JP6555636B2 - 非水系電解質二次電池用正極活物質およびその製造方法 - Google Patents

非水系電解質二次電池用正極活物質およびその製造方法 Download PDF

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JP6555636B2
JP6555636B2 JP2015167280A JP2015167280A JP6555636B2 JP 6555636 B2 JP6555636 B2 JP 6555636B2 JP 2015167280 A JP2015167280 A JP 2015167280A JP 2015167280 A JP2015167280 A JP 2015167280A JP 6555636 B2 JP6555636 B2 JP 6555636B2
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positive electrode
tungsten
active material
lithium
electrode active
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JP2016167439A (ja
JP2016167439A5 (enExample
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佑樹 古市
佑樹 古市
小向　哲史
哲史 小向
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Sumitomo Metal Mining Co Ltd
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Sumitomo Metal Mining Co Ltd
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Priority to CN201680013218.8A priority Critical patent/CN107408690B/zh
Priority to US15/555,597 priority patent/US10854873B2/en
Priority to PCT/JP2016/056177 priority patent/WO2016140207A1/ja
Priority to EP16758900.1A priority patent/EP3267517B1/en
Priority to KR1020177027711A priority patent/KR102034270B1/ko
Publication of JP2016167439A publication Critical patent/JP2016167439A/ja
Publication of JP2016167439A5 publication Critical patent/JP2016167439A5/ja
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00—Compounds of tungsten
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
JP2015167280A 2015-03-03 2015-08-26 非水系電解質二次電池用正極活物質およびその製造方法 Active JP6555636B2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US15/555,597 US10854873B2 (en) 2015-03-03 2016-03-01 Positive electrode active material for nonaqueous electrolyte secondary batteries, and production method thereof
PCT/JP2016/056177 WO2016140207A1 (ja) 2015-03-03 2016-03-01 非水系電解質二次電池用正極活物質およびその製造方法
EP16758900.1A EP3267517B1 (en) 2015-03-03 2016-03-01 Positive electrode active substance for non-aqueous electrolyte secondary battery, and method for producing same
KR1020177027711A KR102034270B1 (ko) 2015-03-03 2016-03-01 비수계 전해질 이차 전지용 정극 활물질 및 그의 제조 방법
CN201680013218.8A CN107408690B (zh) 2015-03-03 2016-03-01 非水系电解质二次电池用正极活性物质及其制造方法
US17/076,077 US11329274B2 (en) 2015-03-03 2020-10-21 Positive electrode active material for nonaqueous electrolyte secondary batteries, and production method thereof

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JP2015041681 2015-03-03
JP2015041681 2015-03-03

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JP2016167439A JP2016167439A (ja) 2016-09-15
JP2016167439A5 JP2016167439A5 (enExample) 2018-09-27
JP6555636B2 true JP6555636B2 (ja) 2019-08-07

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US (1) US10854873B2 (enExample)
EP (1) EP3267517B1 (enExample)
JP (1) JP6555636B2 (enExample)
KR (1) KR102034270B1 (enExample)
CN (1) CN107408690B (enExample)

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JP6978182B2 (ja) * 2015-04-24 2021-12-08 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池
CN107851793B (zh) * 2015-07-30 2021-11-09 住友金属矿山株式会社 非水电解质二次电池用正极活性物质和非水电解质二次电池
KR102133916B1 (ko) 2016-12-28 2020-07-15 주식회사 엘지화학 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지
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JP7220851B2 (ja) * 2017-10-31 2023-02-13 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、及び正極活物質を用いた非水系電解質二次電池
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JP6608013B1 (ja) * 2018-08-01 2019-11-20 住友化学株式会社 リチウム二次電池用正極活物質、リチウム二次電池用正極、リチウム二次電池
JP7164006B2 (ja) * 2019-02-26 2022-11-01 住友金属鉱山株式会社 リチウムイオン二次電池用正極活物質、リチウムイオン二次電池用正極活物質の製造方法、リチウムイオン二次電池
CN113519077B (zh) * 2019-03-29 2024-08-06 松下知识产权经营株式会社 非水电解质二次电池
JP6659894B1 (ja) * 2019-04-12 2020-03-04 住友化学株式会社 リチウム金属複合酸化物粉末、リチウム二次電池用正極活物質、及びリチウム金属複合酸化物粉末の製造方法
EP3992150A4 (en) * 2019-06-25 2023-08-02 Sumitomo Metal Mining Co., Ltd. ACTIVE MATERIAL OF POSITIVE ELECTRODE FOR SECONDARY LITHIUM-ION BATTERIES, ITS PRODUCTION METHOD AND SECONDARY LITHIUM-ION BATTERY
JP7354611B2 (ja) * 2019-06-25 2023-10-03 住友金属鉱山株式会社 リチウムイオン二次電池用正極活物質とその製造方法、及び、リチウムイオン二次電池
CN114424369B (zh) 2019-09-19 2024-10-01 住友金属矿山株式会社 锂离子二次电池用正极活性物质以及锂离子二次电池
KR102691304B1 (ko) * 2020-04-17 2024-08-05 주식회사 엘지화학 양극 활물질의 제조방법
EP4186867A4 (en) * 2020-07-21 2024-09-04 Sumitomo Metal Mining Co., Ltd. METHOD FOR PRODUCING NICKEL-CONTAINING HYDROXIDE, METHOD FOR PRODUCING POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM ION SECONDARY BATTERIES, POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM ION SECONDARY BATTERIES, AND LITHIUM ION SECONDARY BATTERY
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JP5772626B2 (ja) * 2012-01-25 2015-09-02 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池
JP5370515B2 (ja) * 2012-02-22 2013-12-18 住友金属鉱山株式会社 非水系電解質二次電池用正極材料とその製造方法、および該正極材料を用いた非水系電解質二次電池
DE112012006167B4 (de) * 2012-03-30 2024-03-28 Toyota Jidosha Kabushiki Kaisha Lithium-Ionen-Sekundärbatterie
JP5999208B2 (ja) 2014-04-25 2016-09-28 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池
JP6090608B2 (ja) * 2014-11-28 2017-03-08 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池
CN107851793B (zh) * 2015-07-30 2021-11-09 住友金属矿山株式会社 非水电解质二次电池用正极活性物质和非水电解质二次电池
JP6651789B2 (ja) * 2015-10-28 2020-02-19 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質とその製造方法、及び非水系電解質二次電池

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