JPH0417432B2 - - Google Patents
Info
- Publication number
- JPH0417432B2 JPH0417432B2 JP59186202A JP18620284A JPH0417432B2 JP H0417432 B2 JPH0417432 B2 JP H0417432B2 JP 59186202 A JP59186202 A JP 59186202A JP 18620284 A JP18620284 A JP 18620284A JP H0417432 B2 JPH0417432 B2 JP H0417432B2
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- resin
- general formula
- group
- represented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims description 109
- 239000011347 resin Substances 0.000 claims description 109
- 239000002245 particle Substances 0.000 claims description 78
- 239000000178 monomer Substances 0.000 claims description 71
- 239000006185 dispersion Substances 0.000 claims description 61
- 239000007788 liquid Substances 0.000 claims description 45
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 230000000087 stabilizing effect Effects 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 11
- 150000002430 hydrocarbons Chemical group 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 description 57
- 238000006243 chemical reaction Methods 0.000 description 29
- 239000004816 latex Substances 0.000 description 26
- 229920000126 latex Polymers 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 22
- 238000003756 stirring Methods 0.000 description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000011259 mixed solution Substances 0.000 description 15
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- -1 rosins Polymers 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 10
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 10
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 238000007639 printing Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 238000001226 reprecipitation Methods 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 5
- 239000011345 viscous material Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- 239000003125 aqueous solvent Substances 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- ZCGHEBMEQXMRQL-UHFFFAOYSA-N benzyl 2-carbamoylpyrrolidine-1-carboxylate Chemical compound NC(=O)C1CCCN1C(=O)OCC1=CC=CC=C1 ZCGHEBMEQXMRQL-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 239000000025 natural resin Substances 0.000 description 3
- 238000007645 offset printing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 230000007257 malfunction Effects 0.000 description 2
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- FYELGSIOXSRGGW-UHFFFAOYSA-N (2-aminoacetyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(=O)CN FYELGSIOXSRGGW-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- RJUIDDKTATZJFE-NSCUHMNNSA-N (e)-but-2-enoyl chloride Chemical compound C\C=C\C(Cl)=O RJUIDDKTATZJFE-NSCUHMNNSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- GPOGMJLHWQHEGF-UHFFFAOYSA-N 2-chloroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCl GPOGMJLHWQHEGF-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010898 silica gel chromatography Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/12—Developers with toner particles in liquid developer mixtures
- G03G9/13—Developers with toner particles in liquid developer mixtures characterised by polymer components
- G03G9/131—Developers with toner particles in liquid developer mixtures characterised by polymer components obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/001—Electric or magnetic imagery, e.g., xerography, electrography, magnetography, etc. Process, composition, or product
- Y10S430/105—Polymer in developer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Liquid Developers In Electrophotography (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯é»æ°æµæïŒïŒ9Ωcm以äžãèªé»ç3.5以
äžã®æ äœæ¶²ã«å°ãªããšãæš¹èãåæ£ããŠãªãéé»
åççšæ¶²äœçŸåå€ã«é¢ãããã®ã§ãããç¹ã«åå
æ£æ§ãä¿åæ§ãå®å®æ§ãç»åã®åçŸæ§ãå®çæ§ã®
åªãã液äœçŸåå€ã«é¢ããã ãåŸæ¥ã®æè¡ã äžè¬ã®é»ååççšæ¶²äœçŸåå€ã¯ã«ãŒãã³ãã©ã
ã¯ããã°ãã·ã³ããã¿ãã·ã¢ãã³ãã«ãŒçã®ææ©
åã¯ç¡æ©ã®é¡æãããã¯ææãšã¢ã«ãããæš¹èã
ã¢ã¯ãªã«æš¹èãããžã³ãåæãŽã çã®å€©ç¶åã¯å
ææš¹èãç³æ²¹ç³»èèªæçåæ°ŽçŽ ã®ãããªé«çµ¶çž
æ§ã»äœèªé»çã®æ¶²äœäžã«åæ£ãæŽã«éå±ã»ãã±
ã³ãã¬ã·ãã·ãã¢ããæ²¹ãé«çŽèèªé žãããã«ã
ããªãã³ãå«æããããªããŒãªã©ã®æ¥µæ§å¶åŸ¡å€ã
å ãããã®ã§ããããã®ãããªçŸåå€äžã§ã¯æš¹è
ã¯äžæº¶æ§ã©ããã¯ã¹ç²åãšããŠçŽåŸæ°ÎŒïœãæ°çŸ
ÎŒïœã®ç²åç¶ã«åæ£ãããŠãããåŸæ¥ã®æ¶²äœçŸå
å€ã«ãããŠã¯å¯å¡æº¶æ§åæ£å®å®çšæš¹èã極æ§å¶åŸ¡
å€ãšäžæº¶æ§ã©ããã¯ã¹ç²åãšã®çµåãäžå åãªçº
ã«å¯æº¶æ§åæ£å®å®çšæš¹èåã³æ¥µæ§å¶åŸ¡å€ã溶液äž
ã«æ¡æ£ãæãç¶æ ã«ãã€ãããã®çºãé·æéã®ä¿
åãç¹°ãè¿ã䜿çšã«ãã€ãŠå¯æº¶æ§åæ£å®å®çšæš¹è
ãäžæº¶æ§ã©ããã¯ã¹ç²åããè±é¢ãç²åãæ²éã
åéãæšç©ããã極æ§ãäžæçã«ãªãããšããæ¬
ç¹ããã€ããåãäžåºŠåéãå ç©ããç²åã¯åå
æ£ãã«ããã®ã§çŸåæ©ã®éæã«ç²åãä»çãããŸ
ãŸãšãªããç»åéšã®æ±ããé液ãã³ãã®ç®ã¥ãŸã
çã®çŸåæ©ã®æ éã«ãã€ãªãã€ãŠããããããã®
æ¬ ç¹ãæ¹è¯ããçºã«å¯æº¶æ§åæ£å®å®çšæš¹èãšäžæº¶
æ§ã©ããã¯ã¹ç²åãååŠçã«çµåããããæ段ã
èæ¡ãããç±³åœç¹èš±3990980å·çã«é瀺ãããŠã
ããããããªããæ¬çºæè çã®å®éšçµæã«ããã°
åèšç±³åœç¹èš±çã«é瀺ãããŠããæ段ã«ãã€ãŠè£œ
é ãããç²åã¯ç²åŸååžæ²ç·ã«ãããããŒã¯å€ã
ïŒã€ä»¥äžååšããããååžå¹ ãåºããªã©ç²åŸãå
äžã«å¶åŸ¡ããããšãå°é£ã§ããããã€ãŸãããã
ã®çµæã®åçŸæ§ããããªããšããæ¬ ç¹ããã€ãã
äžè¬ã«æš¹èç²åãåæ£ããŠãªã液äœçŸåå€ã®ä¿å
æ§ã»å®å®æ§ãç»ååçŸæ§ãšãã€ãæ§èœã¯æš¹èç²å
ã®ç²åŸã«è² ããšããã倧ãããç²åŸãåäžã«æã€
ãŠããªãæ§èœã®å£åã»æªåãèããã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæã¯ä»¥äžã®ãããªåŸæ¥ã®éé»åççšæ¶²äœçŸ
åå€ãæããæ¬ ç¹ãæ¹è¯ãããã®ã§ãããåŸã€ãŠ
æ¬çºæã®ç®çã¯é·æä¿åãç¹°ãè¿ã䜿çšã«ãã€ãŠ
ãååæ£æ§ãå®å®æ§ãå£åããªã液äœçŸåå€ãæ
äŸããããšã«ãããæ¬çºæã®ä»ã®ç®çã¯åäžãªç²
ååŸããã¡ç»åã®åçŸæ§ã®åªãã液äœçŸåå€ãæ
äŸããããšã«ãããåãæ¬çºæã®æŽã«ä»ã®ç®çã¯
é·æã®ç¹°ãè¿ã䜿çšã«ãã€ãŠãé液ãã³ãã®ç®ã¥
ãŸãçã®çŸåè£ çœ®ã®æ éãç»åæ±ããçããªã液
äœçŸåå€ãæäŸããããšã«ãããåãæ¬çºæã®æŽ
ã«ä»ã®ç®çã¯é·æä¿åãç¹°ãè¿ã䜿çšã«ãã€ãŠã
ç²åã®æ¥µæ§ãå€åããåžžã«é®®æãªç»åãåçŸãã
液äœçŸåå€ãæäŸããããšã«ããã åãæ¬çºæã®å¥ã®ç®çã¯ãåªããå°å·ã€ã³ã¯æ
èæ§ãšèå·æ§ãæãããªãã»ããå°å·çšåçã®é»
ååçæ³ã«ããäœæãå¯èœã«ãã液äœçŸåå€ãæ
äŸããããšã«ããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãé»æ°æµæïŒïŒ9Ωã»cm以äžãèªé»ç
3.5以äžã®æ äœæ¶²ã«å°ãªããšãæš¹èãåæ£ããŠãª
ãéé»åççšæ¶²äœçŸåå€ã«ãããŠã該åæ£æš¹èç²
åãäžèšã¢ãããŒ(A)åã³äžèšã¢ãããŒ(B)ããã¢ã
ããŒ(A)ã®ç·éã«å¯ŸããŠïŒã50ééïŒ ã®å²åã§äžèš
åæ£å®å®çšæš¹èãååšãããŠéåããããšã«ãã€
ãŠåŸããããã®ã§ããããšãç¹åŸŽãšããéé»åç
çšæ¶²äœçŸåå€ã§ããã ã¢ãããŒ(A)ïŒ è©²æ äœæ¶²ã«å¯æº¶ã§ãããéåããããšã«ãã€ãŠ
äžæº¶åããã¢ãã㌠ã¢ãããŒ(B)ïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãã㌠åæ£å®å®æº¶æš¹èïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(C)ãšäžèš
äžè¬åŒïŒïŒã§ç€ºããããã¢ãããŒ(D)ãšãéåã
ãŠåŸãããå ±éåäœã«ãæŽã«äžèšäžè¬åŒïŒïŒã§
瀺ãããã¢ãããŒ(E)ãåå¿ãããŠäžé£œåçµåãå°
å ¥ããããšã«ãã€ãŠåŸããã該æ äœæ¶²ã«å¯æº¶ãªå ±
éåäœ äžè¬åŒïŒïŒ
äžã®æ äœæ¶²ã«å°ãªããšãæš¹èãåæ£ããŠãªãéé»
åççšæ¶²äœçŸåå€ã«é¢ãããã®ã§ãããç¹ã«åå
æ£æ§ãä¿åæ§ãå®å®æ§ãç»åã®åçŸæ§ãå®çæ§ã®
åªãã液äœçŸåå€ã«é¢ããã ãåŸæ¥ã®æè¡ã äžè¬ã®é»ååççšæ¶²äœçŸåå€ã¯ã«ãŒãã³ãã©ã
ã¯ããã°ãã·ã³ããã¿ãã·ã¢ãã³ãã«ãŒçã®ææ©
åã¯ç¡æ©ã®é¡æãããã¯ææãšã¢ã«ãããæš¹èã
ã¢ã¯ãªã«æš¹èãããžã³ãåæãŽã çã®å€©ç¶åã¯å
ææš¹èãç³æ²¹ç³»èèªæçåæ°ŽçŽ ã®ãããªé«çµ¶çž
æ§ã»äœèªé»çã®æ¶²äœäžã«åæ£ãæŽã«éå±ã»ãã±
ã³ãã¬ã·ãã·ãã¢ããæ²¹ãé«çŽèèªé žãããã«ã
ããªãã³ãå«æããããªããŒãªã©ã®æ¥µæ§å¶åŸ¡å€ã
å ãããã®ã§ããããã®ãããªçŸåå€äžã§ã¯æš¹è
ã¯äžæº¶æ§ã©ããã¯ã¹ç²åãšããŠçŽåŸæ°ÎŒïœãæ°çŸ
ÎŒïœã®ç²åç¶ã«åæ£ãããŠãããåŸæ¥ã®æ¶²äœçŸå
å€ã«ãããŠã¯å¯å¡æº¶æ§åæ£å®å®çšæš¹èã極æ§å¶åŸ¡
å€ãšäžæº¶æ§ã©ããã¯ã¹ç²åãšã®çµåãäžå åãªçº
ã«å¯æº¶æ§åæ£å®å®çšæš¹èåã³æ¥µæ§å¶åŸ¡å€ã溶液äž
ã«æ¡æ£ãæãç¶æ ã«ãã€ãããã®çºãé·æéã®ä¿
åãç¹°ãè¿ã䜿çšã«ãã€ãŠå¯æº¶æ§åæ£å®å®çšæš¹è
ãäžæº¶æ§ã©ããã¯ã¹ç²åããè±é¢ãç²åãæ²éã
åéãæšç©ããã極æ§ãäžæçã«ãªãããšããæ¬
ç¹ããã€ããåãäžåºŠåéãå ç©ããç²åã¯åå
æ£ãã«ããã®ã§çŸåæ©ã®éæã«ç²åãä»çãããŸ
ãŸãšãªããç»åéšã®æ±ããé液ãã³ãã®ç®ã¥ãŸã
çã®çŸåæ©ã®æ éã«ãã€ãªãã€ãŠããããããã®
æ¬ ç¹ãæ¹è¯ããçºã«å¯æº¶æ§åæ£å®å®çšæš¹èãšäžæº¶
æ§ã©ããã¯ã¹ç²åãååŠçã«çµåããããæ段ã
èæ¡ãããç±³åœç¹èš±3990980å·çã«é瀺ãããŠã
ããããããªããæ¬çºæè çã®å®éšçµæã«ããã°
åèšç±³åœç¹èš±çã«é瀺ãããŠããæ段ã«ãã€ãŠè£œ
é ãããç²åã¯ç²åŸååžæ²ç·ã«ãããããŒã¯å€ã
ïŒã€ä»¥äžååšããããååžå¹ ãåºããªã©ç²åŸãå
äžã«å¶åŸ¡ããããšãå°é£ã§ããããã€ãŸãããã
ã®çµæã®åçŸæ§ããããªããšããæ¬ ç¹ããã€ãã
äžè¬ã«æš¹èç²åãåæ£ããŠãªã液äœçŸåå€ã®ä¿å
æ§ã»å®å®æ§ãç»ååçŸæ§ãšãã€ãæ§èœã¯æš¹èç²å
ã®ç²åŸã«è² ããšããã倧ãããç²åŸãåäžã«æã€
ãŠããªãæ§èœã®å£åã»æªåãèããã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæã¯ä»¥äžã®ãããªåŸæ¥ã®éé»åççšæ¶²äœçŸ
åå€ãæããæ¬ ç¹ãæ¹è¯ãããã®ã§ãããåŸã€ãŠ
æ¬çºæã®ç®çã¯é·æä¿åãç¹°ãè¿ã䜿çšã«ãã€ãŠ
ãååæ£æ§ãå®å®æ§ãå£åããªã液äœçŸåå€ãæ
äŸããããšã«ãããæ¬çºæã®ä»ã®ç®çã¯åäžãªç²
ååŸããã¡ç»åã®åçŸæ§ã®åªãã液äœçŸåå€ãæ
äŸããããšã«ãããåãæ¬çºæã®æŽã«ä»ã®ç®çã¯
é·æã®ç¹°ãè¿ã䜿çšã«ãã€ãŠãé液ãã³ãã®ç®ã¥
ãŸãçã®çŸåè£ çœ®ã®æ éãç»åæ±ããçããªã液
äœçŸåå€ãæäŸããããšã«ãããåãæ¬çºæã®æŽ
ã«ä»ã®ç®çã¯é·æä¿åãç¹°ãè¿ã䜿çšã«ãã€ãŠã
ç²åã®æ¥µæ§ãå€åããåžžã«é®®æãªç»åãåçŸãã
液äœçŸåå€ãæäŸããããšã«ããã åãæ¬çºæã®å¥ã®ç®çã¯ãåªããå°å·ã€ã³ã¯æ
èæ§ãšèå·æ§ãæãããªãã»ããå°å·çšåçã®é»
ååçæ³ã«ããäœæãå¯èœã«ãã液äœçŸåå€ãæ
äŸããããšã«ããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãé»æ°æµæïŒïŒ9Ωã»cm以äžãèªé»ç
3.5以äžã®æ äœæ¶²ã«å°ãªããšãæš¹èãåæ£ããŠãª
ãéé»åççšæ¶²äœçŸåå€ã«ãããŠã該åæ£æš¹èç²
åãäžèšã¢ãããŒ(A)åã³äžèšã¢ãããŒ(B)ããã¢ã
ããŒ(A)ã®ç·éã«å¯ŸããŠïŒã50ééïŒ ã®å²åã§äžèš
åæ£å®å®çšæš¹èãååšãããŠéåããããšã«ãã€
ãŠåŸããããã®ã§ããããšãç¹åŸŽãšããéé»åç
çšæ¶²äœçŸåå€ã§ããã ã¢ãããŒ(A)ïŒ è©²æ äœæ¶²ã«å¯æº¶ã§ãããéåããããšã«ãã€ãŠ
äžæº¶åããã¢ãã㌠ã¢ãããŒ(B)ïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãã㌠åæ£å®å®æº¶æš¹èïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(C)ãšäžèš
äžè¬åŒïŒïŒã§ç€ºããããã¢ãããŒ(D)ãšãéåã
ãŠåŸãããå ±éåäœã«ãæŽã«äžèšäžè¬åŒïŒïŒã§
瀺ãããã¢ãããŒ(E)ãåå¿ãããŠäžé£œåçµåãå°
å ¥ããããšã«ãã€ãŠåŸããã該æ äœæ¶²ã«å¯æº¶ãªå ±
éåäœ äžè¬åŒïŒïŒ
ãåŒã
äžè¬åŒïŒïŒ
ãåŒã
äžè¬åŒäžããã¯ââãââãâCOâãâ
CO2âãâSO2âãâOCOâãâCONHâãâ
CONR2ïŒR2ã¯çåæ°ŽçŽ åºïŒãâNHCOâãâ
NHCO2âãâNHCONHâãâCH2âã®ãããã
ãè¡šããäºãã«åãã§ãã€ãŠãç°ãªã€ãŠãããã
å Žåã«ãã€ãŠã¯ïŒ¹ã¯ååšããªããŠããããR1ã¯
ççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯â
CO2Hã
CO2âãâSO2âãâOCOâãâCONHâãâ
CONR2ïŒR2ã¯çåæ°ŽçŽ åºïŒãâNHCOâãâ
NHCO2âãâNHCONHâãâCH2âã®ãããã
ãè¡šããäºãã«åãã§ãã€ãŠãç°ãªã€ãŠãããã
å Žåã«ãã€ãŠã¯ïŒ¹ã¯ååšããªããŠããããR1ã¯
ççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯â
CO2Hã
ãåŒãâCOClãâOHãâNH2ãâ
NHR3ïŒR3ã¯çåæ°ŽçŽ åºïŒãâNCOãã®ããããã
è¡šããã ã¯ååå£ïŒ¹ãšååå£ïŒºãé£çµããçåæ°ŽçŽ åº
ãè¡šããããããååãä»ããŠããããåå Žåã«
ãã€ãŠã¯ïŒ¬ã¯ååšããªããŠããããa1ïŒa2ïŒa3ïŒ
b1ïŒb2ïŒb3ã¯æ°ŽçŽ ååãçåæ°ŽçŽ åºãã«ã«ããã·
ã«åºãåã¯çåæ°ŽçŽ åºãä»ããã«ã«ããã·ã«åºã
è¡šããäºãã«åããŠãã€ãŠãç°ãªã€ãŠãããã äžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒçŸ€ããéžã°ã
ãã¢ãããŒ(B)ãšã¢ãããŒ(D)ã¯äºãã«åãã§ãã€ã
ç°ãªã€ãŠãããããŸããäžè¬åŒïŒïŒã§ç€ºããã
ã¢ãããŒçŸ€ããéžã°ããã¢ãããŒ(C)ãšã¢ãããŒ(E)
ã¯ç°ãªã€ããã®ã§ããããã€äž¡è ã®ïŒºéšåãååŠ
çµåãã€ããåŸãããã«éžã°ããã æ¬çºæã«çšããé»æ°æµæ109Ωã»cm以äžãèªé»
ç3.5以äžã®æ äœæ¶²ãšããŠå¥œãŸããã¯çŽéç¶åã¯
åæç¶ã®èèªæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ãè³éŠ
æçåæ°ŽçŽ åã³ãããã®ããã²ã³çœ®æäœãçšãã
ããšãã§ãããäŸãã°ãªã¯ã¿ã³ãã€ãœãªã¯ã¿ã³ã
ãã«ã³ãã€ãœãã«ã³ããã«ãªã³ãããã³ãããã«
ã³ãã€ãœããã«ã³ãã¢ã€ãœããŒïŒ¥ãã¢ã€ãœããŒ
ãã¢ã€ãœããŒïŒšãã¢ã€ãœããŒïŒ¬ïŒã¢ã€ãœããŒïŒ
ãšã¯ãœã³ç€Ÿã®åååïŒãã·ãšã«ãŸãŒã«70ãã·ãšã«
ãŸãŒã«71ïŒã·ãšã«ãŸãŒã«ïŒã·ãšã«ãªã€ã«ç€Ÿã®åå
åïŒãã¢ã ã¹ã³OMSãã¢ã ã¹ã³460溶å€ïŒã¢ã ã¹
ã³ïŒã¹ããªãã瀟ã®åååïŒçãåç¬ãããã¯æ··
åããŠçšãããæ¬çºæã«ãããæš¹èïŒäžæº¶æ§ã©ã
ãã¯ã¹ç²åïŒã¯å¯æº¶æ§åæ£å®å®çšæš¹èãçšããŠã
ããããéåé ç²æ³ã«ãã補é ããããããã®æ
ã®æº¶æ¥³ãšããŠã¯åèšæ äœæ¶²ã«æ··åãããã®ã§ãã
ã°ããçŽéç¶åã¯åæç¶ã®èèªæçåæ°ŽçŽ ãèç°
åŒçåæ°ŽçŽ ãè³éŠæçåæ°ŽçŽ åã³ãããã®ããã²
ã³çœ®æäœãçšããããšãã§ãããäŸãã°ããªã¯ã¿
ã³ãã€ãœãªã¯ã¿ã³ããã«ã³ãã€ãœãã«ã³ããã«ãª
ã³ãããã³ãããã«ã³ãã€ãœããã«ã³ãã¢ã€ãœã
ãŒïŒ¥ãã¢ã€ãœããŒïŒ§ãã¢ã€ãœããŒïŒšãã¢ã€ãœããŒ
ãã·ãšã«ãŸãŒã«70ãã·ãšã«ãŸãŒã«71ãã¢ã ã¹ã³
OMSãã¢ã ã¹ã³460溶å€çãåç¬ãããã¯æ··åã
ãŠçšãããäžæº¶æ§ã©ããã¯ã¹ç²åããã®ãããªé
æ°Žçšæ¥³äžã§å®å®ã«åŸãçºã«åèšã¢ãããŒ(C)ïŒ(D)ïŒ
(E)ããåæãããå¯æº¶æ§åæ£å®å®çšæš¹èãïŒçš®é¡
以äžçšããã該暹èãåæããéã«çšãã溶楳ãš
ããŠã¯ç¹ã«å¶éã¯ç¡ãã該暹èã溶楳é€å»æäœç¡
ãã§æ¬¡ã®éåé ç²ã«é©çšããã«ã¯éåé ç²ã§çšã
ã溶楳ãšæ··åãããã®ãæãŸãããäŸãã°çŽéç¶
åã¯åæç¶ã®èèªæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ã
è³éŠæçåæ°ŽçŽ åã³ãããã®ããã²ã³çœ®æäœãå
ç¬ãããã¯æ··åããŠçšãããåèšäžè¬åŒïŒïŒã§
瀺ãããã¢ãããŒ(D)ã¯è©²æš¹èã«å¯æº¶æ§ãä»äžãã
ãã®ã§ããããçåæ°ŽçŽ åºR2ãé»æ°æµæ109Ωã»
cm以äžãèªé»ç3.5以äžã®æ äœæ¶²ã«æ··åãæã圢
æ ã§ãããã®ãæãŸãããäŸãã°ã¢ã¯ãªã«é žãã
ãã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ãã«ãšã¹ãã«ïŒã¢ã«ãã«
åºãšããŠã¯äŸãã°ãªã¯ãã«åºããã·ã«åºãããã·
ã«åºãããã©ãã·ã«åºããããµãã·ã«åºããªã¯ã¿
ãã·ã«åºãïŒâãšãã«ããã·ã«åºãããïŒãåã¯
ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ã±ãã«ãš
ã¹ãã«ïŒã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãªã¯ããã«
åºããã»ãã«åºããªã¯ã¿ãã»ãã«åºããªã¬ã€ã«åº
ãããïŒçãçšããããšãã§ãããåãåèšäžè¬
åŒïŒïŒã§ç€ºãããã¢ãããŒ(C)ãšããŠã¯äžé£œåã«
ã«ãã³é žïŒäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã
ã¬ã€ã³é žããããŒã«é žãã¯ããã³é žãªã©ãããïŒã
åã¯ãã®å¡©åç©ïŒäŸãã°ãã¢ã¯ãªã«é žã¯ãã©ã€
ããã¡ã¿ã¯ãªã«é žã¯ãã©ã€ããã¯ããã³é žã¯ãã©
ã€ããªã©ãããïŒããããã¯äžé£œåã¢ã«ã³ãŒã«
ïŒäŸãã°ã¢ãªã«ã¢ã«ã³ãŒã«ãªã©ãããïŒãåã¯äžé£œ
åã¢ãã³ïŒäŸãã°ã¢ãªã«ã¢ãã³ãªã©ãããïŒãæŽ
ã«ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã°ãªã·ãžã«
ãšã¹ãã«ãããããã·ãããã«ãšã¹ãã«ãããã
ãã·ãšãã«ãšã¹ãã«çãçšããããšãã§ãããå
èšäžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(E)ãšããŠã¯å
è¿°ã®ã¢ãããŒ(C)ãšããŠæããå ·äœäŸãšåæ§ã®ãã®
ã䜿çšããã°ãããã¢ãããŒ(C)ãšç°ãªããã®ãéž
æãããã€äžè¬åŒïŒïŒã«ãããéšåãã¢ãã
ãŒ(C)ã®ïŒºéšåãšçž®åãä»å çã®åå¿ã§å®¹æã«ååŠ
çµåãé ããããã®ãéžæããå¿ èŠããããäŸã
ã°ã¢ãããŒ(C)ãšããŠïŒºéšåãâCO2Hã§ãããã
ãªãã®ãçšããå Žåã«ã¯ã¢ãããŒ(E)ãšããŠã¯ïŒºéš
åãâOHïŒ
è¡šããã ã¯ååå£ïŒ¹ãšååå£ïŒºãé£çµããçåæ°ŽçŽ åº
ãè¡šããããããååãä»ããŠããããåå Žåã«
ãã€ãŠã¯ïŒ¬ã¯ååšããªããŠããããa1ïŒa2ïŒa3ïŒ
b1ïŒb2ïŒb3ã¯æ°ŽçŽ ååãçåæ°ŽçŽ åºãã«ã«ããã·
ã«åºãåã¯çåæ°ŽçŽ åºãä»ããã«ã«ããã·ã«åºã
è¡šããäºãã«åããŠãã€ãŠãç°ãªã€ãŠãããã äžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒçŸ€ããéžã°ã
ãã¢ãããŒ(B)ãšã¢ãããŒ(D)ã¯äºãã«åãã§ãã€ã
ç°ãªã€ãŠãããããŸããäžè¬åŒïŒïŒã§ç€ºããã
ã¢ãããŒçŸ€ããéžã°ããã¢ãããŒ(C)ãšã¢ãããŒ(E)
ã¯ç°ãªã€ããã®ã§ããããã€äž¡è ã®ïŒºéšåãååŠ
çµåãã€ããåŸãããã«éžã°ããã æ¬çºæã«çšããé»æ°æµæ109Ωã»cm以äžãèªé»
ç3.5以äžã®æ äœæ¶²ãšããŠå¥œãŸããã¯çŽéç¶åã¯
åæç¶ã®èèªæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ãè³éŠ
æçåæ°ŽçŽ åã³ãããã®ããã²ã³çœ®æäœãçšãã
ããšãã§ãããäŸãã°ãªã¯ã¿ã³ãã€ãœãªã¯ã¿ã³ã
ãã«ã³ãã€ãœãã«ã³ããã«ãªã³ãããã³ãããã«
ã³ãã€ãœããã«ã³ãã¢ã€ãœããŒïŒ¥ãã¢ã€ãœããŒ
ãã¢ã€ãœããŒïŒšãã¢ã€ãœããŒïŒ¬ïŒã¢ã€ãœããŒïŒ
ãšã¯ãœã³ç€Ÿã®åååïŒãã·ãšã«ãŸãŒã«70ãã·ãšã«
ãŸãŒã«71ïŒã·ãšã«ãŸãŒã«ïŒã·ãšã«ãªã€ã«ç€Ÿã®åå
åïŒãã¢ã ã¹ã³OMSãã¢ã ã¹ã³460溶å€ïŒã¢ã ã¹
ã³ïŒã¹ããªãã瀟ã®åååïŒçãåç¬ãããã¯æ··
åããŠçšãããæ¬çºæã«ãããæš¹èïŒäžæº¶æ§ã©ã
ãã¯ã¹ç²åïŒã¯å¯æº¶æ§åæ£å®å®çšæš¹èãçšããŠã
ããããéåé ç²æ³ã«ãã補é ããããããã®æ
ã®æº¶æ¥³ãšããŠã¯åèšæ äœæ¶²ã«æ··åãããã®ã§ãã
ã°ããçŽéç¶åã¯åæç¶ã®èèªæçåæ°ŽçŽ ãèç°
åŒçåæ°ŽçŽ ãè³éŠæçåæ°ŽçŽ åã³ãããã®ããã²
ã³çœ®æäœãçšããããšãã§ãããäŸãã°ããªã¯ã¿
ã³ãã€ãœãªã¯ã¿ã³ããã«ã³ãã€ãœãã«ã³ããã«ãª
ã³ãããã³ãããã«ã³ãã€ãœããã«ã³ãã¢ã€ãœã
ãŒïŒ¥ãã¢ã€ãœããŒïŒ§ãã¢ã€ãœããŒïŒšãã¢ã€ãœããŒ
ãã·ãšã«ãŸãŒã«70ãã·ãšã«ãŸãŒã«71ãã¢ã ã¹ã³
OMSãã¢ã ã¹ã³460溶å€çãåç¬ãããã¯æ··åã
ãŠçšãããäžæº¶æ§ã©ããã¯ã¹ç²åããã®ãããªé
æ°Žçšæ¥³äžã§å®å®ã«åŸãçºã«åèšã¢ãããŒ(C)ïŒ(D)ïŒ
(E)ããåæãããå¯æº¶æ§åæ£å®å®çšæš¹èãïŒçš®é¡
以äžçšããã該暹èãåæããéã«çšãã溶楳ãš
ããŠã¯ç¹ã«å¶éã¯ç¡ãã該暹èã溶楳é€å»æäœç¡
ãã§æ¬¡ã®éåé ç²ã«é©çšããã«ã¯éåé ç²ã§çšã
ã溶楳ãšæ··åãããã®ãæãŸãããäŸãã°çŽéç¶
åã¯åæç¶ã®èèªæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ã
è³éŠæçåæ°ŽçŽ åã³ãããã®ããã²ã³çœ®æäœãå
ç¬ãããã¯æ··åããŠçšãããåèšäžè¬åŒïŒïŒã§
瀺ãããã¢ãããŒ(D)ã¯è©²æš¹èã«å¯æº¶æ§ãä»äžãã
ãã®ã§ããããçåæ°ŽçŽ åºR2ãé»æ°æµæ109Ωã»
cm以äžãèªé»ç3.5以äžã®æ äœæ¶²ã«æ··åãæã圢
æ ã§ãããã®ãæãŸãããäŸãã°ã¢ã¯ãªã«é žãã
ãã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ãã«ãšã¹ãã«ïŒã¢ã«ãã«
åºãšããŠã¯äŸãã°ãªã¯ãã«åºããã·ã«åºãããã·
ã«åºãããã©ãã·ã«åºããããµãã·ã«åºããªã¯ã¿
ãã·ã«åºãïŒâãšãã«ããã·ã«åºãããïŒãåã¯
ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ã±ãã«ãš
ã¹ãã«ïŒã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãªã¯ããã«
åºããã»ãã«åºããªã¯ã¿ãã»ãã«åºããªã¬ã€ã«åº
ãããïŒçãçšããããšãã§ãããåãåèšäžè¬
åŒïŒïŒã§ç€ºãããã¢ãããŒ(C)ãšããŠã¯äžé£œåã«
ã«ãã³é žïŒäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã
ã¬ã€ã³é žããããŒã«é žãã¯ããã³é žãªã©ãããïŒã
åã¯ãã®å¡©åç©ïŒäŸãã°ãã¢ã¯ãªã«é žã¯ãã©ã€
ããã¡ã¿ã¯ãªã«é žã¯ãã©ã€ããã¯ããã³é žã¯ãã©
ã€ããªã©ãããïŒããããã¯äžé£œåã¢ã«ã³ãŒã«
ïŒäŸãã°ã¢ãªã«ã¢ã«ã³ãŒã«ãªã©ãããïŒãåã¯äžé£œ
åã¢ãã³ïŒäŸãã°ã¢ãªã«ã¢ãã³ãªã©ãããïŒãæŽ
ã«ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã°ãªã·ãžã«
ãšã¹ãã«ãããããã·ãããã«ãšã¹ãã«ãããã
ãã·ãšãã«ãšã¹ãã«çãçšããããšãã§ãããå
èšäžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(E)ãšããŠã¯å
è¿°ã®ã¢ãããŒ(C)ãšããŠæããå ·äœäŸãšåæ§ã®ãã®
ã䜿çšããã°ãããã¢ãããŒ(C)ãšç°ãªããã®ãéž
æãããã€äžè¬åŒïŒïŒã«ãããéšåãã¢ãã
ãŒ(C)ã®ïŒºéšåãšçž®åãä»å çã®åå¿ã§å®¹æã«ååŠ
çµåãé ããããã®ãéžæããå¿ èŠããããäŸã
ã°ã¢ãããŒ(C)ãšããŠïŒºéšåãâCO2Hã§ãããã
ãªãã®ãçšããå Žåã«ã¯ã¢ãããŒ(E)ãšããŠã¯ïŒºéš
åãâOHïŒ
ãåŒãâNH2ïŒâNHR3ã§ãã
ãããªãã®ãéžæããã°ããããŸãã¢ãããŒ(C)ã®
éšåãâOHã§ããå Žåã«ã¯ã¢ãããŒ(E)ãšããŠ
ã¯ïŒºéšåãâCO2HïŒâCOClïŒâNCOã§ãããã
ãªãã®ãéžæããã°ããããã®ä»ã«ãçš®ã ã®çµã¿
åããããããææ©ååŠã®åéã§ã¯å®¹æã«éžæã§
ããã以äžè¿°ã¹ããããªææãçšããŠæ¬çºæã«çš
ããããäžé£œåçµåãå«ãå¯æº¶æ§å ±éåäœæš¹èã
補é ããã«ã¯æ¬¡ã®ããã«ãããåè¿°ã®æº¶æ¥³ã«ã¢ã
ããŒ(C)ãšã¢ãããŒ(D)ã溶解ãããéåéå§å€ã®å
åšäž50âã200âã§æ°æéå ç±ããã次ã«ã¢ãã
ãŒ(E)åã³å¿ èŠã«ããéåç³»ã§éåžžçšããããå ¬ç¥
ãšéåçŠæ¢å€ãå ããæŽã«åå¿åœ¢æ ã«ãã€ãŠå¿ èŠ
ã§ããã°ã©ãŠãªã«ãžã¡ãã«ã¢ãã³ãªã©ã®è§Šåªãå
ããŠåæ§ã®æž©åºŠã§æ°æéå ç±ããããã®ãšã䜿çš
ããã¢ãããŒ(C)ãšã¢ãããŒ(D)ã®æ¯çãšããŠã¯ã¢ã«
æ¯ã§50ïŒ50ã0.5ïŒ99.5ã奜ãŸããã¯20ïŒ80ã
ïŒïŒ99ãã¢ãããŒ(C)ãšã¢ãããŒ(E)ã®æ¯çãšããŠã¯
ã¢ã«æ¯ã§ïŒïŒïŒãïŒïŒïŒã®ç¯å²ã§ããããšãæãŸ
ãããéåçŠæ¢å€ãçšããå Žåã¯åèšæº¶æ¥³ïŒã
ããã«æç®ããŠ0.01ïœãïŒïœã®éã䜿çšããã以
äžã®ããã«ããŠåŸãããäžé£œåçµåãå«ãå ±éå
äœã®ååéã¯5000ã50äžã§ããã以äžã«ãã®äžé£œ
åçµåãå«ãå ±éåäœã§ããå¯æº¶æ§åæ£å®å®çšæš¹
èã®å ·äœäŸã瀺ããæ¬çºæã¯ãããã«éå®ããã
ãã®ã§ã¯ãªãã 次ã«æš¹èåæ£æ¶²ãåŸãå·¥çšã«ã€ããŠèª¬æããã
åèšã¢ãããŒ(A)ãšããŠã¯åèšæ äœæ¶²ïŒé氎溶楳ïŒ
ã«å¯æº¶ã§ãããéåããããšã«ãã€ãŠäžæº¶åãã
ãã®ãçšãããäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«
é žãã¯ããã³é žãã€ã¿ã³ã³é žããã€ã¬ã³é žçã®äž
飜åã«ã«ãã³é žã®ççŽ æ°ïŒãïŒã®ã¢ã«ãã«ãšã¹ã
ã«ïŒççŽ æ°ïŒãïŒã®èèªæã«ã«ãã³é žã®ããã«ãš
ã¹ãã«ãããã¯ã¢ãªã«ãšã¹ãã«ïŒã¢ã¯ãªã«é žãã¡
ã¿ã¯ãªã«é žãã¯ããã³é žããã¬ã€ã³é žãã€ã¿ã³ã³
é žçã®äžé£œåã«ã«ãã³é žãããã¯ãã®ç¡æ°Žç©ïŒã
ãããã·ãšãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒãïŒïŒ®âããã«ãããªãã³ãã¢ã¯ãªããããª
ã«ãããã«ãšãŒãã«çãçšããããšãã§ããã
åãäžè¬åŒïŒïŒã§ç€ºãããåèšã¢ãããŒ(B)ãšã
ãŠã¯ãäŸãã°ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®
ççŽ æ°ïŒã20ã®ã¢ã«ãã«ãšã¹ãã«ïŒã¢ã«ãã«åºãš
ããŠã¯äŸãã°ãªã¯ãã«åºããã·ã«åºãããã·ã«
åºãããã©ãã·ã«åºããããµãã·ã«åºããªã¯ã¿ã
ã·ã«åºãïŒâãšãã«ããã·ã«åºãããïŒãåã¯ã¢
ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ã±ãã«ãšã¹
ãã«ïŒã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãªã¯ããã«
åºããã»ãã«åºããªã¯ã¿ãã»ãã«åºããªã¬ã€ã«åº
ãããïŒçãçšããããšãã§ããã 以äžã®ãããªã¢ãããŒ(A)ã®ãã¡ã®ïŒçš®é¡ããã
ã¯ïŒçš®é¡ä»¥äžã®æ··åç©ãšãã¢ãããŒ(B)ã®ãã¡ã®ïŒ
çš®é¡ãããã¯ïŒçš®é¡ä»¥äžã®æ··åç©ãšãåèšå·¥çšã«
ãã€ãŠåŸãããäžé£œåçµåãæããå ±éåäœïŒå
解å®å®çšæš¹èïŒã®ãã¡ã®ïŒçš®é¡ãããã¯ïŒçš®é¡ä»¥
äžã®æ··åç©ãåèšé氎溶楳ã«æº¶è§£ãããå¿ èŠã«ã
ãéåç³»ã§éåžžçšããããå ¬ç¥ã®éåéå§å€ã®å
åšäžã50âã200âã§æ°æéå ç±ããã ãã®ãšãåŸæ¥å ¬ç¥ã®åæ£å®å®å€ã䜵ããŠçšãã
ããšãã§ãããå³ã¡é氎溶åªã«å¯æº¶ãªåçš®ã®åæ
åã¯å€©ç¶æš¹èãåç¬ãããã¯ïŒçš®é¡ä»¥äžæ··åããŠ
çšããããšãã§ãããäŸãã°ççŽ æ°ïŒã30ã®ã¢ã«
ãã«éïŒããã²ã³ååãããããã·ã«åºãã¢ãã
åºãã¢ã«ã³ãã·åºçã®çœ®æåºãå«æããŠãããã
ããã¯é žçŽ ååãçªçŽ ååãç¡«é»ååãªã©ã®ãã
ãååã§äž»éã®ççŽ âççŽ ååçµåãä»ãããŠã
ãŠãããïŒãæããã¢ã¯ãªã«é žåã¯ã¡ã¿ã¯ãªã«é ž
ã®ã¢ã«ãã«ãšã¹ãã«ãèèªé žã®ããã«ãšã¹ãã«ã
ãããã¯ããã«ã¢ã«ãã«ãšãŒãã«åã¯ãã¿ãžãš
ã³ãã€ãœãã¬ã³ããžã€ãœããã¬ã³çã®ãªã¬ãã€ã³
çã®åéäœã®éååã¯ïŒçš®é¡ä»¥äžã®çµåãã«ãã
å ±éåäœãæŽã«ã¯äžèšé氎溶åªã«å¯æº¶ãªéåäœã
圢æããåéäœãšãäžèšã®æ§ãªåçš®ã®åéäœïŒçš®
é¡ä»¥äžãšã®å ±éåäœã§ãã€ãŠå ±éåäœãé氎溶åª
ã«å¯æº¶ãªç¯å²ã§äžèšåéäœãå«æãããã®ãäŸã
ã°é ¢é žããã«ïŒã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žåã¯ã¯
ããã³é žçã®ã¡ãã«ããšãã«ãïœâãããã«ãã
ãã¯isoâãããã«ãšã¹ãã«ïŒã¹ãã¬ã³ãããã«
ãã«ãšã³ãαâã¡ãã«ã¹ãã¬ã³ã®åŠãã¹ãã¬ã³èª
å°äœïŒã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žã
ãã¬ã€ã³é žãã€ã¿ã³ã³é žã®åŠãäžé£œåã«ã«ãã³é ž
åã¯ãã®ç¡æ°Žç©ïŒããããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããããããã·ãšãã«ã¢ã¯ãªã¬ãŒãããžãšãã«ã¢
ãããšãã«ã¡ã¿ã¯ãªã¬ãŒããâããã«ãããªã
ã³ãã¢ã¯ãªã«ã¢ãããã¢ã¯ãªããããªã«ãïŒâã¯
ãããšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒïŒâããª
ãã«ãªããšãã«ã¡ã¿ã¯ãªã¬ãŒãã®åŠãããããã·
ã«åºãã¢ããåºãã¢ããåºãã·ã¢ãåºãã¹ã«ãã³
é žåºãã«ã«ããã«åºãããã²ã³ååããããç°ç
ã®å皮極æ§ãå«æããåéäœãªã©ããããããšã
ã§ããããããã¯äžèšã®åææš¹èã®ä»ã«ãã¢ã«ã
ããæš¹èãåçš®ã®èèªé žã§å€æ§ããã¢ã«ãããæš¹
èãã¢ããæ²¹ãå€æ§ããªãŠã¬ã¿ã³æš¹èãªã©ã®å€©ç¶
æš¹èãçšããããšãã§ããã䜿çšããã¢ãããŒ(A)
ã¯åè¿°ã®éãïŒçš®é¡ã§ãïŒçš®é¡ä»¥äžã§ãããŸããª
ãããããã«ããŠããã®ç·éã¯åå¿æº¶åªã§ããå
èšé氎溶åª100éééšã«å¯ŸããŠïŒã80éééšã§ã
ã奜ãŸããã¯10ã50éééšã§ãããã¢ãããŒ(B)ã¯
ãã¯ãïŒçš®é¡ã§ãïŒçš®é¡ä»¥äžã§ãããŸããªããã
ã®ç·éã¯ã¢ãããŒ(A)ã®ç·ééã«å¯ŸããŠ0.1ã50é
éïŒ ã§ããã奜ãŸããã¯0.5ã10ééïŒ ã§ããã
åæ£å®å®çšæš¹èã¯äžèšå šã¢ãããŒ(A)100éééšã«
察ããŠïŒã50éééšã§ãã奜ãŸããã¯ïŒã20éé
éšã§ãããéåéå§å€ãçšããå Žåã¯å šåéäœ
100éééšã«å¯ŸããŠ0.1ãïŒéééšãé©åœã§ããã
以äžã®ããã«ããŠè£œé ãããã©ããã¯ã¹ã¯20âã«
ãããç²åºŠã20cp以äžã§ãéæ°Žåæ£ç³»æš¹èã¯å
äžã§ååæ£ã®ç²åŸååžããã¡ããã€ææã®ç²åŸã«
å¶åŸ¡ããã®ã容æã§ããããããã®åæ£æš¹èã¯é
åžžã«è¯å¥œãªååæ£æ§ãå®å®æ§ãå®çæ§ãæããã
ã®ã§ãããé·æã®ä¿åãå®éã®çŸåæ©ã«ãããç¹°
ãè¿ã䜿çšãè¡ã€ãŠã容åšåã³è£ 眮åéšãžã®æ²
éãåéãä»çæ±ããå šãçããåæŽã«å ç±çã«
ãã€ãŠå®çãè¡ããšåŒ·åºãªè¢«èã圢æããèä¹ å
ã«å¯ãç»åã圢æãããããããé¡èãªæ§èœåäž
ã¯æ¬¡ã®æ°ããªæè¡ã«ããéæããããšæšæž¬ãã
ããåŸæ¥ãéæ°Žåæ£ç³»æš¹èã«ãããŠã¯é·æã®ä¿å
ãç¹°ãè¿ã䜿çšã«ãã€ãŠå¯æº¶æ§åæ£å®å®çšæš¹èã
äžæº¶æ§ã©ããã¯ã¹ç²åããè±é¢ããæ§èœãå£åã
ããšããæ¬ ç¹ãããããã®æ¬ ç¹ãæ¹è¯ãã¹ãç±³åœ
ç¹èš±3990980å·çã«é瀺ãããŠãããããªæ段ã
èæ¡ãããŠããããšã¯åè¿°ããéãã§ããããã
ããªããåèšç±³åœç¹èš±çã«é瀺ãããŠãããããª
æ段ã«ãã€ãŠè£œé ãããç²åã¯ç²åŸååžæ²ç·ã«ã
ããããŒã¯å€ãïŒã€ä»¥äžååšããããããŒã¯ã®å¹
ãåºãã€ãããããªã©ç²åŸãåäžã«å¶åŸ¡ããããš
ãå°é£ã§ããããã€ãŸããããã®çµæã®åçŸæ§ã
ãããªããšããæ¬ ç¹ããã€ããããã«ãã®ãããª
ç²åãé·æã®ä¿åãç¹°ãè¿ã䜿çšã«äŸãããšæ²
éãåéãèµ·ããååæ£ããªããªããåèšç±³åœç¹
èš±ã«é瀺ãããŠãããããªæ段ãçšããªãå Žåã«
æ¯ã¹ãŠå€§ããªæ§èœã®åäžã¯èŠãããªãã€ããåŸã€
ãŠåèšæ段ã«ãã€ãŠãçšããå¯æº¶æ§åæ£å®å®çšæš¹
èã®å šéã®ãã¡äžæº¶æ§ã©ããã¯ã¹ç²åã«äžå¯éç
ã«çµåããŠããéšåã¯å ãã§ããããŸãç²åïŒå
ãããã«çµåããŠããæ°ããã¹ãŠã®äžæº¶æ§ã©ãã
ã¯ã¹ç²åã«ã€ããŠåäžã§ã¯ãªãããªãçå¯ãã®ã
ããã®ã§ãããšèããããã æ¬çºæã«ãããŠã¯åèšç±³åœç¹èš±ã«é瀺ãããŠã
ããããªç³»ã«ãã«éåããŠãå¯æº¶æ§æš¹èãšãªãã
ããããªã¢ãããŒãå ±åãããŠäžæº¶æ§ã©ããã¯ã¹
ç²åã®åœ¢æãè¡ãã®ã§ãå¯æº¶æ§åæ£å®å®çšæš¹èã
ç²åã«ã°ã©ããããéã«è©²ã¢ãããŒãæ°åãªãã
æ°ååãç²åã®éå掻æ§éšãšå¯æº¶æ§åæ£å®å®çšæº¶
æš¹èã®éå掻æ§éšã®éã«ã¯ãã€ãŠãªãã ã¡ããã
ãã®ãšæšæž¬ãããã æ¬çºæã«ãããŠãå¿ èŠãªãçè²å€ã䜿çšããŠã
è¯ãããã®çè²å€ãšããŠã¯ç¹ã«éå®ããããã®ã§
ã¯ãªããåŸæ¥å ¬ç¥ã®åçš®æŽé¡æåã¯ææã䜿çšã
ãããšãã§ããã該çè²å€ã¯åç¬ã§åèšé氎溶åª
äžã«åæ£ä¿é²å€çã䜵çšããŠåæ£ãããŠäœ¿çšããŠ
ãããããçè²å€è¡šé¢ã«ããªããŒãååŠçã«çµå
ãããã°ã©ããåç²åïŒäŸãã°ã¯ã©ããã«ãŒã
ã³ïŒäžè±ã¬ã¹ååŠè£œåååïŒã«ããŠäœ¿çšããŠãã
ããåãäžèšããæš¹èäžã«çè²å€ãå«æãããŠçš
ããŠãããã該åæ£æš¹èãçè²ããæ¹æ³ãšããŠäŸ
ãã°ãç¹éæ48â75242åå ¬å ±çã§å ¬ç¥ã®æ¹æ³ã§
ããåæ£æ©ïŒãã€ã³ãã·ãšãŒã«ãŒãã³ãã€ãã
ã«ãæ¯åãã«ãããŒã«ãã«ãªã©ïŒãçšããŠç©çç
ã«æš¹èäžã«åæ£ããæ¹æ³ãããã䜿çšããé¡æã
ææã¯éåžžã«å€ãç¥ãããŠãããäŸãã°ç£æ§é žå
ééç²ãã«ãŒãã³ãã©ãã¯ããã°ãã·ã³ãã¢ã«ã«
ãªãã«ãŒããã³ã¶ã€ãšããŒãããã¯ãªãã³ã¬ã
ãããã¿ãã·ã¢ãã³ãã«ãŒããã¿ãã·ã¢ãã³ãã©
ãã¯ããã³ãžã³ã€ãšããŒçãæããããã ä»ã®çè²ã®æ¹æ³ãšããŠãç¹éæ57â48738å·å ¬
å ±çã«èšèŒã®åŠããåæ£æš¹èç©ã奜ãŸããææã§
å ç±æè²ããæ¹æ³ãããã äŸãã°ãã³ã¶ã€ãšããŒãã¯ãªã¹ã¿ã«ãã€ãªã¬ã
ãããã¯ããªã¢ãã«ãŒããã©ã«ã€ãã°ãªãŒã³ãã»
ãªãã³ãã¢ã¹ãã¬ããããã¹ããŒã¹ã€ãšããŒãã
ã¹ããŒã¹ã¬ããããã¹ããŒã¹ãã«ãŒããœã«ãã³ã
ã¬ããçãæããããã æŽã«ä»ã®çè²ã®æ¹æ³ãšããŠãåæ£æš¹èãšææã
ååŠçã«çµåãããæ¹æ³ããããäŸãã°ç¹éæ53
â54029å·å ¬å ±çã§ã¯ãæš¹èãšææãšãåå¿ãã
ãæ¹æ³ãããã¯ç¹å ¬æ44â22955å·å ¬å ±çã§ã¯é
åããããšã§äžæº¶åãåæ£ãåŸãæš¹èã®åéäœã«
è²çŽ ãäºãçµåãããŠããæ¹æ³çã䜿çšããããš
ãã§ããã æ¬çºæã®æ¶²äœçŸåå€ã«ã¯ãè·é»ç¹æ§ã®åŒ·åã§ã
ããã¯ç»åæ§ã®æ¹è¯çã®ããã«ãå¿ èŠã«å¿ããŠ
çš®ã ã®æ·»å å€ãå ããŠãè¯ããäŸãã°ãååŽå
次ããé»ååçã第16å·»ã第ïŒå·ã44é ã«å ·äœç
ã«èšèŒãããŠããã äŸãã°ãžãŒïŒâãšãã«ããã·ã«ã¹ã«ãã³ãã¯é ž
éå±å¡©ããããã³é žéå±å¡©ãé«çŽèèªé žéå±å¡©ã
ã¬ã·ãã³ãããªïŒããã«ãããªãã³ïŒçã®æ·»å å€
ãæããããã æ¬çºæã®æ¶²äœçŸåå€ã®äž»èŠãªåçµæåã®éã«ã€
ããŠèª¬æããã°äžèšã®éãã§ããã æš¹èåã³çè²å€ãäž»æåãšããŠæãäžæº¶æ§ã©ã
ãã¯ã¹ç²åã¯ãæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.5
éééšã50éééšã奜ãŸããã0.5éééšä»¥äžã§
ãããšç»åæ¿åºŠãäžè¶³ãã50éééšä»¥äžã§ãããš
éé¢åéšãžã®ã«ããªãçãæããåæã®åæ£å®å®
å€çã®æ äœæ¶²äœå¯æº¶æ§æš¹èãå¿ èŠã«å¿ããŠäœ¿çšã
ããæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.5éééšã100
éééšçšåºŠå ããããšãã§ãããäžè¿°ã®æ§ãªè·é
調ç¯å€ã¯ãæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.001ã
1.0éééšã奜ãŸãããæŽã«å¿ èŠã«å¿ããŠå皮添
å å€ãå ããŠãè¯ãããããæ·»å ç©ã®ç·éã¯çŸå
å€ã®é»æ°æµæã«ãã€ãŠãã®äžéãèŠå¶ããããå³
ã¡ãäžæº¶æ§ã©ããã¯ã¹ç²åãé€å»ããç¶æ ã®æ¶²äœ
çŸåå€ã®é»æ°æµæã109Ωã»cm以äžã«ãªããšè¯è³ª
ã®é£ç¶é調åãåŸããé£ããªãã®ã§åæ·»å ç©ã®å
æ·»å éãããã®é床å ã§ã³ã³ãããŒã«ããããšã
å¿ èŠã§ããã ãå®æœäŸã 以äžã«æ¬çºæã®å®æœæ æ§ãäŸç€ºããæ¬çºæã®å
容ããããã«éå®ããããã®ã§ã¯ãªãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã128.7ïœãïŒâãã
ããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒã2.6ïœãåã³ãã«ãš
ã³240ïœã®æ··å溶液ãçªçŽ æ°æµäžæž©åºŠ75âã«å ç±
ããæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«1.3ïœ
ãæ·»å ãããïŒæéåŸã«åå¿å®¹åšãã€ãŒã³âã¹ã¿
ãŒã¯æ°Žåé¢è£ 眮ããšãã€ãããã€ããããã³0.2
ïœãç¡«é ž0.1ïœãã¡ã¿ã¯ãªã«é ž1.7ïœãå ãããæ¹
æããªãã枩床ã110âè¿ãããæ·»å ããã¡ã¿ã¯
ãªã«é žã65ïŒ æ¶è²»ãããè¿åå¿ãè¡ã€ããåå¿
åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«æå ¥ããŠåæ²
粟補ãããé»è²å³ã垯ã³ãç²æ«ãåŸãã åŸãããç©è³ªã®ç²æ«ã®å¹³åååéãé«é液äœã¯
ãããã°ã©ãæ³ã«ãã枬å®ãããš17.8Ã104ã§ã
ã€ãã å¯æº¶æ§åæ£å®å®æš¹èã®è£œé äŸïŒïŒååç©äŸïŒïŒ ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã93.6ïœãã°ãªãžã«ã¡ã¿
ã¯ãªã¬ãŒã4.5ïœãåã³ãã«ãšã³230ïœã®æ··å液ã
çªçŽ æ°æµäžæž©åºŠ85âã«å ç±ããæ¹æäžã«ãã³ãŸã€
ã«ããŒãªããµã€ã1.0ïœãæ·»å ãããïŒæéåŸã«
枩床ã40âè¿äžããã€ããããã³0.2ïœãã©ãŠãª
ã«ãžã¡ãã«ã¢ãã³0.2ïœãã¡ã¿ã¯ãªã«é ž2.8ïœãå
ãããæ¹æããªãã枩床ã115âè¿ãããæ·»å ã
ãã¡ã¿ã¯ãªé žã®55ïŒ ãæ€åºãããªããªãè¿åå¿ã
è¡ã€ããåå¿åŸãåå¿åŸã4000ïœã®ã¡ã¿ããŒã«ã«
æå ¥ããŠåæ²ç²Ÿè£œãè€è²ã®ç²èª¿ç©ãåŸããåèšè£œ
é äŸïŒãšåæ§ã«ããŠæž¬å®ããå¹³åååéã¯15.0Ã
104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã130ïœãã¡ã¿ã¯ãªã«
é ž1.4ïœãåã³ãã«ãšã³240ïœã®æ··å溶液ãçªçŽ æ°
æµäžæž©åºŠ85âã«å ç±ããæ¹æäžã«ãã³ãŸã€ã«ããŒ
ãªãµã€ã1.3ïœãæ·»å ãããïŒæéåŸã«ã枩床ã
40âè¿äžãããã€ããããã³0.2ïœãã©ãŠãªã«ãž
ã¡ãã«ã¢ãã³0.2ïœãã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒã2.0
ïœãå ãããæ¹æããªãã枩床ã115âè¿ããã
çšããã¡ã¿ã¯ãªã«é žã®55ïŒ ãæ€åºãããªããªãè¿
åå¿ãè¡ã€ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ã
ãŒã«ã«æå ¥ããŠåæ²ç²Ÿè£œãããé»è²å³ã垯ã³ãç²
æ«ãåŸãããã®ãã®ã®å¹³åååéã¯21.3Ã104ã§
ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã97.7ïœã
çšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãããè€è²ã垯
ã³ãç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯18.7
Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã121.9ïœãã¡ã¿ã¯ãª
ã«é žã¯ãã©ã€ã4.2ïœãåã³ãã«ãšã³300ïœã®æ··å
液ãçªçŽ æ°æµäžæž©åºŠ75âã«å ç±ãæ¹æäžã«ã¢ãŸã
ã¹ã€ãœããããããªã«1.2ïœãæ·»å ãããïŒæé
åŸã«ãã€ããããã³0.2ïœãã¢ãªã«ã¢ãã³2.3ïœã
å ãããæ¹æããªããåå¿æº¶æ¶²ããã€ããéæµã
ãè¿æž©åºŠãããããã®ãŸãŸæŽã«ïŒæéåå¿ãã
ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«æå ¥
ããŠåæ²ç²Ÿè£œãçœè²ã®ç²æ«ãåŸãããã®ãã®ã®å¹³
åååéã¯24.7Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã91.6ïœã
ã¢ãªã«ã¢ãã³ã®ãããã«ã¢ãªã«ã¢ã«ã³ãŒã«2.3ïœ
ãçšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãå ãã«è€è²
ã垯ã³ãç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯
12.8Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ç¡æ°Žã°ã«ã¿ã«é ž28.5ïœãïŒâããããã·ãšãã«
ã¡ã¿ã¯ãªã¬ãŒã32.5ïœãç¡«é ž0.5mlãåã³ãã³ãŒ
ã³50mlã®æ··å溶液ã宀枩ã§æ¹æãããçŽ30ååŸã«
çºç±ãå§ãŸããèªç¶ã«éæµãããªããïŒæéæ¹æ
ãç¶ãããåå¿æ¶²ã¯æ°ŽæŽåŸã也ç¥ãããŠããæžå§
äžã«æº¶åªãé€ãããçæç©ã¯æ®ã©åäžã§ãããå¿
èŠã§ããã°ã·ãªã«ã²ã«ã«ã©ã ã¯ãããã°ã©ãã€ãŒ
ã«ãã€ãŠç²Ÿè£œããŠãããããã®ããã«ããŠåŸãã
ãã¢ãããŒ8.8ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã
123.2ïœãåã³ãã«ãšã³240ïœã®æ··å溶液ãçªçŽ æ°
æµäžæž©åºŠ75âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœãã
ããããªã«1.2ïœãæ·»å ãããïŒæéåŸã«ãã€ã
ãããã³0.2ïœãã©ãŠãªã«ãžã¡ãã«ã¢ãã³0.2ïœã
ã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœãå ãããæ¹æ
ããªãã枩床ã110âè¿ãããçšããã¢ãããŒã«
ç±æ¥ããã«ã«ãã³é žã®70ïŒ ãæ¶è²»ãããè¿åå¿ã
è¡ã€ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«
æå ¥ããŠåæ²ç²Ÿè£œãçœè²ç²æ«ãåŸãããã®ãã®ã®
å¹³åååéã¯28.7Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã92.6ïœã
ã°ãªã³ãžã«ã¡ã¿ã¯ãªã¬ãŒãã®ãããã«ã¢ãªã«ã¢ã
ã³2.1ïœãã©ãŠãªã«ãžã¡ãã«ã¢ãã³ã®ãããã«ç¡«
é ž0.1ïœãçšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãç¡
è²éæãªç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯
25.3Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒã®è£œé 補é äŸïŒã«ãããŠçšããã¢ãªã«ã¢ãã³ã®ããã
ã«ã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœãç¡«é žã®ãã
ãã«ã©ãŠãªã«ãžã¡ãã«ã¢ãã³0.2ïœãçšããŠè£œé
äŸïŒãšåæ§ã®æäœãè¡ãå ãã«è€è²ã垯ã³ãç²èª¿
ç©ãåŸãããã®ãã®ã®å¹³åååéã¯28.0Ã104ã§
ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è11.7ïœãé ¢é žã
ãã«90ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã3.3ïœãåã³
ã¢ã€ãœããŒH360ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ70
âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
ïŒïœãæ·»å ãããïŒæéåŸã«åå¿æ¶²ãçœæ¿ãã¯ã
ã枩床ã¯84âè¿äžæãããïŒæéåŸã«ããã«0.5
ïœã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ããæŽã«
ïŒæéåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéã
ãŠåŸãããçœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ
0.18ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è7.2ïœãé ¢é žã
ãã«60ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã2.4ïœãå
ã³ã¢ã€ãœããŒH240ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ
70âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããª
ã«0.7ïœãæ·»å ããã40ååŸã«åå¿æ¶²ãçœæ¿ãã¯
ãã枩床ã¯90âè¿äžæãããïŒæéåŸæŽã«0.3ïœ
ã®ã¢ãŸãã¹ã€ãœãããªã«ãæ·»å ãæŽã«ïŒæéåå¿
ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸããã
çœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.18ÎŒïœã®ã©
ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹èïŒïœãé ¢é žãã
ã«50ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã1.3ïœåã³ã¢ã€
ãœããŒH200ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ75âã«
å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«0.8
ïœãæ·»å ããã15ååŸã«åå¿æ¶²ãçœæ¿ãã¯ããæž©
床ã¯85âè¿äžæãããïŒæéåŸæŽã«0.4ïœã®ã¢ãŸ
ãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒæéåå¿
ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸããã
çœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.11ÎŒïœã®ã©
ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ æš¹èç²åã®è£œé äŸïŒã«ãããŠçšããã©ãŠãªã¡ã«
ã¿ã¯ãªã¬ãŒãã®éã4.5ïœã«å¢ãããæš¹èç²åã®
補é äŸïŒãšåæ§ã®æäœãè¡ã€ããåŸãããçœè²å
æ£ç©ã¯éåç81ïŒ ãå¹³åç²åŸ0.09ÎŒïœã®ã©ããã¯
ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è9.1ïœãé ¢é žã
ãã«65ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœåã³
ã¢ã€ãœããŒH260ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ
75âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããª
ã«0.7ïœãæ·»å ããã40ååŸã«åå¿æ¶²ãçœæ¿ã®ã¯
ãã枩床ã¯85âè¿äžæãããïŒæéåŸã«æŽã«0.3
ïœã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒ
æéåå¿ããããå·åŽåŸã200ã¡ãã·ãŠåžãéã
ãŠåŸãããçœè²åæ£ç©ã¯éåç82ïŒ ãå¹³åç²åŸ
0.10ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è8.3ïœãé ¢é žã
ãã«75ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒãïŒïœåã³ã¢ã€
ãœããŒG300ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ70â
ã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
0.8ïœãæ·»å ããã20ååŸã«åå¿åŸãçœæ¿ãã¯ã
ã枩床ã¯90âè¿äžæãããïŒæéåŸã«æŽã«0.4ïœ
ã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒæ
éåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸ
ãããçœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.11ÎŒ
ïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è13ïœãé ¢é žãã
ã«65ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã1.0ïœãåã³
ã¢ã€ãœããŒG360ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ
80âã«å ç±ãæ¹æäžã«ãã³ãŸã€ã«ããŒãªããµã€ã
0.5ïœãæ·»å ãããïŒæéåŸã«åå¿æ¶²ãçœæ¿ãã¯
ãã枩床ã¯90âè¿äžæãããïŒæéåŸã«æŽã«0.3
ïœã®ãã³ãŸã€ã«ããŒãªããµã€ããæ·»å ãæŽã«ïŒæ
éåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸ
ãããçœè²åæ£ç©ã¯éåç79ïŒ ãå¹³åç²åŸ0.09ÎŒ
ïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ æš¹èç²åã®è£œé äŸïŒã«ãããŠçšããã¹ãã¢ãªã«
ã¡ã¿ã¯ãªã¬ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒ
ã2.5ïœãçšããŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æ
äœãè¡ã€ããåŸãããçœè²åæ£ç©ã¯éåç78ïŒ ã
å¹³åç²åŸ0.08ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è9.8ïœãé ¢é žã
ãã«75ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã2.2ïœåã³ã¢
ã€ãœããŒG225ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ70
âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
0.8ïœãæ·»å ããã30ååŸã«åå¿æ¶²ãçœæ¿ãã¯ã
ã枩床ã¯85âè¿äžæãããïŒæéåŸã«æŽã«0.4ïœ
ã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ããæŽã«ïŒ
æéåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠ
åŸãããçœè²åæ£ç©ã¯éåç87ïŒ ãå¹³åç²åŸ
0.10ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ10ïŒæ¯èŒäŸA1 åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹èïŒïœãé ¢é žãã
ã«50ïœãåã³ã¢ã€ãœããŒH200ïœã®æ··å液ãçšã
ãŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æäœãè¡ã€ããåŸ
ãããçœè²åæ£ã¯éåç89ïŒ ã®ã©ããã¯ã¹ã ãã
ã®å¹³åç²åŸã¯1.04ÎŒïœåã³0.24ÎŒïœã®ïŒã±æã«ãã
ããçžå¯ŸåŒ·åºŠ17ïŒ åã³ïŒïŒ ã®ããŒã¯ãæãããã®
ã§ãã€ãã æš¹èç²åã®è£œé äŸ11ïŒæ¯èŒäŸA2 æš¹èç²åã®è£œé äŸ10ãšåæ§ã®æäœãåã³ç¹°ãè¿
ãããšããåŸãããçœè²åæ£ç©ã¯éåç90ïŒ ã®ã©
ããã¯ã¹ã§å¹³åç²åŸã¯2.00ÎŒïœã1.30ÎŒïœãåã³
0.30ÎŒïœã®ïŒã±æã«ããããçžå¯ŸåŒ·åºŠ17ïŒ ãïŒïŒ ã
åã³13ïŒ ã®ããŒã¯ãæãããã®ã§ãã€ãã æš¹èç²åã®è£œé äŸ12ïŒæ¯èŒäŸB1 åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è13ïœãé ¢é žãã
ã«65ïœãåã³ã¢ã€ãœããŒG360ïœã®æ··å溶液ãçš
ããŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æäœãè¡ã€ãã
åŸãããçœè²åæ£ç©ã¯éåç87ïŒ ã®ã©ããã¯ã¹ã
ããã®å¹³åç²åŸã¯1.52ÎŒïœåã³0.32ÎŒïœã®ïŒã±æã«
ããããçžå¯ŸåŒ·åºŠ20ïŒ åã³ïŒïŒ ã®ããŒã¯ãæãã
ãã®ã§ãã€ãã æš¹èç²åã®è£œé äŸ13ïŒæ¯èŒäŸB2 æš¹èç²åã®è£œé äŸ12ãšåæ§ã®æäœãåã³ç¹°ãè¿
ãããšããåŸãããçœè²åæ£ç©ã¯éåç88ïŒ ã®ã©
ããã¯ã¹ã§å¹³åç²åŸã¯1.20ÎŒïœåã³0.26ÎŒïœã®ïŒã±
æã«ããããçžå¯ŸåŒ·åºŠ10ïŒ åã³25ïŒ ã®ããŒã¯ãæ
ãããã®ã§ãã€ãã å®æœäŸ ïŒ ããªã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã20ïœããã°ãã·ã³
20ïœãåã³ã¢ã€ãœããŒG30ïœãããŒã«ãã«ã«ãã€
ãŠïŒæéåæ£ããã°ãã·ã³ã®åŸ®å°ãªåæ£ç©ãåŸ
ããæš¹èç²åã®è£œé äŸïŒã®æš¹èåæ£ç©40ïœããã°
ãã·ã³åæ£ç©30ïœããããã³é žãžã«ã³ããŠã 0.06
ïœãã¢ã€ãœããŒG2ã«åžéããããšã«ãã液äœ
çŸåå€ãäœè£œããã ïŒæ¯èŒçšçŸåå€ïŒ¡ïŒïŒ¢ïŒ äžèšå®æœäŸã«ãããŠæš¹èåæ£ç©ã以äžã®æš¹èç²
åã«ä»£ããŠæ¯èŒçšã®æ¶²äœçŸåå€ïŒ¡ïŒïŒ¢ã®ïŒçš®ãäœ
補ããã æ¯èŒçšæ¶²äœçŸåå€ïŒ¡ïŒæš¹èç²åã®è£œé äŸ10ã®æš¹è
åæ£ç© æ¯èŒçšæ¶²äœçŸåå€ïŒ¢ïŒæš¹èç²åã®è£œé äŸ12ã®æš¹è
åæ£ç© åŸããã液äœçŸåå€ãå¯å£«å šèªå補çæ©
ELP280ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã®çŸåå€ãšã
ãŠçšããå°å·ãã¹ã¿ãŒçšé»ååçæå ææãšããŠ
ELPãã¹ã¿ãŒïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒãçšã
ãŠé£ç¶é調ãæããéœç»åçš¿ããELPãã¹ã¿ãŒ
ã«ç»åã圢æãããŠãã¹ã¿ãŒãã¬ãŒããåŸããåŸ
ããããã¹ã¿ãŒãã¬ãŒãã®ç»åã¯è¯å¥œã§ãã€ãã
åæ§ã«ELPãã¹ã¿ãŒã2000æåŠçããŠãã®åŸçŸ
åè£ çœ®ãžã®ãããŒã®ä»çæ±ãã®æç¡ã芳å¯ããã
ãã®çµæãæ¬çºæã®æš¹èïŒæš¹èç²åã®è£œé äŸïŒïŒ
ãçšããçŸåå€ã§ã¯å šãæ±ããçããªãã€ããæ¯
èŒçšæ¶²äœçŸåå€ïŒ¡ïŒïŒ¢ã«ïŒçš®ã§ã¯ããŒã©ãŒåšèŸºã
ãã³çŸåé»æ¥µåšèŸºã«ä»çæ±ããèããã€ããåã
æ¬çºæã®çŸåå€ãçšããŠåŸãããããã»ããå°å·
çšãã¹ã¿ãŒãã¬ãŒãã¯æåã«çŸåããã®ã2000æ
çŸååŸã®ãã®ãéåžžã«é®®æãªç»åãæããããã
ã®ãã¹ã¿ãŒãã¬ãŒããåžžæ³ã«ããå°å·ãããšãã
3000æå°å·åŸãé®®æãªå°å·ç©ãåŸãããšãã§ã
ããæŽã«ãã®çŸåå€ãïŒã±æéæŸçœ®ããåŸãäžèš
ãšåæ§ã®åŠçãè¡ã€ããçµæåãšå šãå€ãããªã
ã€ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãããçœè²åæ£æ¶²100
ïœåã³ã¹ãã«ãã³ãã©ãã¯1.5ïœã®æ··åç©ã枩床
100âã«å æž©ããïŒæéå ç±æ¹æããã宀枩ã«å·
åŽåŸ200ã¡ãã·ãŠã®ãã€ãã³åžãéãæ®åããæ
æãé€å»ããããšã§å¹³åç²åŸ0.19ÎŒïœã®é»è²ã®æš¹
èåæ£ç©ãåŸãã äžèšé»è²ã®æš¹èåæ£ç©30ïœããããã³é žãžã«ã³
ããŠã 0.05ïœãã·ãšã«ãŸã«71 ïŒã«åžéããã
ãšã«ãã液äœçŸåå€ãäœè£œããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãçºçããªãã€ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãããçœè²åæ£æ¶²100
ïœåã³ãã¯ããªã¢ãã«ãŒB3ïœã®æ··åç©ã枩床70ã
ã80âã«å æž©ãïŒæéæ¹æããã宀枩ã«å·åŽåŸ
200ã¡ãã·ãŠã®ãã€ãã³åžãéããæ®åããææ
ãé€å»ããŠå¹³åç²åŸ0.12ÎŒïœã®éè²ã®æš¹èåæ£ç©
ãåŸãã äžèšéè²ã®æš¹èåæ£ç©28ïœããããã³é žãžã«ã³
ããŠã 0.05ïœãã¢ã€ãœããŒH1ã«åžéããããš
ã«ãã液äœçŸåå€ãäœæããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãèŠãããªãã€ããåãåŸããããªãã»ã
ãå°å·çšãã¹ã¿ãŒãã¬ãŒãã®ç»è³ªã¯é®®æã§ããã
3000æå°å·åŸãšå°å·ç©ã®ç»è³ªãéåžžã«é®®æã§ãã€
ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãçœè²æš¹èåæ£ç©30
ïœãå®æœäŸïŒã§åŸããã°ãã·ã³åæ£ç©2.5ïœåã³
ãžã€ãœããã¬ã³ãšç¡æ°Žãã¬ã€ã³é žã®å ±éåäœã®å
ãã³ãµãã«ã¢ããåç©0.02ïœãã¢ã€ãœããŒG1
ã«åžéããããšã«ãã液äœçŸåå€ãäœè£œããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãèŠãããªãã€ããååŸããããªãã»ãã
å°å·çšãã¹ã¿ãŒãã¬ãŒãç»è³ªåã³3000æå°å·åŸã®
å°å·ç©ã®ç»è³ªãšãã«é®®æã§ãã€ãã æŽã«ãã®çŸåå€ãïŒã±æéæŸçœ®ããåŸãäžèšãš
å šãåæ§ã®åŠçãè¡ãªã€ãããçµæåãšå šãå€ã
ããªãã€ãã
éšåãâOHã§ããå Žåã«ã¯ã¢ãããŒ(E)ãšããŠ
ã¯ïŒºéšåãâCO2HïŒâCOClïŒâNCOã§ãããã
ãªãã®ãéžæããã°ããããã®ä»ã«ãçš®ã ã®çµã¿
åããããããææ©ååŠã®åéã§ã¯å®¹æã«éžæã§
ããã以äžè¿°ã¹ããããªææãçšããŠæ¬çºæã«çš
ããããäžé£œåçµåãå«ãå¯æº¶æ§å ±éåäœæš¹èã
補é ããã«ã¯æ¬¡ã®ããã«ãããåè¿°ã®æº¶æ¥³ã«ã¢ã
ããŒ(C)ãšã¢ãããŒ(D)ã溶解ãããéåéå§å€ã®å
åšäž50âã200âã§æ°æéå ç±ããã次ã«ã¢ãã
ãŒ(E)åã³å¿ èŠã«ããéåç³»ã§éåžžçšããããå ¬ç¥
ãšéåçŠæ¢å€ãå ããæŽã«åå¿åœ¢æ ã«ãã€ãŠå¿ èŠ
ã§ããã°ã©ãŠãªã«ãžã¡ãã«ã¢ãã³ãªã©ã®è§Šåªãå
ããŠåæ§ã®æž©åºŠã§æ°æéå ç±ããããã®ãšã䜿çš
ããã¢ãããŒ(C)ãšã¢ãããŒ(D)ã®æ¯çãšããŠã¯ã¢ã«
æ¯ã§50ïŒ50ã0.5ïŒ99.5ã奜ãŸããã¯20ïŒ80ã
ïŒïŒ99ãã¢ãããŒ(C)ãšã¢ãããŒ(E)ã®æ¯çãšããŠã¯
ã¢ã«æ¯ã§ïŒïŒïŒãïŒïŒïŒã®ç¯å²ã§ããããšãæãŸ
ãããéåçŠæ¢å€ãçšããå Žåã¯åèšæº¶æ¥³ïŒã
ããã«æç®ããŠ0.01ïœãïŒïœã®éã䜿çšããã以
äžã®ããã«ããŠåŸãããäžé£œåçµåãå«ãå ±éå
äœã®ååéã¯5000ã50äžã§ããã以äžã«ãã®äžé£œ
åçµåãå«ãå ±éåäœã§ããå¯æº¶æ§åæ£å®å®çšæš¹
èã®å ·äœäŸã瀺ããæ¬çºæã¯ãããã«éå®ããã
ãã®ã§ã¯ãªãã 次ã«æš¹èåæ£æ¶²ãåŸãå·¥çšã«ã€ããŠèª¬æããã
åèšã¢ãããŒ(A)ãšããŠã¯åèšæ äœæ¶²ïŒé氎溶楳ïŒ
ã«å¯æº¶ã§ãããéåããããšã«ãã€ãŠäžæº¶åãã
ãã®ãçšãããäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«
é žãã¯ããã³é žãã€ã¿ã³ã³é žããã€ã¬ã³é žçã®äž
飜åã«ã«ãã³é žã®ççŽ æ°ïŒãïŒã®ã¢ã«ãã«ãšã¹ã
ã«ïŒççŽ æ°ïŒãïŒã®èèªæã«ã«ãã³é žã®ããã«ãš
ã¹ãã«ãããã¯ã¢ãªã«ãšã¹ãã«ïŒã¢ã¯ãªã«é žãã¡
ã¿ã¯ãªã«é žãã¯ããã³é žããã¬ã€ã³é žãã€ã¿ã³ã³
é žçã®äžé£œåã«ã«ãã³é žãããã¯ãã®ç¡æ°Žç©ïŒã
ãããã·ãšãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒãïŒïŒ®âããã«ãããªãã³ãã¢ã¯ãªããããª
ã«ãããã«ãšãŒãã«çãçšããããšãã§ããã
åãäžè¬åŒïŒïŒã§ç€ºãããåèšã¢ãããŒ(B)ãšã
ãŠã¯ãäŸãã°ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®
ççŽ æ°ïŒã20ã®ã¢ã«ãã«ãšã¹ãã«ïŒã¢ã«ãã«åºãš
ããŠã¯äŸãã°ãªã¯ãã«åºããã·ã«åºãããã·ã«
åºãããã©ãã·ã«åºããããµãã·ã«åºããªã¯ã¿ã
ã·ã«åºãïŒâãšãã«ããã·ã«åºãããïŒãåã¯ã¢
ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ã±ãã«ãšã¹
ãã«ïŒã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãªã¯ããã«
åºããã»ãã«åºããªã¯ã¿ãã»ãã«åºããªã¬ã€ã«åº
ãããïŒçãçšããããšãã§ããã 以äžã®ãããªã¢ãããŒ(A)ã®ãã¡ã®ïŒçš®é¡ããã
ã¯ïŒçš®é¡ä»¥äžã®æ··åç©ãšãã¢ãããŒ(B)ã®ãã¡ã®ïŒ
çš®é¡ãããã¯ïŒçš®é¡ä»¥äžã®æ··åç©ãšãåèšå·¥çšã«
ãã€ãŠåŸãããäžé£œåçµåãæããå ±éåäœïŒå
解å®å®çšæš¹èïŒã®ãã¡ã®ïŒçš®é¡ãããã¯ïŒçš®é¡ä»¥
äžã®æ··åç©ãåèšé氎溶楳ã«æº¶è§£ãããå¿ èŠã«ã
ãéåç³»ã§éåžžçšããããå ¬ç¥ã®éåéå§å€ã®å
åšäžã50âã200âã§æ°æéå ç±ããã ãã®ãšãåŸæ¥å ¬ç¥ã®åæ£å®å®å€ã䜵ããŠçšãã
ããšãã§ãããå³ã¡é氎溶åªã«å¯æº¶ãªåçš®ã®åæ
åã¯å€©ç¶æš¹èãåç¬ãããã¯ïŒçš®é¡ä»¥äžæ··åããŠ
çšããããšãã§ãããäŸãã°ççŽ æ°ïŒã30ã®ã¢ã«
ãã«éïŒããã²ã³ååãããããã·ã«åºãã¢ãã
åºãã¢ã«ã³ãã·åºçã®çœ®æåºãå«æããŠãããã
ããã¯é žçŽ ååãçªçŽ ååãç¡«é»ååãªã©ã®ãã
ãååã§äž»éã®ççŽ âççŽ ååçµåãä»ãããŠã
ãŠãããïŒãæããã¢ã¯ãªã«é žåã¯ã¡ã¿ã¯ãªã«é ž
ã®ã¢ã«ãã«ãšã¹ãã«ãèèªé žã®ããã«ãšã¹ãã«ã
ãããã¯ããã«ã¢ã«ãã«ãšãŒãã«åã¯ãã¿ãžãš
ã³ãã€ãœãã¬ã³ããžã€ãœããã¬ã³çã®ãªã¬ãã€ã³
çã®åéäœã®éååã¯ïŒçš®é¡ä»¥äžã®çµåãã«ãã
å ±éåäœãæŽã«ã¯äžèšé氎溶åªã«å¯æº¶ãªéåäœã
圢æããåéäœãšãäžèšã®æ§ãªåçš®ã®åéäœïŒçš®
é¡ä»¥äžãšã®å ±éåäœã§ãã€ãŠå ±éåäœãé氎溶åª
ã«å¯æº¶ãªç¯å²ã§äžèšåéäœãå«æãããã®ãäŸã
ã°é ¢é žããã«ïŒã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žåã¯ã¯
ããã³é žçã®ã¡ãã«ããšãã«ãïœâãããã«ãã
ãã¯isoâãããã«ãšã¹ãã«ïŒã¹ãã¬ã³ãããã«
ãã«ãšã³ãαâã¡ãã«ã¹ãã¬ã³ã®åŠãã¹ãã¬ã³èª
å°äœïŒã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žã
ãã¬ã€ã³é žãã€ã¿ã³ã³é žã®åŠãäžé£œåã«ã«ãã³é ž
åã¯ãã®ç¡æ°Žç©ïŒããããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããããããã·ãšãã«ã¢ã¯ãªã¬ãŒãããžãšãã«ã¢
ãããšãã«ã¡ã¿ã¯ãªã¬ãŒããâããã«ãããªã
ã³ãã¢ã¯ãªã«ã¢ãããã¢ã¯ãªããããªã«ãïŒâã¯
ãããšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒïŒâããª
ãã«ãªããšãã«ã¡ã¿ã¯ãªã¬ãŒãã®åŠãããããã·
ã«åºãã¢ããåºãã¢ããåºãã·ã¢ãåºãã¹ã«ãã³
é žåºãã«ã«ããã«åºãããã²ã³ååããããç°ç
ã®å皮極æ§ãå«æããåéäœãªã©ããããããšã
ã§ããããããã¯äžèšã®åææš¹èã®ä»ã«ãã¢ã«ã
ããæš¹èãåçš®ã®èèªé žã§å€æ§ããã¢ã«ãããæš¹
èãã¢ããæ²¹ãå€æ§ããªãŠã¬ã¿ã³æš¹èãªã©ã®å€©ç¶
æš¹èãçšããããšãã§ããã䜿çšããã¢ãããŒ(A)
ã¯åè¿°ã®éãïŒçš®é¡ã§ãïŒçš®é¡ä»¥äžã§ãããŸããª
ãããããã«ããŠããã®ç·éã¯åå¿æº¶åªã§ããå
èšé氎溶åª100éééšã«å¯ŸããŠïŒã80éééšã§ã
ã奜ãŸããã¯10ã50éééšã§ãããã¢ãããŒ(B)ã¯
ãã¯ãïŒçš®é¡ã§ãïŒçš®é¡ä»¥äžã§ãããŸããªããã
ã®ç·éã¯ã¢ãããŒ(A)ã®ç·ééã«å¯ŸããŠ0.1ã50é
éïŒ ã§ããã奜ãŸããã¯0.5ã10ééïŒ ã§ããã
åæ£å®å®çšæš¹èã¯äžèšå šã¢ãããŒ(A)100éééšã«
察ããŠïŒã50éééšã§ãã奜ãŸããã¯ïŒã20éé
éšã§ãããéåéå§å€ãçšããå Žåã¯å šåéäœ
100éééšã«å¯ŸããŠ0.1ãïŒéééšãé©åœã§ããã
以äžã®ããã«ããŠè£œé ãããã©ããã¯ã¹ã¯20âã«
ãããç²åºŠã20cp以äžã§ãéæ°Žåæ£ç³»æš¹èã¯å
äžã§ååæ£ã®ç²åŸååžããã¡ããã€ææã®ç²åŸã«
å¶åŸ¡ããã®ã容æã§ããããããã®åæ£æš¹èã¯é
åžžã«è¯å¥œãªååæ£æ§ãå®å®æ§ãå®çæ§ãæããã
ã®ã§ãããé·æã®ä¿åãå®éã®çŸåæ©ã«ãããç¹°
ãè¿ã䜿çšãè¡ã€ãŠã容åšåã³è£ 眮åéšãžã®æ²
éãåéãä»çæ±ããå šãçããåæŽã«å ç±çã«
ãã€ãŠå®çãè¡ããšåŒ·åºãªè¢«èã圢æããèä¹ å
ã«å¯ãç»åã圢æãããããããé¡èãªæ§èœåäž
ã¯æ¬¡ã®æ°ããªæè¡ã«ããéæããããšæšæž¬ãã
ããåŸæ¥ãéæ°Žåæ£ç³»æš¹èã«ãããŠã¯é·æã®ä¿å
ãç¹°ãè¿ã䜿çšã«ãã€ãŠå¯æº¶æ§åæ£å®å®çšæš¹èã
äžæº¶æ§ã©ããã¯ã¹ç²åããè±é¢ããæ§èœãå£åã
ããšããæ¬ ç¹ãããããã®æ¬ ç¹ãæ¹è¯ãã¹ãç±³åœ
ç¹èš±3990980å·çã«é瀺ãããŠãããããªæ段ã
èæ¡ãããŠããããšã¯åè¿°ããéãã§ããããã
ããªããåèšç±³åœç¹èš±çã«é瀺ãããŠãããããª
æ段ã«ãã€ãŠè£œé ãããç²åã¯ç²åŸååžæ²ç·ã«ã
ããããŒã¯å€ãïŒã€ä»¥äžååšããããããŒã¯ã®å¹
ãåºãã€ãããããªã©ç²åŸãåäžã«å¶åŸ¡ããããš
ãå°é£ã§ããããã€ãŸããããã®çµæã®åçŸæ§ã
ãããªããšããæ¬ ç¹ããã€ããããã«ãã®ãããª
ç²åãé·æã®ä¿åãç¹°ãè¿ã䜿çšã«äŸãããšæ²
éãåéãèµ·ããååæ£ããªããªããåèšç±³åœç¹
èš±ã«é瀺ãããŠãããããªæ段ãçšããªãå Žåã«
æ¯ã¹ãŠå€§ããªæ§èœã®åäžã¯èŠãããªãã€ããåŸã€
ãŠåèšæ段ã«ãã€ãŠãçšããå¯æº¶æ§åæ£å®å®çšæš¹
èã®å šéã®ãã¡äžæº¶æ§ã©ããã¯ã¹ç²åã«äžå¯éç
ã«çµåããŠããéšåã¯å ãã§ããããŸãç²åïŒå
ãããã«çµåããŠããæ°ããã¹ãŠã®äžæº¶æ§ã©ãã
ã¯ã¹ç²åã«ã€ããŠåäžã§ã¯ãªãããªãçå¯ãã®ã
ããã®ã§ãããšèããããã æ¬çºæã«ãããŠã¯åèšç±³åœç¹èš±ã«é瀺ãããŠã
ããããªç³»ã«ãã«éåããŠãå¯æº¶æ§æš¹èãšãªãã
ããããªã¢ãããŒãå ±åãããŠäžæº¶æ§ã©ããã¯ã¹
ç²åã®åœ¢æãè¡ãã®ã§ãå¯æº¶æ§åæ£å®å®çšæš¹èã
ç²åã«ã°ã©ããããéã«è©²ã¢ãããŒãæ°åãªãã
æ°ååãç²åã®éå掻æ§éšãšå¯æº¶æ§åæ£å®å®çšæº¶
æš¹èã®éå掻æ§éšã®éã«ã¯ãã€ãŠãªãã ã¡ããã
ãã®ãšæšæž¬ãããã æ¬çºæã«ãããŠãå¿ èŠãªãçè²å€ã䜿çšããŠã
è¯ãããã®çè²å€ãšããŠã¯ç¹ã«éå®ããããã®ã§
ã¯ãªããåŸæ¥å ¬ç¥ã®åçš®æŽé¡æåã¯ææã䜿çšã
ãããšãã§ããã該çè²å€ã¯åç¬ã§åèšé氎溶åª
äžã«åæ£ä¿é²å€çã䜵çšããŠåæ£ãããŠäœ¿çšããŠ
ãããããçè²å€è¡šé¢ã«ããªããŒãååŠçã«çµå
ãããã°ã©ããåç²åïŒäŸãã°ã¯ã©ããã«ãŒã
ã³ïŒäžè±ã¬ã¹ååŠè£œåååïŒã«ããŠäœ¿çšããŠãã
ããåãäžèšããæš¹èäžã«çè²å€ãå«æãããŠçš
ããŠãããã該åæ£æš¹èãçè²ããæ¹æ³ãšããŠäŸ
ãã°ãç¹éæ48â75242åå ¬å ±çã§å ¬ç¥ã®æ¹æ³ã§
ããåæ£æ©ïŒãã€ã³ãã·ãšãŒã«ãŒãã³ãã€ãã
ã«ãæ¯åãã«ãããŒã«ãã«ãªã©ïŒãçšããŠç©çç
ã«æš¹èäžã«åæ£ããæ¹æ³ãããã䜿çšããé¡æã
ææã¯éåžžã«å€ãç¥ãããŠãããäŸãã°ç£æ§é žå
ééç²ãã«ãŒãã³ãã©ãã¯ããã°ãã·ã³ãã¢ã«ã«
ãªãã«ãŒããã³ã¶ã€ãšããŒãããã¯ãªãã³ã¬ã
ãããã¿ãã·ã¢ãã³ãã«ãŒããã¿ãã·ã¢ãã³ãã©
ãã¯ããã³ãžã³ã€ãšããŒçãæããããã ä»ã®çè²ã®æ¹æ³ãšããŠãç¹éæ57â48738å·å ¬
å ±çã«èšèŒã®åŠããåæ£æš¹èç©ã奜ãŸããææã§
å ç±æè²ããæ¹æ³ãããã äŸãã°ãã³ã¶ã€ãšããŒãã¯ãªã¹ã¿ã«ãã€ãªã¬ã
ãããã¯ããªã¢ãã«ãŒããã©ã«ã€ãã°ãªãŒã³ãã»
ãªãã³ãã¢ã¹ãã¬ããããã¹ããŒã¹ã€ãšããŒãã
ã¹ããŒã¹ã¬ããããã¹ããŒã¹ãã«ãŒããœã«ãã³ã
ã¬ããçãæããããã æŽã«ä»ã®çè²ã®æ¹æ³ãšããŠãåæ£æš¹èãšææã
ååŠçã«çµåãããæ¹æ³ããããäŸãã°ç¹éæ53
â54029å·å ¬å ±çã§ã¯ãæš¹èãšææãšãåå¿ãã
ãæ¹æ³ãããã¯ç¹å ¬æ44â22955å·å ¬å ±çã§ã¯é
åããããšã§äžæº¶åãåæ£ãåŸãæš¹èã®åéäœã«
è²çŽ ãäºãçµåãããŠããæ¹æ³çã䜿çšããããš
ãã§ããã æ¬çºæã®æ¶²äœçŸåå€ã«ã¯ãè·é»ç¹æ§ã®åŒ·åã§ã
ããã¯ç»åæ§ã®æ¹è¯çã®ããã«ãå¿ èŠã«å¿ããŠ
çš®ã ã®æ·»å å€ãå ããŠãè¯ããäŸãã°ãååŽå
次ããé»ååçã第16å·»ã第ïŒå·ã44é ã«å ·äœç
ã«èšèŒãããŠããã äŸãã°ãžãŒïŒâãšãã«ããã·ã«ã¹ã«ãã³ãã¯é ž
éå±å¡©ããããã³é žéå±å¡©ãé«çŽèèªé žéå±å¡©ã
ã¬ã·ãã³ãããªïŒããã«ãããªãã³ïŒçã®æ·»å å€
ãæããããã æ¬çºæã®æ¶²äœçŸåå€ã®äž»èŠãªåçµæåã®éã«ã€
ããŠèª¬æããã°äžèšã®éãã§ããã æš¹èåã³çè²å€ãäž»æåãšããŠæãäžæº¶æ§ã©ã
ãã¯ã¹ç²åã¯ãæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.5
éééšã50éééšã奜ãŸããã0.5éééšä»¥äžã§
ãããšç»åæ¿åºŠãäžè¶³ãã50éééšä»¥äžã§ãããš
éé¢åéšãžã®ã«ããªãçãæããåæã®åæ£å®å®
å€çã®æ äœæ¶²äœå¯æº¶æ§æš¹èãå¿ èŠã«å¿ããŠäœ¿çšã
ããæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.5éééšã100
éééšçšåºŠå ããããšãã§ãããäžè¿°ã®æ§ãªè·é
調ç¯å€ã¯ãæ äœæ¶²äœ1000éééšã«å¯ŸããŠ0.001ã
1.0éééšã奜ãŸãããæŽã«å¿ èŠã«å¿ããŠå皮添
å å€ãå ããŠãè¯ãããããæ·»å ç©ã®ç·éã¯çŸå
å€ã®é»æ°æµæã«ãã€ãŠãã®äžéãèŠå¶ããããå³
ã¡ãäžæº¶æ§ã©ããã¯ã¹ç²åãé€å»ããç¶æ ã®æ¶²äœ
çŸåå€ã®é»æ°æµæã109Ωã»cm以äžã«ãªããšè¯è³ª
ã®é£ç¶é調åãåŸããé£ããªãã®ã§åæ·»å ç©ã®å
æ·»å éãããã®é床å ã§ã³ã³ãããŒã«ããããšã
å¿ èŠã§ããã ãå®æœäŸã 以äžã«æ¬çºæã®å®æœæ æ§ãäŸç€ºããæ¬çºæã®å
容ããããã«éå®ããããã®ã§ã¯ãªãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã128.7ïœãïŒâãã
ããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒã2.6ïœãåã³ãã«ãš
ã³240ïœã®æ··å溶液ãçªçŽ æ°æµäžæž©åºŠ75âã«å ç±
ããæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«1.3ïœ
ãæ·»å ãããïŒæéåŸã«åå¿å®¹åšãã€ãŒã³âã¹ã¿
ãŒã¯æ°Žåé¢è£ 眮ããšãã€ãããã€ããããã³0.2
ïœãç¡«é ž0.1ïœãã¡ã¿ã¯ãªã«é ž1.7ïœãå ãããæ¹
æããªãã枩床ã110âè¿ãããæ·»å ããã¡ã¿ã¯
ãªã«é žã65ïŒ æ¶è²»ãããè¿åå¿ãè¡ã€ããåå¿
åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«æå ¥ããŠåæ²
粟補ãããé»è²å³ã垯ã³ãç²æ«ãåŸãã åŸãããç©è³ªã®ç²æ«ã®å¹³åååéãé«é液äœã¯
ãããã°ã©ãæ³ã«ãã枬å®ãããš17.8Ã104ã§ã
ã€ãã å¯æº¶æ§åæ£å®å®æš¹èã®è£œé äŸïŒïŒååç©äŸïŒïŒ ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã93.6ïœãã°ãªãžã«ã¡ã¿
ã¯ãªã¬ãŒã4.5ïœãåã³ãã«ãšã³230ïœã®æ··å液ã
çªçŽ æ°æµäžæž©åºŠ85âã«å ç±ããæ¹æäžã«ãã³ãŸã€
ã«ããŒãªããµã€ã1.0ïœãæ·»å ãããïŒæéåŸã«
枩床ã40âè¿äžããã€ããããã³0.2ïœãã©ãŠãª
ã«ãžã¡ãã«ã¢ãã³0.2ïœãã¡ã¿ã¯ãªã«é ž2.8ïœãå
ãããæ¹æããªãã枩床ã115âè¿ãããæ·»å ã
ãã¡ã¿ã¯ãªé žã®55ïŒ ãæ€åºãããªããªãè¿åå¿ã
è¡ã€ããåå¿åŸãåå¿åŸã4000ïœã®ã¡ã¿ããŒã«ã«
æå ¥ããŠåæ²ç²Ÿè£œãè€è²ã®ç²èª¿ç©ãåŸããåèšè£œ
é äŸïŒãšåæ§ã«ããŠæž¬å®ããå¹³åååéã¯15.0Ã
104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã130ïœãã¡ã¿ã¯ãªã«
é ž1.4ïœãåã³ãã«ãšã³240ïœã®æ··å溶液ãçªçŽ æ°
æµäžæž©åºŠ85âã«å ç±ããæ¹æäžã«ãã³ãŸã€ã«ããŒ
ãªãµã€ã1.3ïœãæ·»å ãããïŒæéåŸã«ã枩床ã
40âè¿äžãããã€ããããã³0.2ïœãã©ãŠãªã«ãž
ã¡ãã«ã¢ãã³0.2ïœãã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒã2.0
ïœãå ãããæ¹æããªãã枩床ã115âè¿ããã
çšããã¡ã¿ã¯ãªã«é žã®55ïŒ ãæ€åºãããªããªãè¿
åå¿ãè¡ã€ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ã
ãŒã«ã«æå ¥ããŠåæ²ç²Ÿè£œãããé»è²å³ã垯ã³ãç²
æ«ãåŸãããã®ãã®ã®å¹³åååéã¯21.3Ã104ã§
ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã97.7ïœã
çšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãããè€è²ã垯
ã³ãç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯18.7
Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã121.9ïœãã¡ã¿ã¯ãª
ã«é žã¯ãã©ã€ã4.2ïœãåã³ãã«ãšã³300ïœã®æ··å
液ãçªçŽ æ°æµäžæž©åºŠ75âã«å ç±ãæ¹æäžã«ã¢ãŸã
ã¹ã€ãœããããããªã«1.2ïœãæ·»å ãããïŒæé
åŸã«ãã€ããããã³0.2ïœãã¢ãªã«ã¢ãã³2.3ïœã
å ãããæ¹æããªããåå¿æº¶æ¶²ããã€ããéæµã
ãè¿æž©åºŠãããããã®ãŸãŸæŽã«ïŒæéåå¿ãã
ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«æå ¥
ããŠåæ²ç²Ÿè£œãçœè²ã®ç²æ«ãåŸãããã®ãã®ã®å¹³
åååéã¯24.7Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã91.6ïœã
ã¢ãªã«ã¢ãã³ã®ãããã«ã¢ãªã«ã¢ã«ã³ãŒã«2.3ïœ
ãçšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãå ãã«è€è²
ã垯ã³ãç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯
12.8Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ ç¡æ°Žã°ã«ã¿ã«é ž28.5ïœãïŒâããããã·ãšãã«
ã¡ã¿ã¯ãªã¬ãŒã32.5ïœãç¡«é ž0.5mlãåã³ãã³ãŒ
ã³50mlã®æ··å溶液ã宀枩ã§æ¹æãããçŽ30ååŸã«
çºç±ãå§ãŸããèªç¶ã«éæµãããªããïŒæéæ¹æ
ãç¶ãããåå¿æ¶²ã¯æ°ŽæŽåŸã也ç¥ãããŠããæžå§
äžã«æº¶åªãé€ãããçæç©ã¯æ®ã©åäžã§ãããå¿
èŠã§ããã°ã·ãªã«ã²ã«ã«ã©ã ã¯ãããã°ã©ãã€ãŒ
ã«ãã€ãŠç²Ÿè£œããŠãããããã®ããã«ããŠåŸãã
ãã¢ãããŒ8.8ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã
123.2ïœãåã³ãã«ãšã³240ïœã®æ··å溶液ãçªçŽ æ°
æµäžæž©åºŠ75âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœãã
ããããªã«1.2ïœãæ·»å ãããïŒæéåŸã«ãã€ã
ãããã³0.2ïœãã©ãŠãªã«ãžã¡ãã«ã¢ãã³0.2ïœã
ã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœãå ãããæ¹æ
ããªãã枩床ã110âè¿ãããçšããã¢ãããŒã«
ç±æ¥ããã«ã«ãã³é žã®70ïŒ ãæ¶è²»ãããè¿åå¿ã
è¡ã€ããåå¿åŸãåå¿æ¶²ã4000ïœã®ã¡ã¿ããŒã«ã«
æå ¥ããŠåæ²ç²Ÿè£œãçœè²ç²æ«ãåŸãããã®ãã®ã®
å¹³åååéã¯28.7Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒ 補é äŸïŒã«ãããŠçšããã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬
ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã92.6ïœã
ã°ãªã³ãžã«ã¡ã¿ã¯ãªã¬ãŒãã®ãããã«ã¢ãªã«ã¢ã
ã³2.1ïœãã©ãŠãªã«ãžã¡ãã«ã¢ãã³ã®ãããã«ç¡«
é ž0.1ïœãçšããŠè£œé äŸïŒãšåæ§ã®æäœãè¡ãç¡
è²éæãªç²èª¿ç©ãåŸãããã®ãã®ã®å¹³åååéã¯
25.3Ã104ã§ãã€ãã å¯æº¶æ§åæ£å®å®çšæš¹èã®è£œé äŸïŒïŒååç©äŸ
ïŒïŒã®è£œé 補é äŸïŒã«ãããŠçšããã¢ãªã«ã¢ãã³ã®ããã
ã«ã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœãç¡«é žã®ãã
ãã«ã©ãŠãªã«ãžã¡ãã«ã¢ãã³0.2ïœãçšããŠè£œé
äŸïŒãšåæ§ã®æäœãè¡ãå ãã«è€è²ã垯ã³ãç²èª¿
ç©ãåŸãããã®ãã®ã®å¹³åååéã¯28.0Ã104ã§
ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è11.7ïœãé ¢é žã
ãã«90ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã3.3ïœãåã³
ã¢ã€ãœããŒH360ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ70
âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
ïŒïœãæ·»å ãããïŒæéåŸã«åå¿æ¶²ãçœæ¿ãã¯ã
ã枩床ã¯84âè¿äžæãããïŒæéåŸã«ããã«0.5
ïœã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ããæŽã«
ïŒæéåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéã
ãŠåŸãããçœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ
0.18ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è7.2ïœãé ¢é žã
ãã«60ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã2.4ïœãå
ã³ã¢ã€ãœããŒH240ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ
70âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããª
ã«0.7ïœãæ·»å ããã40ååŸã«åå¿æ¶²ãçœæ¿ãã¯
ãã枩床ã¯90âè¿äžæãããïŒæéåŸæŽã«0.3ïœ
ã®ã¢ãŸãã¹ã€ãœãããªã«ãæ·»å ãæŽã«ïŒæéåå¿
ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸããã
çœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.18ÎŒïœã®ã©
ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹èïŒïœãé ¢é žãã
ã«50ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã1.3ïœåã³ã¢ã€
ãœããŒH200ïœã®æ··å液ãçªçŽ æ°æµäžæž©åºŠ75âã«
å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«0.8
ïœãæ·»å ããã15ååŸã«åå¿æ¶²ãçœæ¿ãã¯ããæž©
床ã¯85âè¿äžæãããïŒæéåŸæŽã«0.4ïœã®ã¢ãŸ
ãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒæéåå¿
ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸããã
çœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.11ÎŒïœã®ã©
ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ æš¹èç²åã®è£œé äŸïŒã«ãããŠçšããã©ãŠãªã¡ã«
ã¿ã¯ãªã¬ãŒãã®éã4.5ïœã«å¢ãããæš¹èç²åã®
補é äŸïŒãšåæ§ã®æäœãè¡ã€ããåŸãããçœè²å
æ£ç©ã¯éåç81ïŒ ãå¹³åç²åŸ0.09ÎŒïœã®ã©ããã¯
ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è9.1ïœãé ¢é žã
ãã«65ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã5.1ïœåã³
ã¢ã€ãœããŒH260ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ
75âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããª
ã«0.7ïœãæ·»å ããã40ååŸã«åå¿æ¶²ãçœæ¿ã®ã¯
ãã枩床ã¯85âè¿äžæãããïŒæéåŸã«æŽã«0.3
ïœã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒ
æéåå¿ããããå·åŽåŸã200ã¡ãã·ãŠåžãéã
ãŠåŸãããçœè²åæ£ç©ã¯éåç82ïŒ ãå¹³åç²åŸ
0.10ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è8.3ïœãé ¢é žã
ãã«75ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒãïŒïœåã³ã¢ã€
ãœããŒG300ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ70â
ã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
0.8ïœãæ·»å ããã20ååŸã«åå¿åŸãçœæ¿ãã¯ã
ã枩床ã¯90âè¿äžæãããïŒæéåŸã«æŽã«0.4ïœ
ã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ãæŽã«ïŒæ
éåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸ
ãããçœè²åæ£ç©ã¯éåç88ïŒ ãå¹³åç²åŸ0.11ÎŒ
ïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è13ïœãé ¢é žãã
ã«65ïœãã¹ãã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒã1.0ïœãåã³
ã¢ã€ãœããŒG360ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ
80âã«å ç±ãæ¹æäžã«ãã³ãŸã€ã«ããŒãªããµã€ã
0.5ïœãæ·»å ãããïŒæéåŸã«åå¿æ¶²ãçœæ¿ãã¯
ãã枩床ã¯90âè¿äžæãããïŒæéåŸã«æŽã«0.3
ïœã®ãã³ãŸã€ã«ããŒãªããµã€ããæ·»å ãæŽã«ïŒæ
éåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠåŸ
ãããçœè²åæ£ç©ã¯éåç79ïŒ ãå¹³åç²åŸ0.09ÎŒ
ïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ æš¹èç²åã®è£œé äŸïŒã«ãããŠçšããã¹ãã¢ãªã«
ã¡ã¿ã¯ãªã¬ãŒãã®ãããã«ã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒ
ã2.5ïœãçšããŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æ
äœãè¡ã€ããåŸãããçœè²åæ£ç©ã¯éåç78ïŒ ã
å¹³åç²åŸ0.08ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ ïŒ åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è9.8ïœãé ¢é žã
ãã«75ïœãã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã2.2ïœåã³ã¢
ã€ãœããŒG225ïœã®æ··å液ãçªçŽ æ°æµäžã«æž©åºŠ70
âã«å ç±ãæ¹æäžã«ã¢ãŸãã¹ã€ãœããããããªã«
0.8ïœãæ·»å ããã30ååŸã«åå¿æ¶²ãçœæ¿ãã¯ã
ã枩床ã¯85âè¿äžæãããïŒæéåŸã«æŽã«0.4ïœ
ã®ã¢ãŸãã¹ã€ãœããããããªã«ãæ·»å ããæŽã«ïŒ
æéåå¿ããããå·åŽåŸ200ã¡ãã·ãŠåžãéããŠ
åŸãããçœè²åæ£ç©ã¯éåç87ïŒ ãå¹³åç²åŸ
0.10ÎŒïœã®ã©ããã¯ã¹ã§ãã€ãã æš¹èç²åã®è£œé äŸ10ïŒæ¯èŒäŸA1 åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹èïŒïœãé ¢é žãã
ã«50ïœãåã³ã¢ã€ãœããŒH200ïœã®æ··å液ãçšã
ãŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æäœãè¡ã€ããåŸ
ãããçœè²åæ£ã¯éåç89ïŒ ã®ã©ããã¯ã¹ã ãã
ã®å¹³åç²åŸã¯1.04ÎŒïœåã³0.24ÎŒïœã®ïŒã±æã«ãã
ããçžå¯ŸåŒ·åºŠ17ïŒ åã³ïŒïŒ ã®ããŒã¯ãæãããã®
ã§ãã€ãã æš¹èç²åã®è£œé äŸ11ïŒæ¯èŒäŸA2 æš¹èç²åã®è£œé äŸ10ãšåæ§ã®æäœãåã³ç¹°ãè¿
ãããšããåŸãããçœè²åæ£ç©ã¯éåç90ïŒ ã®ã©
ããã¯ã¹ã§å¹³åç²åŸã¯2.00ÎŒïœã1.30ÎŒïœãåã³
0.30ÎŒïœã®ïŒã±æã«ããããçžå¯ŸåŒ·åºŠ17ïŒ ãïŒïŒ ã
åã³13ïŒ ã®ããŒã¯ãæãããã®ã§ãã€ãã æš¹èç²åã®è£œé äŸ12ïŒæ¯èŒäŸB1 åèšæš¹èã®è£œé äŸïŒã§åŸãæš¹è13ïœãé ¢é žãã
ã«65ïœãåã³ã¢ã€ãœããŒG360ïœã®æ··å溶液ãçš
ããŠæš¹èç²åã®è£œé äŸïŒãšåæ§ã®æäœãè¡ã€ãã
åŸãããçœè²åæ£ç©ã¯éåç87ïŒ ã®ã©ããã¯ã¹ã
ããã®å¹³åç²åŸã¯1.52ÎŒïœåã³0.32ÎŒïœã®ïŒã±æã«
ããããçžå¯ŸåŒ·åºŠ20ïŒ åã³ïŒïŒ ã®ããŒã¯ãæãã
ãã®ã§ãã€ãã æš¹èç²åã®è£œé äŸ13ïŒæ¯èŒäŸB2 æš¹èç²åã®è£œé äŸ12ãšåæ§ã®æäœãåã³ç¹°ãè¿
ãããšããåŸãããçœè²åæ£ç©ã¯éåç88ïŒ ã®ã©
ããã¯ã¹ã§å¹³åç²åŸã¯1.20ÎŒïœåã³0.26ÎŒïœã®ïŒã±
æã«ããããçžå¯ŸåŒ·åºŠ10ïŒ åã³25ïŒ ã®ããŒã¯ãæ
ãããã®ã§ãã€ãã å®æœäŸ ïŒ ããªã©ãŠãªã«ã¡ã¿ã¯ãªã¬ãŒã20ïœããã°ãã·ã³
20ïœãåã³ã¢ã€ãœããŒG30ïœãããŒã«ãã«ã«ãã€
ãŠïŒæéåæ£ããã°ãã·ã³ã®åŸ®å°ãªåæ£ç©ãåŸ
ããæš¹èç²åã®è£œé äŸïŒã®æš¹èåæ£ç©40ïœããã°
ãã·ã³åæ£ç©30ïœããããã³é žãžã«ã³ããŠã 0.06
ïœãã¢ã€ãœããŒG2ã«åžéããããšã«ãã液äœ
çŸåå€ãäœè£œããã ïŒæ¯èŒçšçŸåå€ïŒ¡ïŒïŒ¢ïŒ äžèšå®æœäŸã«ãããŠæš¹èåæ£ç©ã以äžã®æš¹èç²
åã«ä»£ããŠæ¯èŒçšã®æ¶²äœçŸåå€ïŒ¡ïŒïŒ¢ã®ïŒçš®ãäœ
補ããã æ¯èŒçšæ¶²äœçŸåå€ïŒ¡ïŒæš¹èç²åã®è£œé äŸ10ã®æš¹è
åæ£ç© æ¯èŒçšæ¶²äœçŸåå€ïŒ¢ïŒæš¹èç²åã®è£œé äŸ12ã®æš¹è
åæ£ç© åŸããã液äœçŸåå€ãå¯å£«å šèªå補çæ©
ELP280ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã®çŸåå€ãšã
ãŠçšããå°å·ãã¹ã¿ãŒçšé»ååçæå ææãšããŠ
ELPãã¹ã¿ãŒïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒãçšã
ãŠé£ç¶é調ãæããéœç»åçš¿ããELPãã¹ã¿ãŒ
ã«ç»åã圢æãããŠãã¹ã¿ãŒãã¬ãŒããåŸããåŸ
ããããã¹ã¿ãŒãã¬ãŒãã®ç»åã¯è¯å¥œã§ãã€ãã
åæ§ã«ELPãã¹ã¿ãŒã2000æåŠçããŠãã®åŸçŸ
åè£ çœ®ãžã®ãããŒã®ä»çæ±ãã®æç¡ã芳å¯ããã
ãã®çµæãæ¬çºæã®æš¹èïŒæš¹èç²åã®è£œé äŸïŒïŒ
ãçšããçŸåå€ã§ã¯å šãæ±ããçããªãã€ããæ¯
èŒçšæ¶²äœçŸåå€ïŒ¡ïŒïŒ¢ã«ïŒçš®ã§ã¯ããŒã©ãŒåšèŸºã
ãã³çŸåé»æ¥µåšèŸºã«ä»çæ±ããèããã€ããåã
æ¬çºæã®çŸåå€ãçšããŠåŸãããããã»ããå°å·
çšãã¹ã¿ãŒãã¬ãŒãã¯æåã«çŸåããã®ã2000æ
çŸååŸã®ãã®ãéåžžã«é®®æãªç»åãæããããã
ã®ãã¹ã¿ãŒãã¬ãŒããåžžæ³ã«ããå°å·ãããšãã
3000æå°å·åŸãé®®æãªå°å·ç©ãåŸãããšãã§ã
ããæŽã«ãã®çŸåå€ãïŒã±æéæŸçœ®ããåŸãäžèš
ãšåæ§ã®åŠçãè¡ã€ããçµæåãšå šãå€ãããªã
ã€ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãããçœè²åæ£æ¶²100
ïœåã³ã¹ãã«ãã³ãã©ãã¯1.5ïœã®æ··åç©ã枩床
100âã«å æž©ããïŒæéå ç±æ¹æããã宀枩ã«å·
åŽåŸ200ã¡ãã·ãŠã®ãã€ãã³åžãéãæ®åããæ
æãé€å»ããããšã§å¹³åç²åŸ0.19ÎŒïœã®é»è²ã®æš¹
èåæ£ç©ãåŸãã äžèšé»è²ã®æš¹èåæ£ç©30ïœããããã³é žãžã«ã³
ããŠã 0.05ïœãã·ãšã«ãŸã«71 ïŒã«åžéããã
ãšã«ãã液äœçŸåå€ãäœè£œããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãçºçããªãã€ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãããçœè²åæ£æ¶²100
ïœåã³ãã¯ããªã¢ãã«ãŒB3ïœã®æ··åç©ã枩床70ã
ã80âã«å æž©ãïŒæéæ¹æããã宀枩ã«å·åŽåŸ
200ã¡ãã·ãŠã®ãã€ãã³åžãéããæ®åããææ
ãé€å»ããŠå¹³åç²åŸ0.12ÎŒïœã®éè²ã®æš¹èåæ£ç©
ãåŸãã äžèšéè²ã®æš¹èåæ£ç©28ïœããããã³é žãžã«ã³
ããŠã 0.05ïœãã¢ã€ãœããŒH1ã«åžéããããš
ã«ãã液äœçŸåå€ãäœæããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãèŠãããªãã€ããåãåŸããããªãã»ã
ãå°å·çšãã¹ã¿ãŒãã¬ãŒãã®ç»è³ªã¯é®®æã§ããã
3000æå°å·åŸãšå°å·ç©ã®ç»è³ªãéåžžã«é®®æã§ãã€
ãã å®æœäŸ ïŒ æš¹èç²åã®è£œé äŸïŒã§åŸãçœè²æš¹èåæ£ç©30
ïœãå®æœäŸïŒã§åŸããã°ãã·ã³åæ£ç©2.5ïœåã³
ãžã€ãœããã¬ã³ãšç¡æ°Žãã¬ã€ã³é žã®å ±éåäœã®å
ãã³ãµãã«ã¢ããåç©0.02ïœãã¢ã€ãœããŒG1
ã«åžéããããšã«ãã液äœçŸåå€ãäœè£œããã ãããå®æœäŸïŒãšåæ§ã®è£ 眮ã«ããçŸåãã
æã2000æçŸååŸã§ãè£ çœ®ã«å¯ŸãããããŒä»çæ±
ãã¯å šãèŠãããªãã€ããååŸããããªãã»ãã
å°å·çšãã¹ã¿ãŒãã¬ãŒãç»è³ªåã³3000æå°å·åŸã®
å°å·ç©ã®ç»è³ªãšãã«é®®æã§ãã€ãã æŽã«ãã®çŸåå€ãïŒã±æéæŸçœ®ããåŸãäžèšãš
å šãåæ§ã®åŠçãè¡ãªã€ãããçµæåãšå šãå€ã
ããªãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ é»æ°æµæ109Ωã»cm以äžãèªé»ç3.5以äžã®æ
äœæ¶²ã«å°ãªããšãæš¹èãåæ£ããŠãªãéé»åççš
液äœçŸåå€ã«ãããŠã該åæ£æš¹èç²åãäžèšã¢ã
ããŒ(A)åã³äžèšã¢ãããŒ(B)ããã¢ãããŒ(A)ã®ç·é
ã«å¯ŸããŠïŒã50ééïŒ ã®å²åã§äžèšåæ£å®å®çšæš¹
èãååšãããŠéåããããšã«ãã€ãŠåŸãããã
ã®ã§ããããšãç¹åŸŽãšããéé»åççšæ¶²äœçŸå
å€ã ã¢ãããŒ(A)ïŒ è©²æ äœæ¶²ã«å¯æº¶ã§ãããéåããããšã«ãã€ãŠ
äžæº¶åããã¢ãã㌠ã¢ãããŒ(B)ïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãã㌠åæ£å®å®çšæš¹èïŒ äžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(C)ãšäžèš
äžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒ(D)ãšãéåããŠ
åŸãããå ±éåäœã«ãæŽã«äžèšäžè¬åŒïŒïŒã§ç€º
ãããã¢ãããŒ(E)ãåå¿ãããŠäžé£œåçµåãå°å ¥
ããããšã«ãã€ãŠåŸããã該æ äœæ¶²ã«å¯èœãªå ±é
åäœ äžè¬åŒïŒïŒ ãåŒã äžè¬åŒïŒïŒ ãåŒã äžè¬åŒãïŒïŒ¹ã¯ââïŒââïŒâCOâïŒâ
CO2âïŒâSO2âïŒâOCOâïŒâCONHâïŒâ
CONR2âïŒR2ã¯çåæ°ŽçŽ åºïŒïŒâNHCOâïŒâ
NHCO2âïŒâNHCONHâïŒâCH2âã®ãããã
ãè¡šããäºãã«åãã§ãã€ãŠãç°ãªã€ãŠãããã
å Žåã«ãã€ãŠã¯ïŒ¹ã¯ååšããªããŠããããR1ã¯
ççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯â
CO2H.ãåŒãâCOClïŒâOHïŒâNH2ïŒâ NHR3ïŒR3ã¯çåæ°ŽçŽ åºïŒãâNCOã®ãããããè¡š
ããã ã¯ååå£ïŒ¹ãšååå£ïŒºãé£çµããçåæ°ŽçŽ åº
ãè¡šããããããååãä»ããŠããããåå Žåã«
ãã€ãŠã¯ïŒ¬ã¯ååšããªããŠããããa1ïŒa2ïŒa3ïŒ
b1ïŒb2ïŒb3ã¯æ°ŽçŽ ååãçåæ°ŽçŽ åºãã«ã«ããã·
ã«åºãåã¯çåæ°ŽçŽ åºãä»ããã«ã«ããã·ã«åºè¡š
ããäºãã«åãã§ãã€ãŠãç°ãªã€ãŠãããã äžè¬åŒïŒïŒã§ç€ºãããã¢ãããŒçŸ€ããéžã°ã
ãã¢ãããŒ(B)ãšã¢ãããŒ(D)ã¯äºãã«åãã§ãã€ãŠ
ç°ãªã€ãŠãããããŸããäžè¬åŒã§ç€ºãããã¢ã
ããŒçŸ€ããéžã°ããã¢ãããŒ(C)ãšã¢ãããŒ(E)ã¯ç°
ãªã€ããã®ã§ããããã€äž¡è ã®ïŒºéšåãååŠçµå
ãã€ããåŸãããã«éžã°ããã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59186202A JPS6163855A (ja) | 1984-09-05 | 1984-09-05 | éé»åççšæ¶²äœçŸåå€ |
| US06/772,794 US4665002A (en) | 1984-09-05 | 1985-09-05 | Liquid developer for electrostatic photography |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59186202A JPS6163855A (ja) | 1984-09-05 | 1984-09-05 | éé»åççšæ¶²äœçŸåå€ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6163855A JPS6163855A (ja) | 1986-04-02 |
| JPH0417432B2 true JPH0417432B2 (ja) | 1992-03-25 |
Family
ID=16184159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59186202A Granted JPS6163855A (ja) | 1984-09-05 | 1984-09-05 | éé»åççšæ¶²äœçŸåå€ |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4665002A (ja) |
| JP (1) | JPS6163855A (ja) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2614038B2 (ja) * | 1986-09-09 | 1997-05-28 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | éé»åççšæ¶²äœçŸåå€ |
| GB2196139B (en) * | 1986-09-09 | 1990-04-04 | Fuji Photo Film Co Ltd | Liquid developer for electrostatic photography |
| JP2614051B2 (ja) * | 1987-09-07 | 1997-05-28 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | é»ååççšæ¶²äœçŸåå€ã®è£œé æ³ |
| JP2752621B2 (ja) * | 1987-09-09 | 1998-05-18 | æåã·ã£ãã¿ãŒ æ ªåŒäŒç€Ÿ | ã·ã£ãã¿ã®ç®¡çå¶åŸ¡è£ 眮 |
| JPH02103057A (ja) * | 1988-10-12 | 1990-04-16 | Fuji Photo Film Co Ltd | éé»åççšæ¶²äœçŸåå€ |
| JPH0812491B2 (ja) * | 1988-10-27 | 1996-02-07 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | éé»åççšæ¶²äœçŸåå€ |
| JPH087472B2 (ja) * | 1988-10-28 | 1996-01-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | éé»åççšæ¶²äœçŸåå€ |
| US4977055A (en) * | 1988-12-22 | 1990-12-11 | Fuji Photo Film Co., Ltd. | Liquid developer for electrostatic photography |
| EP0376650B1 (en) * | 1988-12-27 | 1996-01-03 | Fuji Photo Film Co., Ltd. | Liquid developer for electrostatic photography |
| US5166028A (en) * | 1989-01-31 | 1992-11-24 | Xerox Corporation | Processes for the preparation of styrene butadiene resins |
| DE69024520T2 (de) * | 1989-04-12 | 1996-06-13 | Fuji Photo Film Co Ltd | FlÃŒssiger Entwickler fÃŒr elektrostatische Photographie |
| US5112718A (en) * | 1989-06-12 | 1992-05-12 | Fuji Photo Film Co., Ltd. | Liquid developer for electrostatic photography |
| US5106716A (en) * | 1989-06-14 | 1992-04-21 | Fuji Photo Film Co., Ltd. | Liquid developer for electrostatic photography |
| US5066559A (en) * | 1990-01-22 | 1991-11-19 | Minnesota Mining And Manufacturing Company | Liquid electrophotographic toner |
| US5114822A (en) * | 1990-01-31 | 1992-05-19 | Fuji Photo Film Co., Ltd. | Liquid developer for electrostatic photography |
| US5283179A (en) * | 1990-09-10 | 1994-02-01 | Promega Corporation | Luciferase assay method |
| US5089362A (en) * | 1991-02-01 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Metallic toner fluid composition |
| JP4087444B2 (ja) * | 1995-09-29 | 2008-05-21 | ã¹ãªãŒãšã ã«ã³ãã㌠| å¶åŸ¡ãããçµæ¶æ§ãªã«ã¬ããŸã«ã䜿çšãã液äœã€ã³ã¯ |
| US6103781A (en) * | 1996-09-26 | 2000-08-15 | 3M Innovative Properties Company | Liquid inks using a controlled crystallinity organosol |
| US6174936B1 (en) * | 1997-05-28 | 2001-01-16 | Fuji Photo Film Co., Ltd. | Oil-based ink for preparation of printing plate by ink jet process and method for preparation of printing plate ink jet process |
| US6133341A (en) * | 1997-12-18 | 2000-10-17 | Fuji Photo Film Co., Ltd. | Oil-based ink for preparation of printing plate by ink jet process and method for preparation of printing plate using the same |
| KR101032275B1 (ko) * | 2007-11-08 | 2011-05-06 | 죌ìíì¬ ìì§íí | ì°©ì ë¶ì°ì¡, ê°êŽì± ìì§ì¡°ì±ë¬Œ ë° ëžë맀ížëŠì€ |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5277731A (en) * | 1975-12-24 | 1977-06-30 | Ricoh Co Ltd | Liquid developer for electrostatic photography |
| JPS5535321A (en) * | 1978-09-04 | 1980-03-12 | Ricoh Co Ltd | Liquid developer for electrostatic photography |
| JPS5571713A (en) * | 1978-11-22 | 1980-05-30 | Ricoh Co Ltd | Preparation of nonaqueous resin dispersion |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3554946A (en) * | 1966-11-21 | 1971-01-12 | Ricoh Kk | Liquid developers for electrophotography containing a pigment coated with a copolymer |
| US3623986A (en) * | 1967-08-04 | 1971-11-30 | Ricoh Kk | Liquid developer for use in electrophotography |
| US3753760A (en) * | 1970-01-30 | 1973-08-21 | Hunt P | Liquid electrostatic development using an amphipathic molecule |
| JPS515945B2 (ja) * | 1972-06-16 | 1976-02-24 |
-
1984
- 1984-09-05 JP JP59186202A patent/JPS6163855A/ja active Granted
-
1985
- 1985-09-05 US US06/772,794 patent/US4665002A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5277731A (en) * | 1975-12-24 | 1977-06-30 | Ricoh Co Ltd | Liquid developer for electrostatic photography |
| JPS5535321A (en) * | 1978-09-04 | 1980-03-12 | Ricoh Co Ltd | Liquid developer for electrostatic photography |
| JPS5571713A (en) * | 1978-11-22 | 1980-05-30 | Ricoh Co Ltd | Preparation of nonaqueous resin dispersion |
Also Published As
| Publication number | Publication date |
|---|---|
| US4665002A (en) | 1987-05-12 |
| JPS6163855A (ja) | 1986-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0417432B2 (ja) | ||
| EP0155788B1 (en) | Liquid developer for electrostatic photography | |
| US4618557A (en) | Liquid developer for electrostatic photography | |
| JPS62151868A (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH0417430B2 (ja) | ||
| JPH02116859A (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH0812491B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH0812490B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2597196B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2614038B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP4030265B2 (ja) | ãã㌠| |
| JP2597187B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH0431108B2 (ja) | ||
| JP2597195B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH087469B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2597203B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPS616662A (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2652237B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPS61151661A (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2655348B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2597189B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH02103057A (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2597190B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JP2592322B2 (ja) | éé»åççšæ¶²äœçŸåå€ | |
| JPH087470B2 (ja) | éé»åççšæ¶²äœçŸåå€ |