JP6442134B2 - 全固体電池、及び、全固体電池の製造方法 - Google Patents
全固体電池、及び、全固体電池の製造方法 Download PDFInfo
- Publication number
- JP6442134B2 JP6442134B2 JP2013044266A JP2013044266A JP6442134B2 JP 6442134 B2 JP6442134 B2 JP 6442134B2 JP 2013044266 A JP2013044266 A JP 2013044266A JP 2013044266 A JP2013044266 A JP 2013044266A JP 6442134 B2 JP6442134 B2 JP 6442134B2
- Authority
- JP
- Japan
- Prior art keywords
- solid electrolyte
- positive electrode
- solid
- electrode layer
- negative electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007787 solid Substances 0.000 title claims description 68
- 238000004519 manufacturing process Methods 0.000 title claims description 44
- 239000007784 solid electrolyte Substances 0.000 claims description 136
- 239000011230 binding agent Substances 0.000 claims description 57
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 42
- 239000002003 electrode paste Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 21
- 239000007774 positive electrode material Substances 0.000 claims description 11
- 239000007773 negative electrode material Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 7
- 239000002001 electrolyte material Substances 0.000 claims 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 40
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 33
- 229910001416 lithium ion Inorganic materials 0.000 description 33
- 239000002245 particle Substances 0.000 description 26
- 239000000203 mixture Substances 0.000 description 17
- 239000008188 pellet Substances 0.000 description 14
- 239000010936 titanium Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 239000002203 sulfidic glass Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- 239000011149 active material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 229940058401 polytetrafluoroethylene Drugs 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 239000002174 Styrene-butadiene Substances 0.000 description 5
- 239000012300 argon atmosphere Substances 0.000 description 5
- 229910052732 germanium Inorganic materials 0.000 description 5
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910007857 Li-Al Inorganic materials 0.000 description 4
- 229910008447 Li—Al Inorganic materials 0.000 description 4
- 238000002847 impedance measurement Methods 0.000 description 4
- 239000010416 ion conductor Substances 0.000 description 4
- 150000002500 ions Chemical group 0.000 description 4
- 239000003273 ketjen black Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000012856 weighed raw material Substances 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 229910009511 Li1.5Al0.5Ge1.5(PO4)3 Inorganic materials 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000000452 restraining effect Effects 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 238000007088 Archimedes method Methods 0.000 description 2
- 229910018091 Li 2 S Inorganic materials 0.000 description 2
- 229910018130 Li 2 S-P 2 S 5 Inorganic materials 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002848 electrochemical method Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000003701 mechanical milling Methods 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910018133 Li 2 S-SiS 2 Inorganic materials 0.000 description 1
- 229910010835 LiI-Li2S-P2S5 Inorganic materials 0.000 description 1
- 229910010823 LiI—Li2S—B2S3 Inorganic materials 0.000 description 1
- 229910010840 LiI—Li2S—P2S5 Inorganic materials 0.000 description 1
- 239000002228 NASICON Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- -1 phosphoric acid compound Chemical class 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910009161 xLi2S-(1-x)P2S5 Inorganic materials 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013044266A JP6442134B2 (ja) | 2013-03-06 | 2013-03-06 | 全固体電池、及び、全固体電池の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013044266A JP6442134B2 (ja) | 2013-03-06 | 2013-03-06 | 全固体電池、及び、全固体電池の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014175080A JP2014175080A (ja) | 2014-09-22 |
| JP2014175080A5 JP2014175080A5 (enrdf_load_stackoverflow) | 2016-04-21 |
| JP6442134B2 true JP6442134B2 (ja) | 2018-12-19 |
Family
ID=51696121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013044266A Active JP6442134B2 (ja) | 2013-03-06 | 2013-03-06 | 全固体電池、及び、全固体電池の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6442134B2 (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017199539A (ja) * | 2016-04-27 | 2017-11-02 | 日本特殊陶業株式会社 | 固体電解質構造体、リチウム電池、および、固体電解質構造体の製造方法 |
| US12341199B2 (en) | 2018-03-22 | 2025-06-24 | Livent USA Corp. | Printed lithium foil and film |
| US11264598B2 (en) | 2018-03-22 | 2022-03-01 | Fmc Lithium Usa Corp. | Battery utilizing printable lithium |
| US11735764B2 (en) | 2018-03-22 | 2023-08-22 | Livent USA Corp. | Printable lithium compositions |
| KR20220144387A (ko) | 2020-02-19 | 2022-10-26 | 리벤트 유에스에이 코포레이션 | 고속 충전 사전 리튬화 규소 애노드 |
| CN111883855B (zh) * | 2020-08-31 | 2021-08-27 | 蜂巢能源科技有限公司 | 一种全固态电芯及其制备方法和固态电池 |
| US20240304854A1 (en) * | 2021-02-19 | 2024-09-12 | Honda Motor Co., Ltd. | Unit solid-state battery and method for producing unit solid-state battery |
| CN114024037A (zh) * | 2021-10-28 | 2022-02-08 | 中国第一汽车股份有限公司 | 一种固态电芯及其制备方法和储能装置 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5626360B2 (ja) * | 2010-12-08 | 2014-11-19 | トヨタ自動車株式会社 | 電極体の製造方法 |
| JP5715003B2 (ja) * | 2011-08-02 | 2015-05-07 | 日本特殊陶業株式会社 | 全固体電池、及び、全固体電池の製造方法 |
-
2013
- 2013-03-06 JP JP2013044266A patent/JP6442134B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014175080A (ja) | 2014-09-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6442134B2 (ja) | 全固体電池、及び、全固体電池の製造方法 | |
| JP6242620B2 (ja) | 全固体電池 | |
| WO2012005296A1 (ja) | 固体電解質材料およびリチウム電池 | |
| JP5970284B2 (ja) | 全固体電池 | |
| CN112088409B (zh) | 离子传导体和蓄电设备 | |
| JP6735425B2 (ja) | イオン伝導性粉末、イオン伝導性成形体および蓄電デバイス | |
| CN106104896B (zh) | 复合固体电解质和全固体电池 | |
| CN111033859A (zh) | 固体电解质及全固体电池 | |
| CN111868840B (zh) | 离子传导体和锂电池 | |
| JP2014060084A (ja) | 全固体リチウムイオン二次電池 | |
| WO2018062085A1 (ja) | 全固体リチウムイオン二次電池 | |
| JP2013051171A (ja) | 全固体電池用電極体及び全固体電池 | |
| JP2023021987A (ja) | リチウムイオン伝導性固体電解質およびリチウムイオン伝導性固体電解質の製造方法 | |
| JP2013045738A (ja) | 固体電解質焼結体、及びその製造方法、並びに全固体リチウム電池 | |
| JP7370728B2 (ja) | 全固体電池およびその製造方法 | |
| JP6063283B2 (ja) | 全固体電池、及び、全固体電池の製造方法 | |
| JP7002199B2 (ja) | 全固体電池の製造方法 | |
| WO2019004001A1 (ja) | イオン伝導複合体、全固体電池及びこれらの製造方法 | |
| JP7692365B2 (ja) | 固体電解質及び全固体電池 | |
| JP2018186016A (ja) | リチウム電池およびリチウム電池の製造方法 | |
| JP2018186017A (ja) | リチウム電池およびリチウム電池の製造方法 | |
| JP2022531386A (ja) | 多層電極－電解質部品およびそれらの生成方法 | |
| KR101627848B1 (ko) | 리튬 이차 전지용 고체 전해질, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지 | |
| JP2014116127A (ja) | 全固体電池 | |
| JP7535981B2 (ja) | 酸化物系固体電解質及び全固体リチウムイオン電池 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20140611 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160303 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160303 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20161221 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170110 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170309 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170606 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170728 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20170905 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180831 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20181126 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6442134 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |