JP6862548B2 - オレフィン重合体、その製造方法、そしてこれを利用したフィルム - Google Patents
オレフィン重合体、その製造方法、そしてこれを利用したフィルム Download PDFInfo
- Publication number
- JP6862548B2 JP6862548B2 JP2019531705A JP2019531705A JP6862548B2 JP 6862548 B2 JP6862548 B2 JP 6862548B2 JP 2019531705 A JP2019531705 A JP 2019531705A JP 2019531705 A JP2019531705 A JP 2019531705A JP 6862548 B2 JP6862548 B2 JP 6862548B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- olefin polymer
- molecular weight
- chemical formula
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 116
- 238000004519 manufacturing process Methods 0.000 title claims description 63
- 125000004432 carbon atom Chemical group C* 0.000 claims description 93
- 150000003623 transition metal compounds Chemical class 0.000 claims description 65
- 229920000642 polymer Polymers 0.000 claims description 53
- 239000003054 catalyst Substances 0.000 claims description 49
- 239000000126 substance Substances 0.000 claims description 48
- 238000009826 distribution Methods 0.000 claims description 42
- 125000000217 alkyl group Chemical group 0.000 claims description 32
- 238000005227 gel permeation chromatography Methods 0.000 claims description 25
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 20
- 239000005977 Ethylene Substances 0.000 claims description 20
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 20
- -1 ethylene, propylene, 1-butene Chemical class 0.000 claims description 19
- 150000001336 alkenes Chemical class 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052736 halogen Inorganic materials 0.000 claims description 15
- 150000002367 halogens Chemical class 0.000 claims description 15
- 239000003426 co-catalyst Substances 0.000 claims description 13
- 239000000178 monomer Substances 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 8
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002879 Lewis base Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Chemical group 0.000 claims description 2
- 229910052795 boron group element Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 47
- 239000003446 ligand Substances 0.000 description 28
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000704 physical effect Effects 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 13
- 125000001424 substituent group Chemical group 0.000 description 12
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
- 238000000465 moulding Methods 0.000 description 10
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 8
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 7
- 239000012968 metallocene catalyst Substances 0.000 description 7
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 6
- FNGROCHVLIICND-UHFFFAOYSA-N 3,4-dimethyl-1h-indene Chemical compound C1=CC(C)=C2C(C)=CCC2=C1 FNGROCHVLIICND-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000012018 catalyst precursor Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- IRAWLGHJHQBREM-UHFFFAOYSA-N 4-methyl-1h-indene Chemical compound CC1=CC=CC2=C1C=CC2 IRAWLGHJHQBREM-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- WFZSIVNWLIYDJZ-UHFFFAOYSA-N dichloro-methyl-[6-[(2-methylpropan-2-yl)oxy]hexyl]silane Chemical compound CC(C)(C)OCCCCCC[Si](C)(Cl)Cl WFZSIVNWLIYDJZ-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000002950 monocyclic group Chemical group 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-Butyllithium Substances [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- WCFQIFDACWBNJT-UHFFFAOYSA-N $l^{1}-alumanyloxy(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]O[Al] WCFQIFDACWBNJT-UHFFFAOYSA-N 0.000 description 1
- RURFJXKOXIWFJX-UHFFFAOYSA-N (2,3,4,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C=C(F)C(F)=C1F RURFJXKOXIWFJX-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- HMDQPBSDHHTRNI-UHFFFAOYSA-N 1-(chloromethyl)-3-ethenylbenzene Chemical compound ClCC1=CC=CC(C=C)=C1 HMDQPBSDHHTRNI-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 description 1
- COOKKJGOGWACMY-UHFFFAOYSA-N 3-methyl-1h-indene Chemical compound C1=CC=C2C(C)=CCC2=C1 COOKKJGOGWACMY-UHFFFAOYSA-N 0.000 description 1
- UDMMZSJNHAWYKX-UHFFFAOYSA-N 4-phenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C(C=C2)CCC21C1=CC=CC=C1 UDMMZSJNHAWYKX-UHFFFAOYSA-N 0.000 description 1
- RSPAIISXQHXRKX-UHFFFAOYSA-L 5-butylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound Cl[Zr+2]Cl.CCCCC1=CC=C[CH-]1.CCCCC1=CC=C[CH-]1 RSPAIISXQHXRKX-UHFFFAOYSA-L 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- CNDYTVOSGLPGNK-UHFFFAOYSA-N C(C)(C)(C)OCCCCCC[Si](NC(C)(C)C)(C)C1(CCC2=CC=CC(=C12)C)C Chemical compound C(C)(C)(C)OCCCCCC[Si](NC(C)(C)C)(C)C1(CCC2=CC=CC(=C12)C)C CNDYTVOSGLPGNK-UHFFFAOYSA-N 0.000 description 1
- JZJDQBZDSBCARL-UHFFFAOYSA-N CC1=C(CC2=C1C1=C(S2)C=CC=C1)C Chemical compound CC1=C(CC2=C1C1=C(S2)C=CC=C1)C JZJDQBZDSBCARL-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- YSSHVZSQQGCSMS-UHFFFAOYSA-N N-[chloro-methyl-[6-[(2-methylpropan-2-yl)oxy]hexyl]silyl]-2-methylpropan-2-amine Chemical compound C(C)(C)(C)OCCCCCC[Si](NC(C)(C)C)(C)Cl YSSHVZSQQGCSMS-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- UMAPFJZTGMTFIR-UHFFFAOYSA-N [2,3,5,6-tetrafluoro-4-tri(propan-2-yl)silylphenoxy]boronic acid Chemical compound CC(C)[Si](C(C)C)(C(C)C)C1=C(F)C(F)=C(OB(O)O)C(F)=C1F UMAPFJZTGMTFIR-UHFFFAOYSA-N 0.000 description 1
- DXJQUQZVFDBVNK-UHFFFAOYSA-N [amino(chloro)silyl]methane Chemical compound C[SiH](N)Cl DXJQUQZVFDBVNK-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 125000002676 chrysenyl group Chemical group C1(=CC=CC=2C3=CC=C4C=CC=CC4=C3C=CC12)* 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- NWKBSEBOBPHMKL-UHFFFAOYSA-N dichloro(methyl)silane Chemical compound C[SiH](Cl)Cl NWKBSEBOBPHMKL-UHFFFAOYSA-N 0.000 description 1
- MYBJXSAXGLILJD-UHFFFAOYSA-N diethyl(methyl)alumane Chemical compound CC[Al](C)CC MYBJXSAXGLILJD-UHFFFAOYSA-N 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SHGOGDWTZKFNSC-UHFFFAOYSA-N ethyl(dimethyl)alumane Chemical compound CC[Al](C)C SHGOGDWTZKFNSC-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JZBZLRKFJWQZHU-UHFFFAOYSA-N n,n,2,4,6-pentamethylaniline Chemical compound CN(C)C1=C(C)C=C(C)C=C1C JZBZLRKFJWQZHU-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- GOJIVVWJAXAPGS-UHFFFAOYSA-N n-dodecyl-n-methylaniline Chemical compound CCCCCCCCCCCCN(C)C1=CC=CC=C1 GOJIVVWJAXAPGS-UHFFFAOYSA-N 0.000 description 1
- UWHRNIXHZAWBMF-UHFFFAOYSA-N n-dodecyl-n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)CCCCCCCCCCCC UWHRNIXHZAWBMF-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QMRNDFMLWNAFQR-UHFFFAOYSA-N prop-2-enenitrile;prop-2-enoic acid;styrene Chemical compound C=CC#N.OC(=O)C=C.C=CC1=CC=CC=C1 QMRNDFMLWNAFQR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- NDUUEFPGQBSFPV-UHFFFAOYSA-N tri(butan-2-yl)alumane Chemical compound CCC(C)[Al](C(C)CC)C(C)CC NDUUEFPGQBSFPV-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- PYLGJXLKFZZEBJ-UHFFFAOYSA-N tricyclopentylalumane Chemical compound C1CCCC1[Al](C1CCCC1)C1CCCC1 PYLGJXLKFZZEBJ-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- JOJQVUCWSDRWJE-UHFFFAOYSA-N tripentylalumane Chemical compound CCCCC[Al](CCCCC)CCCCC JOJQVUCWSDRWJE-UHFFFAOYSA-N 0.000 description 1
- JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- WSITXTIRYQMZHM-UHFFFAOYSA-N tris(4-methylphenyl)alumane Chemical compound C1=CC(C)=CC=C1[Al](C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WSITXTIRYQMZHM-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/10—Short chain branches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/26—Use as polymer for film forming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08J2323/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
Description
本出願は、2017年12月18日付韓国特許出願第10−2017−0174517号および2018年11月27日付韓国特許出願第10−2018−0148557号に基づいた優先権の利益を主張し、当該韓国特許出願の文献に開示全ての内容は本明細書の一部として組み含まれる。
i)前記オレフィン重合体に含有されている複数の高分子鎖のそれぞれが有する炭素1000個当たりの炭素数2乃至7個の分岐含有量の平均値(FT−IRにより測定)が20個/1000C以上であり、ii)厚さ100μmのフィルムで成形してASTM D1709Aを基準に測定した落下衝撃強度が1500g乃至2400gであり、iii)厚さ0.05mmのフィルムで成形してASTM D1003を基準に測定したヘイズが10%乃至30%である。
[Cp1(R7)u][Cp2(R8)v]M2X3X4
C1は下記の化学式3で表されるリガンドであり、
Zは−O−、−S−、−NR3−または−PR4−であり、
R3およびR4は互いに同一または異なり、それぞれ独立して水素、または炭素数1乃至20のアルキル基であり、
M1およびM2は互いに同一または異なり、それぞれ独立してTi、ZrまたはHfであり、
X1乃至X4は互いに同一または異なり、それぞれ独立してハロゲンであり、
Tは
T1はC、Si、Ge、SnまたはPbであり、
Y1は炭素数1乃至20のアルコキシアルキル基であり、
Y2は炭素数1乃至20のアルキル基であり、
Cp1およびCp2はシクロペンタジエニル基であり、
R7およびR8は互いに同一または異なり、それぞれ独立して水素、または炭素数1乃至20のアルキル基であり、
uおよびvはそれぞれ独立して0乃至5の間の整数である。
R3は炭素数1乃至10のアルキル基であり、
M1はTi、ZrまたはHfであり、
X1およびX2は互いに同一または異なり、それぞれ独立してハロゲンであり、
T1はCまたはSiであり、
Y1は炭素数1乃至20のアルコキシアルキル基であり、
Y2は炭素数1乃至20のアルキル基である。
M2はTi、ZrまたはHfであり、
X3およびX4は互いに同一または異なり、それぞれ独立してハロゲンである。
[化学式6]
−[Al(R9)−O]m−
前記化学式6で、R9は互いに同一でも異なっていてもよく、それぞれ独立してハロゲン;炭素数1乃至20のアルキル基;またはハロゲンで置換された炭素数1乃至20のアルキル基であり;mは2以上の整数であり;
[化学式7]
J(R10)3
前記化学式7で、R10は互いに同一でも異なっていてもよく、それぞれ独立してハロゲン;炭素数1乃至20のアルキル基;またはハロゲンで置換された炭素数1乃至20のアルキル基であり;Jはアルミニウムまたはホウ素であり;
[化学式8]
[E−H]+[ZA4]-または[E]+[ZA4]-
前記化学式8で、Eは中性または陽イオン性ルイス塩基であり;Hは水素原子であり;Zは第13族元素であり;Aは互いに同一でも異なっていてもよく、それぞれ独立して1以上の水素原子がハロゲン、炭素数1乃至20のアルキル基、アルコキシまたはフェノキシで置換もしくは非置換された炭素数6乃至20のアリール基または炭素数1乃至20のアルキル基である。
250mLのシュレンクフラスコ(schlenk flask)にt−ブチルアミン13mL(120mmol)とエーテル溶媒20mLを入れ、前記フラスコ(flask)と異なる250mLのシュレンクフラスコ(schlenk flask)に(6−tert−ブトキシヘキシル)ジクロロ(メチル)シラン16g(60mmol)とエーテル溶媒40mLを入れてt−ブチルアミン溶液および(6−tert−ブトキシヘキシル)ジクロロ(メチル)シラン溶液をそれぞれ準備した。そして、前記t−ブチルアミン溶液を−78℃に冷却した後、冷却された溶液に(6−tert−ブトキシヘキシル)ジクロロ(メチル)シラン溶液を徐々に注入し、これを常温で約2時間攪拌した。生成された白色の懸濁液(white suspension)を濾過してアイボリー(ivory)色を浮かび、液状である1−(6−(tert−ブトキシ)ヘキシル)−N−(tert−ブチル)−1−クロロ−1−メチルシランアミン(リガンドB)を得た。
(3)リガンドAおよびBの架橋
250mLのシュレンクフラスコ(schlenk flask)に3,4−ジメチル−1H−インデン(リガンドA)1.7g(8.6mmol)を入れ、THF30mLを添加してリガンドA溶液を製造した。前記リガンドA溶液を−78℃に冷却した後、n−BuLi溶液3.6mL(9.1mmol、2.5M in hexane)を前記リガンドA溶液に添加し、これを常温で一晩攪拌してパープルブラウン(purple−brown)の溶液を得た。前記パープルブラウン(purple−brown)溶液の溶媒をトルエンで置き換え、この溶液にCuCN 39mg(0.43mmol)をTHF2mLに分散させた溶液を注入して溶液Aを製造した。
250mLのシュレンクフラスコ(schlenk flask)に1−(6−(tert−ブトキシ)ヘキシル)−N−(tert−ブチル)−1−(3,4−ジメチル−1H−インデン−3−イル)−1−メチルシランアミン(リガンドAおよびBの架橋生成物)4.2gを入れ、前記フラスコ(flask)にトルエン14mLとn−ヘキサン1.7mLを注入して架橋生成物を溶解した。この溶液を−78℃に冷却した後、n−BuLi溶液7.3mL(18mmol、2.5M in hexane)を前記冷却された溶液に注入した。そして、前記溶液を常温で約12時間攪拌した。次に、前記溶液にトリメチルアミン5.3mL(38mmol)を投入し、この溶液を約40℃で約3時間攪拌して溶液Cを準備した。
製造例1の(1)リガンドAとして3,4−ジメチル−1H−インデンの代わりに4−メチル−1H−インデンを用いたことを除き、製造例1と同様な方法で下記構造の遷移金属化合物を製造した。
製造例1の(1)リガンドAとして3,4−ジメチル−1H−インデンの代わりに3−メチル−1H−インデンを用いたことを除き、製造例1と同様な方法で下記構造の遷移金属化合物を製造した。
製造例1の(1)リガンドAとして3,4−ジメチル−1H−インデンの代わりに1,2−ジメチル−3H−ベンゾ[b]シクロペンタ[d]チオフェンを用いたことを除き、製造例1と同様な方法で下記構造の遷移金属化合物を製造した。
製造例1の(1)リガンドAとして3,4−ジメチル−1H−インデンの代わりに1H−インデンを用いたことを除き、製造例1と同様な方法で下記構造の遷移金属化合物を製造した。
(実施例1:混成担持触媒の製造およびこれを利用したオレフィン重合体の製造)
(1)混成担持触媒の製造
300mLのガラス反応器にトルエン100mLを入れ、反応器温度40℃で、シリカ(Grace Davison、SP952)7gを投入した後、攪拌した。以降、10wt%メチルアルミノキサン(MAO)/トルエン溶液(Albemarle社)を5.3mLを投入し、95℃に昇温しながら2時間攪拌(stirring)させた。以降、反応器温度を40℃に低くした後、攪拌を中止し、10分間沈殿(settling)した後、反応溶液をデカンテーション(decantation)した。以降、トルエン100mLを投入し、10分間攪拌した後、攪拌を中止し、10分間沈殿(settling) させ、トルエン溶液をデカンテーション(decantation) した。以降、反応器にトルエン50mLを投入し、前記製造例1の遷移金属化合物0.30gと第2遷移金属化合物としてビス(n−ブチルシクロペンタジエニル)−ジルコニウムジクロリドをグローブボックス(Glove Box)内で1:0.45のモル比率に混合した後、トルエン25mlに溶かして反応器に移送した後、80℃で500rpmで2時間攪拌した。以降、攪拌を中止し、10分間沈殿(settling) させた後、反応溶液をデカンテーション(decantation) した。以降、トルエン50mLを反応器に投入し、反応器温度を常温に下げた後、攪拌を中止し、10分間沈殿(settling) させた後、反応溶液をデカンテーション(decantation) した。以降、反応器にヘキサン100mLを投入し、アクリロニトリルスチレンアクリレート(Acrylonitrile styrene acrylate、ASA)0.05mmolを入れて10分間攪拌後、ヘキサンスラリーを250mLのシュレンクフラスコ(schlenk flask)に移送し、ヘキサン溶液をデカンテーション(decantation) した。以降、常温で3時間減圧下で乾燥して、混成担持触媒を得た。
オレフィン重合体の製造のために機械式攪拌器が装着されており、温度調節が可能であり、高圧の反応に使用可能な600mLの金属合金反応器を準備した。
一方、前記実施例1の(1)で製造した混成担持触媒をドライボックスで定量して50mLのガラス瓶に入れた後、前記ガラス瓶の入口をゴム隔膜で密封した。
そして、前記600mLの金属合金反応器に1.0mmolのトリエチルアルミニウムが含有されているヘキサン400mLと以前に準備した混成担持触媒を空気接触なしに投入した。次に、前記反応器の温度を約80℃に上げ、前記反応器にエチレンガスを注入して約1時間エチレンを重合した。この時、エチレンガスは反応器の圧力が約30kgf/cm2程度に維持されるように継続して注入された。
以降、エチレンが目的とする水準に重合されると、反応器の攪拌を止め、未反応エチレンガスを排気させて除去した。そして、反応生成物で溶媒を除去して得られた固体を約80℃の真空オーブンで約4時間乾燥させてエチレン単独重合体を得た。
実施例1で第1遷移金属化合物として製造例2で製造した遷移金属化合物を用いたことを除き、実施例1と同様な方法で混成担持触媒を製造し、前記混成担持触媒を利用して実施例1と同様な方法でエチレン単独重合体を得た。
実施例1で第1遷移金属化合物として製造例3で製造した遷移金属化合物を用いたことを除き、実施例1と同様な方法で混成担持触媒を製造し、前記混成担持触媒を利用して実施例1と同様な方法でエチレン単独重合体を得た。
実施例1で第1遷移金属化合物として比較製造例1で製造した遷移金属化合物を用いたことを除き、実施例1と同様な方法で混成担持触媒を製造し、前記混成担持触媒を利用して実施例1と同様な方法でエチレン単独重合体を得た。
実施例1で第1遷移金属化合物として比較製造例2で製造した遷移金属化合物を用いたことを除き、実施例1と同様な方法で混成担持触媒を製造し、前記混成担持触媒を利用して実施例1と同様な方法でエチレン単独重合体を得た。
実施例1で第1遷移金属化合物として比較製造例3で製造した遷移金属化合物を用いたことを除き、実施例1と同様な方法で混成担持触媒を製造し、前記混成担持触媒を利用して実施例1と同様な方法でエチレン単独重合体を得た。
(試験例1:オレフィン重合体の物性測定)
前記実施例1乃至3および比較例1乃至3で製造したエチレン単独重合体の物性を測定し、その結果を下記表1に示した。
ゲル透過クロマトグラフィー(GPC:Gel Permeation Chromatography)を利用して、重合体の重量平均分子量(Mw)と数平均分子量(Mn)を測定し、重量平均分子量を数平均分子量で割って分子量分布(PDI)を計算した。
この時、ゲル透過クロマトグラフィーの測定機器および測定条件は次のとおりである。
Polymer Laboratories PLgel MIX−B 300mm長さのカラム、Waters PL−GPC220機器を利用して、評価温度は160℃であり、1,2,4−トリクロロベンゼンを溶媒として用い、流速は1mL/minの速度であり、サンプルは10mg/10mLの濃度に調製した後、200μLの量で供給し、ポリスチレン標準を利用して形成された検定曲線を利用してMw、Mn、PDIの値を求めることができる。ポリスチレン標準品の分子量は、2,000/10,000/30,000/70,000/200,000/700,000/2,000,000/4,000,000/10,000,000の9種を用いた。
ゲル透過クロマトグラフィー(GPC:Gel Permeation Chromatography)を利用して分子量(M)のログ値(log M)をx軸にし、前記ログ値に対する分子量分布(dwt/dlog M)をy軸にして分子量分布曲線を描いた。下記図1、図2では連続的な実線で表示した。
<測定条件>
波数(wavenumber):2700cm-1乃至3000cm-1
スキャン回数(number of scanning):16回
解像度(resolution):8cm-1
検出器(detector):DTGS
前記実施例1乃至3、比較例1乃至3のオレフィン重合体を酸化防止剤(Iganox 1010+Igafos 168、CIBA社)処方後、二軸押出機で製粒後、短縮押出機(SHINHWA工業 Single Screw Extruder、Blown Film M/C、50パイ、L/D=20)を利用して押出温度165〜200℃で0.05mmの厚さになるようにインフレーション成形してフィルムを製造した。この時、ダイギャップ(Die Gap)は2.0mm、膨張比(Blown−Up Ratio)は2.3であった。
Claims (12)
- 下記i)乃至iii)の条件を満たすエチレン単独重合体、またはエチレンと、プロピレン、1−ブテン、1−ヘキセン、4−メチル−1−ペンテンおよび1−オクテンからなる群より選択されるα―オレフィンの共重合体であるオレフィン重合体:
i)前記オレフィン重合体に含有されている複数の高分子鎖のそれぞれが有する炭素1000個当たりの炭素数2乃至7個の分岐含有量の平均値(FT−IRにより測定)が20個/1000C乃至30個/1000Cであり、
ii)厚さ100μmのフィルムに成形してASTM D1709Aを基準に測定した落下衝撃強度が1550g乃至1700gであり、
iii)厚さ0.05mmのフィルムに成形してASTM D1003を基準に測定したヘイズが20%乃至27.8%である。 - ゲル透過クロマトグラフィーにより得られた分子量(M)のログ値(log M)をx軸にし、FT−IRにより得られた前記ログ値に対する炭素1,000個当たりの炭素数2乃至7個の分岐含有量をy軸にするSCB分布曲線において、
重量平均分子量のログ値に該当するx軸上の地点を0.5といい、最小分子量のログ値に該当するx軸上の地点を0、最大分子量のログ値に該当するx軸上の地点を1という時、
x軸上0.8乃至1.0の区間内に最大の炭素1,000個当たりの炭素数2乃至7個の分岐含有量を有する、請求項1に記載のオレフィン重合体。 - ゲル透過クロマトグラフィーにより得られた分子量(M)のログ値(log M)をx軸にし、FT−IRにより得られた前記ログ値に対する炭素1,000個当たりの炭素数2乃至7個の分岐含有量をy軸にするSCB分布曲線において、
重量平均分子量のログ値に該当するx軸上の地点を0.5といい、最小分子量のログ値に該当するx軸上の地点を0、最大分子量のログ値に該当するx軸上の地点を1という時、
x軸上0乃至0.2の区間内に最小の炭素1,000個当たりの炭素数2乃至7個の分岐含有量を有する、請求項1または2に記載のオレフィン重合体。 - 前記オレフィン重合体は、分子量分布が5乃至10である、請求項1乃至3のいずれかに記載のオレフィン重合体。
- 前記オレフィン重合体は、溶融指数(ASTM D1238により230で2.16kg荷重で測定)が0.80g/10min乃至0.93g/10minである、請求項1乃至4のいずれかに記載のオレフィン重合体。
- 前記オレフィン重合体は、密度(ASTM1505)が0.910g/cm3乃至0.930g/cm3である、請求項1乃至5のいずれかに記載のオレフィン重合体。
- 前記オレフィン重合体は、重量平均分子量(GPC測定)が100000g/mol乃至150000g/molである、請求項1乃至6のいずれかに記載のオレフィン重合体。
- 下記の化学式4で表される第1遷移金属化合物;下記の化学式5で表される第2遷移金属化合物;および前記第1および第2遷移金属化合物が担持された担体を含む混成担持触媒存在下で、オレフィン単量体を重合する段階を含み、
前記オレフィン単量体はエチレンであるか、またはエチレンと、プロピレン、1−ブテン、1−ヘキセン、4−メチル−1−ペンテンおよび1−オクテンからなる群より選択される1種以上を含む、請求項1乃至7のいずれかに記載のオレフィン重合体の製造方法:
R 3 は炭素数1乃至10のアルキル基であり、
M 1 はTi、ZrまたはHfであり、
X 1 およびX 2 は互いに同一または異なり、それぞれ独立してハロゲンであり、
T 1 はCまたはSiであり、
Y 1 は炭素数1乃至20のアルコキシアルキル基であり、
Y 2 は炭素数1乃至20のアルキル基であり、
M 2 はTi、ZrまたはHfであり、
X 3 およびX 4 は互いに同一または異なり、それぞれ独立してハロゲンである。 - 第1遷移金属化合物と第2遷移金属化合物は、1:0.1乃至1:0.9のモル比で含まれる、請求項8に記載のオレフィン重合体の製造方法。
- 前記担体は、シリカ、アルミナ、マグネシアまたはこれらの混合物である、請求項8または9に記載のオレフィン重合体の製造方法。
- 前記混成担持触媒は、下記の化学式6乃至8で表される化合物からなる群より選択される1種以上の助触媒を追加的に含む、請求項8乃至10のいずれかに記載のオレフィン重合体の製造方法:
[化学式6]
−[Al(R9)−O]m−
前記化学式6で、
R9は互いに同一でも異なっていてもよく、それぞれ独立してハロゲン;炭素数1乃至20のアルキル基;またはハロゲンで置換された炭素数1乃至20のアルキル基であり; mは2以上の整数であり;
[化学式7]
J(R10)3
前記化学式7で、
R10は互いに同一でも異なっていてもよく、それぞれ独立してハロゲン;炭素数1乃至20のアルキル基;またはハロゲンで置換された炭素数1乃至20のアルキル基であり; Jはアルミニウムまたはホウ素であり;
[化学式8]
[E−H]+[ZA4]-または[E]+[ZA4]-
前記化学式8で、
Eは中性または陽イオン性ルイス塩基であり;
Hは水素原子であり;
Zは第13族元素であり;
Aは互いに同一でも異なっていてもよく、それぞれ独立して1以上の水素原子がハロゲン、炭素数1乃至20のアルキル基、アルコキシまたはフェノキシで置換もしくは非置換された炭素数6乃至20のアリール基または炭素数1乃至20のアルキル基である。 - 請求項1乃至7のいずれかに記載のオレフィン重合体を含む、フィルム。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20170174517 | 2017-12-18 | ||
KR10-2017-0174517 | 2017-12-18 | ||
KR1020180148557A KR102133030B1 (ko) | 2017-12-18 | 2018-11-27 | 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름 |
KR10-2018-0148557 | 2018-11-27 | ||
PCT/KR2018/014973 WO2019124805A1 (ko) | 2017-12-18 | 2018-11-29 | 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020505480A JP2020505480A (ja) | 2020-02-20 |
JP6862548B2 true JP6862548B2 (ja) | 2021-04-21 |
Family
ID=67104931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019531705A Active JP6862548B2 (ja) | 2017-12-18 | 2018-11-29 | オレフィン重合体、その製造方法、そしてこれを利用したフィルム |
Country Status (6)
Country | Link |
---|---|
US (1) | US10894843B2 (ja) |
EP (1) | EP3560965A4 (ja) |
JP (1) | JP6862548B2 (ja) |
KR (1) | KR102133030B1 (ja) |
CN (1) | CN110291117B (ja) |
BR (1) | BR112019018083A2 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200144973A (ko) | 2019-06-20 | 2020-12-30 | 주식회사 만도 | 스티어 바이 와이어식 조향장치 |
WO2022039425A1 (ko) | 2020-08-19 | 2022-02-24 | 주식회사 엘지화학 | 펠렛형 폴리에틸렌 수지 조성물 및 그 제조방법 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG131121A1 (en) * | 2003-10-22 | 2007-04-26 | Sumitomo Chemical Co | Process for producing modified particle, carrier or catalyst component for addition polymerization, pre-polymerized catalyst component therefor, catalyst therefor, and addition polymer |
US7122691B2 (en) * | 2004-03-30 | 2006-10-17 | Sumitomo Chemical Company, Limited | Process for producing compound, catalyst component for addition polymerization, process for producing catalyst for addition polymerization, and process for producing addition polymer |
JP4655509B2 (ja) * | 2004-05-13 | 2011-03-23 | 住友化学株式会社 | 接触処理物、付加重合用触媒成分、付加重合用触媒および付加重合体の製造方法 |
JP2006002098A (ja) | 2004-06-21 | 2006-01-05 | Nippon Polyethylene Kk | 新規なエチレン系重合体及びその製造方法 |
WO2006080475A1 (ja) * | 2005-01-28 | 2006-08-03 | Sumitomo Chemical Company, Limited | 遷移金属錯体、該遷移金属錯体の製造方法、置換フルオレン化合物、該置換フルオレン化合物の製造方法、オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
KR101038592B1 (ko) | 2008-08-27 | 2011-06-03 | 삼성토탈 주식회사 | 고수축성 선형 저밀도 폴리에틸렌 수지 |
WO2010034464A1 (en) * | 2008-09-25 | 2010-04-01 | Basell Polyolefine Gmbh | Impact resistant lldpe composition and films made thereof |
MX2011003161A (es) | 2008-09-25 | 2011-05-19 | Basell Polyolefine Gmbh | Composicion de polietileno lineal de baja densidad (lldpe) resistente a impactos y peliculas hechas de la misma. |
EP2361281B1 (en) | 2008-09-25 | 2012-11-21 | Basell Polyolefine GmbH | Impact resistant lldpe composition and films made thereof |
WO2010034520A1 (en) | 2008-09-25 | 2010-04-01 | Basell Polyolefine Gmbh | Impact resistant lldpe composition and films made thereof |
EP2177548A1 (en) | 2008-10-14 | 2010-04-21 | Ineos Europe Limited | Copolymers and films thereof |
KR101288500B1 (ko) | 2009-03-12 | 2013-07-26 | 주식회사 엘지화학 | 낙추 충격강도와 투명도가 우수한 필름용 폴리에틸렌 및 이의 제조방법 |
EP2348057A1 (en) | 2010-01-21 | 2011-07-27 | INEOS Manufacturing Belgium NV | Novel polymers |
JP6454152B2 (ja) * | 2011-11-23 | 2019-01-16 | ダウ グローバル テクノロジーズ エルエルシー | 低分子量の抽出物を有する低密度エチレン系ポリマー |
KR101657680B1 (ko) | 2013-09-30 | 2016-09-19 | 주식회사 엘지화학 | 폴리올레핀 |
KR101549209B1 (ko) | 2013-11-18 | 2015-09-02 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
KR101774615B1 (ko) * | 2013-12-02 | 2017-09-04 | 주식회사 엘지화학 | 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법 |
EP3160742A1 (en) * | 2014-06-26 | 2017-05-03 | Dow Global Technologies LLC | Cast films with improved toughness |
KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
JP2016067509A (ja) | 2014-09-29 | 2016-05-09 | 能美防災株式会社 | 消火用ヘッド |
KR101725351B1 (ko) * | 2014-12-04 | 2017-04-10 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매 |
KR101577170B1 (ko) * | 2015-07-03 | 2015-12-11 | 박주현 | 유무선 융합 시스템에서의 음성 통신 제어를 위한 장치 및 방법 |
WO2017048392A1 (en) * | 2015-09-17 | 2017-03-23 | Exxonmobil Chemical Patents Inc. | Polyethylene polymers and articles made therefrom |
EP3168237A1 (en) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
EP3168239A1 (en) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure free radical polymerizations |
KR102204960B1 (ko) | 2015-12-24 | 2021-01-19 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법, 상기 제조방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조방법 |
KR102083001B1 (ko) * | 2016-09-23 | 2020-02-28 | 주식회사 엘지화학 | 올레핀계 공중합체 및 이의 제조 방법 |
KR102140260B1 (ko) * | 2016-12-22 | 2020-07-31 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
US9963529B1 (en) * | 2017-04-19 | 2018-05-08 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization |
US10442921B2 (en) * | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
EP3881502A4 (en) * | 2018-11-14 | 2022-07-06 | ZTE Corporation | METHODS, APPARATUS AND SYSTEMS FOR SATISFYING A TIME CONTROL REQUIREMENT IN WIRELESS COMMUNICATION |
US10961331B2 (en) * | 2018-12-19 | 2021-03-30 | Chevron Phillips Chemical Company Lp | Ethylene homopolymers with a reverse short chain branch distribution |
-
2018
- 2018-11-27 KR KR1020180148557A patent/KR102133030B1/ko active IP Right Grant
- 2018-11-29 BR BR112019018083-4A patent/BR112019018083A2/pt active Search and Examination
- 2018-11-29 EP EP18891719.9A patent/EP3560965A4/en active Pending
- 2018-11-29 CN CN201880011256.9A patent/CN110291117B/zh active Active
- 2018-11-29 US US16/478,692 patent/US10894843B2/en active Active
- 2018-11-29 JP JP2019531705A patent/JP6862548B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
EP3560965A1 (en) | 2019-10-30 |
KR102133030B1 (ko) | 2020-07-10 |
JP2020505480A (ja) | 2020-02-20 |
CN110291117B (zh) | 2021-06-22 |
BR112019018083A2 (pt) | 2020-07-07 |
CN110291117A (zh) | 2019-09-27 |
US10894843B2 (en) | 2021-01-19 |
EP3560965A4 (en) | 2020-01-22 |
KR20190073264A (ko) | 2019-06-26 |
US20200115475A1 (en) | 2020-04-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106687487B (zh) | 具有优异的加工性的基于烯烃的聚合物 | |
CN106661160B (zh) | 具有优异加工性的乙烯/α-烯烃共聚物 | |
EP3031832B1 (en) | Method for preparing polyolefin | |
KR101593666B1 (ko) | 가공성이 우수한 올레핀계 중합체 | |
EP3070108A1 (en) | Ethylene/alpha-olefin copolymer having excellent processability | |
CN107207661B (zh) | 具有优异的加工性能和表面特性的乙烯/α-烯烃共聚物 | |
EP3078682B1 (en) | Olefin-based polymer having excellent processability | |
JP7238135B2 (ja) | オレフィン重合用触媒およびこれを用いて調製されたオレフィン系重合体 | |
KR20100028317A (ko) | 혼성 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한 폴리올레핀의 제조방법 | |
CN117384316A (zh) | 具有优异的长期物理性能和加工性的乙烯/1-己烯共聚物 | |
JP6862548B2 (ja) | オレフィン重合体、その製造方法、そしてこれを利用したフィルム | |
CN110914316B (zh) | 聚丙烯及其制备方法 | |
KR20180046291A (ko) | 내환경 응력 균열성이 우수한 에틸렌/알파-올레핀 공중합체 | |
CN108290971B (zh) | 金属茂负载型催化剂及使用该催化剂制备聚烯烃的方法 | |
JP7118500B2 (ja) | 混成担持触媒およびそれを用いたポリオレフィンの製造方法 | |
JP7362192B2 (ja) | 施工性および加工性に優れたエチレン/1-ヘキセン共重合体 | |
KR20220066744A (ko) | 혼성 담지 촉매 | |
WO2019124805A1 (ko) | 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름 | |
KR20210048330A (ko) | 혼성 담지 촉매 | |
JP2021519854A (ja) | オレフィン系共重合体及びその製造方法 | |
WO2015072658A1 (ko) | 가공성이 우수한 올레핀계 중합체 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20190620 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20200629 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200827 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20201120 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210325 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210331 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6862548 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |