JP6949099B2 - ポリマー材料及び制御ラジカル開始剤を使用した製造方法 - Google Patents

ポリマー材料及び制御ラジカル開始剤を使用した製造方法 Download PDF

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JP6949099B2
JP6949099B2 JP2019500836A JP2019500836A JP6949099B2 JP 6949099 B2 JP6949099 B2 JP 6949099B2 JP 2019500836 A JP2019500836 A JP 2019500836A JP 2019500836 A JP2019500836 A JP 2019500836A JP 6949099 B2 JP6949099 B2 JP 6949099B2
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JP2019520465A (ja
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ダブリュ． グリースグラバー，ジョージ
ダブリュ． グリースグラバー，ジョージ
ビー． ロスコー，スティーブン
ビー． ロスコー，スティーブン
リー，ヘ−スン
ユルト，セルカン
チャタジー，ジューン
ファンスラー，デュアン　ディー．
ディー． ファンスラー，デュアン
エイチ． グリスカ，ステファン
エイチ． グリスカ，ステファン
エヌ． ガダム，バブ
エヌ． ガダム，バブ
エム． レヴァンドフスキ，ケヴィン
エム． レヴァンドフスキ，ケヴィン
エル． バティスト，ジョン
エル． バティスト，ジョン
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/026—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising acrylic acid, methacrylic acid or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/023—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2019500836A 2016-07-11 2017-06-27 ポリマー材料及び制御ラジカル開始剤を使用した製造方法 Active JP6949099B2 (ja)

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Application Number Priority Date Filing Date Title
US201662360788P 2016-07-11 2016-07-11
US62/360,788 2016-07-11
US201762479547P 2017-03-31 2017-03-31
US62/479,547 2017-03-31
PCT/US2017/039368 WO2018013330A1 (en) 2016-07-11 2017-06-27 Polymeric material and methods of making using controlled radical initiators

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JP2019520465A JP2019520465A (ja) 2019-07-18
JP2019520465A5 JP2019520465A5 (https=) 2020-02-20
JP6949099B2 true JP6949099B2 (ja) 2021-10-13

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US (1) US10400055B2 (https=)
EP (1) EP3481872B1 (https=)
JP (1) JP6949099B2 (https=)
CN (1) CN109476774B (https=)
WO (1) WO2018013330A1 (https=)

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EP3728340B1 (en) * 2017-12-19 2023-11-15 3M Innovative Properties Company Polymeric materials formed using initiators with two thiocarbonylthio-containing groups
WO2019123182A1 (en) 2017-12-21 2019-06-27 3M Innovative Properties Company Polymeric compositions prepared with a controlled radical initiator
CN111683981B (zh) * 2018-02-21 2023-04-25 3M创新有限公司 用于聚合反应的含酮可控自由基引发剂
US11319461B2 (en) 2018-02-21 2022-05-03 3M Innovative Properties Company Polymeric materials formed using initiators with a ketone group and two thiocarbonylthio-containing groups
CN113195567B (zh) 2018-12-19 2023-01-03 3M创新有限公司 两性离子共聚物、涂料组合物、制品和涂覆方法
WO2020149385A1 (ja) * 2019-01-16 2020-07-23 積水フーラー株式会社 架橋性ブロック共重合体及びコーティング剤
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JPWO2020149387A1 (ja) * 2019-01-16 2021-02-18 積水フーラー株式会社 架橋性ブロック共重合体及びその製造方法並びに伸縮性部材
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EP4182361A1 (en) 2020-07-16 2023-05-24 3M Innovative Properties Company Phosphonate-containing polymers for virulence suppression
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WO2023037185A1 (en) 2021-09-13 2023-03-16 3M Innovative Properties Company (meth)acrylic-epoxy uv initiated adhesive compositions and adhesive-containing articles
CN120019113A (zh) 2022-10-10 2025-05-16 3M创新有限公司 可电脱粘的uv活化粘合剂
WO2025083620A1 (en) 2023-10-20 2025-04-24 3M Innovative Properties Company Tape including a curable adhesive film and related adhesive system and method
WO2025181577A1 (en) 2024-02-29 2025-09-04 3M Innovative Properties Company Curable adhesive composition comprising epoxy, initiator and metal compound, articles and methods
WO2025215476A1 (en) 2024-04-10 2025-10-16 3M Innovative Properties Company Adhesives comprising epoxy and (meth)acrylic polymer comprising toughening agent
WO2025215510A1 (en) 2024-04-10 2025-10-16 3M Innovative Properties Company Adhesives comprising epoxy and (meth)acrylic polymer comprising polymerized (meth) acryl macromer

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US20190153142A1 (en) 2019-05-23
CN109476774A (zh) 2019-03-15
WO2018013330A1 (en) 2018-01-18
EP3481872A1 (en) 2019-05-15
CN109476774B (zh) 2021-01-12
US10400055B2 (en) 2019-09-03
EP3481872B1 (en) 2020-04-08
JP2019520465A (ja) 2019-07-18

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