JP6574133B2 - 混合硫酸塩含有リン酸マンガン金属リチウム - Google Patents

混合硫酸塩含有リン酸マンガン金属リチウム Download PDF

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Publication number
JP6574133B2
JP6574133B2 JP2015526986A JP2015526986A JP6574133B2 JP 6574133 B2 JP6574133 B2 JP 6574133B2 JP 2015526986 A JP2015526986 A JP 2015526986A JP 2015526986 A JP2015526986 A JP 2015526986A JP 6574133 B2 JP6574133 B2 JP 6574133B2
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Prior art keywords
lithium
mixed
metal phosphate
carbon
manganese metal
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Japanese (ja)
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JP2015526860A (ja
JP2015526860A5 (enExample
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トラン,ニコラス
ナスピル,ゲールハルト
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Johnson Matthey PLC
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Johnson Matthey PLC
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
JP2015526986A 2012-08-14 2013-08-14 混合硫酸塩含有リン酸マンガン金属リチウム Active JP6574133B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12180404.1A EP2698346A1 (en) 2012-08-14 2012-08-14 Mixed sulphate containing lithium-manganese-metal phosphate
EP12180404.1 2012-08-14
PCT/EP2013/067038 WO2014027046A2 (en) 2012-08-14 2013-08-14 Mixed sulphate containing lithium-manganese-metal phosphate

Publications (3)

Publication Number Publication Date
JP2015526860A JP2015526860A (ja) 2015-09-10
JP2015526860A5 JP2015526860A5 (enExample) 2018-08-09
JP6574133B2 true JP6574133B2 (ja) 2019-09-11

Family

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JP2015526986A Active JP6574133B2 (ja) 2012-08-14 2013-08-14 混合硫酸塩含有リン酸マンガン金属リチウム

Country Status (8)

Country Link
US (1) US20150232337A1 (enExample)
EP (2) EP2698346A1 (enExample)
JP (1) JP6574133B2 (enExample)
KR (1) KR101751423B1 (enExample)
CN (1) CN104603050B (enExample)
CA (1) CA2877556C (enExample)
TW (1) TW201431779A (enExample)
WO (1) WO2014027046A2 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220905B1 (ko) * 2016-09-23 2021-02-26 삼성에스디아이 주식회사 리튬이차전지용 음극 활물질 및 이를 포함한 음극을 함유한 리튬이차전지
CN109987616B (zh) * 2019-05-08 2021-07-30 上海中锂实业有限公司 一种由磷酸锂直接制备电池级氢氧化锂的方法
CN110937641B (zh) * 2019-11-20 2022-02-08 哈尔滨工业大学(深圳) 一种Sn元素掺杂的无钴锰基固溶体锂离子电池正极材料及其制备方法
CN113258073B (zh) * 2021-07-06 2021-09-28 湖南长远锂科股份有限公司 包覆改性锂离子电池正极材料及其制备方法
CN114212764B (zh) * 2021-11-30 2023-06-30 厦门厦钨新能源材料股份有限公司 一种磷酸盐正极材料前驱体、其制备方法及应用
CN114348982A (zh) * 2022-01-10 2022-04-15 雅安天蓝新材料科技有限公司 磷酸亚锰铁、磷酸亚锰铁锂及其制备方法、锂离子电池和涉电设备
CN116081589B (zh) * 2022-10-12 2024-03-29 北京钠谛科技有限公司 一种富锂硫磷酸铁锰锂材料及其制备方法
CN116941072B (zh) * 2023-04-13 2026-07-28 宁德时代新能源科技股份有限公司 正极活性材料、正极浆料、正极极片、电池和用电装置
CN117174898A (zh) * 2023-09-27 2023-12-05 惠州亿纬动力电池有限公司 磷酸锰铁锂材料及其制备方法、正极片及其制备方法、电池
CN117865108A (zh) * 2024-01-23 2024-04-12 天津大学 一种掺杂磷酸锰铁及制备方法
WO2026009121A1 (ja) * 2024-07-05 2026-01-08 株式会社半導体エネルギー研究所 リチウムイオン電池

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910382A (en) 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
WO1999061522A1 (en) 1998-05-29 1999-12-02 Solutia Inc. Nucleation of polyamides in the presence of hypophosphite
JP4495336B2 (ja) 2000-11-10 2010-07-07 株式会社Kri 鉄リン酸リチウムの製造方法。
DE10117904B4 (de) 2001-04-10 2012-11-15 Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung
JP3631202B2 (ja) * 2001-12-21 2005-03-23 三洋電機株式会社 非水電解質電池
JP4187524B2 (ja) * 2002-01-31 2008-11-26 日本化学工業株式会社 リチウム鉄リン系複合酸化物炭素複合体、その製造方法、リチウム二次電池正極活物質及びリチウム二次電池
KR100449073B1 (ko) * 2002-10-15 2004-09-18 한국전자통신연구원 리튬 이차 전지용 양극 활물질 및 그 제조 방법
JP4260572B2 (ja) * 2003-07-29 2009-04-30 日本化学工業株式会社 Mn原子を含有するリチウム鉄リン系複合酸化物炭素複合体の製造方法
DE10353266B4 (de) 2003-11-14 2013-02-21 Süd-Chemie Ip Gmbh & Co. Kg Lithiumeisenphosphat, Verfahren zu seiner Herstellung und seine Verwendung als Elektrodenmaterial
JP4794833B2 (ja) * 2004-07-21 2011-10-19 日本コークス工業株式会社 リチウムイオン二次電池用正極材料、その製造方法、及びリチウムイオン二次電池
DE102005012640B4 (de) 2005-03-18 2015-02-05 Süd-Chemie Ip Gmbh & Co. Kg Kreisprozess zur nasschemischen Herstellung von Lithiummetallphosphaten
JP4525474B2 (ja) * 2005-06-06 2010-08-18 株式会社豊田中央研究所 リチウム二次電池用活物質及びその製造方法、リチウム二次電池
CA2566906A1 (en) * 2006-10-30 2008-04-30 Nathalie Ravet Carbon-coated lifepo4 storage and handling
KR101502440B1 (ko) 2007-07-12 2015-03-13 에이일이삼 시스템즈 인코포레이티드 리튬 이온 배터리용 다기능 혼합 금속 감람석
DE102007033460A1 (de) 2007-07-18 2009-01-22 Süd-Chemie AG Kreisprozess zur Herstellung von Bariumsulfat und Lithiummetallphosphatverbindungen
JP5323410B2 (ja) * 2007-07-27 2013-10-23 日本化学工業株式会社 リチウム鉄リン系複合酸化物炭素複合体の製造方法及びリチウム、鉄及びリンを含む共沈体の製造方法
JP5245351B2 (ja) * 2007-10-19 2013-07-24 株式会社豊田中央研究所 リチウム二次電池用活物質及びリチウム二次電池
FR2932396A1 (fr) * 2008-06-11 2009-12-18 Centre Nat Rech Scient Procede de preparation d'oxydes inorganiques par voie solvothermale
JP5509598B2 (ja) * 2009-01-09 2014-06-04 住友大阪セメント株式会社 電極材料及びその製造方法、並びに電極及び電池
CN102449821B (zh) * 2009-06-24 2014-12-24 株式会社杰士汤浅国际 锂二次电池用正极活性物质及锂二次电池
DE102010006077B4 (de) 2010-01-28 2014-12-11 Süd-Chemie Ip Gmbh & Co. Kg Substituiertes Lithium-Mangan-Metallphosphat
WO2011100487A2 (en) * 2010-02-12 2011-08-18 Applied Materials, Inc. HYDROTHERMAL SYNTHESIS OF LiFePO4 NANOPARTICLES
CN102781827B (zh) * 2010-03-19 2016-05-04 户田工业株式会社 磷酸锰铁锂颗粒粉末的制造方法、磷酸锰铁锂颗粒粉末和使用该颗粒粉末的非水电解质二次电池
CN103109399B (zh) * 2010-09-10 2015-11-25 海洋王照明科技股份有限公司 一种含锂盐-石墨烯复合材料及其制备方法
CN101997118A (zh) * 2010-11-02 2011-03-30 天津斯特兰能源科技有限公司 一种锂离子电池正极材料磷酸铁锰锂及其制备方法
US20120138867A1 (en) * 2010-11-11 2012-06-07 Phostech Lithium Inc. Carbon-deposited alkali metal oxyanion electrode material and process for preparing same
CN102290245B (zh) * 2011-04-29 2012-11-21 深圳市惠程电气股份有限公司 一种聚酰亚胺电容电池及其制作方法
CN102249208A (zh) * 2011-05-06 2011-11-23 朱鸥鹭 一种锂离子电池正极材料磷酸锰铁锂的水热合成方法
EP2522625B1 (en) * 2011-05-13 2014-06-04 Shin-Etsu Chemical Co., Ltd. Preparation of particulate positive electrode material for lithium ion cells
WO2012174653A1 (en) * 2011-06-22 2012-12-27 Phostech Lithium Inc. Improved carbon-deposited alkali metal oxyanion electrode material and process of preparing same
US8766697B2 (en) * 2012-08-01 2014-07-01 Stmicroelectronics International N.V. Level shifting circuit with adaptive feedback

Also Published As

Publication number Publication date
KR101751423B1 (ko) 2017-06-27
EP2698346A1 (en) 2014-02-19
KR20150042218A (ko) 2015-04-20
CA2877556C (en) 2020-10-06
EP2885247A2 (en) 2015-06-24
EP2885247B1 (en) 2018-03-28
JP2015526860A (ja) 2015-09-10
TW201431779A (zh) 2014-08-16
US20150232337A1 (en) 2015-08-20
WO2014027046A3 (en) 2014-04-03
WO2014027046A2 (en) 2014-02-20
CA2877556A1 (en) 2014-02-20
CN104603050B (zh) 2017-09-08
CN104603050A (zh) 2015-05-06

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