JPH0251484B2 - - Google Patents
Info
- Publication number
- JPH0251484B2 JPH0251484B2 JP59142195A JP14219584A JPH0251484B2 JP H0251484 B2 JPH0251484 B2 JP H0251484B2 JP 59142195 A JP59142195 A JP 59142195A JP 14219584 A JP14219584 A JP 14219584A JP H0251484 B2 JPH0251484 B2 JP H0251484B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- hexafluoroacetone
- vinylidene fluoride
- polymethyl methacrylate
- sheath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 claims description 42
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 claims description 25
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 21
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 20
- 239000000306 component Substances 0.000 claims description 17
- 230000005540 biological transmission Effects 0.000 claims description 12
- 239000008358 core component Substances 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 11
- 230000003287 optical effect Effects 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 7
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 19
- 239000011347 resin Substances 0.000 description 15
- 229920005989 resin Polymers 0.000 description 15
- 238000002844 melting Methods 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NHAPYGZWSAQWAS-UHFFFAOYSA-N 2,2,3,4,4,4-hexafluorobutanoyl 2,2,3,4,4,4-hexafluorobutaneperoxoate Chemical compound FC(F)(F)C(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)C(F)(F)F NHAPYGZWSAQWAS-UHFFFAOYSA-N 0.000 description 2
- 229920005497 Acrypet® Polymers 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 1
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- HEBNOKIGWWEWCN-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-one;hydrate Chemical compound O.FC(F)(F)C(=O)C(F)(F)F HEBNOKIGWWEWCN-UHFFFAOYSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009778 extrusion testing Methods 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59142195A JPS6122305A (ja) | 1984-07-11 | 1984-07-11 | 光伝送繊維 |
| IT21350/85A IT1185141B (it) | 1984-07-11 | 1985-06-28 | Fibra ottica avente un'anima di polimetacrilato e un rivestimento di fluoro copolimero |
| GB08517036A GB2161954B (en) | 1984-07-11 | 1985-07-05 | Optical fiber having a polymethacrylate core and fluoro-copolymer cladding |
| DE19853524369 DE3524369A1 (de) | 1984-07-11 | 1985-07-08 | Optische faser mit polymethacrylat-kern und fluor-kopolymer-huelle |
| FR8510585A FR2567653B1 (fr) | 1984-07-11 | 1985-07-10 | Fibre optique ayant une ame en polymethacrylate et un revetement en un copolymere fluore |
| US06/753,986 US4687295A (en) | 1984-07-11 | 1985-07-11 | Optical fiber having polymethacrylate core and fluoro-copolymer cladding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59142195A JPS6122305A (ja) | 1984-07-11 | 1984-07-11 | 光伝送繊維 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6122305A JPS6122305A (ja) | 1986-01-30 |
| JPH0251484B2 true JPH0251484B2 (US07118763-20061010-C00002.png) | 1990-11-07 |
Family
ID=15309600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59142195A Granted JPS6122305A (ja) | 1984-07-11 | 1984-07-11 | 光伝送繊維 |
Country Status (6)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61190546A (ja) * | 1985-02-20 | 1986-08-25 | Central Glass Co Ltd | 光学用樹脂組成物 |
| JPS61190304A (ja) * | 1985-02-20 | 1986-08-25 | Central Glass Co Ltd | 光伝送繊維 |
| JPH07113690B2 (ja) * | 1985-06-12 | 1995-12-06 | 三菱レイヨン株式会社 | 光伝送体及びその製造法 |
| JPS62109004A (ja) * | 1985-11-08 | 1987-05-20 | Hitachi Ltd | プラスチツク光フアイバ、その製法及び樹脂 |
| JPH0760204B2 (ja) * | 1986-03-18 | 1995-06-28 | 呉羽化学工業株式会社 | 耐熱性を有する樹脂製光学繊維およびその製造方法 |
| DE3617005A1 (de) * | 1986-05-21 | 1987-11-26 | Hoechst Ag | Lichtleiter mit fluessigem kern und einer umhuellung aus fluorkunststoff |
| GB2196148B (en) * | 1986-09-09 | 1990-03-28 | Central Glass Co Ltd | Optical fiber using vinylidene fluoride base ternary copolymer as cladding material |
| JPS63117085A (ja) * | 1986-11-05 | 1988-05-21 | Central Glass Co Ltd | 粘着剤用樹脂組成物 |
| JP2602242B2 (ja) * | 1987-09-09 | 1997-04-23 | 旭化成工業株式会社 | プラスチツク光フアイバー用鞘材及びこれを用いたプラスチツク光フアイバー |
| JP2652178B2 (ja) * | 1987-12-17 | 1997-09-10 | 旭化成工業株式会社 | 光ファイバコードユニットとその製造方法 |
| JPH0264108A (ja) * | 1988-08-30 | 1990-03-05 | Mitsubishi Rayon Co Ltd | メタクリルイミド基含有重合体の製造法およびそれにより得られる該重合体を構成成分とする光伝送繊維 |
| JPH02173709A (ja) * | 1988-12-27 | 1990-07-05 | Central Glass Co Ltd | 光伝送繊維 |
| US4971424A (en) * | 1989-10-26 | 1990-11-20 | Minnesota Mining And Manufacturing Co. | Radiation curable cladding compositions |
| JP2951677B2 (ja) * | 1990-02-05 | 1999-09-20 | 旭化成工業株式会社 | プラスチック光ファイバコード |
| JP2854669B2 (ja) * | 1990-04-27 | 1999-02-03 | 株式会社 日立製作所 | 光伝送体とそれを用いた光伝送システムおよびエンジンの制御システム |
| US5239026A (en) * | 1991-08-26 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Low loss high numerical aperture cladded optical fibers |
| JP4527921B2 (ja) * | 1999-09-09 | 2010-08-18 | 三菱レイヨン株式会社 | プラスチック光ファイバ、光ファイバケーブル及びプラグ付き光ファイバケーブル並びにこれらの製造方法 |
| JP6787001B2 (ja) * | 2016-09-27 | 2020-11-18 | 三菱ケミカル株式会社 | フィルム |
| GB2563196B (en) * | 2017-05-05 | 2021-10-13 | Michael Brooke Gerard | Electrosurgical instrument with illumination element |
| DK3764131T3 (da) | 2018-03-05 | 2023-09-25 | Toray Industries | Optisk plastfiber og optisk plastfiberledning |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1037498A (en) * | 1965-06-14 | 1966-07-27 | Du Pont | Light transmitting filaments |
| JPS5342260B2 (US07118763-20061010-C00002.png) * | 1973-11-22 | 1978-11-10 | ||
| US4264129A (en) * | 1978-11-17 | 1981-04-28 | Spectronics, Inc. | Fiber bundle termination |
| US4381269A (en) * | 1980-11-11 | 1983-04-26 | Nippon Telegraph & Telephone Public Corporation | Fabrication of a low-loss plastic optical fiber |
| NL186769C (nl) * | 1980-11-11 | 1991-02-18 | Nippon Telegraph & Telephone | Werkwijze voor het vervaardigen van optische kunststofvezels. |
| JPS5865402A (ja) * | 1981-10-14 | 1983-04-19 | Sumitomo Electric Ind Ltd | プラスチツク光フアイバ |
| JPS5898706A (ja) * | 1981-12-07 | 1983-06-11 | Sumitomo Electric Ind Ltd | プラスチツク光フアイバの製造方法 |
| AU560480B2 (en) * | 1982-07-05 | 1987-04-09 | Mitsubishi Rayon Company Limited | Plastic optical fibres |
| JPS5930502A (ja) * | 1982-08-13 | 1984-02-18 | Nippon Telegr & Teleph Corp <Ntt> | プラスチツク光フアイバ |
| JPS5936111A (ja) * | 1982-08-24 | 1984-02-28 | Daikin Ind Ltd | 光学繊維用鞘材 |
| FR2533709B1 (fr) * | 1982-09-23 | 1985-10-18 | Commissariat Energie Atomique | Fibres optiques en matiere plastique, notamment scintillantes et leur procede de fabrication |
| JPS59116702A (ja) * | 1982-12-24 | 1984-07-05 | Mitsubishi Rayon Co Ltd | 光伝送性繊維 |
-
1984
- 1984-07-11 JP JP59142195A patent/JPS6122305A/ja active Granted
-
1985
- 1985-06-28 IT IT21350/85A patent/IT1185141B/it active
- 1985-07-05 GB GB08517036A patent/GB2161954B/en not_active Expired
- 1985-07-08 DE DE19853524369 patent/DE3524369A1/de active Granted
- 1985-07-10 FR FR8510585A patent/FR2567653B1/fr not_active Expired
- 1985-07-11 US US06/753,986 patent/US4687295A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2567653B1 (fr) | 1987-05-07 |
| IT1185141B (it) | 1987-11-04 |
| JPS6122305A (ja) | 1986-01-30 |
| US4687295A (en) | 1987-08-18 |
| GB2161954A (en) | 1986-01-22 |
| DE3524369C2 (US07118763-20061010-C00002.png) | 1988-06-23 |
| DE3524369A1 (de) | 1986-01-30 |
| GB8517036D0 (en) | 1985-08-14 |
| IT8521350A0 (it) | 1985-06-28 |
| FR2567653A1 (fr) | 1986-01-17 |
| GB2161954B (en) | 1988-05-18 |
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