JPH0336209B2 - - Google Patents
Info
- Publication number
- JPH0336209B2 JPH0336209B2 JP58069277A JP6927783A JPH0336209B2 JP H0336209 B2 JPH0336209 B2 JP H0336209B2 JP 58069277 A JP58069277 A JP 58069277A JP 6927783 A JP6927783 A JP 6927783A JP H0336209 B2 JPH0336209 B2 JP H0336209B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- beads
- trimethacrylate
- triacrylate
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011324 bead Substances 0.000 claims description 90
- 239000000203 mixture Substances 0.000 claims description 60
- 239000002904 solvent Substances 0.000 claims description 53
- 239000011230 binding agent Substances 0.000 claims description 41
- 239000000178 monomer Substances 0.000 claims description 39
- 239000008199 coating composition Substances 0.000 claims description 37
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical group ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 229920000642 polymer Polymers 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 18
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 17
- 229920006037 cross link polymer Polymers 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 230000005855 radiation Effects 0.000 claims description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 229920006158 high molecular weight polymer Polymers 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 4
- 229940093475 2-ethoxyethanol Drugs 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 150000003254 radicals Chemical class 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 238000012644 addition polymerization Methods 0.000 claims description 3
- 238000005530 etching Methods 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 238000004299 exfoliation Methods 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims 2
- 229920000620 organic polymer Polymers 0.000 claims 2
- 239000002491 polymer binding agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 description 90
- 239000011248 coating agent Substances 0.000 description 79
- 239000006185 dispersion Substances 0.000 description 42
- 238000001035 drying Methods 0.000 description 22
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 21
- -1 alkylene glycols Chemical class 0.000 description 19
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
- 229910052802 copper Inorganic materials 0.000 description 18
- 239000010949 copper Substances 0.000 description 18
- 229920002120 photoresistant polymer Polymers 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
- 238000011161 development Methods 0.000 description 9
- 239000013557 residual solvent Substances 0.000 description 9
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical group CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000003475 lamination Methods 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- 229920002689 polyvinyl acetate Polymers 0.000 description 5
- 239000011118 polyvinyl acetate Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical group OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000002318 adhesion promoter Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- OPLZHVSHWLZOCP-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(2-methylprop-2-enoyloxy)propoxy]propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)COCC(O)COC(=O)C(C)=C OPLZHVSHWLZOCP-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 2
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- MJVAVZPDRWSRRC-UHFFFAOYSA-N Menadione Chemical compound C1=CC=C2C(=O)C(C)=CC(=O)C2=C1 MJVAVZPDRWSRRC-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 2
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical class C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Chemical class 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical group OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000012719 thermal polymerization Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZCZARILEUZFHJD-UHFFFAOYSA-N (2,2,4-trimethyl-3-prop-2-enoyloxypentyl) prop-2-enoate Chemical compound C=CC(=O)OC(C(C)C)C(C)(C)COC(=O)C=C ZCZARILEUZFHJD-UHFFFAOYSA-N 0.000 description 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- LGPAKRMZNPYPMG-UHFFFAOYSA-N (3-hydroxy-2-prop-2-enoyloxypropyl) prop-2-enoate Chemical compound C=CC(=O)OC(CO)COC(=O)C=C LGPAKRMZNPYPMG-UHFFFAOYSA-N 0.000 description 1
- SFOSXCMICRJFFG-UHFFFAOYSA-N (3e)-3-diazo-4-hydroxy-4h-naphthalene-1-sulfonyl chloride Chemical compound C1=CC=C2C(O)C(=[N+]=[N-])C=C(S(Cl)(=O)=O)C2=C1 SFOSXCMICRJFFG-UHFFFAOYSA-N 0.000 description 1
- OAKFFVBGTSPYEG-UHFFFAOYSA-N (4-prop-2-enoyloxycyclohexyl) prop-2-enoate Chemical compound C=CC(=O)OC1CCC(OC(=O)C=C)CC1 OAKFFVBGTSPYEG-UHFFFAOYSA-N 0.000 description 1
- XHXSXTIIDBZEKB-UHFFFAOYSA-N 1,2,3,4,5,6,7,8-octamethylanthracene-9,10-dione Chemical compound CC1=C(C)C(C)=C2C(=O)C3=C(C)C(C)=C(C)C(C)=C3C(=O)C2=C1C XHXSXTIIDBZEKB-UHFFFAOYSA-N 0.000 description 1
- AZESNEXPGASJRZ-UHFFFAOYSA-N 1,2,3,4-tetrahydrobenzo[a]anthracene-7,12-dione Chemical compound C1CCCC2=CC=C3C(=O)C4=CC=CC=C4C(=O)C3=C21 AZESNEXPGASJRZ-UHFFFAOYSA-N 0.000 description 1
- BHGQSXUNEGPBCB-UHFFFAOYSA-N 1,2,3-tris(prop-1-en-2-yl)benzene Chemical group CC(=C)C1=CC=CC(C(C)=C)=C1C(C)=C BHGQSXUNEGPBCB-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- SYENRPHLJLKTED-UHFFFAOYSA-N 1,3,5-tris(ethenyl)benzene Chemical compound C=CC1=CC(C=C)=CC(C=C)=C1 SYENRPHLJLKTED-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- YNGDWRXWKFWCJY-UHFFFAOYSA-N 1,4-Dihydropyridine Chemical compound C1C=CNC=C1 YNGDWRXWKFWCJY-UHFFFAOYSA-N 0.000 description 1
- ZENYUPUKNXGVDY-UHFFFAOYSA-N 1,4-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=C(C(C)=C)C=C1 ZENYUPUKNXGVDY-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- DVFAVJDEPNXAME-UHFFFAOYSA-N 1,4-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(C)=CC=C2C DVFAVJDEPNXAME-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- LRZPQLZONWIQOJ-UHFFFAOYSA-N 10-(2-methylprop-2-enoyloxy)decyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCCCCCOC(=O)C(C)=C LRZPQLZONWIQOJ-UHFFFAOYSA-N 0.000 description 1
- RHNJVKIVSXGYBD-UHFFFAOYSA-N 10-prop-2-enoyloxydecyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCCCCCOC(=O)C=C RHNJVKIVSXGYBD-UHFFFAOYSA-N 0.000 description 1
- OYKPJMYWPYIXGG-UHFFFAOYSA-N 2,2-dimethylbutane;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(C)(C)C OYKPJMYWPYIXGG-UHFFFAOYSA-N 0.000 description 1
- MIGVPIXONIAZHK-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OCC(C)(C)CO MIGVPIXONIAZHK-UHFFFAOYSA-N 0.000 description 1
- NEBBLNDVSSWJLL-UHFFFAOYSA-N 2,3-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(OC(=O)C(C)=C)COC(=O)C(C)=C NEBBLNDVSSWJLL-UHFFFAOYSA-N 0.000 description 1
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 1
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
- KIJPZYXCIHZVGP-UHFFFAOYSA-N 2,3-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(C)=C2 KIJPZYXCIHZVGP-UHFFFAOYSA-N 0.000 description 1
- LZWVPGJPVCYAOC-UHFFFAOYSA-N 2,3-diphenylanthracene-9,10-dione Chemical compound C=1C=CC=CC=1C=1C=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=1C1=CC=CC=C1 LZWVPGJPVCYAOC-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- OWDBMKZHFCSOOL-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)propoxy]propoxy]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(C)COC(C)COC(=O)C(C)=C OWDBMKZHFCSOOL-UHFFFAOYSA-N 0.000 description 1
- YQZHOBBQNFBTJE-UHFFFAOYSA-N 2-chloro-3-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(Cl)=C2 YQZHOBBQNFBTJE-UHFFFAOYSA-N 0.000 description 1
- FPKCTSIVDAWGFA-UHFFFAOYSA-N 2-chloroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(Cl)=CC=C3C(=O)C2=C1 FPKCTSIVDAWGFA-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Polymers OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- CKKQLOUBFINSIB-UHFFFAOYSA-N 2-hydroxy-1,2,2-triphenylethanone Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C(=O)C1=CC=CC=C1 CKKQLOUBFINSIB-UHFFFAOYSA-N 0.000 description 1
- RZCDMINQJLGWEP-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpent-4-en-1-one Chemical compound C=1C=CC=CC=1C(CC=C)(O)C(=O)C1=CC=CC=C1 RZCDMINQJLGWEP-UHFFFAOYSA-N 0.000 description 1
- DIVXVZXROTWKIH-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(O)(C)C(=O)C1=CC=CC=C1 DIVXVZXROTWKIH-UHFFFAOYSA-N 0.000 description 1
- YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- IXPWKHNDQICVPZ-UHFFFAOYSA-N 2-methylhex-1-en-3-yne Chemical compound CCC#CC(C)=C IXPWKHNDQICVPZ-UHFFFAOYSA-N 0.000 description 1
- NTZCFGZBDDCNHI-UHFFFAOYSA-N 2-phenylanthracene-9,10-dione Chemical compound C=1C=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=1C1=CC=CC=C1 NTZCFGZBDDCNHI-UHFFFAOYSA-N 0.000 description 1
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- DFOKCFWGAKFYBQ-UHFFFAOYSA-N 3,4-di(prop-2-enoyloxy)butyl prop-2-enoate Chemical compound C=CC(=O)OCCC(OC(=O)C=C)COC(=O)C=C DFOKCFWGAKFYBQ-UHFFFAOYSA-N 0.000 description 1
- HTWRFCRQSLVESJ-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCOC(=O)C(C)=C HTWRFCRQSLVESJ-UHFFFAOYSA-N 0.000 description 1
- BVKHQIABCPCWNJ-UHFFFAOYSA-N 3-[bis[5-(diethylamino)-2-methylphenyl]methyl]-n,n-diethyl-4-methylaniline Chemical compound CCN(CC)C1=CC=C(C)C(C(C=2C(=CC=C(C=2)N(CC)CC)C)C=2C(=CC=C(C=2)N(CC)CC)C)=C1 BVKHQIABCPCWNJ-UHFFFAOYSA-N 0.000 description 1
- BJEMXPVDXFSROA-UHFFFAOYSA-N 3-butylbenzene-1,2-diol Chemical group CCCCC1=CC=CC(O)=C1O BJEMXPVDXFSROA-UHFFFAOYSA-N 0.000 description 1
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 1
- QUTBKTUHIQFLPI-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 QUTBKTUHIQFLPI-UHFFFAOYSA-N 0.000 description 1
- IKZMAWGJPJMWJG-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IKZMAWGJPJMWJG-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- XFOHBSLKSOSFBE-UHFFFAOYSA-N 7,8,9,10-tetrahydrotetracene-5,12-dione Chemical compound C1CCCC2=C1C=C1C(=O)C3=CC=CC=C3C(=O)C1=C2 XFOHBSLKSOSFBE-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- 229940076442 9,10-anthraquinone Drugs 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical group OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- JUDXBRVLWDGRBC-UHFFFAOYSA-N [2-(hydroxymethyl)-3-(2-methylprop-2-enoyloxy)-2-(2-methylprop-2-enoyloxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(COC(=O)C(C)=C)COC(=O)C(C)=C JUDXBRVLWDGRBC-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- UOGPKCHLHAWNIY-UHFFFAOYSA-N [2-hydroxy-3-(2-hydroxy-3-prop-2-enoyloxypropoxy)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(O)COCC(O)COC(=O)C=C UOGPKCHLHAWNIY-UHFFFAOYSA-N 0.000 description 1
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 description 1
- RFRIWRLHYDZFRS-UHFFFAOYSA-N [Na].[Na].[Na].P(O)(O)(O)=O Chemical compound [Na].[Na].[Na].P(O)(O)(O)=O RFRIWRLHYDZFRS-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- IYKJEILNJZQJPU-UHFFFAOYSA-N acetic acid;butanedioic acid Chemical compound CC(O)=O.OC(=O)CCC(O)=O IYKJEILNJZQJPU-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- LHMRXAIRPKSGDE-UHFFFAOYSA-N benzo[a]anthracene-7,12-dione Chemical compound C1=CC2=CC=CC=C2C2=C1C(=O)C1=CC=CC=C1C2=O LHMRXAIRPKSGDE-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 229940045803 cuprous chloride Drugs 0.000 description 1
- FSDSKERRNURGGO-UHFFFAOYSA-N cyclohexane-1,3,5-triol Chemical compound OC1CC(O)CC(O)C1 FSDSKERRNURGGO-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 230000037336 dry skin Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- VSQYNPJPULBZKU-UHFFFAOYSA-N mercury xenon Chemical compound [Xe].[Hg] VSQYNPJPULBZKU-UHFFFAOYSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 125000004151 quinonyl group Chemical group 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/115—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having supports or layers with means for obtaining a screen effect or for obtaining better contact in vacuum printing
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Description
æ¬çºæã¯å
æåæ§ã³ãŒãã€ã³ã°çµæç©ã«é¢ã
ããæŽã«è©³ããã¯ãæ¬çºæã¯çµåå€æåã®äžéšã
亀åçµåéåäœããŒãºã§çœ®æããå æåæ§çµæç©
ã«é¢ãããæŽã«æ¬çºæã¯äº€åçµåéåäœããŒãºã
å«æãã也ç¥å æåæ§ãã€ã«ã ã«é¢ããã ãšãã¬ã³æ§äžé£œååéäœååç©ãå éå§å€ãæ
æ©éåäœç¶çµåå€ãªãã³ã«ãã®ä»ã®æ·»å å€ãã補
é ãããå éåæ§çµæç©ã¯ä¹Ÿç¥ãã€ã«ã ã¬ãžã¹ã
ã®è£œé ããã³ãã®ä»ã®äœ¿çšã«å¯ŸããŠæçšã§ããã
ãšãç¥ãããŠãããå éåæ§çµæç©ã®è£œé ã«äœ¿çš
ãããæåãäžè¬ã«éåäœç¶çµåå€ã®ããã®é©åœ
ãªæº¶åªäžã§æ··åãããããŠãã®çµæç©ãäŸãã°æŒ
åºãã³ãŒãã€ã³ã°ãŸãã¯ãã®ä»ã®åœæ¥è ã«ã¯æ¢ç¥
ã®ä¹Ÿç¥ãã€ã«ã 圢ææ段ã«ãã€ãŠã³ãŒãã€ã³ã°ã
ãããŠæº¶åªé€å»ããŠä¹Ÿç¥ãã€ã«ã ãšããã ç¹ã«ä¹Ÿç¥å±€åœ¢æ ã®å éåæ§çµæç©ã¯å°å·ãã¬ãŒ
ãããã³ããã¬ãžã¹ããã€ã«ã ã®ããã«æŒžå¢çã«
äžè¬çãšãªã€ãŠãããäŸãã°ä¹Ÿç¥ãã€ã«ã ããã¬
ãžã¹ãã¯å°å·åè·¯ã®è£œé ã«ãããŠæ¶²äœããã¬ãžã¹
ãã«æ¯ã¹ãŠå€ãã®å©ç¹ãæããŠãããäºå®ã也ç¥
ãã€ã«ã ããã¬ãžã¹ãã¯éåžžã«äžè¬çãšãªã€ãŠã
ãããã®çµæãã©ã³ãã®è£œé èœåã¯éããã«å°é
ãããããããã¬ãžã¹ããã€ã«ã ã®è£œé ã«ãããŠ
çããäžã€ã®åé¡ã¯ãã®ãããªãã€ã«ã ãè¿ éäž
ã€å¹çãã也ç¥ããèœåã§ãããç±é¢šä¹Ÿç¥æ©äžã§
ã®å éåæ§ã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã¯å€ãã®å€æ°äŸã
ã°ã³ãŒãã€ã³ã°ã®åãããã³åºäœåæ¿åºŠã溶åªã®
ç¹æ§ãã³ãŒãã€ã³ã°ãããã¹ãçµæç©ãšã®æº¶åªçž
äºäœçšããã€ã«ã ã®æž©åºŠã空æ°ã®æž©åºŠã空æ°ã®é
床ãæ¹åããã³ä¹±ããçžå¯Ÿæ¹¿åºŠãã®ä»ã«ãã圱é¿
ããããäžè¬ã«ä¹Ÿç¥ã¯ïŒæ®µéã§è¡ããããšèãã
ããšãã§ããã第ïŒæ®µã«ãããŠã¯ã也ç¥é床ã¯çŽ
ç²ãªæº¶åªã®é€å»é床ãšå€§çŽåäžã§ãããå¶éãã¢
ã¯ã¿ãŒã¯æº¶åªååã®ã³ãŒãã€ã³ã°è¡šé¢ïŒãŸãã¯è¡š
é¢äžã®ç©ºæ°ç©ºéïŒããé€å»ããããé床ã§ããã
ã³ãŒãã€ã³ã°ãžã®ç±ãšãã«ã®ãŒäŸçµŠããã³ç©ºæ°é
床ã¯ãã®ç¬¬ïŒä¹Ÿç¥æ®µéã§ã¯éèŠãªãã¢ã¯ã¿ãŒã§ã
ãã第ïŒæ®µã«ãããŠã¯ã³ãŒãã€ã³ã°ã¯ããæ¿åå
ãããã®ã§ä¹Ÿç¥ã¯ããé ããªãããããŠããã¯ã³
ãŒãã€ã³ã°ã®å éšããã³ãŒãã€ã³ã°ã®ç©ºæ°è¡šé¢ãž
ã®æº¶åªååã®æ¡æ£é床ã«ããéå®ãããããã®ç¬¬
ïŒã®ä¹Ÿç¥æ®µéã«ãããŠã¯æž©åºŠããã³ç©ºæ°é床ãé
èŠã§ããã®ã¿ãªãããããã€ãã®å çãã¢ã¯ã¿ãŒ
äŸãã°æº¶åªãšæº¶è³ªãšã®çžäºäœçšãã®ä»ãéèŠãšãª
ãã å éåæ§ã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã«é¢ããå€ãã®å
é¡ã®èŠ³ç¹ããããã®ãããªã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã«
䜿çšããã枩床ã¯ã³ãŒãã€ã³ã°äžã«æ³¡ãçããæž©
床ããäœããã®ã§ããã¹ãã§ããããšãç¥ãããŠ
ããã泡圢æã¯æãŸãããªãããã®çç±ã¯äžåºŠåœ¢
æããããšã泡ã¯åŽ©å£ãããŸãã¯ããããã厩å£
ããå Žåã§ãã³ãŒãã€ã³ã°ã¯ç²çš ããããã®ã§ã
ããããŠå±€äžã«äžåäžãªã¹ãããã圢æãããã
ãã§ããããã®çµæãéåžžãã©ã€ã€ãŒã垯åäžã«
é 眮ãããŠãããå垯åäžã®æž©åºŠã¯ã³ãŒãã€ã³ã°
äžã«æ³¡ãåºçŸãããã枩床ããã以äžã®ããå®å š
ããŒãžã³ã§ä¿æãããŠããã 也ç¥é床ã«é¢ãããã®ä»ã®éå®ã¯éåäœæº¶æ¶²ã®
ãã¹ãã³ãªãŒããŒïŒskin overïŒãã®åŸåã§ããã
ç¹ã«åãã®æ®µéã§ã®æ¥éããã也ç¥ã¯ã³ãŒãã€ã³
ã°è¡šé¢ã«ããªã也ç¥ããã¹ãã³ãçæãããçµæ
ãšãªããããããªãããã®ã¹ãã³ã®äžã«ã¯æº¶åªã«
å¯ãã ã³ãŒãã€ã³ã°ããŸã ååšããŠããããããŠ
ãã®ã¹ãã³ã¯äžåºŠä¹Ÿç¥ãããšãã®äžã«ãã溶åªäž
ã«å®¹æã«ã¯å溶解ããªããããªãã¡ãã®ã¹ãã³ã¯
溶åªèžçºã®éå£ãšããŠåãããã®åé¡ã¯ããé ã
也ç¥äŸãã°ããäœã枩床ã空æ°é床ãããé«æ²žç¹
ã®æº¶åªã®æ·»å ãã®ä»ã«ãã軜æžãããããšãã§ã
ããããããªãããé ã也ç¥ã¯äžå±€é ãå éåæ§
ãã€ã«ã ããã³ãšã¬ã¡ã³ã補é ã®çµæãšãªãã äºæãããããšã«ãå éåæ§ã³ãŒãã€ã³ã°çµæ
ç©ã®æº¶è§£ãããéåäœç¶çµåå€ã®äžéšãã³ãŒãã€
ã³ã°æº¶åªã«äžæº¶æ§ã®äº€åçµåéåäœããŒãºã§çœ®æ
ããããšã«ãã€ãŠã也ç¥å éåæ§ãã€ã«ã ããã³
ãšã¬ã¡ã³ããããå¹çãã補é ãããããšãçºèŠ
ãããããã®ãããªãã€ã«ã ããã³ãšã¬ã¡ã³ãã®
å éåæ§å±€ã¯ããéããã«ããããŠããå°ãã泡
圢æå±éºæ§ããã€ãŠä¹Ÿç¥ããã補é æ©èœã®çŸå®ã®
ãµã€ãºã«å¢å€§ã®ãªãå Žåã§ãããããã«ãã€ãŠç
ç£ãå¢å€§ãããããšãã§ããããã®å éåæ§å±€ã¯
亀åçµåéåäœããŒãºã®ååšã«ããããããæãŸ
ããæ§è³ªãä¿æããŠããããšãèŠåºãããããã®
çç±ã¯ããããå¯æº¶æ§éåäœç¶çµåå€ã®å±æçã«
éåžžã«è¿äŒŒããããã«ãã¶ã€ã³ããããããã§ã
ããããŠããã«ãã€ãŠåŸã ã«ããŠç¡æ©äžæº¶æ§å å¡«
å€ã«é¢é£ããå æ£ä¹±ãæå°åã§ããããã§ããã
äŸãã°åçé床ãé ãžã®æ¥çãéææ§ãŸãã¯è§£å
åããã³å éåæ§å±€ã®å¯ææ§ã¯ä¿æãããŠããã æ¬çºæã«ããã°ãæ¬è³ªçã« (a) æå(a)ã(d)ã®ééåºæºã§ïŒã45ééïŒ ã®ãå°
ããšãïŒåã®æ«ç«¯ãšãã¬ã³åºãæãããããé
é¢ã©ãžã«ã«éå§é£é延é·ä»å éåã«ããé«åå
éåäœã圢æãããå°ããšãïŒçš®ã®éã¬ã¹ç¶ãš
ãã¬ã³æ§äžé£œåååç©ã (b) æå(a)ã(d)ã®ééåºæºã§0.05ã10ééïŒ ã®ã
äžé£œåååç©ã®éåãéå§ããã掻æ§ç·æŸå°ã«
ãã掻æ§åå¯èœãªææ©æŸå°æåæ§ãéé¢ã©ãžã«
ã«çæç³»ã (c) å°ãªããšãïŒçš®ã®ææ©éåäœçµåå€ã (d) 0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ãŒãºã®æ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ããã
ãããŠææ©éåäœç¶çµåå€æåã®ããã®æº¶åªã
ãã³éåäœããŒãºã®è£œé ã«äœ¿çšãããåéäœã®
ããã®æº¶åªäžã§äžæº¶æ§ãã€ééå¡åæ§ã§ããã°
ãã°ããªéèšæœ€æ§ã®äº€åçµåããŒãºãããã³ (d) æå(a)ã(b)ããã³(c)ã«å¯Ÿããå°ããšãïŒçš®ã®
æº¶åª ãããªãããããŠæå(a)ã(d)ã®å šééåºæºã®æå
(c)ããã³(d)ã®çµåãç©ã®åèšééïŒ ã40ã70éé
ïŒ ã§ãããæå(d)ãæå(c)ããã³(d)ã®ééåºæºã§
15ã90ééïŒ ã®éã§ååšããŠããå æåæ§ã³ãŒã
ã€ã³ã°çµæç©ãæäŸãããã æ¬çºæã®ä»ã®æ æ§ã«ããã°ãå°ããšãïŒçš®ã®å
å¯æº¶åå¯èœãªç©è³ª(a)ããã³å°ããšãïŒçš®ã®ææ©é
åäœçµåå€(c)ã(a)ããã³(c)æåã®åèšééåºæºã§
æå(a)ããã³(b)ã¯ãããã50ã95ééïŒ ããã³ïŒ
ã50ééïŒ ã§ååšãããã®åå¿çæç©ãçµæç©ã®
åèšééåºæºã§ïŒã10ééïŒ ã®æŽ»æ§ç·æŸå°ã«ãã
掻æ§åããããæŸå°æåæ§ååç©ãŸãã¯ç³»(b)ãã
ãã³0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ã®ããŒãºã®æ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ãã
ãããŠææ©éåäœçµåå€æåã«å¯Ÿãã溶åªããã³
åèšéåäœããŒãºã®è£œé ã«äœ¿çšãããåéäœã«å¯Ÿ
ãã溶åªäžã§äžæº¶æ§ãã€ééå¡åæ§ã§ãããããŠ
çµæç©ã®å šééåºæºã§20ã65ééïŒ éã«ãããã°
ãã°ããªå®è³ªçã«éèšæœ€æ§ã®äº€åçµåããŒãº(d)ã
ãæ¬è³ªçã«ãªã也ç¥ããããžãšããŠåãçµæç©ã®
å¥é¢æ§çµåå±€ãæããæ¯æäœãå å«ããããžãšã
ãŠåãå æåæ§ãšã¬ã¡ã³ããæäŸãããã æ¬çºæã®å éåæ§ã³ãŒãã€ã³ã°çµæç©ã¯ãå°ã
ãšãïŒåã®æ«ç«¯ãšãã¬ã³åºãå«æããå°ããšãïŒ
çš®ã®éã¬ã¹ç¶ãšãã¬ã³æ§äžé£œåååç©(a)ãææ©æŸ
å°æåæ§éé¢ã©ãžã«ã«çææ§å éå§å€ãŸãã¯å é
å§å€ç³»(b)ãå°ããšãïŒçš®ã®ææ©éåäœç¶çµåå€
(c)ãå éåæ§ã³ãŒãã€ã³ã°äžã«ååšããéåäœç¶
çµåå€æåã®äžéšã眮æããã°ãã°ããªå®è³ªçã«
éèšæœ€æ§ã®äº€åçµåéåäœããŒãº(d)ãããã³åèš
æå(a)ã(b)ããã³(c)ã«å¯Ÿãã溶åª(e)ããæ¬è³ªçã«
ãªã€ãŠããããã®å éåæ§çµæç©äžã«ã¯å°éã®ã
ã®ä»ã®æåäŸãã°ææãç±éåé»å®³å€ãæ¥çä¿é²
å€ãå¯å¡å€ã埮现åå²ç²åãªã©ãååšãããããš
ãã§ããããã®å éåæ§çµæç©ã¯ãããã®åºæ¬ç
æ§è³ªãä¿æããŠãããäŸãã°å±€ã®åœ¢æ ã®å éåæ§
çµæç©ã¯å°ããšã200ïŒ ã奜ãŸããã¯å°ããšã300
ïŒ ã®ç Žæç¹äŒžé·ãæããŠãããããžãšããŠåãã³
ãŒãã€ã³ã°çµæç©äžã«ãããŠã¯ããšãã¬ã³æ§äžé£œ
åååç©(a)ã¯ææ©éåäœç¶çµåå€æå(c)ãšåå¿ã
ãå°ããšãïŒçš®ã®å å¯æº¶åå¯èœãŸãã¯å æžæå¯èœ
ãªç©è³ªã«ãã眮æããããå Žåã«ãããæŸå°æå
æ§ååç©ãŸãã¯ç³»(d)ã¯ã°ãã°ããªå®è³ªçã«éèšæœ€
æ§ã®äº€åçµåéåäœããŒãº(b)ãšäžç·ã«ååšããã
ããšãã§ããããã®ã³ãŒãã€ã³ã°çµæç©ã¯ãŸãæ
å(a)ã(b)ããã³(c)ã«å¯Ÿããå°ããšãïŒçš®ã®æº¶åª(e)
ãå«æããã åèšã®ããã«ãã®å éåæ§çµæç©ã¯å°ããšãïŒ
åã®éåæ§ãšãã¬ã³åºãå«æããå°ããšãïŒçš®ã®
ä»å éåæ§ãšãã¬ã³æ§äžé£œåååç©(a)ãå«æããŠ
ããããã®ãããªååç©ã¯éé¢ã©ãžã«ã«éå§ãã
ãé£é延é·æ§ä»å éåã«ãã€ãŠé«ååéåäœã圢
æãããã奜ãŸããã¯ãã®äžé£œåååç©ïŒãŸãå
éäœååç©ãšããŠãç¥ãããŠããïŒã¯å°ããšãïŒ
åäŸãã°ïŒãïŒåã®æ«ç«¯ãšãã¬ã³æ§äžé£œååºãå«
æããŠããããã®åéäœååç©ã¯éã¬ã¹ç¶ã§ã
ããããªãã¡20âããã³å€§æ°å§ã§ã¯ããã¯100â
以äžã®éåžžã®æ²žç¹ããã³ææ©éåäœç¶çµåå€ã«å¯Ÿ
ããŠå¯å¡åäœçšãæããŠããã åç¬ã§ããŸãã¯ä»ã®åéäœãšã®çµåãã§äœ¿çšã§
ããé©åœãªäžé£œååéäœååç©ãšããŠã¯ã第ïŒçŽ
ããã«ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãã1.5
âãã³ã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿
ã¯ãªã¬ãŒããïŒïŒ®âãžãšãã«ã¢ãããšãã«ã¢ã¯
ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãããšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
1.4âãã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡
ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãããããµã¡ãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ãã³ãžã¡ã¿ã¯ãªã¬ãŒãããã«ã¡ãã¬ã³ã°ãªã³ãŒã«
ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒ
âã·ã¯ããããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³
ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãžã¡ãããŒã«ããã
ã³ãžã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããã°ãªã»
ããŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³
ãžã¡ã¿ã¯ãªã¬ãŒããã°ãªã»ããŒã«ããªã¢ã¯ãªã¬ãŒ
ãããã³ããªã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ã
ããã³ããªã¢ã¯ãªã¬ãŒãããã³ããªã¡ã¿ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒããã
ã³ããªã¡ã¿ã¯ãªã¬ãŒããããªãªãã·ãšãã«åããª
ã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãããã³ããª
ã¡ã¿ã¯ãªã¬ãŒããããã³ç±³åœç¹èš±ç¬¬3380831å·æ
现æžã«é瀺ãããåæ§ãªååç©ãïŒïŒïŒâãžïŒïœ
âããããã·ããšãã«ïŒãããã³ãžã¢ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯ãªã¬ãŒãã
ãã³ããã©ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãžïŒïœâã
ãããã·ããšãã«ïŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããªãª
ãã·ãšãã«âïŒïŒïŒâãžïŒïœâããããã·ããšã
ã«ïŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãããã¹ããšããŒã«
ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâããããã·
ãããã«ïŒãšãŒãã«ããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒ
âã¡ã¿ã¯ãªã«ãªãã·ãšãã«ïŒãšãŒãã«ããã¹ããš
ããŒã«ïŒ¡ã®ãžïŒïŒâã¢ã¯ãªã«ãªãã·âïŒâããã
ãã·ãããã«ïŒãšãŒãã«ããã¹ããšããŒã«ïŒ¡ã®ãž
ïŒïŒâã¢ã¯ãªã«ãªãã·ãšãã«ïŒãšãŒãã«ãããã©
ã¯ãããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãª
ãã·âïŒâããããã·ãããã«ïŒãšãŒãã«ããã
ã©ã¯ãããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«
ãªãã·ãšãã«ïŒãšãŒãã«ãããã©ããã¢ãã¹ããš
ããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâãã
ããã·ãããã«ïŒãšãŒãã«ãããã©ããã¢ãã¹ã
ãšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·ãšãã«ïŒ
ãšãŒãã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ã®ãžïŒïŒâã¡
ã¿ã¯ãªã«ãªãã·ïŒâããããã·ãããã«ïŒãšãŒã
ã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãªãã·ãããã«ããªã¡ãããŒã«ãããã³ããª
ã¢ã¯ãªã¬ãŒããããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒ
ãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâãã¿ã³
ããªãªãŒã«ããªã¢ã¯ãªã¬ãŒãããã³ããªã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâãã³
ã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬
ãŒããïŒâããšãã«ãšãã¬ã³âïŒïŒïŒâãžã¡ã¿ã¯
ãªã¬ãŒãããžã¢ãªã«ããã¬ãŒããã¹ãã¬ã³ãïŒïŒ
ïŒâãã³ãŒãžãªãŒã«ãžãŠã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒ
âãžã€ãœããããã«ãã³ãŒã³ããã³ïŒïŒïŒïŒïŒâ
ããªã€ãœããããã«ãã³ãŒã³ããããããããŸã
å°ããšã300ã®ååéãæãããšãã¬ã³æ§äžé£œå
ååç©äŸãã°ïŒã15åã®ççŽ ååãå«æããã¢ã«
ãã¬ã³ã°ãªã³ãŒã«ãŸãã¯ïŒã10åã®ãšãŒãã«çµå
ãå«æãããã€ã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ã
ã補é ãããã¢ã«ãã¬ã³ãŸãã¯ããªã¢ã«ãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ç±³åœç¹èš±ç¬¬
2927022å·æ现æžã«é瀺ã®ãã®äŸãã°ç¹ã«æ«ç«¯çµ
åãšããŠååšããå Žåã®è€æ°ã®ä»å éåæ§ãšãã¬
ã³çµåãæãããã®ããŸãæçšã§ããããã®ãã
ãªçµåã®å°ããšãïŒåãããŠå¥œãŸããã¯ã»ãšãã©
ãççŽ ããã³çªçŽ ãé žçŽ ããã³ç¡«é»ã®ãããªãã
ãååãšã®ççŽ äºéçµåãå«ãäºéçµåççŽ ã«å ±
圹ããŠãããã®ã奜ãŸãããé¡èãªãã®ã¯ãšãã¬
ã³æ§äžé£œååºãç¹ã«ãããªãã³åºããšã¹ãã«ãŸã
ã¯ã¢ããæ§é ã«å ±åœ¹ããŠãããããªç©è³ªã§ããã
äžé£œååéäœæåã¯ä¹Ÿç¥å éåæ§å±€ã®å šééåºæº
ã§ïŒã45ééïŒ ã§ååšããããããã 掻æ§å ç·ã«ãã掻æ§åå¯èœã§ãããããŠ185â
ããã³ãã以äžã®æž©åºŠã§ã¯ç±çã«äžæŽ»æ§ãªå¥œãŸã
ãéé¢ã©ãžã«ã«çææ§ä»å éåéå§å€(b)ãšããŠã¯
å ±åœ¹ççŽ ç°ç³»äžã«ïŒåã®ç°å ã«ã«ããã«åºãæã
ã眮æãŸãã¯é眮æã®å€æ žããã³äŸãã°ïŒïŒ10â
ã¢ã³ãã©ããã³ãïŒâã¯ããã¢ã³ãã©ããã³ãïŒ
âã¯ããã¢ã³ãã©ããã³ãïŒã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒâãšãã«ã¢ã³ãã©ããã³ãïŒâ第ïŒçŽãã
ã«ã¢ã³ãã©ããã³ããªã¯ã¿ã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒïŒïŒâãããããã³ãïŒïŒ10âããšãã³ã
ã¬ã³ããã³ããã³ãº(a)âã¢ã³ãã©ã»ã³âïŒïŒ12â
ãžãªã³ãïŒïŒïŒâããã¿ã»ã³âïŒïŒ12âãžãªã³ã
ïŒâã¡ãã«âïŒïŒïŒâãããããã³ãïŒïŒïŒâãž
ã¯ãããããããã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©
ããã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©ããã³ãïŒâ
ããšãã«ã¢ã³ãã©ããã³ãïŒïŒïŒâãžããšãã«ã¢
ã³ãã©ããã³ãã¢ã³ãã©ããã³Î±âã¹ã«ãã³é žãŸ
ãã¯Î²âã¹ã«ãã³é žã®ãããªãŠã å¡©ãïŒâã¯ãã
âïŒâã¡ãã«ã¢ã³ãã©ããã³ãã¬ãã³ããã³ã
ïŒïŒïŒïŒïŒïŒ10âããã©ãããããã¿ã»ã³âïŒïŒ
12âãžãªã³ããã³ïŒïŒïŒïŒïŒïŒïŒâããã©ããã
ãã³ãº(a)ã¢ã³ãã©ã»ã³âïŒïŒ12âãžãªã³ãããã
ãããããã®ãããã®ã¯85âçšåºŠã®äœæž©åºŠã§ç±ç
ã«æŽ»æ§ã§ããã«ããŠããããŸãæçšãªãã®ä»ã®å
éå§å€ã¯ç±³åœç¹èš±ç¬¬2760863å·æ现æžã«èšèŒãã
ãŠãããããããšããŠã¯ãã·ãã«ã±ãã¢ã«ããã«
ã¢ã«ã³ãŒã«äŸãã°ãã³ãŸã€ã³ããããã€ã³ãã¢ã·
ãã€ã³ãšãŒãã«äŸãã°ãã³ãŸã€ã³ã¡ãã«ããã³ãš
ãã«ãšãŒãã«ãαâã¡ãã«ãã³ãŸã€ã³ãαâã¢ãª
ã«ãã³ãŸã€ã³ããã³Î±âããšãã«ãã³ãŸã€ã³ãå«
ãαâçåæ°ŽçŽ çœ®æè³éŠæã¢ã·ãã€ã³ããããã
ããç±³åœç¹èš±ç¬¬2850445å·ãå第2875047å·ãå第
3097096å·ãå第3074974å·ãå第3097097å·ãã
ã³å第3145104å·åæ现æžã«é瀺ãããå éå æ§
ææããã³éå å€ãªãã³ã«ããšããžã³ããªããµãž
ã³ããã³ããã³çŸ€ã®ææãããã©ãŒã®ã±ãã³ãã
ã³ãŸããšãã³ãïŒïŒïŒïŒïŒâããªããšãã«ã€ãã
ãŸãªã«äºéäœããã³ãã€ã³ææãå«ãæ°ŽçŽ ãããŒ
ãšã®çµåããããã³ãããã®æ··åç©ç±³åœç¹èš±ç¬¬
3427161å·ãå第3479185å·ããã³å第3549367å·
åæ现æžåç §ãéå§å€ãšããŠäœ¿çšã§ããããŸãç±³
åœç¹èš±ç¬¬4162162å·æ现æžã«é瀺ã®å¢æå€ããŸã
å éå§å€ããã³å é»å®³å€ã«é¢ããŠæçšã§ãããã
ã®å éå§å€ãŸãã¯éå§å€ç³»ã¯ä¹Ÿç¥å éåæ§å±€ã®å š
ééåºæºã§0.05ã10ééïŒ éã§ååšããã ãã®å éåæ§çµæç©ã¯å°ããšãïŒçš®ã®ææ©éå
äœç¶çµåå€(c)äŸãã°ããªã¢ã¯ãªã¬ãŒãããã³Î±â
ã¢ã«ãã«ããªã¢ã¯ãªã¬ãŒããšã¹ãã«äŸãã°0.5ã
3.0ã®ç¯å²ã®åºæç²åºŠãæããããªã¡ãã«ã¡ã¿ã¯
ãªã¬ãŒãããã³ããªãšãã«ã¡ã¿ã¯ãªã¬ãŒããããª
ããã«ãšã¹ãã«äŸãã°ããªããã«ã¢ã»ããŒããã
ãªããã«ã¢ã»ããŒãïŒã¢ã¯ãªã¬ãŒããããªããã«
ã¢ã»ããŒãïŒã¡ã¿ã¯ãªã¬ãŒãããã³æ°Žè§£ããªãã
ã«ã¢ã»ããŒãããšãã¬ã³ïŒããã«ã¢ã»ããŒãå ±é
åäœãããªã¹ãã¬ã³éåäœããã³äŸãã°ãã¬ã€ã³
é žç¡æ°Žç©ããã³ãšã¹ãã«ãšã®å ±éåäœããããªã
ã³ã¯ããªãå ±éåäœäŸãã°ãããªãã³ã¯ããªãïŒ
ã¢ã¯ãªããããªã«ããããªãã³ã¯ããªãïŒã¡ã¿ã¯
ãªã¬ãŒãããã³ãããªãã³ã¯ããªãïŒããã«ã¢ã»
ããŒãå ±éåäœãããªå¡©åããã«ããã³å ±éåäœ
äŸãã°ããªå¡©åããã«ïŒã¢ã»ããŒãã飜åããã³
äžé£œåããªãŠã¬ã¿ã³ãåæãŽã äŸãã°ãã¿ãžãš
ã³ïŒã¢ã¯ãªããããªã«ãã¢ã¯ãªããããªã«ïŒãã¿
ãžãšã³ïŒã¹ãã¬ã³ãã¡ã¿ã¯ãªã¬ãŒãïŒã¢ã¯ãªãã
ããªã«ïŒãã¿ãžãšã³ïŒã¹ããšã³å ±éåäœãïŒâã¯
ãããã¿ãžãšã³âïŒïŒïŒéåäœãå¡©çŽ åãŽã ãã
ãã³ã¹ãã¬ã³ïŒãã¿ãžãšã³ïŒã¹ãã¬ã³ãã¹ãã¬
ã³ïŒã€ãœãã¬ã³ïŒã¹ãã¬ã³ãããã¯å ±éåäœãçŽ
ïŒïŒ000ãïŒïŒ000ïŒ000ã®æ°å¹³åååéãæãã
ããªã°ãªã³ãŒã«ã®é«ååéããªãšãã¬ã³ãªãã·
ãããšããã·ãäŸãã°ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯
ãªã¬ãŒãåºãå«æãããšããã·ããã³ããªãšã¹ã
ã«äŸãã°åŒHOïŒCH2ïŒoâOHïŒåŒäžïœã¯ïŒã10ã®
å šæ°ã§ããïŒã®ããªã¡ãã¬ã³ã°ãªã³ãŒã«ãš(1)ãã
ãµããããã¬ãã¿ã«é žãã»ãã·ã³é žããã³ãã¬ã
ã¿ã«é žã(2)ãã¬ãã¿ã«é žãã€ãœãã¿ã«é žããã³ã»
ãã·ã³é žã(3)ãã¬ãã¿ã«é žããã³ã»ãã·ã³é žã(4)
ãã¬ãã¿ã«é žããã³ã€ãœãã¿ã«é žãšã®åå¿çæç©
ãã補é ããããã®ãããã³(5)åèšã°ãªã³ãŒã«ãš
ïŒïŒãã¬ãã¿ã«é žãã€ãœãã¿ã«é žããã³ã»ãã·
ã³é žããã³ïŒïŒãã¬ãã¿ã«é žãã€ãœãã¿ã«é žã
ã»ãã·ã³é žããã³ã¢ãžãã³é žãã補é ãããã³ã
ãªãšã¹ãã«æ··åç©ããã€ãã³ãŸãã¯ããªã¢ããäŸ
ãã°ïŒ®âã¡ããã·ã¡ãã«ããªãããµã¡ãã¬ã³ã¢ãž
ããããã»ã«ããŒã¹ãšã¹ãã«äŸãã°ã»ã«ããŒã¹ã¢
ã»ããŒããã»ã«ããŒã¹ã¢ã»ããŒããµã¯ã·ããŒãã
ãã³ã»ã«ããŒã¹ã¢ã»ããŒãããã¬ãŒããã»ã«ããŒ
ã¹ãšãŒãã«äŸãã°ã¡ãã«ã»ã«ããŒã¹ããšãã«ã»ã«
ããŒã¹ããã³ãã³ãžã«ã»ã«ããŒã¹ãããªã«ãŒãã
ãŒããããªããã«ã¢ã»ã¿ãŒã«äŸãã°ããªããã«ã
ãã©ãŒã«ãããªããã«ãã«ãã«ãããªãã«ã ã¢ã«
ãããããããããã ãã®çµåå€ã¯æ°Žæ§çŸå液äžã§çµæç©ãåŠçå¯èœ
ãšããã«å åãªé žæ§ãŸãã¯ãã®ä»ã®åºãå«æãã
ããæçšãªæ°Žæ§åŠçå¯èœãªçµåå€ãšããŠã¯ç±³åœç¹
蚱第3458311å·ããã³ç±³åœç¹èš±ç¬¬1507704å·åæ现
æžã«é瀺ã®ãã®ãããããããæçšãªäž¡æ§éåäœ
ãšããŠã¯ãâã¢ã«ãã«ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ãããé žæ§ãã€ã«ã 圢ææ§å ±åéäœã
ãã³ã¢ã«ãã«ãŸãã¯ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬
ãŒãããå°ãããå ±éåäœäŸãã°ç±³åœç¹èš±ç¬¬
3927199å·æ现æžã«é瀺ã®ãã®ãããããããã
ããç±³åœç¹èš±æ现æžã¯ããã«åç §ãšããŠå å«ãã
ããéåäœç¶çµåå€ïŒããã³ååšãããã®ä»ã®é
åäœïŒã®æ°å¹³åååéïŒïœïŒã¯ããªãã¿ãžãšã³
æšæºãŸãã¯ãã®ä»ã®åœæ¥è ã«ã¯æ¢ç¥ã®æšæºã䜿çš
ããŠã²ã«ééã¯ãããã°ã©ãã€ãŒã«ãã枬å®ãã
ãã ãã®å éåæ§çµæç©äžã«ã¯0.02ã4.0ÎŒïœå¥œãŸã
ãã¯0.1ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ã®ããŒãºæ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ããã
ããäžèšã®æº¶åªãªãã³ã«éåäœããŒãºã®è£œé ã«äœ¿
çšãããåéäœã®ããã®æº¶åªäžã§äžæº¶æ§ãã€éé
å¡åæ§ã§ããã°ãã°ãã®å®è³ªçã«éèšæœ€æ§ã®äº€å
çµåéåäœããŒãº(d)ãååšããããããããã®äº€
åçµåéåäœããŒãºã¯ïŒåååœãïŒåãŸãã¯ãã
以äžã®éé¢ã©ãžã«ã«éåæ§äºéçµåãå«æããå
éäœã®ãã¢éåäœãŸãã¯å ±éåäœã§ããããã奜
ãŸãã亀åçµåéèšæœ€æ§éåäœããŒãºã¯ããªãã
ã³ããã©ã¢ã¯ãªã¬ãŒãããã³ããªããã³ããã©ã¡
ã¿ã¯ãªã¬ãŒãåéäœã®ãã¢éåäœãåèšããªãã
ã³ããã©ã¢ã¯ãªã¬ãŒãããã³ããªããã³ããã©ã¡
ã¿ã¯ãªã¬ãŒãåéäœã®å ±éåäœãå°ããšãïŒçš®ã®
åèšããªããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯åèšã
ãªããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãåéäœã®ïŒåã®æ«
端ãšãã¬ã³åºãå«æããå°ããšãïŒçš®ã®åéäœ25
ééïŒ ãŸã§ã®å ±éåäœãå°ããšãïŒçš®ã®åèšããª
ããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯åèšããªããã³
ããã©ã¡ã¿ã¯ãªã¬ãŒãåéäœãšïŒåã®æ«ç«¯ãšãã¬
ã³åºãŸãã¯ïŒåã®æ«ç«¯ãšãã¬ã³åºãå«æããå°ã
ãšãïŒçš®ã®åèšããªã¢ã¯ãªã¬ãŒããŸãã¯ããªã¡ã¿
ã¯ãªã¬ãŒãåéäœãšã¯å¥ã®åéäœ75ééïŒ ãŸã§ã®
å ±éåäœãããªã矀ããéžã°ããããã®äº€åçµå
ããŒãºãææéã®ã³ãŒãã€ã³ã°æº¶åªãåžåããå Ž
åã«ã¯æ¥é也ç¥å¹æã¯å€±ãããããã®çç±ã¯ããŒ
ãºãããããŠåŸã€ãŠããŒãºå«æçµæç©ãã溶åªã
é€å»ããã®ã«äžå±€é·ãæéããããããã§ããã
åŸã€ãŠãã®ããŒãºã溶åªã«ããå®è³ªçã«éèšæœ€æ§
ã§ããããšãæ¬çºæã«ãšã€ãŠæ¬è³ªçã§ããã奜ãŸ
ãã亀åçµåãããéèšæœ€æ§éåäœããŒãºã®è£œé
ããã³å¯èœæ§ããããŒãºèšæœ€è©Šéšã¯ç±³åœç¹èš±åºé¡
第370992å·æ现æžã«èšèŒãããŠããããŸããã®è¡š
é¢ãå æ°Žå解ããã亀åçµåéåäœããŒãºããŸã
æçšã§ãããããã¯ãšã¹ãã«çµåå«æéåäœããŒ
ãºãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠã ãŸãã¯ã
ã®ä»ã®ã¢ã«ã«ãªæ§è©Šè¬ã§åŠçããããšã«ãã€ãŠé
æããããšãã§ããã ãã®ä»ã®æçšãªäº€åçµåãããéåäœããŒãºãš
ããŠã¯ãžããããã·ååç©äŸãã°ãžãšãã¬ã³ã°ãª
ã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãããã©ã¡ãã¬
ã³ã°ãªã³ãŒã«ããã¹ããšããŒã«ïŒ¡ãã®ä»ã®ãžã¢ã¯
ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã®éåäœããã³
å ±éåäœäŸãã°ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿
ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢ã¯ãª
ã¬ãŒãïŒã¹ãã¬ã³ïŒ25ïŒ ãŸã§ïŒãããªã¡ãããŒã«
ãããã³ããªã¢ã¯ãªã¬ãŒãïŒ25ã10ïŒïŒããªãšã
ã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ75ã90ïŒãããª
ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒãïŒ25ïŒ ãŸã§ïŒãããã©ãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
ïŒ25ïŒ ãŸã§ïŒããžããã«ãã³ãŒã³ãïŒïŒïŒïŒïŒâã
ãªããã«ãã³ãŒã³ãããªã¢ã¯ãªã«ãªãã·ã·ã¢ãã¬
ãŒããããªã¢ãªã«ã·ã¢ãã¬ãŒããããªã¢ã¯ãªã«ãª
ãã·ãã³ãŒã³äŸãã°ãããã°ã«ã·ãã«ããªã¢ã¯ãª
ã¬ãŒããããã³ããªããããã·ååç©äŸãã°ãã³
ãããŒã«ãã€ãã·ããŒã«ããã³èç³ãã®ä»ã®ã¢ã¯
ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãããå°ãããéå
äœããããããã æå(a)ã(d)ã®åèšééåºæºãšææ©éåäœç¶çµå
å€(c)ãšäº€åçµåããŒãº(d)ãšã®çµåãã®åèšééïŒ
ã¯40ã70ééïŒ ã§ããã亀åçµåããŒãº(d)ã¯æå
(c)ããã³(d)ã®åèšééåºæºã§15ã90ééïŒ ã®éã§
ååšãããã以äžã®å¯Ÿç §äŸïŒã«èšèŒã®ããã«ææ©
éåäœç¶çµåå€ã®ååéã¯ååšããããã亀åçµ
åããŒãºéã«é¢ä¿ãæããŠããã亀åçµåããŒãº
(d)ã®å¥œãŸããééïŒ ã¯çµåå€æå(c)ã®ååéã«äŸ
åãããäŸãã°çµåå€äž»æåã40000ãŸã§ã®æ°å¹³
åååéãæããŠããå Žåã«ã¯15ã40ééïŒ éã®
ããŒãºãæçšã§ãããçµåå€äž»æåã100000000
以äžã®æ°å¹³åååéïŒé«ååéçµåå€ïŒãæããŠ
ããå Žåã«ã¯30ã90ééïŒ ã®ããŒãºãæçšã§ã
ãã å éåæ§çµæç©ã®è£œé ã«ãããŠã¯ãææ©éåäœ
ç¶çµåå€ã«å¯Ÿãã溶åªãŸãã¯æº¶åªæ··åç©(c)ãååš
ãããããæçšãªæº¶åªãšããŠã¯ã¡ãã¬ã³ã¯ããª
ããïŒâãšããã·ãšã¿ããŒã«ãã¡ã¿ããŒã«ãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³ãïŒïŒïŒâããªã¯ãã
ãšã¿ã³ãã¡ãã«ã€ãœããã«ã±ãã³ãã®ä»ãŸãã¯ã
ãã溶åªã®çµåãããããããã溶åªã¯å éåæ§
çµæç©ã®è£œé ã®ããã«äœ¿çšãããæåã®ééåºæº
ã§45ã95ééïŒ éã§ååšããã溶åªã¯åœæ¥è ã«ã¯
åšç¥ã®ããã«äŸãã°ç±é¢šãã©ã€ã€ãŒã䜿çšããŠä¹Ÿ
ç¥ãããããšã«ããé€å»ãããã åèšã®å éåæ§çµæç©ã®äž»èŠãªæåã«å ããŠã
å°éã®æ¬¡ã®æåããŸãå Žåã«ããååšãããããš
ãã§ãããçš®ã ã®çè²å€äŸãã°ææããã³é¡æã
å ããŠåã®å¯èŠæ§ãäžæãããããšãã§ãããå
æåæ§ææåé§äœãå å«ãããŠé²å ããããå Žå
ã«å¯èŠåãçæãããããšãã§ãããããããªã
ã䜿çšããããã¹ãŠã®çè²å€ã¯å¥œãŸããã¯äœ¿çšã
ãã掻æ§ç·æŸå°ã«å¯ŸããŠéæã§ããã¹ãã§ããã
é¡æããŸãç¬ç«ãªå®è³ªçã«éèšæœ€æ§ã®äº€åçµåã
ãŒãºäžã«å å«ãããããšãã§ããããããããŒãº
ã¯é¡æãå ååŠç³»ãšã®ååŠççžäºäœçšããåé¢ã
ãã ååšããããã奜ãŸããç±éåé»å®³å€ãšããŠã¯
ïœâã¡ããã·ããšããŒã«ããããããã³ããã³ã¢
ã«ãã«ããã³ã¢ãªãŒã«çœ®æãããããã³ããã³ã
ãã³ã第ïŒçŽããã«ã«ãã³ãŒã«ãããã¬ããŒã«ã
é ã¬ãžããŒãïŒæš¹èé žé ïŒããããã«ã¢ãã³ãβ
âããããŒã«ãå¡©å第ïŒé ãïŒïŒïŒâãžç¬¬ïŒçŽã
ãã«ïœâã¯ã¬ãŸãŒã«ãããšããã¢ãã³ãããªãž
ã³ãããããã³ãŒã³ããã³ãžããããã³ãŒã³ãïœ
âãã«ããã³ããã³ã¯ãã©ãã«ããã³ç±³åœç¹èš±ç¬¬
4168982å·æ现æžã«é瀺ã®ããããœçµæç©ããã
ãããã䜿çšãããå Žåã®é»å®³å€ã¯å éåæ§çµæ
ç©ã®0.001ã2.0ééïŒ éã§ååšããã å éåæ§çµæç©ã«ãããŠã¯ãæ¥çä¿é²å€ããŸã
æçšã§ããããã®ãããªæ¥çä¿é²å€ã®äŸãšããŠã¯
å°éã®åŒ ïŒåŒäžïŒ²ã¯ãªã«ãè³éŠæçåæ°ŽçŽ æ žäŸãã°ãã³ãŒ
ã³ãŸãã¯ããã¿ã¬ã³ã§ãããã¯CH2ãNHã
ãããŸãã¯Seã§ãããã¯ïŒ®ãŸãã¯ïŒ£â
ã§ãããã¯ïŒšãNH2ãïŒãïŒåã®ççŽ ååã
å«æããã¢ã«ãã«ãŸãã¯ããã²ã³äŸãã°ClãŸãã¯
Brã§ããïŒã®çªçŽ å«æååç©ããããããã奜
ãŸããååç©ã¯ãã³ãŸããªã¢ãŸãŒã«ã§ããã䜿çš
ãããå Žåãæ¥çä¿é²å€ã¯å éåæ§çµæç©ã®åé
äœããã³çµåå€ã®å°ããšã0.001ééïŒ éã§ååš
ããããããé©åœãªååç©ã¯ããã«åç §ãšããŠå
å«ãããŠããç±³åœç¹èš±ç¬¬3622334å·æ现æžäžã«é
瀺ãããŠããã å éåæ§çµæç©ãšçžå®¹æ§ã®ïŒçš®ãŸãã¯ãã以äž
ã®å¯å¡å€ããã®äžã«ååšãããŠä¹Ÿç¥ãã€ã«ã ã®éž
æççŸåæ§ãå¯èœãªãããã匟æ§ãæ¹åãããã
ãã¯ãã®ç©å±€æž©åºŠãäœäžãããããšãã§ãããå¯
å¡å€ã®äŸãšããŠã¯ãžã¢ã«ãã«ãã¿ã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãã¢ã«ãã«ãã¹ããšãŒããã®ä»
ããããããã ææã«ããå éåæ§çµæç©ã«ã¯0.1ã2.0ÎŒïœç¯
å²ã®ç²åãµã€ãºãæããããŠå éåæ§çµæç©ã®å±€
ã«é²å ã«äœ¿çšãããæ³¢é·ã§ã¯æ¬è³ªçã«éæãªãã
ãŠæŽ»æ§ç·æŸå°ãæ£ä¹±ãããªãéæ··åæ§ç¡æ©å å¡«å€
ãŸãã¯è£åŒ·å€äŸãã°èŠªææ©æ§ã·ãªã«ãã·ãªã«ãç²
æ«ã¬ã©ã¹ãã®ä»ãå å«ãããããšãã§ããããã®
ãããªç©è³ªã¯å éåæ§çµæç©ã®ææã®æ§è³ªã«å¿ã
ãŠå€åããéã§äœ¿çšãããããã®å å¡«å€ã¯å éå
æ§å±€ã®åŒ·åºŠããã³ãããã®æ¹åã«æçšã§ããã åè¿°ããããã«ã亀åçµåããŒãºãå«æããã
ãžãšããŠåãå æåæ§ã³ãŒãã€ã³ã°çµæç©ã¯ã(a)
ç±³åœç¹èš±ç¬¬3837860å·æ现æžèšèŒã®ããã«ããŠè£œ
é ãããæžåãžã¢ãŸããã³åºå«æå å¯æº¶åæ§éå
äœã(b)ç±³åœç¹èš±ç¬¬3778270å·æ现æžèšèŒã®ããã«
æžåããããã·ã«ãŸãã¯ã¢ããåºãæããéåäœ
ãšãã¹ã¢ãŸããŠã å¡©ãæ··åããããšã«ãã補é ã
ããå æžææ§éåäœãããã³(c)ç±³åœç¹èš±ç¬¬
4271260å·æ现æžã«èšèŒã®ãããªãžãããããªãž
ã³ãïŒæåãšããŠå«æããå æåæ§çµæç©ã䜿çš
ããŠè£œé ãããããããç±³åœç¹èš±æ现æžã¯ããã«
åç §ãšããŠå å«ãããŠãããå 溶解æ§ããã³å æž
ææ§ã¬ãžã¹ãçµæç©ã¯ããã«åç §ãšããŠå å«ãã
ãŠããç±³åœç¹èš±ç¬¬4193797å·æ现æžç¬¬ïŒæ¬ç¬¬19è¡
ã第ïŒæ¬ç¬¬68è¡ã«é瀺ãããŠããã 亀åçµåããŒãºãå«æããå éåæ§ã³ãŒãã€ã³
ã°çµæç©ã¯æ¬¡ã®ããã«ããŠè£œé ããããšãã§ã
ããããŒãºãäžç床åªæã§æº¶åªã®äžéšã«åæ£ãã
ããã«ãã€ãŠååšããããã¹ãŠã®ãããç²åéå¡
ããããã次ãã§ãã®åæ£æ¶²ãæ®äœã®æº¶åªãšå
ãããããŠåèšããã³äžèšã®å®æœäŸã«èšèŒã®ãã®
ä»ã®æåãæ¹æãã€ã€å ããã䜿çšããã溶åªã®
éã¯ããçšåºŠã¯å éåæ§ã³ãŒãã€ã³ã°çµæç©ã®ã³
ãŒãã€ã³ã°æ³ã«äŸåããã äŸãã°åè¿°ã®ããã«ããŠããŸãã¯ãã®ä»ã®æ¹æ³
ã§è£œé ãããå éåæ§ã³ãŒãã€ã³ã°çµæç©ãäŸã
ã°10ÎŒïœã®åãµã€ãºã®ã€ã³ã©ã€ã³ïŒinâlineïŒã
ã€ã«ã¿ãŒãéãããšã«ãã€ãŠéãããéãã
溶液ãã³ãŒãã€ã³ã°è£ 眮äŸãã°ã³ãŒãã€ã³ã°éé
èŠå¶ã®ããã®ãšã¢ãã€ããä»ãããã®ã§ãããã
ã¹ãã ã³ãŒã¿ãŒãæŒåºããã€ãã°ã©ãã¢ããŒã«ã
ã¯ã€ã€å·»ãããããŸãã¯åœæ¥è ã«ã¯æ¢ç¥ã®ãã®ä»
ã®ã³ãŒãã€ã³ã°æ段ã«ãã³ãã§çµŠéããããšãã§
ããããã®å éåæ§ã³ãŒãã€ã³ã°çµæç©ã¯é©åœãª
幟äœåŠçé¢ä¿ã§ã³ãŒãã€ã³ã°ãŠããããééãã
ãã€ã«ã ã®ç§»åãŠãšãã«åäžã«é©çšããããšãã§
ãããã³ãŒãã€ã³ã°ããããŠãšãã¯é垞匷å¶ãã©
ããå ç±ç©ºæ°äŸçµŠãä»ãããã©ã€ã€ãŒäžã«éã
ããããã§ã¯ç©ºæ°é床ãæ¹åããã³æž©åºŠã¯ã³ãŒã
ã€ã³ã°äžã®æº¶åªãé€å»ããããã«å¶åŸ¡ãããŠã
ãããã®ä¹Ÿç¥ãŠãšããäŸãã°é©åœãªããŒã«äžã«å·»
ãåããå·»ãåãã®éã«ããŒã·ãŒãã也ç¥å éå
æ§è¡šé¢ã«ç©å±€ãããããšãã§ãããåœæ¥è ã«æ¢ç¥
ã®ãã®ä»ã®æ¹æ³ã䜿çšããŠä¹Ÿç¥å éåæ§ãã€ã«ã
ã補é ã§ããã åè¿°ããããã«ä¹Ÿç¥ãã€ã«ã ããã¬ãžã¹ããšã¬
ã¡ã³ãã®è£œé ã«ãããŠã¯ãå¥é¢æ§æ¯æäœäžã®åç
ææ§å éåæ§åºå±€ã奜ãŸããã¯äœ¿çšããããæ¯æ
äœã€ãå éåæ§åºå±€ã®æ®ãã®è¡šé¢ã¯é€å»å¯èœãªã«
ããŒã·ãŒãã§ä¿è·ããããšãã§ããããããã¯ãŸ
ããšã¬ã¡ã³ããããŒã«åœ¢æ ã§ä¿åãããŠããå Žå
ã«ã¯ãåºå±€è¡šé¢ã¯æ¯æäœã®é£æ¥ããéè¡šé¢ã§ä¿è·
ããããããã®å éåæ§çµæç©ã¯çŽ0.0003ã€ã³ã
ïŒã0.0008cmïŒãçŽ0.01ã€ã³ãïŒã0.025cmïŒãŸã
ã¯ãã以äžã®ä¹Ÿç¥ã³ãŒãã€ã³ã°åãã§ååšããã
奜ãŸããã¯æž©åºŠå€åã«å¯ŸããŠé«åºŠã®å¯žæ³å®å®æ§ã
æããé©åœãªå¥é¢æ§æ¯æäœã¯é«ååééåäœäŸã
ã°ããªã¢ãããããªãªã¬ãã€ã³ãããªãšã¹ãã«ã
ããã«éåäœããã³ã»ã«ããŒã¹ãšã¹ãã«ãããªã
åºç¯å²ã®çš®çš®ãªãã€ã«ã ããéžã¶ããšãã§ããã
ãŠãããã¯0.00025ã€ã³ãïŒã0.0006cmïŒã0.008
ã€ã³ãïŒã0.02cmïŒãŸãã¯ãã以äžã®åããæã
ãããå¥é¢æ§æ¯æäœãé€å»ããåã«é²å ãå®æœã
ããå Žåã«ã¯ãããã¯å¿è«ããã«ç §å°ããã掻æ§
ç·æŸå°ã®å®è³ªçå²åãééãããªããŠã¯ãªããª
ããå¥é¢æ§æ¯æäœãé²å ã®åã«é€å»ãããå Žåã«
ã¯ããã®ãããªå¶éã¯é©çšãããªããç¹ã«é©åœãª
æ¯æäœã¯çŽ0.001ã€ã³ãïŒã0.0025cmïŒã®åãã
æããéæããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã
ã§ããã ãšã¬ã¡ã³ããé€å»å¯èœãªä¿è·ã«ããŒã·ãŒããæ
ããŠããããããŠããŒã«åœ¢æ ã§ä¿åãããå Žåã«
ã¯ã奜ãŸããã¯å¥é¢æ§æ¯æäœã®è£åŽã¯ããã«èã
é¢åäœçšç©è³ªå±€äŸãã°ã¯ãã¯ã¹ãŸãã¯ã·ãªã³ãŒã³
ãé©çšããŠå éåæ§åºå±€ãšã®ãããã¯åœ¢æãé»æ¢
ãããããããã¯ãŸãã³ãŒãã€ã³ã°ãããå éå
æ§å±€ãžã®æ¥çã¯ã³ãŒãã€ã³ã°ãã¹ãæ¯æäœè¡šé¢ã®
çåŠçãŸãã¯æŸé»åŠçã«ãã€ãŠåªå çã«äžæãã
ãããšãã§ããã 䜿çšãããå Žåã®é©åœãªé€å»å¯èœãªä¿è·ã«ããŒ
ã·ãŒãã¯åèšãšåäžã®é«åºŠéåäœãã€ã«ã 矀ãã
éžã¶ããšãã§ãããããŠããã¯åäžã®åºç¯å²ã®å
ããæãããã0.001ã€ã³ãïŒã0.0025cmïŒåã
ã®ããªãšãã¬ã³ã«ããŒã·ãŒãã¯ç¹ã«é©åœã§ããã
åèšæ¯æäœããã³ã«ããŒã·ãŒãã¯å éåæ§ã¬ãžã¹
ãå±€ã«è¯å¥œãªä¿è·ãäžããã äžè¬ã«å°å·åè·¯ã®åœ¢æãå«ãæ¬çºæã®æ¹æ³ã«é©
åœãªåºæã¯æ©æ¢°ç匷床ãååŠçæµææ§ããã³è¯å¥œ
ãªèªé»æ§ãæãããã®ã§ãããããªãã¡å°å·åè·¯
ã®ããã®ã»ãšãã©ã®æ¿ææã¯éåžžè£åŒ·å€ãå ãã
ç±ç¡¬åæ§ãŸãã¯ç±å¯å¡æ§æš¹èã§ãããè£åŒ·å€ãå
ããç±ç¡¬åæ§æš¹èãåæ§æ¿ã®ããã«äžè¬ã«äœ¿çšã
ããããŠè£åŒ·ãªãã®ç±å¯å¡æ§æš¹èã¯å¯ææ§åè·¯æ¿
ã«é垞䜿çšãããã å žåçæ¿æ§é ã¯çµåãç©äŸãã°çŽãŸãã¯çŽâã¬
ã©ã¹è€åäœã®äžã®ããšããŒã«ãŸãã¯ãšããã·æš¹è
ãªãã³ã«ã¬ã©ã¹äžã®ããªãšã¹ãã«ããšããã·ãã
ãªã€ãããããªããã©ãã«ãªããšãã¬ã³ãŸãã¯ã¬
ã©ã¹äžã®ããªã¹ãã¬ã³ãå å«ãããã»ãšãã©ã®å Ž
åæ¿ã«ã¯é»æ°äŒå°æ§éå±ã®èãå±€ã被èŠããã
ãããã®éå±ã®äžã§ã¯é ãæãäžè¬çã§ããã ç³çå°å·çšãã¬ãŒãã®è£œé ãå å«ããæ¬çºæã®
æ¹æ³ã«é©åœãªåºæã¯ãæ©æ¢°ç匷床ãæããããŠå
æåæ§å±€ã®ç©å±€ãåèšå±€ã®é²å ããã³çŸåã«ãã
圢æããããã®äžã®å圢æãããå æåæ§éšåã®
è¡šé¢ãšã¯èŠªæ°Žæ§ãŸãã¯èŠªæ²¹æ§ã«ãããŠç°ãªãè¡šé¢
ãæããŠãããã®ã§ããããã®ãããªåºæã¯ç±³åœ
ç¹èš±ç¬¬4072528å·æ现æžã«é瀺ãããŠããããã®
ç®çã«å¯ŸããŠã¯å€ãã®åºæãæºè¶³ãã¹ããã®ã§ã¯
ããããã©ããèãã¢ããŒãåŠçããã¢ã«ãããŠ
ã ãã¬ãŒãäŸãã°ç±³åœç¹èš±ç¬¬3458311å·æ现æžã«
é瀺ã®ãã®ãç¹ã«æçšã§ãããã¢ããŒãåŠçãã
ã³ã·ãªã±ãŒãåŠçã¢ã«ãããŠã ãã¬ãŒãããŸãæ
çšã§ããã åœæ¥è ã¯ç©å±€ãããã¹ãå°å·åè·¯åºæè¡šé¢ãæž
æµã§ãããã€å€æ¥æ§ç©è³ªã®å šãååšããŠããªãã®
ã奜ãŸããããšãèªèããŠããã§ãããããã®ç
ç±ã®æ ã«å°å·åè·¯æ¿è£œé ã®åéã§ã¯åšç¥ã®æ°çš®ã®
æž æµåæ³ã®äžã€ãŸãã¯ãã以äžã«ããç©å±€ã®åã«
å°å·åè·¯åºæãæž æµåããããšãåŸåŸã«ããŠæãŸ
ãããæž æµåã®ç¹å®ã®ã¿ã€ãã¯æ±æã®ã¿ã€ãäŸã
ã°ææ©æ§ã§ããããç²åç¶ã§ããããŸãã¯éå±æ§
ã§ãããã«äŸåããããã®ãããªæ¹æ³ã¯æº¶åªãŸã
ã¯æº¶åªãšãã«ãžãšã³ã«ããè±èãæ©æ¢°çã¹ã¯ã©ã
ã³ã°ãã¢ã«ã«ãªå«æµžãé žæ§åãã®ä»ããã³ããã«
ã€ã¥ããããããã³ä¹Ÿç¥ãå å«ããã ãšã¬ã¡ã³ãã®è£œé ããã³ãã®ãšã¬ã¡ã³ãã也ç¥
ããã¬ãžã¹ããšããŠäœ¿çšãããå Žåã«ã¯ãã®å é
åæ§å±€ã®å°å·åè·¯æ¿ãžã®ç©å±€ã®åŸããã®å éåæ§
å±€ã¯é©åœãªåäŸãã°åå«æéæç»ãéœç»ãŸãã¯é°
ç»ãŸãã¯é©åœãªãããã¹ã¯ãéããŠæŽ»æ§ç·æŸå°ã«
åæ§é²å ããããããã掻æ§ç·æŸå°æºã¯äžè¬ã«æ
å¹éã®çŽ«å€ç·ç¯å²ã®æŸå°ãäžãããé©åœãªæºãšã
ãŠã¯ã«ãŒãã³ã¢ãŒã¯ãæ°Žéèžæ°ã¢ãŒã¯ãç¹å¥ã®çŽ«
å€éšçºå è¢å äœãæããè¢å ç¯ãã¢ã«ãŽã³ã°ããŒ
ã©ã³ããé»åãã©ãã·ãŠãŠãããããã³åççšã
ã©ããã©ã³ããã®ä»ãããããããããå éåäœ
å±€ã®æºè¶³ãã¹ãè€åã«å¯ŸããŠèŠæ±ãããé²å ã®é
ã¯é²å æéã䜿çšãããæŸå°æºã®ã¿ã€ããããã³
æŸå°æºãšå±€è¡šé¢ãšã®éã®è·é¢ã®åŸæ°ã§ãããäžè¬
ã«æšæºã®åæ¥çæŸå°æºã䜿çšããå Žåã«ã¯é²å æ
éã¯0.5ã10åãŸãã¯ãã以äžã®ç¯å²ã§ããã åæ§é²å ã®åŸãå éåå±€ã®æªé²å éšåã液äœçŸ
åäŸãã°ææ©éåäœçµåå€æåã«å¯Ÿãã溶åªãŸã
ã¯æº¶åªæ··åç©ã«ããé€å»ãããçŸåã¯ããããã®
䟿å©ãªæ¹æ³äŸãã°æ³šæ¶²ãå«æµžãã¹ãã¬ãŒãŸãã¯ã
ãŒã©ãŒé©çšã«ããå®æœããããããã©ã·ããã¯çµ
æç©ã®æªéåãŸãã¯æªäº€åçµåéšåã®é€å»ãå©æ
ããããçŸåã¯æž©æº¶æ¶²ã䜿çšããŠå®æœã§ããããŠ
æéã¯å éåæ§å±€ã«ãã€ãŠäŸãã°ãã®çµæãåã
ãã®ä»ã«ããå€åãããæçšãªçŸåç¯å²ã¯ïŒç§ã
25åã®ç¯å²ã§ãããããçŸååŸãšã¬ã¡ã³ããäŸã
ã°å¿ èŠãªå Žåã«ã¯ãã¢ã³ã®åé¢ã«çœ®ãããšãå«ã
ãŠç©ºæ°äžã§ä¹Ÿç¥ãããããšãã§ããã å éåæ§çµæç©ã«å¯Ÿããæè¯ã®æ§åŒã¯äŸïŒã«èª¬
æãããŠããããã®å Žåã亀åçµåéåäœããŒãº
ã¯ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãã®ã
ã¢éåäœã§ããã ææ©éåäœç¶çµåå€ã®äžéšãã°ãã°ããªå®è³ªç
ã«éèšæœ€æ§ã®äº€åçµåããŒãºã§çœ®æããããæ¬çº
æã®å éåæ§çµæç©ã¯äº€åçµåããŒãºãå šãå«æ
ããªãåæ§ã®å éåæ§çµæç©ã«æ¯ã¹ãŠææã«äžå±€
è¿ éã«ä¹Ÿç¥ããããšãèŠåºããããæ¬çºæã®å é
åæ§çµæç©ã¯åŸæ¥æè¡ã®çµæç©ãããäžå±€éãã
ã«ããŠäžå±€å¹çãã也ç¥ãã€ã«ã¿ããã¬ãžã¹ããŸ
ãã¯ä¹Ÿç¥å éåæ§ãšã¬ã¡ã³ãã«èª¿è£œããããšãã§
ããããã®ä¹Ÿç¥ããã¬ãžã¹ãã¯å°å·åè·¯ã®è£œé ã«
䜿çšãããããã®ãããªããã¬ãžã¹ãã¯ããéã
ãã«åŠçããããšãã§ããããšã¬ã¡ã³ã圢æ ã«ã
ããŠã¯ããã®ä¹Ÿç¥å éåæ§çµæç©ã®å±€ã¯æ¯æäœäŸ
ãã°ãã€ã«ã ãŸãã¯ã·ãŒããšé€å»å¯èœãªã«ããŒã·
ãŒããšã®éã«ååšããããããããã®ãããªãšã¬
ã¡ã³ãã¯å°å·ãã¬ãŒãã®è£œé ã«äœ¿çšãããå Žåã«
ã¯å éåæ§å±€ã«æ°žä¹ çã«æ¥çãããæ¯æäœãæã
ããããã®ãšã¬ã¡ã³ãã也ç¥ãã€ã«ã ã¬ãžã¹ããš
ããŠäœ¿çšããå Žåã«ã¯æ¯æäœã¯ããã«æå·ãäžã
ãããšãªãå éåæ§å±€ããé€å»ããããããã®å
éåæ§å±€ã¯ã亀åçµåéåäœããŒãºãæ¯èŒç倧é
ã«ååšããŠããã«ããããããæãŸããæ§è³ªãä¿
æããŠãããããªãã¡æ¬çºæã®å éåæ§å±€ã®åç
é床ãé ãžã®æ¥çãéæããŸãã¯è§£åæ§ãããã³
å¯ææ§ã¯ä¿æãããŠããã åã ã«ç¬ç«ããå®è³ªçã«éèšæœ€æ§ã®äº€åçµåã
ãŒãºãå«æãããã®å éåæ§ã³ãŒãã€ã³ã°çµæç©
ã¯ãã¬ãšããŠåãç³»ã§ã¯ããããã©ããåèšã®æº¶
åªå¯æº¶æ§çµåå€ããã³äº€åçµåããŒãºã«å¯Ÿããå
äžã®èšççåºæºãæºè¶³ãããå Žåã«ã¯åæ§ã®å©ç¹
ãããžãšããŠåãå æåæ§ç³»ãå«æããå æåæ§
çµæç©ã«å¯ŸããŠãé©çšãããã ããžãšããŠåãå æåæ§ã³ãŒãã€ã³ã°çµæç©äž
ããã³ä¹Ÿç¥ãã€ã«ã ãšã¬ã¡ã³ããšããŠã®äº€åçµå
ããŒãºã®äœ¿çšã¯ããã®å æåæ§ãã€ã«ã ãå°å·å
è·¯æ¿è£œé ã®ããã¬ãžã¹ããã€ã«ã ãšããŠã®äœ¿çšã«
察ããŠãã¶ã€ã³ãããŠããå Žåã«ã¯ç¹ã«æå©ã§ã
ãããã®ãããªãã€ã«ã ã¯ãã€ã¯ããšã¬ã¯ããã
ã¯ã¹é©çšã«å¯ŸããŠäœ¿çšãããããžãšããŠåãã³ãŒ
ãã€ã³ã°ãããäžè¬ã«äžå±€åããåŸã€ãŠãããã®
æ¯èŒçåãã³ãŒãã€ã³ã°ãé©çšããããŠè¿ éã«ä¹Ÿ
ç¥ãããŠãã®éåŸããã也ç¥ãã€ã«ã ãšã¬ã¡ã³ã
äžã«åªããç©ççæ§è³ªãéæãããããšã¯æå©ã§
ããã也ç¥ãã€ã«ã ã¬ãžã¹ããšããŠç¹ã«æçšãªã
ãžãšããŠåã也ç¥ãã€ã«ã åŠæ¹ã®æçšãªã¿ã€ãã¯
ç±³åœç¹èš±ç¬¬4193797å·ããã³å第4271260å·åæ现
æžã«èšèŒãããŠããããããç±³åœç¹èš±ã¯ããã«å
ç §ãšããŠå å«ãããã ãžã¢ãŸããã³ååç©ã®å å¯æº¶åã«åºãããžãšã
ãŠåãã³ãŒãã€ã³ã°çµæç©ã¯ãŸããããã§èšèŒã
ãç¬ç«ããå®è³ªçã«éèšæœ€æ§ã®äº€åçµåããŒãºã«
é¢ããŠããŸãæçšã§ããããžã¢ãŸããã³ååç©ã¯
ãã¬ãšããŠåãå éåæ§çµæç©äžã«éåžžååšãã
ããšãã¬ã³æ§äžé£œåååç©ã®ä»£ãã«äœ¿çšãããã
ã®ã§ããããã¬ãšããŠåãçµæç©äžã§å¿ èŠãªå¥å
ã®å éå§å€ç³»ã¯å±¡ã èŠæ±ãããªãã æ¬çºæã以äžã®å®æœäŸã«ãã説æãããããã
æ¬çºæã¯ããã«éå®ãããããšãæå³ãããã®ã§
ã¯ãªããããã«éšããã³ïŒ ã¯ééåºæºã§ãããé
åäœã®ååéã¯æ°å¹³åååéã§ãããåºæç²åºŠã¯
ãã€ãã³ããšã³ã¹ã±ç²åºŠèšã䜿çšããŠ20âã§ã¡ã
ã¬ã³ã¯ããªã50mläžéåäœ0.25ïœãå«æãã溶液
ã«ã€ããŠæž¬å®ããããå®æœäŸäžã«èšèŒã®åºæç²åºŠ
ã¯æ¯ç²åºŠã®ãŒãæ¿åºŠãžã®å€æ¿ã«ãã枬å®ãããã
æ¯ç²åºŠã¯ïœân0ïŒn0ã§ãããããã«ïœã¯æº¶æ¶²ç²åºŠã§ ãããããŠn0ã¯çŽæº¶åªã®ç²åºŠã§ãããããŠäž¡è ã¯
å ±ã«25âã§ãªã¹ãã¯ã«ãç²åºŠèšããããã䜿çšã
ãŠæž¬å®ããããã®ã§ããã也ç¥å éåæ§å±€ã®ç Žæ
ç¹äŒžé·ã¯ASTMâD412â75ã«ãã枬å®ãããã
ã³ãŒãã€ã³ã°çµæç©ã®è©Šæã0.008ã€ã³ãïŒ0.20
mmïŒãã¯ã¿ãŒãã€ãã䜿çšããŠãã€ã«ã æ¯æäœäž
ã«ã³ãŒãã€ã³ã°ããããŠ48æé宀枩ã§ä¹Ÿç¥ãã
ããç¹èšãããŠããªãéãã¯ãã®ã³ãŒãã€ã³ã°è©Š
æãæ¯æäœããå¥é¢ããããããŠäžç·ã«ç©å±€ããŠ
çŽ0.006ã€ã³ãïŒçŽ0.15mmïŒã®å±€åããçæãã
ããïŒã€ã³ãÃïŒã€ã³ãïŒ2.54cmÃ7.62cmïŒã®ç©
å±€äœçããïŒã€ã³ãïŒåïŒ2.54cmïŒåïŒã®ã¯ãã¹
ãããé床ã§ïŒã€ã³ãïŒ2.54cmïŒã®åæåé¢ã§ã€
ã³ã¹ããã³ ãã¹ã¿ãŒååŒTMã®ãžãšãŒäžã«çœ®
ãã äŸ ïŒ ïŒ¡ ããŒãºã®è£œé 500ïœã®ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãª
ã¬ãŒãã193ppmã®ãããããã³ããã³130ppm
ã®ïœâã¡ããã·ããšããŒã«ãå«æããïŒããŒ
ã«ãŒã«ã5.7ïœã®ãã³ãŸã€ã«ããŒãªãã·ããå
ããããã®æ··åç©ããã³ãŸã€ã«ããŒãªãã·ãã
溶解ãããŸã§å®€æž©ã§æ¹æããããŠæº¶è§£å®äºåŸïŒ
æé以å ã«ãã®æº¶æ¶²ã䜿çšãããã¹ãã³ã¬ã¹ã¹
ããŒã«ããŒã«ãŒäžã«2.5ïœã®ãããªãŠã ãžãªã¯
ãã«ã¹ã«ããµã¯ã·ããŒãããã³4.2ïœã®è¡šé¢æŽ»
æ§å€ïŒããã¹ã¿ãã³ïŒHostapon ïŒãTHCãã¢
ã¡ãªã«ã³ã»ããã¹ã瀟補åïŒïŒ2.5ïœã®ãªã¬ã€ã«
ã¡ãã«ã¿ãŠãªãã®ãããªãŠã å¡©å«æïŒã®æ°Ž1200
mläžæº¶æ¶²ã補é ããããã®æº¶æ¶²ãäœéã§V2銬
åãšããã³ããããããµãŒã䜿çšããŠæ¹æãã
ãã®éããŒãªãã·ãïŒåéäœæº¶æ¶²ãå ãããã
ããµãŒã®å ¥åé»å§ãçŽ70ãã«ããŸã§äžæããã
ããšã«ãã€ãŠããããµãŒã®é床ãåŸåŸã«äžæã
ããïŒçŽ10åã«ãããïŒãé床ããã®ç¹ã«çŽïŒ
æéä¿æããã次ãã§ã¯ãªãŒã ç¶çœè²ä¹³æ¿æ¶²ã
å«æããã¹ãã³ã¬ã¹ã¹ããŒã«ã®çŒ¶ãèŠããããŠ
60âã®æ°ŽæµŽäžã«72æéä¿æããããéåä¹³æ¿æ¶²
ãå·åŽãããããŠé å¿ãããäžæŸã¿ãæšãŠãã
ãŠéåäœã±ãŒããçŽïŒã®æ°Žãšæ¹æããŠåã³é
å¿ãããæ°Žãšã®æ¹æããã³é å¿ãæŽã«ïŒåãã
ããããããŠéåäœããŒãºã®ã±ãŒãã颚也ãã
ãããã®ä¹Ÿç¥éåäœã¯æ°ŽãŸãã¯ææ©æº¶åªäŸãã°
ã¡ãã¬ã³ã¯ããªããã¢ã»ãã³ãŸãã¯ãšã¿ããŒã«
äžã«äœéã®å®¶åºçšã¿ã€ããã¬ã³ããŒãã¢ã²ãã€
ã¶ãŒã®äœ¿çšã«ãã€ãŠå®¹æã«ååæ£ããããã¯ãŒ
ã«ã¿ãŒã«ãŠã³ã¿ãŒïŒã¯ãŒã«ã¿ãŒã»ãšã¬ã¯ããã
ã¯ã¹ç€Ÿè£œåïŒã䜿çšããŠæž¬å®ãããæ°åºæºã®å¹³
åç²åãµã€ãºã¯0.66ÎŒïœã§ãããããŠå¹³å容é
ç²åãµã€ãºã¯1.2ÎŒïœã§ãã€ãã  ããã¬ãžã¹ãçšã³ãŒãã€ã³ã°åæ£æ¶²ã®è£œé åèšã®ããã«ããŠè£œé ããã也ç¥ããŒãº26.8
éšãã¡ãã¬ã³ã¯ããªã66éšãšäžç·ã«æ¹æããã
ãšã«ãã€ãŠã¡ãã¬ã³ã¯ããªãäžã®ããŒãºã®ã¹ã
ãã¯åæ£æ¶²ã補é ããããã®åæ£æ¶²ããã€ãã³
ããšã«ããã€ã«ã¿ãŒããããéããŠéããã
å®è³ªçã«åºäœç©è³ªã¯äœãä¿æãããªãã€ãã
1.25ã®åºæç²åºŠãæããããªã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒã5.5éšãš0.5ã®åºæç²åºŠãæããããªã¡ãã«
ã¡ã¿ã¯ãªã¬ãŒã1.2éšãšããã®æžæ¿æ¶²ã«æº¶è§£ã
ãããéåäœãå ããŠåæ£æ¶²ã®å®å®æ§ãäžæã
ããããããããã¯äžèŠã§ããããšãèŠåºãã
ãã è¡šïŒèšèŒã®æåãå«æããã³ãŒãã€ã³ã°çµæ
ç©ã補é ããã亀åçµåããŒãºãå«æããªãã³
ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã¯å¯Ÿç §ïŒã³ã³ãããŒã«ïŒãš
ããŠäœ¿çšããããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ããã³
ã«ãããŠã¯çµåå€ããã³ããŒãºã®åèšééã®
ãããã40ïŒ ããã³20ïŒ ã亀åçµåããŒãºã§ã
ã€ããããã¯æå(a)ã(b)ã(c)ããã³(d)ã®åèšé
éåºæºã§ããããçŽ24.24ïŒ ããã³çŽ12.12ïŒ ã«
çžåœããã
ããæŽã«è©³ããã¯ãæ¬çºæã¯çµåå€æåã®äžéšã
亀åçµåéåäœããŒãºã§çœ®æããå æåæ§çµæç©
ã«é¢ãããæŽã«æ¬çºæã¯äº€åçµåéåäœããŒãºã
å«æãã也ç¥å æåæ§ãã€ã«ã ã«é¢ããã ãšãã¬ã³æ§äžé£œååéäœååç©ãå éå§å€ãæ
æ©éåäœç¶çµåå€ãªãã³ã«ãã®ä»ã®æ·»å å€ãã補
é ãããå éåæ§çµæç©ã¯ä¹Ÿç¥ãã€ã«ã ã¬ãžã¹ã
ã®è£œé ããã³ãã®ä»ã®äœ¿çšã«å¯ŸããŠæçšã§ããã
ãšãç¥ãããŠãããå éåæ§çµæç©ã®è£œé ã«äœ¿çš
ãããæåãäžè¬ã«éåäœç¶çµåå€ã®ããã®é©åœ
ãªæº¶åªäžã§æ··åãããããŠãã®çµæç©ãäŸãã°æŒ
åºãã³ãŒãã€ã³ã°ãŸãã¯ãã®ä»ã®åœæ¥è ã«ã¯æ¢ç¥
ã®ä¹Ÿç¥ãã€ã«ã 圢ææ段ã«ãã€ãŠã³ãŒãã€ã³ã°ã
ãããŠæº¶åªé€å»ããŠä¹Ÿç¥ãã€ã«ã ãšããã ç¹ã«ä¹Ÿç¥å±€åœ¢æ ã®å éåæ§çµæç©ã¯å°å·ãã¬ãŒ
ãããã³ããã¬ãžã¹ããã€ã«ã ã®ããã«æŒžå¢çã«
äžè¬çãšãªã€ãŠãããäŸãã°ä¹Ÿç¥ãã€ã«ã ããã¬
ãžã¹ãã¯å°å·åè·¯ã®è£œé ã«ãããŠæ¶²äœããã¬ãžã¹
ãã«æ¯ã¹ãŠå€ãã®å©ç¹ãæããŠãããäºå®ã也ç¥
ãã€ã«ã ããã¬ãžã¹ãã¯éåžžã«äžè¬çãšãªã€ãŠã
ãããã®çµæãã©ã³ãã®è£œé èœåã¯éããã«å°é
ãããããããã¬ãžã¹ããã€ã«ã ã®è£œé ã«ãããŠ
çããäžã€ã®åé¡ã¯ãã®ãããªãã€ã«ã ãè¿ éäž
ã€å¹çãã也ç¥ããèœåã§ãããç±é¢šä¹Ÿç¥æ©äžã§
ã®å éåæ§ã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã¯å€ãã®å€æ°äŸã
ã°ã³ãŒãã€ã³ã°ã®åãããã³åºäœåæ¿åºŠã溶åªã®
ç¹æ§ãã³ãŒãã€ã³ã°ãããã¹ãçµæç©ãšã®æº¶åªçž
äºäœçšããã€ã«ã ã®æž©åºŠã空æ°ã®æž©åºŠã空æ°ã®é
床ãæ¹åããã³ä¹±ããçžå¯Ÿæ¹¿åºŠãã®ä»ã«ãã圱é¿
ããããäžè¬ã«ä¹Ÿç¥ã¯ïŒæ®µéã§è¡ããããšèãã
ããšãã§ããã第ïŒæ®µã«ãããŠã¯ã也ç¥é床ã¯çŽ
ç²ãªæº¶åªã®é€å»é床ãšå€§çŽåäžã§ãããå¶éãã¢
ã¯ã¿ãŒã¯æº¶åªååã®ã³ãŒãã€ã³ã°è¡šé¢ïŒãŸãã¯è¡š
é¢äžã®ç©ºæ°ç©ºéïŒããé€å»ããããé床ã§ããã
ã³ãŒãã€ã³ã°ãžã®ç±ãšãã«ã®ãŒäŸçµŠããã³ç©ºæ°é
床ã¯ãã®ç¬¬ïŒä¹Ÿç¥æ®µéã§ã¯éèŠãªãã¢ã¯ã¿ãŒã§ã
ãã第ïŒæ®µã«ãããŠã¯ã³ãŒãã€ã³ã°ã¯ããæ¿åå
ãããã®ã§ä¹Ÿç¥ã¯ããé ããªãããããŠããã¯ã³
ãŒãã€ã³ã°ã®å éšããã³ãŒãã€ã³ã°ã®ç©ºæ°è¡šé¢ãž
ã®æº¶åªååã®æ¡æ£é床ã«ããéå®ãããããã®ç¬¬
ïŒã®ä¹Ÿç¥æ®µéã«ãããŠã¯æž©åºŠããã³ç©ºæ°é床ãé
èŠã§ããã®ã¿ãªãããããã€ãã®å çãã¢ã¯ã¿ãŒ
äŸãã°æº¶åªãšæº¶è³ªãšã®çžäºäœçšãã®ä»ãéèŠãšãª
ãã å éåæ§ã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã«é¢ããå€ãã®å
é¡ã®èŠ³ç¹ããããã®ãããªã³ãŒãã€ã³ã°ã®ä¹Ÿç¥ã«
䜿çšããã枩床ã¯ã³ãŒãã€ã³ã°äžã«æ³¡ãçããæž©
床ããäœããã®ã§ããã¹ãã§ããããšãç¥ãããŠ
ããã泡圢æã¯æãŸãããªãããã®çç±ã¯äžåºŠåœ¢
æããããšã泡ã¯åŽ©å£ãããŸãã¯ããããã厩å£
ããå Žåã§ãã³ãŒãã€ã³ã°ã¯ç²çš ããããã®ã§ã
ããããŠå±€äžã«äžåäžãªã¹ãããã圢æãããã
ãã§ããããã®çµæãéåžžãã©ã€ã€ãŒã垯åäžã«
é 眮ãããŠãããå垯åäžã®æž©åºŠã¯ã³ãŒãã€ã³ã°
äžã«æ³¡ãåºçŸãããã枩床ããã以äžã®ããå®å š
ããŒãžã³ã§ä¿æãããŠããã 也ç¥é床ã«é¢ãããã®ä»ã®éå®ã¯éåäœæº¶æ¶²ã®
ãã¹ãã³ãªãŒããŒïŒskin overïŒãã®åŸåã§ããã
ç¹ã«åãã®æ®µéã§ã®æ¥éããã也ç¥ã¯ã³ãŒãã€ã³
ã°è¡šé¢ã«ããªã也ç¥ããã¹ãã³ãçæãããçµæ
ãšãªããããããªãããã®ã¹ãã³ã®äžã«ã¯æº¶åªã«
å¯ãã ã³ãŒãã€ã³ã°ããŸã ååšããŠããããããŠ
ãã®ã¹ãã³ã¯äžåºŠä¹Ÿç¥ãããšãã®äžã«ãã溶åªäž
ã«å®¹æã«ã¯å溶解ããªããããªãã¡ãã®ã¹ãã³ã¯
溶åªèžçºã®éå£ãšããŠåãããã®åé¡ã¯ããé ã
也ç¥äŸãã°ããäœã枩床ã空æ°é床ãããé«æ²žç¹
ã®æº¶åªã®æ·»å ãã®ä»ã«ãã軜æžãããããšãã§ã
ããããããªãããé ã也ç¥ã¯äžå±€é ãå éåæ§
ãã€ã«ã ããã³ãšã¬ã¡ã³ã補é ã®çµæãšãªãã äºæãããããšã«ãå éåæ§ã³ãŒãã€ã³ã°çµæ
ç©ã®æº¶è§£ãããéåäœç¶çµåå€ã®äžéšãã³ãŒãã€
ã³ã°æº¶åªã«äžæº¶æ§ã®äº€åçµåéåäœããŒãºã§çœ®æ
ããããšã«ãã€ãŠã也ç¥å éåæ§ãã€ã«ã ããã³
ãšã¬ã¡ã³ããããå¹çãã補é ãããããšãçºèŠ
ãããããã®ãããªãã€ã«ã ããã³ãšã¬ã¡ã³ãã®
å éåæ§å±€ã¯ããéããã«ããããŠããå°ãã泡
圢æå±éºæ§ããã€ãŠä¹Ÿç¥ããã補é æ©èœã®çŸå®ã®
ãµã€ãºã«å¢å€§ã®ãªãå Žåã§ãããããã«ãã€ãŠç
ç£ãå¢å€§ãããããšãã§ããããã®å éåæ§å±€ã¯
亀åçµåéåäœããŒãºã®ååšã«ããããããæãŸ
ããæ§è³ªãä¿æããŠããããšãèŠåºãããããã®
çç±ã¯ããããå¯æº¶æ§éåäœç¶çµåå€ã®å±æçã«
éåžžã«è¿äŒŒããããã«ãã¶ã€ã³ããããããã§ã
ããããŠããã«ãã€ãŠåŸã ã«ããŠç¡æ©äžæº¶æ§å å¡«
å€ã«é¢é£ããå æ£ä¹±ãæå°åã§ããããã§ããã
äŸãã°åçé床ãé ãžã®æ¥çãéææ§ãŸãã¯è§£å
åããã³å éåæ§å±€ã®å¯ææ§ã¯ä¿æãããŠããã æ¬çºæã«ããã°ãæ¬è³ªçã« (a) æå(a)ã(d)ã®ééåºæºã§ïŒã45ééïŒ ã®ãå°
ããšãïŒåã®æ«ç«¯ãšãã¬ã³åºãæãããããé
é¢ã©ãžã«ã«éå§é£é延é·ä»å éåã«ããé«åå
éåäœã圢æãããå°ããšãïŒçš®ã®éã¬ã¹ç¶ãš
ãã¬ã³æ§äžé£œåååç©ã (b) æå(a)ã(d)ã®ééåºæºã§0.05ã10ééïŒ ã®ã
äžé£œåååç©ã®éåãéå§ããã掻æ§ç·æŸå°ã«
ãã掻æ§åå¯èœãªææ©æŸå°æåæ§ãéé¢ã©ãžã«
ã«çæç³»ã (c) å°ãªããšãïŒçš®ã®ææ©éåäœçµåå€ã (d) 0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ãŒãºã®æ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ããã
ãããŠææ©éåäœç¶çµåå€æåã®ããã®æº¶åªã
ãã³éåäœããŒãºã®è£œé ã«äœ¿çšãããåéäœã®
ããã®æº¶åªäžã§äžæº¶æ§ãã€ééå¡åæ§ã§ããã°
ãã°ããªéèšæœ€æ§ã®äº€åçµåããŒãºãããã³ (d) æå(a)ã(b)ããã³(c)ã«å¯Ÿããå°ããšãïŒçš®ã®
æº¶åª ãããªãããããŠæå(a)ã(d)ã®å šééåºæºã®æå
(c)ããã³(d)ã®çµåãç©ã®åèšééïŒ ã40ã70éé
ïŒ ã§ãããæå(d)ãæå(c)ããã³(d)ã®ééåºæºã§
15ã90ééïŒ ã®éã§ååšããŠããå æåæ§ã³ãŒã
ã€ã³ã°çµæç©ãæäŸãããã æ¬çºæã®ä»ã®æ æ§ã«ããã°ãå°ããšãïŒçš®ã®å
å¯æº¶åå¯èœãªç©è³ª(a)ããã³å°ããšãïŒçš®ã®ææ©é
åäœçµåå€(c)ã(a)ããã³(c)æåã®åèšééåºæºã§
æå(a)ããã³(b)ã¯ãããã50ã95ééïŒ ããã³ïŒ
ã50ééïŒ ã§ååšãããã®åå¿çæç©ãçµæç©ã®
åèšééåºæºã§ïŒã10ééïŒ ã®æŽ»æ§ç·æŸå°ã«ãã
掻æ§åããããæŸå°æåæ§ååç©ãŸãã¯ç³»(b)ãã
ãã³0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ã®ããŒãºã®æ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ãã
ãããŠææ©éåäœçµåå€æåã«å¯Ÿãã溶åªããã³
åèšéåäœããŒãºã®è£œé ã«äœ¿çšãããåéäœã«å¯Ÿ
ãã溶åªäžã§äžæº¶æ§ãã€ééå¡åæ§ã§ãããããŠ
çµæç©ã®å šééåºæºã§20ã65ééïŒ éã«ãããã°
ãã°ããªå®è³ªçã«éèšæœ€æ§ã®äº€åçµåããŒãº(d)ã
ãæ¬è³ªçã«ãªã也ç¥ããããžãšããŠåãçµæç©ã®
å¥é¢æ§çµåå±€ãæããæ¯æäœãå å«ããããžãšã
ãŠåãå æåæ§ãšã¬ã¡ã³ããæäŸãããã æ¬çºæã®å éåæ§ã³ãŒãã€ã³ã°çµæç©ã¯ãå°ã
ãšãïŒåã®æ«ç«¯ãšãã¬ã³åºãå«æããå°ããšãïŒ
çš®ã®éã¬ã¹ç¶ãšãã¬ã³æ§äžé£œåååç©(a)ãææ©æŸ
å°æåæ§éé¢ã©ãžã«ã«çææ§å éå§å€ãŸãã¯å é
å§å€ç³»(b)ãå°ããšãïŒçš®ã®ææ©éåäœç¶çµåå€
(c)ãå éåæ§ã³ãŒãã€ã³ã°äžã«ååšããéåäœç¶
çµåå€æåã®äžéšã眮æããã°ãã°ããªå®è³ªçã«
éèšæœ€æ§ã®äº€åçµåéåäœããŒãº(d)ãããã³åèš
æå(a)ã(b)ããã³(c)ã«å¯Ÿãã溶åª(e)ããæ¬è³ªçã«
ãªã€ãŠããããã®å éåæ§çµæç©äžã«ã¯å°éã®ã
ã®ä»ã®æåäŸãã°ææãç±éåé»å®³å€ãæ¥çä¿é²
å€ãå¯å¡å€ã埮现åå²ç²åãªã©ãååšãããããš
ãã§ããããã®å éåæ§çµæç©ã¯ãããã®åºæ¬ç
æ§è³ªãä¿æããŠãããäŸãã°å±€ã®åœ¢æ ã®å éåæ§
çµæç©ã¯å°ããšã200ïŒ ã奜ãŸããã¯å°ããšã300
ïŒ ã®ç Žæç¹äŒžé·ãæããŠãããããžãšããŠåãã³
ãŒãã€ã³ã°çµæç©äžã«ãããŠã¯ããšãã¬ã³æ§äžé£œ
åååç©(a)ã¯ææ©éåäœç¶çµåå€æå(c)ãšåå¿ã
ãå°ããšãïŒçš®ã®å å¯æº¶åå¯èœãŸãã¯å æžæå¯èœ
ãªç©è³ªã«ãã眮æããããå Žåã«ãããæŸå°æå
æ§ååç©ãŸãã¯ç³»(d)ã¯ã°ãã°ããªå®è³ªçã«éèšæœ€
æ§ã®äº€åçµåéåäœããŒãº(b)ãšäžç·ã«ååšããã
ããšãã§ããããã®ã³ãŒãã€ã³ã°çµæç©ã¯ãŸãæ
å(a)ã(b)ããã³(c)ã«å¯Ÿããå°ããšãïŒçš®ã®æº¶åª(e)
ãå«æããã åèšã®ããã«ãã®å éåæ§çµæç©ã¯å°ããšãïŒ
åã®éåæ§ãšãã¬ã³åºãå«æããå°ããšãïŒçš®ã®
ä»å éåæ§ãšãã¬ã³æ§äžé£œåååç©(a)ãå«æããŠ
ããããã®ãããªååç©ã¯éé¢ã©ãžã«ã«éå§ãã
ãé£é延é·æ§ä»å éåã«ãã€ãŠé«ååéåäœã圢
æãããã奜ãŸããã¯ãã®äžé£œåååç©ïŒãŸãå
éäœååç©ãšããŠãç¥ãããŠããïŒã¯å°ããšãïŒ
åäŸãã°ïŒãïŒåã®æ«ç«¯ãšãã¬ã³æ§äžé£œååºãå«
æããŠããããã®åéäœååç©ã¯éã¬ã¹ç¶ã§ã
ããããªãã¡20âããã³å€§æ°å§ã§ã¯ããã¯100â
以äžã®éåžžã®æ²žç¹ããã³ææ©éåäœç¶çµåå€ã«å¯Ÿ
ããŠå¯å¡åäœçšãæããŠããã åç¬ã§ããŸãã¯ä»ã®åéäœãšã®çµåãã§äœ¿çšã§
ããé©åœãªäžé£œååéäœååç©ãšããŠã¯ã第ïŒçŽ
ããã«ã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãã1.5
âãã³ã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿
ã¯ãªã¬ãŒããïŒïŒ®âãžãšãã«ã¢ãããšãã«ã¢ã¯
ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãããšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
1.4âãã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡
ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãããããµã¡ãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ãã³ãžã¡ã¿ã¯ãªã¬ãŒãããã«ã¡ãã¬ã³ã°ãªã³ãŒã«
ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒ
âã·ã¯ããããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³
ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãžã¡ãããŒã«ããã
ã³ãžã¢ã¯ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒããã°ãªã»
ããŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³
ãžã¡ã¿ã¯ãªã¬ãŒããã°ãªã»ããŒã«ããªã¢ã¯ãªã¬ãŒ
ãããã³ããªã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ã
ããã³ããªã¢ã¯ãªã¬ãŒãããã³ããªã¡ã¿ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒããã
ã³ããªã¡ã¿ã¯ãªã¬ãŒããããªãªãã·ãšãã«åããª
ã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãããã³ããª
ã¡ã¿ã¯ãªã¬ãŒããããã³ç±³åœç¹èš±ç¬¬3380831å·æ
现æžã«é瀺ãããåæ§ãªååç©ãïŒïŒïŒâãžïŒïœ
âããããã·ããšãã«ïŒãããã³ãžã¢ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯ãªã¬ãŒãã
ãã³ããã©ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãžïŒïœâã
ãããã·ããšãã«ïŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããªãª
ãã·ãšãã«âïŒïŒïŒâãžïŒïœâããããã·ããšã
ã«ïŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãããã¹ããšããŒã«
ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâããããã·
ãããã«ïŒãšãŒãã«ããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒ
âã¡ã¿ã¯ãªã«ãªãã·ãšãã«ïŒãšãŒãã«ããã¹ããš
ããŒã«ïŒ¡ã®ãžïŒïŒâã¢ã¯ãªã«ãªãã·âïŒâããã
ãã·ãããã«ïŒãšãŒãã«ããã¹ããšããŒã«ïŒ¡ã®ãž
ïŒïŒâã¢ã¯ãªã«ãªãã·ãšãã«ïŒãšãŒãã«ãããã©
ã¯ãããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãª
ãã·âïŒâããããã·ãããã«ïŒãšãŒãã«ããã
ã©ã¯ãããã¹ããšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«
ãªãã·ãšãã«ïŒãšãŒãã«ãããã©ããã¢ãã¹ããš
ããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·âïŒâãã
ããã·ãããã«ïŒãšãŒãã«ãããã©ããã¢ãã¹ã
ãšããŒã«ïŒ¡ã®ãžïŒïŒâã¡ã¿ã¯ãªã«ãªãã·ãšãã«ïŒ
ãšãŒãã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ã®ãžïŒïŒâã¡
ã¿ã¯ãªã«ãªãã·ïŒâããããã·ãããã«ïŒãšãŒã
ã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ããªãªãã·ãããã«ããªã¡ãããŒã«ãããã³ããª
ã¢ã¯ãªã¬ãŒããããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒ
ãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâãã¿ã³
ããªãªãŒã«ããªã¢ã¯ãªã¬ãŒãããã³ããªã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâãã³
ã¿ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬
ãŒããïŒâããšãã«ãšãã¬ã³âïŒïŒïŒâãžã¡ã¿ã¯
ãªã¬ãŒãããžã¢ãªã«ããã¬ãŒããã¹ãã¬ã³ãïŒïŒ
ïŒâãã³ãŒãžãªãŒã«ãžãŠã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒ
âãžã€ãœããããã«ãã³ãŒã³ããã³ïŒïŒïŒïŒïŒâ
ããªã€ãœããããã«ãã³ãŒã³ããããããããŸã
å°ããšã300ã®ååéãæãããšãã¬ã³æ§äžé£œå
ååç©äŸãã°ïŒã15åã®ççŽ ååãå«æããã¢ã«
ãã¬ã³ã°ãªã³ãŒã«ãŸãã¯ïŒã10åã®ãšãŒãã«çµå
ãå«æãããã€ã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ã
ã補é ãããã¢ã«ãã¬ã³ãŸãã¯ããªã¢ã«ãã¬ã³ã°
ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ç±³åœç¹èš±ç¬¬
2927022å·æ现æžã«é瀺ã®ãã®äŸãã°ç¹ã«æ«ç«¯çµ
åãšããŠååšããå Žåã®è€æ°ã®ä»å éåæ§ãšãã¬
ã³çµåãæãããã®ããŸãæçšã§ããããã®ãã
ãªçµåã®å°ããšãïŒåãããŠå¥œãŸããã¯ã»ãšãã©
ãççŽ ããã³çªçŽ ãé žçŽ ããã³ç¡«é»ã®ãããªãã
ãååãšã®ççŽ äºéçµåãå«ãäºéçµåççŽ ã«å ±
圹ããŠãããã®ã奜ãŸãããé¡èãªãã®ã¯ãšãã¬
ã³æ§äžé£œååºãç¹ã«ãããªãã³åºããšã¹ãã«ãŸã
ã¯ã¢ããæ§é ã«å ±åœ¹ããŠãããããªç©è³ªã§ããã
äžé£œååéäœæåã¯ä¹Ÿç¥å éåæ§å±€ã®å šééåºæº
ã§ïŒã45ééïŒ ã§ååšããããããã 掻æ§å ç·ã«ãã掻æ§åå¯èœã§ãããããŠ185â
ããã³ãã以äžã®æž©åºŠã§ã¯ç±çã«äžæŽ»æ§ãªå¥œãŸã
ãéé¢ã©ãžã«ã«çææ§ä»å éåéå§å€(b)ãšããŠã¯
å ±åœ¹ççŽ ç°ç³»äžã«ïŒåã®ç°å ã«ã«ããã«åºãæã
ã眮æãŸãã¯é眮æã®å€æ žããã³äŸãã°ïŒïŒ10â
ã¢ã³ãã©ããã³ãïŒâã¯ããã¢ã³ãã©ããã³ãïŒ
âã¯ããã¢ã³ãã©ããã³ãïŒã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒâãšãã«ã¢ã³ãã©ããã³ãïŒâ第ïŒçŽãã
ã«ã¢ã³ãã©ããã³ããªã¯ã¿ã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒïŒïŒâãããããã³ãïŒïŒ10âããšãã³ã
ã¬ã³ããã³ããã³ãº(a)âã¢ã³ãã©ã»ã³âïŒïŒ12â
ãžãªã³ãïŒïŒïŒâããã¿ã»ã³âïŒïŒ12âãžãªã³ã
ïŒâã¡ãã«âïŒïŒïŒâãããããã³ãïŒïŒïŒâãž
ã¯ãããããããã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©
ããã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©ããã³ãïŒâ
ããšãã«ã¢ã³ãã©ããã³ãïŒïŒïŒâãžããšãã«ã¢
ã³ãã©ããã³ãã¢ã³ãã©ããã³Î±âã¹ã«ãã³é žãŸ
ãã¯Î²âã¹ã«ãã³é žã®ãããªãŠã å¡©ãïŒâã¯ãã
âïŒâã¡ãã«ã¢ã³ãã©ããã³ãã¬ãã³ããã³ã
ïŒïŒïŒïŒïŒïŒ10âããã©ãããããã¿ã»ã³âïŒïŒ
12âãžãªã³ããã³ïŒïŒïŒïŒïŒïŒïŒâããã©ããã
ãã³ãº(a)ã¢ã³ãã©ã»ã³âïŒïŒ12âãžãªã³ãããã
ãããããã®ãããã®ã¯85âçšåºŠã®äœæž©åºŠã§ç±ç
ã«æŽ»æ§ã§ããã«ããŠããããŸãæçšãªãã®ä»ã®å
éå§å€ã¯ç±³åœç¹èš±ç¬¬2760863å·æ现æžã«èšèŒãã
ãŠãããããããšããŠã¯ãã·ãã«ã±ãã¢ã«ããã«
ã¢ã«ã³ãŒã«äŸãã°ãã³ãŸã€ã³ããããã€ã³ãã¢ã·
ãã€ã³ãšãŒãã«äŸãã°ãã³ãŸã€ã³ã¡ãã«ããã³ãš
ãã«ãšãŒãã«ãαâã¡ãã«ãã³ãŸã€ã³ãαâã¢ãª
ã«ãã³ãŸã€ã³ããã³Î±âããšãã«ãã³ãŸã€ã³ãå«
ãαâçåæ°ŽçŽ çœ®æè³éŠæã¢ã·ãã€ã³ããããã
ããç±³åœç¹èš±ç¬¬2850445å·ãå第2875047å·ãå第
3097096å·ãå第3074974å·ãå第3097097å·ãã
ã³å第3145104å·åæ现æžã«é瀺ãããå éå æ§
ææããã³éå å€ãªãã³ã«ããšããžã³ããªããµãž
ã³ããã³ããã³çŸ€ã®ææãããã©ãŒã®ã±ãã³ãã
ã³ãŸããšãã³ãïŒïŒïŒïŒïŒâããªããšãã«ã€ãã
ãŸãªã«äºéäœããã³ãã€ã³ææãå«ãæ°ŽçŽ ãããŒ
ãšã®çµåããããã³ãããã®æ··åç©ç±³åœç¹èš±ç¬¬
3427161å·ãå第3479185å·ããã³å第3549367å·
åæ现æžåç §ãéå§å€ãšããŠäœ¿çšã§ããããŸãç±³
åœç¹èš±ç¬¬4162162å·æ现æžã«é瀺ã®å¢æå€ããŸã
å éå§å€ããã³å é»å®³å€ã«é¢ããŠæçšã§ãããã
ã®å éå§å€ãŸãã¯éå§å€ç³»ã¯ä¹Ÿç¥å éåæ§å±€ã®å š
ééåºæºã§0.05ã10ééïŒ éã§ååšããã ãã®å éåæ§çµæç©ã¯å°ããšãïŒçš®ã®ææ©éå
äœç¶çµåå€(c)äŸãã°ããªã¢ã¯ãªã¬ãŒãããã³Î±â
ã¢ã«ãã«ããªã¢ã¯ãªã¬ãŒããšã¹ãã«äŸãã°0.5ã
3.0ã®ç¯å²ã®åºæç²åºŠãæããããªã¡ãã«ã¡ã¿ã¯
ãªã¬ãŒãããã³ããªãšãã«ã¡ã¿ã¯ãªã¬ãŒããããª
ããã«ãšã¹ãã«äŸãã°ããªããã«ã¢ã»ããŒããã
ãªããã«ã¢ã»ããŒãïŒã¢ã¯ãªã¬ãŒããããªããã«
ã¢ã»ããŒãïŒã¡ã¿ã¯ãªã¬ãŒãããã³æ°Žè§£ããªãã
ã«ã¢ã»ããŒãããšãã¬ã³ïŒããã«ã¢ã»ããŒãå ±é
åäœãããªã¹ãã¬ã³éåäœããã³äŸãã°ãã¬ã€ã³
é žç¡æ°Žç©ããã³ãšã¹ãã«ãšã®å ±éåäœããããªã
ã³ã¯ããªãå ±éåäœäŸãã°ãããªãã³ã¯ããªãïŒ
ã¢ã¯ãªããããªã«ããããªãã³ã¯ããªãïŒã¡ã¿ã¯
ãªã¬ãŒãããã³ãããªãã³ã¯ããªãïŒããã«ã¢ã»
ããŒãå ±éåäœãããªå¡©åããã«ããã³å ±éåäœ
äŸãã°ããªå¡©åããã«ïŒã¢ã»ããŒãã飜åããã³
äžé£œåããªãŠã¬ã¿ã³ãåæãŽã äŸãã°ãã¿ãžãš
ã³ïŒã¢ã¯ãªããããªã«ãã¢ã¯ãªããããªã«ïŒãã¿
ãžãšã³ïŒã¹ãã¬ã³ãã¡ã¿ã¯ãªã¬ãŒãïŒã¢ã¯ãªãã
ããªã«ïŒãã¿ãžãšã³ïŒã¹ããšã³å ±éåäœãïŒâã¯
ãããã¿ãžãšã³âïŒïŒïŒéåäœãå¡©çŽ åãŽã ãã
ãã³ã¹ãã¬ã³ïŒãã¿ãžãšã³ïŒã¹ãã¬ã³ãã¹ãã¬
ã³ïŒã€ãœãã¬ã³ïŒã¹ãã¬ã³ãããã¯å ±éåäœãçŽ
ïŒïŒ000ãïŒïŒ000ïŒ000ã®æ°å¹³åååéãæãã
ããªã°ãªã³ãŒã«ã®é«ååéããªãšãã¬ã³ãªãã·
ãããšããã·ãäŸãã°ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯
ãªã¬ãŒãåºãå«æãããšããã·ããã³ããªãšã¹ã
ã«äŸãã°åŒHOïŒCH2ïŒoâOHïŒåŒäžïœã¯ïŒã10ã®
å šæ°ã§ããïŒã®ããªã¡ãã¬ã³ã°ãªã³ãŒã«ãš(1)ãã
ãµããããã¬ãã¿ã«é žãã»ãã·ã³é žããã³ãã¬ã
ã¿ã«é žã(2)ãã¬ãã¿ã«é žãã€ãœãã¿ã«é žããã³ã»
ãã·ã³é žã(3)ãã¬ãã¿ã«é žããã³ã»ãã·ã³é žã(4)
ãã¬ãã¿ã«é žããã³ã€ãœãã¿ã«é žãšã®åå¿çæç©
ãã補é ããããã®ãããã³(5)åèšã°ãªã³ãŒã«ãš
ïŒïŒãã¬ãã¿ã«é žãã€ãœãã¿ã«é žããã³ã»ãã·
ã³é žããã³ïŒïŒãã¬ãã¿ã«é žãã€ãœãã¿ã«é žã
ã»ãã·ã³é žããã³ã¢ãžãã³é žãã補é ãããã³ã
ãªãšã¹ãã«æ··åç©ããã€ãã³ãŸãã¯ããªã¢ããäŸ
ãã°ïŒ®âã¡ããã·ã¡ãã«ããªãããµã¡ãã¬ã³ã¢ãž
ããããã»ã«ããŒã¹ãšã¹ãã«äŸãã°ã»ã«ããŒã¹ã¢
ã»ããŒããã»ã«ããŒã¹ã¢ã»ããŒããµã¯ã·ããŒãã
ãã³ã»ã«ããŒã¹ã¢ã»ããŒãããã¬ãŒããã»ã«ããŒ
ã¹ãšãŒãã«äŸãã°ã¡ãã«ã»ã«ããŒã¹ããšãã«ã»ã«
ããŒã¹ããã³ãã³ãžã«ã»ã«ããŒã¹ãããªã«ãŒãã
ãŒããããªããã«ã¢ã»ã¿ãŒã«äŸãã°ããªããã«ã
ãã©ãŒã«ãããªããã«ãã«ãã«ãããªãã«ã ã¢ã«
ãããããããããã ãã®çµåå€ã¯æ°Žæ§çŸå液äžã§çµæç©ãåŠçå¯èœ
ãšããã«å åãªé žæ§ãŸãã¯ãã®ä»ã®åºãå«æãã
ããæçšãªæ°Žæ§åŠçå¯èœãªçµåå€ãšããŠã¯ç±³åœç¹
蚱第3458311å·ããã³ç±³åœç¹èš±ç¬¬1507704å·åæ现
æžã«é瀺ã®ãã®ãããããããæçšãªäž¡æ§éåäœ
ãšããŠã¯ãâã¢ã«ãã«ã¢ã¯ãªã«ã¢ãããŸãã¯ã¡
ã¿ã¯ãªã«ã¢ãããé žæ§ãã€ã«ã 圢ææ§å ±åéäœã
ãã³ã¢ã«ãã«ãŸãã¯ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬
ãŒãããå°ãããå ±éåäœäŸãã°ç±³åœç¹èš±ç¬¬
3927199å·æ现æžã«é瀺ã®ãã®ãããããããã
ããç±³åœç¹èš±æ现æžã¯ããã«åç §ãšããŠå å«ãã
ããéåäœç¶çµåå€ïŒããã³ååšãããã®ä»ã®é
åäœïŒã®æ°å¹³åååéïŒïœïŒã¯ããªãã¿ãžãšã³
æšæºãŸãã¯ãã®ä»ã®åœæ¥è ã«ã¯æ¢ç¥ã®æšæºã䜿çš
ããŠã²ã«ééã¯ãããã°ã©ãã€ãŒã«ãã枬å®ãã
ãã ãã®å éåæ§çµæç©äžã«ã¯0.02ã4.0ÎŒïœå¥œãŸã
ãã¯0.1ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ã®ããŒãºæ°ã®å°ããšã90ïŒ ã10ÎŒïœä»¥äžã§ããã
ããäžèšã®æº¶åªãªãã³ã«éåäœããŒãºã®è£œé ã«äœ¿
çšãããåéäœã®ããã®æº¶åªäžã§äžæº¶æ§ãã€éé
å¡åæ§ã§ããã°ãã°ãã®å®è³ªçã«éèšæœ€æ§ã®äº€å
çµåéåäœããŒãº(d)ãååšããããããããã®äº€
åçµåéåäœããŒãºã¯ïŒåååœãïŒåãŸãã¯ãã
以äžã®éé¢ã©ãžã«ã«éåæ§äºéçµåãå«æããå
éäœã®ãã¢éåäœãŸãã¯å ±éåäœã§ããããã奜
ãŸãã亀åçµåéèšæœ€æ§éåäœããŒãºã¯ããªãã
ã³ããã©ã¢ã¯ãªã¬ãŒãããã³ããªããã³ããã©ã¡
ã¿ã¯ãªã¬ãŒãåéäœã®ãã¢éåäœãåèšããªãã
ã³ããã©ã¢ã¯ãªã¬ãŒãããã³ããªããã³ããã©ã¡
ã¿ã¯ãªã¬ãŒãåéäœã®å ±éåäœãå°ããšãïŒçš®ã®
åèšããªããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯åèšã
ãªããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãåéäœã®ïŒåã®æ«
端ãšãã¬ã³åºãå«æããå°ããšãïŒçš®ã®åéäœ25
ééïŒ ãŸã§ã®å ±éåäœãå°ããšãïŒçš®ã®åèšããª
ããã³ããã©ã¢ã¯ãªã¬ãŒããŸãã¯åèšããªããã³
ããã©ã¡ã¿ã¯ãªã¬ãŒãåéäœãšïŒåã®æ«ç«¯ãšãã¬
ã³åºãŸãã¯ïŒåã®æ«ç«¯ãšãã¬ã³åºãå«æããå°ã
ãšãïŒçš®ã®åèšããªã¢ã¯ãªã¬ãŒããŸãã¯ããªã¡ã¿
ã¯ãªã¬ãŒãåéäœãšã¯å¥ã®åéäœ75ééïŒ ãŸã§ã®
å ±éåäœãããªã矀ããéžã°ããããã®äº€åçµå
ããŒãºãææéã®ã³ãŒãã€ã³ã°æº¶åªãåžåããå Ž
åã«ã¯æ¥é也ç¥å¹æã¯å€±ãããããã®çç±ã¯ããŒ
ãºãããããŠåŸã€ãŠããŒãºå«æçµæç©ãã溶åªã
é€å»ããã®ã«äžå±€é·ãæéããããããã§ããã
åŸã€ãŠãã®ããŒãºã溶åªã«ããå®è³ªçã«éèšæœ€æ§
ã§ããããšãæ¬çºæã«ãšã€ãŠæ¬è³ªçã§ããã奜ãŸ
ãã亀åçµåãããéèšæœ€æ§éåäœããŒãºã®è£œé
ããã³å¯èœæ§ããããŒãºèšæœ€è©Šéšã¯ç±³åœç¹èš±åºé¡
第370992å·æ现æžã«èšèŒãããŠããããŸããã®è¡š
é¢ãå æ°Žå解ããã亀åçµåéåäœããŒãºããŸã
æçšã§ãããããã¯ãšã¹ãã«çµåå«æéåäœããŒ
ãºãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠã ãŸãã¯ã
ã®ä»ã®ã¢ã«ã«ãªæ§è©Šè¬ã§åŠçããããšã«ãã€ãŠé
æããããšãã§ããã ãã®ä»ã®æçšãªäº€åçµåãããéåäœããŒãºãš
ããŠã¯ãžããããã·ååç©äŸãã°ãžãšãã¬ã³ã°ãª
ã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãããã©ã¡ãã¬
ã³ã°ãªã³ãŒã«ããã¹ããšããŒã«ïŒ¡ãã®ä»ã®ãžã¢ã¯
ãªã¬ãŒãããã³ãžã¡ã¿ã¯ãªã¬ãŒãã®éåäœããã³
å ±éåäœäŸãã°ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿
ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢ã¯ãª
ã¬ãŒãïŒã¹ãã¬ã³ïŒ25ïŒ ãŸã§ïŒãããªã¡ãããŒã«
ãããã³ããªã¢ã¯ãªã¬ãŒãïŒ25ã10ïŒïŒããªãšã
ã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ75ã90ïŒãããª
ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒãïŒ25ïŒ ãŸã§ïŒãããã©ãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
ïŒ25ïŒ ãŸã§ïŒããžããã«ãã³ãŒã³ãïŒïŒïŒïŒïŒâã
ãªããã«ãã³ãŒã³ãããªã¢ã¯ãªã«ãªãã·ã·ã¢ãã¬
ãŒããããªã¢ãªã«ã·ã¢ãã¬ãŒããããªã¢ã¯ãªã«ãª
ãã·ãã³ãŒã³äŸãã°ãããã°ã«ã·ãã«ããªã¢ã¯ãª
ã¬ãŒããããã³ããªããããã·ååç©äŸãã°ãã³
ãããŒã«ãã€ãã·ããŒã«ããã³èç³ãã®ä»ã®ã¢ã¯
ãªã¬ãŒãããã³ã¡ã¿ã¯ãªã¬ãŒãããå°ãããéå
äœããããããã æå(a)ã(d)ã®åèšééåºæºãšææ©éåäœç¶çµå
å€(c)ãšäº€åçµåããŒãº(d)ãšã®çµåãã®åèšééïŒ
ã¯40ã70ééïŒ ã§ããã亀åçµåããŒãº(d)ã¯æå
(c)ããã³(d)ã®åèšééåºæºã§15ã90ééïŒ ã®éã§
ååšãããã以äžã®å¯Ÿç §äŸïŒã«èšèŒã®ããã«ææ©
éåäœç¶çµåå€ã®ååéã¯ååšããããã亀åçµ
åããŒãºéã«é¢ä¿ãæããŠããã亀åçµåããŒãº
(d)ã®å¥œãŸããééïŒ ã¯çµåå€æå(c)ã®ååéã«äŸ
åãããäŸãã°çµåå€äž»æåã40000ãŸã§ã®æ°å¹³
åååéãæããŠããå Žåã«ã¯15ã40ééïŒ éã®
ããŒãºãæçšã§ãããçµåå€äž»æåã100000000
以äžã®æ°å¹³åååéïŒé«ååéçµåå€ïŒãæããŠ
ããå Žåã«ã¯30ã90ééïŒ ã®ããŒãºãæçšã§ã
ãã å éåæ§çµæç©ã®è£œé ã«ãããŠã¯ãææ©éåäœ
ç¶çµåå€ã«å¯Ÿãã溶åªãŸãã¯æº¶åªæ··åç©(c)ãååš
ãããããæçšãªæº¶åªãšããŠã¯ã¡ãã¬ã³ã¯ããª
ããïŒâãšããã·ãšã¿ããŒã«ãã¡ã¿ããŒã«ãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³ãïŒïŒïŒâããªã¯ãã
ãšã¿ã³ãã¡ãã«ã€ãœããã«ã±ãã³ãã®ä»ãŸãã¯ã
ãã溶åªã®çµåãããããããã溶åªã¯å éåæ§
çµæç©ã®è£œé ã®ããã«äœ¿çšãããæåã®ééåºæº
ã§45ã95ééïŒ éã§ååšããã溶åªã¯åœæ¥è ã«ã¯
åšç¥ã®ããã«äŸãã°ç±é¢šãã©ã€ã€ãŒã䜿çšããŠä¹Ÿ
ç¥ãããããšã«ããé€å»ãããã åèšã®å éåæ§çµæç©ã®äž»èŠãªæåã«å ããŠã
å°éã®æ¬¡ã®æåããŸãå Žåã«ããååšãããããš
ãã§ãããçš®ã ã®çè²å€äŸãã°ææããã³é¡æã
å ããŠåã®å¯èŠæ§ãäžæãããããšãã§ãããå
æåæ§ææåé§äœãå å«ãããŠé²å ããããå Žå
ã«å¯èŠåãçæãããããšãã§ãããããããªã
ã䜿çšããããã¹ãŠã®çè²å€ã¯å¥œãŸããã¯äœ¿çšã
ãã掻æ§ç·æŸå°ã«å¯ŸããŠéæã§ããã¹ãã§ããã
é¡æããŸãç¬ç«ãªå®è³ªçã«éèšæœ€æ§ã®äº€åçµåã
ãŒãºäžã«å å«ãããããšãã§ããããããããŒãº
ã¯é¡æãå ååŠç³»ãšã®ååŠççžäºäœçšããåé¢ã
ãã ååšããããã奜ãŸããç±éåé»å®³å€ãšããŠã¯
ïœâã¡ããã·ããšããŒã«ããããããã³ããã³ã¢
ã«ãã«ããã³ã¢ãªãŒã«çœ®æãããããã³ããã³ã
ãã³ã第ïŒçŽããã«ã«ãã³ãŒã«ãããã¬ããŒã«ã
é ã¬ãžããŒãïŒæš¹èé žé ïŒããããã«ã¢ãã³ãβ
âããããŒã«ãå¡©å第ïŒé ãïŒïŒïŒâãžç¬¬ïŒçŽã
ãã«ïœâã¯ã¬ãŸãŒã«ãããšããã¢ãã³ãããªãž
ã³ãããããã³ãŒã³ããã³ãžããããã³ãŒã³ãïœ
âãã«ããã³ããã³ã¯ãã©ãã«ããã³ç±³åœç¹èš±ç¬¬
4168982å·æ现æžã«é瀺ã®ããããœçµæç©ããã
ãããã䜿çšãããå Žåã®é»å®³å€ã¯å éåæ§çµæ
ç©ã®0.001ã2.0ééïŒ éã§ååšããã å éåæ§çµæç©ã«ãããŠã¯ãæ¥çä¿é²å€ããŸã
æçšã§ããããã®ãããªæ¥çä¿é²å€ã®äŸãšããŠã¯
å°éã®åŒ ïŒåŒäžïŒ²ã¯ãªã«ãè³éŠæçåæ°ŽçŽ æ žäŸãã°ãã³ãŒ
ã³ãŸãã¯ããã¿ã¬ã³ã§ãããã¯CH2ãNHã
ãããŸãã¯Seã§ãããã¯ïŒ®ãŸãã¯ïŒ£â
ã§ãããã¯ïŒšãNH2ãïŒãïŒåã®ççŽ ååã
å«æããã¢ã«ãã«ãŸãã¯ããã²ã³äŸãã°ClãŸãã¯
Brã§ããïŒã®çªçŽ å«æååç©ããããããã奜
ãŸããååç©ã¯ãã³ãŸããªã¢ãŸãŒã«ã§ããã䜿çš
ãããå Žåãæ¥çä¿é²å€ã¯å éåæ§çµæç©ã®åé
äœããã³çµåå€ã®å°ããšã0.001ééïŒ éã§ååš
ããããããé©åœãªååç©ã¯ããã«åç §ãšããŠå
å«ãããŠããç±³åœç¹èš±ç¬¬3622334å·æ现æžäžã«é
瀺ãããŠããã å éåæ§çµæç©ãšçžå®¹æ§ã®ïŒçš®ãŸãã¯ãã以äž
ã®å¯å¡å€ããã®äžã«ååšãããŠä¹Ÿç¥ãã€ã«ã ã®éž
æççŸåæ§ãå¯èœãªãããã匟æ§ãæ¹åãããã
ãã¯ãã®ç©å±€æž©åºŠãäœäžãããããšãã§ãããå¯
å¡å€ã®äŸãšããŠã¯ãžã¢ã«ãã«ãã¿ã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãã¢ã«ãã«ãã¹ããšãŒããã®ä»
ããããããã ææã«ããå éåæ§çµæç©ã«ã¯0.1ã2.0ÎŒïœç¯
å²ã®ç²åãµã€ãºãæããããŠå éåæ§çµæç©ã®å±€
ã«é²å ã«äœ¿çšãããæ³¢é·ã§ã¯æ¬è³ªçã«éæãªãã
ãŠæŽ»æ§ç·æŸå°ãæ£ä¹±ãããªãéæ··åæ§ç¡æ©å å¡«å€
ãŸãã¯è£åŒ·å€äŸãã°èŠªææ©æ§ã·ãªã«ãã·ãªã«ãç²
æ«ã¬ã©ã¹ãã®ä»ãå å«ãããããšãã§ããããã®
ãããªç©è³ªã¯å éåæ§çµæç©ã®ææã®æ§è³ªã«å¿ã
ãŠå€åããéã§äœ¿çšãããããã®å å¡«å€ã¯å éå
æ§å±€ã®åŒ·åºŠããã³ãããã®æ¹åã«æçšã§ããã åè¿°ããããã«ã亀åçµåããŒãºãå«æããã
ãžãšããŠåãå æåæ§ã³ãŒãã€ã³ã°çµæç©ã¯ã(a)
ç±³åœç¹èš±ç¬¬3837860å·æ现æžèšèŒã®ããã«ããŠè£œ
é ãããæžåãžã¢ãŸããã³åºå«æå å¯æº¶åæ§éå
äœã(b)ç±³åœç¹èš±ç¬¬3778270å·æ现æžèšèŒã®ããã«
æžåããããã·ã«ãŸãã¯ã¢ããåºãæããéåäœ
ãšãã¹ã¢ãŸããŠã å¡©ãæ··åããããšã«ãã補é ã
ããå æžææ§éåäœãããã³(c)ç±³åœç¹èš±ç¬¬
4271260å·æ现æžã«èšèŒã®ãããªãžãããããªãž
ã³ãïŒæåãšããŠå«æããå æåæ§çµæç©ã䜿çš
ããŠè£œé ãããããããç±³åœç¹èš±æ现æžã¯ããã«
åç §ãšããŠå å«ãããŠãããå 溶解æ§ããã³å æž
ææ§ã¬ãžã¹ãçµæç©ã¯ããã«åç §ãšããŠå å«ãã
ãŠããç±³åœç¹èš±ç¬¬4193797å·æ现æžç¬¬ïŒæ¬ç¬¬19è¡
ã第ïŒæ¬ç¬¬68è¡ã«é瀺ãããŠããã 亀åçµåããŒãºãå«æããå éåæ§ã³ãŒãã€ã³
ã°çµæç©ã¯æ¬¡ã®ããã«ããŠè£œé ããããšãã§ã
ããããŒãºãäžç床åªæã§æº¶åªã®äžéšã«åæ£ãã
ããã«ãã€ãŠååšããããã¹ãŠã®ãããç²åéå¡
ããããã次ãã§ãã®åæ£æ¶²ãæ®äœã®æº¶åªãšå
ãããããŠåèšããã³äžèšã®å®æœäŸã«èšèŒã®ãã®
ä»ã®æåãæ¹æãã€ã€å ããã䜿çšããã溶åªã®
éã¯ããçšåºŠã¯å éåæ§ã³ãŒãã€ã³ã°çµæç©ã®ã³
ãŒãã€ã³ã°æ³ã«äŸåããã äŸãã°åè¿°ã®ããã«ããŠããŸãã¯ãã®ä»ã®æ¹æ³
ã§è£œé ãããå éåæ§ã³ãŒãã€ã³ã°çµæç©ãäŸã
ã°10ÎŒïœã®åãµã€ãºã®ã€ã³ã©ã€ã³ïŒinâlineïŒã
ã€ã«ã¿ãŒãéãããšã«ãã€ãŠéãããéãã
溶液ãã³ãŒãã€ã³ã°è£ 眮äŸãã°ã³ãŒãã€ã³ã°éé
èŠå¶ã®ããã®ãšã¢ãã€ããä»ãããã®ã§ãããã
ã¹ãã ã³ãŒã¿ãŒãæŒåºããã€ãã°ã©ãã¢ããŒã«ã
ã¯ã€ã€å·»ãããããŸãã¯åœæ¥è ã«ã¯æ¢ç¥ã®ãã®ä»
ã®ã³ãŒãã€ã³ã°æ段ã«ãã³ãã§çµŠéããããšãã§
ããããã®å éåæ§ã³ãŒãã€ã³ã°çµæç©ã¯é©åœãª
幟äœåŠçé¢ä¿ã§ã³ãŒãã€ã³ã°ãŠããããééãã
ãã€ã«ã ã®ç§»åãŠãšãã«åäžã«é©çšããããšãã§
ãããã³ãŒãã€ã³ã°ããããŠãšãã¯é垞匷å¶ãã©
ããå ç±ç©ºæ°äŸçµŠãä»ãããã©ã€ã€ãŒäžã«éã
ããããã§ã¯ç©ºæ°é床ãæ¹åããã³æž©åºŠã¯ã³ãŒã
ã€ã³ã°äžã®æº¶åªãé€å»ããããã«å¶åŸ¡ãããŠã
ãããã®ä¹Ÿç¥ãŠãšããäŸãã°é©åœãªããŒã«äžã«å·»
ãåããå·»ãåãã®éã«ããŒã·ãŒãã也ç¥å éå
æ§è¡šé¢ã«ç©å±€ãããããšãã§ãããåœæ¥è ã«æ¢ç¥
ã®ãã®ä»ã®æ¹æ³ã䜿çšããŠä¹Ÿç¥å éåæ§ãã€ã«ã
ã補é ã§ããã åè¿°ããããã«ä¹Ÿç¥ãã€ã«ã ããã¬ãžã¹ããšã¬
ã¡ã³ãã®è£œé ã«ãããŠã¯ãå¥é¢æ§æ¯æäœäžã®åç
ææ§å éåæ§åºå±€ã奜ãŸããã¯äœ¿çšããããæ¯æ
äœã€ãå éåæ§åºå±€ã®æ®ãã®è¡šé¢ã¯é€å»å¯èœãªã«
ããŒã·ãŒãã§ä¿è·ããããšãã§ããããããã¯ãŸ
ããšã¬ã¡ã³ããããŒã«åœ¢æ ã§ä¿åãããŠããå Žå
ã«ã¯ãåºå±€è¡šé¢ã¯æ¯æäœã®é£æ¥ããéè¡šé¢ã§ä¿è·
ããããããã®å éåæ§çµæç©ã¯çŽ0.0003ã€ã³ã
ïŒã0.0008cmïŒãçŽ0.01ã€ã³ãïŒã0.025cmïŒãŸã
ã¯ãã以äžã®ä¹Ÿç¥ã³ãŒãã€ã³ã°åãã§ååšããã
奜ãŸããã¯æž©åºŠå€åã«å¯ŸããŠé«åºŠã®å¯žæ³å®å®æ§ã
æããé©åœãªå¥é¢æ§æ¯æäœã¯é«ååééåäœäŸã
ã°ããªã¢ãããããªãªã¬ãã€ã³ãããªãšã¹ãã«ã
ããã«éåäœããã³ã»ã«ããŒã¹ãšã¹ãã«ãããªã
åºç¯å²ã®çš®çš®ãªãã€ã«ã ããéžã¶ããšãã§ããã
ãŠãããã¯0.00025ã€ã³ãïŒã0.0006cmïŒã0.008
ã€ã³ãïŒã0.02cmïŒãŸãã¯ãã以äžã®åããæã
ãããå¥é¢æ§æ¯æäœãé€å»ããåã«é²å ãå®æœã
ããå Žåã«ã¯ãããã¯å¿è«ããã«ç §å°ããã掻æ§
ç·æŸå°ã®å®è³ªçå²åãééãããªããŠã¯ãªããª
ããå¥é¢æ§æ¯æäœãé²å ã®åã«é€å»ãããå Žåã«
ã¯ããã®ãããªå¶éã¯é©çšãããªããç¹ã«é©åœãª
æ¯æäœã¯çŽ0.001ã€ã³ãïŒã0.0025cmïŒã®åãã
æããéæããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã
ã§ããã ãšã¬ã¡ã³ããé€å»å¯èœãªä¿è·ã«ããŒã·ãŒããæ
ããŠããããããŠããŒã«åœ¢æ ã§ä¿åãããå Žåã«
ã¯ã奜ãŸããã¯å¥é¢æ§æ¯æäœã®è£åŽã¯ããã«èã
é¢åäœçšç©è³ªå±€äŸãã°ã¯ãã¯ã¹ãŸãã¯ã·ãªã³ãŒã³
ãé©çšããŠå éåæ§åºå±€ãšã®ãããã¯åœ¢æãé»æ¢
ãããããããã¯ãŸãã³ãŒãã€ã³ã°ãããå éå
æ§å±€ãžã®æ¥çã¯ã³ãŒãã€ã³ã°ãã¹ãæ¯æäœè¡šé¢ã®
çåŠçãŸãã¯æŸé»åŠçã«ãã€ãŠåªå çã«äžæãã
ãããšãã§ããã 䜿çšãããå Žåã®é©åœãªé€å»å¯èœãªä¿è·ã«ããŒ
ã·ãŒãã¯åèšãšåäžã®é«åºŠéåäœãã€ã«ã 矀ãã
éžã¶ããšãã§ãããããŠããã¯åäžã®åºç¯å²ã®å
ããæãããã0.001ã€ã³ãïŒã0.0025cmïŒåã
ã®ããªãšãã¬ã³ã«ããŒã·ãŒãã¯ç¹ã«é©åœã§ããã
åèšæ¯æäœããã³ã«ããŒã·ãŒãã¯å éåæ§ã¬ãžã¹
ãå±€ã«è¯å¥œãªä¿è·ãäžããã äžè¬ã«å°å·åè·¯ã®åœ¢æãå«ãæ¬çºæã®æ¹æ³ã«é©
åœãªåºæã¯æ©æ¢°ç匷床ãååŠçæµææ§ããã³è¯å¥œ
ãªèªé»æ§ãæãããã®ã§ãããããªãã¡å°å·åè·¯
ã®ããã®ã»ãšãã©ã®æ¿ææã¯éåžžè£åŒ·å€ãå ãã
ç±ç¡¬åæ§ãŸãã¯ç±å¯å¡æ§æš¹èã§ãããè£åŒ·å€ãå
ããç±ç¡¬åæ§æš¹èãåæ§æ¿ã®ããã«äžè¬ã«äœ¿çšã
ããããŠè£åŒ·ãªãã®ç±å¯å¡æ§æš¹èã¯å¯ææ§åè·¯æ¿
ã«é垞䜿çšãããã å žåçæ¿æ§é ã¯çµåãç©äŸãã°çŽãŸãã¯çŽâã¬
ã©ã¹è€åäœã®äžã®ããšããŒã«ãŸãã¯ãšããã·æš¹è
ãªãã³ã«ã¬ã©ã¹äžã®ããªãšã¹ãã«ããšããã·ãã
ãªã€ãããããªããã©ãã«ãªããšãã¬ã³ãŸãã¯ã¬
ã©ã¹äžã®ããªã¹ãã¬ã³ãå å«ãããã»ãšãã©ã®å Ž
åæ¿ã«ã¯é»æ°äŒå°æ§éå±ã®èãå±€ã被èŠããã
ãããã®éå±ã®äžã§ã¯é ãæãäžè¬çã§ããã ç³çå°å·çšãã¬ãŒãã®è£œé ãå å«ããæ¬çºæã®
æ¹æ³ã«é©åœãªåºæã¯ãæ©æ¢°ç匷床ãæããããŠå
æåæ§å±€ã®ç©å±€ãåèšå±€ã®é²å ããã³çŸåã«ãã
圢æããããã®äžã®å圢æãããå æåæ§éšåã®
è¡šé¢ãšã¯èŠªæ°Žæ§ãŸãã¯èŠªæ²¹æ§ã«ãããŠç°ãªãè¡šé¢
ãæããŠãããã®ã§ããããã®ãããªåºæã¯ç±³åœ
ç¹èš±ç¬¬4072528å·æ现æžã«é瀺ãããŠããããã®
ç®çã«å¯ŸããŠã¯å€ãã®åºæãæºè¶³ãã¹ããã®ã§ã¯
ããããã©ããèãã¢ããŒãåŠçããã¢ã«ãããŠ
ã ãã¬ãŒãäŸãã°ç±³åœç¹èš±ç¬¬3458311å·æ现æžã«
é瀺ã®ãã®ãç¹ã«æçšã§ãããã¢ããŒãåŠçãã
ã³ã·ãªã±ãŒãåŠçã¢ã«ãããŠã ãã¬ãŒãããŸãæ
çšã§ããã åœæ¥è ã¯ç©å±€ãããã¹ãå°å·åè·¯åºæè¡šé¢ãæž
æµã§ãããã€å€æ¥æ§ç©è³ªã®å šãååšããŠããªãã®
ã奜ãŸããããšãèªèããŠããã§ãããããã®ç
ç±ã®æ ã«å°å·åè·¯æ¿è£œé ã®åéã§ã¯åšç¥ã®æ°çš®ã®
æž æµåæ³ã®äžã€ãŸãã¯ãã以äžã«ããç©å±€ã®åã«
å°å·åè·¯åºæãæž æµåããããšãåŸåŸã«ããŠæãŸ
ãããæž æµåã®ç¹å®ã®ã¿ã€ãã¯æ±æã®ã¿ã€ãäŸã
ã°ææ©æ§ã§ããããç²åç¶ã§ããããŸãã¯éå±æ§
ã§ãããã«äŸåããããã®ãããªæ¹æ³ã¯æº¶åªãŸã
ã¯æº¶åªãšãã«ãžãšã³ã«ããè±èãæ©æ¢°çã¹ã¯ã©ã
ã³ã°ãã¢ã«ã«ãªå«æµžãé žæ§åãã®ä»ããã³ããã«
ã€ã¥ããããããã³ä¹Ÿç¥ãå å«ããã ãšã¬ã¡ã³ãã®è£œé ããã³ãã®ãšã¬ã¡ã³ãã也ç¥
ããã¬ãžã¹ããšããŠäœ¿çšãããå Žåã«ã¯ãã®å é
åæ§å±€ã®å°å·åè·¯æ¿ãžã®ç©å±€ã®åŸããã®å éåæ§
å±€ã¯é©åœãªåäŸãã°åå«æéæç»ãéœç»ãŸãã¯é°
ç»ãŸãã¯é©åœãªãããã¹ã¯ãéããŠæŽ»æ§ç·æŸå°ã«
åæ§é²å ããããããã掻æ§ç·æŸå°æºã¯äžè¬ã«æ
å¹éã®çŽ«å€ç·ç¯å²ã®æŸå°ãäžãããé©åœãªæºãšã
ãŠã¯ã«ãŒãã³ã¢ãŒã¯ãæ°Žéèžæ°ã¢ãŒã¯ãç¹å¥ã®çŽ«
å€éšçºå è¢å äœãæããè¢å ç¯ãã¢ã«ãŽã³ã°ããŒ
ã©ã³ããé»åãã©ãã·ãŠãŠãããããã³åççšã
ã©ããã©ã³ããã®ä»ãããããããããå éåäœ
å±€ã®æºè¶³ãã¹ãè€åã«å¯ŸããŠèŠæ±ãããé²å ã®é
ã¯é²å æéã䜿çšãããæŸå°æºã®ã¿ã€ããããã³
æŸå°æºãšå±€è¡šé¢ãšã®éã®è·é¢ã®åŸæ°ã§ãããäžè¬
ã«æšæºã®åæ¥çæŸå°æºã䜿çšããå Žåã«ã¯é²å æ
éã¯0.5ã10åãŸãã¯ãã以äžã®ç¯å²ã§ããã åæ§é²å ã®åŸãå éåå±€ã®æªé²å éšåã液äœçŸ
åäŸãã°ææ©éåäœçµåå€æåã«å¯Ÿãã溶åªãŸã
ã¯æº¶åªæ··åç©ã«ããé€å»ãããçŸåã¯ããããã®
䟿å©ãªæ¹æ³äŸãã°æ³šæ¶²ãå«æµžãã¹ãã¬ãŒãŸãã¯ã
ãŒã©ãŒé©çšã«ããå®æœããããããã©ã·ããã¯çµ
æç©ã®æªéåãŸãã¯æªäº€åçµåéšåã®é€å»ãå©æ
ããããçŸåã¯æž©æº¶æ¶²ã䜿çšããŠå®æœã§ããããŠ
æéã¯å éåæ§å±€ã«ãã€ãŠäŸãã°ãã®çµæãåã
ãã®ä»ã«ããå€åãããæçšãªçŸåç¯å²ã¯ïŒç§ã
25åã®ç¯å²ã§ãããããçŸååŸãšã¬ã¡ã³ããäŸã
ã°å¿ èŠãªå Žåã«ã¯ãã¢ã³ã®åé¢ã«çœ®ãããšãå«ã
ãŠç©ºæ°äžã§ä¹Ÿç¥ãããããšãã§ããã å éåæ§çµæç©ã«å¯Ÿããæè¯ã®æ§åŒã¯äŸïŒã«èª¬
æãããŠããããã®å Žåã亀åçµåéåäœããŒãº
ã¯ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãã®ã
ã¢éåäœã§ããã ææ©éåäœç¶çµåå€ã®äžéšãã°ãã°ããªå®è³ªç
ã«éèšæœ€æ§ã®äº€åçµåããŒãºã§çœ®æããããæ¬çº
æã®å éåæ§çµæç©ã¯äº€åçµåããŒãºãå šãå«æ
ããªãåæ§ã®å éåæ§çµæç©ã«æ¯ã¹ãŠææã«äžå±€
è¿ éã«ä¹Ÿç¥ããããšãèŠåºããããæ¬çºæã®å é
åæ§çµæç©ã¯åŸæ¥æè¡ã®çµæç©ãããäžå±€éãã
ã«ããŠäžå±€å¹çãã也ç¥ãã€ã«ã¿ããã¬ãžã¹ããŸ
ãã¯ä¹Ÿç¥å éåæ§ãšã¬ã¡ã³ãã«èª¿è£œããããšãã§
ããããã®ä¹Ÿç¥ããã¬ãžã¹ãã¯å°å·åè·¯ã®è£œé ã«
䜿çšãããããã®ãããªããã¬ãžã¹ãã¯ããéã
ãã«åŠçããããšãã§ããããšã¬ã¡ã³ã圢æ ã«ã
ããŠã¯ããã®ä¹Ÿç¥å éåæ§çµæç©ã®å±€ã¯æ¯æäœäŸ
ãã°ãã€ã«ã ãŸãã¯ã·ãŒããšé€å»å¯èœãªã«ããŒã·
ãŒããšã®éã«ååšããããããããã®ãããªãšã¬
ã¡ã³ãã¯å°å·ãã¬ãŒãã®è£œé ã«äœ¿çšãããå Žåã«
ã¯å éåæ§å±€ã«æ°žä¹ çã«æ¥çãããæ¯æäœãæã
ããããã®ãšã¬ã¡ã³ãã也ç¥ãã€ã«ã ã¬ãžã¹ããš
ããŠäœ¿çšããå Žåã«ã¯æ¯æäœã¯ããã«æå·ãäžã
ãããšãªãå éåæ§å±€ããé€å»ããããããã®å
éåæ§å±€ã¯ã亀åçµåéåäœããŒãºãæ¯èŒç倧é
ã«ååšããŠããã«ããããããæãŸããæ§è³ªãä¿
æããŠãããããªãã¡æ¬çºæã®å éåæ§å±€ã®åç
é床ãé ãžã®æ¥çãéæããŸãã¯è§£åæ§ãããã³
å¯ææ§ã¯ä¿æãããŠããã åã ã«ç¬ç«ããå®è³ªçã«éèšæœ€æ§ã®äº€åçµåã
ãŒãºãå«æãããã®å éåæ§ã³ãŒãã€ã³ã°çµæç©
ã¯ãã¬ãšããŠåãç³»ã§ã¯ããããã©ããåèšã®æº¶
åªå¯æº¶æ§çµåå€ããã³äº€åçµåããŒãºã«å¯Ÿããå
äžã®èšççåºæºãæºè¶³ãããå Žåã«ã¯åæ§ã®å©ç¹
ãããžãšããŠåãå æåæ§ç³»ãå«æããå æåæ§
çµæç©ã«å¯ŸããŠãé©çšãããã ããžãšããŠåãå æåæ§ã³ãŒãã€ã³ã°çµæç©äž
ããã³ä¹Ÿç¥ãã€ã«ã ãšã¬ã¡ã³ããšããŠã®äº€åçµå
ããŒãºã®äœ¿çšã¯ããã®å æåæ§ãã€ã«ã ãå°å·å
è·¯æ¿è£œé ã®ããã¬ãžã¹ããã€ã«ã ãšããŠã®äœ¿çšã«
察ããŠãã¶ã€ã³ãããŠããå Žåã«ã¯ç¹ã«æå©ã§ã
ãããã®ãããªãã€ã«ã ã¯ãã€ã¯ããšã¬ã¯ããã
ã¯ã¹é©çšã«å¯ŸããŠäœ¿çšãããããžãšããŠåãã³ãŒ
ãã€ã³ã°ãããäžè¬ã«äžå±€åããåŸã€ãŠãããã®
æ¯èŒçåãã³ãŒãã€ã³ã°ãé©çšããããŠè¿ éã«ä¹Ÿ
ç¥ãããŠãã®éåŸããã也ç¥ãã€ã«ã ãšã¬ã¡ã³ã
äžã«åªããç©ççæ§è³ªãéæãããããšã¯æå©ã§
ããã也ç¥ãã€ã«ã ã¬ãžã¹ããšããŠç¹ã«æçšãªã
ãžãšããŠåã也ç¥ãã€ã«ã åŠæ¹ã®æçšãªã¿ã€ãã¯
ç±³åœç¹èš±ç¬¬4193797å·ããã³å第4271260å·åæ现
æžã«èšèŒãããŠããããããç±³åœç¹èš±ã¯ããã«å
ç §ãšããŠå å«ãããã ãžã¢ãŸããã³ååç©ã®å å¯æº¶åã«åºãããžãšã
ãŠåãã³ãŒãã€ã³ã°çµæç©ã¯ãŸããããã§èšèŒã
ãç¬ç«ããå®è³ªçã«éèšæœ€æ§ã®äº€åçµåããŒãºã«
é¢ããŠããŸãæçšã§ããããžã¢ãŸããã³ååç©ã¯
ãã¬ãšããŠåãå éåæ§çµæç©äžã«éåžžååšãã
ããšãã¬ã³æ§äžé£œåååç©ã®ä»£ãã«äœ¿çšãããã
ã®ã§ããããã¬ãšããŠåãçµæç©äžã§å¿ èŠãªå¥å
ã®å éå§å€ç³»ã¯å±¡ã èŠæ±ãããªãã æ¬çºæã以äžã®å®æœäŸã«ãã説æãããããã
æ¬çºæã¯ããã«éå®ãããããšãæå³ãããã®ã§
ã¯ãªããããã«éšããã³ïŒ ã¯ééåºæºã§ãããé
åäœã®ååéã¯æ°å¹³åååéã§ãããåºæç²åºŠã¯
ãã€ãã³ããšã³ã¹ã±ç²åºŠèšã䜿çšããŠ20âã§ã¡ã
ã¬ã³ã¯ããªã50mläžéåäœ0.25ïœãå«æãã溶液
ã«ã€ããŠæž¬å®ããããå®æœäŸäžã«èšèŒã®åºæç²åºŠ
ã¯æ¯ç²åºŠã®ãŒãæ¿åºŠãžã®å€æ¿ã«ãã枬å®ãããã
æ¯ç²åºŠã¯ïœân0ïŒn0ã§ãããããã«ïœã¯æº¶æ¶²ç²åºŠã§ ãããããŠn0ã¯çŽæº¶åªã®ç²åºŠã§ãããããŠäž¡è ã¯
å ±ã«25âã§ãªã¹ãã¯ã«ãç²åºŠèšããããã䜿çšã
ãŠæž¬å®ããããã®ã§ããã也ç¥å éåæ§å±€ã®ç Žæ
ç¹äŒžé·ã¯ASTMâD412â75ã«ãã枬å®ãããã
ã³ãŒãã€ã³ã°çµæç©ã®è©Šæã0.008ã€ã³ãïŒ0.20
mmïŒãã¯ã¿ãŒãã€ãã䜿çšããŠãã€ã«ã æ¯æäœäž
ã«ã³ãŒãã€ã³ã°ããããŠ48æé宀枩ã§ä¹Ÿç¥ãã
ããç¹èšãããŠããªãéãã¯ãã®ã³ãŒãã€ã³ã°è©Š
æãæ¯æäœããå¥é¢ããããããŠäžç·ã«ç©å±€ããŠ
çŽ0.006ã€ã³ãïŒçŽ0.15mmïŒã®å±€åããçæãã
ããïŒã€ã³ãÃïŒã€ã³ãïŒ2.54cmÃ7.62cmïŒã®ç©
å±€äœçããïŒã€ã³ãïŒåïŒ2.54cmïŒåïŒã®ã¯ãã¹
ãããé床ã§ïŒã€ã³ãïŒ2.54cmïŒã®åæåé¢ã§ã€
ã³ã¹ããã³ ãã¹ã¿ãŒååŒTMã®ãžãšãŒäžã«çœ®
ãã äŸ ïŒ ïŒ¡ ããŒãºã®è£œé 500ïœã®ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãª
ã¬ãŒãã193ppmã®ãããããã³ããã³130ppm
ã®ïœâã¡ããã·ããšããŒã«ãå«æããïŒããŒ
ã«ãŒã«ã5.7ïœã®ãã³ãŸã€ã«ããŒãªãã·ããå
ããããã®æ··åç©ããã³ãŸã€ã«ããŒãªãã·ãã
溶解ãããŸã§å®€æž©ã§æ¹æããããŠæº¶è§£å®äºåŸïŒ
æé以å ã«ãã®æº¶æ¶²ã䜿çšãããã¹ãã³ã¬ã¹ã¹
ããŒã«ããŒã«ãŒäžã«2.5ïœã®ãããªãŠã ãžãªã¯
ãã«ã¹ã«ããµã¯ã·ããŒãããã³4.2ïœã®è¡šé¢æŽ»
æ§å€ïŒããã¹ã¿ãã³ïŒHostapon ïŒãTHCãã¢
ã¡ãªã«ã³ã»ããã¹ã瀟補åïŒïŒ2.5ïœã®ãªã¬ã€ã«
ã¡ãã«ã¿ãŠãªãã®ãããªãŠã å¡©å«æïŒã®æ°Ž1200
mläžæº¶æ¶²ã補é ããããã®æº¶æ¶²ãäœéã§V2銬
åãšããã³ããããããµãŒã䜿çšããŠæ¹æãã
ãã®éããŒãªãã·ãïŒåéäœæº¶æ¶²ãå ãããã
ããµãŒã®å ¥åé»å§ãçŽ70ãã«ããŸã§äžæããã
ããšã«ãã€ãŠããããµãŒã®é床ãåŸåŸã«äžæã
ããïŒçŽ10åã«ãããïŒãé床ããã®ç¹ã«çŽïŒ
æéä¿æããã次ãã§ã¯ãªãŒã ç¶çœè²ä¹³æ¿æ¶²ã
å«æããã¹ãã³ã¬ã¹ã¹ããŒã«ã®çŒ¶ãèŠããããŠ
60âã®æ°ŽæµŽäžã«72æéä¿æããããéåä¹³æ¿æ¶²
ãå·åŽãããããŠé å¿ãããäžæŸã¿ãæšãŠãã
ãŠéåäœã±ãŒããçŽïŒã®æ°Žãšæ¹æããŠåã³é
å¿ãããæ°Žãšã®æ¹æããã³é å¿ãæŽã«ïŒåãã
ããããããŠéåäœããŒãºã®ã±ãŒãã颚也ãã
ãããã®ä¹Ÿç¥éåäœã¯æ°ŽãŸãã¯ææ©æº¶åªäŸãã°
ã¡ãã¬ã³ã¯ããªããã¢ã»ãã³ãŸãã¯ãšã¿ããŒã«
äžã«äœéã®å®¶åºçšã¿ã€ããã¬ã³ããŒãã¢ã²ãã€
ã¶ãŒã®äœ¿çšã«ãã€ãŠå®¹æã«ååæ£ããããã¯ãŒ
ã«ã¿ãŒã«ãŠã³ã¿ãŒïŒã¯ãŒã«ã¿ãŒã»ãšã¬ã¯ããã
ã¯ã¹ç€Ÿè£œåïŒã䜿çšããŠæž¬å®ãããæ°åºæºã®å¹³
åç²åãµã€ãºã¯0.66ÎŒïœã§ãããããŠå¹³å容é
ç²åãµã€ãºã¯1.2ÎŒïœã§ãã€ãã  ããã¬ãžã¹ãçšã³ãŒãã€ã³ã°åæ£æ¶²ã®è£œé åèšã®ããã«ããŠè£œé ããã也ç¥ããŒãº26.8
éšãã¡ãã¬ã³ã¯ããªã66éšãšäžç·ã«æ¹æããã
ãšã«ãã€ãŠã¡ãã¬ã³ã¯ããªãäžã®ããŒãºã®ã¹ã
ãã¯åæ£æ¶²ã補é ããããã®åæ£æ¶²ããã€ãã³
ããšã«ããã€ã«ã¿ãŒããããéããŠéããã
å®è³ªçã«åºäœç©è³ªã¯äœãä¿æãããªãã€ãã
1.25ã®åºæç²åºŠãæããããªã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒã5.5éšãš0.5ã®åºæç²åºŠãæããããªã¡ãã«
ã¡ã¿ã¯ãªã¬ãŒã1.2éšãšããã®æžæ¿æ¶²ã«æº¶è§£ã
ãããéåäœãå ããŠåæ£æ¶²ã®å®å®æ§ãäžæã
ããããããããã¯äžèŠã§ããããšãèŠåºãã
ãã è¡šïŒèšèŒã®æåãå«æããã³ãŒãã€ã³ã°çµæ
ç©ã補é ããã亀åçµåããŒãºãå«æããªãã³
ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã¯å¯Ÿç §ïŒã³ã³ãããŒã«ïŒãš
ããŠäœ¿çšããããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ããã³
ã«ãããŠã¯çµåå€ããã³ããŒãºã®åèšééã®
ãããã40ïŒ ããã³20ïŒ ã亀åçµåããŒãºã§ã
ã€ããããã¯æå(a)ã(b)ã(c)ããã³(d)ã®åèšé
éåºæºã§ããããçŽ24.24ïŒ ããã³çŽ12.12ïŒ ã«
çžåœããã
ãè¡šã
ã¢ããªã³ïŒ
ãè¡šã
ãã®æº¶æ¶²ãããããæŒåºãã³ãŒãã€ã³ã°ããŠ
50.8ÎŒïœã®ä¹Ÿç¥ã³ãŒãã€ã³ã°åããçæãããã
è©Šæã¯4.57ïœïŒåã§ã³ãŒãã€ã³ã°ããããã³ãé
床ã¯ä¹Ÿç¥ã³ãŒãã€ã³ã°åãã50.8ÎŒïœãšãªããŸã§
åå Žåã«èª¿æŽãããã次ãã§ãã³ãé床ã6.10ã
7.62ã9.14ããã³10.67ïœïŒåã§åäžã³ãŒãã€ã³ã°
åããšããããã«èšç®ããã以åŸã®åãã®æž¬å®ã¯
äžå®ã®ã³ãŒãã€ã³ã°åãã確èªãããã³ãŒãã€ã³
ã°åŸãã³ãŒãã€ã³ã°ããããŠãšããïŒâãã€ã³ã
ãŒãã©ã€ã€ãŒäžã«å°ãããäžé£ã®ïŒåã®ãã€ã³ã
ãŒäžã®æž©åºŠã¯38ãã66ãããã³121âã«ä¿æãããŠ
ããããã®ïŒåã®åž¯åäžã§ã®ç©ºæ°é床ããã³æž©åºŠ
ã¯ä¹Ÿç¥ã®å šéçšã«ããã€ãŠäžå®ã«ä¿æãããŠã
ãããã©ã€ã€ãŒããåºãŠè¡ãéãã³ãŒãã€ã³ã°ã
ãããŠãšãã25ÎŒïœåãã®ããªãšãã¬ã³ãã€ã«ã
ã§ç©å±€ãããããŠå·»ãäžãããäžããããã³ãŒã
ã€ã³ã°åæ£æ¶²ããã®ã³ãŒãã€ã³ã°ã¯ãã¹ãŠé£ç¶ç
ã«åäžã³ã¢äžã«å·»ãäžãããïŒæ倧ã³ãŒãã€ã³ã°
é床ã«ãããïŒæåŸã®ã³ãŒãã€ã³ã°ã®ããåŸã«è©Š
æããšã€ããåã³ãŒãã€ã³ã°ã®ïŒã10ïœè©Šæãå
ãã€ãŠã¢ã«ãããŠã ç®ã§èŠã€ãã³ã¢äžã«å·»ããã
ããŠè©Šæãå·»ããåŸãã¢ã«ãããŠã ç®ãå€åŽã®ãŸ
ããã«å·»ããŠãã¹ãŠã®æº¶åªèžæ°ã®æ£éžãé»æ¢ã
ããã³ãŒãã€ã³ã°ãããææè©Šæãå¯é容éäžã§
å ç±ããããŠåŸãããèžæ°ãïŒçš®ã®ååšãã溶åª
ããªãã¡ã¡ãã¬ã³ã¯ããªãããã³ïŒâãšããã·ãš
ã¿ããŒã«ã«é¢ããŠèµ€å€ç·åžåã«ããåæããããš
ã«åºãæ¹æ³ã«ãã€ãŠãè©Šæã®æ®å溶åªãåæã
ãã次ãã§å溶åªã®æ®åéïŒ ãèšç®ãããããã¯
è¡šïŒã«ç€ºãããŠããã
50.8ÎŒïœã®ä¹Ÿç¥ã³ãŒãã€ã³ã°åããçæãããã
è©Šæã¯4.57ïœïŒåã§ã³ãŒãã€ã³ã°ããããã³ãé
床ã¯ä¹Ÿç¥ã³ãŒãã€ã³ã°åãã50.8ÎŒïœãšãªããŸã§
åå Žåã«èª¿æŽãããã次ãã§ãã³ãé床ã6.10ã
7.62ã9.14ããã³10.67ïœïŒåã§åäžã³ãŒãã€ã³ã°
åããšããããã«èšç®ããã以åŸã®åãã®æž¬å®ã¯
äžå®ã®ã³ãŒãã€ã³ã°åãã確èªãããã³ãŒãã€ã³
ã°åŸãã³ãŒãã€ã³ã°ããããŠãšããïŒâãã€ã³ã
ãŒãã©ã€ã€ãŒäžã«å°ãããäžé£ã®ïŒåã®ãã€ã³ã
ãŒäžã®æž©åºŠã¯38ãã66ãããã³121âã«ä¿æãããŠ
ããããã®ïŒåã®åž¯åäžã§ã®ç©ºæ°é床ããã³æž©åºŠ
ã¯ä¹Ÿç¥ã®å šéçšã«ããã€ãŠäžå®ã«ä¿æãããŠã
ãããã©ã€ã€ãŒããåºãŠè¡ãéãã³ãŒãã€ã³ã°ã
ãããŠãšãã25ÎŒïœåãã®ããªãšãã¬ã³ãã€ã«ã
ã§ç©å±€ãããããŠå·»ãäžãããäžããããã³ãŒã
ã€ã³ã°åæ£æ¶²ããã®ã³ãŒãã€ã³ã°ã¯ãã¹ãŠé£ç¶ç
ã«åäžã³ã¢äžã«å·»ãäžãããïŒæ倧ã³ãŒãã€ã³ã°
é床ã«ãããïŒæåŸã®ã³ãŒãã€ã³ã°ã®ããåŸã«è©Š
æããšã€ããåã³ãŒãã€ã³ã°ã®ïŒã10ïœè©Šæãå
ãã€ãŠã¢ã«ãããŠã ç®ã§èŠã€ãã³ã¢äžã«å·»ããã
ããŠè©Šæãå·»ããåŸãã¢ã«ãããŠã ç®ãå€åŽã®ãŸ
ããã«å·»ããŠãã¹ãŠã®æº¶åªèžæ°ã®æ£éžãé»æ¢ã
ããã³ãŒãã€ã³ã°ãããææè©Šæãå¯é容éäžã§
å ç±ããããŠåŸãããèžæ°ãïŒçš®ã®ååšãã溶åª
ããªãã¡ã¡ãã¬ã³ã¯ããªãããã³ïŒâãšããã·ãš
ã¿ããŒã«ã«é¢ããŠèµ€å€ç·åžåã«ããåæããããš
ã«åºãæ¹æ³ã«ãã€ãŠãè©Šæã®æ®å溶åªãåæã
ãã次ãã§å溶åªã®æ®åéïŒ ãèšç®ãããããã¯
è¡šïŒã«ç€ºãããŠããã
ãè¡šã
è¡šïŒããä»»æã®èšèŒã®ã³ãŒãã€ã³ã°é床ã«ãã
ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ããåŸãããæ®å溶åªé
ãšã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã®ãããšã®éã«ã¯é¡
èãªå·®ãååšããããšãèªããããã4.57ïœïŒå
ã§ã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããåŸãããæ®å溶åª
éã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã10.67ïœïŒåããª
ãã¡ïŒå以äžéãã³ãŒãã€ã³ã°ããå Žåã«åŸãã
ããã®ããã倧ã§ãããéåäœç¶çµåå€ããã³ã
ãŒãºã®åèšééã®40ïŒ ã亀åçµåéåäœããŒãºã§
ããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã¯åèšæ®å溶åªãçŽ
0.4ïŒ ä»¥äžã«æžå°ãããçšåºŠãŸã§ä¹Ÿç¥ããããã
ã«ã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ïŒå¯Ÿç §ïŒã®åå以äž
ã®æéããå¿ èŠãšããªãã€ããéåäœç¶çµåå€ãš
ããŒãºãšã®åèšééã®20ïŒ ã亀åçµåéåäœããŒ
ãºã§ããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ£ã¯ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¡ãšã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãšã®äžéã®çµæã
äžãããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã®ã³ãŒãã€ã³
ã°ã¯4.57ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã®0.3ïŒ
ïœm2ãã10.67ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã®
20ïŒïœm2ã®ç¯å²ã§æ³¡æ¬ é¥ïŒbubble defectsïŒãå«
æããŠãããæ³¡æ¬ é¥ã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãã
ã³ïŒ£ããã®ã³ãŒãã€ã³ã°äžã«ã¯ã¿ãããªãã€ãã ãããã4.57ïœïŒåã§è£œé ãããã³ãŒãã€ã³ã°
åæ£æ¶²ïŒ¡ãããã³ïŒ£ããã®è©Šæã也ç¥ãã€ã«ã
ããã¬ãžã¹ããšããŠè©Šéšããã也ç¥ãã€ã«ã ã®é
ãžã®ç©å±€ã¯220ãïŒ104.4âïŒã§å®æœãããããã€
ã«ã å¯ææ§ãåçé床ãç»åå質ãFeCl3ã«ãã
ãšããã³ã°çµæãããã³é ãã€ãã¯ïŒçš®ã®ããã¬
ãžã¹ãããããã«å¯ŸããŠå®è³ªçã«åäžã§ãã€ãã
ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã³ïŒ¢ãã補é ãããã
ãã¬ãžã¹ãã«å¯ŸããŠèŠæ±ãããçŸåæéã¯æ¬¡ã®é
ãã§ãã€ãã æéïŒç§ïŒ ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ 105 ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ 68 çŸåã¯ã也ç¥ãã€ã«ã ç©å±€äœãä¿æãããããŠ
ã¡ãã«ã¯ãããã«ã 溶åªããã³ãã§ãã®äžã®ã¹ã
ã¬ãŒããºã«ã«æ±²ã¿å ¥ããŠããªãé«é床ã§æ¿ïŒããŒ
ãïŒãã¿ãŒã³ã«æº¶åªãéãåºãã¹ãã¬ãŒããã»ãµ
ãŒäžã§å®æœãããã也ç¥ã³ãŒãã€ã³ã°ïŒ¡ããã
ã³ïŒ£ã®ç Žæç¹äŒžé·ã¯æ¬¡ã®éãã§ãã€ãã ç Žæç¹äŒžé·ïŒïŒ ïŒ ïŒ¡ 360  670  437 äŸ ïŒ ïŒ¡ æ¹æ³ 亀åçµåéåäœããŒãºã®è¡šé¢ãšã¹ãã«åºãå
æ°Žå解åŠçããŠã«ã«ããã·ã«åºãšãããäŸïŒèš
èŒã®ããã«ããŠè£œé ãããããŒãºã®40.0ïœåºå
éãã(H)宀枩ã«ãããŠïŒæéïŒïŒ æ°Žæ§æ°Žé žåã
ããªãŠã 48.4ïœãšã(I)54ã57âã«ãããŠ20åé
10ïŒ æ°Žæ§æ°Žé žåãããªãŠã 33.3ïœãšã(J)57ã62
âã«ãããŠ40åéïŒïŒ æ°Žæ§æ°Žé žåãããªãŠã
48.4ïœãšã(K)60ã65âã«ãããŠ50åéïŒïŒ æ°Žæ§
æ°Žé žåãããªãŠã 48.4ïœãšããããŠ(L)60ã70â
ã«ãããŠçŽïŒæéïŒïŒ æ°Žæ§æ°Žé žåãããªãŠã
48.4ïœãšããããå ±ã«æ¹æãããåŠçåŸãåã¹
ã©ãªãŒãçŽ100mlã®æ°·å·æ°Žã«æ³šããããŠé å¿ã
ããäžæŸæ¶²ã®ç²åºŠããªã¹ã¯ã«ãããããã䜿çš
ããŠæž¬å®ãããç²åºŠã¯åæ§ã«åžéãããæ°Žé žå
ãããªãŠã ã®ç²åºŠïŒ1.2cps以äžïŒãšææã«ç°ãª
ããã®ã§ã¯ãªãã€ãããã ãè©Šæã¯13.4cps
ã®ç²åºŠãæããŠããããã®ããšã¯è©Šæãã§
ã¯å æ°Žå解ã¯è¡šé¢ã«éå®ãããŠããããããè©Š
æã§ã¯å æ°Žå解ã¯æŽã«é²ãã§æº¶æ¶²äžã«éåäœ
ïŒããªã¢ã¯ãªã«é žïŒãçæããããšã瀺ããŠã
ããé å¿ããããŒãºã120mlã®æ°Žã§æ¹æããã
ãŠåé å¿ããããšã«ããïŒåæŽã€ãã次ãã§æŽ
ã€ãè©Šæã也ç¥ããããè©Šæäžã®ã«ã«ããã·ã«
åºã®ååšã¯0.1ïœã®ä¹Ÿç¥ç²æ«ãïŒmlãŸãã¯ïŒml
ã®æ°Žãšæ¹æãããããŠæ¬¡ãã§æ°Ž80mläžã®0.1ïœ
ã®ã¡ãã¬ã³ãã«ãŒããã³20mlã®PHïŒã®ãããã¢
ãŒæº¶æ¶²10.0mlãå ããããšã«ãã瀺ããããã
ã®æ··åç©ãé å¿ããäžæŸã¿ãæšãŠããããŠæ²æ®¿
ã35mlã®æ°Žãšæ¹æããããŠåé å¿ããããšã«ã
ã€ãŠïŒåæŽã€ãã次ãã§æ²æ®¿ãçŽäžã§ä¹Ÿç¥ã
ãããéè²ã®æ·±ãã¯ïŒšãã®é ã«äžæãããè©Š
æã¯æ·¡éè²ã§ãããããŠè©Šæã¯éåžžã«æè²
ã§ãã€ãã  æ¬çºæã®ããŒãºã®è£œé ããã³äœ¿çš åèšè©Šæã®ããã«ããŠäœã500ïœã®ããã
ã§è©Šæã補é ããã375mlã®æ°Žäžæ°Žé žåãããª
ãŠã 41.6ïœã®æº¶æ¶²ã70âã«å ç±ãããããŠäŸïŒ
èšèŒã®500ïœã®éåäœããŒãºãæ¹æãã€ã€å ã
ãã枩床ãåŸããã53âãã60âã«ïŒåéãã
ãŠäžæãããããããŠåœ¢æãããã¹ã©ãªãŒã50
åé60ã65âã§æ¹æããããã®ã¹ã©ãªãŒã1500
mlã®æ°·æ°Žã«å ãããããŠæ¬¡ãã§é å¿ããããäž
æŸã¿ã®ç²åºŠã¯åæ§ã«åžéãããæ°Žæ§æ°Žé žåãã
ãªãŠã ã®ãããšææã«ã¯ç°ã€ãŠããªãã€ããæ²
殿ãçŽïŒã®æ°Žãšæ¹æãããããŠPHã2.5ã«èª¿
æŽããŠè¡šé¢ã«ã«ã«ããã·ã«åºãçæããããã
ã®ã¹ã©ãªãŒãæŽã«çŽïŒã«åžéããããŠé å¿ã
ãããããŒãºãçŽïŒã«åžéããããŠåé å¿ã
ãããšã«ããïŒåæŽãããããŠæåŸã«é¢šä¹Ÿãã
ããåéã¯çŽ480ïœã§ãã€ãã äŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã«ããããããªå¯Ÿ
ç §çµæç©ãšãäŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãšåæ§
ã§ããããã®äŸã«ãããéåäœããŒãºã®ä»£ãã«é
åäœçµåå€ãšããŒãºãšã®åèšééã®ïŒïŒ ãåèšã®
ããã«ããŠè£œé ãããã«ã«ããã·ã«ïŒå æ°Žå解ïŒ
è¡šé¢ãæããããŒãºã§ãããããªçµæç©ãšã®ä¹Ÿç¥
é床ãæ¯èŒããããã®çµæã¯äŸïŒã®ãããšåæ§ã§
ãã€ãã亀åçµåããŒãºå«æçµæç©ã¯ã9.14ïœïŒ
åã§ã³ãŒãã€ã³ã°ãããå Žå4.57ïœïŒåã§ã³ãŒã
ã€ã³ã°ãããå¯Ÿç §ãšå€§çŽåéã®æ®å溶åªãäžã
ããããªãã¡ããã¯çŽïŒåè¿ éã«ä¹Ÿç¥ããããã®
çµæç©ããŸã也ç¥ãã€ã«ã ããã¬ãžã¹ããšããŠäœ¿
çšãããå Žåã®å¯Ÿç §ã³ãŒãã€ã³ã°ãšãæ¯èŒããã
åçé床ããã³ãšããã³ã°ããã³ãã€ãå質ãã
ã³äŸïŒèšèŒã®å®æåè·¯ããã®å éåäœå±€ã®å¥é¢ã«
ãããŠåæ§ã®çµæãåŸãããããã®ã©ãïŒlabïŒ
ã³ãŒãã€ã³ã°ã®ç Žæç¹äŒžé·ã¯570ïŒ ã§ãã€ãã äŸ ïŒ æ¬¡ã®ããã«ããŠã³ãŒãã€ã³ã°çµæç©ã補é ã
ãã éš äº€åçµåããŒãºïŒäŸïŒåç §ïŒ 55.52 ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã 13.10 ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒã 13.10 é«ååéããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒåºæç²åºŠ
2.7ïŒ 6.620 ããã©ãŒã®ã±ãã³ 0.106 ãã³ãŸããšãã³ 3.517 ãã¹ïŒïŒâïœâã¯ããããšãã«âïŒïŒïŒâãã¹
âããšãã«ïŒã€ãããŸãŒã« 2.193 ããªã¹âïŒïŒâãžãšãã«ã¢ããâïœâããªã«ïŒ
ã¡ã¿ã³ 0.132 ïŒïŒ4â²ïŒ4â³âã¡ããªãžã³ããªã¹ïŒïŒ®ïŒïŒ®âãžã¡
ãã«ã¢ããªã³ïŒ 0.088 ãã¯ããªã¢ã°ãªãŒã³ïŒC.I.ãã°ã¡ã³ãã°ãªãŒã³
18ïŒ 0.031 ã¢ãã¹ãã©ã«ã°ãªãŒã³ãã°ã¡ã³ãïŒC.I.ãã°ã¡
ã³ãã°ãªãŒã³ïŒïŒ 0.098 ãªã«ãâããã³ãã©ãŒãã«ãšã³ã¹ã«ãã³ã¢ãã
æ··åç© 5.275 ãã³ãŸããªã¢ãŸãŒã« 0.176 ïœâãã«ãšã³ã¹ã«ãã³é ž 0.044 èš 100ïŒ000 溶åªCH2Cl2 196.2 ããŒãºã¯ã¡ãã¬ã³ã¯ããªãäžã®28.9ïŒ ã¹ã©ãªãŒ
ãšããŠããããŠããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã¯ïŒïŒ
溶液ãšããŠå ããããããããçµæç©ãåãïŒã
ã§ã«èŠæ±éã®æº¶åªãå«æïŒãããŠæ®åæåãå ã
ãããã®ã³ãŒãã€ã³ã°çµæç©ã¯33.8ïŒ ã®æŽ»æ§æå
ãå«æããŠããã äŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ãšåæ§ã«ããŠå¯Ÿç §
ã³ãŒãã€ã³ã°çµæç©ã補é ããããã ããã®æº¶åª
ã¯ã¡ãã¬ã³ã¯ããªãïŒïŒâãšããã·ãšã¿ããŒã«æ··
åç©ã§ãã代ãã«20732ïœã®çŽã¡ãã¬ã³ã¯ããªã
ã§ãã€ãŠ33.8ïŒ æŽ»æ§æåã®æº¶æ¶²ãçæãããã也
ç¥é床ãäŸïŒã«ãããããã«ããŠäŸïŒã«ããããš
åäžã®ã³ãŒã¿ãŒããã³ïŒæ®µéãã©ã€ã€ãŒã䜿çšã
ãããŠ50.8ÎŒïœåãã«ã³ãŒãã€ã³ã°ããŠæ¯èŒããã
ããŒãºå«æçµæç©ããã®æ®å溶åªéã¯ã10.67
ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã«ã¯4.57ïœïŒåã§
ã³ãŒãã€ã³ã°ãããå¯Ÿç §ãããææã«äžå±€äœãã
ããŠããã¯å¯Ÿç §ã®20ïŒ ã«æ¯ã¹ãŠ0.10ïŒ ã§ãããã
ã®ä¹Ÿç¥ã³ãŒãã€ã³ã°ãé æ¿ã«ç©å±€ãããããŠäŸïŒ
èšèŒã®ããã«åŠçããŠæ¿äžã«é åè·¯ãçæãã
ãããã®ä¹Ÿç¥ã³ãŒãã€ã³ã°çµæç©ã®ç Žæç¹äŒžé·ã¯
700ïŒ ã§ããã äŸ ïŒ äŸïŒã«èšèŒã®äº€åçµåããŒãºã®è£œé ããããã
ããããã ã500ïœã®ããªã¡ãã«ãããã³ããªã¢
ã¯ãªã¬ãŒãã®ä»£ãã«ç¬¬ïŒã®å®éš(F)ã§ã¯500ïœã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãã䜿çšãã
ãããŠä»ã®å®éš(G)ã§ã¯250ïœã®ããªã¡ãããŒã«ã
ããã³ããªã¢ã¯ãªã¬ãŒããš250ïœã®ããªãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããšã®æ··åç©ã䜿çšãã
ããã³ãŒãã€ã³ã°çµæç©ã¯çŽïŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¢ãšåæ§ã«ããŠè£œé ãããããã ã第ïŒã®å®
éšã«ãããŠã¯äœ¿çšããã亀åçµåããŒãºã¯ã³ãŒã
ã€ã³ã°åæ£æ¶²ïŒ§ã®ãã®ã§ãããããŠç¬¬ïŒã®å®éšã«
ãããŠã¯ããã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒŠã®ãã®ã§ã
ããäŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ãšãšåæ§ã®ã³ãŒ
ãã€ã³ã°çµæç©ãå¯Ÿç §ãšããŠã³ãŒãã€ã³ã°ããã
ãã®çµæã¯åèšã®ãã®ãšåæ§ã§ãããããŒãº(F)ãŸ
ãã¯(G)ãå«æããã³ãŒãã€ã³ã°åæ£æ¶²ã«å¯Ÿãã
10ïŒ67ïœïŒåã«ããã也ç¥æéã¯4.57ïœïŒåã«ã
ããçŽ0.4ïŒ æ®å溶åªã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã«
察ãããã®ãšå€§çŽåäžã§ãããããªãã¡ä¹Ÿç¥ã¯
0.4ïŒ æº¶åªæ°Žæºãéæããã«ïŒåæ©ãããããçµ
æç©ãåèšã®ããã«ããŠé ã«ç©å±€ãããããŠé©åœ
ãªããã¬ãžã¹ãç»åãé²å ããã³çŸååŸã«é äžã«
åŸããããããã³ïŒ§ã«çžåœãã也ç¥ã³ãŒãã€ã³
ã°çµæç©ã®ç Žæç¹äŒžé·ã¯400ïŒ ä»¥äžã§ããã äŸ ïŒ æ¬¡ã®ããã«ããŠé»æ°å°å·åè·¯ã補é ãããç±³åœ
ç¹èš±ç¬¬3837860å·æ现æžã«èšèŒã®ããã«ããŠè£œé
ãããïŒâãžã¢ãŸâïŒâããããŒã«âïŒâã¹ã«ã
ãã«ã¯ããªã12éšã20éšã®ãžãªããµã³ã«å ããã
ããŠãã®æ··åç©ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒããã
ãã·ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒ90ïŒ10ïŒå ±éåäœ20
éšãå«æãã50éšã®ãžãªããµã³æº¶æ¶²ã«åŸã ã«å ã
ããïŒïŒ çé žãããªãŠã 溶液10éšã®æ·»å ã¯ãã®æº¶
液ã玫è²ã«ãããããã«ãã€ãŠæžåãžã¢ãŸãã€ã
ã³åºãå«æããå ±éåäœã圢æãããããã®å ±é
åäœãæ°Žã§æ²æ®¿ãããéããããŠäŸïŒèšèŒã®äº€å
çµåéåäœããŒãº9.3éšãåæ£å«æãããžãªããµ
ã³äžã«æº¶è§£ãããããã®ã³ãŒãã€ã³ã°çµæç©ã¯çŽ
20.0ïŒ ã®åºäœåããžãªããµã³äžã«å«æããŠããã
ãããŠããã4.57ïœïŒåã§ç§»åããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããŠãšãäžã«äŸïŒèšèŒã®ããã«ããŠ
ã³ãŒãã€ã³ã°ãããããŠä¹Ÿç¥ãããã也ç¥ã¯ããŒ
ãºã®ååšãªãã®20ïŒ ãžã¢ãŸããã³éåäœå«æã®å
æ§ã®ã³ãŒãã€ã³ã°çµæç©ã®ããããææã«æ©ãã
ãã®æ¯æãã€ã«ã ãšå ±ã«äº€åçµåéåäœããŒãºã
å«æãã也ç¥ã³ãŒãã€ã³ã°çµæç©è©Šæãå æåæ§
å±€ã®è¡šé¢ãé è¡šé¢ã«æ¥è§Šç¶æ ãšããŠé 被èŠãšãã
ã·ãã¢ã€ããŒã°ã©ã¹ æ¿ã®æž æµãªçã«ç©å±€ãã
ããç©å±€ã¯120âã®ãŽã 被èŠããŒã©ãŒã®å©ããã
ããŠå®æœããããåŸãããã¬ãžã¹ã被èŠãšã¬ã¡ã³
ããããã®äžã«é»æ°åè·¯ãã¿ãŒã³ã®éœç»åãæã
ãéæç»ãéããŠ16ã€ã³ãïŒ40.64cmïŒã®è·é¢ã§
500ã¯ããã®æ°Žéç¯å æºã䜿çšããŠïŒåéåæ§é²
å ããããé²å åŸãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒã
æ¯æäœãã€ã«ã ãã¬ãžã¹ãããå¥é¢ããã次ãã§
ïŒïŒ æ°Žæ§ããªãããªãŠã çé žã§é²å éšåãæŽå»ã
ãããšã«ãã€ãŠãã®æ¿ãçŸåãããããã®æ®µéã¯
é²å éæç»ã®äžéæéšåã®ãã¿ãŒã³ã§ã¬ãžã¹ãã
é äžã«æ®ããããããŠéœç»åãäžãããé²å éæ
ç»ã®éæéšåã«çžåœããå¯æº¶æ§ã¬ãžã¹ãã®æŽå»ã«
ããé²å ãããåéšåã¯ãã®æ¿ã45ãããŒã¡ã®å¡©
å第ïŒé溶液äžã«çœ®ãããšã«ãããšããã·ãã¢ã€
ããŒã°ã©ã¹ ã®ãšãããŸã§ãšããã³ã°ããããã
ã¯ãã¢ã€ããŒã°ã©ã¹ æ¿äžã«ã¬ãžã¹ã被èŠé å°äœ
ãã¿ãŒã³ãæ®ããæåŸã«ãã®ã¬ãžã¹ããåžå Žçã«
å ¥æå¯èœãªã¡ã¿ããŒã«ïŒãžã¯ããã¡ã¿ã³ïŒ10ïŒ
90ïŒã®å¥é¢ïŒã¹ããªããã³ã°ïŒå€ã䜿çšããŠé å
è·¯ããé€å»ããã å¯Ÿç §äŸ ïŒ æ¬äŸã¯å¯Ÿç §äŸã§ããã次ã®ããã«ããŠïŒçš®ã®ã³
ãŒãã€ã³ã°çµæç©ã補é ããã
ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ããåŸãããæ®å溶åªé
ãšã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã®ãããšã®éã«ã¯é¡
èãªå·®ãååšããããšãèªããããã4.57ïœïŒå
ã§ã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããåŸãããæ®å溶åª
éã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã10.67ïœïŒåããª
ãã¡ïŒå以äžéãã³ãŒãã€ã³ã°ããå Žåã«åŸãã
ããã®ããã倧ã§ãããéåäœç¶çµåå€ããã³ã
ãŒãºã®åèšééã®40ïŒ ã亀åçµåéåäœããŒãºã§
ããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã¯åèšæ®å溶åªãçŽ
0.4ïŒ ä»¥äžã«æžå°ãããçšåºŠãŸã§ä¹Ÿç¥ããããã
ã«ã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ïŒå¯Ÿç §ïŒã®åå以äž
ã®æéããå¿ èŠãšããªãã€ããéåäœç¶çµåå€ãš
ããŒãºãšã®åèšééã®20ïŒ ã亀åçµåéåäœããŒ
ãºã§ããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ£ã¯ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¡ãšã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãšã®äžéã®çµæã
äžãããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã®ã³ãŒãã€ã³
ã°ã¯4.57ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã®0.3ïŒ
ïœm2ãã10.67ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã®
20ïŒïœm2ã®ç¯å²ã§æ³¡æ¬ é¥ïŒbubble defectsïŒãå«
æããŠãããæ³¡æ¬ é¥ã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãã
ã³ïŒ£ããã®ã³ãŒãã€ã³ã°äžã«ã¯ã¿ãããªãã€ãã ãããã4.57ïœïŒåã§è£œé ãããã³ãŒãã€ã³ã°
åæ£æ¶²ïŒ¡ãããã³ïŒ£ããã®è©Šæã也ç¥ãã€ã«ã
ããã¬ãžã¹ããšããŠè©Šéšããã也ç¥ãã€ã«ã ã®é
ãžã®ç©å±€ã¯220ãïŒ104.4âïŒã§å®æœãããããã€
ã«ã å¯ææ§ãåçé床ãç»åå質ãFeCl3ã«ãã
ãšããã³ã°çµæãããã³é ãã€ãã¯ïŒçš®ã®ããã¬
ãžã¹ãããããã«å¯ŸããŠå®è³ªçã«åäžã§ãã€ãã
ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ããã³ïŒ¢ãã補é ãããã
ãã¬ãžã¹ãã«å¯ŸããŠèŠæ±ãããçŸåæéã¯æ¬¡ã®é
ãã§ãã€ãã æéïŒç§ïŒ ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ 105 ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ 68 çŸåã¯ã也ç¥ãã€ã«ã ç©å±€äœãä¿æãããããŠ
ã¡ãã«ã¯ãããã«ã 溶åªããã³ãã§ãã®äžã®ã¹ã
ã¬ãŒããºã«ã«æ±²ã¿å ¥ããŠããªãé«é床ã§æ¿ïŒããŒ
ãïŒãã¿ãŒã³ã«æº¶åªãéãåºãã¹ãã¬ãŒããã»ãµ
ãŒäžã§å®æœãããã也ç¥ã³ãŒãã€ã³ã°ïŒ¡ããã
ã³ïŒ£ã®ç Žæç¹äŒžé·ã¯æ¬¡ã®éãã§ãã€ãã ç Žæç¹äŒžé·ïŒïŒ ïŒ ïŒ¡ 360  670  437 äŸ ïŒ ïŒ¡ æ¹æ³ 亀åçµåéåäœããŒãºã®è¡šé¢ãšã¹ãã«åºãå
æ°Žå解åŠçããŠã«ã«ããã·ã«åºãšãããäŸïŒèš
èŒã®ããã«ããŠè£œé ãããããŒãºã®40.0ïœåºå
éãã(H)宀枩ã«ãããŠïŒæéïŒïŒ æ°Žæ§æ°Žé žåã
ããªãŠã 48.4ïœãšã(I)54ã57âã«ãããŠ20åé
10ïŒ æ°Žæ§æ°Žé žåãããªãŠã 33.3ïœãšã(J)57ã62
âã«ãããŠ40åéïŒïŒ æ°Žæ§æ°Žé žåãããªãŠã
48.4ïœãšã(K)60ã65âã«ãããŠ50åéïŒïŒ æ°Žæ§
æ°Žé žåãããªãŠã 48.4ïœãšããããŠ(L)60ã70â
ã«ãããŠçŽïŒæéïŒïŒ æ°Žæ§æ°Žé žåãããªãŠã
48.4ïœãšããããå ±ã«æ¹æãããåŠçåŸãåã¹
ã©ãªãŒãçŽ100mlã®æ°·å·æ°Žã«æ³šããããŠé å¿ã
ããäžæŸæ¶²ã®ç²åºŠããªã¹ã¯ã«ãããããã䜿çš
ããŠæž¬å®ãããç²åºŠã¯åæ§ã«åžéãããæ°Žé žå
ãããªãŠã ã®ç²åºŠïŒ1.2cps以äžïŒãšææã«ç°ãª
ããã®ã§ã¯ãªãã€ãããã ãè©Šæã¯13.4cps
ã®ç²åºŠãæããŠããããã®ããšã¯è©Šæãã§
ã¯å æ°Žå解ã¯è¡šé¢ã«éå®ãããŠããããããè©Š
æã§ã¯å æ°Žå解ã¯æŽã«é²ãã§æº¶æ¶²äžã«éåäœ
ïŒããªã¢ã¯ãªã«é žïŒãçæããããšã瀺ããŠã
ããé å¿ããããŒãºã120mlã®æ°Žã§æ¹æããã
ãŠåé å¿ããããšã«ããïŒåæŽã€ãã次ãã§æŽ
ã€ãè©Šæã也ç¥ããããè©Šæäžã®ã«ã«ããã·ã«
åºã®ååšã¯0.1ïœã®ä¹Ÿç¥ç²æ«ãïŒmlãŸãã¯ïŒml
ã®æ°Žãšæ¹æãããããŠæ¬¡ãã§æ°Ž80mläžã®0.1ïœ
ã®ã¡ãã¬ã³ãã«ãŒããã³20mlã®PHïŒã®ãããã¢
ãŒæº¶æ¶²10.0mlãå ããããšã«ãã瀺ããããã
ã®æ··åç©ãé å¿ããäžæŸã¿ãæšãŠããããŠæ²æ®¿
ã35mlã®æ°Žãšæ¹æããããŠåé å¿ããããšã«ã
ã€ãŠïŒåæŽã€ãã次ãã§æ²æ®¿ãçŽäžã§ä¹Ÿç¥ã
ãããéè²ã®æ·±ãã¯ïŒšãã®é ã«äžæãããè©Š
æã¯æ·¡éè²ã§ãããããŠè©Šæã¯éåžžã«æè²
ã§ãã€ãã  æ¬çºæã®ããŒãºã®è£œé ããã³äœ¿çš åèšè©Šæã®ããã«ããŠäœã500ïœã®ããã
ã§è©Šæã補é ããã375mlã®æ°Žäžæ°Žé žåãããª
ãŠã 41.6ïœã®æº¶æ¶²ã70âã«å ç±ãããããŠäŸïŒ
èšèŒã®500ïœã®éåäœããŒãºãæ¹æãã€ã€å ã
ãã枩床ãåŸããã53âãã60âã«ïŒåéãã
ãŠäžæãããããããŠåœ¢æãããã¹ã©ãªãŒã50
åé60ã65âã§æ¹æããããã®ã¹ã©ãªãŒã1500
mlã®æ°·æ°Žã«å ãããããŠæ¬¡ãã§é å¿ããããäž
æŸã¿ã®ç²åºŠã¯åæ§ã«åžéãããæ°Žæ§æ°Žé žåãã
ãªãŠã ã®ãããšææã«ã¯ç°ã€ãŠããªãã€ããæ²
殿ãçŽïŒã®æ°Žãšæ¹æãããããŠPHã2.5ã«èª¿
æŽããŠè¡šé¢ã«ã«ã«ããã·ã«åºãçæããããã
ã®ã¹ã©ãªãŒãæŽã«çŽïŒã«åžéããããŠé å¿ã
ãããããŒãºãçŽïŒã«åžéããããŠåé å¿ã
ãããšã«ããïŒåæŽãããããŠæåŸã«é¢šä¹Ÿãã
ããåéã¯çŽ480ïœã§ãã€ãã äŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã«ããããããªå¯Ÿ
ç §çµæç©ãšãäŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ãšåæ§
ã§ããããã®äŸã«ãããéåäœããŒãºã®ä»£ãã«é
åäœçµåå€ãšããŒãºãšã®åèšééã®ïŒïŒ ãåèšã®
ããã«ããŠè£œé ãããã«ã«ããã·ã«ïŒå æ°Žå解ïŒ
è¡šé¢ãæããããŒãºã§ãããããªçµæç©ãšã®ä¹Ÿç¥
é床ãæ¯èŒããããã®çµæã¯äŸïŒã®ãããšåæ§ã§
ãã€ãã亀åçµåããŒãºå«æçµæç©ã¯ã9.14ïœïŒ
åã§ã³ãŒãã€ã³ã°ãããå Žå4.57ïœïŒåã§ã³ãŒã
ã€ã³ã°ãããå¯Ÿç §ãšå€§çŽåéã®æ®å溶åªãäžã
ããããªãã¡ããã¯çŽïŒåè¿ éã«ä¹Ÿç¥ããããã®
çµæç©ããŸã也ç¥ãã€ã«ã ããã¬ãžã¹ããšããŠäœ¿
çšãããå Žåã®å¯Ÿç §ã³ãŒãã€ã³ã°ãšãæ¯èŒããã
åçé床ããã³ãšããã³ã°ããã³ãã€ãå質ãã
ã³äŸïŒèšèŒã®å®æåè·¯ããã®å éåäœå±€ã®å¥é¢ã«
ãããŠåæ§ã®çµæãåŸãããããã®ã©ãïŒlabïŒ
ã³ãŒãã€ã³ã°ã®ç Žæç¹äŒžé·ã¯570ïŒ ã§ãã€ãã äŸ ïŒ æ¬¡ã®ããã«ããŠã³ãŒãã€ã³ã°çµæç©ã補é ã
ãã éš äº€åçµåããŒãºïŒäŸïŒåç §ïŒ 55.52 ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã 13.10 ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒã 13.10 é«ååéããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒåºæç²åºŠ
2.7ïŒ 6.620 ããã©ãŒã®ã±ãã³ 0.106 ãã³ãŸããšãã³ 3.517 ãã¹ïŒïŒâïœâã¯ããããšãã«âïŒïŒïŒâãã¹
âããšãã«ïŒã€ãããŸãŒã« 2.193 ããªã¹âïŒïŒâãžãšãã«ã¢ããâïœâããªã«ïŒ
ã¡ã¿ã³ 0.132 ïŒïŒ4â²ïŒ4â³âã¡ããªãžã³ããªã¹ïŒïŒ®ïŒïŒ®âãžã¡
ãã«ã¢ããªã³ïŒ 0.088 ãã¯ããªã¢ã°ãªãŒã³ïŒC.I.ãã°ã¡ã³ãã°ãªãŒã³
18ïŒ 0.031 ã¢ãã¹ãã©ã«ã°ãªãŒã³ãã°ã¡ã³ãïŒC.I.ãã°ã¡
ã³ãã°ãªãŒã³ïŒïŒ 0.098 ãªã«ãâããã³ãã©ãŒãã«ãšã³ã¹ã«ãã³ã¢ãã
æ··åç© 5.275 ãã³ãŸããªã¢ãŸãŒã« 0.176 ïœâãã«ãšã³ã¹ã«ãã³é ž 0.044 èš 100ïŒ000 溶åªCH2Cl2 196.2 ããŒãºã¯ã¡ãã¬ã³ã¯ããªãäžã®28.9ïŒ ã¹ã©ãªãŒ
ãšããŠããããŠããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã¯ïŒïŒ
溶液ãšããŠå ããããããããçµæç©ãåãïŒã
ã§ã«èŠæ±éã®æº¶åªãå«æïŒãããŠæ®åæåãå ã
ãããã®ã³ãŒãã€ã³ã°çµæç©ã¯33.8ïŒ ã®æŽ»æ§æå
ãå«æããŠããã äŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ãšåæ§ã«ããŠå¯Ÿç §
ã³ãŒãã€ã³ã°çµæç©ã補é ããããã ããã®æº¶åª
ã¯ã¡ãã¬ã³ã¯ããªãïŒïŒâãšããã·ãšã¿ããŒã«æ··
åç©ã§ãã代ãã«20732ïœã®çŽã¡ãã¬ã³ã¯ããªã
ã§ãã€ãŠ33.8ïŒ æŽ»æ§æåã®æº¶æ¶²ãçæãããã也
ç¥é床ãäŸïŒã«ãããããã«ããŠäŸïŒã«ããããš
åäžã®ã³ãŒã¿ãŒããã³ïŒæ®µéãã©ã€ã€ãŒã䜿çšã
ãããŠ50.8ÎŒïœåãã«ã³ãŒãã€ã³ã°ããŠæ¯èŒããã
ããŒãºå«æçµæç©ããã®æ®å溶åªéã¯ã10.67
ïœïŒåã§ã³ãŒãã€ã³ã°ããå Žåã«ã¯4.57ïœïŒåã§
ã³ãŒãã€ã³ã°ãããå¯Ÿç §ãããææã«äžå±€äœãã
ããŠããã¯å¯Ÿç §ã®20ïŒ ã«æ¯ã¹ãŠ0.10ïŒ ã§ãããã
ã®ä¹Ÿç¥ã³ãŒãã€ã³ã°ãé æ¿ã«ç©å±€ãããããŠäŸïŒ
èšèŒã®ããã«åŠçããŠæ¿äžã«é åè·¯ãçæãã
ãããã®ä¹Ÿç¥ã³ãŒãã€ã³ã°çµæç©ã®ç Žæç¹äŒžé·ã¯
700ïŒ ã§ããã äŸ ïŒ äŸïŒã«èšèŒã®äº€åçµåããŒãºã®è£œé ããããã
ããããã ã500ïœã®ããªã¡ãã«ãããã³ããªã¢
ã¯ãªã¬ãŒãã®ä»£ãã«ç¬¬ïŒã®å®éš(F)ã§ã¯500ïœã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãã䜿çšãã
ãããŠä»ã®å®éš(G)ã§ã¯250ïœã®ããªã¡ãããŒã«ã
ããã³ããªã¢ã¯ãªã¬ãŒããš250ïœã®ããªãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããšã®æ··åç©ã䜿çšãã
ããã³ãŒãã€ã³ã°çµæç©ã¯çŽïŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¢ãšåæ§ã«ããŠè£œé ãããããã ã第ïŒã®å®
éšã«ãããŠã¯äœ¿çšããã亀åçµåããŒãºã¯ã³ãŒã
ã€ã³ã°åæ£æ¶²ïŒ§ã®ãã®ã§ãããããŠç¬¬ïŒã®å®éšã«
ãããŠã¯ããã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒŠã®ãã®ã§ã
ããäŸïŒã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ãšãšåæ§ã®ã³ãŒ
ãã€ã³ã°çµæç©ãå¯Ÿç §ãšããŠã³ãŒãã€ã³ã°ããã
ãã®çµæã¯åèšã®ãã®ãšåæ§ã§ãããããŒãº(F)ãŸ
ãã¯(G)ãå«æããã³ãŒãã€ã³ã°åæ£æ¶²ã«å¯Ÿãã
10ïŒ67ïœïŒåã«ããã也ç¥æéã¯4.57ïœïŒåã«ã
ããçŽ0.4ïŒ æ®å溶åªã®ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¡ã«
察ãããã®ãšå€§çŽåäžã§ãããããªãã¡ä¹Ÿç¥ã¯
0.4ïŒ æº¶åªæ°Žæºãéæããã«ïŒåæ©ãããããçµ
æç©ãåèšã®ããã«ããŠé ã«ç©å±€ãããããŠé©åœ
ãªããã¬ãžã¹ãç»åãé²å ããã³çŸååŸã«é äžã«
åŸããããããã³ïŒ§ã«çžåœãã也ç¥ã³ãŒãã€ã³
ã°çµæç©ã®ç Žæç¹äŒžé·ã¯400ïŒ ä»¥äžã§ããã äŸ ïŒ æ¬¡ã®ããã«ããŠé»æ°å°å·åè·¯ã補é ãããç±³åœ
ç¹èš±ç¬¬3837860å·æ现æžã«èšèŒã®ããã«ããŠè£œé
ãããïŒâãžã¢ãŸâïŒâããããŒã«âïŒâã¹ã«ã
ãã«ã¯ããªã12éšã20éšã®ãžãªããµã³ã«å ããã
ããŠãã®æ··åç©ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒããã
ãã·ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒ90ïŒ10ïŒå ±éåäœ20
éšãå«æãã50éšã®ãžãªããµã³æº¶æ¶²ã«åŸã ã«å ã
ããïŒïŒ çé žãããªãŠã 溶液10éšã®æ·»å ã¯ãã®æº¶
液ã玫è²ã«ãããããã«ãã€ãŠæžåãžã¢ãŸãã€ã
ã³åºãå«æããå ±éåäœã圢æãããããã®å ±é
åäœãæ°Žã§æ²æ®¿ãããéããããŠäŸïŒèšèŒã®äº€å
çµåéåäœããŒãº9.3éšãåæ£å«æãããžãªããµ
ã³äžã«æº¶è§£ãããããã®ã³ãŒãã€ã³ã°çµæç©ã¯çŽ
20.0ïŒ ã®åºäœåããžãªããµã³äžã«å«æããŠããã
ãããŠããã4.57ïœïŒåã§ç§»åããããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããŠãšãäžã«äŸïŒèšèŒã®ããã«ããŠ
ã³ãŒãã€ã³ã°ãããããŠä¹Ÿç¥ãããã也ç¥ã¯ããŒ
ãºã®ååšãªãã®20ïŒ ãžã¢ãŸããã³éåäœå«æã®å
æ§ã®ã³ãŒãã€ã³ã°çµæç©ã®ããããææã«æ©ãã
ãã®æ¯æãã€ã«ã ãšå ±ã«äº€åçµåéåäœããŒãºã
å«æãã也ç¥ã³ãŒãã€ã³ã°çµæç©è©Šæãå æåæ§
å±€ã®è¡šé¢ãé è¡šé¢ã«æ¥è§Šç¶æ ãšããŠé 被èŠãšãã
ã·ãã¢ã€ããŒã°ã©ã¹ æ¿ã®æž æµãªçã«ç©å±€ãã
ããç©å±€ã¯120âã®ãŽã 被èŠããŒã©ãŒã®å©ããã
ããŠå®æœããããåŸãããã¬ãžã¹ã被èŠãšã¬ã¡ã³
ããããã®äžã«é»æ°åè·¯ãã¿ãŒã³ã®éœç»åãæã
ãéæç»ãéããŠ16ã€ã³ãïŒ40.64cmïŒã®è·é¢ã§
500ã¯ããã®æ°Žéç¯å æºã䜿çšããŠïŒåéåæ§é²
å ããããé²å åŸãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒã
æ¯æäœãã€ã«ã ãã¬ãžã¹ãããå¥é¢ããã次ãã§
ïŒïŒ æ°Žæ§ããªãããªãŠã çé žã§é²å éšåãæŽå»ã
ãããšã«ãã€ãŠãã®æ¿ãçŸåãããããã®æ®µéã¯
é²å éæç»ã®äžéæéšåã®ãã¿ãŒã³ã§ã¬ãžã¹ãã
é äžã«æ®ããããããŠéœç»åãäžãããé²å éæ
ç»ã®éæéšåã«çžåœããå¯æº¶æ§ã¬ãžã¹ãã®æŽå»ã«
ããé²å ãããåéšåã¯ãã®æ¿ã45ãããŒã¡ã®å¡©
å第ïŒé溶液äžã«çœ®ãããšã«ãããšããã·ãã¢ã€
ããŒã°ã©ã¹ ã®ãšãããŸã§ãšããã³ã°ããããã
ã¯ãã¢ã€ããŒã°ã©ã¹ æ¿äžã«ã¬ãžã¹ã被èŠé å°äœ
ãã¿ãŒã³ãæ®ããæåŸã«ãã®ã¬ãžã¹ããåžå Žçã«
å ¥æå¯èœãªã¡ã¿ããŒã«ïŒãžã¯ããã¡ã¿ã³ïŒ10ïŒ
90ïŒã®å¥é¢ïŒã¹ããªããã³ã°ïŒå€ã䜿çšããŠé å
è·¯ããé€å»ããã å¯Ÿç §äŸ ïŒ æ¬äŸã¯å¯Ÿç §äŸã§ããã次ã®ããã«ããŠïŒçš®ã®ã³
ãŒãã€ã³ã°çµæç©ã補é ããã
ãè¡šã
ãè¡šã
äŸïŒã«èšèŒã®ããã«ããããŠãŸã4.0ïœïŒåã
ãã³12.2ïœïŒåã«ãããŠã³ãŒãã€ã³ã°ã補é ã
ãã12.2ïœïŒåã«ãããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¥ã®
ç·æ®å溶åªã¯4.0ïœïŒåã§ã®ã³ãŒãã€ã³ã°åæ£æ¶²
ã®ããïŒ0.3ïŒ ïŒãããæŽã«äœããããªãã¡ã³
ãŒãã€ã³ã°åæ£æ¶²ïŒ¥ã0.3ïŒ ã®æ®å溶åªæ°ŽæºãŸã§
也ç¥ãããã«å¿ èŠãªæéã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ€
ãåäžæ°ŽæºãŸã§ä¹Ÿç¥ãããã«èŠããæéã®1/3以
äžã§ãããäž¡æ¹ã®ã³ãŒãã€ã³ã°ãé ã«ç©å±€ããã
éæç»ãéããŠ2000ã¯ããããŒããŒâã¢ã¹ã³ãŒã«
æ°Žéãã»ãã³ã¢ãŒã¯ã«30ç§éé²å ãããäŸïŒèšèŒ
ã®ã¹ãã¬ãŒããã»ããµãŒäžã§30ç§é43âã«ãããŠ
ïŒïŒ æ°Žæ§çé žãããªãŠã ã§çŸåãããæŽããããŠ
也ç¥ããŠé è¡šé¢äžã«ããã¬ãžã¹ãåãçæãã
ãã也ç¥ã³ãŒãã€ã³ã°çµæç©ã®ç Žæç¹äŒžé·ã¯ïŒ€ã«
察ããŠã¯245ïŒ ã§ãããããŠïŒ¥ã«å¯ŸããŠã¯10ïŒ ã§
ãã€ããã®å±€åãã¯0.12ã€ã³ãïŒ0.30mmïŒã§ã
ã€ãããã«å¯Ÿãããã®äœã䌞é·å€ã¯èãã³ãŒã
ã€ã³ã°ã§ããããšã瀺ãããã®å¯Ÿç §ã¯æ¯èŒçäœå
åéã®éåäœç¶çµåå€ã¯çŽ85ïŒ ã®äº€åçµåããŒãº
ã«ãã眮æã§ããªãããšã瀺ãã å¯Ÿç §äŸ ïŒ ïŒçš®ã®ã³ãŒãã€ã³ã°åæ£æ¶²ã補é ãããïŒçš®ã®
ã³ãŒãã€ã³ã°åæ£æ¶²ã¯ç¬¬ïŒèšèŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¡ããã³ïŒ¢ã§ãã€ãã第ïŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã®è£œé ãšåäžã®æ¹
æ³ã§è£œé ãããããã ãçŽ2.0ÎŒïœå¹³åç²åãµã€ãº
ã®ããªãšãã¬ã³ããŒãºã䜿çšããã³ãŒãã€ã³ã°å
æ£æ¶²ïŒã§ãã€ãããã®ã³ãŒãã€ã³ã°ïŒã¯éåžžã«è
ãããšã芳å¯ãããã0.006ã€ã³ãïŒ0.15mmïŒãŸ
ãã¯0.02ã€ã³ãïŒ0.30mmïŒã®ç©å±€äœã¯å¯Ÿç §äŸïŒã®
ã³ãŒãã€ã³ã°ïŒ¥ãšåæ§ã«ç Žæãªãã«åæ±ãããšã¯
éåžžã«å°é£ã§ãã€ãã
ãã³12.2ïœïŒåã«ãããŠã³ãŒãã€ã³ã°ã補é ã
ãã12.2ïœïŒåã«ãããã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¥ã®
ç·æ®å溶åªã¯4.0ïœïŒåã§ã®ã³ãŒãã€ã³ã°åæ£æ¶²
ã®ããïŒ0.3ïŒ ïŒãããæŽã«äœããããªãã¡ã³
ãŒãã€ã³ã°åæ£æ¶²ïŒ¥ã0.3ïŒ ã®æ®å溶åªæ°ŽæºãŸã§
也ç¥ãããã«å¿ èŠãªæéã¯ã³ãŒãã€ã³ã°åæ£æ¶²ïŒ€
ãåäžæ°ŽæºãŸã§ä¹Ÿç¥ãããã«èŠããæéã®1/3以
äžã§ãããäž¡æ¹ã®ã³ãŒãã€ã³ã°ãé ã«ç©å±€ããã
éæç»ãéããŠ2000ã¯ããããŒããŒâã¢ã¹ã³ãŒã«
æ°Žéãã»ãã³ã¢ãŒã¯ã«30ç§éé²å ãããäŸïŒèšèŒ
ã®ã¹ãã¬ãŒããã»ããµãŒäžã§30ç§é43âã«ãããŠ
ïŒïŒ æ°Žæ§çé žãããªãŠã ã§çŸåãããæŽããããŠ
也ç¥ããŠé è¡šé¢äžã«ããã¬ãžã¹ãåãçæãã
ãã也ç¥ã³ãŒãã€ã³ã°çµæç©ã®ç Žæç¹äŒžé·ã¯ïŒ€ã«
察ããŠã¯245ïŒ ã§ãããããŠïŒ¥ã«å¯ŸããŠã¯10ïŒ ã§
ãã€ããã®å±€åãã¯0.12ã€ã³ãïŒ0.30mmïŒã§ã
ã€ãããã«å¯Ÿãããã®äœã䌞é·å€ã¯èãã³ãŒã
ã€ã³ã°ã§ããããšã瀺ãããã®å¯Ÿç §ã¯æ¯èŒçäœå
åéã®éåäœç¶çµåå€ã¯çŽ85ïŒ ã®äº€åçµåããŒãº
ã«ãã眮æã§ããªãããšã瀺ãã å¯Ÿç §äŸ ïŒ ïŒçš®ã®ã³ãŒãã€ã³ã°åæ£æ¶²ã補é ãããïŒçš®ã®
ã³ãŒãã€ã³ã°åæ£æ¶²ã¯ç¬¬ïŒèšèŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ïŒ¡ããã³ïŒ¢ã§ãã€ãã第ïŒã®ã³ãŒãã€ã³ã°å
æ£æ¶²ã¯ãã³ãŒãã€ã³ã°åæ£æ¶²ïŒ¢ã®è£œé ãšåäžã®æ¹
æ³ã§è£œé ãããããã ãçŽ2.0ÎŒïœå¹³åç²åãµã€ãº
ã®ããªãšãã¬ã³ããŒãºã䜿çšããã³ãŒãã€ã³ã°å
æ£æ¶²ïŒã§ãã€ãããã®ã³ãŒãã€ã³ã°ïŒã¯éåžžã«è
ãããšã芳å¯ãããã0.006ã€ã³ãïŒ0.15mmïŒãŸ
ãã¯0.02ã€ã³ãïŒ0.30mmïŒã®ç©å±€äœã¯å¯Ÿç §äŸïŒã®
ã³ãŒãã€ã³ã°ïŒ¥ãšåæ§ã«ç Žæãªãã«åæ±ãããšã¯
éåžžã«å°é£ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšã®ã (a) æå(a)ã(d)ã®ééåºæºã§ïŒã45ééïŒ ã®ãå°
ãªããšãïŒåã®æ«ç«¯ãšãã¬ã³åºãæãããéé¢
ã©ãžã«ã«éå§é£é延é·ä»å éåã«ããé«ååé
åäœã圢æãããå°ãªããšãïŒçš®ã®éã¬ã¹ç¶ãš
ãã¬ã³æ§äžé£œåååç©ã (b) æå(a)ã(d)ã®ééåºæºã§0.05ã10ééïŒ ã®ã
äžé£œåååç©ã®éåãéå§ããã掻æ§ç·ç §å°ã«
ãã掻æ§åå¯èœãªææ©ç §å°æåæ§éé¢ã©ãžã«ã«
çæç³»ã (c) å°ãªããšãïŒçš®ã®ææ©éåäœçµåå€ã (d) 0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠã
ã®æ°ã®å°ãªããšã90ïŒ ã10ÎŒïœããå°ãããã
ããŠææ©éåäœçµåå€æåã«å¯Ÿãã溶åªããã³
éåäœããŒãºã®è£œé ã«äœ¿çšãããåéäœã«å¯Ÿã
ã溶åªã«äžæº¶æ§ã§äžã€éåéæ§ã§ãããã°ãã°
ãã§å®è³ªçã«éèšæœ€æ§ã®äº€åçµåéåäœããŒ
ãºãããã§è©²äº€åçµåéèšæœ€æ§éåäœããŒãº
ã¯ãããªã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒãã
ããªã¡ã¿ã¯ãªã¬ãŒããŸãã¯ããã©ã¡ã¿ã¯ãªã¬ãŒ
ãåéäœã®ãã¢éåäœïŒåèšããªã¢ã¯ãªã¬ãŒ
ããããã©ã¢ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬ãŒã
ããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãåéäœã®ïŒçš®ä»¥äž
ã®å ±éåäœïŒåèšããªã¢ã¯ãªã¬ãŒããããã©ã¢
ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬ãŒãããã³ããã©
ã¡ã¿ã¯ãªã¬ãŒãåéäœã®å°ãªããšãïŒçš®ãš25é
éïŒ ãŸã§ã®ïŒåã®æ«ç«¯ãšãã¬ã³åºå«æåéäœã®
å°ãªããšãïŒçš®ãšã®å ±éåäœïŒãªãã³ã«åèšã
ãªã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒããããªã¡
ã¿ã¯ãªã¬ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãåé
äœã®å°ãªããšãïŒçš®ãš75ééïŒ ãŸã§ã®åèšããª
ã¢ã¯ãªã¬ãŒããŸãã¯ããªã¡ã¿ã¯ãªã¬ãŒãåéäœ
ãšã¯ç°ã€ãïŒåã®æ«ç«¯ãšãã¬ã³åºãŸãã¯ïŒåã®
æ«ç«¯ãšãã¬ã³åºãå«æããåéäœã®å°ãªããšã
ïŒçš®ã®å ±éåäœïŒãããªã矀ããéžã°ãããã®
ã§ãããããã³ (e) æå(a)ã(b)ããã³(c)ã«å¯Ÿããå°ãªããšãïŒçš®
ã®æº¶åª ããæ¬è³ªçã«ãªãããããŠæå(a)ã(d)ã®å šééåº
æºã§æå(c)ããã³(d)ã®çµåãã®åèšééïŒ ã40ã
70ééïŒ ã§ãããæå(d)ãæå(c)ããã³(d)ã®éé
åºæºã§15ã90ééïŒ éã§ååšããŠããããšãç¹åŸŽ
ãšãããå æåæ§ã³ãŒãã€ã³ã°çµæç©ã ïŒ äº€åçµåéåäœããŒãºãããªã¡ãããŒã«ãã
ãã³ããªã¢ã¯ãªã¬ãŒãããŒãºã§ããåèšç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°çµæ
ç©ã ïŒ äº€åçµåéåäœããŒãºããã®è¡šé¢ãå æ°Žå解
ãããã®ã§ããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
å æåæ§ã³ãŒãã€ã³ã°çµæç©ã ïŒ å æ°Žå解衚é¢ãé žæ§åºãå«æããŠããåèšç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°
çµæç©ã ïŒ ããŒãºè¡šé¢ãæ°Žé žåãããªãŠã ãŸãã¯æ°Žé žå
ã«ãªãŠã ã§åŠçãããŠããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°çµæç©ã ïŒ ææ©éåäœçµåå€ã0.5ã3.0ã®ç¯å²ã®åºæç²
床ãæããå°ãªããšãïŒçš®ã®ããªã¡ãã«ã¡ã¿ã¯ãª
ã¬ãŒãéåäœã§ããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®å æåæ§ã³ãŒãã€ã³ã°çµæç©ã ïŒ çµåå€(c)ãæ°Žæ§å¯æº¶æ§çµåå€ã§ããåèšç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°çµ
æç©ã ïŒ çµåå€ã«å¯Ÿãã溶åªãææ©æº¶åªã§ããåèšç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°
çµæç©ã ïŒ çµåå€ã«å¯Ÿããææ©æº¶åªãã¡ãã¬ã³ã¯ããª
ããïŒâãšããã·ãšã¿ããŒã«ãã¡ã¿ããŒã«ãŸãã¯
ãããã®çµåããããªã矀ããéžã°ããåèšç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å æåæ§ã³ãŒãã€ã³ã°çµ
æç©ã ïŒïŒ () åºæäžã« (a) æå(a)ã(d)ã®ééåºæºã§ïŒã45ééïŒ ã®ã
å°ãªããšãïŒåã®æ«ç«¯ãšãã¬ã³åºãæããã
éé¢ã©ãžã«ã«éå§é£é延é·ä»å éåã«ããé«
ååéåäœã圢æãããå°ãªããšãïŒçš®ã®é
ã¬ã¹ç¶ãšãã¬ã³æ§äžé£œåååç©ã (b) æå(a)ã(d)ã®ééåºæºã§0.05ã10ééïŒ
ã®ãäžé£œåååç©ã®éåãéå§ããã掻æ§ç·
ç §å°ã«ãã掻æ§åå¯èœãªææ©ç §å°æåæ§éé¢
ã©ãžã«ã«çæç³»ã (c) å°ãªããšãïŒçš®ã®ææ©éåäœçµåå€ã (d) 0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠ
ãã®æ°ã®å°ãªããšã90ïŒ ã10ÎŒïœããå°ã
ãããããŠææ©éåäœçµåå€æåã«å¯Ÿãã溶
åªããã³éåäœããŒãºã®è£œé ã«äœ¿çšãããå
éäœã«å¯Ÿãã溶åªã«äžæº¶æ§ã§äžã€éåéæ§ã§
ãããã°ãã°ãã§å®è³ªçã«éèšæœ€æ§ã®äº€åçµ
åéåäœããŒãºãããã§è©²äº€åçµåéèšæœ€æ§
éåäœããŒãºã¯ãããªã¢ã¯ãªã¬ãŒããããã©
ã¢ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬ãŒããŸãã¯ã
ãã©ã¡ã¿ã¯ãªã¬ãŒãåéäœã®ãã¢éåäœïŒå
èšããªã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒãã
ããªã¡ã¿ã¯ãªã¬ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬
ãŒãåéäœã®ïŒçš®ä»¥äžã®å ±éåäœïŒåèšããª
ã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒããããªã¡
ã¿ã¯ãªã¬ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãå
éäœã®å°ãªããšãïŒçš®ãš25ééïŒ ãŸã§ã®ïŒå
ã®æ«ç«¯ãšãã¬ã³åºå«æåéäœã®å°ãªããšãïŒ
çš®ãšã®å ±éåäœïŒãªãã³ã«åèšããªã¢ã¯ãªã¬
ãŒããããã©ã¢ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬
ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãã®å°ãªããš
ãïŒçš®ãš75ééïŒ ãŸã§ã®åèšããªã¢ã¯ãªã¬ãŒ
ããŸãã¯ããªã¡ã¿ã¯ãªã¬ãŒãåéäœãšã¯ç°ã€
ãïŒåã®æ«ç«¯ãšãã¬ã³åºãŸãã¯ïŒåã®æ«ç«¯ãš
ãã¬ã³åºãå«æããåéäœã®å°ãªããšãïŒçš®
ã®å ±éåäœïŒãããªã矀ããéžã°ãããã®ã§
ãããããã³ (e) æå(a)ã(b)ããã³(c)ã«å¯Ÿããå°ãªããšãïŒ
çš®ã®æº¶åª ããæ¬è³ªçã«ãªãããããŠæå(a)ã(d)ã®å šéé
åºæºã§æå(c)ããã³(d)ã®çµåãã®åèšééïŒ ã
40ã70ééïŒ ã§ãããæå(d)ãæå(c)ããã³(d)
ã®ééåºæºã§15ã90ééïŒ éã§ååšããŠããå
æåæ§ã³ãŒãã€ã³ã°çµæç©ããæ¬è³ªçã«ãªãå
éåæ§ä¹Ÿç¥ãã€ã«ã ã®è¡šé¢ãé©çšãã次ãã§ä»»
æã®é åºã§ () ãã®ä¹Ÿç¥ãã€ã«ã ã掻æ§ç·ç §å°ã«åæ§é²å
ãããŠåã圢æãããããŸã㯠() æ©æ¢°çå¥é¢ãŸãã¯æ¶²äœæº¶è§£ã«ãã€ãŠãã€ã«
ã è¡šé¢ããæ¯æäœãé€å»ã次ã㧠() é²å åŸã«ããŸã å¯èœæ§ã«çãŸã€ãŠãããã€
ã«ã éšåæŽå»ããŠåºæäžã«ã¬ãžã¹ãåãçæã
ãã ããšãããªããåºæäžã«ã¬ãžã¹ãåã圢æããã
æ¹æ³ã ïŒïŒ ã¬ãžã¹ãåã«ããä¿è·ãããŠããªãåºæè¡š
é¢ããšããã³ã°ãŸãã¯ãã€ãã«ãã€ãŠååŠçã«å€
æ§ãããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹
æ³ã ïŒïŒ () åºæäžã«ã (a) å°ãªããšãïŒçš®ã®å å¯æº¶åæ§ç©è³ªãš(c)å°ãª
ããšãïŒçš®ã®ææ©éåäœçµåå€ãæå(a)ãš(c)
ãšã¯æå(a)ããã³(c)ã®åèšééåºæºã§ããã
ã50ã95ééïŒ ããã³ïŒã50ééïŒ ãŸã§åšã
ããã®åå¿çæç©ã (b) çµæç©ã®å šééåºæºã§ïŒã10ééïŒ ã§æŽ»æ§
ç·ç §å°ã«ãã掻æ§åå¯èœãªç §å°æåæ§ååç©
ãŸãã¯ç³»ãããã³ (d) 0.02ã4.0ÎŒïœç¯å²ã®å¹³åçŽåŸãæããããŠ
ãã®ããŒãºæ°ã®å°ãªããšã90ïŒ ã10ÎŒïœãã
å°ããããããŠææ©éåäœçµåå€æåã«å¯Ÿã
ã溶åªããã³åèšéåäœããŒãºã®è£œé ã«äœ¿çš
ãããåéäœã«å¯Ÿãã溶åªã«äžæº¶æ§ã§äžã€å
éæ§ã§ãããã°ãã°ãã§å®è³ªçã«éèšæœ€æ§ã®
亀åçµåããŒãºãããã§è©²äº€åçµåéèšæœ€æ§
éåäœããŒãºã¯ãããªã¢ã¯ãªã¬ãŒããããã©
ã¢ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬ãŒããŸãã¯ã
ãã©ã¡ã¿ã¯ãªã¬ãŒãåéäœã®ãã¢éåäœïŒå
èšããªã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒãã
ããªã¡ã¿ã¯ãªã¬ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬
ãŒãåéäœã®ïŒçš®ä»¥äžã®å ±éåäœïŒåèšããª
ã¢ã¯ãªã¬ãŒããããã©ã¢ã¯ãªã¬ãŒããããªã¡
ã¿ã¯ãªã¬ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãå
éäœã®å°ãªããšãïŒçš®ãš25ééïŒ ãŸã§ã®ïŒå
ã®æ«ç«¯ãšãã¬ã³åºå«æåéäœã®å°ãªããšãïŒ
çš®ãšã®å ±éåäœïŒãªãã³ã«åèšããªã¢ã¯ãªã¬
ãŒããããã©ã¢ã¯ãªã¬ãŒããããªã¡ã¿ã¯ãªã¬
ãŒãããã³ããã©ã¡ã¿ã¯ãªã¬ãŒãã®å°ãªããš
ãïŒçš®ãš75ééïŒ ãŸã§ã®åèšããªã¢ã¯ãªã¬ãŒ
ããŸãã¯ããªã¡ã¿ã¯ãªã¬ãŒãåéäœãšã¯ç°ã€
ãïŒåã®æ«ç«¯ãšãã¬ã³åºãŸãã¯ïŒåã®æ«ç«¯ãš
ãã¬ã³åºãå«æããåéäœã®å°ãªããšãïŒçš®
ã®å ±éåäœïŒãããªã矀ããéžã°ãããã®ã§
ãã ããæ¬è³ªçã«ãªãããããŠæå(d)ã®ééãçµæ
ç©ã®å šééåºæºã§20ã65ééïŒ ã§ãããé€å»å¯
èœçã«çµåãã也ç¥ããããžãšããŠåãçµæç©
ã®å±€ãå«ãæ¯æäœãããªãããžãšããŠåãå æ
åæ§ãšã¬ã¡ã³ãã®è¡šé¢ãé©çšãã () ããžãšããŠåããšã¬ã¡ã³ããšåºæã®éã«åŒ·
åºãªçµåã圢æããã次ãã§ä»»æã®é åºã§äžèš
ããªãã¡ () ãã®ããžãšããŠåããšã¬ã¡ã³ãã掻æ§ç·ç §
å°ã«åæ§é²å ãããŠåã圢æããã () æ©æ¢°çå¥é¢ãŸãã¯æ¶²äœæº¶è§£ã«ãã€ãŠããžãš
ããŠåãå±€ã®è¡šé¢ããæ¯æäœãé€å»ãã次ã㧠() é²å åŸã«ããŸã å¯æº¶æ§ã«çãŸã€ãŠããããž
ãšããŠåãå±€ã®éšåãæŽå»ããŠåºæäžã«ããžã®
ã¬ãžã¹ãåãçæããã ããšãããªããåºæäžã«ããžã¬ãžã¹ãåã圢æã
ããæ¹æ³ã ïŒïŒ ã¬ãžã¹ãåã«ããä¿è·ãããŠããªãåºæè¡š
é¢ããšããã³ã°ãŸãã¯ãã€ãã«ãã€ãŠååŠçã«å€
æ§ãããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹
æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37099182A | 1982-04-22 | 1982-04-22 | |
| US370991 | 1982-04-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58190945A JPS58190945A (ja) | 1983-11-08 |
| JPH0336209B2 true JPH0336209B2 (ja) | 1991-05-30 |
Family
ID=23462043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6927783A Granted JPS58190945A (ja) | 1982-04-22 | 1983-04-21 | 亀åçµåãâãºå«æå æåæ§ã³âãã€ã³ã° |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0092783B1 (ja) |
| JP (1) | JPS58190945A (ja) |
| DE (1) | DE3374450D1 (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61162501A (ja) * | 1985-01-10 | 1986-07-23 | Nippon Paint Co Ltd | é«ãšãã«ã®âç·ç¡¬åæš¹èçµæç© |
| US4753865A (en) * | 1986-01-22 | 1988-06-28 | E. I. Du Pont De Nemours And Company | Photosensitive compositions containing microgels |
| JPH0746224B2 (ja) * | 1986-06-27 | 1995-05-17 | æ¥æ¬ãã€ã³ãæ ªåŒäŒç€Ÿ | æå æ§ãã¬ããœå°å·ç |
| JPS6317903A (ja) * | 1986-07-10 | 1988-01-25 | Nippon Paint Co Ltd | å 硬åæ§æš¹èçµæç© |
| US4956252A (en) * | 1988-08-30 | 1990-09-11 | E. I. Dupont De Nemours And Company | Aqueous processible photosensitive compositions containing core shell microgels |
| US5075192A (en) * | 1988-08-30 | 1991-12-24 | E. I. Du Pont De Nemours And Company | Aqueous processible photosensitive compositions containing core shell microgels |
| US5002854A (en) * | 1989-04-21 | 1991-03-26 | E. I. Du Pont De Nemours And Company | Solid imaging method using compositions containing core-shell polymers |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55124147A (en) * | 1979-03-16 | 1980-09-25 | Fuji Photo Film Co Ltd | Manufacture of photosensitive printing plate |
| JPS561056A (en) * | 1979-06-15 | 1981-01-08 | Fuji Photo Film Co Ltd | Preparation of photosensitive printing plate |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE603930A (ja) * | 1960-05-19 | |||
| DE3009928C2 (de) * | 1979-03-16 | 1987-03-12 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | Lichtempfindliche Druckplatte und Verfahren zu ihrer Herstellung |
| DE2926235A1 (de) * | 1979-06-29 | 1981-01-08 | Hoechst Ag | Photopolymerisierbares kopiermaterial und verfahren zur herstellung von reliefbildern |
-
1983
- 1983-04-20 DE DE8383103825T patent/DE3374450D1/de not_active Expired
- 1983-04-20 EP EP19830103825 patent/EP0092783B1/en not_active Expired
- 1983-04-21 JP JP6927783A patent/JPS58190945A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55124147A (en) * | 1979-03-16 | 1980-09-25 | Fuji Photo Film Co Ltd | Manufacture of photosensitive printing plate |
| JPS561056A (en) * | 1979-06-15 | 1981-01-08 | Fuji Photo Film Co Ltd | Preparation of photosensitive printing plate |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58190945A (ja) | 1983-11-08 |
| EP0092783B1 (en) | 1987-11-11 |
| DE3374450D1 (en) | 1987-12-17 |
| EP0092783A2 (en) | 1983-11-02 |
| EP0092783A3 (en) | 1985-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0041640B1 (en) | Photopolymerizable composition | |
| JPH0711700B2 (ja) | ãã€ã¯ãã²ã«ãå«æããæå æ§çµæç© | |
| JP3479510B2 (ja) | æ®çç©ã¬ãã«ã®äœãæå æ§çµæç©ã®é£ç¶æ¶²äœåŠçã®ããã®æ¹æ³ | |
| JPS58144824A (ja) | ãã©ãã¬ãžã¹ã補å | |
| JPH0143942B2 (ja) | ||
| US4551415A (en) | Photosensitive coatings containing crosslinked beads | |
| JPH0614185B2 (ja) | æå æ§æš¹èçµæç©åã³ãããçšããç©å±€äœ | |
| JPH0143943B2 (ja) | ||
| JPH0336209B2 (ja) | ||
| US5077175A (en) | Plasticized polyvinyl alcohol release layer for a flexographic printing plate | |
| AU613519B2 (en) | A plasticized polyvinyl alcohol release layer for a flexographic printing plate | |
| EP0041643B1 (en) | Self-trimming photosensitive layer | |
| US4601970A (en) | Dry photosensitive film containing crosslinked beads | |
| JPH01167749A (ja) | æå æ§å°å·æ¿åã³ãã®è£œæ³ | |
| US4230790A (en) | Photopolymerizable compositions useful in dry film photoresist | |
| US4668604A (en) | Positive-working photosensitive elements containing crosslinked beads and process of use | |
| JPH0143944B2 (ja) | ||
| JP2526316B2 (ja) | æ°Žæ§ãŸãã¯åæ°Žæ§ã§åŠçå¯èœãªãã¬ããœã°ã©ãå°å·æ¿çšã®ã¬ãªâãºå±€ | |
| JP2004138809A (ja) | æå æ§æš¹èçµæç©ããã³ãããçšããæå æ§ãšã¬ã¡ã³ã | |
| JP2003228168A (ja) | ã¬ãžã¹ããã¿ãŒã³ã®è£œé æ³ãããªã³ãé ç·æ¿ã®è£œé æ³åã³ãªãŒããã¬ãŒã ã®è£œé æ³ | |
| JPS5854335A (ja) | ç»å圢æææ | |
| JP2003035953A (ja) | é«å¯åºŠã»é«è§£å床çšã®æå æ§æš¹èçµæç©åã³ãã®çšé | |
| JPS59193446A (ja) | æå æ§ç©å±€ç© | |
| JP2001154346A (ja) | æå æ§ãšã¬ã¡ã³ãããããçšããã¬ãžã¹ããã¿ãŒã³ã®è£œé æ³åã³ããªã³ãé ç·æ¿ã®è£œé æ³ | |
| JP2003131370A (ja) | æå æ§æš¹èçµæç©ããããçšããæå æ§ãšã¬ã¡ã³ã |