JPS60118799A - 金属加工用潤滑剤 - Google Patents

金属加工用潤滑剤

Info

Publication number
JPS60118799A
JPS60118799A JP58224963A JP22496383A JPS60118799A JP S60118799 A JPS60118799 A JP S60118799A JP 58224963 A JP58224963 A JP 58224963A JP 22496383 A JP22496383 A JP 22496383A JP S60118799 A JPS60118799 A JP S60118799A
Authority
JP
Japan
Prior art keywords
acid
oil
water
lubricant
rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58224963A
Other languages
English (en)
Other versions
JPH0380199B2 (ja
Inventor
Shigetoshi Ogura
小倉　茂稔
Katsumi Seki
関　克己
Hiroyuki Takashima
高島　宏之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Priority to JP58224963A priority Critical patent/JPS60118799A/ja
Priority to KR1019840007448A priority patent/KR910009187B1/ko
Publication of JPS60118799A publication Critical patent/JPS60118799A/ja
Priority to US06/844,343 priority patent/US4759861A/en
Publication of JPH0380199B2 publication Critical patent/JPH0380199B2/ja
Granted legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
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    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/04—Fatty oil fractions
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    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
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    • C10M105/06—Well-defined hydrocarbons aromatic
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    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M105/12—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
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    • C10M105/14—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms polyhydroxy
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
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    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
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    • C10M129/26—Carboxylic acids; Salts thereof
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    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/42—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms polycarboxylic
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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 本発明は、金属を加工づる際の潤滑剤に関りるものであ
り、さらに詳（）くは鋼材、たとえば鉄鋼ならびにステ
ンレス綱、ケイ素綱および上リブデン綱などの特殊綱を
加工、特に冷間圧延加工する際に使用する潤滑剤に関す
るものである。
通常、金属を加工する方法としては、圧延、引抜き、プ
レス、切削、絞り、）フイ］ニングなどがあり、それぞ
れの方法に適した沿ワ滑剤が使用されている。特に、金
属の圧延加工、りなわら金属を圧延機で圧延して薄い金
属板を作るためには熱間圧延と冷寒圧延が行われており
、冷寒圧延に【よ種々の潤滑剤が使用されている。また
、熱間圧延においてもアルミニウムおよびその合金など
の場合には潤滑剤が使用されている。金属の冷寒「延に
おいては、さらに圧延後に加工面の硬化を防ぐ目的で金
属板を焼鈍し、その硬度を工げる作業が行われることが
多い。
このような金属加工、特に金属の冷寒圧延にＪ３いて用
いられる潤滑剤に要求される性質は、圧延性が良好、ず
なわち油性および油膜強度が大であること、冷却性が良
好であること、金属材の什上げ而（光沢）が良好である
こと、潤Ｗ１剤が安定、安全′Ｃ寿命が長いこと、金属
材表面に均一ににり付着Ｊること、給油が曲中で経済的
であること、焼鈍後に金属板上にＡイルスティンとげば
れる除去しがたい汚れを発生しないこと、金ｌ１ｊｌ材
および圧延機部品にさびを発生さＵないことなどである
。
近年冷間圧延機が高速化し、塑性加工にお＄ノる変形熱
および摩擦熱が人さくなってきたため、潤滑剤に要求さ
れる性質の中′ｒ：特に冷ＩＪＩ　ｆｌ：　Ｊｊよび熱
に対づる安全性が重視されるようになってさた。
従来、冷寒圧延用潤滑剤には低粘腐品はど玲１４１性が
大きいという］！１１山から低粘度組曲が使用されてい
たが、低粘度鉱油は引火点も低いにため、高速圧延時に
火災が発生するという危険性がある。
そこで水が火災安全性Ｊ３　Ｊ：び冷却１りに優れ（い
るという性質を利用して、低粘度鉱油またはパーム油、
牛脂などの油脂類を水に乳化さＵた鉱油系または油脂系
ソリュープル油が使用されだしてきた。
たとえば鉱油系ソリューブル油は低粘度の鉱油に乳化剤
を混合したものを水に加え撹拌、乳化し−（作られる。
しかしながら鉱油系ツリー１−ゾル油は潤滑性が乏しく
、しかも種々の添加剤、特に金属系の添加剤が焼鈍工程
においてＡイルスティンを生ずる場合があり、大きな欠
点とされている。一方、油脂系ソリューブル油も広く使
われＵＪ３す、その潤滑性のすぐれた点で注目されてい
るが、使用時に絶えず加熱撹拌しながら給油しないと均
一なエマルジョンが得られない欠にべがある。ま〕こＡ
イルスティン発生防止のため行なう洗浄には）？ルカリ
、溶剤、あるいは展開線状などがあるが、かなりの設備
と労力を要するにもかかわらず十分な洗浄効果をあげる
には至ってはいない。
そこで本発明者らは、上記の従来公知の金属加工用潤滑
剤、特に金属冷間圧延用ｆ、］滑剤の問題点を解決づる
ために研究を重ねた結果、本発明を完成するに至った。
本発明は、金属加工、特に金属の冷間圧延において高速
圧延時におＧｅする冷却性および火災防止性がきわめて
良好であり、かつ圧延性、防錆性、乳化安全性に優れ、
しかも焼鈍処理による７１−（ルステインの発生が少な
く、圧延後の金属の表面状態がきわめて良好であるとい
う種−々の１５性をかね備え１こ、金属、狛に鉄鋼や！
１．！ＩＴＡｔ１４などの鋼（４の金属加工用潤滑剤を
提供することを目的とづ゛る。すなわら、本発明は、 ［Ｉ］＜ａ）Ｉａ素数ε３〜２２の１１ｈ肋ｊｌＮ’Ｅ
ノカルボン酸もしくはジカルボン酸Ｊ、人：　４．Ｌこ
れらの２〜３ｍイ本からなるポリカルボン酸 ＜ｂ＞６油スルホン酸 （Ｃ）ナフテン酸 の申らか選ばれる酸のアルカリ金属ｊ！＋　＋アルカリ
土類金１ｉｆｉ塩、炭素数１・〜・２４のアミンもしく
はアルカノールアミン どの塩よｌこは該アミンもしく（ま）′ルアＪノールア
ミンとのアミド、１〜／ｌ　Ｏ　ｔｐ■％ ［ＩＩ］一般式１−１　０→ＣＩＴ　ｌ−１２　１１　
Ｏ→苗−１１［式中、ｍは１〜３、ｎは２〜１８の 整数をそれぞれ示づ」Ｃ表わされる）′ルキレングリコ
ール、０．１〜２０重 量％ ［ｎｌ］水、１〜５０重損％おＪ、び ［ＩＶ］残部の鉱油、合成潤滑油、油脂またはこれらの
混合物 からなり、かつ系中に［Ｉ［ｌ］水がｉｉｊ　′７Ｆｊ
化されていることを１シｆ徴どする金ｈｉ＋加工用１’
ｌ滑剤をｉｉｊ供りるものである。
以下、本発明により金属加工用ｉ１ＶＩ　Ｈ’ｌ削につ
い（より具体的に謬１明Ｊる。
本発明でいう［Ｉ］酸成分、（ａ）炭素数８〜２２の脂
１１／ｊ族モノカルボン酸−ムしくはジカルボン酸また
はこれらの２〜３相体からなるポリカルボン酸、（１１
）石油スルホン酸、（Ｃ）ナフテン酸の中から選ばれる
酸のアルカリ金１ｆｉ　Ｈｙ、アルカリ土類金属塩、体
系数１〜２４のアミンムしくはアルカノ−Ｊレアシンと
の」甚よｌこは該ノ′ミンし１ノく【よアルカノールア
ミンとのアミドのことである。
ここでいう（ａ）の体系数８〜２２の脂肪族モノカルボ
ン酸もしくはジカルボン酸は、直鎖状ぐも分枝状でもよ
く、また飽和カルボン酸でも不飽和カルボン酸でもよい
。このような脂肪族モノカルボン酸もしくはジカルボン
酸としＣ１具体的にはたとえばＡクタン酸（カプリル酸
）、デカン酸（カプリン酸）、ドデカン酸（ラウリン酸
）、デ１〜ラデカン酸（ミリスチン酸）、ヘキリデカン
酸（バルミブーン１ｌｌｌ）、７１クタデカン酸くスデ
アリン酸）、エイコサンＭ（アラギジン酸）、ド］リン
酸（ベヘニン酸）、ヘキヒン酸、デセン酸、ドブピン酸
、テｌ〜ラデセン酸、ヘキザデヒン酸、Ａフタデセン酸
（ぺ１−ロセリニン酸、Ａレイン酸、」二ライシン酸、
バクセン酸）、エイコセン酸、ドニＪレン酸くエルレノ
ｙＦａ、ブラシジン酸）、オクタデカトリエニル酸くリ
ノールｌ１ｕ）、Δクタンニ酸（スペリン酸）、ノブン
ニ酸（アビライン酸）、デカン二酸（セバシン酸）、ウ
ンデカン二酸、ドデカン二酸、１−リデカンニ酸くブラ
シリンＭ）　、’ｊ　ｌ・ラデカンニ酸、ペンタデカン
二酸、ベキ１ノデｊＪン二酸（タブシン酸）、ヘブタデ
カンニ酸、Ａクタデカンニ酸、ノナデカン二酸、アイコ
リン二酸、ド４リンニ酸などがあげられる。
また、（ａ）でいうこれらの２〜３量体からなるポリカ
ルボン酸どは、体系数８〜２２の脂肪族カルボン酸で不
飽和結合を１個以上含む酸をたとえば熱重合などにより
２〜３圀体に東合さｔ！ｃ４すられるダイマー酸や１−
リマー酸のことを魚味しくいる。
また、（ｂ）の石油スルホン酸どは、石油留分の硫ｆｌ
ｉｔ精製の際に副生ずる炭化水素のスルホン６り混合物
のことであり、主成分はアルキルノＩリールスルボン酸
である。通常番よ？：ｉ　１ＩＩＩｆｒ１分、特に白油
を硫酸または溶剤精製してスラッジ分を除き、発煙ｔｉ
ｔ！ｌｌｉ！と加温、スルボン化したのち、未反応油、
廃酸を除いて精製することにより得られる。
一方、（Ｃ）のナフテン酸とは、石油中に含まれるノー
フテン核を有する飽和カルボン酸類のことである。通常
、原油や対油、軽油などの石油留分を少量のｉｌｌ！硫
酸とふって塩基性物質を除いたのノう油相から水酸化す
１〜リウム水溶液などを用いて抽出することにより得ら
れる。
本発明の［Ｉ］酸成分、上記＜ａ　＞　（ｂ　）　（ｃ
　）の中から選ばれる酸のアルカリ金属」ｎ１アルカリ
土類金属塩、炭素数１〜２４のアミンもしくはアルカノ
ールアミン フルカノールアミンどのアミドから選ばれる一種類以上
の化合物である。
アルカリ金属塩どしては、具体的にはリヂウムｊ為、ナ
トリウムＪＲ、カリウム塩、ルビジウム塩などがあげら
れ、特にプ１ーリウム塩やカリウムｊＭが好ましい。ア
ルカリ土類金１７１どしては、具体的にはベリリウム塩
、マグネシウム塩、カルシウム塩、バリウム塩などがあ
げられ、特にマグネシウム塩やカルシウム塩が好ましい
。また、炭素数１〜１８のアミンもしくはアルカノール
アミンどしては、具体的には例えばメチルアミン、■ヂ
ルノノミン、プロピルアミン、ブヂルアミン、ベンプル
アミン、ヘキシルアミン、ヘキシルアミン、Ａクチルア
ミン、ノニルアミン、デシルアミン、ウンデシルアミン
、ドデシルアミン、トリデシルアミン、テトラデシルア
ミン、ペンタデシルアミン、ヘキサデシルアミン、ヘプ
タデシルアミン、Ａフタデシルアミン、シクロペンデル
アミン、シフ［１ヘキシルアミン、シクロヘプヂルＩミ
ン、）７ニリン、１ヘルイジン、キシリジン、ジメヂル
アミン、ジエヂルアミン、ジブ［１ピルアミン、ジーｆ
ブ−ルノ７ミン、ジペンチルアミン、ジヘ４；ジルアミ
ン、ジヘプチルアミン、ジオクヂルアミン、ジノニルノ
７ミン、ジシクロペンチルアミン、ジシクＬ１へ−１−
ジルアミン、ジシクロペンチルアミン、シフ」−ニルア
ミン、トリメヂルノアミン、１−リニ■ーブールアミン
、］〜リブロビルアミン、トリデシルアミン、トリベン
ヂルアミン、トリヘキシルアミン、トリシフ１コベンヂ
ルアミン、トリシクロヘキシルアミン、メタノールアミ
ン、エタノールアミン、プロパツールアミン、ジメタツ
ールアミン、ジェタノールアミン、ジブロバノールアミ
ン、１−ジメタツールアミン、１〜リエタノールアミン
、］・リプｌ」パノールアミン、メチルメタノールアミ
ン、メチル１タノールアミン、■デルメタノールアミン
、エチル１タノールアミン、プロピルメタノールアミン
、プロピルエタノールアミン、シクロへ４：シルメタノ
ールリンフミン、シクロへギシル１タノールアミン、メ
チルメタノールアミン、１デルジメタツールアミン、プ
ロビルジメタノールアミン、シクロへキシルジメタツー
ルアミン、メチルメタノールアミン、ニブルジェタノー
ルアミン、プロピルジェタノールアミン、シクロへキシ
ルジェタノールアミンなどがあげられる。
［ｉ］酸成分しては、上記に記載したものが使用できる
が、その中でも炭素数８〜２２の脂肪族モノカルボン酸
のアルカノールアミン塩および石油スルホン酸のナトリ
ウム塩が特に好ましい。
［Ｉ］の配合量は、潤滑剤全学に対して１〜４０重量％
、好ましくは５〜３０重重％である。
［Ｉ］酸成分配合間がこの範囲に達しない場合には、水
可溶化の温度範囲が狭くなり、また０°０以下で潤滑剤
が凍結しやすくなるため好ましくない。−ｎ、［Ｉ］酸
成分配合間がこの範囲を越える場合には、配合量に見合
うだ（）の効果が１！１られず、潤滑剤のコストが高く
なるため好ましくない。
本発明でいう［Ｉ］酸成分は、 一般式ＨＯ−＋Ｃｎ　ｌ−１２１１Ｏ九−−１１で表わ
されるポリアル４：レングリコールである。この式にお
いて、ｍは１〜３．１１は２〜１８の整数をそれそ゛れ
示している。したがって、−Ｃｎｌ−１２ｎ−ぐ表わさ
れる基としては、具体的にはたとえばエチレン基、プロ
ピレン基、ブヂレン基、ベンヂレン阜、ヘキシレン基、
トリメチレン基、テトラメチレン基、ペンタメチレン基
、ヘキザメチレン基などのアルキレン基があげられる。
また、−分子中に炭素数の異なるアルキレン基が存在し
てもよい。
［１１重成分の配合量は、ＴＩＩ滑剤全量に対し゛ｃｏ
６１〜２０重量％、好ましくは１〜１０ｉｎｆｆ１％で
ある。［１１重成分の配合間がこの範囲に達しない場合
には、水が均一に可溶化せず、また潤滑剤の潤ｎ性が低
下づるため好ましくない。一方、［Ｉ［］成分の配合量
がこの範囲を越える場合には、［Ｉ［］成分がこの系に
おい゛Ｃ均一に溶解しなくなるため好ましくない。
本発明でいう［１１１］成分は水であり、その配合Φは
潤滑剤全量に対して１〜５０重伍％、好ましくは１０〜
４０重艮％である。特に、その配合間が３５重（５）％
以上の場合には、潤滑剤が難燃性となるため特に好まし
い。［Ｉｌ］成分の配合間がこの範囲に達しない場合に
は、潤滑剤の冷７．ＩＩ性が低下し、圧延の際に焼何し
やすくなるため好ましくない。一方、［Ｉ［ｌ］酸成分
配合間がこの範囲を越える場合には、均一にｌ溶化さＵ
ることが困雌になるため好ましくない。
本発明でいう［ＩＶ］成分は、鉱油、合成潤滑油、油脂
またはこれらの混合物のことである。鉱油、合成潤滑油
および油脂としては、通常４０’Ｃにおける粘度が１．
５〜３Ｑｃｓｔのものが使用される。
鉱油どしては、通常潤滑油留分を任意の精製処理、たと
えば溶剤精製、硫酸処理、水添精製、白土処理およびこ
れらの組み合ゎμなどにか【ノ（ｔ！７られる精製鉱油
を使用づるのがりｒましい。
合成潤滑油としては、任意のものが使用できるが、通常
高級アルコール、エステル油、ポリ−α−オレフィン油
、アルキル化芳香族化合物などが使用できる。より具体
的には、たとえばドデシルアルコール、ラウリルアルコ
ールなどの炭素数８〜２２の脂肪族１価アルコール、メ
チルラウレー１−やブヂルスデアレートなどの炭素数１
０〜２２の脂肪族モノカルボン酸と炭素数１〜１ｏの脂
肪１／Ｘ１価アルコールどのエステル、ジーα−−■−
１＝ルヘキシルセバケートに代表される二塩基酸ど１１
ｉ１１＋アルコールとのジエスデル、ｌ−リメヂロール
プ［１パンカブリレートに代表される多ｆｔｈｊノルコ
ール土ステル、炭素数／Ｉ〜１／Ｉのα−Δレフインの
１１１独重合ないしは共重合によりｉｑられるポリ−α
−オレフィン油、直鎖または分校のアルキル塁で置換さ
れたアルキルベンゼンおよびアルキルナフタレンなどが
あげられる。
油脂としては、牛脂、豚脂、羊脂、魚油、鯨油、Ｉ１１
油、などの動物油、オリーブ油、やし油、ひまし油、な
たね油、パーム油、大豆油、などの植物油およびこれら
の混合物などがあげられる。
本発明の潤滑剤は、前記の［１］〜［ＩＶ］成分を所定
量混合することにより得られるが、この際に必要に応じ
て油性剤１極圧祠、酸化防止剤、殺菌剤、防腐剤などの
公知の潤滑油添加剤を配合りることもできる。これら公
知の潤滑油添加剤は、甲独ぐもよく、また数種類組み合
わＵて配合しくもよい。添加剤の配合量は、任意である
が、通常わ１滑剤全量に対して１５重量％以下、好まし
くは１０重量％以下である。
本発明の金属加工用潤滑剤は、前記［１］〜［ＩＶ］戒
分く場合によつ（は上記の公知のｆｖｌ　１（１油添加
剤も含む）を混合し、［１１１１水を可溶化させること
により得られる。なお、本発明でいうＩ　ｉｉＪ溶化°
′とは、水が油中に完全に溶り込み、外観上透明な溶液
となっている状態を意味しており、水が単に油中に分散
しているだけの外観上不透明な゛乳化″とは異なるもの
である。水を可溶化さける方法は、任意であるが、たと
えば［ｉ］〜「１■」成分を撹拌容器に入れ、通常の撹
拌手段により撹拌することで容易に可溶化できる。
また、本発明の金属加工用潤滑剤は、金属の冷間圧延加
工だけでなく、熱間圧延加工、引抜き加工、プレス加工
、切削ｈロエ、絞り加重「、アイ」ニング加工などの他
の金属加工においても潤滑剤として好ましく使用される
ものであり、その用途（よ金属冷間圧延加工用だ（プに
限定されるしのでは４「い。
以下、実施例ににり本発明をさらに具体的に説明する。
ただし、以下の実施例は本発明に何ら制限を加えるもの
ではない。
実　施　例 第１表の組成にしたがって本発明にかかる金属加工用潤
滑剤（本発明品１〜３）を調整した。なＪ３、比較のた
め市販の乳化型圧延油の１０重ｎ１％乳化液（比較量１
）、精製パー１１油を水に分散させたもの（比較量２）
、市販品と類似の鉱油系、圧延油（比較量３）、本発明
におい（［ＩＩ］成分を加えないものく比較量４　；Ｊ
３　Ｊ：び５）および［１１成分の代わりに非イオン系
の界面活性剤を用いたものく比較量６）も第２表の組成
にしたがつＣ調整した。
次に、本発明品１〜３　Ｊ３よび比較量について各種試
験を行った結果を以下に示す。
１、圧延試験 本発明品１〜３おＪ、び比較量１〜３を使用し−Ｃ圧延
別による圧延試験を行い、同一圧下率ドでの圧延何重、
圧延板表面の光沢、圧延板表面の傷の比較をｉ−１つた
。なお、板表面の光沢は３Ｍカラーコンビ」−ター（ス
ガ試験機（株）製）で板表面の反射率を測定することに
Ｊ、す、また板表面の傷は目視により観察し、比較判定
した。
ワークＩ」−ル的径　５Ｑｍｍ 汀延速ＨＢ　／ｌ□ｍ／ｍ１ｐ Ｉｆ二十率３５〕％ 圧延合属材 １Ｂ−８ステンレス鋼祠 板厚Ｑ、３ｍｍ、板幅５Ｑｍｍ 試験結果を第３表に示す。
エ旦光 鉱油系の圧延油（比較量３）に比べて本発明品１へ３は
、水が可溶化されていることにより、板傷が防止され、
また圧延荷重がイル下していることがわかる。これは、
ロールバイトへ導入された水が初１１とロールどの接触
面を冷却しで焼イ］さを防止するためと思われる。
また、通常の乳化型圧延油く比較量１）は、水による冷
ＭＩ性の面では良好であるが、潤滑に必葭な油分がロー
ルバイトへ十分に（ｊされたらないＩこめ逆に板表面の
傷が大ぎくなっている。
一方鉄鋼の冷間圧延油として広く使用されているパーム
油は、圧延性（荷重低下）、板倶防止ｆ＋−能は優れて
いるが、板表面の光沢がイ１（りなるという欠点を有し
ている。
これらに対し、本発明品は、圧延１１．４に光沢、板間
防止性のいずれにＪ３いても良好な性能を示している。
２、可溶化試験 本発明品１〜３および比較量４〜６につい（潤滑剤の温
度を変化させて水が可溶化でさる（溶液が外観上透明で
ある）懸磨範囲を調べた。その結果を第４表に承り。
担４酉 − １両 水を可溶化さＵるためには、本発明にｊＪいて［１１］
成分を用いない場合（比較量４および５）ａ３Ｊ：び［
Ｉ］酸成分代わりに非イＡン系界面活性剤を多量に使用
した場合（比較量６）にも可Ｆｌｕであるが、可溶化状
態にある湿度範囲が狭いという欠員がある。
それに対して本発明品は、０〜８０℃以上の広い温度範
囲で可溶化状態を保つことがひき、通常の鉱油系圧延油
ど同様の取り扱いがＣさる。
第１頁の続き ■Ｉｎｔ、Ｃ１，’　識別記号　庁内整理番号特許庁長
官　殿 １．事件の表示　特願昭５８−２２　／１９６３号２、
発明の名称　金属加工用潤滑剤 ３、？ｎｉ正をりる者 事イ′ｌとの関係　Ｖ＋　Ｋ’ｌ出願人名　称　（４４
４）日木石浦株式会社 ６、補正により増加づる発明の数　変化１．Ｅ　Ｌ／７
、補正の対象　明細書（発明の詳細な説明）８、？ｉｌ
ｉ正の内容 〔１〕明細川中、２頁１９行＜　２　ＩＱ所）の（゛冷
寒圧延」を「冷間圧延」と補正づる。
（２〕同、３頁２（）、６行おＪ、び２０行の１冷寒圧
延」を「冷間圧延」と補正する。
〔３〕同、４頁１行の「低粘度桐油」を１低粘１α鉱油
」と補正づる。

Claims (1)

  1. 【特許請求の範囲】 １）［Ｉ］　（ａ　）炭素数８〜２２脂肋族モノカルボ
    ン酸もしくはジカルボン酸またはこ れらの２〜３ｊｆｉ（木からなるポリカルボン酸 （ｂ）石油スルホン酸 （ｃ）ナフテン酸 の中から選ばれる酸のアルカリ金属塩、アルカリ土類金
    属塩、炭素数１〜２４ のアミンもしくはアルカノールアミン どの塩または該アミンｂ　Ｌ、　＜　Ｌ；＆アルカノー
    ルアミンどのアミド、１〜４　Ｏｉｎ最％ ［■コ一般式１−１０→Ｃｎ　ｌ−１２１１Ｏ−指「−
    −ｌ−１［式中、ｍは１へ・３、口は２〜１８の整数を
    それぞれ示′９］で表わされるアルキレングリコール、
    ０．１〜２０重 Ｍ％ ［Ｉ［］水、１〜５０　ｍ　ｍ　％　＃　Ｊ：　Ｕ［］
    Ｖ］残部の鉱油、合成潤滑油、油脂または これらの混合物 からなり、かつ系中にＩＩ］水が可溶化されＣいること
    を特徴と覆る金属加工用潤滑剤。
JP58224963A 1983-11-29 1983-11-29 金属加工用潤滑剤 Granted JPS60118799A (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP58224963A JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤
KR1019840007448A KR910009187B1 (ko) 1983-11-29 1984-11-28 금속 가공용 윤활제 및 그 제법
US06/844,343 US4759861A (en) 1983-11-29 1986-03-26 Metal working lubricant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58224963A JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤

Publications (2)

Publication Number Publication Date
JPS60118799A true JPS60118799A (ja) 1985-06-26
JPH0380199B2 JPH0380199B2 (ja) 1991-12-24

Family

ID=16821944

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58224963A Granted JPS60118799A (ja) 1983-11-29 1983-11-29 金属加工用潤滑剤

Country Status (3)

Country Link
US (1) US4759861A (ja)
JP (1) JPS60118799A (ja)
KR (1) KR910009187B1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
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JPS6140400A (ja) * 1984-08-02 1986-02-26 Idemitsu Kosan Co Ltd 水溶性潤滑剤
JPS61141793A (ja) * 1984-12-14 1986-06-28 Idemitsu Kosan Co Ltd 摺動兼金属加工用潤滑組成物を用いた工作機械の潤滑方法
JPS61233091A (ja) * 1985-04-09 1986-10-17 Idemitsu Kosan Co Ltd 潤滑油組成物
JPS6218495A (ja) * 1985-07-16 1987-01-27 Yushiro Do Brazil Ind Chem Ltd 水溶性切削研削油剤
JPS6281494A (ja) * 1985-10-05 1987-04-14 Toyota Motor Corp 摺動面用潤滑剤組成物
JPS62252498A (ja) * 1986-04-24 1987-11-04 Meikoo Kouyu:Goushi 潤滑油兼用水溶性切削油剤
JPH04178500A (ja) * 1990-11-13 1992-06-25 Yushiro Chem Ind Co Ltd 切削性良好な水溶性切削油剤組成物
JP2004018758A (ja) * 2002-06-19 2004-01-22 Yushiro Chem Ind Co Ltd 温間・熱間塑性加工用水溶性潤滑剤組成物
JP2008037894A (ja) * 2006-08-01 2008-02-21 Japan Energy Corp エンジン油組成物

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* Cited by examiner, † Cited by third party
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US5441654A (en) * 1988-07-14 1995-08-15 Diversey Corp., A Corp. Of Canada Composition for inhibiting stress cracks in plastic articles and methods of use therefor
US5009801A (en) * 1988-07-14 1991-04-23 Diversey Corporation Compositions for preventing stress cracks in poly(alkylene terephthalate) articles and methods of use therefor
US4929375A (en) * 1988-07-14 1990-05-29 Diversey Corporation Conveyor lubricant containing alkyl amine coupling agents
US4927550A (en) * 1989-01-27 1990-05-22 Castrol Industrial Inc. Corrosion preventive composition
EP0435444A1 (en) * 1989-11-27 1991-07-03 Mobil Oil Corporation Branched surfactants and cutting oil formulations, using these surfactants, which resist microbial degradation
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JPS6140400A (ja) * 1984-08-02 1986-02-26 Idemitsu Kosan Co Ltd 水溶性潤滑剤
JPS61141793A (ja) * 1984-12-14 1986-06-28 Idemitsu Kosan Co Ltd 摺動兼金属加工用潤滑組成物を用いた工作機械の潤滑方法
JPH04516B2 (ja) * 1984-12-14 1992-01-07 Idemitsu Kosan Co
JPS61233091A (ja) * 1985-04-09 1986-10-17 Idemitsu Kosan Co Ltd 潤滑油組成物
JPH0329277B2 (ja) * 1985-04-09 1991-04-23 Idemitsu Kosan Co
JPS6218495A (ja) * 1985-07-16 1987-01-27 Yushiro Do Brazil Ind Chem Ltd 水溶性切削研削油剤
JPH0369400B2 (ja) * 1985-07-16 1991-10-31 Yushiro Chem Ind
JPS6281494A (ja) * 1985-10-05 1987-04-14 Toyota Motor Corp 摺動面用潤滑剤組成物
JPS62252498A (ja) * 1986-04-24 1987-11-04 Meikoo Kouyu:Goushi 潤滑油兼用水溶性切削油剤
JPH04178500A (ja) * 1990-11-13 1992-06-25 Yushiro Chem Ind Co Ltd 切削性良好な水溶性切削油剤組成物
JP2004018758A (ja) * 2002-06-19 2004-01-22 Yushiro Chem Ind Co Ltd 温間・熱間塑性加工用水溶性潤滑剤組成物
JP2008037894A (ja) * 2006-08-01 2008-02-21 Japan Energy Corp エンジン油組成物

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KR910009187B1 (ko) 1991-11-04
JPH0380199B2 (ja) 1991-12-24
KR850003569A (ko) 1985-06-20
US4759861A (en) 1988-07-26

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