JP7051511B2 - 半導体装置及びその製造方法 - Google Patents
半導体装置及びその製造方法 Download PDFInfo
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- JP7051511B2 JP7051511B2 JP2018053641A JP2018053641A JP7051511B2 JP 7051511 B2 JP7051511 B2 JP 7051511B2 JP 2018053641 A JP2018053641 A JP 2018053641A JP 2018053641 A JP2018053641 A JP 2018053641A JP 7051511 B2 JP7051511 B2 JP 7051511B2
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- 239000004065 semiconductor Substances 0.000 title claims description 144
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 239000010410 layer Substances 0.000 claims description 265
- 239000000463 material Substances 0.000 claims description 32
- 239000011229 interlayer Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 238000005530 etching Methods 0.000 claims description 8
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 8
- 239000003990 capacitor Substances 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 claims description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 238000001312 dry etching Methods 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000006870 function Effects 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000001020 plasma etching Methods 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 6
- 229910001195 gallium oxide Inorganic materials 0.000 description 6
- 229910003437 indium oxide Inorganic materials 0.000 description 6
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 206010021143 Hypoxia Diseases 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000000231 atomic layer deposition Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 4
- 238000001459 lithography Methods 0.000 description 4
- 238000000059 patterning Methods 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
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Description
第1の実施形態の半導体装置は、第1の電極と、第2の電極と、第1の電極と第2の電極との間に設けられ、第1の方向に伸長する酸化物半導体層と、酸化物半導体層を囲むゲート電極と、ゲート電極と酸化物半導体層との間に酸化物半導体層を囲んで設けられ、第1の方向の長さが酸化物半導体層の第1の方向の長さより短い第1のゲート絶縁層と、を備える。さらに、第1の実施形態の半導体装置は、第1のゲート絶縁層と酸化物半導体層との間に酸化物半導体層を囲んで設けられ、第1の方向の長さが第1のゲート絶縁層の第1の方向の長さより長い第2のゲート絶縁層を、備える。
第2の実施形態の半導体装置は、第2のゲート絶縁層を備えない点で、第1の実施形態と異なっている。以下、第1の実施形態と重複する内容については、一部記述を省略する。
第3の実施形態の半導体装置は、第1の電極と酸化物半導体層との間に設けられ、酸化物半導体層と異なる材料の第1の酸化物層、及び、第2の電極と酸化物半導体層との間に設けられ、酸化物半導体層と異なる材料の第2の酸化物層の、少なくともいずれか一方を備える点で、第1の実施形態と異なる。以下、第1の実施形態と重複する内容については、一部記述を省略する。
第4の実施形態の半導体装置は、第1の電極及び第2の電極の一方に接続されるキャパシタを備える点、第1の電極及び第2の電極の他方に接続される第1の配線と、第1の配線と交差し、ゲート電極に接続される第2の配線と、を備える点で、第1の実施形態と異なる。以下、第1の実施形態と重複する内容については一部記述を省略する。
第4の実施形態のメモリセルアレイ210は、メモリセルMCが立体的に配置された三次元構造を備える。図14、図15において破線で囲まれた領域が1個のメモリセルMCを表している。
12a 凹部
14 ドレイン電極(第2の電極)
16 チャネル層(酸化物半導体層)
18 ゲート電極
20 第1のゲート絶縁層
22 第2のゲート絶縁層
51 第1の層間絶縁膜
52 第2の層間絶縁膜
53 開口部
61 補助層(第1の酸化物層)
62 補助層(第2の酸化物層)
100 トランジスタ(半導体装置)
101 キャパシタ
200 トランジスタ(半導体装置)
300 トランジスタ(半導体装置)
BL ビット線(第1の配線)
WL ワード線(第2の配線)
Claims (16)
- 第1の電極と、
第2の電極と、
前記第1の電極と前記第2の電極との間に設けられ、第1の方向に伸長する酸化物半導体層と、
前記酸化物半導体層を囲むゲート電極と、
前記ゲート電極と前記酸化物半導体層との間に前記酸化物半導体層を囲んで設けられ、前記第1の方向の長さが前記酸化物半導体層の前記第1の方向の長さより短い第1のゲート絶縁層と、
前記第1のゲート絶縁層と前記酸化物半導体層との間に前記酸化物半導体層を囲んで設けられ、前記第1の方向の長さが前記第1のゲート絶縁層の前記第1の方向の長さより長い第2のゲート絶縁層と、
を備える半導体装置。 - 前記第1のゲート絶縁層の前記第1の方向の長さが前記ゲート電極の前記第1の方向の長さと略同一である請求項1記載の半導体装置。
- 前記第1のゲート絶縁層と前記第2のゲート絶縁層との材料は異なる請求項1又は請求項2記載の半導体装置。
- 前記第2のゲート絶縁層は酸化シリコンを含む請求項1ないし請求項3いずれか一項記載の半導体装置。
- 前記第1のゲート絶縁層は酸化アルミニウム又は酸化ハフニウムを含む請求項4記載の半導体装置。
- 前記第1のゲート絶縁層は酸化シリコンを含む請求項1ないし請求項3いずれか一項記載の半導体装置。
- 前記第1のゲート絶縁層は窒化シリコン又は酸窒化シリコンを含む請求項1ないし請求項4いずれか一項記載の半導体装置。
- 前記第1の電極と前記酸化物半導体層との間に設けられ、前記酸化物半導体層と異なる材料の第1の酸化物層、及び、
前記第2の電極と前記酸化物半導体層との間に設けられ、前記酸化物半導体層と異なる材料の第2の酸化物層の、少なくともいずれか一方を備える請求項1ないし請求項7いずれか一項記載の半導体装置。 - 前記第1の電極と前記酸化物半導体層との間、及び、前記第1のゲート絶縁層と前記酸化物半導体層との間に設けられ、前記酸化物半導体層と異なる材料の第1の酸化物層を備える請求項1ないし請求項7いずれか一項記載の半導体装置。
- 前記酸化物半導体層はインジウムを含む請求項1ないし請求項9いずれか一項記載の半導体装置。
- 前記第1の電極は、前記酸化物半導体層の側に凹部を有する請求項1ないし請求項10いずれか一項記載の半導体装置。
- 前記第1の電極及び前記第2の電極の一方に接続されるキャパシタを備える請求項1ないし請求項11いずれか一項記載の半導体装置。
- 前記第1の電極及び前記第2の電極の他方に接続される第1の配線と、
前記第1の配線と交差し、前記ゲート電極に接続される第2の配線と、
を備える請求項12記載の半導体装置。 - 第1の電極を形成し、
前記第1の電極の上に第1の層間絶縁膜を形成し、
前記第1の層間絶縁膜の上にゲート電極を形成し、
前記ゲート電極の上に第2の層間絶縁膜を形成し、
前記第2の層間絶縁膜、前記ゲート電極及び前記第1の層間絶縁膜を貫通し前記第1の電極に達する開口部を形成し、
前記開口部の側面に露出した前記ゲート電極を、前記ゲート電極が残存する範囲で横方向にエッチングし、
前記ゲート電極が前記横方向にエッチングされた領域に第1のゲート絶縁層を形成し、
前記開口部を酸化物半導体層で埋め込み、
前記酸化物半導体層の上に第2の電極を形成する半導体装置の製造方法。 - 前記第1のゲート絶縁層を形成した後、前記酸化物半導体層を形成する前に、前記開口部の中に第2のゲート絶縁層を形成する請求項14記載の半導体装置の製造方法。
- 前記エッチングは等方性ドライエッチングにより行う請求項14又は請求項15記載の半導体装置の製造方法。
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