JPH0452277B2 - - Google Patents
Info
- Publication number
- JPH0452277B2 JPH0452277B2 JP58203780A JP20378083A JPH0452277B2 JP H0452277 B2 JPH0452277 B2 JP H0452277B2 JP 58203780 A JP58203780 A JP 58203780A JP 20378083 A JP20378083 A JP 20378083A JP H0452277 B2 JPH0452277 B2 JP H0452277B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- trimethyl
- trialkyl
- methylaluminoxane
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 26
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 19
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 9
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
- 238000002425 crystallisation Methods 0.000 claims description 5
- 230000008025 crystallization Effects 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- TYYRFZAVEXQXSN-UHFFFAOYSA-H aluminium sulfate hexadecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O TYYRFZAVEXQXSN-UHFFFAOYSA-H 0.000 claims 1
- 239000003643 water by type Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000006384 oligomerization reaction Methods 0.000 description 6
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- -1 aluminum hydrocarbon compounds Chemical class 0.000 description 3
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- ZZCONUBOESKGOK-UHFFFAOYSA-N aluminum;trinitrate;hydrate Chemical compound O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZZCONUBOESKGOK-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- CAYKLJBSARHIDI-UHFFFAOYSA-K trichloroalumane;hydrate Chemical compound O.Cl[Al](Cl)Cl CAYKLJBSARHIDI-UHFFFAOYSA-K 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19823240383 DE3240383A1 (de) | 1982-11-02 | 1982-11-02 | Verfahren zur herstellung von oligomeren aluminoxanen |
| DE3240383.6 | 1982-11-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5995292A JPS5995292A (ja) | 1984-06-01 |
| JPH0452277B2 true JPH0452277B2 (instruction) | 1992-08-21 |
Family
ID=6177080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58203780A Granted JPS5995292A (ja) | 1982-11-02 | 1983-11-01 | オリゴマ−のアルミノキサン類の製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4544762A (instruction) |
| EP (1) | EP0108339B1 (instruction) |
| JP (1) | JPS5995292A (instruction) |
| AU (1) | AU557540B2 (instruction) |
| CA (1) | CA1217777A (instruction) |
| DE (2) | DE3240383A1 (instruction) |
| ES (1) | ES8406079A1 (instruction) |
| ZA (1) | ZA838140B (instruction) |
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3678024D1 (de) | 1985-03-26 | 1991-04-18 | Mitsui Petrochemical Ind | Fluessiges statisches ethylencopolymer, verfahren zur herstellung und anwendung desselben. |
| US4665208A (en) * | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| USRE35289E (en) * | 1985-11-11 | 1996-07-02 | Idemitsu Kosan Company Limited | Process for production of styrene polymers |
| US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
| US4730071A (en) * | 1986-08-15 | 1988-03-08 | Shell Oil Company | Process for preparing aluminoxanes |
| US4730072A (en) * | 1986-08-15 | 1988-03-08 | Shell Oil Company | Process for preparing aluminoxanes |
| CA1338046C (en) † | 1986-09-19 | 1996-02-06 | Howard Curtis Welborn Jr. | High pressure high temperature polymerization of ethylene |
| EP0268214B1 (en) * | 1986-11-13 | 1991-08-21 | Idemitsu Kosan Company Limited | Process for producing propylene oligomers |
| US4808680A (en) * | 1987-06-08 | 1989-02-28 | The Dow Chemical Company | Polymerization of vinyl aromatic monomers using cyclopentadienyl zirconium catalysts |
| US4774301A (en) * | 1987-06-08 | 1988-09-27 | The Dow Chemical Company | Zirconium containing catalysts and method of use |
| US5045517A (en) * | 1987-06-17 | 1991-09-03 | The Dow Chemical Company | Catalyst and process for preparation of syndiotactic polystyrene |
| JP2566889B2 (ja) * | 1987-07-13 | 1996-12-25 | 出光興産株式会社 | オレフィン系重合体またはスチレン系重合体の製造方法 |
| US5015749A (en) * | 1987-08-31 | 1991-05-14 | The Dow Chemical Company | Preparation of polyhydrocarbyl-aluminoxanes |
| AU596918B2 (en) * | 1987-08-31 | 1990-05-17 | Dow Chemical Company, The | Preparation of polyhydrocarbylaluminoxanes |
| US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US5043515A (en) * | 1989-08-08 | 1991-08-27 | Shell Oil Company | Ethylene oligomerization catalyst and process |
| US4960878A (en) * | 1988-12-02 | 1990-10-02 | Texas Alkyls, Inc. | Synthesis of methylaluminoxanes |
| US5041584A (en) * | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
| EP0955322A3 (en) | 1988-12-26 | 1999-12-08 | Mitsui Chemicals, Inc. | Olefin copolymers and processes for preparing same |
| AU624219B2 (en) * | 1989-02-16 | 1992-06-04 | Idemitsu Kosan Company Limited | Process for preparation of aluminoxane |
| US4937363A (en) * | 1989-02-21 | 1990-06-26 | Ethyl Corporation | Falling film aluminoxane process |
| US5103031A (en) * | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| US5093295A (en) * | 1989-03-23 | 1992-03-03 | Idemitsu Kosan Company Limited | Process for producing homogeneous aluminoxane solution |
| US4968827A (en) * | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) * | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| GB8914703D0 (en) * | 1989-06-27 | 1989-08-16 | Dow Europ Sa | Bioriented film |
| US5763547A (en) * | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
| US6025448A (en) * | 1989-08-31 | 2000-02-15 | The Dow Chemical Company | Gas phase polymerization of olefins |
| DE4004477A1 (de) * | 1990-02-14 | 1991-08-22 | Schering Ag | Verfahren zur herstellung von loesungen oligomerer methylaluminoxane |
| US5003095A (en) * | 1990-03-08 | 1991-03-26 | Ethyl Corporation | Process for preparing methylaluminoxanes |
| US5041583A (en) * | 1990-06-28 | 1991-08-20 | Ethyl Corporation | Preparation of aluminoxanes |
| US6538080B1 (en) | 1990-07-03 | 2003-03-25 | Bp Chemicals Limited | Gas phase polymerization of olefins |
| US5049687A (en) * | 1990-10-22 | 1991-09-17 | Ethyl Corporation | Ethylene chain growth process |
| US5099050A (en) * | 1991-04-15 | 1992-03-24 | Ethyl Corporation | Preparation of aluminoxanes |
| US5411925A (en) * | 1993-02-12 | 1995-05-02 | Phillips Petroleum Company | Organo-aluminoxy product and use |
| US5235081A (en) * | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5395471A (en) * | 1991-10-15 | 1995-03-07 | The Dow Chemical Company | High drawdown extrusion process with greater resistance to draw resonance |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5783638A (en) * | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| US5674342A (en) * | 1991-10-15 | 1997-10-07 | The Dow Chemical Company | High drawdown extrusion composition and process |
| US5582923A (en) * | 1991-10-15 | 1996-12-10 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
| US5562958A (en) * | 1991-10-15 | 1996-10-08 | The Dow Chemical Company | Packaging and wrapping film |
| US5811618A (en) * | 1991-10-16 | 1998-09-22 | Amoco Corporation | Ethylene trimerization |
| DE4205932A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von propenoligomeren |
| KR940007081A (ko) * | 1992-09-29 | 1994-04-26 | 리챠드 데이비드 크락 | 폴리케톤의 제조 방법 |
| US5391793A (en) * | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
| US5939346A (en) * | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| US5420220A (en) * | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
| KR100301978B1 (ko) * | 1993-01-29 | 2001-11-14 | 리챠드 지. 워터맨 | 에틸렌공중합법 |
| DE4314986A1 (de) * | 1993-05-06 | 1994-11-10 | Witco Gmbh | Verfahren zur Herstellung von Aluminoxanen |
| EP0739360B1 (en) | 1993-09-17 | 2001-04-11 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5773106A (en) * | 1994-10-21 | 1998-06-30 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
| US7153909B2 (en) * | 1994-11-17 | 2006-12-26 | Dow Global Technologies Inc. | High density ethylene homopolymers and blend compositions |
| CN1039587C (zh) * | 1994-12-27 | 1998-08-26 | 化学工业部北京化工研究院 | 一种铝氧烷化合物的制备方法 |
| US5869575A (en) * | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| US5831109A (en) * | 1995-12-22 | 1998-11-03 | Akzo Nobel Nv | Polyalkylaluminoxane compositions formed by non-hydrolytic means |
| US6114477A (en) * | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
| US5959044A (en) * | 1996-07-08 | 1999-09-28 | Villar; Juan Carlos | Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems |
| US5849823A (en) * | 1996-09-04 | 1998-12-15 | The Dow Chemical Company | Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications |
| US6812289B2 (en) | 1996-12-12 | 2004-11-02 | Dow Global Technologies Inc. | Cast stretch film of interpolymer compositions |
| US6153551A (en) * | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
| TR200000363T2 (tr) | 1997-08-08 | 2000-06-21 | The Dow Chemical Company | Bir yer, duvar ya da tavan kaplama malzemesi olarak kullanım için uygun olan levha halinde malzemeler, ve aynısını yapmaya mahsus yöntemler ve ara ürünler. |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| WO2002083754A1 (en) | 2001-04-12 | 2002-10-24 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| US5990035A (en) * | 1997-10-21 | 1999-11-23 | Koeppl; Alexander | Polymerization catalyst systems, their preparation, and use |
| AR018359A1 (es) * | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano |
| US6706827B1 (en) * | 1998-06-08 | 2004-03-16 | Samsung Atofina Co. Ltd. | Metallocene catalysts for olefin or styrene polymerization and polymerization method using the metallocene catalysts |
| KR100287955B1 (ko) | 1998-06-08 | 2001-05-02 | 유현식 | 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법 |
| EP1522553B1 (en) | 1998-07-01 | 2007-04-11 | ExxonMobil Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| KR100328866B1 (ko) | 1999-07-02 | 2002-03-20 | 유현식 | 미세유동법을 사용한 스티렌계 중합체의 제조방법 |
| KR100349071B1 (ko) | 2000-02-02 | 2002-08-14 | 삼성종합화학주식회사 | 생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법 |
| US6777510B1 (en) | 2000-09-12 | 2004-08-17 | California Institute Of Technology | Internal Lewis acid single site catalyst family for polymerization of polar monomers |
| US6518445B1 (en) | 2000-12-15 | 2003-02-11 | Albemarle Corporation | Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof |
| US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| US6943215B2 (en) * | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
| US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| WO2003040201A1 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| US8389634B2 (en) * | 2002-10-02 | 2013-03-05 | Dow Global Technologies Llc | Polymer compositions comprising a low-viscosity, homogeneously branched ethylene α-olefin extender |
| EP1558655B1 (en) | 2002-10-15 | 2012-08-29 | ExxonMobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US7579407B2 (en) * | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| JP4476657B2 (ja) | 2004-03-22 | 2010-06-09 | 東ソー・ファインケム株式会社 | ポリメチルアルミノキサン調製物、その製造方法、重合触媒およびオレフィン類の重合方法 |
| US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
| EP2328944B1 (en) * | 2008-09-16 | 2018-01-24 | Dow Global Technologies LLC | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| JP5525847B2 (ja) | 2009-03-17 | 2014-06-18 | 日本ポリプロ株式会社 | プロピレン系多層シートおよびそれを用いた加圧処理用包装袋 |
| KR101716292B1 (ko) | 2009-03-30 | 2017-03-14 | 도레이 배터리 세퍼레이터 필름 주식회사 | 미세다공막, 이러한 막의 제조 방법, 및 전지 세퍼레이터 필름으로서의 이러한 막의 사용 |
| KR101707696B1 (ko) | 2009-03-31 | 2017-02-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균질 에틸렌/알파-올레핀 혼성중합체로부터 제조된 필름 |
| US8722817B2 (en) * | 2009-06-05 | 2014-05-13 | Dow Global Technologies Llc | Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene |
| EP2438093B1 (en) | 2009-06-05 | 2013-07-24 | Dow Global Technologies LLC | Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene |
| US20120129417A1 (en) | 2009-07-01 | 2012-05-24 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| WO2011002986A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
| US8987385B2 (en) | 2009-09-14 | 2015-03-24 | Dow Global Technologies Llc | Interconnected copolymers of ethylene in combination with one other polyalkene |
| SG179052A1 (en) | 2009-09-14 | 2012-04-27 | Dow Global Technologies Llc | Polymers comprising units derived from ethylene and poly(alkoxide) |
| ES2711958T3 (es) | 2009-09-14 | 2019-05-08 | Dow Global Technologies Llc | Polímeros que comprenden unidades derivadas de etileno y siloxano |
| EP2576686A1 (en) | 2010-06-04 | 2013-04-10 | Dow Global Technologies LLC | Electronic device module comprising film of homogeneous polyolefin copolymer and adhesive property enhancing graft polymer |
| BR112012030650A2 (pt) | 2010-06-04 | 2016-08-16 | Dow Global Technologies Llc | módulo de dispositivo eletrônico compreendendo película de copolímero de poliolefina homogêneo e silano enxertado |
| WO2011163025A1 (en) | 2010-06-24 | 2011-12-29 | Dow Global Technologies Llc | Electronic device module comprising heterogeneous polyolefin copolymer and optionally silane |
| BR112013005340B1 (pt) | 2010-09-14 | 2020-06-23 | Japan Polypropylene Corporation | Folha de múltiplas camadas de resina de propileno, e, bolsa de acondicionamento termotratável |
| BR112013005339B1 (pt) | 2010-09-17 | 2019-12-03 | Japan Polypropylene Corp | folha de resina de propileno, e, material de embalagem termicamente tratável |
| ES2694590T3 (es) | 2012-05-09 | 2018-12-21 | Dow Global Technologies Llc | Procedimiento de polimerización de poliolefina, polímero basado en etileno semicristalino fabricado a partir del mismo, y artículos fabricados a partir del polímero |
| US9534070B2 (en) | 2013-01-18 | 2017-01-03 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polymers |
| JP6499927B2 (ja) | 2015-06-10 | 2019-04-10 | Ｊｘｔｇエネルギー株式会社 | 網状構造体 |
| US10808052B2 (en) | 2015-09-28 | 2020-10-20 | Petrochina Company Limited | Spherical supported transition metal catalyst |
| JP6936795B2 (ja) | 2015-10-29 | 2021-09-22 | ダウ グローバル テクノロジーズ エルエルシー | 可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法 |
| JP6845005B2 (ja) | 2016-12-27 | 2021-03-17 | Ｅｎｅｏｓ株式会社 | 粘着テープ |
| CN114716468A (zh) * | 2022-03-18 | 2022-07-08 | 浙江石油化工有限公司 | 一种改性mao的合成方法 |
| CN115368395B (zh) * | 2022-08-13 | 2025-09-02 | 北京化工大学 | 烷基铝氧烷的制备方法与应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL86609C (instruction) * | 1955-10-06 | 1957-10-15 | Noury & Van Der Lande | |
| US2979497A (en) * | 1957-02-12 | 1961-04-11 | J W Ayers & Co | Cyclic aluminum oxide acylates, alkoxides, and phenoxides |
| US3054816A (en) * | 1958-06-30 | 1962-09-18 | Agrashell Inc | Cyclic alkoxy- and phenoxy-aluminum oxide trimers and process for making same |
| US3055847A (en) * | 1959-05-18 | 1962-09-25 | United States Borax Chem | Preparation of a foamed resin from alkoxyaryloxyaluminum compounds |
| US3657149A (en) * | 1968-10-14 | 1972-04-18 | Hercules Inc | Catalyst compositions |
| SU566844A1 (ru) * | 1973-06-18 | 1977-07-30 | Институт Химии Башкирского Филиала Ан Ссср | Способ получени алюмоксанов |
| US4055634A (en) * | 1974-02-22 | 1977-10-25 | Hoffmann-La Roche, Inc. | Antiperspirants |
-
1982
- 1982-11-02 DE DE19823240383 patent/DE3240383A1/de not_active Withdrawn
-
1983
- 1983-10-26 EP EP83110692A patent/EP0108339B1/de not_active Expired
- 1983-10-26 DE DE8383110692T patent/DE3377715D1/de not_active Expired
- 1983-10-31 US US06/546,862 patent/US4544762A/en not_active Expired - Fee Related
- 1983-10-31 AU AU20861/83A patent/AU557540B2/en not_active Ceased
- 1983-10-31 ES ES526938A patent/ES8406079A1/es not_active Expired
- 1983-11-01 CA CA000440182A patent/CA1217777A/en not_active Expired
- 1983-11-01 ZA ZA838140A patent/ZA838140B/xx unknown
- 1983-11-01 JP JP58203780A patent/JPS5995292A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU2086183A (en) | 1984-05-10 |
| DE3240383A1 (de) | 1984-05-03 |
| US4544762A (en) | 1985-10-01 |
| ZA838140B (en) | 1984-07-25 |
| AU557540B2 (en) | 1986-12-24 |
| CA1217777A (en) | 1987-02-10 |
| EP0108339B1 (de) | 1988-08-17 |
| EP0108339A2 (de) | 1984-05-16 |
| ES526938A0 (es) | 1984-07-16 |
| ES8406079A1 (es) | 1984-07-16 |
| DE3377715D1 (en) | 1988-09-22 |
| JPS5995292A (ja) | 1984-06-01 |
| EP0108339A3 (en) | 1985-10-23 |
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