JPH0380199B2 - - Google Patents

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Publication number
JPH0380199B2
JPH0380199B2 JP58224963A JP22496383A JPH0380199B2 JP H0380199 B2 JPH0380199 B2 JP H0380199B2 JP 58224963 A JP58224963 A JP 58224963A JP 22496383 A JP22496383 A JP 22496383A JP H0380199 B2 JPH0380199 B2 JP H0380199B2
Authority
JP
Japan
Prior art keywords
acid
oil
rolling
salts
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP58224963A
Other languages
English (en)
Other versions
JPS60118799A (ja
Inventor
Shigetoshi Ogura
Katsumi Seki
Hiroyuki Takashima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Priority to JP58224963A priority Critical patent/JPS60118799A/ja
Priority to KR1019840007448A priority patent/KR910009187B1/ko
Publication of JPS60118799A publication Critical patent/JPS60118799A/ja
Priority to US06/844,343 priority patent/US4759861A/en
Publication of JPH0380199B2 publication Critical patent/JPH0380199B2/ja
Granted legal-status Critical Current

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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M101/02Petroleum fractions
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Description

【発明の詳細な説明】
本発明は、金属を加工する際の潤滑剤に関する
ものであり、さらに詳しくは鋼材、たとえば鉄鋼
ならびにステンレス網、ケイ素網およびモリブデ
ン網などの特殊網を加工、特に冷間圧延加工する
際に使用する潤滑剤に関するものである。 通常、金属を加工する方法としては、圧延、引
抜き、プレス、切削、絞り、アイヨニングなどが
あり、それぞれの方法に適した潤滑剤が使用され
ている。特に、金属の圧延加工、すなわち金属を
圧延機で圧延して薄い金属板を作るためには熱間
圧延と冷間圧延が行われており、冷間圧延には
種々の潤滑剤が使用されている。また、熱間圧延
においてもアルミニウムおよびその合金などの場
合には潤滑剤が使用されている。金属の冷間圧延
においては、さらに圧延後に加工面の硬化を防ぐ
目的で金属板を焼鈍し、その硬度を下げる作業が
行われることが多い。 このような金属加工、特に金属の冷間圧延にお
いて用いられる潤滑剤に要求される性質は、圧延
性が良好、すなわち油性および油膜強度が大であ
ること、冷却性が良好であること、金属材の仕上
げ面(光択)が良好であること、潤滑剤が安定、
安全で寿命が長いこと、金属材表面に均一によく
付着すること、給油が簡単で経済的であること、
焼鈍後に金属板上にオイルステインと呼ばれる除
去しがたい汚れを発生しないこと、金属材および
圧延機部品にさびを発生させないことなどであ
る。近年冷間圧延機が高速化し、塑性加工におけ
る変形熱および摩擦熱が大きくなつてきたため、
潤滑剤に要求される性質の中で特に冷却性および
熱に対する安全性が重視されるようになつてき
た。 従来、冷間圧延用潤滑剤には低粘度品ほど冷却
性が大きいという理由から低粘度鉱油が使用され
ていたが、低粘度鉱油は引火点も低いにため、高
速圧延時に火災が発生するという危険性がある。
そこで水が火災安全性および冷却性に優れている
という性質を利用して、低粘度鉱油またはパーム
油、牛脂などの油脂類を水に乳化させた鉱油系ま
たは油脂系ソリユーブル油が使用されだしてき
た。たとえば鉱油系ソリユーブル油は低粘度の鉱
油に乳化剤を混合したものを水に加え攪拌、乳化
して作られる。しかしながら鉱油系ソリユーブル
油は潤滑性が乏しく、しかも種々の添加剤、特に
金属系の添加剤が焼鈍工程においてオイルステイ
ンを生ずる場合があり、大きな欠点とされてい
る。一方、油脂系ソリユーブル油も広く使われて
おり、その潤滑性のすぐれた点で注目されている
が、使用時に絶えず加熱攪拌しながら給油しない
と均一なエマルジヨンが得られない欠点がある。
またオイルステイン発生防止のため行なう洗浄に
はアルカリ、溶剤、あるいは展開線状などがある
が、かなりの設備と労力を要するにもかかわらず
十分な洗浄効果をあげるには至つてはいない。 そこで本発明者らは、上記の従来公知の金属加
工用潤滑剤、特に金属冷間圧延用潤滑剤の問題点
を解決するために研究を重ねた結果、本発明を完
成するに至つた。 本発明は、金属加工、特に金属の冷間圧延にお
いて高速圧延時における冷却性および火災防止性
がきわめて良好であり、かつ圧延性、防錆性、乳
化安全性に優れ、しかも焼鈍処理によるオイルス
テインの発生が少なく、圧延後の金属の表面状態
がきわめて良好であるという種々の特性をかね備
えた、金属、特に鉄鋼や特殊鋼などの鋼材の金属
加工用潤滑剤を提供することを目的とする。すな
わち、本発明は、 [](a) 炭素数8〜22の脂肪族モノカルボン酸も
しくはジカルボン酸またはこれらの2〜3量
体からなるポリカルボン酸 (b) 石油スルホン酸 (c) ナフテン酸 の中らか選ばれる酸のアルカリ金属塩、アル
カリ土類金属塩、炭素数1〜24のアミンもし
くはアルカノールアミンとの塩または該アミ
ンもしくはアルカノールアミンとのアミド、
1〜40重量% [] 一般式HO―(CnH2nO―)nH [式中、mは1〜3、nは2〜18の整数をそれ
ぞれ示す]で表わされるアルキレングリコー
ル、0.1〜20重量% [] 水、1〜50重量%および [] 残部の鉱油、合成潤滑油、油脂またはこれ
らの混合物 からなり、かつ系中に[]水が可溶化されてい
ることを特徴とする金属加工用潤滑剤を提供する
ものである。 以下、本発明により金属加工用潤滑剤について
より具体的に説明する。 本発明でいう[]成分は、(a)炭素数8〜22の
脂肪族モノカルボン酸もしくはジカルボン酸また
はこれらの2〜3量体からなるポリカルボン酸、
(b)石油スルホン酸、(c)ナフテン酸の中から選ばれ
る酸のアルカリ金属塩、アルカリ土類金属塩、体
素数1〜24のアミンもしくはアルカノールアミン
との塩または該アミンもしくはアルカノールアミ
ンとのアミドのことである。 ここでいう(a)の体素数8〜22の脂肪族モノカル
ボン酸もしくはジカルボン酸は、直鎖状でも分枝
状でもよく、また飽和カルボン酸でも不飽和カル
ボン酸でもよい。このような脂肪族モノカルボン
酸もしくはジカルボン酸として、具体的にはたと
えばオクタン酸(カプリル酸)、デカン酸(カプ
リン酸)、ドデカン酸(ラウリン酸)、テトラデカ
ン酸(ミリスチン酸)、ヘキサデカン酸(パルミ
チン酸)、オクタデカン酸(ステアリン酸)、エイ
コサン酸(アラキジン酸)、ドコサン酸(ベヘニ
ン酸)、ヘキセン酸、デセン酸、ドデセン酸、テ
トラデセン酸、ヘキサデセン酸、オクタデセン酸
(ペトロセリニン酸、オレイン酸、エライジン酸、
バクセン酸)、エイコセン酸、ドコセン酸(エル
カ酸、ブラシジン酸)、オクタデカトリエニル酸
(リノール酸)、オクタン二酸(スベリン酸)、ノ
ナン二酸(アゼライン酸)、デカン二酸(セバシ
ン酸)、ウンデカン二酸、ドデカン二酸、トリデ
カン二酸(ブラシリン酸)、テトラデカン二酸、
ペンタデカン二酸、ヘキサデカン二酸(タプシン
酸)、ヘプタデカン二酸、オクタデカン二酸、ノ
ナデカン二酸、アイコサン二酸、ドコサン二酸な
どがあげられる。 また、(a)でいうこれらの2〜3量体からなるポ
リカルボン酸とは、体素数8〜22の脂肪族カルボ
ン酸で不飽和結合を1個以上含む酸をたとえば熱
重合などにより2〜3量体に重合させて得られる
タイマー酸やトリマー酸のことを意味している。 また、(b)の石油スルホン酸とは、石油留分の硫
酸精製の際に副生する炭化水素のスルホン酸混合
物のことであり、主成分はアルキルアリールスル
ホン酸である。通常は石油留分、特に白油を硫酸
または溶剤精製してスラツジ分を除き、発煙硫酸
と加温、スルホン化したのち、未反応油、廃酸を
除いて精製することにより得られる。 一方、(c)のナフテン酸とは、石油中に含まれる
ナフテン核を有する飽和カルボン酸類のことであ
る。通常、原油や灯油、軽油などの石油留分を少
量の濃硫酸とふつて塩基性物質を除いたのち油相
から水酸化ナトリウム水溶液などを用いて抽出す
ることにより得られる。 本発明の[]成分は、上記(a)(b)(c)の中から選
ばれる酸のアルカリ金属塩、アルカリ土類金属
塩、炭素数1〜24のアミンもしくはアルカノール
アミンとの塩または該アミンもしくはアルカノー
ルアミンとのアミドから選ばれる一種類以上の化
合物である。 アルカリ金属塩としては、具体的にはリチウム
塩、ナトリウム塩、カリウム塩、ルビジウム塩な
どがあげられ、特にナトリウム塩やカリウム塩が
好ましい。アルカリ土類金属塩としては、具体的
にはベリリウム塩、マグネシウム塩、カルシウム
塩、バリウム塩などがあげられ、特にマグネシウ
ム塩やカルシウム塩が好ましい。また、炭素数1
〜18のアミンもしくはアルカノールアミンとして
は、具体的には例えばメチルアミン、エチルアミ
ン、プロピルアミン、ブチルアミン、ペンチルア
ミン、ヘキシルアミン、ヘプチルアミン、オクチ
ルアミン、ノニルアミン、デシルアミン、ウンデ
シルアミン、ドデシルアミン、トリデシルアミ
ン、テトラデシルアミン、ペンタデシルアミン、
ヘキサデシルアミン、ヘプタデシルアミン、オク
タデシルアミン、シクロペンチルアミン、シクロ
ヘキシルアミン、シクロヘプチルアミン、アニリ
ン、トルイジン、キシリジン、ジメチルアミン、
ジエチルアミン、ジプロピルアミン、ジブチルア
ミン、ジペンチルアミン、ジヘキシルアミン、ジ
ヘプチルアミン、ジオクチルアミン、ジノニルア
ミン、ジシクロペンチルアミン、ジシクロヘキシ
ルアミン、ジシクロヘプチルアミン、ジフエニル
アミン、トリメチルアミン、トリエチルアミン、
トリプロピルアミン、トリブチルアミン、トリペ
ンチルアミン、トリヘキシルアミン、トリシクロ
ペンチルアミン、トリシクロヘキシルアミン、メ
タノールアミン、エタノールアミン、プロパノー
ルアミン、ジメタノールアミン、ジエタノールア
ミン、ジプロパノールアミン、トリメタノールア
ミン、トリエタノールアミン、トリプロパノール
アミン、メチルメタノールアミン、メチルエタノ
ールアミン、エチルメタノールアミン、エチルエ
タノールアミン、プロピルメタノールアミン、プ
ロピルエタノールアミン、シクロヘキシルメタノ
ールアミン、シクロヘキシルエタノールアミン、
メチルジメタノールアミン、エチルジメタノール
アミン、プロピルジメタノールアミン、シクロヘ
キシルジメタノールアミン、メチルジエタノール
アミン、エチルジエタノールアミン、プロピルジ
エタノールアミン、シクロヘキシルジエタノール
アミンなどがあげられる。 []成分としては、上記に記載したものが使
用できるが、その中でも炭素数8〜22の脂肪族モ
ノカルボン酸のアルカノールアミン塩および石油
スルホン酸のナトリウム塩が特に好ましい。 []の配合量は、潤滑剤全量に対して1〜40
重量%、好ましくは5〜30重量%である。[]
成分の配合量がこの範囲に達しない場合には、水
可溶化の温度範囲が狭くなり、また0℃以下で潤
滑剤が凍結しやすくなるため好ましくない。一
方、[]成分の配合量がこの範囲を越える場合
には、配合量に見合うだけの効果が得られず、潤
滑剤のコストが高くなるため好ましくない。 本発明でいう[]成分とは、 一般式HO―(CnH2nO―)nHで表わされるポリアル
キレングリコールである。この式において、mは
1〜3、nは2〜18の整数をそれぞれ示してい
る。したがつて、−CnH2n−で表わされる基とし
ては、具体的にはたとえばエチレン基、プロピレ
ン基、ブチレン基、ペンチレン基、ヘキシレン
基、トリメチレン基、テトラメチレン基、ペンタ
メチレン基、ヘキサメチレン基などのアルキレン
基があげられる。また、一分子中に炭素数の異な
るアルキレン基が存在してもよい。 []成分の配合量は、潤滑剤全量に対して
0.1〜20重量%、好ましくは1〜10重量%である。
[]成分の配合量がこの範囲に達しない場合に
は、水が均一に可溶化せず、また潤滑剤の潤滑性
が低下するため好ましくない。一方、[]成分
の配合量がこの範囲を越える場合には、[]成
分がこの系において均一に溶解しなくなるため好
ましくない。 本発明でいう[]成分は水であり、その配合
量は潤滑剤全量に対して1〜50重量%、好ましく
は10〜40重量%である。特に、その配合量が35重
量%以上の場合には、潤滑剤が難燃性となるため
特に好ましい。[]成分の配合量がこの範囲に
達しない場合には、潤滑剤の冷却性が低下し、圧
延の際に焼付しやすくなるため好ましくない。一
方、[]成分の配合量がこの範囲を越える場合
には、均一に可溶化させることが困難になるため
好ましくない。 本発明でいう[]成分は、鉱油、合成潤滑
油、油脂またはこれらの混合物のことである。鉱
油、合成潤滑油および油脂としては、通常40℃に
おける粘度が1.5〜30cstのものが使用される。 鉱油としては、通常潤滑油留分を任意の精製処
理、たとえば溶剤精製、硫酸処理、水添精製、白
土処理およびこれらの組み合わせなどにかけて得
られる精製鉱油を使用するのが好ましい。 合成潤滑油としては、任意のものが使用できる
が、通常高級アルコール、エステル油、ポリ−α
−オレフイン油、アルキル化芳香族化合物などが
使用できる。より具体的には、たとえばドデシル
アルコール、ラウリルアルコールなどの炭素数8
〜22の脂肪族1価アルコール、メチルラウレート
やブチルステアレートなどの炭素数10〜22の脂肪
族モノカルボン酸と炭素数1〜10の脂肪族1価ア
ルコールとのエステル、ジ−α−エチルヘキシル
セバケートに代表される二塩基酸と1価アルコー
ルとのジエステル、トリメチロールプロパンカプ
リレートに代表される多価アルコールエステル、
炭素数4〜14のα−オレフインの単独重合ないし
は共重合により得られるポリ−α−オレフイン
油、直鎖または分枝のアルキル基で置換されたア
ルキルベンゼンおよびアルキルナフタレンなどが
あげられる。 油脂としては、牛脂、豚脂、羊脂、魚油、鯨
油、肝油、などの動物油、オリーブ油、やし油、
ひまし油、なたね油、パーム油、大豆油、などの
植物油およびこれらの混合物などがあげられる。 本発明の潤滑剤は、前記の[]〜[]成分
を所定量混合することにより得られるが、この際
に必要に応じて油性剤、極圧材、酸化防止剤、殺
菌剤、防腐剤などの公知の潤滑油添加剤を配合す
ることもできる。これら公知の潤滑油添加剤は、
単独でもよく、また数種類組み合わせて配合して
もよい。添加剤の配合量は、任意であるが、通常
潤滑剤全量に対して15重量%以下、好ましくは10
重量%以下である。 本発明の金属加工用潤滑剤は、前記[]〜
[]成分(場合によつては上記の公知の潤滑油
添加剤も含む)を混合し、[]水を可溶化させ
ることにより得られる。なお、本発明でいう“可
溶化”とは、水が油中に完全に溶け込み、外観上
透明な溶液となつている状態を意味しており、水
が単に油中に分散しているだけの外観上不透明な
“乳化”とは異なるものである。水を可溶化させ
る方法は、任意であるが、たとえば[]〜
[]成分を攪拌容器に入れ、通常の攪拌手段に
より攪拌することで容易に可溶化できる。 また、本発明の金属加工用潤滑剤は、金属の冷
間圧延加工だけでなく、熱間圧延加工、引抜き加
工、プレス加工、切削加工、絞り加工、アイヨニ
ング加工などの他の金属加工においても潤滑剤と
して好ましく使用されるものであり、その用途は
金属冷間圧延加工用だけに限定されるものではな
い。 以下、実施例により本発明をさらに具体的に説
明する。ただし、以下の実施例は本発明に何ら制
限を加えるものではない。 実施例 第1表の組成にしたがつて本発明にかかる金属
加工用潤滑剤(本発明品1〜3)を調製した。な
お、比較のため市販の乳化型圧延油の10重量%乳
化液(比較品1)、精製パーム油を水に分散させ
たもの(比較品2)、市販品と類似の鉱油系、圧
延油(比較品3)、本発明において[]成分を
加えないもの(比較品4および5)および[]
成分の代わりに非イオン系の界面活性剤を用いた
もの(比較例6)も第2表の組成にしたがつて調
整した。 次に、本発明品1〜3および比較品について各
種試験を行つた結果を以下に示す。 1 圧延試験 本発明品1〜3および比較品1〜3を使用し
て圧延機による圧延試験を行い、同一圧下率下
での圧延荷重、圧延板表面の光択、圧延板表面
の傷の比較を行つた。なお、板表面の光沢は
SMカラーコンピユーター(スガ試験機(株)製)
で板表面の反射率を測定することにより、また
板表面の傷は目視により観察し、比較判定し
た。 使用圧延機の仕様 ワークロール直径 50mm 圧延速度 40m/min 圧下率 35% 圧延金属材 18−8ステンレス鋼材 板厚0.3mm、板幅50mm 試験結果を第3表に示す。
【表】 鉱油系の圧延油(比較品3)に比べて本発明
品1〜3は、水が可溶化されていることによ
り、板傷が防止され、また圧延荷重が低下して
いることがわかる。これは、ロールバイトへ導
入された水が材料とロールとの接触面を冷却し
て焼付きを防止するためと思われる。 また、通常の乳化型圧延油(比較品1)は、
水による冷却性の面では良好であるが、潤滑に
必要な油分がロールバイトへ十分に行きわたら
ないため逆に板表面の傷が大きくなつている。 一方鉄鋼の冷間圧延油として広く使用されて
いるパーム油は、圧延性(荷重低下)、板傷防
止性能は優れているが、板表面の光択が低くな
るという欠点を有している。 これらに対し、本発明品は、圧延性、板光
沢、板傷防止性のいずれにおいても良好な性能
を示している。 2 可溶化試験 本発明品1〜3および比較品4〜6について
潤滑剤の温度を変化させて水が可溶化できる
(溶液が外観上透明である)温度範囲を調べた。
その結果を第4表に示す。
【表】 水を可溶化させるためには、本発明において
[]成分を用いない場合(比較品4および5)
および[]成分の代わりに非イオン系界面活
性剤を多量に使用した場合(比較品6)にも可
能であるが、可溶化状態にある温度範囲が狭い
という欠点がある。 それに対して本発明品は、0〜80℃以上の広
い温度範囲で可溶化状態を保つことができ、通
常の鉱油系圧延油と同様の取り扱いができる。
【表】
【表】

Claims (1)

  1. 【特許請求の範囲】 1 [](a) 炭素数8〜22脂肪族モノカルボン酸
    もしくはジカルボン酸またはこれらの2〜3
    量体からなるポリカルボン酸 (b) 石油スルホン酸 (c) ナフテン酸 の中から選ばれる酸のアルカリ金属塩、アルカリ
    土類金属塩、炭素数1〜24のアミンもしくはアル
    カノールアミンとの塩または該アミンもしくはア
    ルカノールアミンとのアミド、1〜40重量% [] 一般式HO―(CnH2nO―)nH [式中、mは1〜3、nは2〜18の整数をそれ
    ぞれ示す]で表わされるアルキレングリコー
    ル、0.1〜20重量% [] 水、1〜50重量%および [] 残部の鉱油、合成潤滑油、油脂または これらの混合物 からなり、かつ系中に[]水が可溶化されてい
    ることを特徴とする金属加工用潤滑剤。
JP58224963A 1983-11-29 1983-11-29 金属加工用潤滑剤 Granted JPS60118799A (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP58224963A JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤
KR1019840007448A KR910009187B1 (ko) 1983-11-29 1984-11-28 금속 가공용 윤활제 및 그 제법
US06/844,343 US4759861A (en) 1983-11-29 1986-03-26 Metal working lubricant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58224963A JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤

Publications (2)

Publication Number Publication Date
JPS60118799A JPS60118799A (ja) 1985-06-26
JPH0380199B2 true JPH0380199B2 (ja) 1991-12-24

Family

ID=16821944

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58224963A Granted JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤

Country Status (3)

Country Link
US (1) US4759861A (ja)
JP (1) JPS60118799A (ja)
KR (1) KR910009187B1 (ja)

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Also Published As

Publication number Publication date
KR910009187B1 (ko) 1991-11-04
US4759861A (en) 1988-07-26
JPS60118799A (ja) 1985-06-26
KR850003569A (ko) 1985-06-20

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