (ja) | 1992-11-09 |
Family
ID=16197737
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18696086A Granted JPS6343155A (ja) | 1985-12-06 | 1986-08-11 | ãã¿ãã·ã¢ãã³ååç©ãçšããé»ååççšæå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6343155A (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0277766A (ja) * | 1988-09-14 | 1990-03-16 | Canon Inc | ç»å圢æè£ çœ® |
JP2008127294A (ja) * | 2006-11-17 | 2008-06-05 | Konica Minolta Business Technologies Inc | ãã¬ã³ç³»ååç©ã該ååç©ãçšããææ©æå äœãç»å圢ææ¹æ³åã³ç»å圢æè£ çœ® |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5669644A (en) * | 1979-11-13 | 1981-06-11 | Konishiroku Photo Ind Co Ltd | Original plate for printing |
JPS57148745A (en) * | 1981-03-11 | 1982-09-14 | Nippon Telegr & Teleph Corp <Ntt> | Lamination type electrophotographic receptor |
JPS57211149A (en) * | 1981-06-23 | 1982-12-24 | Nippon Telegr & Teleph Corp <Ntt> | Laminated type electrophotographic receptor |
JPS58158649A (ja) * | 1982-03-15 | 1983-09-20 | Nippon Telegr & Teleph Corp <Ntt> | ç©å±€åé»ååçæå äœ |
JPS58209748A (ja) * | 1982-06-01 | 1983-12-06 | Asahi Chem Ind Co Ltd | ææ©ç³»é»ååççšæå äœ |
JPS59133550A (ja) * | 1983-01-20 | 1984-07-31 | Oki Electric Ind Co Ltd | é»ååççšæå äœ |
JPS6026947A (ja) * | 1983-07-25 | 1985-02-09 | Asahi Chem Ind Co Ltd | ææ©ç³»é»ååççšæå äœ |
JPS6052853A (ja) * | 1983-09-02 | 1985-03-26 | Asahi Chem Ind Co Ltd | é»ååççšææ©æå äœ |
-
1986
- 1986-08-11 JP JP18696086A patent/JPS6343155A/ja active Granted
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5669644A (en) * | 1979-11-13 | 1981-06-11 | Konishiroku Photo Ind Co Ltd | Original plate for printing |
JPS57148745A (en) * | 1981-03-11 | 1982-09-14 | Nippon Telegr & Teleph Corp <Ntt> | Lamination type electrophotographic receptor |
JPS57211149A (en) * | 1981-06-23 | 1982-12-24 | Nippon Telegr & Teleph Corp <Ntt> | Laminated type electrophotographic receptor |
JPS58158649A (ja) * | 1982-03-15 | 1983-09-20 | Nippon Telegr & Teleph Corp <Ntt> | ç©å±€åé»ååçæå äœ |
JPS58209748A (ja) * | 1982-06-01 | 1983-12-06 | Asahi Chem Ind Co Ltd | ææ©ç³»é»ååççšæå äœ |
JPS59133550A (ja) * | 1983-01-20 | 1984-07-31 | Oki Electric Ind Co Ltd | é»ååççšæå äœ |
JPS6026947A (ja) * | 1983-07-25 | 1985-02-09 | Asahi Chem Ind Co Ltd | ææ©ç³»é»ååççšæå äœ |
JPS6052853A (ja) * | 1983-09-02 | 1985-03-26 | Asahi Chem Ind Co Ltd | é»ååççšææ©æå äœ |
Also Published As
Publication number | Publication date |
---|---|
JPS6343155A (ja) | 1988-02-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0228265A (ja) | ãã¿ãã·ã¢ãã³çµæ¶ã®è£œé æ¹æ³ | |
JPH0560863B2 (ja) | ||
JPH09157540A (ja) | ãã¿ãã·ã¢ãã³çµæç©ããã®è£œé æ³ããããçšããé»ååçæå äœåã³é»è·çºçå±€çšå¡æ¶² | |
US5328788A (en) | Organic photoconductive material for electrophotography and method for making the same | |
JPH0469952B2 (ja) | ||
US4732832A (en) | Electrophotographic photoconductor using aluminum phthalocyanine compound in charge generating layer | |
EP0449565A1 (en) | Photosensitive material for electrophotography | |
JP2599170B2 (ja) | é»ååçæå äœ | |
JPS62133462A (ja) | ãã¿ãã·ã¢ãã³ååç©ãçšããé»ååççšæå äœ | |
JP4233388B2 (ja) | æ°èŠãªããã³ååç©ãããã³è©²ååç©ãçšããé»ååçæå äœãé»ååçè£ çœ® | |
JPS62177069A (ja) | æ°èŠãªãã¿ãã·ã¢ãã³çµæ¶ããã³ãããçšããé»ååççšæå äœ | |
JPH10142818A (ja) | é»ååçæå äœ | |
JPH0229661A (ja) | é»ååççšæå äœ | |
JP2001154387A (ja) | é»ååçæå äœ | |
JPH0570709A (ja) | å¡©çŽ åã€ã³ãžãŠã ãã¿ãã·ã¢ãã³ããã®è£œé æ³ããã³ãããçšããé»ååçæå äœ | |
JP2707630B2 (ja) | é»ååçæå äœ | |
JP2899871B2 (ja) | ãã¿ãã«ãã¿ãã·ã¢ãã³ãšïŒïŒïŒâãã¿ã³ãžãªãŒã«ã®ä»å äœååç© | |
JP2001033999A (ja) | é»ååçæå äœ | |
JPS63262657A (ja) | é»ååçæå äœ | |
JPH01291256A (ja) | é»ååçæå äœ | |
JPH0598179A (ja) | èçŽ åã€ã³ãžãŠã ãã¿ãã·ã¢ãã³ããã®è£œé æ¹æ³ããã³ãããçšããé»ååçæå äœ | |
JP2000072975A (ja) | é»è·çºçææããã³é»ååçæå äœ | |
JPH0570710A (ja) | å¡©çŽ åã€ã³ãžãŠã ãã¿ãã·ã¢ãã³ããã®è£œé æ³ããã³ãããçšããé»ååçæå äœ | |
JP2001033998A (ja) | é»ååçæå äœ | |
JPH02165156A (ja) | é»ååçæå äœ |