JPH0119720B2 - - Google Patents
Info
- Publication number
- JPH0119720B2 JPH0119720B2 JP57129876A JP12987682A JPH0119720B2 JP H0119720 B2 JPH0119720 B2 JP H0119720B2 JP 57129876 A JP57129876 A JP 57129876A JP 12987682 A JP12987682 A JP 12987682A JP H0119720 B2 JPH0119720 B2 JP H0119720B2
- Authority
- JP
- Japan
- Prior art keywords
- phosphor
- mercury vapor
- vapor discharge
- discharge lamp
- pressure mercury
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 70
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 21
- -1 europium-activated yttrium oxide phosphor Chemical class 0.000 claims description 17
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims description 13
- 229910052590 monazite Inorganic materials 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 12
- 229910052693 Europium Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 8
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 5
- 229910052765 Lutetium Inorganic materials 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- QXQVDANUNXECKG-UHFFFAOYSA-N OP(O)(Cl)=O.OP(O)(Cl)=O.OP(O)(Cl)=O.P.P Chemical compound OP(O)(Cl)=O.OP(O)(Cl)=O.OP(O)(Cl)=O.P.P QXQVDANUNXECKG-UHFFFAOYSA-N 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 150000004645 aluminates Chemical class 0.000 claims 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052771 Terbium Inorganic materials 0.000 description 16
- 229910052684 Cerium Inorganic materials 0.000 description 13
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 13
- 230000004907 flux Effects 0.000 description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 10
- 229910052796 boron Inorganic materials 0.000 description 10
- 238000009877 rendering Methods 0.000 description 10
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 238000000295 emission spectrum Methods 0.000 description 5
- 230000005284 excitation Effects 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- 108010043121 Green Fluorescent Proteins Proteins 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- HEQHIXXLFUMNDC-UHFFFAOYSA-N O.O.O.O.O.O.O.[Tb].[Tb].[Tb].[Tb] Chemical compound O.O.O.O.O.O.O.[Tb].[Tb].[Tb].[Tb] HEQHIXXLFUMNDC-UHFFFAOYSA-N 0.000 description 1
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 description 1
- OSGMVZPLTVJAFX-UHFFFAOYSA-N [Gd].[Lu] Chemical compound [Gd].[Lu] OSGMVZPLTVJAFX-UHFFFAOYSA-N 0.000 description 1
- LWNCNSOPVUCKJL-UHFFFAOYSA-N [Mg].[P] Chemical compound [Mg].[P] LWNCNSOPVUCKJL-UHFFFAOYSA-N 0.000 description 1
- FOUHTHSUSZNYNK-UHFFFAOYSA-M [O-2].[OH-].O.P.[Y+3] Chemical class [O-2].[OH-].O.P.[Y+3] FOUHTHSUSZNYNK-UHFFFAOYSA-M 0.000 description 1
- FRVIZQXVKAWYRM-UHFFFAOYSA-N [P].[Ba] Chemical compound [P].[Ba] FRVIZQXVKAWYRM-UHFFFAOYSA-N 0.000 description 1
- ZQBZAOZWBKABNC-UHFFFAOYSA-N [P].[Ca] Chemical compound [P].[Ca] ZQBZAOZWBKABNC-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- ITVPBBDAZKBMRP-UHFFFAOYSA-N chloro-dioxido-oxo-$l^{5}-phosphane;hydron Chemical compound OP(O)(Cl)=O ITVPBBDAZKBMRP-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- SMKQIOCKGHFKQZ-UHFFFAOYSA-N phosphanylidynecerium Chemical compound [Ce]#P SMKQIOCKGHFKQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/38—Devices for influencing the colour or wavelength of the light
- H01J61/42—Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
- H01J61/46—Devices characterised by the binder or other non-luminescent constituent of the luminescent material, e.g. for obtaining desired pouring or drying properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7777—Phosphates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7777—Phosphates
- C09K11/7778—Phosphates with alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7777—Phosphates
- C09K11/7778—Phosphates with alkaline earth metals
- C09K11/7779—Phosphates with alkaline earth metals with halogens
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/778—Borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/38—Devices for influencing the colour or wavelength of the light
- H01J61/42—Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
- H01J61/44—Devices characterised by the luminescent material
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12987682A JPS5920378A (ja) | 1982-07-26 | 1982-07-26 | 螢光体およびこの螢光体を使用した低圧水銀蒸気放電灯 |
| CA000433100A CA1211781A (en) | 1982-07-26 | 1983-07-25 | Green-emitting phosphor and a low pressure mercury vapor lamp employing this phosphor |
| FR8312271A FR2537151B1 (fr) | 1982-07-26 | 1983-07-25 | Luminophore emetteur de vert et lampe a vapeur de mercure a basse pression employant ce luminophore |
| NL8302657A NL188756C (nl) | 1982-07-26 | 1983-07-26 | Luminescerend materiaal, alsmede lagedrukkwikdampontladingslamp welke deze stof bevat. |
| DE19833326921 DE3326921A1 (de) | 1982-07-26 | 1983-07-26 | Gruenes licht aussendende phosphoreszenzfaehige stoffe und niederdruck-quecksilberdampflampe, in der diese stoffe verwendet werden |
| GB08320036A GB2124243B (en) | 1982-07-26 | 1983-07-26 | A green-emitting phosphor and a low pressure mercury vapor lamp employing this phosphor |
| DE19833348146 DE3348146C2 (US08124317-20120228-C00026.png) | 1982-07-26 | 1983-07-26 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12987682A JPS5920378A (ja) | 1982-07-26 | 1982-07-26 | 螢光体およびこの螢光体を使用した低圧水銀蒸気放電灯 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5920378A JPS5920378A (ja) | 1984-02-02 |
| JPH0119720B2 true JPH0119720B2 (US08124317-20120228-C00026.png) | 1989-04-12 |
Family
ID=15020492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12987682A Granted JPS5920378A (ja) | 1982-07-26 | 1982-07-26 | 螢光体およびこの螢光体を使用した低圧水銀蒸気放電灯 |
Country Status (6)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59226088A (ja) * | 1983-06-07 | 1984-12-19 | Toshiba Corp | 緑色発光螢光体 |
| US4623816A (en) * | 1985-04-22 | 1986-11-18 | General Electric Company | Fluorescent lamp using multi-layer phosphor coating |
| JPS62197488A (ja) * | 1986-02-25 | 1987-09-01 | Mitsubishi Electric Corp | 螢光体 |
| DE3729711A1 (de) * | 1987-09-04 | 1989-03-23 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Quecksilberniederdruckentladungslampe zur uv-bestrahlung |
| US5116532A (en) * | 1990-05-14 | 1992-05-26 | Gte Products Corporation | Method of making lanthanum cerium terbium phosphate phosphor |
| US5132042A (en) * | 1990-05-14 | 1992-07-21 | Gte Products Corporation | Method of making lanthanum cerium terbium phosphate phosphor with improved brightness |
| FR2672281B1 (fr) * | 1991-02-04 | 1993-04-16 | Rhone Poulenc Chimie | Phosphate mixte de lanthane, terbium et cerium, procede de fabrication de celui-ci. |
| FR2679242A1 (fr) * | 1991-07-19 | 1993-01-22 | Rhone Poulenc Chimie | Phosphate mixte de lanthane, terbium et cerium, procede de fabrication de ceux-ci a partir de sels insolubles de terres rares. |
| FR2694299B1 (fr) † | 1992-07-29 | 1994-09-09 | Rhone Poulenc Chimie | Nouveaux luminophores verts à base de phosphate mixte de lanthane, cérium et terbium, précurseur de ceux-ci et procédés de synthèse. |
| FR2694281B1 (fr) † | 1992-07-29 | 1994-09-16 | Rhone Poulenc Chimie | Procédé de préparation de phosphates de terres rares et produits obtenus. |
| DE19806213B4 (de) * | 1998-02-16 | 2005-12-01 | Tews, Walter, Dipl.-Chem. Dr.rer.nat.habil. | Kompakte Energiesparlampe |
| US5989454A (en) * | 1998-07-06 | 1999-11-23 | Matsushita Electric Industrial Co., Ltd. | Method for making small particle blue emitting lanthanum phosphate based phosphors |
| DE10158273A1 (de) * | 2001-11-28 | 2003-06-18 | Philips Intellectual Property | Plasmafarbbildschirm mit grünem Leuchtstoff |
| US7179402B2 (en) * | 2004-02-02 | 2007-02-20 | General Electric Company | Phosphors containing phosphate and/or borate of metals of group IIIA, group IVA, and lanthanide series, and light sources incorporating the same |
| US7238302B2 (en) * | 2004-12-28 | 2007-07-03 | Osram Sylvania Inc. | Single-component, UV-emitting phosphor |
| US7288215B2 (en) | 2005-03-30 | 2007-10-30 | Osram Sylvania Inc. | Method of making narrow-band UVB-emitting phosphors |
| FR2938526B1 (fr) * | 2008-11-20 | 2011-01-07 | Rhodia Operations | Phosphate de cerium et/ou de terbium, eventuellement avec du lanthane, luminophore issu de ce phosphate et procedes de preparation de ceux-ci |
| FR2938525B1 (fr) * | 2008-11-20 | 2011-01-07 | Rhodia Operations | Phosphate de cerium et/ou de terbium, eventuellement avec du lanthane, luminophore issu de ce phosphate et procedes de preparation de ceux-ci |
| FR2938524B1 (fr) * | 2008-11-20 | 2011-01-07 | Rhodia Operations | Phosphate de cerium et/ou de terbium, eventuellement avec du lanthane, luminophore issu de ce phosphate et procedes de preparation de ceux-ci |
| FR2938523B1 (fr) * | 2008-11-20 | 2011-01-07 | Rhodia Operations | Phosphate de cerium et/ou de terbium, eventuellement avec du lanthane, luminophore issu de ce phosphate et procedes de preparation de ceux-ci |
| FR2943658B1 (fr) * | 2009-03-24 | 2011-07-22 | Rhodia Operations | Composition comprenant un phosphate de cerium et/ou de terbium,de type coeur/coquille,luminophore issu de cette composition et leurs procedes de preparation |
| FR2948655A1 (fr) * | 2009-07-29 | 2011-02-04 | Rhodia Operations | Composition comprenant un phosphate de cerium et/ou de terbium et du sodium, de type coeur/coquille, luminophore issu de cette composition et leurs procedes de preparation |
| JP5667215B2 (ja) * | 2010-02-04 | 2015-02-12 | オーシャンズ キング ライティング サイエンスアンドテクノロジー カンパニー リミテッド | テルビウムをドープしたリン酸塩緑色発光材料及びその製造方法 |
| FR2979351B1 (fr) | 2011-08-31 | 2013-10-11 | Rhodia Operations | Luminophore a base d'un phosphate de lanthane, de cerium et de terbium a brillance stabilisee, procede de preparation et utilisation dans un dispositif luminescent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634282A (en) * | 1968-09-26 | 1972-01-11 | Anvar | Luminescent compounds of cerium phosphates activated by terbium |
| JPS5413479A (en) * | 1977-05-18 | 1979-01-31 | Rhone Poulenc Ind | Novel luminescence substance for screen or tube |
| JPS5456086A (en) * | 1977-10-12 | 1979-05-04 | Mitsubishi Electric Corp | Fluorescent substance |
| JPS57133182A (en) * | 1981-02-12 | 1982-08-17 | Toshiba Corp | Fluorescent substance |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3211666A (en) * | 1963-02-18 | 1965-10-12 | Westinghouse Electric Corp | Phosphor |
| GB1134798A (en) * | 1966-08-17 | 1968-11-27 | Matsushita Electronics Corp | A phosphor |
| US3525698A (en) * | 1967-10-20 | 1970-08-25 | American Cyanamid Co | Cerium and lanthanide activated alkaline earth metal phosphate phosphors |
| US3507804A (en) * | 1968-06-13 | 1970-04-21 | Westinghouse Electric Corp | Method of coprecipitating mixed rare-earth orthophosphates suitable for making phosphor |
| JPS5275674A (en) * | 1975-12-19 | 1977-06-24 | Matsushita Electric Ind Co Ltd | Fluorescent substeance |
| GB1565811A (en) * | 1976-06-28 | 1980-04-23 | Minnesota Mining & Mfg | Luminescent phosphor materials |
| JPS5821380B2 (ja) * | 1978-09-05 | 1983-04-28 | 株式会社東芝 | 螢光ランプ |
| GB2058117B (en) * | 1979-08-03 | 1983-06-08 | Kasei Optonix | Borate phosphor |
| US4305019A (en) * | 1979-12-31 | 1981-12-08 | Westinghouse Electric Corp. | Warm-white fluorescent lamp having good efficacy and color rendering and using special phosphor blend as separate undercoat |
| JPS6010065B2 (ja) * | 1981-06-16 | 1985-03-14 | 株式会社東芝 | 緑色発光螢光体 |
| JPH0561887A (ja) * | 1991-09-02 | 1993-03-12 | Tokyo Electric Co Ltd | 注文管理装置 |
| JP3241084B2 (ja) * | 1992-03-25 | 2001-12-25 | 株式会社東芝 | 固体撮像装置 |
-
1982
- 1982-07-26 JP JP12987682A patent/JPS5920378A/ja active Granted
-
1983
- 1983-07-25 CA CA000433100A patent/CA1211781A/en not_active Expired
- 1983-07-25 FR FR8312271A patent/FR2537151B1/fr not_active Expired
- 1983-07-26 DE DE19833326921 patent/DE3326921A1/de active Granted
- 1983-07-26 NL NL8302657A patent/NL188756C/xx not_active IP Right Cessation
- 1983-07-26 GB GB08320036A patent/GB2124243B/en not_active Expired
- 1983-07-26 DE DE19833348146 patent/DE3348146C2/de not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634282A (en) * | 1968-09-26 | 1972-01-11 | Anvar | Luminescent compounds of cerium phosphates activated by terbium |
| JPS5413479A (en) * | 1977-05-18 | 1979-01-31 | Rhone Poulenc Ind | Novel luminescence substance for screen or tube |
| JPS5456086A (en) * | 1977-10-12 | 1979-05-04 | Mitsubishi Electric Corp | Fluorescent substance |
| JPS57133182A (en) * | 1981-02-12 | 1982-08-17 | Toshiba Corp | Fluorescent substance |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2124243B (en) | 1985-12-04 |
| FR2537151A1 (fr) | 1984-06-08 |
| FR2537151B1 (fr) | 1987-02-20 |
| GB2124243A (en) | 1984-02-15 |
| GB8320036D0 (en) | 1983-08-24 |
| JPS5920378A (ja) | 1984-02-02 |
| DE3326921A1 (de) | 1984-02-02 |
| DE3348146C2 (US08124317-20120228-C00026.png) | 1992-01-30 |
| NL188756B (nl) | 1992-04-16 |
| NL8302657A (nl) | 1984-02-16 |
| DE3326921C2 (US08124317-20120228-C00026.png) | 1987-09-03 |
| CA1211781A (en) | 1986-09-23 |
| NL188756C (nl) | 1992-09-16 |
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