JPH0118018B2 - - Google Patents
Info
- Publication number
- JPH0118018B2 JPH0118018B2 JP57082876A JP8287682A JPH0118018B2 JP H0118018 B2 JPH0118018 B2 JP H0118018B2 JP 57082876 A JP57082876 A JP 57082876A JP 8287682 A JP8287682 A JP 8287682A JP H0118018 B2 JPH0118018 B2 JP H0118018B2
- Authority
- JP
- Japan
- Prior art keywords
- valence
- compensated
- perovskite compound
- alkoxide
- perovskite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims description 52
- 150000004703 alkoxides Chemical class 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 239000010955 niobium Substances 0.000 claims description 11
- 229910052788 barium Inorganic materials 0.000 claims description 9
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 8
- 229910052712 strontium Inorganic materials 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- 229910052727 yttrium Inorganic materials 0.000 claims description 8
- 229910052693 Europium Inorganic materials 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052746 lanthanum Inorganic materials 0.000 claims description 7
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 7
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 7
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 7
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 6
- 230000003301 hydrolyzing effect Effects 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 230000000977 initiatory effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 229910010293 ceramic material Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- -1 tantalum alkoxides Chemical class 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- VSFQMZYFJAOOOG-UHFFFAOYSA-N di(propan-2-yloxy)lead Chemical compound CC(C)O[Pb]OC(C)C VSFQMZYFJAOOOG-UHFFFAOYSA-N 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- RWZKAROCZDFJEI-UHFFFAOYSA-N ethanol;zinc Chemical compound [Zn].CCO.CCO RWZKAROCZDFJEI-UHFFFAOYSA-N 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- QCQJPUZAVFHPMN-UHFFFAOYSA-N iron(2+);propan-2-olate Chemical class [Fe+2].CC(C)[O-].CC(C)[O-] QCQJPUZAVFHPMN-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HAUKUGBTJXWQMF-UHFFFAOYSA-N lithium;propan-2-olate Chemical compound [Li+].CC(C)[O-] HAUKUGBTJXWQMF-UHFFFAOYSA-N 0.000 description 1
- CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- WBQTXTBONIWRGK-UHFFFAOYSA-N sodium;propan-2-olate Chemical compound [Na+].CC(C)[O-] WBQTXTBONIWRGK-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- OHULXNKDWPTSBI-UHFFFAOYSA-N strontium;propan-2-olate Chemical compound [Sr+2].CC(C)[O-].CC(C)[O-] OHULXNKDWPTSBI-UHFFFAOYSA-N 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Landscapes
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287682A JPS58199716A (ja) | 1982-05-17 | 1982-05-17 | 原子価補償型ペロブスカイト化合物の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287682A JPS58199716A (ja) | 1982-05-17 | 1982-05-17 | 原子価補償型ペロブスカイト化合物の製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9954088A Division JPH01119515A (ja) | 1988-04-22 | 1988-04-22 | 原子価補償型ペロブスカイト化合物の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58199716A JPS58199716A (ja) | 1983-11-21 |
| JPH0118018B2 true JPH0118018B2 (fr) | 1989-04-03 |
Family
ID=13786487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8287682A Granted JPS58199716A (ja) | 1982-05-17 | 1982-05-17 | 原子価補償型ペロブスカイト化合物の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58199716A (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61261214A (ja) * | 1985-05-16 | 1986-11-19 | Mitsubishi Mining & Cement Co Ltd | ニオブ複酸化物微粉末の製造方法 |
| JPS61275108A (ja) * | 1985-05-30 | 1986-12-05 | Mitsubishi Mining & Cement Co Ltd | 誘電体粉末の製造方法 |
| JPS62113723A (ja) * | 1985-11-09 | 1987-05-25 | Tohoku Metal Ind Ltd | 複合ペロブスカイト化合物の製造方法 |
| JPS62113724A (ja) * | 1985-11-09 | 1987-05-25 | Tohoku Metal Ind Ltd | 複合ペロブスカイト化合物の製造方法 |
| JPS62202821A (ja) * | 1986-03-04 | 1987-09-07 | Ube Ind Ltd | 多段湿式法による易焼結性の複合ペロブスカイトの原料粉末の製造方法 |
| EP0237081B1 (fr) * | 1986-03-14 | 1992-01-22 | Matsushita Electric Industrial Co., Ltd. | Procédé pour la préparation de composés complexes de type pérovskite |
| JPH0660016B2 (ja) * | 1986-03-14 | 1994-08-10 | 松下電器産業株式会社 | 複合ペロブスカイト型化合物の製造方法 |
| JPS62265119A (ja) * | 1986-05-10 | 1987-11-18 | Mitsubishi Mining & Cement Co Ltd | ニオブ複酸化物微粉末の製造方法 |
| US4853199A (en) * | 1987-01-08 | 1989-08-01 | Matsushita Electric Industrial Co., Ltd. | Method for producing crystalline complex perovskite compounds |
| JPS63176309A (ja) * | 1987-01-13 | 1988-07-20 | Natl Inst For Res In Inorg Mater | ペロブスカイト型のニオブ酸鉛マグネシウムの製造法 |
| US5304533A (en) * | 1987-08-24 | 1994-04-19 | Mitsubishi Denki Kabushiki Kaisha | Process for producing an oxide superconductor from alkoxides |
| JPH02255536A (ja) * | 1989-03-29 | 1990-10-16 | Fuji Elelctrochem Co Ltd | 原子価補償型ペロブスカイト化合物の製造方法 |
| JPH03164432A (ja) * | 1989-11-24 | 1991-07-16 | Fuji Elelctrochem Co Ltd | 複合ペロブスカイト型化合物およびその製造方法 |
| JPH03170305A (ja) * | 1989-11-29 | 1991-07-23 | Koroido Res:Kk | 複合酸化物粉末の製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3647364A (en) * | 1970-01-06 | 1972-03-07 | Us Air Force | Process for producing high-purity submicron barium and strontium titanate powders |
| JPS5557204A (en) * | 1978-10-24 | 1980-04-26 | Nippon Electric Co | Porcelain composition |
-
1982
- 1982-05-17 JP JP8287682A patent/JPS58199716A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3647364A (en) * | 1970-01-06 | 1972-03-07 | Us Air Force | Process for producing high-purity submicron barium and strontium titanate powders |
| JPS5557204A (en) * | 1978-10-24 | 1980-04-26 | Nippon Electric Co | Porcelain composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58199716A (ja) | 1983-11-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4636378A (en) | Method of preparation of perovskite-type compounds | |
| KR100583844B1 (ko) | 티탄산바륨 및 그의 제조방법 | |
| US4636248A (en) | Method for production of dielectric powder | |
| KR100497938B1 (ko) | 복합산화물 분말의 제조방법 및 복합산화물 분말 | |
| JPH0118018B2 (fr) | ||
| KR100692282B1 (ko) | 바륨 티타네이트 및 이 재료를 사용한 전자부품 | |
| EP0255193B1 (fr) | Procédé de préparation des titanates de métaux alcalinoterreux sous forme de poudre | |
| US6136229A (en) | Method for the mechanochemical preparation of high performance ceramics | |
| US4937213A (en) | Process for preparing titanates and zirconates | |
| JP2017071537A (ja) | チタン酸バリウム粉末の製造方法 | |
| US4918035A (en) | Process for the preparation of complex perovskite type compounds | |
| JPH0246531B2 (fr) | ||
| JPS6241177B2 (fr) | ||
| JPS623768B2 (fr) | ||
| JP2001089230A (ja) | チタン酸バリウム系焼結体製造用粉末組成物および焼結体 | |
| JPH08119745A (ja) | セラミック粉体の製造方法 | |
| JPS6049137B2 (ja) | 錫酸塩の製造方法 | |
| JPH0321487B2 (fr) | ||
| JPS6186423A (ja) | ビスマス複酸化物の製造方法 | |
| JPH0873219A (ja) | セラミック粉体の製造方法 | |
| JPH01119515A (ja) | 原子価補償型ペロブスカイト化合物の製造方法 | |
| JPS582220A (ja) | 金属酸化物固溶体の製造方法 | |
| JP2865975B2 (ja) | 鉛のペロブスキー型化合物の製造法 | |
| JPH0210763B2 (fr) | ||
| KR100523960B1 (ko) | 초임계 유체상태하에서 액상콜롬바이트법에 의한 페로부스카이트형 납계 복합산화물 분말의 제조방법 |