JP6516739B2 - 親水性/疎水性ポリマー水性エマルジョン並びにそれらに関連する製品及び方法 - Google Patents
親水性/疎水性ポリマー水性エマルジョン並びにそれらに関連する製品及び方法 Download PDFInfo
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- JP6516739B2 JP6516739B2 JP2016526275A JP2016526275A JP6516739B2 JP 6516739 B2 JP6516739 B2 JP 6516739B2 JP 2016526275 A JP2016526275 A JP 2016526275A JP 2016526275 A JP2016526275 A JP 2016526275A JP 6516739 B2 JP6516739 B2 JP 6516739B2
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- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 6
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- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 4
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
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- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
- Polymerization Catalysts (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
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| US61/896,733 | 2013-10-29 | ||
| PCT/US2014/062984 WO2015066227A1 (en) | 2013-10-29 | 2014-10-29 | Hydrophilic/hydrophobic aqueous polymer emulsions and products and methods relating thereto |
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| US11529439B2 (en) * | 2017-05-04 | 2022-12-20 | Hollister Incorporated | Lubricious hydrophilic coatings and methods of forming the same |
| US10479874B1 (en) * | 2018-02-15 | 2019-11-19 | Shimon Amdur | Latex compositions and antistatic articles manufactured therefrom |
| CN111836870B (zh) * | 2018-03-08 | 2023-03-24 | Agc株式会社 | 拒水拒油剂组合物的制造方法及拒水拒油性物品的制造方法 |
| CN112142903B (zh) * | 2019-06-28 | 2022-07-15 | 长兴化学工业(中国)有限公司 | 有机硅改性丙烯酸树脂及其制备方法 |
| CN113004826A (zh) * | 2019-12-20 | 2021-06-22 | 3M创新有限公司 | 导电胶带、层压制品及一种制备制品的方法 |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3998772A (en) | 1974-09-27 | 1976-12-21 | Alan Beerbower | Novel rubber latices and method of producing same |
| US4482577A (en) | 1980-12-16 | 1984-11-13 | Albert Goldstein | Coating process of elastomeric material |
| JPS58129065A (ja) * | 1982-01-27 | 1983-08-01 | Nippon Paint Co Ltd | 塗料組成物 |
| PT77275B (en) | 1982-09-03 | 1986-02-04 | Lrc Products | Rubber article with a lubricating layer and a process for the production thereof by dipping means |
| US4499154A (en) | 1982-09-03 | 1985-02-12 | Howard L. Podell | Dipped rubber article |
| WO1984002138A1 (en) | 1982-11-30 | 1984-06-07 | Lrc Products | Method of coating rubber or polymer articles |
| JPS60203603A (ja) * | 1984-03-29 | 1985-10-15 | Toyo Ink Mfg Co Ltd | 高濃度乳化重合体の製造方法 |
| JP2884653B2 (ja) | 1990-01-22 | 1999-04-19 | 日本油脂株式会社 | 架橋重合体微粒子及びそれを含む塗料組成物 |
| JP2663079B2 (ja) | 1992-05-05 | 1997-10-15 | 昭和高分子株式会社 | 水性撥水加工用コーティング剤 |
| JP3296524B2 (ja) | 1994-02-18 | 2002-07-02 | 日本カーバイド工業株式会社 | 水性分散液 |
| US5700585A (en) * | 1995-02-14 | 1997-12-23 | Avery Dennison Corporation | Acrylic emulsion coatings for formed articles |
| AU710920B2 (en) | 1995-02-14 | 1999-09-30 | Avery Dennison Corporation | Acrylic emulsion coatings for rubber articles |
| US6284856B1 (en) | 1995-02-14 | 2001-09-04 | Avery Dennison Corporation | Acrylate, silicone, styrene, urethane copolymer coatings for natural and synthetic rubber articles |
| JP3457795B2 (ja) | 1996-03-27 | 2003-10-20 | 三菱レイヨン株式会社 | 水性被覆組成物 |
| US6013722A (en) | 1998-01-27 | 2000-01-11 | 3M Innovative Properties Company | Non-whitening emulsion pressure sensitive adhesives |
| US6195805B1 (en) | 1998-02-27 | 2001-03-06 | Allegiance Corporation | Powder free neoprene surgical gloves |
| US6242042B1 (en) | 1998-09-14 | 2001-06-05 | Lrc Products Ltd. | Aqueous coating composition and method |
| US6391409B1 (en) | 1999-02-12 | 2002-05-21 | Allegiance Corporation | Powder-free nitrile-coated gloves with an intermediate rubber-nitrile layer between the glove and the coating and method of making same |
| US6759473B1 (en) | 1999-11-18 | 2004-07-06 | Zeon Corporation | Coating material and molded article |
| US6706836B1 (en) * | 2000-03-31 | 2004-03-16 | Avery Dennison Corporation | Hydrophilic polymers, pressure sensitive adhesives and coatings |
| US6653427B2 (en) | 2000-03-31 | 2003-11-25 | Avery Dennison Corporation | Hydrophilic polymers, pressure sensitive adhesives and coatings |
| US6683129B1 (en) | 2000-03-31 | 2004-01-27 | National Starch And Chemical Investment Holding Corporation | Salt sensitive aqueous emulsions |
| US6743880B2 (en) | 2000-03-31 | 2004-06-01 | Avery Denison Corporation | Hydrophilic polymers and methods of preparation |
| US6465591B1 (en) | 2000-04-24 | 2002-10-15 | Avery Dennison Corporation | Acrylic emulsion coating for films, paper and rubber |
| GB0025777D0 (en) | 2000-10-20 | 2000-12-06 | S S L Internat | Neoprene glove |
| JP4116884B2 (ja) | 2001-03-12 | 2008-07-09 | アレジアンス、コーポレイション | ポリイソプレン製品及びその製造プロセス |
| US7148000B2 (en) | 2001-04-23 | 2006-12-12 | Fuji Photo Film Co., Ltd. | Heat-developable photosensitive material and image-forming process |
| JP3915899B2 (ja) | 2001-06-05 | 2007-05-16 | 信越化学工業株式会社 | コーティング剤 |
| US7032251B2 (en) | 2002-12-10 | 2006-04-25 | Kimberly-Clark Worldwide, Inc. | Crosslinking agent for coated elastomeric articles |
| US6772443B2 (en) | 2002-12-30 | 2004-08-10 | Kimberly-Clark Worldwide, Inc. | Breathable elastomeric glove |
| JP2004292512A (ja) | 2003-03-25 | 2004-10-21 | Mitsubishi Rayon Co Ltd | 水性被覆組成物 |
| US7309731B2 (en) * | 2003-06-02 | 2007-12-18 | Avery Dennison Corporation | Ink-receptive coatings, composites and adhesive-containing facestocks and labels |
| US7138681B2 (en) * | 2004-07-27 | 2006-11-21 | Micron Technology, Inc. | High density stepped, non-planar nitride read only memory |
| US20060141186A1 (en) | 2004-12-28 | 2006-06-29 | Janssen Robert A | Gloves with hydrogel coating for damp hand donning and method of making same |
| US20060235131A1 (en) * | 2005-04-15 | 2006-10-19 | Hughes Kathleen A | Process for preparing aqueous dispersions of multistage emulsion polymers |
| JP2006342221A (ja) | 2005-06-08 | 2006-12-21 | Daicel Chem Ind Ltd | 水分散性樹脂組成物 |
| US7989545B2 (en) * | 2006-01-25 | 2011-08-02 | Celanese International Corporations | Salt-sensitive binders for nonwoven webs and method of making same |
| CN100516100C (zh) | 2006-05-23 | 2009-07-22 | 青岛科技大学 | 阳离子丙烯酰胺共聚物水包水乳液及其制备方法 |
| PL2094799T3 (pl) * | 2006-11-02 | 2014-01-31 | Avery Dennison Corp | Klej emulsyjny do folii zmywalnej |
| US8110266B2 (en) | 2007-02-08 | 2012-02-07 | Allegiance Corporation | Glove coating and manufacturing process |
| KR20090101119A (ko) * | 2008-03-21 | 2009-09-24 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Soi 웨이퍼의 제조 방법 |
| KR20100003912A (ko) * | 2008-07-02 | 2010-01-12 | 삼성전자주식회사 | 동일 포맷의 미디어 파일 간에 미디어 정보 호환이 가능한미디어 파일을 생성하는 방법 및 장치와 미디어 파일을실행하는 방법 및 장치 |
| WO2012014761A1 (ja) * | 2010-07-24 | 2012-02-02 | 株式会社日本触媒 | 親水化処理剤 |
| CN101948555B (zh) * | 2010-09-30 | 2013-08-21 | 东莞长联新材料科技股份有限公司 | 一种含丙烯酸酯的弹性乳液及其制备方法和复配印花胶浆 |
| CN102070738B (zh) * | 2010-11-30 | 2012-05-23 | 山东电力研究院 | 含羟基功能单体改性丙烯酸酯系共聚物乳液的制备方法 |
| CN102358769B (zh) * | 2011-08-03 | 2013-02-27 | 山东奔腾漆业有限公司 | 一种常温自交联丙烯酸乳液及其制备方法 |
| US9486399B2 (en) * | 2011-12-22 | 2016-11-08 | Rohm And Hass Company | Water resistant personal care polymers |
| CN105960418B (zh) * | 2013-10-29 | 2019-01-25 | 阿利吉安斯公司 | 亲水/疏水的水性聚合物乳液和与其相关的产品和方法 |
| SG11201603291UA (en) | 2013-10-29 | 2016-05-30 | Allegiance Corp | Hydrophilic/hydrophobic aqueous polymer emulsions and products and methods relating thereto |
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| CN110194815B (zh) | 2022-12-30 |
| EP3063181B1 (en) | 2019-01-02 |
| CN105960418A (zh) | 2016-09-21 |
| US20150284584A1 (en) | 2015-10-08 |
| JP2016536395A (ja) | 2016-11-24 |
| CN105960418B (zh) | 2019-01-25 |
| US10662347B2 (en) | 2020-05-26 |
| SG11201603374PA (en) | 2016-05-30 |
| KR102227872B1 (ko) | 2021-03-12 |
| CA2928949C (en) | 2022-10-18 |
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