JPH0466023B2 - - Google Patents
Info
- Publication number
- JPH0466023B2 JPH0466023B2 JP58205994A JP20599483A JPH0466023B2 JP H0466023 B2 JPH0466023 B2 JP H0466023B2 JP 58205994 A JP58205994 A JP 58205994A JP 20599483 A JP20599483 A JP 20599483A JP H0466023 B2 JPH0466023 B2 JP H0466023B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- charge
- substituted
- unsubstituted
- photoreceptor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 40
- 239000000126 substance Substances 0.000 claims description 25
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 14
- 125000001424 substituent group Chemical group 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 10
- 125000000732 arylene group Chemical group 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 48
- -1 stilbene compound Chemical class 0.000 description 23
- 230000032258 transport Effects 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- 239000000049 pigment Substances 0.000 description 17
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 14
- 235000021286 stilbenes Nutrition 0.000 description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000002800 charge carrier Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052711 selenium Inorganic materials 0.000 description 6
- 239000011669 selenium Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000006163 transport media Substances 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical group OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 3
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical group C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- NGQSLSMAEVWNPU-YTEMWHBBSA-N 1,2-bis[(e)-2-phenylethenyl]benzene Chemical group C=1C=CC=CC=1/C=C/C1=CC=CC=C1\C=C\C1=CC=CC=C1 NGQSLSMAEVWNPU-YTEMWHBBSA-N 0.000 description 1
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- PANZFQYXPMCHFD-UHFFFAOYSA-N 2,3-diphenyl-1h-indene Chemical compound C12=CC=CC=C2CC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 PANZFQYXPMCHFD-UHFFFAOYSA-N 0.000 description 1
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- PQJUJGAVDBINPI-UHFFFAOYSA-N 9H-thioxanthene Chemical compound C1=CC=C2CC3=CC=CC=C3SC2=C1 PQJUJGAVDBINPI-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical group C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- JYDZYJYYCYREGF-UHFFFAOYSA-N [Cd].[Se]=S Chemical compound [Cd].[Se]=S JYDZYJYYCYREGF-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000000278 alkyl amino alkyl group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000005128 aryl amino alkyl group Chemical group 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 125000005160 aryl oxy alkyl group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- MRQIXHXHHPWVIL-UHFFFAOYSA-N chembl1397023 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=CC=C1 MRQIXHXHHPWVIL-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- QPJORFLSOJAUNL-UHFFFAOYSA-N dibenzo[a,d][7]annulene Chemical compound C1=CC2=CC=CC=C2CC2=CC=CC=C21 QPJORFLSOJAUNL-UHFFFAOYSA-N 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical group C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000005186 naphthyloxy group Chemical group C1(=CC=CC2=CC=CC=C12)O* 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical group C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical class C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000005649 substituted arylene group Chemical group 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000006617 triphenylamine group Chemical group 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0666—Dyes containing a methine or polymethine group
- G03G5/0668—Dyes containing a methine or polymethine group containing only one methine or polymethine group
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Light Receiving Elements (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
æè¡åé
æ¬çºæã¯é»ååççšæå
äœã«é¢ãã詳ããã¯æ
å å±€äžã«ç¹å®ã®Î±â眮æã¹ãã«ãã³ååç©ãé»è·
æ¬éç©è³ªãšããŠå«æããæ©èœåé¢åæå å±€ãšãã
é»ååççšæå äœã«é¢ããã åŸæ¥æè¡ åŸæ¥ãé»ååçæ¹åŒã«ãããŠäœ¿çšãããæå äœ
ã®å å°é»æ§çŽ æãšããŠçšããããŠãããã®ã«ã»ã¬
ã³ãç¡«åã«ãããŠã ãé žåäºéãªã©ã®ç¡æ©ç©è³ªã
ãããããã«ãããé»ååçæ¹åŒããšã¯ãäžè¬ã«
å å°é»æ§ã®æå äœããŸãææã§ãäŸãã°ã³ããæŸ
é»ã«ãã€ãŠåž¯é»ãããã次ãã§åé²å ããé²å éš
ã®ã¿ã®é»è·ãéžæçã«éžæ£ããããŠéé»æœåã
åŸããã®æœåéšãææãé¡æãªã©ã®çè²æãšé«å
åç©è³ªãªã©ã®çµåå€ãšããæ§æãããæ€é»åŸ®ç²å
ïŒãããŒïŒã§çŸåãå¯èŠåããŠç»åã圢æããã
ãã«ããç»å圢ææ³ã®äžã€ã§ããã ãã®ãããªé»ååçæ³ã«ãããŠæå äœã«èŠæ±ã
ããåºæ¬çãªç¹æ§ãšããŠã¯ã(1)ææã§é©åœãªé»äœ
ã«åž¯é»ã§ããããšã(2)ææã«ãããŠé»è·ã®éžæ£ã
å°ãªãããšã(3)å ç §å°ã«ãã€ãŠéããã«é»è·ãéž
æ£ããããããšãªã©ããããããã ãšããã§ãåèšã®ç¡æ©ç©è³ªã¯ããããå€ãã®é·
æããã€ãŠãããšåæã«ãããŸããŸãªæ¬ ç¹ããæ
ããŠããã®ãäºå®ã§ãããäŸãã°ãçŸåšåºãçšã
ãããŠããã»ã¬ã³ã¯åèš(1)ã(3)ã®æ¡ä»¶ã¯å åã«æº
足ãããã補é ããæ¡ä»¶ããããããã補é ã³ã¹
ããé«ããªããå¯ææ§ããªãããã«ãç¶ã«å å·¥ã
ãããšãããããããç±ãæ©æ¢°çã®è¡æã«éæãª
ããåæ±ãã«æ³šæãèŠãããªã©ã®æ¬ ç¹ããããç¡«
åã«ãããŠã ãé žåäºéã¯ãçµåå€ãšããŠã®æš¹è
ã«åæ£ãããŠæå äœãšããŠçšããããŠããããå¹³
æ»æ§ã硬床ãåŒåŒµã匷床ãèæ©æŠæ§ãªã©ã®æ©æ¢°ç
ãªæ¬ ç¹ãããããã«ãã®ãŸãŸã§ã¯å埩ããŠäœ¿çšã
ãããšãã§ããªãã è¿å¹Žããããã®ç¡æ©ç©è³ªã®æ¬ ç¹ãæé€ãããã
ã«ãããããªææ©ç©è³ªãçšããé»ååççšæå äœ
ãææ¡ãããå®çšã«äŸãããŠãããã®ããããäŸ
ãã°ãããªââããã«ã«ã«ããŸãŒã«ãšïŒïŒïŒïŒ
ïŒâããªããããã«ãªã¬ã³âïŒâãªã³ãšãããªã
æå äœïŒç±³åœç¹èš±ç¬¬3484237å·æ现æžã«èšèŒïŒãã
ãªââããã«ã«ã«ããŸãŒã«ãããªãªãŠã å¡©ç³»è²
çŽ ã§å¢æããŠãªãæå äœïŒç¹å ¬æ48â25658å·å ¬
å ±ã«èšèŒïŒãææ©é¡æãäž»æåãšããæå äœïŒç¹
éæ47â37543å·å ¬å ±ã«èšèŒïŒãææãšæš¹èãšãã
ãªãå ±æ¶é¯äœãäž»æåãšããæå äœïŒç¹éæ47â
10735å·å ¬å ±ã«èšèŒïŒãªã©ã§ããã çºæã解決ããããšãã課é¡ïŒœ ãããã®æå äœã¯åªããç¹æ§ãæããŠããå®çš
çã«ã䟡å€ãé«ããšæããããã®ã§ããããé»å
åçæ³ã«ãããŠãæå äœã«å¯ŸãããããããªèŠæ±
ãèæ ®ãããšããŸã ãããã®èŠæ±ãååã«æºè¶³ã
ããã®ãåŸãããŠããªãã®ãå®ç¶ã§ããã ããããŠãæ¬çºæã®ç®çã¯ãå ã«è¿°ã¹ãåŸæ¥ã®
æå äœãšã¯ç°ãªããé»è·çºçç©è³ªãšé»è·æ¬éç©è³ª
ãšãçµåããŠå å°é»æ§ã瀺ãæå å±€ã«ãããŠãæ°
èŠãªé»æ°æ¬éç©è³ªãçšããæ床çã®é»ååçæ³ã«
ãããŠèŠæ±ãããæ¡ä»¶ãå åæºè¶³ããããã€ã補
é ã容æã§ãããæ¯èŒçå®äŸ¡ã«è¡ãªããèä¹ æ§ã«
ãåªããé»ååççšæå äœãæäŸããããšã«ã
ãã æ§ æ æ¬çºæè ã¯ãå€ãã®é»è·æ¬éç©è³ªã«ã€ããŠã®ç
究ãæ€èšãè¡ãªã€ãçµæãäžèšäžè¬åŒïŒïŒ ïŒåŒäžãAr1åã³Ar2ã¯ã眮æãããã¯ç¡çœ®æã®
ã¢ãªãŒã«åºïŒ»äœããåæã«ç¡çœ®æããšãã«åºã®å Ž
åã¯é€ããåã¯å ±åããŠç°ã圢æããåºãè¡šãã
Ar3ã¯ã眮æåã¯ç¡çœ®æã®ã¢ãªãŒã¬ã³åºãè¡šãã
R1ãR2åã³R3ã¯ãæ°ŽçŽ ååã眮æãããã¯ç¡çœ®
æã®ã¢ã«ãã«åºåã¯çœ®æãããã¯ç¡çœ®æã¢ãªãŒã«
åºãè¡šãããäžèšã¢ãªãŒã«åºåã³ã¢ãªãŒã¬ã³åºã®
眮æåºã¯ãã¢ã«ã³ãã·åºãããšããã·åºãã¢ã«ã
ã«åºãããããã·åºãããã²ã³ååãã·ã¢ãåºã
ãŸãã¯ãããåºã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§ã
ããïŒ ã§è¡šããããαâ眮æã¹ãã«ãã³ãŒã³ååç©ãé»
ååççšæå äœã®æ©èœåé¢åæå å±€ã«ãããé»è·
æ¬éç©è³ªãšããŠæå¹ã«æ©èœããããšãèŠåºããã
æ¬çºæã¯ãã®ç¥èŠã«åºã¥ããŠå®æããããã®ã§ã
ãã å³ã¡ãæ¬çºæã¯å°é»æ§æ¯æäœäžã«é»è·çºçç©è³ª
ãšé»è·æ¬éç©è³ªãšãçµåããŠå«æããæ©èœåé¢å
æå å±€ãèšããé»ååççšæå äœã«ãããŠãåèš
é»è·æ¬éç©è³ªãšããŠäžèšã®äžè¬åŒïŒïŒã§è¡šãã
ãαâ眮æã¹ãã«ãã³ååç©ãçšããããšãç¹åŸŽ
ãšãããã®ã§ããã äžèšäžè¬åŒïŒïŒã®R1ãR2åã³R3ã«ãããã¢
ã«ãã«åºãšããŠã¯ãã¡ãã«åºããšãã«åºãããã
ã«åºãããã«åºããã³ãã«åºãããã·ã«åºãªã©ã
ããããã眮æã¢ã«ãã«åºã«ããã眮æåºãšããŠ
ã¯ã¡ããã·åºããšããã·åºãããããã·åºããã
ãã·åºããã³ãã«ãªãã·åºãªã©ã®ã¢ã«ã³ãã·åºã
ããšããã·åºãããªã«ãªãã·åºããããã«ãªãã·
åºãªã©ã®ã¢ãªãŒã«ãªãã·åºãããšãã«åºãããã
ã«åºãªã©ã®ã¢ãªãŒã«åºããžã¡ãã«ã¢ããåºããžãš
ãã«ã¢ããåºããžãããã«ã¢ããåºãâã¡ãã«
âã»ãšãã«ã¢ããåºãªã©ã®ã¢ã«ãã«ã¢ããåºã
âããšãã«ã¢ããåºãïŒïŒ®âãžããšãã«ã¢ã
ãåºãªã©ã®ã¢ãªãŒã«ã¢ããåºãããããã·åºãã¢
ããåºãªã©ãããããããã¢ããåºäžã®çœ®æåºã¯
ããïŒã€åã¯ãã以äžã§ããããïŒã€ä»¥äžã®å Žå
ã¯åäžã®åºã§ãç°ãªãåºã§ãããã眮æã¢ã«ãã«
åºã®å ·äœäŸãšããŠã¯äŸãã°ãã¢ã«ã³ãã·ã¢ã«ãã«
åºãã¢ãªãŒã«ãªãã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«
åºãããããã·ã¢ã«ãã«åºãã¢ã©ã«ãã«åºãã¢ã«
ãã«ã¢ããã¢ã«ãã«åºãã¢ãªãŒã«ã¢ããã¢ã«ãã«
åºãªã©ããããããã ãŸããAr1ãAr2ãR1ãR2åã³R3ã«ãããã¢ãª
ãŒã«åºãšããŠã¯ççŽ ç°åŒãŸãã¯è€çŽ ç°åŒã®åæ žãŸ
ãã¯å€æ žã®è³éŠæç°æ®åºãæŽã«å ·äœçã«ã¯ããšã
ã«åºããããã«åºãã¢ã³ããªã«åºãããšãã«åºã
ããªãžã«åºãããªã«åºãã«ã«ããŸãªã«åºãããã¯
ã¹ããªã«åºãªã©ãããããã眮æã¢ãªãŒã«åºã«ã
ãã眮æåºãšããŠã¯ã¡ããã·åºããšããã·åºãã
ãããã·åºããããã·åºãªã©ã®ã¢ã«ã³ãã·åºãã¡
ãã«åºããšãã«åºããããã«åºãããã«åºãªã©ã®
ã¢ã«ãã«åºãããããã·åºãå¡©çŽ ååãèçŽ åå
ãªã©ã®ããã²ã³ååãã·ã¢ãåºããããåºãªã©ã
ãããããã ã¢ãªãŒã«åºäžã®çœ®æåºã¯ïŒã€ãŸãã¯ãã以äžã§
ããããïŒã€ä»¥äžã®å Žåã«ã¯åäžã®åºã§ãç°ãªã
åºã§ãããã Ar3ã®ã¢ãªãŒã¬ã³åºãšããŠã¯ãäžèšã®ççŽ ç°åŒ
ãŸãã¯è€çŽ ç°åŒã®åæ žãŸãã¯å€æ žã®è³éŠææ®åºã
ããããããŸã眮æã¢ãªãŒã¬ã³åºã«ããã眮æåº
ãšããŠã¯ãäžèšã®çœ®æã¢ãªãŒã«åºã«ããã眮æåº
ãããããããã¢ãªãŒã¬ã³åºã«ããã眮æåºã¯ïŒ
ã€ãŸãã¯ïŒã€ä»¥äžã§ããããïŒã€ä»¥äžã®å Žåã¯å
äžã®åºã§ããç°ãªãåºã§ãããã Ar1ãšAr2ãšã§å ±åããŠç°ã圢æãããã®ãšã
ãŠã¯ããã«ãªã¬ã³ãã·ã¯ããã³ã¿ãžãšã³ãã·ã¯ã
ãããµãžãšã³ãã·ã¯ãããã»ã³ãã·ã¯ããã³ã
ã³ãã€ã³ãã³ãïŒïŒïŒâãžããšãã«ã€ã³ãã³ã
5Hâãžãã³ãŸïŒ»ïœïŒïœïŒœã·ã¯ããããã³ã10ïŒ
11âãžãããâ5Hâãžãã³ãŸïŒ»ïœïŒïœïŒœã·ã¯ã
ãããã³ãããµã³ãã³åã³ããªããµã³ãã³ãªã©ã
ãããããããããã®ç°ã¯ãäžèšã®çœ®æåºãæã
ãŠãããã æ¬çºæã§çšããããåèšäžè¬åŒïŒïŒã§ç€ºãã
ãαâ眮æã¹ãã«ãã³ååç©ã¯ãäžèšäžè¬åŒ
ïŒïŒ åŒäžAr1åã³Ar2ã¯åã§å®çŸ©ãããšããã§ããã
ã¯â âïŒR4ïŒ3Z ïŒããã§R4ã¯ããšãã«åºå
ã¯äœçŽã¢ã«ãã«åºã ã¯ããã²ã³ã€ãªã³ã瀺
ãïŒã§è¡šãããããªããšãã«ãã¹ãããŠã åºãã
ããã¯ããªã¢ã«ãã«ãã¹ãããŠã å¡©ãåã¯âPO
ïŒOR5ïŒ2ïŒããã§R5ã¯äœçŽã¢ã«ãã«åºã瀺ãïŒã§è¡š
ãããããžã¢ã«ãã«äºçé žåºã§ãã ã§è¡šãããååç©ãšäžèšäžè¬åŒïŒïŒ ïŒåŒäžãR1ãR2ãR3ãAr3åã³ïœã¯åã§å®çŸ©ã
ããã®åäžã§ããïŒ ã§è¡šããããã«ã«ããã«ååç©ãšãåå¿ãããã
ãšã«ããåŸãããšãã§ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ã察å¿ãã
ããã¡ãã«ååç©ãšããªããšãã«ãã¹ãã€ã³ãã
ãã¯ããªã¢ã«ãã«ãã¹ãã€ã³ãåã¯äºãªã³é žããª
ã¢ã«ãã«ãšãçŽæ¥ãããã¯ãã«ãšã³ããã·ã¬ã³ç
ã®æº¶åªäžã§å ç±ããäºã«ãã容æã«è£œé ãããã
ããªã¢ã«ãã«ãã¹ãã€ã³ãšããŠã¯ççŽ æ°ïŒãïŒã®
ã¢ã«ãã«åºãç¹ã«ïœâããã«åºã奜ãŸããããŸã
äºãªã³é žããªã¢ã«ãã«ãšããŠã¯ççŽ æ°ïŒãïŒã®ã¢
ã«ãã«åºãç¹ã«ã¡ãã«åºããšãã«åºã奜ãŸããã ããããŠåŸãããäžè¬åŒïŒïŒã§è¡šããããå
åç©ãšäžè¬åŒïŒïŒã§è¡šããããã«ã«ããã«åå
ç©ãšãå¡©åºæ§è§Šåªã®ååšäžã宀枩ãã100âçšåºŠ
ã®æž©åºŠã«ãããŠåå¿ãããã å¡©åºæ§è§ŠåªãšããŠã¯ãèæ§ãœãŒããèæ§ã«ãªã
ãããªãŠã ã¢ãããæ°ŽçŽ åãããªãŠã åã³ãããª
ãŠã ã¡ãã©ãŒããã«ãªãŠã âïœâããããµã€ããª
ã©ã®ã¢ã«ã³ã©ãŒããæããããšãã§ããããŸãå
å¿æº¶åªãšããŠã¯ãã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœ
ãããããŒã«ããã¿ããŒã«ãïŒâã¡ããã·ãšã¿ã
ãŒã«ãïŒïŒïŒâãžã¡ããã·ãšã¿ã³ããã¹ïŒïŒâã¡
ããã·ãšãã«ïŒãšãŒãã«ããžãªããµã³ãããã©ã
ãããã©ã³ããã«ãšã³ããã·ã¬ã³ããžã¡ãã«ã¹ã«
ããã·ããïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããâ
ã¡ãã«ãããªãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã€ã
ããŸãªãžãã³ãªã©ãæããããšãã§ãããäžã§ã
極æ§æº¶åªãäŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãã
åã³ãžã¡ãã«ã¹ã«ããã·ãã奜é©ã§ããã åå¿æž©åºŠã¯ã(1)䜿çšãã溶åªã®å¡©åºæ§è§Šåªã«å¯Ÿ
ããå®å®æ§ã(2)çž®åæåïŒäžè¬åŒïŒïŒåã³
ïŒïŒã®ååç©ïŒã®åå¿æ§ã(3)åèšå¡©åºæ§è§Šåªã®
溶åªäžã«ãããçž®åå€ãšããŠã®åå¿æ§ã«ãã€ãŠåº
ç¯å²ã«éžæããããšãã§ãããäŸãã°æ¥µæ§æº¶åªã
çšããæã¯ãå®éã«ã¯å®€æž©ãã100âã奜ãŸãã
ã¯å®€æž©ãã80âã§ãããããããåå¿æéã®ççž®
åã¯æŽ»æ§ã®äœãçž®åå€ã䜿çšããæã¯é«ã枩床ã§
ãããã ããããŠåŸãããäžè¬åŒïŒïŒã§è¡šããããα
â眮æã¹ãã«ãã³ååç©ã®å ·äœäŸã以äžã«äŸç€ºã
ãã
å å±€äžã«ç¹å®ã®Î±â眮æã¹ãã«ãã³ååç©ãé»è·
æ¬éç©è³ªãšããŠå«æããæ©èœåé¢åæå å±€ãšãã
é»ååççšæå äœã«é¢ããã åŸæ¥æè¡ åŸæ¥ãé»ååçæ¹åŒã«ãããŠäœ¿çšãããæå äœ
ã®å å°é»æ§çŽ æãšããŠçšããããŠãããã®ã«ã»ã¬
ã³ãç¡«åã«ãããŠã ãé žåäºéãªã©ã®ç¡æ©ç©è³ªã
ãããããã«ãããé»ååçæ¹åŒããšã¯ãäžè¬ã«
å å°é»æ§ã®æå äœããŸãææã§ãäŸãã°ã³ããæŸ
é»ã«ãã€ãŠåž¯é»ãããã次ãã§åé²å ããé²å éš
ã®ã¿ã®é»è·ãéžæçã«éžæ£ããããŠéé»æœåã
åŸããã®æœåéšãææãé¡æãªã©ã®çè²æãšé«å
åç©è³ªãªã©ã®çµåå€ãšããæ§æãããæ€é»åŸ®ç²å
ïŒãããŒïŒã§çŸåãå¯èŠåããŠç»åã圢æããã
ãã«ããç»å圢ææ³ã®äžã€ã§ããã ãã®ãããªé»ååçæ³ã«ãããŠæå äœã«èŠæ±ã
ããåºæ¬çãªç¹æ§ãšããŠã¯ã(1)ææã§é©åœãªé»äœ
ã«åž¯é»ã§ããããšã(2)ææã«ãããŠé»è·ã®éžæ£ã
å°ãªãããšã(3)å ç §å°ã«ãã€ãŠéããã«é»è·ãéž
æ£ããããããšãªã©ããããããã ãšããã§ãåèšã®ç¡æ©ç©è³ªã¯ããããå€ãã®é·
æããã€ãŠãããšåæã«ãããŸããŸãªæ¬ ç¹ããæ
ããŠããã®ãäºå®ã§ãããäŸãã°ãçŸåšåºãçšã
ãããŠããã»ã¬ã³ã¯åèš(1)ã(3)ã®æ¡ä»¶ã¯å åã«æº
足ãããã補é ããæ¡ä»¶ããããããã補é ã³ã¹
ããé«ããªããå¯ææ§ããªãããã«ãç¶ã«å å·¥ã
ãããšãããããããç±ãæ©æ¢°çã®è¡æã«éæãª
ããåæ±ãã«æ³šæãèŠãããªã©ã®æ¬ ç¹ããããç¡«
åã«ãããŠã ãé žåäºéã¯ãçµåå€ãšããŠã®æš¹è
ã«åæ£ãããŠæå äœãšããŠçšããããŠããããå¹³
æ»æ§ã硬床ãåŒåŒµã匷床ãèæ©æŠæ§ãªã©ã®æ©æ¢°ç
ãªæ¬ ç¹ãããããã«ãã®ãŸãŸã§ã¯å埩ããŠäœ¿çšã
ãããšãã§ããªãã è¿å¹Žããããã®ç¡æ©ç©è³ªã®æ¬ ç¹ãæé€ãããã
ã«ãããããªææ©ç©è³ªãçšããé»ååççšæå äœ
ãææ¡ãããå®çšã«äŸãããŠãããã®ããããäŸ
ãã°ãããªââããã«ã«ã«ããŸãŒã«ãšïŒïŒïŒïŒ
ïŒâããªããããã«ãªã¬ã³âïŒâãªã³ãšãããªã
æå äœïŒç±³åœç¹èš±ç¬¬3484237å·æ现æžã«èšèŒïŒãã
ãªââããã«ã«ã«ããŸãŒã«ãããªãªãŠã å¡©ç³»è²
çŽ ã§å¢æããŠãªãæå äœïŒç¹å ¬æ48â25658å·å ¬
å ±ã«èšèŒïŒãææ©é¡æãäž»æåãšããæå äœïŒç¹
éæ47â37543å·å ¬å ±ã«èšèŒïŒãææãšæš¹èãšãã
ãªãå ±æ¶é¯äœãäž»æåãšããæå äœïŒç¹éæ47â
10735å·å ¬å ±ã«èšèŒïŒãªã©ã§ããã çºæã解決ããããšãã課é¡ïŒœ ãããã®æå äœã¯åªããç¹æ§ãæããŠããå®çš
çã«ã䟡å€ãé«ããšæããããã®ã§ããããé»å
åçæ³ã«ãããŠãæå äœã«å¯ŸãããããããªèŠæ±
ãèæ ®ãããšããŸã ãããã®èŠæ±ãååã«æºè¶³ã
ããã®ãåŸãããŠããªãã®ãå®ç¶ã§ããã ããããŠãæ¬çºæã®ç®çã¯ãå ã«è¿°ã¹ãåŸæ¥ã®
æå äœãšã¯ç°ãªããé»è·çºçç©è³ªãšé»è·æ¬éç©è³ª
ãšãçµåããŠå å°é»æ§ã瀺ãæå å±€ã«ãããŠãæ°
èŠãªé»æ°æ¬éç©è³ªãçšããæ床çã®é»ååçæ³ã«
ãããŠèŠæ±ãããæ¡ä»¶ãå åæºè¶³ããããã€ã補
é ã容æã§ãããæ¯èŒçå®äŸ¡ã«è¡ãªããèä¹ æ§ã«
ãåªããé»ååççšæå äœãæäŸããããšã«ã
ãã æ§ æ æ¬çºæè ã¯ãå€ãã®é»è·æ¬éç©è³ªã«ã€ããŠã®ç
究ãæ€èšãè¡ãªã€ãçµæãäžèšäžè¬åŒïŒïŒ ïŒåŒäžãAr1åã³Ar2ã¯ã眮æãããã¯ç¡çœ®æã®
ã¢ãªãŒã«åºïŒ»äœããåæã«ç¡çœ®æããšãã«åºã®å Ž
åã¯é€ããåã¯å ±åããŠç°ã圢æããåºãè¡šãã
Ar3ã¯ã眮æåã¯ç¡çœ®æã®ã¢ãªãŒã¬ã³åºãè¡šãã
R1ãR2åã³R3ã¯ãæ°ŽçŽ ååã眮æãããã¯ç¡çœ®
æã®ã¢ã«ãã«åºåã¯çœ®æãããã¯ç¡çœ®æã¢ãªãŒã«
åºãè¡šãããäžèšã¢ãªãŒã«åºåã³ã¢ãªãŒã¬ã³åºã®
眮æåºã¯ãã¢ã«ã³ãã·åºãããšããã·åºãã¢ã«ã
ã«åºãããããã·åºãããã²ã³ååãã·ã¢ãåºã
ãŸãã¯ãããåºã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§ã
ããïŒ ã§è¡šããããαâ眮æã¹ãã«ãã³ãŒã³ååç©ãé»
ååççšæå äœã®æ©èœåé¢åæå å±€ã«ãããé»è·
æ¬éç©è³ªãšããŠæå¹ã«æ©èœããããšãèŠåºããã
æ¬çºæã¯ãã®ç¥èŠã«åºã¥ããŠå®æããããã®ã§ã
ãã å³ã¡ãæ¬çºæã¯å°é»æ§æ¯æäœäžã«é»è·çºçç©è³ª
ãšé»è·æ¬éç©è³ªãšãçµåããŠå«æããæ©èœåé¢å
æå å±€ãèšããé»ååççšæå äœã«ãããŠãåèš
é»è·æ¬éç©è³ªãšããŠäžèšã®äžè¬åŒïŒïŒã§è¡šãã
ãαâ眮æã¹ãã«ãã³ååç©ãçšããããšãç¹åŸŽ
ãšãããã®ã§ããã äžèšäžè¬åŒïŒïŒã®R1ãR2åã³R3ã«ãããã¢
ã«ãã«åºãšããŠã¯ãã¡ãã«åºããšãã«åºãããã
ã«åºãããã«åºããã³ãã«åºãããã·ã«åºãªã©ã
ããããã眮æã¢ã«ãã«åºã«ããã眮æåºãšããŠ
ã¯ã¡ããã·åºããšããã·åºãããããã·åºããã
ãã·åºããã³ãã«ãªãã·åºãªã©ã®ã¢ã«ã³ãã·åºã
ããšããã·åºãããªã«ãªãã·åºããããã«ãªãã·
åºãªã©ã®ã¢ãªãŒã«ãªãã·åºãããšãã«åºãããã
ã«åºãªã©ã®ã¢ãªãŒã«åºããžã¡ãã«ã¢ããåºããžãš
ãã«ã¢ããåºããžãããã«ã¢ããåºãâã¡ãã«
âã»ãšãã«ã¢ããåºãªã©ã®ã¢ã«ãã«ã¢ããåºã
âããšãã«ã¢ããåºãïŒïŒ®âãžããšãã«ã¢ã
ãåºãªã©ã®ã¢ãªãŒã«ã¢ããåºãããããã·åºãã¢
ããåºãªã©ãããããããã¢ããåºäžã®çœ®æåºã¯
ããïŒã€åã¯ãã以äžã§ããããïŒã€ä»¥äžã®å Žå
ã¯åäžã®åºã§ãç°ãªãåºã§ãããã眮æã¢ã«ãã«
åºã®å ·äœäŸãšããŠã¯äŸãã°ãã¢ã«ã³ãã·ã¢ã«ãã«
åºãã¢ãªãŒã«ãªãã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«
åºãããããã·ã¢ã«ãã«åºãã¢ã©ã«ãã«åºãã¢ã«
ãã«ã¢ããã¢ã«ãã«åºãã¢ãªãŒã«ã¢ããã¢ã«ãã«
åºãªã©ããããããã ãŸããAr1ãAr2ãR1ãR2åã³R3ã«ãããã¢ãª
ãŒã«åºãšããŠã¯ççŽ ç°åŒãŸãã¯è€çŽ ç°åŒã®åæ žãŸ
ãã¯å€æ žã®è³éŠæç°æ®åºãæŽã«å ·äœçã«ã¯ããšã
ã«åºããããã«åºãã¢ã³ããªã«åºãããšãã«åºã
ããªãžã«åºãããªã«åºãã«ã«ããŸãªã«åºãããã¯
ã¹ããªã«åºãªã©ãããããã眮æã¢ãªãŒã«åºã«ã
ãã眮æåºãšããŠã¯ã¡ããã·åºããšããã·åºãã
ãããã·åºããããã·åºãªã©ã®ã¢ã«ã³ãã·åºãã¡
ãã«åºããšãã«åºããããã«åºãããã«åºãªã©ã®
ã¢ã«ãã«åºãããããã·åºãå¡©çŽ ååãèçŽ åå
ãªã©ã®ããã²ã³ååãã·ã¢ãåºããããåºãªã©ã
ãããããã ã¢ãªãŒã«åºäžã®çœ®æåºã¯ïŒã€ãŸãã¯ãã以äžã§
ããããïŒã€ä»¥äžã®å Žåã«ã¯åäžã®åºã§ãç°ãªã
åºã§ãããã Ar3ã®ã¢ãªãŒã¬ã³åºãšããŠã¯ãäžèšã®ççŽ ç°åŒ
ãŸãã¯è€çŽ ç°åŒã®åæ žãŸãã¯å€æ žã®è³éŠææ®åºã
ããããããŸã眮æã¢ãªãŒã¬ã³åºã«ããã眮æåº
ãšããŠã¯ãäžèšã®çœ®æã¢ãªãŒã«åºã«ããã眮æåº
ãããããããã¢ãªãŒã¬ã³åºã«ããã眮æåºã¯ïŒ
ã€ãŸãã¯ïŒã€ä»¥äžã§ããããïŒã€ä»¥äžã®å Žåã¯å
äžã®åºã§ããç°ãªãåºã§ãããã Ar1ãšAr2ãšã§å ±åããŠç°ã圢æãããã®ãšã
ãŠã¯ããã«ãªã¬ã³ãã·ã¯ããã³ã¿ãžãšã³ãã·ã¯ã
ãããµãžãšã³ãã·ã¯ãããã»ã³ãã·ã¯ããã³ã
ã³ãã€ã³ãã³ãïŒïŒïŒâãžããšãã«ã€ã³ãã³ã
5Hâãžãã³ãŸïŒ»ïœïŒïœïŒœã·ã¯ããããã³ã10ïŒ
11âãžãããâ5Hâãžãã³ãŸïŒ»ïœïŒïœïŒœã·ã¯ã
ãããã³ãããµã³ãã³åã³ããªããµã³ãã³ãªã©ã
ãããããããããã®ç°ã¯ãäžèšã®çœ®æåºãæã
ãŠãããã æ¬çºæã§çšããããåèšäžè¬åŒïŒïŒã§ç€ºãã
ãαâ眮æã¹ãã«ãã³ååç©ã¯ãäžèšäžè¬åŒ
ïŒïŒ åŒäžAr1åã³Ar2ã¯åã§å®çŸ©ãããšããã§ããã
ã¯â âïŒR4ïŒ3Z ïŒããã§R4ã¯ããšãã«åºå
ã¯äœçŽã¢ã«ãã«åºã ã¯ããã²ã³ã€ãªã³ã瀺
ãïŒã§è¡šãããããªããšãã«ãã¹ãããŠã åºãã
ããã¯ããªã¢ã«ãã«ãã¹ãããŠã å¡©ãåã¯âPO
ïŒOR5ïŒ2ïŒããã§R5ã¯äœçŽã¢ã«ãã«åºã瀺ãïŒã§è¡š
ãããããžã¢ã«ãã«äºçé žåºã§ãã ã§è¡šãããååç©ãšäžèšäžè¬åŒïŒïŒ ïŒåŒäžãR1ãR2ãR3ãAr3åã³ïœã¯åã§å®çŸ©ã
ããã®åäžã§ããïŒ ã§è¡šããããã«ã«ããã«ååç©ãšãåå¿ãããã
ãšã«ããåŸãããšãã§ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ã察å¿ãã
ããã¡ãã«ååç©ãšããªããšãã«ãã¹ãã€ã³ãã
ãã¯ããªã¢ã«ãã«ãã¹ãã€ã³ãåã¯äºãªã³é žããª
ã¢ã«ãã«ãšãçŽæ¥ãããã¯ãã«ãšã³ããã·ã¬ã³ç
ã®æº¶åªäžã§å ç±ããäºã«ãã容æã«è£œé ãããã
ããªã¢ã«ãã«ãã¹ãã€ã³ãšããŠã¯ççŽ æ°ïŒãïŒã®
ã¢ã«ãã«åºãç¹ã«ïœâããã«åºã奜ãŸããããŸã
äºãªã³é žããªã¢ã«ãã«ãšããŠã¯ççŽ æ°ïŒãïŒã®ã¢
ã«ãã«åºãç¹ã«ã¡ãã«åºããšãã«åºã奜ãŸããã ããããŠåŸãããäžè¬åŒïŒïŒã§è¡šããããå
åç©ãšäžè¬åŒïŒïŒã§è¡šããããã«ã«ããã«åå
ç©ãšãå¡©åºæ§è§Šåªã®ååšäžã宀枩ãã100âçšåºŠ
ã®æž©åºŠã«ãããŠåå¿ãããã å¡©åºæ§è§ŠåªãšããŠã¯ãèæ§ãœãŒããèæ§ã«ãªã
ãããªãŠã ã¢ãããæ°ŽçŽ åãããªãŠã åã³ãããª
ãŠã ã¡ãã©ãŒããã«ãªãŠã âïœâããããµã€ããª
ã©ã®ã¢ã«ã³ã©ãŒããæããããšãã§ããããŸãå
å¿æº¶åªãšããŠã¯ãã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœ
ãããããŒã«ããã¿ããŒã«ãïŒâã¡ããã·ãšã¿ã
ãŒã«ãïŒïŒïŒâãžã¡ããã·ãšã¿ã³ããã¹ïŒïŒâã¡
ããã·ãšãã«ïŒãšãŒãã«ããžãªããµã³ãããã©ã
ãããã©ã³ããã«ãšã³ããã·ã¬ã³ããžã¡ãã«ã¹ã«
ããã·ããïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããâ
ã¡ãã«ãããªãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã€ã
ããŸãªãžãã³ãªã©ãæããããšãã§ãããäžã§ã
極æ§æº¶åªãäŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãã
åã³ãžã¡ãã«ã¹ã«ããã·ãã奜é©ã§ããã åå¿æž©åºŠã¯ã(1)䜿çšãã溶åªã®å¡©åºæ§è§Šåªã«å¯Ÿ
ããå®å®æ§ã(2)çž®åæåïŒäžè¬åŒïŒïŒåã³
ïŒïŒã®ååç©ïŒã®åå¿æ§ã(3)åèšå¡©åºæ§è§Šåªã®
溶åªäžã«ãããçž®åå€ãšããŠã®åå¿æ§ã«ãã€ãŠåº
ç¯å²ã«éžæããããšãã§ãããäŸãã°æ¥µæ§æº¶åªã
çšããæã¯ãå®éã«ã¯å®€æž©ãã100âã奜ãŸãã
ã¯å®€æž©ãã80âã§ãããããããåå¿æéã®ççž®
åã¯æŽ»æ§ã®äœãçž®åå€ã䜿çšããæã¯é«ã枩床ã§
ãããã ããããŠåŸãããäžè¬åŒïŒïŒã§è¡šããããα
â眮æã¹ãã«ãã³ååç©ã®å ·äœäŸã以äžã«äŸç€ºã
ãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
以äžã«æ¬çºæãæ·»ä»ã®å³é¢ãåç
§ããªããæŽã«
詳现ã«èª¬æããã第ïŒå³ãªãã第ïŒå³ã¯æ¬çºæã«
ä¿ãæå äœã®ä»£è¡šçãªäºäŸã®æé¢å³ã§ããããã
ã«ä»ãããçªå·ã§ïŒã¯å°é»æ§æ¯æäœãïŒâ²ïŒïŒâ³ã¯
æå å±€ãïŒã¯é»è·çºçç©è³ªãïŒã¯é»è·æ¬éåªäœå
ã¯é»è·æ¬éå±€ãïŒã¯é»è·çºçå±€ãè¡šãããŠããã æ¬çºææ©èœåé¢åæå å±€ã®æ§æã¯ããã®ç¬¬ïŒ
å³ã第ïŒå³ã«ç€ºããããšãã«çšããããšãã§ã
ãã 第ïŒå³ã«ãããæå äœã¯ãå°é»æ§æ¯æäœïŒäžã«
é»è·çºçç©è³ªç²åïŒãαâ眮æã¹ãã«ãã³ååç©
ãšçµåå€ãšãããªãé»è·æ¬éåªäœïŒã®äžã«åæ£ã
ãããæå å±€ïŒâ²ãèšãããããã®ã§ããããã
ã§ã®Î±â眮æã¹ãã«ãã³ååç©ã¯çµåå€ïŒåã¯çµ
åå€åã³å¯å¡å€ïŒãšãšãã«é»è·æ¬éåªäœã圢æ
ããäžæ¹ãé»è·çºçç©è³ªç²åïŒïŒç¡æ©åã¯ææ©é¡
æã®ãããªé»è·çºçç©è³ªç²åïŒãé»è·æ äœãçºç
ããããã®å Žåãé»è·æ¬éåªäœïŒã¯äž»ãšããŠé»è·
çºçç©è³ªç²åïŒãçºçããé»è·æ äœãåå ¥ããã
ããæ¬éããäœçšãæ åœããŠããããããŠããã®
æå äœã«ãã€ãŠã¯é»è·çºçç©è³ªãšÎ±â眮æã¹ãã«
ãã³ååç©ãšãäºãã«äž»ãšããŠå¯èŠé åã«ãããŠ
åžåæ³¢é·é åãéãªããªããšããã®ãåºæ¬çæ¡ä»¶
ã§ãããããã¯é»è·çºçç©è³ªç²åïŒã¯é»è·æ äœã
å¹çããçºçãããããã«ã¯ãé»è·çºçç©è³ªç²å
è¡šé¢ãŸã§ãå ãééãããå¿ èŠãããããã§ã
ããäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å¯èŠé å
ã«ã»ãšãã©åžåããªããäžè¬ã«å¯èŠé åã®å ç·ã
åžåããé»è·æ äœãçºçããé»è·çºçç©è³ªç²åïŒ
ãšçµåããå Žåãç¹ã«æå¹ã«é»è·æ¬éç©è³ªç²åãš
ããŠåãã®ããã®ç¹åŸŽã§ããã 第ïŒå³ã«ãããæå äœã¯ãå°é»æ§æ¯æäœïŒäžã«
é»è·çºçç©è³ªïŒãäž»äœãšããé»è·çºçå±€ïŒãšÎ±â
眮æã¹ãã«ãã³ååç©ãšçµçå€ãå«æãé»è·æ¬é
åªäœïŒãšã®ç©å±€ãããªãæå å±€ïŒâ³ãèšãããã
ãã®ã§ããããã®æå äœã§ã¯ãé»è·æ¬éå±€ïŒãé
éããå ãé»è·çºçå±€ïŒã«å°éãããã®é åã§é»
è·æ äœã®çºçãèµ·ãããäžæ¹ãé»è·æ¬éå±€ïŒã¯é»
è·æ äœã®æ³šå ¥ãåãããã®æ¬éãè¡ãªããã®ã§ã
å æžè¡°ã«å¿ èŠãªé»è·æ äœã®çºçã¯ãé»è·çºçç©è³ª
ç²åïŒã§è¡ãªããããŸãé»è·æ äœã®æ¬éã¯ãé»è·
æ¬éå±€ïŒïŒäž»ãšããŠäžè¬åŒïŒïŒã®ååç©ãå
ãïŒã§è¡ãªããããããããæ©æ§ã¯ç¬¬ïŒå³ã«ç€ºã
ãæå äœã«ãããŠãã説æãšåæ§ã§ãããåãé»
è·çºçå±€ïŒãšé»è·æ¬éå±€ïŒãšã®ç©å±€é ãéã«ããŠ
ãããããšã¯å®¹æã«ç解ããããã 第ïŒå³ã«ç€ºããæå äœãäœè£œããã«ã¯ãïŒçš®å
ã¯ïŒçš®ä»¥äžã®Î±â眮æã¹ãã«ãã³ååç©ãšçµåå€
ãšæº¶è§£ãã溶液ã«é»è·çºçç©è³ªïŒã®åŸ®ç²åãšåæ£
ãããããããå°é»æ§æ¯æäœïŒäžã«å¡åžãã也ç¥
ããŠæå å±€ïŒâ²ã圢æããã°ããã æå å±€ïŒâ²ã®åãã¯ïŒã50ÎŒïœã奜ãŸããã¯ïŒ
ã20ÎŒïœãé©åœã§ãããæå å±€ïŒâ²ã«å ããαâ
眮æã¹ãã«ãã³ååç©ã®éã¯10ã95ééïŒ ã奜ãŸ
ããã¯30ã90ééïŒ ã§ããããŸããæå å±€ïŒâ²ã«
å ããé»è·çºçç©è³ªïŒã®éã¯0.1ã50ééïŒ å¥œãŸ
ããã¯ïŒã20ééïŒ ã§ãããé»è·çºçç©è³ªïŒãšã
ãŠã¯ãäŸãã°ã»ã¬ã³ãã»ã¬ã³âãã«ã«ãç¡«åã«ã
ããŠã ãç¡«åã«ãããŠã âã»ã¬ã³ãαâã·ãªã³ã³
ãªã©ã®ç¡æ©é¡æãææ©é¡æãšããŠã¯äŸãã°ã·ãŒã¢
ã€ãã°ã¡ã³ããã«â25ïŒã«ã©ãŒã€ã³ããã¯ã¹
CI21180ïŒãã·ãŒã€ã¢ãã°ã¡ã³ãã¬ãã41ïŒCI
21200ïŒãã·ãŒã¢ã€ã¢ã·ããã¬ãã52ïŒCI 45100ïŒã
ã·ãŒã¢ã€ããŒã·ãã¯ã¬ããïŒïŒCI 45210ïŒãã«ã«
ããŸãŒã«éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ53â
95033å·å ¬å ±ã«èšèŒïŒããžã¹ããªã«ãã³ãŒã³éªšæ Œã
æããã¢ãŸé¡æïŒç¹éæ53â133445å·å ¬å ±ã«èš
èŒïŒãããªããšãã«ã¢ãã³éªšæ Œãæããã¢ãŸé¡æ
ïŒç¹éæ53â132347å·å ¬å ±ã«èšèŒïŒããžãã³ãŸããª
ããšã³éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â21728
å·å ¬å ±ã«èšèŒïŒããªããµãžã¢ãŸãŒã«éªšæ Œãæãã
ã¢ãŸé¡æïŒç¹éæ54â12742å·å ¬å ±ã«èšèŒïŒããã«
ãªã¬ãã³éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â
22834å·å ¬å ±ã«èšèŒïŒããã¹ã¹ãã«ãã³éªšæ Œãæã
ãã¢ãŸé¡æïŒç¹éæ54â17733å·å ¬å ±ã«èšèŒïŒããž
ã¹ããªã«ãªããµãžã¢ãŸãŒã«éªšæ Œãæããã¢ãŸé¡æ
ïŒç¹éæ54â2129å·å ¬å ±ã«èšèŒïŒããžã¹ããªã«ã«ã«
ããŸãŒã«éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â
14976å·å ¬å ±ã«èšèŒïŒãªã©ã®ã¢ãŸé¡æãäŸãã°ã·
ãŒã¢ã€ãã°ã¡ã³ããã«ãŒ16ïŒCI 741100ïŒãªã©ã®
ãã¿ãã·ã¢ãã³ç³»é¡æãäŸãã°ã·ãŒã¢ã€ãããã
ã©ãŠã³ïŒïŒCI 73410ïŒãã·ãŒã¢ã€ããããã€ïŒCI
73030ïŒãªã©ã®ã€ã³ãžãŽç³»é¡æãã¢ã«ãŽã¹ã«ãŒã¬
ããïŒãã€ãšã«ç€Ÿè£œïŒãã€ã³ãã¹ã¬ã³ã¹ã«ãŒã¬ã
ãïŒãã€ãšã«ç€Ÿè£œïŒãªã©ã®ããªã¬ã³ç³»é¡æãªã©
ãæããããããªãããããã®é»è·çºçç©è³ªã¯å
ç¬ã§çšããããŠãïŒçš®é¡ä»¥äžã䜵çšãããŠãã
ãã åã第ïŒå³ã«ç€ºããæå äœãäœè£œããã«ã¯ãå°
é»æ§æ¯æäœïŒäžã«é»è·çºçç©è³ªãç空èžçããã
æãã¯ãé»è·çºçç©è³ªã®åŸ®ç²åïŒãå¿ èŠã«ãã€ãŠ
çµåå€ã溶解ããé©åœã«æº¶åªäžã«åæ£ããåæ£æ¶²
ãå¡åžã也ç¥ãããããŠãæŽã«å¿ èŠã§ããã°ãã
ç 磚ãªã©ã®æ¹æ³ã«ãã€ãŠè¡šé¢ä»äžããèå調æŽãª
ã©ãè¡ã€ãŠé»è·çºçå±€ïŒã圢æãããã®äžã«ïŒçš®
åã¯ïŒçš®ä»¥äžÎ±â眮æã¹ãã«ãã³ååç©ãšçµåå€
ãšã溶解ãã溶液ãå¡åžã也ç¥ããŠé»è·æ¬éå±€ïŒ
ã圢æããã°ããããªããããã§é»è·çºçå±€ïŒã®
圢æã«çšããããé»è·çºçç©è³ªã¯åèšã®æå å±€
ïŒâ²ã®èª¬æã«ãããŠããã®ãšåããã®ã§ããã é»è·çºçå±€ïŒã®åãã¯5ÎŒïœä»¥äžå¥œãŸããã¯2ÎŒ
ïœä»¥äžã§ãããé»è·æ¬éå±€ïŒã®åãã¯ïŒã50ÎŒïœ
奜ãŸããã¯ïŒã20ÎŒïœãé©åœã§ãããé»è·çºçå±€
ïŒãé»è·çºçç©è³ªã®åŸ®ç²åïŒãçµåå€äžã«åæ£ã
ããã¿ã€ãã®ãã®ã«ãã€ãŠã¯ãé»è·çºçç©è³ªã®åŸ®
ç²åïŒã®é»è·çºçå±€ïŒã«å ããå²åã¯10ã95éé
ïŒ ã奜ãŸããã¯50ã90ééïŒ çšåºŠã§ããããŸãã
é»è·æ¬éå±€ïŒã«å ããαâ眮æã¹ãã«ãã³ååç©
ã®éã¯ã10ã95ééïŒ å¥œãŸããã¯30ã90ééïŒ ã§
ããã ãªãããããã®ãããã®æå äœè£œé ã«ãããŠã¯
å°é»æ§æ¯æäœïŒã«ãã¢ã«ãããŠã ãªã©ã®éå±æ¿å
ã¯éå±ç®ãã¢ã«ãããŠã ãªã©ã®éå±ãèžçããã
ã©ã¹ããã¯ãã€ã«ã ããããã¯ãå°é»åŠçãæœã
ãçŽãªã©ãçšããããããŸããçµåå€ãšããŠã¯ã
ããªã¢ãããããªãŠã¬ã¿ã³ãããªãšã¹ãã«ããšã
ãã·æš¹èãããªã±ãã³ãããªã«ãŒãããŒããªã©ã®
çž®åæš¹èããããªããã«ã±ãã³ãããªã¹ãã¬ã³ã
ããªââããã«ã«ã«ããŸãŒã«ãããªã¢ã¯ãªã«ã¢
ããã®ãããªããã«éåäœãªã©ãçšãããããã
絶çžæ§ã§ãã€æ¥çæ§ã®ããæš¹èã¯ãã¹ãŠäœ¿çšãã§
ãããå¿ èŠã«ããå¯å¡å€ãçµåå€ã«å ãããã
ããããããå¯å¡å€ãšããŠã¯ããã²ã³åãã©ãã€
ã³ãããªå¡©åãããšãã«ããžã¡ãã«ããã¿ãªã³ã
ãžããã«ãã¿ã¬ãŒããªã©ãäŸç€ºã§ããã æŽã«ã以äžã®ããã«ããŠåŸãããæå äœã«ã¯ã
å°é»æ§æ¯æäœãšæå å±€ã®éã«ãå¿ èŠã«å¿ããŠæ¥ç
å±€åã¯ããªã€å±€ãèšããããšãã§ããããããã®
å±€ã«çšããããææãšããŠã¯ãããªã¢ããããã
ãã»ã«ããŒã¹ãé žåã¢ã«ãããŠã ãªã©ã§ããããŸ
ãèåã¯1ÎŒïœä»¥äžã奜ãŸããã æ¬çºæã®æå äœãçšããŠè¢«åãè¡ãªãã«ã¯ãæ
å é¢ã«åž¯é»ãé²å ãæœããåŸãçŸåãè¡ãªããå¿
èŠã«ãã€ãŠãçŽãªã©ãžè»¢åãè¡ãªããæ¬çºæã®æ
å äœã¯æ床ãé«ãããŸãå¯ææ§ã«å¯ããªã©ã®åªã
ãå©ç¹ãæããŠããã 以äžã«äŸç€ºååç©No.13ã®è£œé äŸã瀺ãã 補é äŸ ïŒâããªâïœâããã«ãã¹ãããŠã ãã«ãªã¬ã
ãªã4.40ïœãšïŒïŒ4â²âãžã¡ãã«â4â³âãã«ãã«ã
ãªããšãã«ã¢ãã³3.62ïœã也ç¥ãã³ãŒã³40ml溶解
ããçªçŽ æ°æµäžïŒæéå ç±éæµããã宀枩ãŸã§å·
åŽåŸæº¶åªãæžå§äžçå»ããã®ã¡ã«ã©ã ã¯ããã
ïŒã·ãªã«ã²ã«ã溶é¢æ¶²ãã«ãšã³ïŒåŠçãããåŸã
ããé»æ©è²ç²æ«ãé ¢é žãšãã«ãšãšã¿ããŒã«ã®æ··å
溶åªããåçµæ¶ãé»æ©è²ããªãºã ç¶çµæ¶ã®ïŒâ
ïŒâïŒïŒ®ïŒïŒ®âãžâïœâããªã«ã¢ããïŒãã³ãžãª
ãã³ïŒœãã«ãªã¬ã³ïŒäŸç€ºååç©No.13ïŒ1.64ïœãåŸ
ããèç¹ã¯149.5ã150.5âã§ãã€ãã å çŽ åæå€ã¯C14H27NãšããŠäžèšã®ãšããã§ã
ã€ãã
詳现ã«èª¬æããã第ïŒå³ãªãã第ïŒå³ã¯æ¬çºæã«
ä¿ãæå äœã®ä»£è¡šçãªäºäŸã®æé¢å³ã§ããããã
ã«ä»ãããçªå·ã§ïŒã¯å°é»æ§æ¯æäœãïŒâ²ïŒïŒâ³ã¯
æå å±€ãïŒã¯é»è·çºçç©è³ªãïŒã¯é»è·æ¬éåªäœå
ã¯é»è·æ¬éå±€ãïŒã¯é»è·çºçå±€ãè¡šãããŠããã æ¬çºææ©èœåé¢åæå å±€ã®æ§æã¯ããã®ç¬¬ïŒ
å³ã第ïŒå³ã«ç€ºããããšãã«çšããããšãã§ã
ãã 第ïŒå³ã«ãããæå äœã¯ãå°é»æ§æ¯æäœïŒäžã«
é»è·çºçç©è³ªç²åïŒãαâ眮æã¹ãã«ãã³ååç©
ãšçµåå€ãšãããªãé»è·æ¬éåªäœïŒã®äžã«åæ£ã
ãããæå å±€ïŒâ²ãèšãããããã®ã§ããããã
ã§ã®Î±â眮æã¹ãã«ãã³ååç©ã¯çµåå€ïŒåã¯çµ
åå€åã³å¯å¡å€ïŒãšãšãã«é»è·æ¬éåªäœã圢æ
ããäžæ¹ãé»è·çºçç©è³ªç²åïŒïŒç¡æ©åã¯ææ©é¡
æã®ãããªé»è·çºçç©è³ªç²åïŒãé»è·æ äœãçºç
ããããã®å Žåãé»è·æ¬éåªäœïŒã¯äž»ãšããŠé»è·
çºçç©è³ªç²åïŒãçºçããé»è·æ äœãåå ¥ããã
ããæ¬éããäœçšãæ åœããŠããããããŠããã®
æå äœã«ãã€ãŠã¯é»è·çºçç©è³ªãšÎ±â眮æã¹ãã«
ãã³ååç©ãšãäºãã«äž»ãšããŠå¯èŠé åã«ãããŠ
åžåæ³¢é·é åãéãªããªããšããã®ãåºæ¬çæ¡ä»¶
ã§ãããããã¯é»è·çºçç©è³ªç²åïŒã¯é»è·æ äœã
å¹çããçºçãããããã«ã¯ãé»è·çºçç©è³ªç²å
è¡šé¢ãŸã§ãå ãééãããå¿ èŠãããããã§ã
ããäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å¯èŠé å
ã«ã»ãšãã©åžåããªããäžè¬ã«å¯èŠé åã®å ç·ã
åžåããé»è·æ äœãçºçããé»è·çºçç©è³ªç²åïŒ
ãšçµåããå Žåãç¹ã«æå¹ã«é»è·æ¬éç©è³ªç²åãš
ããŠåãã®ããã®ç¹åŸŽã§ããã 第ïŒå³ã«ãããæå äœã¯ãå°é»æ§æ¯æäœïŒäžã«
é»è·çºçç©è³ªïŒãäž»äœãšããé»è·çºçå±€ïŒãšÎ±â
眮æã¹ãã«ãã³ååç©ãšçµçå€ãå«æãé»è·æ¬é
åªäœïŒãšã®ç©å±€ãããªãæå å±€ïŒâ³ãèšãããã
ãã®ã§ããããã®æå äœã§ã¯ãé»è·æ¬éå±€ïŒãé
éããå ãé»è·çºçå±€ïŒã«å°éãããã®é åã§é»
è·æ äœã®çºçãèµ·ãããäžæ¹ãé»è·æ¬éå±€ïŒã¯é»
è·æ äœã®æ³šå ¥ãåãããã®æ¬éãè¡ãªããã®ã§ã
å æžè¡°ã«å¿ èŠãªé»è·æ äœã®çºçã¯ãé»è·çºçç©è³ª
ç²åïŒã§è¡ãªããããŸãé»è·æ äœã®æ¬éã¯ãé»è·
æ¬éå±€ïŒïŒäž»ãšããŠäžè¬åŒïŒïŒã®ååç©ãå
ãïŒã§è¡ãªããããããããæ©æ§ã¯ç¬¬ïŒå³ã«ç€ºã
ãæå äœã«ãããŠãã説æãšåæ§ã§ãããåãé»
è·çºçå±€ïŒãšé»è·æ¬éå±€ïŒãšã®ç©å±€é ãéã«ããŠ
ãããããšã¯å®¹æã«ç解ããããã 第ïŒå³ã«ç€ºããæå äœãäœè£œããã«ã¯ãïŒçš®å
ã¯ïŒçš®ä»¥äžã®Î±â眮æã¹ãã«ãã³ååç©ãšçµåå€
ãšæº¶è§£ãã溶液ã«é»è·çºçç©è³ªïŒã®åŸ®ç²åãšåæ£
ãããããããå°é»æ§æ¯æäœïŒäžã«å¡åžãã也ç¥
ããŠæå å±€ïŒâ²ã圢æããã°ããã æå å±€ïŒâ²ã®åãã¯ïŒã50ÎŒïœã奜ãŸããã¯ïŒ
ã20ÎŒïœãé©åœã§ãããæå å±€ïŒâ²ã«å ããαâ
眮æã¹ãã«ãã³ååç©ã®éã¯10ã95ééïŒ ã奜ãŸ
ããã¯30ã90ééïŒ ã§ããããŸããæå å±€ïŒâ²ã«
å ããé»è·çºçç©è³ªïŒã®éã¯0.1ã50ééïŒ å¥œãŸ
ããã¯ïŒã20ééïŒ ã§ãããé»è·çºçç©è³ªïŒãšã
ãŠã¯ãäŸãã°ã»ã¬ã³ãã»ã¬ã³âãã«ã«ãç¡«åã«ã
ããŠã ãç¡«åã«ãããŠã âã»ã¬ã³ãαâã·ãªã³ã³
ãªã©ã®ç¡æ©é¡æãææ©é¡æãšããŠã¯äŸãã°ã·ãŒã¢
ã€ãã°ã¡ã³ããã«â25ïŒã«ã©ãŒã€ã³ããã¯ã¹
CI21180ïŒãã·ãŒã€ã¢ãã°ã¡ã³ãã¬ãã41ïŒCI
21200ïŒãã·ãŒã¢ã€ã¢ã·ããã¬ãã52ïŒCI 45100ïŒã
ã·ãŒã¢ã€ããŒã·ãã¯ã¬ããïŒïŒCI 45210ïŒãã«ã«
ããŸãŒã«éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ53â
95033å·å ¬å ±ã«èšèŒïŒããžã¹ããªã«ãã³ãŒã³éªšæ Œã
æããã¢ãŸé¡æïŒç¹éæ53â133445å·å ¬å ±ã«èš
èŒïŒãããªããšãã«ã¢ãã³éªšæ Œãæããã¢ãŸé¡æ
ïŒç¹éæ53â132347å·å ¬å ±ã«èšèŒïŒããžãã³ãŸããª
ããšã³éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â21728
å·å ¬å ±ã«èšèŒïŒããªããµãžã¢ãŸãŒã«éªšæ Œãæãã
ã¢ãŸé¡æïŒç¹éæ54â12742å·å ¬å ±ã«èšèŒïŒããã«
ãªã¬ãã³éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â
22834å·å ¬å ±ã«èšèŒïŒããã¹ã¹ãã«ãã³éªšæ Œãæã
ãã¢ãŸé¡æïŒç¹éæ54â17733å·å ¬å ±ã«èšèŒïŒããž
ã¹ããªã«ãªããµãžã¢ãŸãŒã«éªšæ Œãæããã¢ãŸé¡æ
ïŒç¹éæ54â2129å·å ¬å ±ã«èšèŒïŒããžã¹ããªã«ã«ã«
ããŸãŒã«éªšæ Œãæããã¢ãŸé¡æïŒç¹éæ54â
14976å·å ¬å ±ã«èšèŒïŒãªã©ã®ã¢ãŸé¡æãäŸãã°ã·
ãŒã¢ã€ãã°ã¡ã³ããã«ãŒ16ïŒCI 741100ïŒãªã©ã®
ãã¿ãã·ã¢ãã³ç³»é¡æãäŸãã°ã·ãŒã¢ã€ãããã
ã©ãŠã³ïŒïŒCI 73410ïŒãã·ãŒã¢ã€ããããã€ïŒCI
73030ïŒãªã©ã®ã€ã³ãžãŽç³»é¡æãã¢ã«ãŽã¹ã«ãŒã¬
ããïŒãã€ãšã«ç€Ÿè£œïŒãã€ã³ãã¹ã¬ã³ã¹ã«ãŒã¬ã
ãïŒãã€ãšã«ç€Ÿè£œïŒãªã©ã®ããªã¬ã³ç³»é¡æãªã©
ãæããããããªãããããã®é»è·çºçç©è³ªã¯å
ç¬ã§çšããããŠãïŒçš®é¡ä»¥äžã䜵çšãããŠãã
ãã åã第ïŒå³ã«ç€ºããæå äœãäœè£œããã«ã¯ãå°
é»æ§æ¯æäœïŒäžã«é»è·çºçç©è³ªãç空èžçããã
æãã¯ãé»è·çºçç©è³ªã®åŸ®ç²åïŒãå¿ èŠã«ãã€ãŠ
çµåå€ã溶解ããé©åœã«æº¶åªäžã«åæ£ããåæ£æ¶²
ãå¡åžã也ç¥ãããããŠãæŽã«å¿ èŠã§ããã°ãã
ç 磚ãªã©ã®æ¹æ³ã«ãã€ãŠè¡šé¢ä»äžããèå調æŽãª
ã©ãè¡ã€ãŠé»è·çºçå±€ïŒã圢æãããã®äžã«ïŒçš®
åã¯ïŒçš®ä»¥äžÎ±â眮æã¹ãã«ãã³ååç©ãšçµåå€
ãšã溶解ãã溶液ãå¡åžã也ç¥ããŠé»è·æ¬éå±€ïŒ
ã圢æããã°ããããªããããã§é»è·çºçå±€ïŒã®
圢æã«çšããããé»è·çºçç©è³ªã¯åèšã®æå å±€
ïŒâ²ã®èª¬æã«ãããŠããã®ãšåããã®ã§ããã é»è·çºçå±€ïŒã®åãã¯5ÎŒïœä»¥äžå¥œãŸããã¯2ÎŒ
ïœä»¥äžã§ãããé»è·æ¬éå±€ïŒã®åãã¯ïŒã50ÎŒïœ
奜ãŸããã¯ïŒã20ÎŒïœãé©åœã§ãããé»è·çºçå±€
ïŒãé»è·çºçç©è³ªã®åŸ®ç²åïŒãçµåå€äžã«åæ£ã
ããã¿ã€ãã®ãã®ã«ãã€ãŠã¯ãé»è·çºçç©è³ªã®åŸ®
ç²åïŒã®é»è·çºçå±€ïŒã«å ããå²åã¯10ã95éé
ïŒ ã奜ãŸããã¯50ã90ééïŒ çšåºŠã§ããããŸãã
é»è·æ¬éå±€ïŒã«å ããαâ眮æã¹ãã«ãã³ååç©
ã®éã¯ã10ã95ééïŒ å¥œãŸããã¯30ã90ééïŒ ã§
ããã ãªãããããã®ãããã®æå äœè£œé ã«ãããŠã¯
å°é»æ§æ¯æäœïŒã«ãã¢ã«ãããŠã ãªã©ã®éå±æ¿å
ã¯éå±ç®ãã¢ã«ãããŠã ãªã©ã®éå±ãèžçããã
ã©ã¹ããã¯ãã€ã«ã ããããã¯ãå°é»åŠçãæœã
ãçŽãªã©ãçšããããããŸããçµåå€ãšããŠã¯ã
ããªã¢ãããããªãŠã¬ã¿ã³ãããªãšã¹ãã«ããšã
ãã·æš¹èãããªã±ãã³ãããªã«ãŒãããŒããªã©ã®
çž®åæš¹èããããªããã«ã±ãã³ãããªã¹ãã¬ã³ã
ããªââããã«ã«ã«ããŸãŒã«ãããªã¢ã¯ãªã«ã¢
ããã®ãããªããã«éåäœãªã©ãçšãããããã
絶çžæ§ã§ãã€æ¥çæ§ã®ããæš¹èã¯ãã¹ãŠäœ¿çšãã§
ãããå¿ èŠã«ããå¯å¡å€ãçµåå€ã«å ãããã
ããããããå¯å¡å€ãšããŠã¯ããã²ã³åãã©ãã€
ã³ãããªå¡©åãããšãã«ããžã¡ãã«ããã¿ãªã³ã
ãžããã«ãã¿ã¬ãŒããªã©ãäŸç€ºã§ããã æŽã«ã以äžã®ããã«ããŠåŸãããæå äœã«ã¯ã
å°é»æ§æ¯æäœãšæå å±€ã®éã«ãå¿ èŠã«å¿ããŠæ¥ç
å±€åã¯ããªã€å±€ãèšããããšãã§ããããããã®
å±€ã«çšããããææãšããŠã¯ãããªã¢ããããã
ãã»ã«ããŒã¹ãé žåã¢ã«ãããŠã ãªã©ã§ããããŸ
ãèåã¯1ÎŒïœä»¥äžã奜ãŸããã æ¬çºæã®æå äœãçšããŠè¢«åãè¡ãªãã«ã¯ãæ
å é¢ã«åž¯é»ãé²å ãæœããåŸãçŸåãè¡ãªããå¿
èŠã«ãã€ãŠãçŽãªã©ãžè»¢åãè¡ãªããæ¬çºæã®æ
å äœã¯æ床ãé«ãããŸãå¯ææ§ã«å¯ããªã©ã®åªã
ãå©ç¹ãæããŠããã 以äžã«äŸç€ºååç©No.13ã®è£œé äŸã瀺ãã 補é äŸ ïŒâããªâïœâããã«ãã¹ãããŠã ãã«ãªã¬ã
ãªã4.40ïœãšïŒïŒ4â²âãžã¡ãã«â4â³âãã«ãã«ã
ãªããšãã«ã¢ãã³3.62ïœã也ç¥ãã³ãŒã³40ml溶解
ããçªçŽ æ°æµäžïŒæéå ç±éæµããã宀枩ãŸã§å·
åŽåŸæº¶åªãæžå§äžçå»ããã®ã¡ã«ã©ã ã¯ããã
ïŒã·ãªã«ã²ã«ã溶é¢æ¶²ãã«ãšã³ïŒåŠçãããåŸã
ããé»æ©è²ç²æ«ãé ¢é žãšãã«ãšãšã¿ããŒã«ã®æ··å
溶åªããåçµæ¶ãé»æ©è²ããªãºã ç¶çµæ¶ã®ïŒâ
ïŒâïŒïŒ®ïŒïŒ®âãžâïœâããªã«ã¢ããïŒãã³ãžãª
ãã³ïŒœãã«ãªã¬ã³ïŒäŸç€ºååç©No.13ïŒ1.64ïœãåŸ
ããèç¹ã¯149.5ã150.5âã§ãã€ãã å çŽ åæå€ã¯C14H27NãšããŠäžèšã®ãšããã§ã
ã€ãã
ãè¡šã
以äžã«å®æœäŸã瀺ããäžèšå®æœäŸã«ãããŠéšã¯
ãã¹ãŠéééšã§ããã å®æœäŸ ïŒ é»è·çºçç©è³ªãšããŠãã€ã¢ã³ãã«ãŒïŒã·ãŒã¢ã€
ãã°ã¡ã³ããã«ãŒ25ãCI21180ïŒ76éšãããªãšã¹
ãã«æš¹èïŒãã€ãã³200ã(æ ª)æ±æŽçŽ¡çžŸè£œïŒã®ïŒïŒ
ããã©ããããã©ã³æº¶æ¶²1260éšããã³ããã©ãã
ããã©ã³3700éšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ãã¢ã«ãããŠã èžçããããªãšã¹ã
ã«ããŒã¹ãããªãå°é»æ§æ¯æäœã®ã¢ã«ãããŠã é¢
äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèªç¶ä¹Ÿç¥
ããŠåãçŽ1ÎŒïœã®é»è·çºçå±€ã圢æããã äžæ¹ãé»è·æ¬éç©è³ªãšããŠNo.ïŒã®çœ®æã¹ãã«ã
ã³ååç©ïŒéšãããªã«ãŒãããŒãæš¹èïŒãã³ã©ã€
ãK1300ã(æ ª)åžäººè£œïŒïŒéšããã³ããã©ãããã
ã©ã³16éšãæ··å溶解ããŠæº¶æ¶²ãšããåŸããããå
èšé»è·çºçå±€äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åž
ãã80âã§ïŒåéãã€ãã§105âã§ïŒåé也ç¥ã
ãŠåãçŽ20ÎŒïœã®é»è·æ¬éå±€ã圢æããããŠæå
äœNo.ïŒãäœæããã å®æœäŸ ïŒã10 é»è·çºçç©è³ªããã³é»è·æ¬éç©è³ªïŒÎ±â眮æã¹
ãã«ãã³ååç©ïŒãè¡šïŒã«ç€ºãããã®ã«ä»£ãã以
å€ã¯å®æœäŸïŒãšãŸã€ããåæ§ã«ããŠæå äœNo.ïŒã
18ãäœæããã
ãã¹ãŠéééšã§ããã å®æœäŸ ïŒ é»è·çºçç©è³ªãšããŠãã€ã¢ã³ãã«ãŒïŒã·ãŒã¢ã€
ãã°ã¡ã³ããã«ãŒ25ãCI21180ïŒ76éšãããªãšã¹
ãã«æš¹èïŒãã€ãã³200ã(æ ª)æ±æŽçŽ¡çžŸè£œïŒã®ïŒïŒ
ããã©ããããã©ã³æº¶æ¶²1260éšããã³ããã©ãã
ããã©ã³3700éšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ãã¢ã«ãããŠã èžçããããªãšã¹ã
ã«ããŒã¹ãããªãå°é»æ§æ¯æäœã®ã¢ã«ãããŠã é¢
äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèªç¶ä¹Ÿç¥
ããŠåãçŽ1ÎŒïœã®é»è·çºçå±€ã圢æããã äžæ¹ãé»è·æ¬éç©è³ªãšããŠNo.ïŒã®çœ®æã¹ãã«ã
ã³ååç©ïŒéšãããªã«ãŒãããŒãæš¹èïŒãã³ã©ã€
ãK1300ã(æ ª)åžäººè£œïŒïŒéšããã³ããã©ãããã
ã©ã³16éšãæ··å溶解ããŠæº¶æ¶²ãšããåŸããããå
èšé»è·çºçå±€äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åž
ãã80âã§ïŒåéãã€ãã§105âã§ïŒåé也ç¥ã
ãŠåãçŽ20ÎŒïœã®é»è·æ¬éå±€ã圢æããããŠæå
äœNo.ïŒãäœæããã å®æœäŸ ïŒã10 é»è·çºçç©è³ªããã³é»è·æ¬éç©è³ªïŒÎ±â眮æã¹
ãã«ãã³ååç©ïŒãè¡šïŒã«ç€ºãããã®ã«ä»£ãã以
å€ã¯å®æœäŸïŒãšãŸã€ããåæ§ã«ããŠæå äœNo.ïŒã
18ãäœæããã
ãè¡šã
ãè¡šã
ãè¡šã
å®æœäŸ 11
åãçŽ300ÎŒïœã®ã¢ã«ãããŠã æ¿äžã«ãã»ã¬ã³
ãåãçŽ1ÎŒïœã«ç空èžçããŠé»è·çºçå±€ã圢æ
ããããã次ãã§No.ïŒã®Î±â眮æã¹ãã«ãã³åå
ç©ïŒéšãããªãšã¹ãã«æš¹èïŒããŠãã³ç€Ÿè£œããªãš
ã¹ãã«ã¢ããâã·ã49000ïŒïŒéšããã³ããã©ã
ãããã©ã³45éšãæ··åã溶解ããŠé»è·æ¬é局圢æ
液ãã€ããããããäžèšã®é»è·çºçå±€ïŒã»ã¬ã³èž
çå±€ïŒäžãªãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèª
ç¶ä¹Ÿç¥ããåŸãæžå§äžã§ä¹Ÿç¥ããŠåãçŽ10ÎŒïœã®
é»è·æ¬éå±€ã圢æããããŠãæ¬çºæã®æå äœNo.11
ãåŸãã å®æœäŸ 12 ã»ã¬ã³ã®ä»£ãã«ããªã¬ã³ç³»é¡æ ãçšããŠé»è·çºçå±€ïŒäœããåãçŽ0.3ÎŒïœïŒã圢
æãããŸãαâ眮æã¹ãã«ãã³ååç©ãNo.ïŒã®ä»£
ãã«No.ïŒã®ãã®ãçšãã以å€ã¯å®æœäŸ10ãšãŸã€ã
ãåæ§ã«ããŠæå äœNo.12ãäœæããã å®æœäŸ 13 ãã€ã¢ã³ãã«ãŒïŒå®æœäŸïŒã§çšãããã®ãšå
ãïŒïŒéšã«ããã©ããããã©ã³158éšãå ããæ··
åç©ãããŒã«ãã«äžã§ç²ç ãæ··åããåŸãããã«
No.ïŒã®Î±â眮æã¹ãã«ãã³ååç©12éšãããªãšã¹
ãã«æš¹èïŒããŠãã³ç€Ÿè£œããªãšã¹ãã«ã¢ãããŒã·
ã49000ïŒ18éšãå ããŠãããã«æ··åããŠåŸãæ
å 局圢æ液ããã¢ã«ãããŠã èžçããªãšã¹ãã«ã
ã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžãã
100âã§30åé也ç¥ããŠåãçŽ16ÎŒïœã®æå å±€ã
圢æãããŠãæ¬çºæã®æå äœNo.13ãäœæããã ããããŠã€ããããæå äœNo.ïŒã13ã«ã€ããŠã
åžè²©ã®éé»è€åçŽè©Šéšè£ 眮ïŒKKå·å£é»æ©è£œäœæ
補SP 428åïŒãçšããŠâ6KVåã¯ïŒ6KVã®ã³ã
ãæŸé»ã20ç§éè¡ãªã€ãŠåž¯é»ããããåŸã20ç§é
ææã«æŸçœ®ãããã®æã®è¡šé¢é»äœVppïŒãã«ãïŒ
ã枬å®ããã€ãã§ã¿ã³ã°ã¹ãã³ã©ã³ãå ãæå äœ
è¡šé¢ã®ç §åºŠã20ã«ãã¯ã¹ã«ãªãããç §å°ããŠãã®
è¡šé¢é»äœãVppã®1/2ã«ãªããŸã§ã®æéïŒç§ïŒã
æ±ããé²å é1/2ïŒã«ãã¯ã¹ã»ç§ïŒãç®åºããã
ãã®çµæãè¡šïŒã«ç€ºãã ãŸãã以äžã®åæå äœãåžè²©ã®é»ååçè€åæ©
ãçšããŠåé»ããããåŸãåå³ãä»ããŠå ç §å°ã
è¡ãªã€ãŠéé»æœåã圢æãããã也åŒçŸåå€ãçš
ããŠçŸåããåŸãããç»åïŒãããŒç»åïŒãæ®é
çŽäžã«éé»è»¢åããå®çãããšãããé®®æãªè»¢å
ç»åãåŸããããçŸåå€ãšããŠæ¹¿åŒçŸåå€ãçšã
ãå Žåã«ãåæ§ã«é®®æãªè»¢åç»åãåŸãããã
ãåãçŽ1ÎŒïœã«ç空èžçããŠé»è·çºçå±€ã圢æ
ããããã次ãã§No.ïŒã®Î±â眮æã¹ãã«ãã³åå
ç©ïŒéšãããªãšã¹ãã«æš¹èïŒããŠãã³ç€Ÿè£œããªãš
ã¹ãã«ã¢ããâã·ã49000ïŒïŒéšããã³ããã©ã
ãããã©ã³45éšãæ··åã溶解ããŠé»è·æ¬é局圢æ
液ãã€ããããããäžèšã®é»è·çºçå±€ïŒã»ã¬ã³èž
çå±€ïŒäžãªãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèª
ç¶ä¹Ÿç¥ããåŸãæžå§äžã§ä¹Ÿç¥ããŠåãçŽ10ÎŒïœã®
é»è·æ¬éå±€ã圢æããããŠãæ¬çºæã®æå äœNo.11
ãåŸãã å®æœäŸ 12 ã»ã¬ã³ã®ä»£ãã«ããªã¬ã³ç³»é¡æ ãçšããŠé»è·çºçå±€ïŒäœããåãçŽ0.3ÎŒïœïŒã圢
æãããŸãαâ眮æã¹ãã«ãã³ååç©ãNo.ïŒã®ä»£
ãã«No.ïŒã®ãã®ãçšãã以å€ã¯å®æœäŸ10ãšãŸã€ã
ãåæ§ã«ããŠæå äœNo.12ãäœæããã å®æœäŸ 13 ãã€ã¢ã³ãã«ãŒïŒå®æœäŸïŒã§çšãããã®ãšå
ãïŒïŒéšã«ããã©ããããã©ã³158éšãå ããæ··
åç©ãããŒã«ãã«äžã§ç²ç ãæ··åããåŸãããã«
No.ïŒã®Î±â眮æã¹ãã«ãã³ååç©12éšãããªãšã¹
ãã«æš¹èïŒããŠãã³ç€Ÿè£œããªãšã¹ãã«ã¢ãããŒã·
ã49000ïŒ18éšãå ããŠãããã«æ··åããŠåŸãæ
å 局圢æ液ããã¢ã«ãããŠã èžçããªãšã¹ãã«ã
ã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžãã
100âã§30åé也ç¥ããŠåãçŽ16ÎŒïœã®æå å±€ã
圢æãããŠãæ¬çºæã®æå äœNo.13ãäœæããã ããããŠã€ããããæå äœNo.ïŒã13ã«ã€ããŠã
åžè²©ã®éé»è€åçŽè©Šéšè£ 眮ïŒKKå·å£é»æ©è£œäœæ
補SP 428åïŒãçšããŠâ6KVåã¯ïŒ6KVã®ã³ã
ãæŸé»ã20ç§éè¡ãªã€ãŠåž¯é»ããããåŸã20ç§é
ææã«æŸçœ®ãããã®æã®è¡šé¢é»äœVppïŒãã«ãïŒ
ã枬å®ããã€ãã§ã¿ã³ã°ã¹ãã³ã©ã³ãå ãæå äœ
è¡šé¢ã®ç §åºŠã20ã«ãã¯ã¹ã«ãªãããç §å°ããŠãã®
è¡šé¢é»äœãVppã®1/2ã«ãªããŸã§ã®æéïŒç§ïŒã
æ±ããé²å é1/2ïŒã«ãã¯ã¹ã»ç§ïŒãç®åºããã
ãã®çµæãè¡šïŒã«ç€ºãã ãŸãã以äžã®åæå äœãåžè²©ã®é»ååçè€åæ©
ãçšããŠåé»ããããåŸãåå³ãä»ããŠå ç §å°ã
è¡ãªã€ãŠéé»æœåã圢æãããã也åŒçŸåå€ãçš
ããŠçŸåããåŸãããç»åïŒãããŒç»åïŒãæ®é
çŽäžã«éé»è»¢åããå®çãããšãããé®®æãªè»¢å
ç»åãåŸããããçŸåå€ãšããŠæ¹¿åŒçŸåå€ãçšã
ãå Žåã«ãåæ§ã«é®®æãªè»¢åç»åãåŸãããã
ãè¡šã
å¹ æ
æ¬çºæã®æå
äœã¯æå
ç¹æ§ã«åªããŠããããšã¯
å¿è«ã®ããšãç±ãæ©æ¢°çã®è¡æã«å¯Ÿãã匷床ã倧
ã§ããããå®äŸ¡ã«è£œé ããããšãã§ããã
å¿è«ã®ããšãç±ãæ©æ¢°çã®è¡æã«å¯Ÿãã匷床ã倧
ã§ããããå®äŸ¡ã«è£œé ããããšãã§ããã
第ïŒå³åã³ç¬¬ïŒå³ã¯æ¬çºæã«ããããé»ååç
æå äœã®åãæ¹åã«æ¡å€§ããæé¢å³ã§ããã ïŒâŠâŠå°é»æ§æ¯æäœãïŒâ²ïŒïŒâ³âŠâŠæå å±€ãïŒ
âŠâŠé»è·çºçç©è³ªãïŒâŠâŠé»è·æ¬éåªäœåã¯é»è·
æ¬éå±€ãïŒâŠâŠé»è·çºçå±€ã
æå äœã®åãæ¹åã«æ¡å€§ããæé¢å³ã§ããã ïŒâŠâŠå°é»æ§æ¯æäœãïŒâ²ïŒïŒâ³âŠâŠæå å±€ãïŒ
âŠâŠé»è·çºçç©è³ªãïŒâŠâŠé»è·æ¬éåªäœåã¯é»è·
æ¬éå±€ãïŒâŠâŠé»è·çºçå±€ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§æ¯æäœäžã«äžèšäžè¬åŒïŒïŒã§ç€ºãã
ãé»è·æ¬éç©è³ªãšæš¹èçµçå€ãšãããªãé»è·æ¬é
åªäœäžã«å°ããšãé»è·çºçç©è³ªç²åãåæ£ããŠãª
ãæ©èœåé¢åæå å±€ãæããããšãç¹åŸŽãšããé»
ååççšæå äœã ïŒåŒäžãAr1åã³Ar2ã¯ã眮æãããã¯ç¡çœ®æã®
ã¢ãªãŒã«åºïŒ»äœããåæã«ç¡çœ®æããšãã«åºã®å Ž
åã¯é€ããåã¯å ±åããŠç°ã圢æããåºãè¡šãã
Ar3ã¯ã眮æåã¯ç¡çœ®æã®ã¢ãªãŒã¬ã³åºãè¡šãã
R1ãR2åã³R3ã¯ãæ°ŽçŽ ååã眮æãããã¯ç¡çœ®
æã®ã¢ã«ãã«åºåã¯çœ®æãããã¯ç¡çœ®æã¢ãªãŒã«
åºãè¡šãããäžèšã¢ãªãŒã«åºåã³ã¢ãªãŒã¬ã³åºã®
眮æåºã¯ãã¢ã«ã³ãã·åºãããšããã·åºãã¢ã«ã
ã«åºãããããã·åºãããã²ã³ååãã·ã¢ãåºã
ãŸãã¯ãããåºã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§ã
ããïŒ ïŒ å°é»æ§æ¯æäœäžã«ãé»è·çºçå±€ãšäžèšäžè¬åŒ
ïŒïŒã§ç€ºãããé»è·æ¬éç©è³ªåã³æš¹èçµçå€ãš
ãããªãé»è·æ¬éå±€ãšãç©å±€ããŠåœ¢æãããæ©èœ
åé¢åæå å±€ãæããããšãç¹åŸŽãšããé»ååç
çšæå äœã ïŒåŒäžãAr1åã³Ar2ã¯ã眮æãããã¯ç¡çœ®æã®
ã¢ãªãŒã«åºïŒ»äœããåæã«ç¡çœ®æããšãã«åºã®å Ž
åã¯é€ããåã¯å ±åããŠç°ã圢æããåºãè¡šãã
Ar3ã¯ã眮æåã¯ç¡çœ®æã®ã¢ãªãŒã¬ã³åºãè¡šãã
R1ãR2åã³R3ã¯ãæ°ŽçŽ ååã眮æãããã¯ç¡çœ®
æã®ã¢ã«ãã«åºåã¯çœ®æãããã¯ç¡çœ®æã¢ãªãŒã«
åºãè¡šãããäžèšã¢ãªãŒã«åºåã³ã¢ãªãŒã¬ã³åºã®
眮æåºã¯ãã¢ã«ã³ãã·åºãããšããã·åºãã¢ã«ã
ã«åºãããããã·åºãããã²ã³ååãã·ã¢ãåºã
ãŸãã¯ãããåºã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§ã
ããïŒ
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58205994A JPS6098437A (ja) | 1983-11-04 | 1983-11-04 | é»ååççšæå äœ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58205994A JPS6098437A (ja) | 1983-11-04 | 1983-11-04 | é»ååççšæå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6098437A JPS6098437A (ja) | 1985-06-01 |
JPH0466023B2 true JPH0466023B2 (ja) | 1992-10-21 |
Family
ID=16516145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58205994A Granted JPS6098437A (ja) | 1983-11-04 | 1983-11-04 | é»ååççšæå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6098437A (ja) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61210363A (ja) * | 1985-03-15 | 1986-09-18 | Canon Inc | é»ååçæå äœ |
JPH0791478B2 (ja) * | 1986-09-10 | 1995-10-04 | ãã€ãã³æ ªåŒäŒç€Ÿ | ïŒïŒšâãžãã³ãŸãïœïŒïœãã·ã¯ãããã¿ããªãã³èªå°äœåã³ïŒïŒšâãžãã³ãŸãïœïŒïœãã·ã¯ããããããªãã³èªå°äœããã®è£œé æ³åã³ãããçšããé»ååçæå äœ |
JP2615031B2 (ja) * | 1987-01-30 | 1997-05-28 | æ ªåŒäŒç€Ÿãªã³ãŒ | é»ååççšæå äœ |
DE3814105C2 (de) * | 1987-04-27 | 1999-02-04 | Minolta Camera Kk | Elektrophotographisches Aufzeichnungsmaterial |
JPH0675204B2 (ja) * | 1987-08-13 | 1994-09-21 | ã³ãã«æ ªåŒäŒç€Ÿ | é»ååçæå äœ |
JPH02156247A (ja) * | 1988-12-09 | 1990-06-15 | Canon Inc | é»ååçæå äœ |
JPH0373961A (ja) * | 1989-04-28 | 1991-03-28 | Mitsui Toatsu Chem Inc | é»ååçæå äœ |
US5393629A (en) * | 1991-04-26 | 1995-02-28 | Fuji Xerox Co., Ltd. | Electrophotographic photoreceptor |
JP3577853B2 (ja) * | 1996-10-23 | 2004-10-20 | äžè±ååŠæ ªåŒäŒç€Ÿ | é»ååçæå äœ |
US6225015B1 (en) | 1998-06-04 | 2001-05-01 | Mitsubishi Paper Mills Ltd. | Oxytitanium phthalocyanine process for the production thereof and electrophotographic photoreceptor to which the oxytitanium phthalocyanine is applied |
EP2009064B1 (en) | 2002-07-29 | 2012-10-24 | Mitsubishi Paper Mills Limited | Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device |
US7166689B2 (en) | 2003-02-13 | 2007-01-23 | Ricoh Company, Ltd. | Aryl amine polymer, thin film transistor using the aryl amine polymer, and method of manufacturing the thin film transistor |
JP5416118B2 (ja) | 2008-08-06 | 2014-02-12 | äžè±è£œçŽæ ªåŒäŒç€Ÿ | è²çŽ å¢æå倪éœé»æ± çšè²çŽ ãåå°äœé»æ¥µåã³è²çŽ å¢æå倪éœé»æ± |
JP6337561B2 (ja) | 2014-03-27 | 2018-06-06 | æ ªåŒäŒç€Ÿãªã³ãŒ | ãããã¹ã«ã€ãå倪éœé»æ± |
EP3975278A1 (en) | 2014-04-16 | 2022-03-30 | Ricoh Company, Ltd. | Photoelectric conversion element |
JP6447754B2 (ja) | 2016-01-25 | 2019-01-09 | æ ªåŒäŒç€Ÿãªã³ãŒ | å é»å€æçŽ å |
US10651390B2 (en) | 2016-06-08 | 2020-05-12 | Ricoh Company, Ltd. | Tertiary amine compound, photoelectric conversion element, and solar cell |
US10930443B2 (en) | 2016-12-07 | 2021-02-23 | Ricoh Company, Ltd. | Photoelectric conversion element |
KR20220016961A (ko) | 2019-06-10 | 2022-02-10 | ê°ë¶ìí€ê°ìŽì€ ëŠ¬ìœ | êŽì ë³í ìì, êŽì ë³í ìì 몚ë, ì ì ì¥ì¹ ë° ì ì 몚ë |
KR102636393B1 (ko) | 2019-07-16 | 2024-02-13 | ê°ë¶ìí€ê°ìŽì€ ëŠ¬ìœ | íì ì ì§ ëªšë, ì ì êž°êž°, ë° ì ì 몚ë |
US20210167287A1 (en) | 2019-11-28 | 2021-06-03 | Tamotsu Horiuchi | Photoelectric conversion element, photoelectric conversion module, electronic device, and power supply module |
US11502264B2 (en) | 2020-02-27 | 2022-11-15 | Ricoh Company, Ltd. | Photoelectric conversion element and photoelectric conversion module |
JP7413833B2 (ja) | 2020-02-27 | 2024-01-16 | æ ªåŒäŒç€Ÿãªã³ãŒ | å é»å€æçŽ ååã³å é»å€æã¢ãžã¥ãŒã« |
EP4064355A1 (en) | 2021-03-23 | 2022-09-28 | Ricoh Company, Ltd. | Solar cell module |
WO2023008085A1 (en) | 2021-07-29 | 2023-02-02 | Ricoh Company, Ltd. | Photoelectric conversion element and solar cell module |
JP2023137773A (ja) | 2022-03-18 | 2023-09-29 | æ ªåŒäŒç€Ÿãªã³ãŒ | å é»å€æçŽ åãå é»å€æã¢ãžã¥ãŒã«ãé»åæ©åšãåã³å€ªéœé»æ± ã¢ãžã¥ãŒã« |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3677752A (en) * | 1969-09-02 | 1972-07-18 | Eastman Kodak Co | Bis(dialkylaminoaryl)ethylene photoconductors |
JPS5865440A (ja) * | 1981-09-18 | 1983-04-19 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58198043A (ja) * | 1982-05-14 | 1983-11-17 | Ricoh Co Ltd | é»ååççšæå äœ |
-
1983
- 1983-11-04 JP JP58205994A patent/JPS6098437A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3677752A (en) * | 1969-09-02 | 1972-07-18 | Eastman Kodak Co | Bis(dialkylaminoaryl)ethylene photoconductors |
JPS5865440A (ja) * | 1981-09-18 | 1983-04-19 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58198043A (ja) * | 1982-05-14 | 1983-11-17 | Ricoh Co Ltd | é»ååççšæå äœ |
Also Published As
Publication number | Publication date |
---|---|
JPS6098437A (ja) | 1985-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0466023B2 (ja) | ||
JPH0339306B2 (ja) | ||
JPS62116943A (ja) | é»ååçæå äœ | |
JPH045382B2 (ja) | ||
JPH0423771B2 (ja) | ||
JP2753582B2 (ja) | é»ååççšæå äœ | |
JPH0336222B2 (ja) | ||
JPH0462377B2 (ja) | ||
JP2701852B2 (ja) | é»ååççšæå äœ | |
JP3054659B2 (ja) | é»ååççšæå äœ | |
JP3030441B2 (ja) | é»ååççšæå äœ | |
JP3435476B2 (ja) | é»ååççšæå äœ | |
JPH01566A (ja) | é»ååççšæå äœ | |
JP3289049B2 (ja) | é»ååççšæå äœ | |
JP3303200B2 (ja) | é»ååççšæå äœ | |
JP2700231B2 (ja) | é»ååççšæå äœ | |
JPH0689040A (ja) | é»ååççšæå äœ | |
JP3194389B2 (ja) | é»ååççšæå äœ | |
JPS61228450A (ja) | é»ååççšæå äœ | |
JP3081662B2 (ja) | é»ååççšæå äœ | |
JPH05703B2 (ja) | ||
JP3245694B2 (ja) | é»ååççšæå äœ | |
JP2876063B2 (ja) | é»ååççšæå äœ | |
JP3054782B2 (ja) | é»ååççšæå äœ | |
JP2742564B2 (ja) | é»ååççšæå äœ |