JP7037562B2 - 触媒 - Google Patents

触媒 Download PDF

Info

Publication number
JP7037562B2
JP7037562B2 JP2019526520A JP2019526520A JP7037562B2 JP 7037562 B2 JP7037562 B2 JP 7037562B2 JP 2019526520 A JP2019526520 A JP 2019526520A JP 2019526520 A JP2019526520 A JP 2019526520A JP 7037562 B2 JP7037562 B2 JP 7037562B2
Authority
JP
Japan
Prior art keywords
group
catalyst
hydrocarbyl
alkyl
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019526520A
Other languages
English (en)
Japanese (ja)
Other versions
JP2019536779A5 (OSRAM
JP2019536779A (ja
Inventor
アジェラル，ノウレディン
レスコニ，ルイジ
ブイ． イズマール，ヴャチェスラフ
エス． コノノヴィッチ，ドミトリー
ゼット． オスコボイニコフ，アレクサンダー
ヴィルックネン，ヴィレ
Original Assignee
ボレアリス エージー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ボレアリス エージー filed Critical ボレアリス エージー
Publication of JP2019536779A publication Critical patent/JP2019536779A/ja
Publication of JP2019536779A5 publication Critical patent/JP2019536779A5/ja
Application granted granted Critical
Publication of JP7037562B2 publication Critical patent/JP7037562B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
    • C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/427—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having two rings
    • C07C49/443—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having two rings the condensed ring system containing eight or nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6498—Catalysts containing a specific non-metal or metal-free compound organic containing another heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2019526520A 2016-11-18 2017-11-17 触媒 Active JP7037562B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16199646 2016-11-18
EP16199646.7 2016-11-18
PCT/EP2017/079662 WO2018091684A1 (en) 2016-11-18 2017-11-17 Catalysts

Publications (3)

Publication Number Publication Date
JP2019536779A JP2019536779A (ja) 2019-12-19
JP2019536779A5 JP2019536779A5 (OSRAM) 2020-08-06
JP7037562B2 true JP7037562B2 (ja) 2022-03-16

Family

ID=57389239

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019526520A Active JP7037562B2 (ja) 2016-11-18 2017-11-17 触媒

Country Status (6)

Country Link
US (1) US11352376B2 (OSRAM)
EP (1) EP3541823B1 (OSRAM)
JP (1) JP7037562B2 (OSRAM)
KR (1) KR102505086B1 (OSRAM)
CN (1) CN110177798B (OSRAM)
WO (1) WO2018091684A1 (OSRAM)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
JP7130644B2 (ja) 2016-12-15 2022-09-05 ボレアリス エージー 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系
US11530280B2 (en) 2016-12-15 2022-12-20 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP3562831B1 (en) 2016-12-29 2021-10-20 Borealis AG Catalysts
US11078304B2 (en) * 2017-07-07 2021-08-03 Borealis Ag Process for preparing heterophasic propylene copolymers
CN112292406B (zh) 2018-03-19 2023-04-04 博里利斯股份公司 烯烃聚合催化剂
WO2019215120A1 (en) * 2018-05-09 2019-11-14 Borealis Ag Process for preparing propylene polymers
KR20210027401A (ko) 2018-06-28 2021-03-10 보레알리스 아게 촉매
EP3647356B8 (en) 2018-10-31 2022-03-30 Borealis AG Polyolefin composition with improved balance of properties
JP7555972B2 (ja) 2019-05-29 2024-09-25 ボレアリス エージー 触媒系
WO2021058742A1 (en) 2019-09-25 2021-04-01 Borealis Ag Heterophasic polypropylene copolymers
WO2025051400A1 (en) * 2023-09-07 2025-03-13 Borealis Ag Methods of producing metallocene catalyst components
WO2025016566A1 (en) * 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016569A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016564A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
KR20250026537A (ko) * 2023-08-17 2025-02-25 한화솔루션 주식회사 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법
WO2025190884A1 (en) 2024-03-13 2025-09-18 Borealis Gmbh Metallocenes for the manufacture of propylene copolymers

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004502699A (ja) 2000-06-30 2004-01-29 エクソンモービル・ケミカル・パテンツ・インク 架橋ビス（インデニル）メタロセン化合物
JP2005511866A (ja) 2001-12-19 2005-04-28 ボレアリス テクノロジィ オイ オレフィン重合触媒の製造方法
JP2005511751A (ja) 2001-12-10 2005-04-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン類、及びそれらから誘導される触媒組成物
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
JP2014525950A (ja) 2011-07-08 2014-10-02 ボレアリス エージー 触媒
JP2014193846A (ja) 2013-02-27 2014-10-09 Japan Polyethylene Corp メタロセン化合物およびオレフィン重合体の製造方法

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
US5756609A (en) 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US6252019B1 (en) 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
ATE222257T1 (de) 1998-08-11 2002-08-15 Dow Chemical Co Katalysatoraktivatorverbindung
MXPA01003978A (es) 1998-10-23 2003-06-06 Exxonmobil Chem Patents Inc Metalocenos puenteados para copolimerizacion de olefinas-.
DE69922536T2 (de) 1998-10-23 2005-12-15 Exxonmobil Chemical Patents Inc., Baytown Verbrückte hafnocenen für die copolymerisation von olefinen
WO2003049856A1 (en) 2001-12-05 2003-06-19 Exxonmobil Chemical Patents Inc. Bulky borate activators
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
KR100702413B1 (ko) 2002-09-27 2007-04-02 미쓰이 가가쿠 가부시키가이샤 가교 메탈로센 화합물, 올레핀 중합 촉매 및 올레핀의 중합 방법
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
ATE514485T1 (de) 2004-12-31 2011-07-15 Borealis Tech Oy Verfahren zur herstellung eines festen olefinpolymerisationskatalysators
US7842764B2 (en) 2005-03-18 2010-11-30 Basell Poliolefine Italia S.R.L. Metallocene compounds
JP2008534705A (ja) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン類の重合法
JP5295098B2 (ja) 2006-04-21 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンコポリマーの製造方法
US7429635B2 (en) 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
KR101278336B1 (ko) 2007-10-25 2013-06-25 루머스 노보렌 테크놀로지 게엠베하 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머
WO2010052263A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
CN102666603B (zh) 2009-12-22 2014-10-15 北欧化工公司 在单活性中心催化剂存在的情况下的聚丙烯制备
EP2516486B1 (en) 2009-12-22 2018-02-07 Borealis AG Catalysts
WO2011135004A2 (en) 2010-04-28 2011-11-03 Borealis Ag Catalysts
CN103025767B (zh) 2010-04-28 2015-01-14 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
KR20140007360A (ko) * 2010-12-22 2014-01-17 보레알리스 아게 가교된 메탈로센 촉매
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
ES2550044T3 (es) 2012-04-25 2015-11-04 Borealis Ag Polipropileno moldeado con alto contenido de forma beta
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
WO2014096282A1 (en) 2012-12-21 2014-06-26 Borealis Ag Catalyst
ES2589053T3 (es) 2013-06-10 2016-11-08 Borealis Ag Procedimiento para la preparación de un polímero de propileno
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
ES2612627T3 (es) * 2013-07-24 2017-05-17 Borealis Ag Proceso
WO2015158790A2 (en) 2014-04-17 2015-10-22 Borealis Ag Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2933277A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2995629B1 (en) 2014-09-12 2018-03-07 Borealis AG Process for producing propylene copolymers in gas phase
US10081686B2 (en) 2014-09-12 2018-09-25 Borealis Ag Process for the preparation of copolymers of propylene
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
US11530280B2 (en) 2016-12-15 2022-12-20 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
JP7130644B2 (ja) 2016-12-15 2022-09-05 ボレアリス エージー 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系
EP3562831B1 (en) 2016-12-29 2021-10-20 Borealis AG Catalysts
KR102549873B1 (ko) 2017-06-29 2023-06-29 보레알리스 아게 폴리프로필렌 조성물의 제조 방법
PT3456776T (pt) 2017-09-13 2020-03-09 Borealis Ag Composição de polipropileno
CN112292406B (zh) 2018-03-19 2023-04-04 博里利斯股份公司 烯烃聚合催化剂

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004502699A (ja) 2000-06-30 2004-01-29 エクソンモービル・ケミカル・パテンツ・インク 架橋ビス（インデニル）メタロセン化合物
JP2005511751A (ja) 2001-12-10 2005-04-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン類、及びそれらから誘導される触媒組成物
JP2005511866A (ja) 2001-12-19 2005-04-28 ボレアリス テクノロジィ オイ オレフィン重合触媒の製造方法
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
JP2014525950A (ja) 2011-07-08 2014-10-02 ボレアリス エージー 触媒
JP2014193846A (ja) 2013-02-27 2014-10-09 Japan Polyethylene Corp メタロセン化合物およびオレフィン重合体の製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KUKLIN, M. S. et al.，Quantitative structure-property relationships in propene polymerization by zirconocenes with a rac-SiMe2[Ind]2 based ligand framework，Journal of Molecular Catalysis A: Chemical，2016年，Vol.412，pp.39-46
NIFANT'EV, I. E.，5-Methoxy-Substituted Zirconium Bis-indenyl ansa-Complexes: Synthesis, Structure, and Catalytic Activity in the Polymerization and Copolymerization of Alkenes，ORGANOMETALLICS，2012年，Vol.31, No.14，pp.4962-4970，DOI:10.1021/om300160v
TYNYS, A. et al.，Propylene polymerisations with novel heterogeneous combination metallocene catalyst systems，Polymer，2007年，Vol.48，pp.1893-1902

Also Published As

Publication number Publication date
WO2018091684A1 (en) 2018-05-24
EP3541823A1 (en) 2019-09-25
EP3541823B1 (en) 2020-12-30
US11352376B2 (en) 2022-06-07
US20190308995A1 (en) 2019-10-10
CN110177798A (zh) 2019-08-27
JP2019536779A (ja) 2019-12-19
CN110177798B (zh) 2022-08-30
KR20190085534A (ko) 2019-07-18
KR102505086B1 (ko) 2023-02-28

Similar Documents

Publication Publication Date Title
JP7037562B2 (ja) 触媒
JP7130649B2 (ja) 触媒
JP6140152B2 (ja) 触媒
CN104870461B (zh) 催化剂
JP6193398B2 (ja) 触媒
US9079985B2 (en) Bridged metallocene catalysts
US8933256B2 (en) Catalysts
US8865848B2 (en) Process for olefin polymerisation using group 4 metallocene as catalysts
JP6178864B2 (ja) 触媒
EP3649162B1 (en) Process for preparing heterophasic propylene copolymers
JP2021517202A (ja) Ｃ４−Ｃ１２−αオレフィンコモノマー単位を含むプロピレンコポリマーの調製方法
JP2015532346A (ja) 触媒
JP7440431B2 (ja) 触媒

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20200626

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20200626

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20210428

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20210513

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20210811

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20211012

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20211025

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220121

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20220207

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20220304

R150 Certificate of patent or registration of utility model

Ref document number: 7037562

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250